B.08 GFI SJAFB SS033 Raw Lab Data_Jan 2023.pdf

01/17/23

Technical Report for

AECOM, INC.

Seymour Johnson AFB SS033; Goldsboro, NC

60417848

SGS Job Number: FC1820

Sampling Dates: 01/06/23 - 01/09/23

Report to:

AECOM, INC.

12120 Shamrock Plaza Suite 100 Omaha, NE 68154 jeff.aust@aecom.com; jared.desadier@aecom.com;

paul.m.wilson@aecom.com ATTN: Paul Wilson

Total number of pages in report:

Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)

DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177), AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV

This report shall not be reproduced, except in its entirety, without the written approval of SGS.

Test results relate only to samples analyzed.

SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: 407-425-6700 • fax: 407-425-0707

Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable.

Client Service contact: Muna Mohammed 407-425-6700

Norm Farmer Technical Director

Orlando, FL 01/17/23 e-Hardcopy 2.0 Automated Report

SGS is the sole authority for authorizing edits or modifications to this document.

Unauthorized modification of this report is strictly prohibited.

Review standard terms at: http://www.sgs.com/en/terms-and-conditions

The results set forth herein are provided by SGS North America Inc.

Please share your ideas about how we can serve you better at:

EHS.US.CustomerCare@sgs.com

FC1820

mailto:EHS.US.CustomerCare@sgs.com?subject=Customer care improvement idea (report FC1820)

Table of Contents -1-

Sections:

Section 1: Sample Summary Section 2: Case Narrative/Conformance Summary Section 3: Summary of Hits Section 4: Sample Results

4.1: FC1820-1: MW-5-0123

4.2: FC1820-2: MW-6-0123

4.3: FC1820-3: MW-7-0123

4.4: FC1820-4: MW-8-0123

4.5: FC1820-5: MW-10-0123

4.6: FC1820-6: IW-12-0123

4.7: FC1820-7: MW-13-0123

4.8: FC1820-8: DUP-1-0123

4.9: FC1820-9: TRIP BLANK

Section 5: Misc. Forms 5.1: Chain of Custody 5.2: QC Evaluation: DOD QSM5.x Limits

Section 6: MS Volatiles - QC Data Summaries 6.1: Method Blank Summary 6.2: Blank Spike Summary 6.3: Matrix Spike/Matrix Spike Duplicate Summary 6.4: Instrument Performance Checks (BFB) 6.5: Internal Standard Area Summaries 6.6: Surrogate Recovery Summaries 6.7: Initial and Continuing Calibration Summaries 6.8: Run Sequence Reports

Section 7: MS Volatiles - Raw Data 7.1: Samples 7.2: Method Blanks 7.3: Blank Spikes 7.4: Matrix Spike/Matrix Spike Duplicates 7.5: Instrument Performance Checks (BFB) 7.6: Initial and Continuing Calibrations 7.7: Instrument Run Logs

SGS North America Inc.

Sample Summary

AECOM, INC.

Job No: FC1820

Seymour Johnson AFB SS033; Goldsboro, NC Project No: 60417848

Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID

FC1820-1 01/06/23 13:30 TB 01/11/23 AQ Ground Water MW-5-0123

FC1820-1D 01/06/23 13:30 TB 01/11/23 AQ Water Dup/MSD MW-5-0123

FC1820-1S 01/06/23 13:30 TB 01/11/23 AQ Water Matrix Spike MW-5-0123

FC1820-2 01/09/23 14:25 TB 01/11/23 AQ Ground Water MW-6-0123

FC1820-3 01/09/23 12:30 TB 01/11/23 AQ Ground Water MW-7-0123

FC1820-4 01/09/23 11:05 TB 01/11/23 AQ Ground Water MW-8-0123

FC1820-5 01/09/23 13:40 TB 01/11/23 AQ Ground Water MW-10-0123

FC1820-6 01/09/23 13:05 TB 01/11/23 AQ Ground Water IW-12-0123

FC1820-7 01/09/23 11:40 TB 01/11/23 AQ Ground Water MW-13-0123

FC1820-8 01/06/23 09:00 TB 01/11/23 AQ Ground Water DUP-1-0123

FC1820-9 01/06/23 00:00 TB 01/11/23 AQ Trip Blank Water TRIP BLANK

SAMPLE DELIVERY GROUP CASE NARRATIVE

Client: AECOM, INC. Job No: FC1820

Site: Seymour Johnson AFB SS033; Goldsboro, NC Report Date: 1/17/2023 11:33:17 AM

On 01/11/2023, 8 Sample(s), 1 Trip Blank(s) and 0 Field Blank(s) were received at SGS North America Inc - Orlando. at a maximum corrected temperature of 1.2 C. Samples were intact and chemically preserved, unless noted below. A SGS North America Inc. - Orlando Job Number of FC1820 was assigned to the project.

Laboratory sample ID, client sample ID and dates of sample collection are detailed in the report’s Results Summary Section.

Specified quality control criteria were achieved for this job except as noted below. For more information, please refer to the analytical results and QC summary pages.

MS Volatiles By Method SW846 8260D Matrix: AQ Batch ID: V1A1711 Sample(s) FC1820-1MS, FC1820-1MSD were used as the QC samples indicated.

Matrix: AQ Batch ID: V2A1689 Sample(s) FC1741-2MS, FC1741-2MSD were used as the QC samples indicated.

V2A1689-MB: Sample was treated with an anti-foaming agent.

SGS North America Inc. - Orlando certifies that data reported for samples received, listed on the associated custody chain or analytical task order, were produced to specifications meeting the Quality System precision, accuracy and completeness objectives except as noted. Estimated non-standard method measurement uncertainty data is available on request, based on quality control bias and implicit for standard methods. Acceptable uncertainty requires tested parameter quality control data to meet method criteria.

SGS North America Inc.- Orlando is not responsible for data quality assumptions if partial reports are used and recommends that this report be used in its entirety.

Narrative prepared by:

Kim Benham, Client Services (Signature on File)

Summary of Hits Page 1 of 2 Job Number: FC1820 Account: AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC Collected: 01/06/23 thru 01/09/23

Lab Sample ID Client Sample ID Result/ Analyte Qual LOQ LOD Units Method

FC1820-1 MW-5-0123

Benzene 11.1 5.0 2.5 ug/l SW846 8260D Naphthalene 73.2 25 10 ug/l SW846 8260D Xylene (total) 375 15 7.5 ug/l SW846 8260D

FC1820-2 MW-6-0123

Benzene 2.2 1.0 0.50 ug/l SW846 8260D Naphthalene 72.1 5.0 2.0 ug/l SW846 8260D Xylene (total) 53.8 3.0 1.5 ug/l SW846 8260D

FC1820-3 MW-7-0123

No hits reported in this sample.

FC1820-4 MW-8-0123

Xylene (total) 1.9 J 3.0 1.5 ug/l SW846 8260D

FC1820-5 MW-10-0123

Benzene 3.9 1.0 0.50 ug/l SW846 8260D Naphthalene 5.1 5.0 2.0 ug/l SW846 8260D Xylene (total) 0.74 J 3.0 1.5 ug/l SW846 8260D

FC1820-6 IW-12-0123

Benzene 7.3 1.0 0.50 ug/l SW846 8260D Naphthalene 33.8 5.0 2.0 ug/l SW846 8260D Xylene (total) 97.9 3.0 1.5 ug/l SW846 8260D

FC1820-7 MW-13-0123

Benzene 13.5 5.0 2.5 ug/l SW846 8260D Naphthalene 72.9 25 10 ug/l SW846 8260D Xylene (total) 607 15 7.5 ug/l SW846 8260D

FC1820-8 DUP-1-0123

Benzene 13.6 1.0 0.50 ug/l SW846 8260D Naphthalene 84.9 5.0 2.0 ug/l SW846 8260D Xylene (total) 372 30 15 ug/l SW846 8260D

Summary of Hits Page 2 of 2

Account: AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC Collected: 01/06/23 thru 01/09/23

Lab Sample ID Client Sample ID Result/ Analyte Qual LOQ LOD Units Method

FC1820-9 TRIP BLANK

No hits reported in this sample.

Sample Results

Report of Analysis

Orlando, FL Section 4

Report of Analysis Page 1 of 1

Client Sample ID: MW-5-0123

Lab Sample ID: FC1820-1 Date Sampled: 01/06/23

Matrix: AQ - Ground Water Date Received: 01/11/23

Method: SW846 8260D Percent Solids: n/a

Project: Seymour Johnson AFB SS033; Goldsboro, NC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 1A42638.D 5 01/12/23 13:05 KG n/a n/a V1A1711

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 11.1 5.0 2.5 1.6 ug/l

91-20-3 Naphthalene 73.2 25 10 5.0 ug/l

1330-20-7 Xylene (total) 375 15 7.5 3.6 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 100% 83-118%

17060-07-0 1,2-Dichloroethane-D4 95% 79-125%

2037-26-5 Toluene-D8 104% 85-112%

460-00-4 4-Bromofluorobenzene 96% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: 1A42638.D

FC1820

4.1

Client Sample ID: MW-6-0123

Lab Sample ID: FC1820-2 Date Sampled: 01/09/23

Matrix: AQ - Ground Water Date Received: 01/11/23

Method: SW846 8260D Percent Solids: n/a

Project: Seymour Johnson AFB SS033; Goldsboro, NC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 1A42640.D 1 01/12/23 13:39 KG n/a n/a V1A1711

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 2.2 1.0 0.50 0.31 ug/l

91-20-3 Naphthalene 72.1 5.0 2.0 1.0 ug/l

1330-20-7 Xylene (total) 53.8 3.0 1.5 0.72 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 98% 83-118%

17060-07-0 1,2-Dichloroethane-D4 93% 79-125%

2037-26-5 Toluene-D8 104% 85-112%

460-00-4 4-Bromofluorobenzene 95% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: 1A42640.D

FC1820

4.2

Client Sample ID: MW-7-0123

Lab Sample ID: FC1820-3 Date Sampled: 01/09/23

Matrix: AQ - Ground Water Date Received: 01/11/23

Method: SW846 8260D Percent Solids: n/a

Project: Seymour Johnson AFB SS033; Goldsboro, NC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 1A42642.D 1 01/12/23 14:14 KG n/a n/a V1A1711

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 0.50 U 1.0 0.50 0.31 ug/l

91-20-3 Naphthalene 2.0 U 5.0 2.0 1.0 ug/l

1330-20-7 Xylene (total) 1.5 U 3.0 1.5 0.72 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 99% 83-118%

17060-07-0 1,2-Dichloroethane-D4 93% 79-125%

2037-26-5 Toluene-D8 103% 85-112%

460-00-4 4-Bromofluorobenzene 96% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: 1A42642.D

FC1820

4.3

Client Sample ID: MW-8-0123

Lab Sample ID: FC1820-4 Date Sampled: 01/09/23

Matrix: AQ - Ground Water Date Received: 01/11/23

Method: SW846 8260D Percent Solids: n/a

Project: Seymour Johnson AFB SS033; Goldsboro, NC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 1A42644.D 1 01/12/23 14:48 KG n/a n/a V1A1711

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 0.50 U 1.0 0.50 0.31 ug/l

91-20-3 Naphthalene 2.0 U 5.0 2.0 1.0 ug/l

1330-20-7 Xylene (total) 1.9 3.0 1.5 0.72 ug/l J

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 100% 83-118%

17060-07-0 1,2-Dichloroethane-D4 93% 79-125%

2037-26-5 Toluene-D8 103% 85-112%

460-00-4 4-Bromofluorobenzene 96% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: 1A42644.D

FC1820

4.4

Client Sample ID: MW-10-0123

Lab Sample ID: FC1820-5 Date Sampled: 01/09/23

Matrix: AQ - Ground Water Date Received: 01/11/23

Method: SW846 8260D Percent Solids: n/a

Project: Seymour Johnson AFB SS033; Goldsboro, NC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 1A42646.D 1 01/12/23 15:23 KG n/a n/a V1A1711

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 3.9 1.0 0.50 0.31 ug/l

91-20-3 Naphthalene 5.1 5.0 2.0 1.0 ug/l

1330-20-7 Xylene (total) 0.74 3.0 1.5 0.72 ug/l J

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 99% 83-118%

17060-07-0 1,2-Dichloroethane-D4 94% 79-125%

2037-26-5 Toluene-D8 105% 85-112%

460-00-4 4-Bromofluorobenzene 93% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: 1A42646.D

FC1820

4.5

Client Sample ID: IW-12-0123

Lab Sample ID: FC1820-6 Date Sampled: 01/09/23

Matrix: AQ - Ground Water Date Received: 01/11/23

Method: SW846 8260D Percent Solids: n/a

Project: Seymour Johnson AFB SS033; Goldsboro, NC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 2A42701.D 1 01/13/23 16:50 KG n/a n/a V2A1689

Run #2 1A42648.D 5 01/12/23 15:57 KG n/a n/a V1A1711

Purge Volume

Run #1 5.0 ml

Run #2 5.0 ml

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 7.3 1.0 0.50 0.31 ug/l

91-20-3 Naphthalene 33.8 5.0 2.0 1.0 ug/l

1330-20-7 Xylene (total) 97.9 3.0 1.5 0.72 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 96% 99% 83-118%

17060-07-0 1,2-Dichloroethane-D4 90% 94% 79-125%

2037-26-5 Toluene-D8 106% 103% 85-112%

460-00-4 4-Bromofluorobenzene 95% 95% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: 2A42701.D 1A42648.D

FC1820

4.6

Client Sample ID: MW-13-0123

Lab Sample ID: FC1820-7 Date Sampled: 01/09/23

Matrix: AQ - Ground Water Date Received: 01/11/23

Method: SW846 8260D Percent Solids: n/a

Project: Seymour Johnson AFB SS033; Goldsboro, NC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 1A42650.D 5 01/12/23 16:32 KG n/a n/a V1A1711

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 13.5 5.0 2.5 1.6 ug/l

91-20-3 Naphthalene 72.9 25 10 5.0 ug/l

1330-20-7 Xylene (total) 607 15 7.5 3.6 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 98% 83-118%

17060-07-0 1,2-Dichloroethane-D4 93% 79-125%

2037-26-5 Toluene-D8 104% 85-112%

460-00-4 4-Bromofluorobenzene 94% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: 1A42650.D

FC1820

4.7

Client Sample ID: DUP-1-0123

Lab Sample ID: FC1820-8 Date Sampled: 01/06/23

Matrix: AQ - Ground Water Date Received: 01/11/23

Method: SW846 8260D Percent Solids: n/a

Project: Seymour Johnson AFB SS033; Goldsboro, NC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 1A42652.D 1 01/12/23 17:06 KG n/a n/a V1A1711

Run #2 2A42703.D 10 01/13/23 17:24 KG n/a n/a V2A1689

Purge Volume

Run #1 5.0 ml

Run #2 5.0 ml

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 13.6 1.0 0.50 0.31 ug/l

91-20-3 Naphthalene 84.9 5.0 2.0 1.0 ug/l

1330-20-7 Xylene (total) 372 a 30 15 7.2 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 99% 99% 83-118%

17060-07-0 1,2-Dichloroethane-D4 93% 93% 79-125%

2037-26-5 Toluene-D8 108% 104% 85-112%

460-00-4 4-Bromofluorobenzene 96% 95% 83-118%

(a) Result is from Run# 2

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: 1A42652.D 2A42703.D

FC1820

4.8

Client Sample ID: TRIP BLANK

Lab Sample ID: FC1820-9 Date Sampled: 01/06/23

Matrix: AQ - Trip Blank Water Date Received: 01/11/23

Method: SW846 8260D Percent Solids: n/a

Project: Seymour Johnson AFB SS033; Goldsboro, NC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 1A42636.D 1 01/12/23 12:31 KG n/a n/a V1A1711

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 0.50 U 1.0 0.50 0.31 ug/l

91-20-3 Naphthalene 2.0 U 5.0 2.0 1.0 ug/l

1330-20-7 Xylene (total) 1.5 U 3.0 1.5 0.72 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 99% 83-118%

17060-07-0 1,2-Dichloroethane-D4 93% 79-125%

2037-26-5 Toluene-D8 103% 85-112%

460-00-4 4-Bromofluorobenzene 94% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: 1A42636.D

FC1820

4.9

Misc. Forms

Custody Documents and Other Forms

Includes the following where applicable:

• Chain of Custody

• QC Evaluation: DOD QSM5.x Limits

Orlando, FL Section 5

FC1820: Chain of Custody

FC1820

5.1

Job Number: FC1820 Client: AECOM

Date / Time Received: 1/11/2023 9:30:00 AM Delivery Method: FX

Project: STAFB - SS033

Airbill #'s: 570790504809

Cooler Information

1. Custody Seals Present

2. Custody Seals Intact

4. Cooler temp verification

3. Temp criteria achieved

5. Cooler media

IR Gun

Ice (Bag)

Trip Blank Information

1. Trip Blank present / cooler

2. Trip Blank listed on COC

2. Samples preserved properly

Sample Information

1. Sample labels present on bottles

5. Sample recvd within HT

4. Condition of sample

3. Sufficient volume/containers recvd for analysis:

Intact

Comments

SM001

Rev. Date 05/24/17

SGS Sample Receipt Summary

Cooler Temps (Raw Measured) °C:

Cooler Temps (Corrected) °C:

Cooler 1: (1.0);

Cooler 1: (1.2);

3. Type Of TB Received

W or S N/A

6. Dates/Times/IDs on COC match Sample Label

7. VOCs have headspace

8. Bottles received for unspecified tests

9. Compositing instructions clear

10. Voa Soil Kits/Jars received past 48hrs?

11. % Solids Jar received?

Misc. Information

25-Gram 5-GramNumber of Encores: Number of 5035 Field Kits: Number of Lab Filtered Metals:

Test Strip Lot #s: pH 0-3 230315 pH 10-12 219813A Other: (Specify)

Y or N N/A

Y or N

Therm ID: IR 1; Therm CF: 0.2; # of Coolers: 1

Y or N N/A

12. Residual Chlorine Present?

Residual Chlorine Test Strip Lot #:

Technician: Reviewer:NATHANS Date:Date: 1/11/2023 9:30:00 AM

FC1820: Chain of Custody

FC1820

5.1

QC Evaluation: DOD QSM5.x Limits Page 1 of 3

Account: AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC Collected: 01/06/23 thru 01/09/23

QC Sample ID CAS# Analyte Sample Result Result Units Limits Type Type

V1A1711 SW846 8260D

V1A1711-BS 71-43-2 Benzene BSP REC 88 % 79-120 V1A1711-BS 91-20-3 Naphthalene BSP REC 78 % 61-128 V1A1711-BS 1330-20-7 Xylene (total) BSP REC 93 % 79-121 V1A1711-BS 1868-53-7 Dibromofluoromethane BSP SURR 99 % 80-119 V1A1711-BS 17060-07-0 1,2-Dichloroethane-D4 BSP SURR 96 % 81-118 V1A1711-BS 2037-26-5 Toluene-D8 BSP SURR 101 % 89-112 V1A1711-BS 460-00-4 4-Bromofluorobenzene BSP SURR 96 % 85-114 FC1820-1MS 71-43-2 Benzene MS REC 88 % 79-120 FC1820-1MS 91-20-3 Naphthalene MS REC 82 % 61-128 FC1820-1MS 1330-20-7 Xylene (total) MS REC 86 % 79-121 FC1820-1MS 1868-53-7 Dibromofluoromethane MS SURR 100 % 80-119 FC1820-1MS 17060-07-0 1,2-Dichloroethane-D4 MS SURR 95 % 81-118 FC1820-1MS 2037-26-5 Toluene-D8 MS SURR 100 % 89-112 FC1820-1MS 460-00-4 4-Bromofluorobenzene MS SURR 94 % 85-114 FC1820-1MSD 71-43-2 Benzene MSD REC 85 % 79-120 FC1820-1MSD 71-43-2 Benzene MSD RPD 3 % 20 FC1820-1MSD 91-20-3 Naphthalene MSD REC 79 % 61-128 FC1820-1MSD 91-20-3 Naphthalene MSD RPD 2 % 20 FC1820-1MSD 1330-20-7 Xylene (total) MSD REC 81 % 79-121 FC1820-1MSD 1330-20-7 Xylene (total) MSD RPD 3 % 20 FC1820-1MSD 1868-53-7 Dibromofluoromethane MSD SURR 100 % 80-119 FC1820-1MSD 17060-07-0 1,2-Dichloroethane-D4 MSD SURR 96 % 81-118 FC1820-1MSD 2037-26-5 Toluene-D8 MSD SURR 101 % 89-112 FC1820-1MSD 460-00-4 4-Bromofluorobenzene MSD SURR 95 % 85-114 V1A1711-MB 1868-53-7 Dibromofluoromethane MB SURR 99 % 80-119 V1A1711-MB 17060-07-0 1,2-Dichloroethane-D4 MB SURR 93 % 81-118 V1A1711-MB 2037-26-5 Toluene-D8 MB SURR 103 % 89-112 V1A1711-MB 460-00-4 4-Bromofluorobenzene MB SURR 94 % 85-114 FC1820-1 1868-53-7 Dibromofluoromethane SAMP SURR 100 % 80-119 FC1820-1 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 95 % 81-118 FC1820-1 2037-26-5 Toluene-D8 SAMP SURR 104 % 89-112 FC1820-1 460-00-4 4-Bromofluorobenzene SAMP SURR 96 % 85-114 FC1820-2 1868-53-7 Dibromofluoromethane SAMP SURR 98 % 80-119 FC1820-2 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 93 % 81-118 FC1820-2 2037-26-5 Toluene-D8 SAMP SURR 104 % 89-112 FC1820-2 460-00-4 4-Bromofluorobenzene SAMP SURR 95 % 85-114 FC1820-3 1868-53-7 Dibromofluoromethane SAMP SURR 99 % 80-119 FC1820-3 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 93 % 81-118 FC1820-3 2037-26-5 Toluene-D8 SAMP SURR 103 % 89-112 FC1820-3 460-00-4 4-Bromofluorobenzene SAMP SURR 96 % 85-114 FC1820-4 1868-53-7 Dibromofluoromethane SAMP SURR 100 % 80-119 FC1820-4 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 93 % 81-118

* Sample used for QC is not from job FC1820

FC1820

5.2

QC Evaluation: DOD QSM5.x Limits Page 2 of 3

Account: AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC Collected: 01/06/23 thru 01/09/23

QC Sample ID CAS# Analyte Sample Result Result Units Limits Type Type

FC1820-4 2037-26-5 Toluene-D8 SAMP SURR 103 % 89-112 FC1820-4 460-00-4 4-Bromofluorobenzene SAMP SURR 96 % 85-114 FC1820-5 1868-53-7 Dibromofluoromethane SAMP SURR 99 % 80-119 FC1820-5 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 94 % 81-118 FC1820-5 2037-26-5 Toluene-D8 SAMP SURR 105 % 89-112 FC1820-5 460-00-4 4-Bromofluorobenzene SAMP SURR 93 % 85-114 FC1820-6 1868-53-7 Dibromofluoromethane SAMP SURR 99 % 80-119 FC1820-6 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 94 % 81-118 FC1820-6 2037-26-5 Toluene-D8 SAMP SURR 103 % 89-112 FC1820-6 460-00-4 4-Bromofluorobenzene SAMP SURR 95 % 85-114 FC1820-7 1868-53-7 Dibromofluoromethane SAMP SURR 98 % 80-119 FC1820-7 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 93 % 81-118 FC1820-7 2037-26-5 Toluene-D8 SAMP SURR 104 % 89-112 FC1820-7 460-00-4 4-Bromofluorobenzene SAMP SURR 94 % 85-114 FC1820-8 1868-53-7 Dibromofluoromethane SAMP SURR 99 % 80-119 FC1820-8 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 93 % 81-118 FC1820-8 2037-26-5 Toluene-D8 SAMP SURR 108 % 89-112 FC1820-8 460-00-4 4-Bromofluorobenzene SAMP SURR 96 % 85-114 FC1820-9 1868-53-7 Dibromofluoromethane SAMP SURR 99 % 80-119 FC1820-9 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 93 % 81-118 FC1820-9 2037-26-5 Toluene-D8 SAMP SURR 103 % 89-112 FC1820-9 460-00-4 4-Bromofluorobenzene SAMP SURR 94 % 85-114

V2A1689 SW846 8260D

V2A1689-BS 71-43-2 Benzene BSP REC 88 % 79-120 V2A1689-BS 91-20-3 Naphthalene BSP REC 89 % 61-128 V2A1689-BS 1330-20-7 Xylene (total) BSP REC 93 % 79-121 V2A1689-BS 1868-53-7 Dibromofluoromethane BSP SURR 99 % 80-119 V2A1689-BS 17060-07-0 1,2-Dichloroethane-D4 BSP SURR 93 % 81-118 V2A1689-BS 2037-26-5 Toluene-D8 BSP SURR 102 % 89-112 V2A1689-BS 460-00-4 4-Bromofluorobenzene BSP SURR 95 % 85-114 FC1741-2MS* 71-43-2 Benzene MS REC 92 % 79-120 FC1741-2MS* 91-20-3 Naphthalene MS REC 92 % 61-128 FC1741-2MS* 1330-20-7 Xylene (total) MS REC 95 % 79-121 FC1741-2MS* 1868-53-7 Dibromofluoromethane MS SURR 98 % 80-119 FC1741-2MS* 17060-07-0 1,2-Dichloroethane-D4 MS SURR 94 % 81-118 FC1741-2MS* 2037-26-5 Toluene-D8 MS SURR 101 % 89-112 FC1741-2MS* 460-00-4 4-Bromofluorobenzene MS SURR 94 % 85-114 FC1741-2MSD* 71-43-2 Benzene MSD REC 88 % 79-120 FC1741-2MSD* 71-43-2 Benzene MSD RPD 4 % 20 FC1741-2MSD* 91-20-3 Naphthalene MSD REC 90 % 61-128 FC1741-2MSD* 91-20-3 Naphthalene MSD RPD 2 % 20 FC1741-2MSD* 1330-20-7 Xylene (total) MSD REC 91 % 79-121 FC1741-2MSD* 1330-20-7 Xylene (total) MSD RPD 4 % 20

* Sample used for QC is not from job FC1820

FC1820

QC Evaluation: DOD QSM5.x Limits Page 3 of 3

Account: AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC Collected: 01/06/23 thru 01/09/23

QC Sample ID CAS# Analyte Sample Result Result Units Limits Type Type

FC1741-2MSD* 1868-53-7 Dibromofluoromethane MSD SURR 100 % 80-119 FC1741-2MSD* 17060-07-0 1,2-Dichloroethane-D4 MSD SURR 94 % 81-118 FC1741-2MSD* 2037-26-5 Toluene-D8 MSD SURR 101 % 89-112 FC1741-2MSD* 460-00-4 4-Bromofluorobenzene MSD SURR 94 % 85-114 V2A1689-MB 1868-53-7 Dibromofluoromethane MB SURR 102 % 80-119 V2A1689-MB 17060-07-0 1,2-Dichloroethane-D4 MB SURR 93 % 81-118 V2A1689-MB 2037-26-5 Toluene-D8 MB SURR 103 % 89-112 V2A1689-MB 460-00-4 4-Bromofluorobenzene MB SURR 92 % 85-114 FC1820-6 1868-53-7 Dibromofluoromethane SAMP SURR 96 % 80-119 FC1820-6 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 90 % 81-118 FC1820-6 2037-26-5 Toluene-D8 SAMP SURR 106 % 89-112 FC1820-6 460-00-4 4-Bromofluorobenzene SAMP SURR 95 % 85-114 FC1820-8 1868-53-7 Dibromofluoromethane SAMP SURR 99 % 80-119 FC1820-8 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 93 % 81-118 FC1820-8 2037-26-5 Toluene-D8 SAMP SURR 104 % 89-112 FC1820-8 460-00-4 4-Bromofluorobenzene SAMP SURR 95 % 85-114

* Sample used for QC is not from job FC1820

FC1820

MS Volatiles

QC Data Summaries

Includes the following where applicable:

• Method Blank Summaries

• Blank Spike Summaries

• Matrix Spike and Duplicate Summaries

• Instrument Performance Checks (BFB)

• Internal Standard Area Summaries

• Surrogate Recovery Summaries

• Initial and Continuing Calibration Summaries

• Run Sequence Reports

Orlando, FL Section 6

Method Blank Summary Page 1 of 1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1A1711-MB 1A42634.D 1 01/12/23 KG n/a n/a V1A1711

The QC reported here applies to the following samples: Method: SW846 8260D

FC1820-1, FC1820-2, FC1820-3, FC1820-4, FC1820-5, FC1820-6, FC1820-7, FC1820-8, FC1820-9

CAS No. Compound Result RL MDL Units Q

71-43-2 Benzene ND 1.0 0.31 ug/l 91-20-3 Naphthalene ND 5.0 1.0 ug/l 1330-20-7 Xylene (total) ND 3.0 0.72 ug/l

CAS No. Surrogate Recoveries Limits

1868-53-7 Dibromofluoromethane 99% 83-118% 17060-07-0 1,2-Dichloroethane-D4 93% 79-125% 2037-26-5 Toluene-D8 103% 85-112% 460-00-4 4-Bromofluorobenzene 94% 83-118%

Raw Data: 1A42634.D

FC1820

6.1.1

Method Blank Summary Page 1 of 1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2A1689-MB a 2A42681.D 1 01/13/23 KG n/a n/a V2A1689

The QC reported here applies to the following samples: Method: SW846 8260D

FC1820-6, FC1820-8

CAS No. Compound Result RL MDL Units Q

71-43-2 Benzene ND 1.0 0.31 ug/l 91-20-3 Naphthalene ND 5.0 1.0 ug/l 1330-20-7 Xylene (total) ND 3.0 0.72 ug/l

CAS No. Surrogate Recoveries Limits

1868-53-7 Dibromofluoromethane 102% 83-118% 17060-07-0 1,2-Dichloroethane-D4 93% 79-125% 2037-26-5 Toluene-D8 103% 85-112% 460-00-4 4-Bromofluorobenzene 92% 83-118%

(a) Sample was treated with an anti-foaming agent.

Raw Data: 2A42681.D

FC1820

6.1.2

Blank Spike Summary Page 1 of 1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1A1711-BS 1A42630.D 1 01/12/23 KG n/a n/a V1A1711

The QC reported here applies to the following samples: Method: SW846 8260D

FC1820-1, FC1820-2, FC1820-3, FC1820-4, FC1820-5, FC1820-6, FC1820-7, FC1820-8, FC1820-9

Spike BSP BSP CAS No. Compound ug/l ug/l % Limits

71-43-2 Benzene 25 22.0 88 81-122 91-20-3 Naphthalene 25 19.6 78 63-132 1330-20-7 Xylene (total) 75 69.4 93 80-126

CAS No. Surrogate Recoveries BSP Limits

1868-53-7 Dibromofluoromethane 99% 83-118% 17060-07-0 1,2-Dichloroethane-D4 96% 79-125% 2037-26-5 Toluene-D8 101% 85-112% 460-00-4 4-Bromofluorobenzene 96% 83-118%

* = Outside of Control Limits.

Raw Data: 1A42630.D

FC1820

6.2.1

Blank Spike Summary Page 1 of 1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2A1689-BS 2A42677.D 1 01/13/23 KG n/a n/a V2A1689

The QC reported here applies to the following samples: Method: SW846 8260D

FC1820-6, FC1820-8

Spike BSP BSP CAS No. Compound ug/l ug/l % Limits

71-43-2 Benzene 25 22.1 88 81-122 91-20-3 Naphthalene 25 22.3 89 63-132 1330-20-7 Xylene (total) 75 69.5 93 80-126

CAS No. Surrogate Recoveries BSP Limits

1868-53-7 Dibromofluoromethane 99% 83-118% 17060-07-0 1,2-Dichloroethane-D4 93% 79-125% 2037-26-5 Toluene-D8 102% 85-112% 460-00-4 4-Bromofluorobenzene 95% 83-118%

* = Outside of Control Limits.

Raw Data: 2A42677.D

FC1820

6.2.2

Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch FC1820-1MS 1A42664.D 5 01/12/23 KG n/a n/a V1A1711 FC1820-1MSD 1A42666.D 5 01/12/23 KG n/a n/a V1A1711 FC1820-1 1A42638.D 5 01/12/23 KG n/a n/a V1A1711

The QC reported here applies to the following samples: Method: SW846 8260D

FC1820-1, FC1820-2, FC1820-3, FC1820-4, FC1820-5, FC1820-6, FC1820-7, FC1820-8, FC1820-9

FC1820-1 Spike MS MS Spike MSD MSD Limits CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

71-43-2 Benzene 11.1 125 121 88 125 117 85 3 81-122/14 91-20-3 Naphthalene 73.2 125 176 82 125 172 79 2 63-132/25 1330-20-7 Xylene (total) 375 375 696 86 375 677 81 3 80-126/15

CAS No. Surrogate Recoveries MS MSD FC1820-1 Limits

1868-53-7 Dibromofluoromethane 100% 100% 100% 83-118% 17060-07-0 1,2-Dichloroethane-D4 95% 96% 95% 79-125% 2037-26-5 Toluene-D8 100% 101% 104% 85-112% 460-00-4 4-Bromofluorobenzene 94% 95% 96% 83-118%

* = Outside of Control Limits.

Raw Data: 1A42664.D 1A42666.D

FC1820

6.3.1

Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch FC1741-2MS 2A42711.D 10 01/13/23 KG n/a n/a V2A1689 FC1741-2MSD 2A42713.D 10 01/13/23 KG n/a n/a V2A1689 FC1741-2 2A42687.D 1 01/13/23 KG n/a n/a V2A1689

The QC reported here applies to the following samples: Method: SW846 8260D

FC1820-6, FC1820-8

FC1741-2 Spike MS MS Spike MSD MSD Limits CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

71-43-2 Benzene 1.0 U 250 231 92 250 221 88 4 81-122/14 91-20-3 Naphthalene 5.0 U 250 229 92 250 224 90 2 63-132/25 1330-20-7 Xylene (total) 3.0 U 750 716 95 750 685 91 4 80-126/15

CAS No. Surrogate Recoveries MS MSD FC1741-2 Limits

1868-53-7 Dibromofluoromethane 98% 100% 100% 83-118% 17060-07-0 1,2-Dichloroethane-D4 94% 94% 93% 79-125% 2037-26-5 Toluene-D8 101% 101% 104% 85-112% 460-00-4 4-Bromofluorobenzene 94% 94% 97% 83-118%

* = Outside of Control Limits.

Raw Data: 2A42711.D 2A42713.D

FC1820

6.3.2

Instrument Performance Check (BFB) Page 1 of 1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Sample: V1A1700-BFB Injection Date: 12/16/22 Lab File ID: 1A42170.D Injection Time: 08:38 Instrument ID: GCMS1A

Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail

50 15.0 - 40.0% of mass 95 9303 18.2 Pass 75 30.0 - 60.0% of mass 95 24882 48.6 Pass 95 Base peak, 100% relative abundance 51205 100.0 Pass 96 5.0 - 9.0% of mass 95 3433 6.70 Pass 173 Less than 2.0% of mass 174 316 0.62 (0.70) a Pass 174 50.0 - 100.0% of mass 95 44958 87.8 Pass 175 5.0 - 9.0% of mass 174 3172 6.19 (7.06) a Pass 176 95.0 - 101.0% of mass 174 44027 86.0 (97.9) a Pass 177 5.0 - 9.0% of mass 176 2898 5.66 (6.58) b Pass

(a) Value is % of mass 174

(b) Value is % of mass 176

This check applies to the following Samples, MS, MSD, Blanks, and Standards:

Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID

V1A1700-IC1700 1A42172.D 12/16/22 09:51 01:13 Initial cal 1 V1A1700-IC1700 1A42174.D 12/16/22 10:26 01:48 Initial cal 2 V1A1700-IC1700 1A42176.D 12/16/22 11:01 02:23 Initial cal 3 V1A1700-IC1700 1A42178.D 12/16/22 11:37 02:59 Initial cal 4 V1A1700-ICC1700 1A42180.D 12/16/22 12:14 03:36 Initial cal 5 V1A1700-IC1700 1A42182.D 12/16/22 12:49 04:11 Initial cal 6 V1A1700-IC1700 1A42184.D 12/16/22 13:23 04:45 Initial cal 7 V1A1700-ICV1700 1A42188.D 12/16/22 15:02 06:24 Initial cal verification 5 V1A1700-ICV1700 1A42190.D 12/16/22 15:37 06:59 Initial cal verification 4

Raw Data: 1A42170.D

FC1820

6.4.1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Sample: V1A1711-BFB Injection Date: 01/12/23 Lab File ID: 1A42624.D Injection Time: 09:04 Instrument ID: GCMS1A

Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail

50 15.0 - 40.0% of mass 95 7270 17.1 Pass 75 30.0 - 60.0% of mass 95 20124 47.3 Pass 95 Base peak, 100% relative abundance 42531 100.0 Pass 96 5.0 - 9.0% of mass 95 2979 7.00 Pass 173 Less than 2.0% of mass 174 246 0.58 (0.59) a Pass 174 50.0 - 100.0% of mass 95 41613 97.8 Pass 175 5.0 - 9.0% of mass 174 2925 6.88 (7.03) a Pass 176 95.0 - 101.0% of mass 174 40003 94.1 (96.1) a Pass 177 5.0 - 9.0% of mass 176 2708 6.37 (6.77) b Pass

(a) Value is % of mass 174

(b) Value is % of mass 176

This check applies to the following Samples, MS, MSD, Blanks, and Standards:

Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID

V1A1711-CC1700 1A42628.D 01/12/23 10:13 01:09 Continuing cal 5 V1A1711-BS 1A42630.D 01/12/23 10:47 01:43 Blank Spike V1A1711-MB 1A42634.D 01/12/23 11:56 02:52 Method Blank

FC1820-9 1A42636.D 01/12/23 12:31 03:27 TRIP BLANK

FC1820-1 1A42638.D 01/12/23 13:05 04:01 MW-5-0123

FC1820-2 1A42640.D 01/12/23 13:39 04:35 MW-6-0123

FC1820-3 1A42642.D 01/12/23 14:14 05:10 MW-7-0123

FC1820-4 1A42644.D 01/12/23 14:48 05:44 MW-8-0123

FC1820-5 1A42646.D 01/12/23 15:23 06:19 MW-10-0123

FC1820-6 1A42648.D 01/12/23 15:57 06:53 IW-12-0123

FC1820-7 1A42650.D 01/12/23 16:32 07:28 MW-13-0123

FC1820-8 1A42652.D 01/12/23 17:06 08:02 DUP-1-0123

ZZZZZZ 1A42654.D 01/12/23 17:41 08:37 (unrelated sample) ZZZZZZ 1A42656.D 01/12/23 18:15 09:11 (unrelated sample) ZZZZZZ 1A42658.D 01/12/23 18:49 09:45 (unrelated sample) ZZZZZZ 1A42660.D 01/12/23 19:24 10:20 (unrelated sample) FC1820-1MS 1A42664.D 01/12/23 20:33 11:29 Matrix Spike FC1820-1MSD 1A42666.D 01/12/23 21:07 12:03 Matrix Spike Duplicate V1A1711-ECC1700 1A42668.D 01/12/23 21:41 12:37 Ending cal 5

Raw Data: 1A42624.D

FC1820

6.4.2

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Sample: V2A1677-BFB Injection Date: 12/16/22 Lab File ID: 2A42171.D Injection Time: 08:55 Instrument ID: GCMS2A

Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail

50 15.0 - 40.0% of mass 95 9531 17.8 Pass 75 30.0 - 60.0% of mass 95 26064 48.7 Pass 95 Base peak, 100% relative abundance 53549 100.0 Pass 96 5.0 - 9.0% of mass 95 3467 6.47 Pass 173 Less than 2.0% of mass 174 335 0.63 (0.70) a Pass 174 50.0 - 100.0% of mass 95 47877 89.4 Pass 175 5.0 - 9.0% of mass 174 3469 6.48 (7.25) a Pass 176 95.0 - 101.0% of mass 174 47005 87.8 (98.2) a Pass 177 5.0 - 9.0% of mass 176 3012 5.62 (6.41) b Pass

(a) Value is % of mass 174

(b) Value is % of mass 176

This check applies to the following Samples, MS, MSD, Blanks, and Standards:

Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID

V2A1677-IC1677 2A42173.D 12/16/22 10:08 01:13 Initial cal 1 V2A1677-IC1677 2A42175.D 12/16/22 10:43 01:48 Initial cal 2 V2A1677-IC1677 2A42177.D 12/16/22 11:19 02:24 Initial cal 3 V2A1677-IC1677 2A42179.D 12/16/22 11:54 02:59 Initial cal 4 V2A1677-ICC1677 2A42181.D 12/16/22 12:31 03:36 Initial cal 5 V2A1677-IC1677 2A42183.D 12/16/22 13:06 04:11 Initial cal 6 V2A1677-IC1677 2A42185.D 12/16/22 13:41 04:46 Initial cal 7 V2A1677-ICV1677 2A42189.D 12/16/22 15:19 06:24 Initial cal verification 5 V2A1677-BS 2A42191.D 12/16/22 15:54 06:59 Blank Spike V2A1677-MB 2A42193.D 12/16/22 16:42 07:47 Method Blank ZZZZZZ 2A42194.D 12/16/22 17:06 08:11 (unrelated sample) ZZZZZZ 2A42195.D 12/16/22 17:30 08:35 (unrelated sample) ZZZZZZ 2A42196.D 12/16/22 17:54 08:59 (unrelated sample) ZZZZZZ 2A42197.D 12/16/22 18:18 09:23 (unrelated sample) ZZZZZZ 2A42198.D 12/16/22 18:43 09:48 (unrelated sample) ZZZZZZ 2A42199.D 12/16/22 19:07 10:12 (unrelated sample) ZZZZZZ 2A42200.D 12/16/22 19:31 10:36 (unrelated sample) V2A1677-ECC1677 2A42201.D 12/16/22 19:55 11:00 Ending cal 5

Raw Data: 2A42171.D

FC1820

6.4.3

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Sample: V2A1689-BFB Injection Date: 01/13/23 Lab File ID: 2A42673.D Injection Time: 08:44 Instrument ID: GCMS2A

Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail

50 15.0 - 40.0% of mass 95 6387 16.0 Pass 75 30.0 - 60.0% of mass 95 18724 47.0 Pass 95 Base peak, 100% relative abundance 39851 100.0 Pass 96 5.0 - 9.0% of mass 95 2691 6.75 Pass 173 Less than 2.0% of mass 174 249 0.62 (0.64) a Pass 174 50.0 - 100.0% of mass 95 38685 97.1 Pass 175 5.0 - 9.0% of mass 174 2729 6.85 (7.05) a Pass 176 95.0 - 101.0% of mass 174 37640 94.5 (97.3) a Pass 177 5.0 - 9.0% of mass 176 2509 6.30 (6.67) b Pass

(a) Value is % of mass 174

(b) Value is % of mass 176

This check applies to the following Samples, MS, MSD, Blanks, and Standards:

Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID

V2A1689-CC1677 2A42675.D 01/13/23 09:18 00:34 Continuing cal 5 V2A1689-BS 2A42677.D 01/13/23 09:53 01:09 Blank Spike V2A1689-MB 2A42681.D 01/13/23 11:02 02:18 Method Blank ZZZZZZ 2A42683.D 01/13/23 11:37 02:53 (unrelated sample) ZZZZZZ 2A42685.D 01/13/23 12:12 03:28 (unrelated sample) FC1741-2 2A42687.D 01/13/23 12:47 04:03 (used for QC only; not part of job FC1820) ZZZZZZ 2A42689.D 01/13/23 13:21 04:37 (unrelated sample) ZZZZZZ 2A42691.D 01/13/23 13:56 05:12 (unrelated sample) ZZZZZZ 2A42693.D 01/13/23 14:31 05:47 (unrelated sample) ZZZZZZ 2A42695.D 01/13/23 15:06 06:22 (unrelated sample) ZZZZZZ 2A42697.D 01/13/23 15:41 06:57 (unrelated sample) ZZZZZZ 2A42699.D 01/13/23 16:16 07:32 (unrelated sample)

FC1820-6 2A42701.D 01/13/23 16:50 08:06 IW-12-0123

FC1820-8 2A42703.D 01/13/23 17:24 08:40 DUP-1-0123

ZZZZZZ 2A42705.D 01/13/23 17:58 09:14 (unrelated sample) ZZZZZZ 2A42707.D 01/13/23 18:32 09:48 (unrelated sample) ZZZZZZ 2A42709.D 01/13/23 19:06 10:22 (unrelated sample) FC1741-2MS 2A42711.D 01/13/23 19:40 10:56 Matrix Spike FC1741-2MSD 2A42713.D 01/13/23 20:14 11:30 Matrix Spike Duplicate V2A1689-ECC1677 2A42715.D 01/13/23 20:48 12:04 Ending cal 5

Raw Data: 2A42673.D

FC1820

6.4.4

Internal Standard Area Summary Page 1 of 1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Check Std: V1A1711-CC1700 Injection Date: 01/12/23 Lab File ID: 1A42628.D Injection Time: 10:13 Instrument ID: GCMS1A Method: SW846 8260D

IS 1 IS 2 IS 3

AREA RT AREA RT AREA RT

Initial Cal a 237594 3.65 181476 5.64 88622 7.38

Check Std b 204443 3.65 152239 5.63 84686 7.38 Upper Limit c 408886 3.82 304478 5.80 169372 7.55 Lower Limit d 102222 3.48 76120 5.46 42343 7.21

Lab IS 1 IS 2 IS 3 Sample ID AREA RT AREA RT AREA RT

V1A1711-BS 206194 3.65 152672 5.63 88068 7.38

V1A1711-MB 178820 3.65 133495 5.63 76115 7.38

FC1820-9 182752 3.65 136009 5.63 76582 7.38

FC1820-1 182441 3.65 137765 5.63 79532 7.38

FC1820-2 183695 3.65 141275 5.63 82284 7.38

FC1820-3 184243 3.65 138363 5.63 78177 7.38

FC1820-4 176236 3.65 132351 5.63 74428 7.38

FC1820-5 181046 3.65 136641 5.63 79202 7.38

FC1820-6 176019 3.65 131939 5.63 75113 7.38

FC1820-7 176362 3.65 132172 5.63 77020 7.38

FC1820-8 183955 3.65 137784 5.63 80737 7.38

ZZZZZZ 176550 3.65 133209 5.63 75674 7.38

ZZZZZZ 172669 3.65 130572 5.63 74361 7.38

ZZZZZZ 175320 3.65 131015 5.63 75299 7.38

ZZZZZZ 172960 3.65 130095 5.63 74077 7.38

FC1820-1MS 189420 3.65 143419 5.63 82797 7.38

FC1820-1MSD 193741 3.65 145484 5.63 84307 7.38

V1A1711-ECC1700196708 3.65 148305 5.63 84874 7.38

IS 1 = Fluorobenzene IS 2 = Chlorobenzene-D5 IS 3 = 1,4-Dichlorobenzene-d4

(a) Initial Cal is: V1A1700-ICC1700 1A42180.D 12/16/22 12:14

(b) Check Std Limit = -50 to +100% of initial cal area.

(c) Upper Limit = +100% of check standard area; Retention time +0.167 minutes.

(d) Lower Limit = -50% of check standard area; Retention time -0.167 minutes.

FC1820

6.5.1

Internal Standard Area Summary Page 1 of 1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Check Std: V2A1689-CC1677 Injection Date: 01/13/23 Lab File ID: 2A42675.D Injection Time: 09:18 Instrument ID: GCMS2A Method: SW846 8260D

IS 1 IS 2 IS 3

AREA RT AREA RT AREA RT

Initial Cal a 226426 3.65 178646 5.64 100356 7.38

Check Std b 189857 3.65 146471 5.63 90706 7.38 Upper Limit c 379714 3.82 292942 5.80 181412 7.55 Lower Limit d 94929 3.48 73236 5.46 45353 7.21

Lab IS 1 IS 2 IS 3 Sample ID AREA RT AREA RT AREA RT

V2A1689-BS 186496 3.65 143781 5.64 90746 7.38

V2A1689-MB e 161523 3.65 130971 5.63 81473 7.38

ZZZZZZ 158202 3.65 127563 5.64 74660 7.38

ZZZZZZ 161800 3.65 129878 5.63 76180 7.38

FC1741-2 164158 3.65 130037 5.63 76686 7.38

ZZZZZZ 156955 3.65 126693 5.63 74369 7.38

ZZZZZZ 155475 3.65 124900 5.64 73967 7.38

ZZZZZZ 160907 3.65 126490 5.64 73757 7.38

ZZZZZZ 158234 3.65 127886 5.64 78927 7.38

ZZZZZZ 160285 3.65 127062 5.64 73657 7.38

ZZZZZZ 156085 3.65 126102 5.64 72491 7.38

FC1820-6 169705 3.65 132527 5.64 80432 7.38

FC1820-8 156722 3.65 124561 5.63 75303 7.38

ZZZZZZ 156257 3.65 124284 5.63 73040 7.38

ZZZZZZ 156008 3.65 124385 5.63 72488 7.38

ZZZZZZ 154072 3.65 124617 5.63 75606 7.38

FC1741-2MS 174120 3.65 135348 5.64 84512 7.38

FC1741-2MSD 173934 3.65 135309 5.63 85266 7.38

V2A1689-ECC1677181280 3.65 139253 5.64 87143 7.38

IS 1 = Fluorobenzene IS 2 = Chlorobenzene-D5 IS 3 = 1,4-Dichlorobenzene-d4

(a) Initial Cal is: V2A1677-ICC1677 2A42181.D 12/16/22 12:31

(b) Check Std Limit = -50 to +100% of initial cal area.

(c) Upper Limit = +100% of check standard area; Retention time +0.167 minutes.

(d) Lower Limit = -50% of check standard area; Retention time -0.167 minutes.

(e) Sample was treated with an anti-foaming agent.

FC1820

6.5.2

Surrogate Recovery Summary Page 1 of 1

Account: URSNCM AECOM, INC.

Project: Seymour Johnson AFB SS033; Goldsboro, NC

Method: SW846 8260D Matrix: AQ

Samples and QC shown here apply to the above method

Lab Lab Sample ID File ID S1 S2 S3 S4

FC1820-1 1A42638.D 100 95 104 96

FC1820-2 1A42640.D 98 93 104 95

FC1820-3 1A42642.D 99 93 103 96

FC1820-4 1A42644.D 100 93 103 96

FC1820-5 1A42646.D 99 94 105 93

FC1820-6 2A42701.D 96 90 106 95

FC1820-6 1A42648.D 99 94 103 95

FC1820-7 1A42650.D 98 93 104 94

FC1820-8 2A42703.D 99 93 104 95

FC1820-8 1A42652.D 99 93 108 96

FC1820-9 1A42636.D 99 93 103 94

FC1741-2MS 2A42711.D 98 94 101 94

FC1741-2MSD 2A42713.D 100 94 101 94

FC1820-1MS 1A42664.D 100 95 100 94

FC1820-1MSD 1A42666.D 100 96 101 95

V1A1711-BS 1A42630.D 99 96 101 96

V1A1711-MB 1A42634.D 99 93 103 94

V2A1689-BS 2A42677.D 99 93 102 95

V2A1689-MB 2A42681.D 102 93 103 92

Surrogate Recovery Compounds Limits

S1 = Dibromofluoromethane 83-118% S2 = 1,2-Dichloroethane-D4 79-125% S3 = Toluene-D8 85-112% S4 = 4-Bromofluorobenzene 83-118%

FC1820

6.6.1

Initial Calibration Summary Page 1 of 3 Job Number: FC1820 Sample: V1A1700-ICC1700 Account: URSNCM AECOM, INC. Lab FileID: 1A42180.D Project: Seymour Johnson AFB SS033; Goldsboro, NC

Response Factor Report MSVOA17

Method : C:\msdchem\1\MET...V1A_12-16-2022.M (RTE Integrator) Title : SW-846 Method 5035A/8260B Last Update : Mon Dec 19 08:52:38 2022 Response via : Initial Calibration

Calibration Files 1 =1A42172.D 2 =1A42174.D 3 =1A42176.D 4 =1A42178.D 5 =1A42180.D 6 =1A42182.D 7 =1A42184.D

Compound 1 2 3 4 5 6 7 Avg %RSD

1) I Fluorobenzene ----------------ISTD---------------------

2) Dichlorodifluorom 0.307 0.251 0.267 0.279 0.300 0.294 0.285 0.283 6.93 3)P Chloromethane 0.280 0.213 0.211 0.216 0.230 0.224 0.215 0.227 10.67

4) 1,3-butadiene 0.178 0.202 0.177 0.173 0.187 0.168 0.156 0.177 8.21 5)C Vinyl Chloride 0.283 0.232 0.239 0.249 0.265 0.257 0.244 0.253 6.87

6) Bromomethane 0.176 0.144 0.150 0.154 0.170 0.162 0.158 0.159 7.17

7) Chloroethane 0.161 0.118 0.118 0.115 0.104 0.080 0.116 22.77

---- Quadratic regr., Force(0,0) ---- Coefficient = 0.9985 Response Ratio = 0.00000 + 0.13124 *A + -0.03625 *A^2

8) Trichlorofluorome 0.439 0.366 0.382 0.407 0.439 0.402 0.362 0.400 7.98

9) Ethyl Ether 0.226 0.187 0.182 0.183 0.206 0.186 0.183 0.193 8.65

10) Ethanol 0.003 0.004 0.003 0.004 0.003 0.003 7.32

11) 1,2-Dichlorotrifl 0.393 0.293 0.292 0.283 0.318 0.303 0.293 0.311 12.19 12)C 1,1-Dichloroethen 0.457 0.350 0.353 0.344 0.388 0.370 0.354 0.374 10.58

13) Freon 113 0.313 0.257 0.261 0.258 0.287 0.279 0.268 0.275 7.26

14) Carbon Disulfide 0.980 0.700 0.653 0.624 0.702 0.651 0.622 0.704 17.84

---- Quadratic regr., Force(0,0) ---- Coefficient = 0.9981 Response Ratio = 0.00000 + 0.69310 *A + -0.03352 *A^2

15) Iodomethane 0.344 0.305 0.309 0.319 0.385 0.367 0.353 0.340 8.94

16) Acrolein 0.052 0.062 0.048 0.047 0.054 0.050 0.047 0.051 10.12

17) Allyl chloride 0.280 0.314 0.284 0.277 0.328 0.300 0.292 0.297 6.38

18) Methylene Chlorid 0.696 0.366 0.303 0.277 0.310 0.272 0.260 0.355 43.52

---- Quadratic regr., Force(0,0) ---- Coefficient = 0.9960 Response Ratio = 0.00000 + 0.32546 *A + -0.03406 *A^2

19) Acetone 0.165 0.096 0.091 0.089 0.094 0.083 0.074 0.099 30.34 ---- Quadratic regr., Force(0,0) ---- Coefficient = 0.9976

Response Ratio = 0.00000 + 0.09989 *A + -0.00249 *A^2

20) Methyl acetate 0.276 0.201 0.201 0.198 0.232 0.203 0.190 0.214 14.11

21) trans-1,2-Dichlor 0.461 0.358 0.335 0.332 0.390 0.354 0.344 0.368 12.34

22) Hexane 0.274 0.206 0.208 0.207 0.229 0.219 0.207 0.221 11.10

23) Methyl Tert Butyl 0.920 0.747 0.726 0.723 0.832 0.754 0.739 0.777 9.35

24) Acetonitrile 0.055 0.038 0.039 0.038 0.041 0.039 0.038 0.041 14.80

---- Quadratic regr., Force(0,0) ---- Coefficient = 0.9989 Response Ratio = 0.00000 + 0.04065 *A + -0.00014 *A^2

25) Tert Butyl Alcoho 0.062 0.052 0.052 0.053 0.062 0.055 0.048 0.055 9.79

26) Di-isopropyl ethe 0.807 0.670 0.652 0.646 0.733 0.662 0.647 0.688 8.76

27) Chloroprene 0.802 0.864 0.809 0.770 0.898 0.821 0.769 0.819 5.78 28)P 1,1-Dichloroethan 0.551 0.447 0.430 0.422 0.492 0.449 0.434 0.461 9.97

29) Acrylonitrile 0.109 0.104 0.099 0.095 0.111 0.099 0.092 0.101 6.76

30) ETBE 0.892 0.734 0.726 0.734 0.835 0.751 0.726 0.771 8.50

31) Vinyl acetate 0.490 0.465 0.450 0.427 0.489 0.446 0.422 0.455 5.99

Raw Data: 1A42172.D 1A42174.D 1A42176.D 1A42178.D 1A42180.D 1A42182.D 1A42184.D

FC1820

6.7.1

Initial Calibration Summary Page 2 of 3

Account: URSNCM AECOM, INC. Lab FileID: 1A42180.D Project: Seymour Johnson AFB SS033; Goldsboro, NC

32) cis-1,2-Dichloroe 0.372 0.296 0.284 0.279 0.318 0.289 0.280 0.303 11.11

33) 2,2-Dichloropropa 0.547 0.418 0.400 0.395 0.458 0.425 0.407 0.436 12.21

34) Bromochloromethan 0.183 0.144 0.145 0.147 0.162 0.140 0.132 0.150 11.31

35) Cyclohexane 0.481 0.359 0.378 0.373 0.419 0.403 0.385 0.400 10.23 36)C Chloroform 0.653 0.493 0.477 0.482 0.551 0.501 0.488 0.521 12.15

37) Ethyl acetate 0.309 0.287 0.273 0.259 0.301 0.272 0.253 0.279 7.54

38) Tetrahydrofuran 0.083 0.077 0.093 0.088 0.090 0.074 0.084 9.12 39)S Dibromofluorometh 0.280 0.279 0.282 0.279 0.282 0.283 0.284 0.281 0.71

40) Carbon Tetrachlor 0.481 0.377 0.366 0.371 0.418 0.405 0.386 0.401 10.03

41) 1,1,1-Trichloroet 0.568 0.418 0.415 0.412 0.478 0.443 0.425 0.451 12.47

42) 2-Butanone 0.231 0.153 0.148 0.153 0.165 0.144 0.127 0.160 20.76

---- Quadratic regr., Force(0,0) ---- Coefficient = 0.9965 Response Ratio = 0.00000 + 0.17079 *A + -0.00417 *A^2

43) 1,1-Dichloroprope 0.470 0.360 0.356 0.355 0.404 0.375 0.361 0.383 10.93

44) tert-Butyl format 0.213 0.268 0.210 0.218 0.244 0.229 0.221 0.229 9.00

45) Propionitrile 0.034 0.046 0.043 0.044 0.050 0.042 0.037 0.042 12.34

46) Methacrylonitrile 0.135 0.170 0.161 0.166 0.191 0.161 0.149 0.162 10.68

47) Benzene 1.380 1.068 1.015 1.022 1.171 1.057 1.014 1.104 12.09

48) TAME 0.877 0.715 0.706 0.732 0.827 0.731 0.709 0.756 8.93

49)S 1,2-Dichloroethan 0.301 0.308 0.311 0.320 0.321 0.330 0.303 0.313 3.38

50) 1,2-Dichloroethan 0.461 0.353 0.355 0.363 0.403 0.362 0.347 0.378 10.86

51) Isobutyl Alcohol 0.011 0.012 0.012 0.016 0.015 0.011 0.013 16.11

---- Quadratic regr., Force(0,0) ---- Coefficient = 0.9924 Response Ratio = 0.00000 + 0.01814 *A + -0.00024 *A^2

52) Tert Amyl Alcohol 0.047 0.037 0.038 0.038 0.045 0.037 0.033 0.039 12.14

53) Trichloroethene 0.405 0.294 0.291 0.291 0.329 0.304 0.288 0.315 13.40

54) Methylcyclohexane 0.580 0.427 0.456 0.457 0.493 0.483 0.459 0.479 10.26

55) Dibromomethane 0.229 0.185 0.182 0.183 0.206 0.186 0.177 0.192 9.58 56)C 1,2-Dichloropropa 0.305 0.257 0.254 0.253 0.283 0.254 0.245 0.264 8.09

57) Bromodichlorometh 0.425 0.349 0.337 0.346 0.392 0.353 0.344 0.364 8.86

58) Methyl methacryla 0.185 0.240 0.228 0.231 0.274 0.227 0.217 0.229 11.61

59) 1,4-Dioxane 0.004 0.003 0.004 0.004 0.004 0.004 0.003 0.004 11.19

60) 2-Chloroethyl vin 0.185 0.243 0.186 0.188 0.209 0.188 0.180 0.197 11.32

61) cis-1,3-Dichlorop 0.513 0.425 0.404 0.415 0.475 0.429 0.413 0.439 9.05

62) I Chlorobenzene-d5 ----------------ISTD--------------------- 63)S Toluene-d8 1.287 1.264 1.276 1.269 1.283 1.298 1.327 1.286 1.65 64)C Toluene 2.100 1.536 1.461 1.454 1.678 1.537 1.502 1.610 14.20

---- Quadratic regr., Force(0,0) ---- Coefficient = 0.9975 Response Ratio = 0.00000 + 1.58633 *A + -0.03613 *A^2

65) 2-Nitropropane 0.126 0.097 0.100 0.102 0.122 0.110 0.105 0.109 10.34

66) 4-Methyl-2-pentan 0.593 0.408 0.387 0.404 0.428 0.389 0.367 0.425 18.02

---- Quadratic regr., Force(0,0) ---- Coefficient = 0.9983 Response Ratio = 0.00000 + 0.43157 *A + -0.00619 *A^2

67) trans-1,3-Dichlor 0.607 0.462 0.464 0.485 0.545 0.506 0.496 0.509 10.06

68) Tetrachloroethene 0.581 0.439 0.435 0.441 0.505 0.472 0.457 0.476 11.01

69) Ethyl methacrylat 0.319 0.449 0.428 0.450 0.520 0.461 0.450 0.439 13.74

70) 1,1,2-Trichloroet 0.335 0.271 0.271 0.274 0.308 0.280 0.272 0.287 8.65

71) Dibromochlorometh 0.483 0.349 0.362 0.379 0.428 0.400 0.395 0.399 11.25

72) 1,3-Dichloropropa 0.679 0.548 0.545 0.545 0.608 0.552 0.529 0.572 9.30

73) 1,2-Dibromoethane 0.476 0.370 0.364 0.366 0.408 0.374 0.362 0.389 10.68

74) 3,3-Dimethyl-1-Bu 0.059 0.069 0.054 0.056 0.062 0.059 0.057 0.059 8.48

75) 2-hexanone 0.540 0.429 0.387 0.400 0.414 0.381 0.362 0.416 14.15

76) 1-Chlorohexane 0.742 0.541 0.515 0.507 0.547 0.524 0.484 0.551 15.71

---- Quadratic regr., Force(0,0) ---- Coefficient = 0.9984 Response Ratio = 0.00000 + 0.55361 *A + -0.03107 *A^2

FC1820

Initial Calibration Summary Page 3 of 3

Account: URSNCM AECOM, INC. Lab FileID: 1A42180.D Project: Seymour Johnson AFB SS033; Goldsboro, NC

77)C Ethylbenzene 2.228 1.708 1.612 1.592 1.799 1.646 1.588 1.739 13.13 78)P Chlorobenzene 1.307 1.014 0.974 0.967 1.109 1.000 0.962 1.047 11.93

79) 1,1,1,2-Tetrachlo 0.435 0.349 0.354 0.361 0.405 0.370 0.363 0.377 8.35

80) m,p-Xylene 1.776 1.356 1.300 1.286 1.444 1.326 1.263 1.393 12.83

81) o-Xylene 1.760 1.383 1.324 1.308 1.452 1.329 1.274 1.404 11.91

82) Styrene 1.233 1.072 1.035 1.052 1.157 1.059 1.014 1.089 7.15…