B.08 GFI JBCW_AB062_Analytical Data only.pdf

Cover

ANALYTICAL RESULTS

PERFORMED BY

Pace Analytical Gulf Coast 7979 Innovation Park Dr.

Baton Rouge, LA 70820

(225) 769-4900

Report Date 12/19/2022

Report # 222120507

9999999999

Project JBC / 112G07681

Samples Collected 11/29/22 - 11/30/22

Deliver To Additional Recipients Leah Adams Scott Nesbit, Tetra Tech Tetra Tech Michelle Coffman, Tetra Tech 661 Andersen Drive

Suite 200 Carrie Stock, Tetra Tech

Pittsburgh, PA 15220 Amy Thomson, Tetra Tech, Inc.

740-607-4055

LELAP Certificate Number: 01955 A2LA Accredited (DoD ELAP-QSM 5.4) Certificate Number: 6429.01

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Laboratory Endorsement

Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast’s Standard Operating Procedures.

Common Abbreviations that may be Utilized in this Report

ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub-Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re-analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM

Reporting Flags that may be Utilized in this Report

J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non-compliant QC Result (See Q Flag Application Report)

* Indicates a non-compliant or not applicable QC recovery or RPD – see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk-based limit.

P RPD between primary and confirmation result is greater than 40 DL Diluted analysis – when appended to Client Sample ID

Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report.

This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited.

I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature.

Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable.

Authorized Signature Pace Gulf Coast Report 222120507

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Certifications

Certification Certification Number

A2LA Accredited (DoD ELAP-QSM 5.4) 6429.01

Alabama 01955

Arkansas 88-0655

Colorado 01955

Delaware 01955

Florida E87854

Georgia 01955

Hawaii 01955

Idaho 01955

Illinois 200048

Indiana 01955

Kansas E-10354

Kentucky 95

Louisiana 01955

Maryland 01955

Massachusetts 01955

Michigan 01955

Mississippi 01955

Missouri 01955

Montana N/A

Nebraska 01955

New Mexico 01955

North Carolina 618

North Dakota R-195

Oklahoma 9403

South Carolina 73006001

South Dakota 01955

Tennessee 01955

Texas T104704178

Vermont 01955

Virginia 460215

Washington C929

USDA Soil Permit P330-16-00234

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Case Narrative

Client: Tetra Tech, Inc. Report: 222120507

Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report.

No sample integrity or quality control exceptions were identified unless noted below.

This report was completed in accordance with DOD QSM 5.0 as specified in the contract.

No anomalies were found for the analyzed sample(s).

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Sample Summary

Lab ID Client ID Matrix Collect Date Receive Date

22212050701 62-MW01-LTM-GW-1122 Water 11/29/22 16:20 12/02/22 16:20

22212050702 62-MW02-LTM-GW-1122 Water 11/30/22 13:50 12/02/22 16:20

22212050703 62-MW03-LTM-GW-1122 Water 11/29/22 13:50 12/02/22 16:20

22212050704 62-MW04D-LTM-GW-1122 Water 11/29/22 15:10 12/02/22 16:20

22212050705 62-MW05-LTM-GW-1122 Water 11/30/22 12:20 12/02/22 16:20

22212050706 62-MW05-LTM-GW-1122 MS Water 11/30/22 12:20 12/02/22 16:20

22212050707 62-MW05-LTM-GW-1122 MSD Water 11/30/22 12:20 12/02/22 16:20

22212050708 62-MW06-LTM-GW-1122 Water 11/30/22 10:40 12/02/22 16:20

22212050709 62-MW07-LTM-GW-1122 Water 11/30/22 17:05 12/02/22 16:20

22212050710 62-DUP01-LTM-GW-1122 Water 11/30/22 00:01 12/02/22 16:20

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Test Summary

EPA 6020B

Lab ID Client ID Matrix Batch Instru RunDate

22212050701 62-MW01-LTM-GW-1122 Water 755770 ICPMS2 12/10/22 11:20

22212050702 62-MW02-LTM-GW-1122 Water 755770 ICPMS2 12/10/22 11:34

22212050703 62-MW03-LTM-GW-1122 Water 755770 ICPMS2 12/10/22 11:27

22212050704 62-MW04D-LTM-GW-1122 Water 755770 ICPMS2 12/10/22 11:38

22212050705 62-MW05-LTM-GW-1122 Water 755770 ICPMS2 12/10/22 11:48

22212050706 62-MW05-LTM-GW-1122 MS Water 755770 ICPMS2 12/10/22 11:52

22212050707 62-MW05-LTM-GW-1122 MSD Water 755770 ICPMS2 12/10/22 11:55

22212050708 62-MW06-LTM-GW-1122 Water 755770 ICPMS2 12/10/22 12:05

22212050709 62-MW07-LTM-GW-1122 Water 755770 ICPMS2 12/10/22 12:09

22212050710 62-DUP01-LTM-GW-1122 Water 755770 ICPMS2 12/10/22 12:12

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Manual Integrations

Manual Integrations for LC and IC (if performed) are documented in the raw data.

No other manual integrations were performed by Pace Gulf Coast.

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Q Flag Summary

NO Q FLAGS FOR THIS WORKORDER

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Detect Summary Results and Detection Limits are adjusted for dilution and moisture when applicable

EPA 6020B

Lab ID Client ID Parameter Units Result Dil. %Moist

22212050701 62-MW01-LTM-GW-1122 Arsenic ug/L 10.8 1 NA

22212050701 62-MW01-LTM-GW-1122 Cobalt ug/L 1.92 1 NA

22212050703 62-MW03-LTM-GW-1122 Arsenic ug/L 1.56 1 NA

22212050704 62-MW04D-LTM-GW-1122 Arsenic ug/L 7.31 1 NA

22212050705 62-MW05-LTM-GW-1122 Arsenic ug/L 3.93 1 NA

22212050705 62-MW05-LTM-GW-1122 Cobalt ug/L 2.38 1 NA

22212050708 62-MW06-LTM-GW-1122 Arsenic ug/L 2.92 1 NA

22212050708 62-MW06-LTM-GW-1122 Cobalt ug/L 1.91 1 NA

22212050709 62-MW07-LTM-GW-1122 Arsenic ug/L 19.2 1 NA

22212050709 62-MW07-LTM-GW-1122 Cobalt ug/L 31.8 1 NA

22212050710 62-DUP01-LTM-GW-1122 Arsenic ug/L 3.22 1 NA

22212050710 62-DUP01-LTM-GW-1122 Cobalt ug/L 2.06 1 NA

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Metals

Form I

Sample Results

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ANALYTE RESULT

INORGANIC ANALYSIS DATA SHEET

QUNITS

LIMS Use: FORM I~ME~SAMPLE~22212050701

Matrix: Water

Sample Amt: 50

% Solids: NA Instrument ID: ICPMS2 mL

GCAL Sample ID: 22212050701Collect Date: 11/29/22

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1334SMPL.d

Dilution Factor: 1 Analyst: TDM

Time: 1620

Time: 1120

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Client Sample ID: 62-MW01-LTM-GW-1122

Prep Vol.: 50

Prep Method: 3010A

Prep Date: 12/06/22

Prep Batch: 755365

( mL )

I

DL LOQLOD

Arsenic 10.8 ug/L 0.25 0.50 1.00

Cadmium 0.50 Uug/L 0.25 0.50 1.00

Cobalt 1.92 ug/L 0.25 0.50 1.00

FORM I - IN

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Sample Report

12/10/2022 20:04

Sample Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.b22212050701 Data Path Name

File Name ICPMS-2,TDM1334SMPL.d Comment

12/10/2022 11:20:34Acq Time Total Dilution 1.0000

PassSample Type Sample Sample Pass/Fail

ISTD Pass/FailISTD Ref FileName Pass004CALB.d

Units : ppb

QC Analyte Table

Name Mass ISTD Mode MeasValue Final Conc RSD CPS LDR QC Flag

Li 7 6 No Gas 3.094 3.094 2.5 74279.51 500

Be 9 6 No Gas 0.276 0.276 6.4 628.02 1000

B 11 6 No Gas 35.852 35.852 0.3 48749.02 500

Sr 88 72 No Gas 144.219 144.219 0.5 11280057.75 1000

Zr 90 72 No Gas 0.13 0.130 23.7 7973.22 100

Mo 95 115 No Gas 0.238 0.238 1.4 6351.47 1000

Ag 107 115 No Gas 0.002 0.002 19.8 133.34 100

Cd 111 115 No Gas -0.002 -0.002 10.7 147.78 1000

Sb 121 115 No Gas 0.022 0.022 3.4 5538.92 1000

Ba 137 115 No Gas 40.745 40.745 0.4 647844.42 1000

Tl 205 209 No Gas -0.065 -0.065 4.0 7235.56 1000

Pb 208 209 No Gas 0.169 0.169 2.3 24736.56 1000

Na 23 45 He 5194.763 5194.763 0.1 1557359.46 100000

Mg 24 45 He 3589.775 3589.775 0.3 444222.33 100000

Al 27 45 He 197.504 197.504 0.5 5385.00 20000

Si 29 45 He 4758.99 4758.990 5.4 5597.08 10000

K 39 45 He 2163.428 2163.428 1.1 211097.70 100000

Ca 44 45 He 28855.361 28855.361 0.6 136784.20 500000

Ti 47 45 He 1.129 1.129 7.6 59.33 1000

V 51 72 He 3.15 3.150 0.9 8408.01 1000

Cr 52 72 He 0.781 0.781 3.5 2992.55 1000

Mn 55 72 He 20.739 20.739 1.6 23767.06 5000

Fe 57 72 He 2533.56 2533.560 0.5 158619.77 100000

Co 59 72 He 1.919 1.919 1.2 13841.08 1000

Ni 60 72 He 1.871 1.871 1.7 4492.96 2000

Cu 63 45 He 1.669 1.669 1.5 10205.86 1000

Zn 66 72 He 6.861 6.861 2.8 4913.10 20000

As 75 72 He 10.757 10.757 0.5 6949.33 1000

Se 78 72 He -0.617 -0.617 -37.6 -8.28 50

Sn 120 115 He -0.049 -0.049 6.5 286.67 1000

Recovery Limits: 30 - 120% DOD 6020B / 70-130% 6020B / 60-125% 200.8QC ISTD Table

Name Mass Mode CPS Ref CPS Rec Flag

Bi 209 He 3933358.80 4372390.87 89.96

Ge 72 He 98888.09 101592.94 97.34

In 115 He 888248.66 973424.783333333 91.25

Lu 175 He 2248211.48 2521338.45333333 89.17

Rh 103 He 3898264.85 4157890.11333333 93.76

Sc 45 He 82062.82 86308.98 95.08

Tb 159 He 4485533.27 4839386.28333333 92.69

Name Mass Mode CPS Ref CPS Rec Flag

(Li) 6 No Gas 885225.98 1237951.57 71.51

Bi 209 No Gas 17070382.66 17243668.9066667 99

Ge 72 No Gas 2001074.85 2016196.03 99.25

In 115 No Gas 16502394.57 16558394.01 99.66

Lu 175 No Gas 24469344.63 24350311.3033333 100.49

Rh 103 No Gas 14408363.32 14926839.9633333 96.53

Sc 45 No Gas 6007939.07 6445657.66 93.21

Tb 159 No Gas 24022679.64 23765411.3133333 101.08

Page 12 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

QUNITS

LIMS Use: FORM I~ME~SAMPLE~22212050702

Matrix: Water

Sample Amt: 50

% Solids: NA Instrument ID: ICPMS2 mL

GCAL Sample ID: 22212050702Collect Date: 11/30/22

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1338SMPL.d

Dilution Factor: 1 Analyst: TDM

Time: 1350

Time: 1134

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Client Sample ID: 62-MW02-LTM-GW-1122

Prep Vol.: 50

Prep Method: 3010A

Prep Date: 12/06/22

Prep Batch: 755365

( mL )

I

DL LOQLOD

Arsenic 0.50 Uug/L 0.25 0.50 1.00

Cadmium 0.50 Uug/L 0.25 0.50 1.00

Cobalt 0.50 Uug/L 0.25 0.50 1.00

Page 13 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Sample Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.b22212050702 Data Path Name

File Name ICPMS-2,TDM1338SMPL.d Comment

12/10/2022 11:34:34Acq Time Total Dilution 1.0000

PassSample Type Sample Sample Pass/Fail

ISTD Pass/FailISTD Ref FileName Fail004CALB.d

Units : ppb

QC Analyte Table

Name Mass ISTD Mode MeasValue Final Conc RSD CPS LDR QC Flag

Li 7 6 No Gas 0.642 0.642 2.2 52946.50 500

Be 9 6 No Gas -0.008 -0.008 24.1 76.00 1000

B 11 6 No Gas 58.35 58.350 0.7 68203.74 500

Sr 88 72 No Gas 153.39 153.390 0.4 11544125.66 1000

Zr 90 72 No Gas 0.005 0.005 5.9 1783.46 100

Mo 95 115 No Gas -0.069 -0.069 6.3 1823.47 1000

Ag 107 115 No Gas 0.001 0.001 10.1 68.89 100

Cd 111 115 No Gas -0.005 -0.005 27.8 121.11 1000

Sb 121 115 No Gas -0.036 -0.036 2.0 3183.73 1000

Ba 137 115 No Gas 42.269 42.269 0.2 672097.87 1000

Tl 205 209 No Gas -0.115 -0.115 12.8 2393.64 1000

Pb 208 209 No Gas 0.04 0.040 4.4 7441.12 1000

Na 23 45 He 4455.382 4455.382 0.8 1251461.39 100000

Mg 24 45 He 2413.702 2413.702 1.1 279964.31 100000

Al 27 45 He 28.264 28.264 4.2 741.35 20000

Si 29 45 He 2837.314 2837.314 7.8 3379.07 10000

K 39 45 He 2090.714 2090.714 0.7 191198.59 100000

Ca 44 45 He 42476.131 42476.131 0.4 188396.66 500000

Ti 47 45 He 0.048 0.048 24.1 6.33 1000

V 51 72 He 0.646 0.646 2.3 1805.69 1000

Cr 52 72 He 0.186 0.186 3.8 887.82 1000

Mn 55 72 He 0.92 0.920 6.6 1167.84 5000

Fe 57 72 He 122.659 122.659 6.5 7408.83 100000

Co 59 72 He 0.069 0.069 3.0 552.24 1000

Ni 60 72 He -0.15 -0.150 12.8 296.68 2000

Cu 63 45 He 0.32 0.320 2.1 2071.27 1000

Zn 66 72 He 2.451 2.451 2.7 1793.47 20000

As 75 72 He 0.176 0.176 7.6 199.33 1000

Se 78 72 He -0.433 -0.433 -79.0 -3.84 50

Sn 120 115 He -0.054 -0.054 17.2 257.78 1000

Recovery Limits: 30 - 120% DOD 6020B / 70-130% 6020B / 60-125% 200.8QC ISTD Table

Name Mass Mode CPS Ref CPS Rec Flag

Bi 209 He 3811792.55 4372390.87 87.18

Ge 72 He 93783.82 101592.94 92.31

In 115 He 846801.67 973424.783333333 86.99

Lu 175 He 2136504.76 2521338.45333333 84.74

Rh 103 He 3754230.68 4157890.11333333 90.29

Sc 45 He 76815.38 86308.98 89

Tb 159 He 4299553.69 4839386.28333333 88.85

Name Mass Mode CPS Ref CPS Rec

(Li) 6 No Gas 784219.31 1237951.57 63.35

Bi 209 No Gas 17659518.07 17243668.9066667 102.41

Ge 72 No Gas 1925488.53 2016196.03 95.5

In 115 No Gas 16502596.51 16558394.01 99.66

Lu 175 No Gas 24705747.96 24350311.3033333 101.46

Rh 103 No Gas 14201892.77 14926839.9633333 95.14

Sc 45 No Gas 5575593.67 6445657.66 86.5

Tb 159 No Gas 24090115.47 23765411.3133333 101.37

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Flag

<70% or >120%

Page 15 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

QUNITS

LIMS Use: FORM I~ME~SAMPLE~22212050703

Matrix: Water

Sample Amt: 50

% Solids: NA Instrument ID: ICPMS2 mL

GCAL Sample ID: 22212050703Collect Date: 11/29/22

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1336SMPL.d

Dilution Factor: 1 Analyst: TDM

Time: 1350

Time: 1127

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Client Sample ID: 62-MW03-LTM-GW-1122

Prep Vol.: 50

Prep Method: 3010A

Prep Date: 12/06/22

Prep Batch: 755365

( mL )

I

DL LOQLOD

Arsenic 1.56 ug/L 0.25 0.50 1.00

Cadmium 0.50 Uug/L 0.25 0.50 1.00

Cobalt 0.50 Uug/L 0.25 0.50 1.00

Page 16 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Sample Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.b22212050703 Data Path Name

File Name ICPMS-2,TDM1336SMPL.d Comment

12/10/2022 11:27:34Acq Time Total Dilution 1.0000

PassSample Type Sample Sample Pass/Fail

ISTD Pass/FailISTD Ref FileName Fail004CALB.d

Units : ppb

QC Analyte Table

Name Mass ISTD Mode MeasValue Final Conc RSD CPS LDR QC Flag

Li 7 6 No Gas 0.405 0.405 0.4 55522.37 500

Be 9 6 No Gas 0.076 0.076 2.3 234.00 1000

B 11 6 No Gas 17.062 17.062 0.5 23929.51 500

Sr 88 72 No Gas 178.907 178.907 0.4 13304042.30 1000

Zr 90 72 No Gas 0.081 0.081 3.2 5282.14 100

Mo 95 115 No Gas 1.349 1.349 0.9 22133.86 1000

Ag 107 115 No Gas 0.096 0.096 5.8 4006.17 100

Cd 111 115 No Gas -0.002 -0.002 16.6 151.11 1000

Sb 121 115 No Gas -0.04 -0.040 3.4 2947.01 1000

Ba 137 115 No Gas 47.983 47.983 0.5 744132.05 1000

Tl 205 209 No Gas -0.124 -0.124 1.2 1430.14 1000

Pb 208 209 No Gas 0.129 0.129 0.5 19746.66 1000

Na 23 45 He 2315.305 2315.305 1.1 658988.56 100000

Mg 24 45 He 6958.271 6958.271 0.1 810160.06 100000

Al 27 45 He 67.598 67.598 2.7 1750.78 20000

Si 29 45 He 2288.366 2288.366 9.9 2866.29 10000

K 39 45 He 839.851 839.851 1.3 81831.68 100000

Ca 44 45 He 56466.529 56466.529 1.0 252086.92 500000

Ti 47 45 He 0.556 0.556 18.6 29.67 1000

V 51 72 He 1.776 1.776 0.9 4479.61 1000

Cr 52 72 He 0.565 0.565 1.0 2077.95 1000

Mn 55 72 He 26.896 26.896 0.9 28485.41 5000

Fe 57 72 He 1929 1929.000 1.8 111860.95 100000

Co 59 72 He 0.172 0.172 7.4 1225.62 1000

Ni 60 72 He 0.041 0.041 3.1 655.58 2000

Cu 63 45 He 7.621 7.621 1.8 42863.55 1000

Zn 66 72 He 10.632 10.632 2.3 6938.39 20000

As 75 72 He 1.559 1.559 4.0 1009.71 1000

Se 78 72 He 0.1 0.100 33.5 7.66 50

Sn 120 115 He 0.056 0.056 5.8 603.35 1000

Recovery Limits: 30 - 120% DOD 6020B / 70-130% 6020B / 60-125% 200.8QC ISTD Table

Name Mass Mode CPS Ref CPS Rec Flag

Bi 209 He 3779675.25 4372390.87 86.44

Ge 72 He 91590.25 101592.94 90.15

In 115 He 832927.54 973424.783333333 85.57

Lu 175 He 2125077.62 2521338.45333333 84.28

Rh 103 He 3707693.32 4157890.11333333 89.17

Sc 45 He 77378.10 86308.98 89.65

Tb 159 He 4280369.10 4839386.28333333 88.45

Name Mass Mode CPS Ref CPS Rec

(Li) 6 No Gas 842142.59 1237951.57 68.03

Bi 209 No Gas 17421812.66 17243668.9066667 101.03

Ge 72 No Gas 1902560.34 2016196.03 94.36

In 115 No Gas 16095602.81 16558394.01 97.21

Lu 175 No Gas 24811337.13 24350311.3033333 101.89

Rh 103 No Gas 13944303.89 14926839.9633333 93.42

Sc 45 No Gas 5633461.03 6445657.66 87.4

Tb 159 No Gas 24119831.31 23765411.3133333 101.49

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Flag

<70% or >120%

Page 18 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

QUNITS

LIMS Use: FORM I~ME~SAMPLE~22212050704

Matrix: Water

Sample Amt: 50

% Solids: NA Instrument ID: ICPMS2 mL

GCAL Sample ID: 22212050704Collect Date: 11/29/22

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1339SMPL.d

Dilution Factor: 1 Analyst: TDM

Time: 1510

Time: 1138

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Client Sample ID: 62-MW04D-LTM-GW-1122

Prep Vol.: 50

Prep Method: 3010A

Prep Date: 12/06/22

Prep Batch: 755365

( mL )

I

DL LOQLOD

Arsenic 7.31 ug/L 0.25 0.50 1.00

Cadmium 0.50 Uug/L 0.25 0.50 1.00

Cobalt 0.50 Uug/L 0.25 0.50 1.00

Page 19 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Sample Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.b22212050704 Data Path Name

File Name ICPMS-2,TDM1339SMPL.d Comment

12/10/2022 11:38:04Acq Time Total Dilution 1.0000

PassSample Type Sample Sample Pass/Fail

ISTD Pass/FailISTD Ref FileName Fail004CALB.d

Units : ppb

QC Analyte Table

Name Mass ISTD Mode MeasValue Final Conc RSD CPS LDR QC Flag

Li 7 6 No Gas 0.79 0.790 4.3 52054.05 500

Be 9 6 No Gas 0.045 0.045 25.1 160.67 1000

B 11 6 No Gas 19.803 19.803 1.2 24553.81 500

Sr 88 72 No Gas 180.228 180.228 0.8 13283164.38 1000

Zr 90 72 No Gas 0.099 0.099 1.5 6052.46 100

Mo 95 115 No Gas 0.989 0.989 1.2 17032.45 1000

Ag 107 115 No Gas 0.001 0.001 25.6 65.55 100

Cd 111 115 No Gas -0.003 -0.003 24.1 141.11 1000

Sb 121 115 No Gas -0.046 -0.046 3.8 2691.40 1000

Ba 137 115 No Gas 43.76 43.760 0.9 681231.67 1000

Tl 205 209 No Gas -0.127 -0.127 4.0 1136.76 1000

Pb 208 209 No Gas 0.026 0.026 4.0 5454.02 1000

Na 23 45 He 4019.714 4019.714 0.7 1131670.69 100000

Mg 24 45 He 4942.943 4942.943 1.0 572940.24 100000

Al 27 45 He 19.554 19.554 3.9 520.68 20000

Si 29 45 He 4524.097 4524.097 4.6 5017.54 10000

K 39 45 He 1218.808 1218.808 1.9 114772.15 100000

Ca 44 45 He 56862.405 56862.405 0.6 252538.94 500000

Ti 47 45 He 0.363 0.363 2.8 20.67 1000

V 51 72 He 0.97 0.970 5.8 2554.70 1000

Cr 52 72 He 0.512 0.512 2.7 1917.92 1000

Mn 55 72 He 32.762 32.762 1.1 34787.69 5000

Fe 57 72 He 4426.835 4426.835 0.1 257464.36 100000

Co 59 72 He 0.201 0.201 2.9 1416.75 1000

Ni 60 72 He 0.011 0.011 6.3 600.02 2000

Cu 63 45 He 0.607 0.607 1.8 3670.50 1000

Zn 66 72 He 3.639 3.639 1.7 2513.58 20000

As 75 72 He 7.311 7.311 1.4 4419.02 1000

Se 78 72 He -0.163 -0.163 38.2 2.01 50

Sn 120 115 He -0.057 -0.057 8.9 244.45 1000

Recovery Limits: 30 - 120% DOD 6020B / 70-130% 6020B / 60-125% 200.8QC ISTD Table

Name Mass Mode CPS Ref CPS Rec Flag

Bi 209 He 3778971.51 4372390.87 86.43

Ge 72 He 91914.04 101592.94 90.47

In 115 He 833370.60 973424.783333333 85.61

Lu 175 He 2124495.80 2521338.45333333 84.26

Rh 103 He 3729912.35 4157890.11333333 89.71

Sc 45 He 76924.60 86308.98 89.13

Tb 159 He 4288536.81 4839386.28333333 88.62

Name Mass Mode CPS Ref CPS Rec

(Li) 6 No Gas 760070.28 1237951.57 61.4

Bi 209 No Gas 17488527.66 17243668.9066667 101.42

Ge 72 No Gas 1885657.42 2016196.03 93.53

In 115 No Gas 16157590.07 16558394.01 97.58

Lu 175 No Gas 24598752.97 24350311.3033333 101.02

Rh 103 No Gas 14006079.44 14926839.9633333 93.83

Sc 45 No Gas 5481827.98 6445657.66 85.05

Tb 159 No Gas 23908952.98 23765411.3133333 100.6

Page 20 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Flag

<70% or >120%

Page 21 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

QUNITS

LIMS Use: FORM I~ME~SAMPLE~22212050705

Matrix: Water

Sample Amt: 50

% Solids: NA Instrument ID: ICPMS2 mL

GCAL Sample ID: 22212050705Collect Date: 11/30/22

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1342SMPL.d

Dilution Factor: 1 Analyst: TDM

Time: 1220

Time: 1148

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Client Sample ID: 62-MW05-LTM-GW-1122

Prep Vol.: 50

Prep Method: 3010A

Prep Date: 12/06/22

Prep Batch: 755365

( mL )

I

DL LOQLOD

Arsenic 3.93 ug/L 0.25 0.50 1.00

Cadmium 0.50 Uug/L 0.25 0.50 1.00

Cobalt 2.38 ug/L 0.25 0.50 1.00

Page 22 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Reference Sample Report

12/10/2022 20:05

Sample Name 22212050705

1342SMPL.dFile Name

C:\Agilent\ICPMH\1\DATA\2221210A_MS2.bData Path Name

Acq Time 12/10/2022 11:48:31

AllRefSample Type

Total Dilution 1.0000

Comment ICPMS-2,TDM

ISTD Ref FileName 004CALB.d

Sample QC Pass/Fial Pass

ISTD QC Pass/Fail Fail

QC Analyte Table

Name Mass ISTD Tune Mode Conc. Conc. RSD CPS LDR QC Flag

Li 7 6 No Gas 4.292 2.0 68040.41 500

Be 9 6 No Gas 0.370 4.9 674.69 1000

B 11 6 No Gas 31.369 2.3 36060.52 500

Sr 88 72 No Gas 106.549 0.5 7862427.80 1000

Zr 90 72 No Gas 0.039 9.6 3323.77 100

Mo 95 115 No Gas 0.049 14.5 3528.26 1000

Ag 107 115 No Gas 0.002 35.5 123.33 100

Cd 111 115 No Gas 0.021 1.7 364.46 1000

Sb 121 115 No Gas 0.000 N/A 4581.90 1000

Ba 137 115 No Gas 82.902 0.6 1306420.50 1000

Tl 205 209 No Gas -0.094 N/A 4474.26 1000

Pb 208 209 No Gas 0.117 0.8 18315.57 1000

Na 23 45 He 3939.516 1.7 1094063.71 100000

Mg 24 45 He 2411.040 1.0 276237.57 100000

Al 27 45 He 73.632 3.6 1870.13 20000

Si 29 45 He 4944.393 6.4 5349.64 10000

K 39 45 He 1202.886 1.4 111822.37 100000

Ca 44 45 He 7922.302 2.1 34827.69 500000

Ti 47 45 He 0.748 13.5 37.67 1000

V 51 72 He 5.226 1.0 12737.80 1000

Cr 52 72 He 0.520 1.6 1927.93 1000

Mn 55 72 He 44.969 0.6 47371.49 5000

Fe 57 72 He 2779.728 0.7 160637.09 100000

Co 59 72 He 2.384 2.4 15853.09 1000

Ni 60 72 He 1.810 4.5 4030.59 2000

Cu 63 45 He 0.715 1.5 4212.87 1000

Zn 66 72 He 7.628 3.2 5020.92 20000

As 75 72 He 3.932 1.0 2401.87 1000

Se 78 72 He 0.240 64.1 10.55 50

Sn 120 115 He -0.057 N/A 244.45 1000

QC ISTD Table

Name Mass Tune Mode CPS CPS RSD Ref CPS % Rec %QC Low %QC High QC Flag

(Li) 6 No Gas 740191.57 1.0 1237951.57 59.79 70 120 <70% or >120%

Sc 45 No Gas 5400566.73 1.1 6445657.66 83.79 70 120

Ge 72 No Gas 1887858.88 0.3 2016196.03 93.63 70 120

Page 23 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Reference Sample Report

Name Mass Tune Mode CPS CPS RSD Ref CPS % Rec %QC Low %QC High QC Flag

Rh 103 No Gas 14212621.66 0.4 14926839.9633333 95.22 70 120

In 115 No Gas 16356959.60 0.1 16558394.01 98.78 70 120

Tb 159 No Gas 23991837.98 0.7 23765411.3133333 100.95 70 120

Lu 175 No Gas 24595217.13 0.5 24350311.3033333 101.01 70 120

Bi 209 No Gas 17725416.41 0.3 17243668.9066667 102.79 70 120

Sc 45 He 75874.80 1.2 86308.98 87.91 70 120

Ge 72 He 91282.22 0.5 101592.94 89.85 70 120

Rh 103 He 3758001.38 1.2 4157890.11333333 90.38 70 120

In 115 He 834942.56 0.9 973424.783333333 85.77 70 120

Tb 159 He 4275373.79 1.6 4839386.28333333 88.35 70 120

Lu 175 He 2102373.20 1.4 2521338.45333333 83.38 70 120

Bi 209 He 3824514.21 1.7 4372390.87 87.47 70 120

Page 24 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

QUNITS

LIMS Use: FORM I~ME~MS~22212050706

Matrix: Water

Sample Amt: 50

% Solids: NA Instrument ID: ICPMS2 mL

GCAL Sample ID: 22212050706Collect Date: 11/30/22

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1343SMPL.d

Dilution Factor: 1 Analyst: TDM

Time: 1220

Time: 1152

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Client Sample ID: 62-MW05-LTM-GW-1122 MS

Prep Vol.: 50

Prep Method: 3010A

Prep Date: 12/06/22

Prep Batch: 755365

( mL )

I

DL LOQLOD

Arsenic 52.7 ug/L 0.25 0.50 1.00

Cadmium 50.0 ug/L 0.25 0.50 1.00

Cobalt 52.6 ug/L 0.25 0.50 1.00

Page 25 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Matrix Spike Sample (MS) Report

Sample Name 22212050706

File Name 1343SMPL.d

Data Path Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.b

12/10/2022 11:52:00Acq Time

MSSample Type

Total Dilution 1.0000

Comment ICPMS-2,TDM

ISTD Ref FileName 004CALB.d

Sample QC Pass/Fial Fail

ISTD QC Pass/Fail Fail

QC Ref File Name 1342SMPL.d

QC Analyte Table

Name Mass Tune Conc. Conc. RSD CPS Reference Conc Spk Amt % Rec %Low %High Flag

Li 7 No Gas 265.636 8.4 1317966.28 4.29183774409855 250 104.54 80 120

Be 9 No Gas 58.998 6.4 91127.34 0.370275226448935 50 117.25 80 120

B 11 No Gas 337.536 6.6 346283.48 31.3689810190167 250 122.47 80 120 > +/- 20%

Sr 88 No Gas 162.516 4.1 11480072.75 106.54901013132 50 111.93 80 120

Zr 90 No Gas 10.546 5.4 467605.07 0.0393857088432323 10 105.06 80 120

Mo 95 No Gas 49.022 6.2 678291.20 0.0487124814769656 50 97.95 80 120

Ag 107 No Gas 49.250 5.8 1962762.22 0.00190978390476096 50 98.5 80 120

Cd 111 No Gas 49.960 6.1 443048.61 0.0208304433773533 50 99.88 80 120

Sb 121 No Gas 110.501 6.3 4240316.08 -0.000406722053797066 100 110.5 80 120

Ba 137 No Gas 137.112 6.5 2041355.75 82.9020239738857 50 108.42 80 120

Tl 205 No Gas 50.300 7.4 4890340.76 -0.0944761203655223 50 100.79 80 120

Pb 208 No Gas 50.757 6.8 6797402.14 0.11658613710631 50 101.28 80 120

Na 23 He 9082.448 1.6 2458181.42 3939.51550927199 5000 102.86 80 120

Mg 24 He 7268.695 2.5 812806.13 2411.04047145313 5000 97.15 80 120

Al 27 He 1120.979 2.3 27555.22 73.6315256651556 1000 104.73 80 120

Si 29 He 9893.258 3.5 9865.96 4944.39345271178 5000 98.98 80 120

K 39 He 6182.019 1.9 532428.35 1202.88637882906 5000 99.58 80 120

Ca 44 He 31762.861 2.6 136236.08 7922.30178023464 25000 95.36 80 120

Ti 47 He 49.690 2.0 2191.17 0.747545176557879 50 97.88 80 120

V 51 He 54.557 0.7 129709.56 5.22610649548513 50 98.66 80 120

Cr 52 He 50.310 1.0 159249.80 0.519588334126311 50 99.58 80 120

Mn 55 He 91.786 1.1 95557.26 44.968758730786 50 93.63 80 120

Fe 57 He 7720.164 0.8 441523.61 2779.72839971225 5000 98.81 80 120

Co 59 He 52.590 0.3 344518.10 2.38447352925905 50 100.41 80 120

Ni 60 He 102.250 1.1 193875.63 1.80998744160793 100 100.44 80 120

Cu 63 He 53.264 2.3 285950.14 0.715067835484518 50 105.1 80 120

Zn 66 He 989.739 1.0 620000.20 7.62825705986813 1000 98.21 80 120

As 75 He 52.689 0.8 30761.32 3.93165327311439 50 97.52 80 120

Se 78 He 8.633 1.3 187.10 0.240044510926296 10 83.93 80 120

Sn 120 He 49.797 1.6 154560.39 -0.056659621485701 50 99.71 80 120

QC ISTD Table

Page 26 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Name Mass Tune Mode CPS CPS RSD Ref CPS % Rec %QC Low %QC High QC Flag

(Li) 6 No Gas 718871.43 6.5 1237951.57 58.07 70 120 <70% or >120%

Sc 45 No Gas 5182910.91 6.5 6445657.66 80.41 70 120

Ge 72 No Gas 1809642.84 4.8 2016196.03 89.76 70 120

Rh 103 No Gas 13326759.47 5.2 14926839.9633333 89.28 70 120

In 115 No Gas 15490112.57 5.4 16558394.01 93.55 70 120

Tb 159 No Gas 23412622.98 3.9 23765411.3133333 98.52 70 120

Lu 175 No Gas 24109192.97 4.1 24350311.3033333 99.01 70 120

Bi 209 No Gas 16786579.33 5.5 17243668.9066667 97.35 70 120

Sc 45 He 74291.49 2.8 86308.98 86.08 70 120

Ge 72 He 90385.46 0.9 101592.94 88.97 70 120

Rh 103 He 3658624.30 1.2 4157890.11333333 87.99 70 120

In 115 He 809391.90 1.7 973424.783333333 83.15 70 120

Tb 159 He 4205158.69 1.1 4839386.28333333 86.89 70 120

Lu 175 He 2068579.45 1.3 2521338.45333333 82.04 70 120

Bi 209 He 3694936.09 1.4 4372390.87 84.51 70 120

Page 27 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

QUNITS

LIMS Use: FORM I~ME~MSD~22212050707

Matrix: Water

Sample Amt: 50

% Solids: NA Instrument ID: ICPMS2 mL

GCAL Sample ID: 22212050707Collect Date: 11/30/22

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1344SMPL.d

Dilution Factor: 1 Analyst: TDM

Time: 1220

Time: 1155

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Client Sample ID: 62-MW05-LTM-GW-1122 MSD

Prep Vol.: 50

Prep Method: 3010A

Prep Date: 12/06/22

Prep Batch: 755365

( mL )

I

DL LOQLOD

Arsenic 52.6 ug/L 0.25 0.50 1.00

Cadmium 48.0 ug/L 0.25 0.50 1.00

Cobalt 52.2 ug/L 0.25 0.50 1.00

Page 28 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Matrix Spike Duplicate (MSD) Sample Report

22212050707Sample Name

1344SMPL.dFile Name

C:\Agilent\ICPMH\1\DATA\2221210A_MS2.bData Path Name

Acq Time 12/10/2022 11:55:29

MSDSample Type

1.0000Total Dilution

ICPMS-2,TDMComment

ISTD Ref FileName 004CALB.d

Sample QC Pass/Fial Pass

ISTD Ref FileName Fail

QC Ref File Name 1343SMPL.d

QC Analyte Table

Name Mass Tune Mode Conc. Conc. RSD CPS Reference Conc RPD RPD Max Flag

Li 7 No Gas 262.588 3.2 1289300.94 265.636269463608 1.15 20

Be 9 No Gas 58.127 2.7 88759.61 58.9976157635079 1.49 20

B 11 No Gas 335.987 2.5 340825.84 337.53563161599 0.46 20

Sr 88 No Gas 155.010 1.2 11146661.92 162.516242273561 4.73 20

Zr 90 No Gas 10.073 0.6 454929.60 10.5458146276348 4.58 20

Mo 95 No Gas 47.106 0.2 671835.61 49.0221374842541 3.99 20

Ag 107 No Gas 46.818 0.6 1922645.69 49.2499871572785 5.06 20

Cd 111 No Gas 47.975 0.4 438458.23 49.9598522353044 4.05 20

Sb 121 No Gas 105.673 0.6 4179545.80 110.501023681822 4.47 20

Ba 137 No Gas 129.392 1.0 1985574.30 137.111566206506 5.79 20

Tl 205 No Gas 48.405 2.7 4842010.76 50.299552696953 3.84 20

Pb 208 No Gas 48.758 1.8 6716430.37 50.7571079126929 4.02 20

Na 23 He 8858.672 2.9 2389993.14 9082.44777571611 2.49 20

Mg 24 He 7139.841 3.2 795987.67 7268.69512970015 1.79 20

Al 27 He 1119.399 2.6 27433.00 1120.97887613647 0.14 20

Si 29 He 9640.382 0.8 9605.78 9893.25801082196 2.59 20

K 39 He 6061.403 2.2 520587.13 6182.01948907322 1.97 20

Ca 44 He 31130.440 3.2 133114.37 31762.860605666 2.01 20

Ti 47 He 51.536 3.4 2264.85 49.6898536417598 3.65 20

V 51 He 54.265 1.2 128264.71 54.5565816446081 0.54 20

Cr 52 He 50.265 0.5 158181.82 50.310250871795 0.09 20

Mn 55 He 90.015 0.9 93174.06 91.785701198739 1.95 20

Fe 57 He 7477.150 1.0 425130.50 7720.16433456014 3.2 20

Co 59 He 52.246 0.9 340258.81 52.590360544325 0.66 20

Ni 60 He 102.614 0.3 193434.86 102.250419923817 0.36 20

Cu 63 He 52.537 3.2 281159.55 53.264329402926 1.37 20

Zn 66 He 978.203 1.0 609218.66 989.739466197662 1.17 20

As 75 He 52.630 1.3 30548.87 52.6894655768583 0.11 20

Se 78 He 9.007 2.6 193.81 8.63345462247147 4.23 20

Sn 120 He 49.694 1.2 152867.60 49.7969184883613 0.21 20

QC ISTD Table

Page 29 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Name Mass Tune Mode CPS CPS RSD Ref CPS % Rec %QC Low %QC High QC Flag

(Li) 6 No Gas 709068.75 2.9 1237951.57 57.28 70 120 <70% or >120%

Sc 45 No Gas 5213054.66 0.8 6445657.66 80.88 70 120

Ge 72 No Gas 1839777.22 0.1 2016196.03 91.25 70 120

Rh 103 No Gas 13626947.79 0.1 14926839.9633333 91.29 70 120

In 115 No Gas 15929145.39 0.6 16558394.01 96.2 70 120

Tb 159 No Gas 23903251.31 1.1 23765411.3133333 100.58 70 120

Lu 175 No Gas 24591681.30 0.7 24350311.3033333 100.99 70 120

Bi 209 No Gas 17225023.08 0.8 17243668.9066667 99.89 70 120

Sc 45 He 74064.67 2.3 86308.98 85.81 70 120

Ge 72 He 89857.95 0.3 101592.94 88.45 70 120

Rh 103 He 3638971.66 0.8 4157890.11333333 87.52 70 120

In 115 He 802064.75 0.5 973424.783333333 82.4 70 120

Tb 159 He 4153616.19 0.5 4839386.28333333 85.83 70 120

Lu 175 He 2053763.46 0.4 2521338.45333333 81.46 70 120

Bi 209 He 3648686.30 0.3 4372390.87 83.45 70 120

Page 30 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

QUNITS

LIMS Use: FORM I~ME~SAMPLE~22212050708

Matrix: Water

Sample Amt: 50

% Solids: NA Instrument ID: ICPMS2 mL

GCAL Sample ID: 22212050708Collect Date: 11/30/22

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1347SMPL.d

Dilution Factor: 1 Analyst: TDM

Time: 1040

Time: 1205

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Client Sample ID: 62-MW06-LTM-GW-1122

Prep Vol.: 50

Prep Method: 3010A

Prep Date: 12/06/22

Prep Batch: 755365

( mL )

I

DL LOQLOD

Arsenic 2.92 ug/L 0.25 0.50 1.00

Cadmium 0.50 Uug/L 0.25 0.50 1.00

Cobalt 1.91 ug/L 0.25 0.50 1.00

Page 31 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

12/10/2022 20:06

Sample Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.b22212050708 Data Path Name

File Name ICPMS-2,TDM1347SMPL.d Comment

12/10/2022 12:05:56Acq Time Total Dilution 1.0000

PassSample Type Sample Sample Pass/Fail

ISTD Pass/FailISTD Ref FileName Fail004CALB.d

Units : ppb

QC Analyte Table

Name Mass ISTD Mode MeasValue Final Conc RSD CPS LDR QC Flag

Li 7 6 No Gas 1.438 1.438 0.7 48648.86 500

Be 9 6 No Gas 0.279 0.279 8.2 477.34 1000

B 11 6 No Gas 98.346 98.346 0.3 96000.33 500

Sr 88 72 No Gas 300.313 300.313 0.2 21338826.35 1000

Zr 90 72 No Gas 0.231 0.231 1.8 11738.25 100

Mo 95 115 No Gas 0.162 0.162 7.2 5042.05 1000

Ag 107 115 No Gas 0.009 0.009 4.4 421.12 100

Cd 111 115 No Gas 0.133 0.133 5.7 1376.75 1000

Sb 121 115 No Gas 0.183 0.183 4.4 11712.76 1000

Ba 137 115 No Gas 84.813 84.813 0.4 1302031.23 1000

Tl 205 209 No Gas -0.089 -0.089 5.3 4941.09 1000

Pb 208 209 No Gas 0.934 0.934 2.3 131533.36 1000

Na 23 45 He 4404.889 4404.889 0.8 1183731.99 100000

Mg 24 45 He 2804.197 2804.197 0.8 310962.37 100000

Al 27 45 He 3507.215 3507.215 0.3 85248.37 20000

Si 29 45 He 4522.518 4522.518 7.9 4790.79 10000

K 39 45 He 2820.818 2820.818 0.7 244260.45 100000

Ca 44 45 He 41138.614 41138.614 0.3 174553.03 500000

Ti 47 45 He 6.409 6.409 9.3 283.00 1000

V 51 72 He 4.982 4.982 3.0 11671.38 1000

Cr 52 72 He 1.483 1.483 3.5 4803.06 1000

Mn 55 72 He 4.178 4.178 1.5 4374.03 5000

Fe 57 72 He 1629.875 1629.875 1.6 90488.15 100000

Co 59 72 He 1.912 1.912 0.8 12220.70 1000

Ni 60 72 He 0.551 0.551 2.6 1561.22 2000

Cu 63 45 He 3.756 3.756 1.1 20218.48 1000

Zn 66 72 He 16.9 16.900 4.8 10453.84 20000

As 75 72 He 2.924 2.924 3.9 1738.44 1000

Se 78 72 He 0.087 0.087 41.5 7.03 50

Sn 120 115 He 0.006 0.006 13.4 421.12 1000

Recovery Limits: 30 - 120% DOD 6020B / 70-130% 6020B / 60-125% 200.8QC ISTD Table

Name Mass Mode CPS Ref CPS Rec Flag

Bi 209 He 3597031.09 4372390.87 82.27

Ge 72 He 87670.16 101592.94 86.3

In 115 He 792656.20 973424.783333333 81.43

Lu 175 He 2013539.34 2521338.45333333 79.86

Rh 103 He 3605680.00 4157890.11333333 86.72

Sc 45 He 73476.07 86308.98 85.13

Tb 159 He 4111985.46 4839386.28333333 84.97

Name Mass Mode CPS Ref CPS Rec

(Li) 6 No Gas 667971.66 1237951.57 53.96

Bi 209 No Gas 17374365.57 17243668.9066667 100.76

Ge 72 No Gas 1818009.51 2016196.03 90.17

In 115 No Gas 15935001.54 16558394.01 96.24

Lu 175 No Gas 24635084.63 24350311.3033333 101.17

Rh 103 No Gas 13594086.96 14926839.9633333 91.07

Sc 45 No Gas 5077663.13 6445657.66 78.78

Tb 159 No Gas 23875826.31 23765411.3133333 100.46

Page 32 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Flag

<70% or >120%

Page 33 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

QUNITS

LIMS Use: FORM I~ME~SAMPLE~22212050709

Matrix: Water

Sample Amt: 50

% Solids: NA Instrument ID: ICPMS2 mL

GCAL Sample ID: 22212050709Collect Date: 11/30/22

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1348SMPL.d

Dilution Factor: 1 Analyst: TDM

Time: 1705

Time: 1209

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Client Sample ID: 62-MW07-LTM-GW-1122

Prep Vol.: 50

Prep Method: 3010A

Prep Date: 12/06/22

Prep Batch: 755365

( mL )

I

DL LOQLOD

Arsenic 19.2 ug/L 0.25 0.50 1.00

Cadmium 0.50 Uug/L 0.25 0.50 1.00

Cobalt 31.8 ug/L 0.25 0.50 1.00

Page 34 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Sample Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.b22212050709 Data Path Name

File Name ICPMS-2,TDM1348SMPL.d Comment

12/10/2022 12:09:25Acq Time Total Dilution 1.0000

PassSample Type Sample Sample Pass/Fail

ISTD Pass/FailISTD Ref FileName Fail004CALB.d

Units : ppb

QC Analyte Table

Name Mass ISTD Mode MeasValue Final Conc RSD CPS LDR QC Flag

Li 7 6 No Gas 1.431 1.431 1.1 47405.00 500

Be 9 6 No Gas 0.185 0.185 0.9 334.68 1000

B 11 6 No Gas 47.901 47.901 2.4 47000.48 500

Sr 88 72 No Gas 200.781 200.781 0.4 13846068.12 1000

Zr 90 72 No Gas 0.995 0.995 6.2 44332.61 100

Mo 95 115 No Gas 1.818 1.818 1.4 28163.26 1000

Ag 107 115 No Gas 0.005 0.005 10.5 240.00 100

Cd 111 115 No Gas 0.166 0.166 3.1 1657.89 1000

Sb 121 115 No Gas 0.17 0.170 1.7 11045.55 1000

Ba 137 115 No Gas 95.987 95.987 0.5 1452227.82 1000

Tl 205 209 No Gas -0.096 -0.096 1.8 4257.49 1000

Pb 208 209 No Gas 0.971 0.971 0.3 138308.22 1000

Na 23 45 He 2263.65 2263.650 0.9 589100.98 100000

Mg 24 45 He 2249.596 2249.596 1.3 240190.95 100000

Al 27 45 He 2384.309 2384.309 0.8 55756.72 20000

Si 29 45 He 6399.916 6399.916 5.2 6281.35 10000

K 39 45 He 4683.093 4683.093 0.8 385533.39 100000

Ca 44 45 He 46287.732 46287.732 0.8 188912.82 500000

Ti 47 45 He 7.965 7.965 10.0 337.34 1000

V 51 72 He 8.921 8.921 1.5 20186.09 1000

Cr 52 72 He 3.115 3.115 3.0 9542.05 1000

Mn 55 72 He 1564.996 1564.996 1.3 1535670.81 5000

Fe 57 72 He 34564.019 34564.019 0.9 1865704.50 100000

Co 59 72 He 31.766 31.766 0.6 196476.00 1000

Ni 60 72 He 4.787 4.787 1.3 9080.66 2000

Cu 63 45 He 5.922 5.922 1.9 30501.83 1000

Zn 66 72 He 40.792 40.792 2.3 24301.37 20000

As 75 72 He 19.246 19.246 0.8 10661.24 1000

Se 78 72 He -0.394 -0.394 -57.3 -2.71 50

Sn 120 115 He -0.017 -0.017 5.5 344.45 1000

Recovery Limits: 30 - 120% DOD 6020B / 70-130% 6020B / 60-125% 200.8QC ISTD Table

Name Mass Mode CPS Ref CPS Rec Flag

Bi 209 He 3596666.72 4372390.87 82.26

Ge 72 He 85331.96 101592.94 83.99

In 115 He 772949.50 973424.783333333 79.41

Lu 175 He 1971908.46 2521338.45333333 78.21

Rh 103 He 3569447.22 4157890.11333333 85.85

Sc 45 He 70681.64 86308.98 81.89

Tb 159 He 4060749.31 4839386.28333333 83.91

Name Mass Mode CPS Ref CPS Rec

(Li) 6 No Gas 651239.68 1237951.57 52.61

Bi 209 No Gas 17592827.66 17243668.9066667 102.02

Ge 72 No Gas 1764470.59 2016196.03 87.51

In 115 No Gas 15704694.74 16558394.01 94.84

Lu 175 No Gas 24477574.64 24350311.3033333 100.52

Rh 103 No Gas 13404939.47 14926839.9633333 89.8

Sc 45 No Gas 4933228.41 6445657.66 76.54

Tb 159 No Gas 23672217.15 23765411.3133333 99.61

Page 35 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Flag

<70% or >120%

Page 36 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

QUNITS

LIMS Use: FORM I~ME~FLDDUP~22212050710

Matrix: Water

Sample Amt: 50

% Solids: NA Instrument ID: ICPMS2 mL

GCAL Sample ID: 22212050710Collect Date: 11/30/22

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1349SMPL.d

Dilution Factor: 1 Analyst: TDM

Time: 0001

Time: 1212

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Client Sample ID: 62-DUP01-LTM-GW-1122

Prep Vol.: 50

Prep Method: 3010A

Prep Date: 12/06/22

Prep Batch: 755365

( mL )

I

DL LOQLOD

Arsenic 3.22 ug/L 0.25 0.50 1.00

Cadmium 0.50 Uug/L 0.25 0.50 1.00

Cobalt 2.06 ug/L 0.25 0.50 1.00

Page 37 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Sample Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.b22212050710 Data Path Name

File Name ICPMS-2,TDM1349SMPL.d Comment

12/10/2022 12:12:55Acq Time Total Dilution 1.0000

PassSample Type Sample Sample Pass/Fail

ISTD Pass/FailISTD Ref FileName Fail004CALB.d

Units : ppb

QC Analyte Table

Name Mass ISTD Mode MeasValue Final Conc RSD CPS LDR QC Flag

Li 7 6 No Gas 1.348 1.348 1.3 45639.64 500

Be 9 6 No Gas 0.256 0.256 13.2 420.01 1000

B 11 6 No Gas 98.607 98.607 0.7 91047.05 500

Sr 88 72 No Gas 298.506 298.506 1.0 20792121.36 1000

Zr 90 72 No Gas 0.235 0.235 10.9 11669.52 100

Mo 95 115 No Gas 0.127 0.127 5.1 4509.64 1000

Ag 107 115 No Gas 0.007 0.007 11.4 321.12 100

Cd 111 115 No Gas 0.132 0.132 5.4 1355.64 1000

Sb 121 115 No Gas 0.038 0.038 3.1 5930.20 1000

Ba 137 115 No Gas 83.979 83.979 0.1 1277669.08 1000

Tl 205 209 No Gas -0.097 -0.097 9.7 4140.80 1000

Pb 208 209 No Gas 1.027 1.027 0.8 145523.94 1000

Na 23 45 He 4345.528 4345.528 1.3 1146924.85 100000

Mg 24 45 He 2733.922 2733.922 0.5 297753.53 100000

Al 27 45 He 3871.201 3871.201 0.1 92406.17 20000

Si 29 45 He 4443.745 4443.745 6.0 4634.08 10000

K 39 45 He 2776.068 2776.068 1.5 236197.21 100000

Ca 44 45 He 40377.02 40377.020 0.8 168248.86 500000

Ti 47 45 He 6.822 6.822 11.1 295.67 1000

V 51 72 He 5.45 5.450 2.0 12725.60 1000

Cr 52 72 He 1.612 1.612 4.0 5190.97 1000

Mn 55 72 He 4.35 4.350 3.3 4542.96 5000

Fe 57 72 He 1797.297 1797.297 0.9 99647.65 100000

Co 59 72 He 2.058 2.058 2.4 13132.65 1000

Ni 60 72 He 0.598 0.598 10.0 1646.78 2000

Cu 63 45 He 2.278 2.278 2.0 12152.89 1000

Zn 66 72 He 20.529 20.529 1.1 12638.90 20000

As 75 72 He 3.215 3.215 2.0 1898.79 1000

Se 78 72 He -0.241 -0.241 1773.8 0.30 50

Sn 120 115 He 0.043 0.043 9.1 531.13 1000

Recovery Limits: 30 - 120% DOD 6020B / 70-130% 6020B / 60-125% 200.8QC ISTD Table

Name Mass Mode CPS Ref CPS Rec Flag

Bi 209 He 3553080.05 4372390.87 81.26

Ge 72 He 87548.52 101592.94 86.18

In 115 He 785692.49 973424.783333333 80.71

Lu 175 He 1982421.79 2521338.45333333 78.63

Rh 103 He 3601234.44 4157890.11333333 86.61

Sc 45 He 72158.68 86308.98 83.61

Tb 159 He 4096279.00 4839386.28333333 84.64

Name Mass Mode CPS Ref CPS Rec

(Li) 6 No Gas 631818.70 1237951.57 51.04

Bi 209 No Gas 17501619.32 17243668.9066667 101.5

Ge 72 No Gas 1782122.85 2016196.03 88.39

In 115 No Gas 15791950.01 16558394.01 95.37

Lu 175 No Gas 24771474.63 24350311.3033333 101.73

Rh 103 No Gas 13519041.69 14926839.9633333 90.57

Sc 45 No Gas 4862759.25 6445657.66 75.44

Tb 159 No Gas 23976061.31 23765411.3133333 100.89

Page 38 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Flag

<70% or >120%

Page 39 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Form II

Calibration Verifications

Page 40 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

ANALYTE TRUE %RECOVERYFOUND UNITS

INITIAL CALIBRATION VERIFICATION (ICV) STANDARD

II

GenI_Standards -- LIMS Use: FORM II~ME~12/10/22~0852~ICP

Instrument ID: ICPMS2

GCAL QC ID: 1600

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\009_ICV.d

Analyst: TDM

Time: 0852

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Q

Arsenic 50.0 49.7 99 ug/L

Cadmium 50.0 51.1 102 ug/L

Cobalt 50.0 51.9 104 ug/L

CONTROL LIMITS 90-110%

FORM II - IN

Page 41 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Initial Calibration Verification (ICV) Report

12/10/2022 19:56

Sample Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.b1600 Data Path Name

File Name ICPMS-2,TDM009_ICV.d Comment

12/10/2022 08:52:48Acq Time Total Dilution 1.0000

FailSample Type ICV Sample Pass/Fail

ISTD Pass/FailISTD Ref FileName Pass004CALB.d

Units : ppb

Recovery Limits: 90-110%QC Analyte Table

Name Mass ISTD Mode Conc RSD CPS ExpValue Rec QC Flag

Li 7 6 No Gas 270.053 0.9 2169410.85 250 108.02

Be 9 6 No Gas 54.424 0.4 136093.57 50 108.85

B 11 6 No Gas 290.479 1.1 483160.07 250 116.19 > +/- 10%

Sr 88 72 No Gas 51.024 0.8 3988262.75 50 102.05

Zr 90 72 No Gas 46.896 0.2 2295805.33 50 93.79

Mo 95 115 No Gas 50.037 0.4 718470.84 50 100.07

Ag 107 115 No Gas 51.621 0.4 2134748.94 50 103.24

Cd 111 115 No Gas 51.075 0.3 470059.97 50 102.15

Sb 121 115 No Gas 56.724 0.0 2261372.90 50 113.45 > +/- 10%

Ba 137 115 No Gas 51.253 0.2 792111.72 50 102.51

Tl 205 209 No Gas 51.593 0.8 4967790.34 50 103.19

Pb 208 209 No Gas 50.603 0.6 6710633.75 50 101.21

Na 23 45 He 5306.140 0.4 1629361.44 5000 106.12

Mg 24 45 He 5170.458 1.3 654930.41 5000 103.41

Al 27 45 He 1034.498 0.3 28784.13 1000 103.45

Si 29 45 He 5520.484 1.7 6538.12 5000 110.41 > +/- 10%

K 39 45 He 5248.766 0.4 512883.31 5000 104.98

Ca 44 45 He 25701.193 0.7 124824.67 25000 102.8

Ti 47 45 He 50.814 1.1 2535.56 50 101.63

V 51 72 He 50.685 0.7 133942.06 50 101.37

Cr 52 72 He 52.478 1.1 184593.18 50 104.96

Mn 55 72 He 49.992 1.2 57930.97 50 99.98

Fe 57 72 He 5142.902 0.8 326900.79 5000 102.86

Co 59 72 He 51.910 1.1 377944.91 50 103.82

Ni 60 72 He 103.424 1.2 217952.65 100 103.42

Cu 63 45 He 54.584 0.9 331703.07 50 109.17

Zn 66 72 He 1040.952 0.9 724728.93 1000 104.1

As 75 72 He 49.708 0.3 32258.53 50 99.42

Se 78 72 He 24.635 2.2 582.25 25 98.54

Sn 120 115 He 51.084 0.6 182828.73 50 102.17

Recovery Limits: 30 - 120% DOD 6020B / 70-130% 6020B / 60-125% 200.8QC ISTD Table

Name Mass Mode CPS Ref CPS Rec Flag

Bi 209 He 4136380.36 4372390.87 94.6

Ge 72 He 100464.09 101592.94 98.89

In 115 He 933237.30 973424.783333333 95.87

Lu 175 He 2408070.23 2521338.45333333 95.51

Rh 103 He 3999592.90 4157890.11333333 96.19

Sc 45 He 84069.49 86308.98 97.41

Tb 159 He 4713512.43 4839386.28333333 97.4

Name Mass Mode CPS Ref CPS Rec Flag

(Li) 6 No Gas 1160661.75 1237951.57 93.76

Bi 209 No Gas 16581467.67 17243668.9066667 96.16

Ge 72 No Gas 1999404.43 2016196.03 99.17

In 115 No Gas 16040747.92 16558394.01 96.87

Lu 175 No Gas 23900704.64 24350311.3033333 98.15

Rh 103 No Gas 14205792.77 14926839.9633333 95.17

Sc 45 No Gas 6362585.72 6445657.66 98.71

Tb 159 No Gas 23476816.32 23765411.3133333 98.79

Page 42 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

LOW LEVEL CONTINUING CALIBRATION VERIFICATION (LLCCV) STANDARD

II

GenI_Standards -- LIMS Use: FORM II~ME~12/10/22~0914~ICP

Instrument ID: ICPMS2

GCAL QC ID: 1803

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1311CCV1.d

Analyst: TDM

Time: 0914

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Q

Arsenic 1.00 0.890 89 ug/L

Cadmium 1.00 1.00 100 ug/L

Cobalt 1.00 1.04 104 ug/L

CONTROL LIMITS 80-120%

Page 43 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Low Level Continuing Calibration Verification(LLCCV) Report

12/10/2022 19:58

Sample Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.b1803 Data Path Name

File Name ICPMS-2,TDM1311CCV1.d Comment

12/10/2022 09:14:11Acq Time Total Dilution 1.0000

FailSample Type LLCCV1 Sample Pass/Fail

ISTD Pass/FailISTD Ref FileName Pass004CALB.d

Units : ppb

Recovery Limits: Initial 6020B DOD 80-120% / 70-130% 6020B and 200.8QC Analyte Table

Name Mass ISTD Mode Conc RSD CPS ExpValue Rec QC Flag

Li 7 6 No Gas 6.102 1.8 113655.26 5 122.04 > +/- 20%

Be 9 6 No Gas 1.025 2.8 2536.89 1 102.5

B 11 6 No Gas 12.150 0.4 23432.20 10 121.5 > +/- 20%

Sr 88 72 No Gas 1.040 1.0 83096.73 1 104

Zr 90 72 No Gas 1.174 0.7 59516.82 1 117.4

Mo 95 115 No Gas 0.836 2.2 15140.31 1 83.6

Ag 107 115 No Gas 1.018 1.2 43354.85 1 101.8

Cd 111 115 No Gas 1.000 2.4 9632.25 1 100

Sb 121 115 No Gas 1.953 0.8 84600.40 2 97.65

Ba 137 115 No Gas 0.983 1.9 15771.21 1 98.3

Tl 205 209 No Gas 0.879 1.2 102133.82 1 87.9

Pb 208 209 No Gas 1.002 0.5 140596.19 1 100.2

Na 23 45 He 104.768 1.2 42483.98 100 104.77

Mg 24 45 He 97.867 4.2 13940.35 100 97.87

Al 27 45 He 21.312 4.1 630.69 20 106.56

Si 29 45 He 229.428 22.7 955.37 200 114.71

K 39 45 He 98.564 2.6 18068.21 100 98.56

Ca 44 45 He 507.020 4.5 2671.96 500 101.4

Ti 47 45 He 0.931 16.8 52.00 1 93.1

V 51 72 He 0.969 4.1 2823.64 1 96.9

Cr 52 72 He 1.022 4.0 3940.57 1 102.2

Mn 55 72 He 5.224 0.8 6304.74 5 104.48

Fe 57 72 He 103.593 4.0 6818.47 100 103.59

Co 59 72 He 1.041 3.4 7761.01 1 104.1

Ni 60 72 He 1.848 3.7 4574.09 2 92.4

Cu 63 45 He 1.074 0.9 6989.53 1 107.4

Zn 66 72 He 20.522 0.3 14690.80 20 102.61

As 75 72 He 0.892 2.4 685.69 1 89.2

Se 78 72 He 0.944 8.6 28.49 1 94.4

Sn 120 115 He 0.922 2.3 3842.79 1 92.2

Recovery Limits: 30 - 120% DOD 6020B / 70-130% 6020B / 60-125% 200.8QC ISTD Table

Name Mass Mode CPS Ref CPS Rec Flag

Bi 209 He 4255725.46 4372390.87 97.33

Ge 72 He 101799.78 101592.94 100.2

In 115 He 952673.45 973424.783333333 97.87

Lu 175 He 2423469.34 2521338.45333333 96.12

Rh 103 He 4162130.39 4157890.11333333 100.1

Sc 45 He 85829.22 86308.98 99.44

Tb 159 He 4734395.76 4839386.28333333 97.83

Name Mass Mode CPS Ref CPS Rec Flag

(Li) 6 No Gas 1092694.89 1237951.57 88.27

Bi 209 No Gas 17339060.16 17243668.9066667 100.55

Ge 72 No Gas 2016703.46 2016196.03 100.03

In 115 No Gas 16503996.26 16558394.01 99.67

Lu 175 No Gas 24224449.64 24350311.3033333 99.48

Rh 103 No Gas 14791798.85 14926839.9633333 99.1

Sc 45 No Gas 6296222.67 6445657.66 97.68

Tb 159 No Gas 23822437.98 23765411.3133333 100.24

Page 44 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

LINEAR DYNAMIC RANGE (LDR) STANDARD

II

GenI_Standards -- LIMS Use: FORM II~ME~12/10/22~0924~ICP

Instrument ID: ICPMS2

GCAL QC ID: 2500

Analysis Date: 12/10/22

Lab File ID: 2221210A_MS2.b\1314_QC1.d

Analyst: TDM

Time: 0924

222120507Report No:

Analytical Batch: 755770

Analytical Method: EPA 6020B

Q

Arsenic 1000 994 99 ug/L

Cadmium 1000 950 95 ug/L

Cobalt 1000 970 97 ug/L

CONTROL LIMITS 90-110%

Page 45 of 13012/19/2022 09:04Pace Gulf Coast Report#: 222120507

Linear Dynamic Range Check (LDR) Report

12/10/2022 19:59

Sample Name C:\Agilent\ICPMH\1\DATA\2221210A_MS2.bLDR Data Path Name

File Name ICPMS-2,TDM1314_QC1.d Comment

12/10/2022 09:24:38Acq Time Total Dilution 1.0000

PassSample Type QC1 Sample Pass/Fail

ISTD Pass/FailISTD Ref FileName Pass004CALB.d

Units : ppb

Recovery Limits: 90-110%QC Analyte Table

Name Mass ISTD Mode Conc RSD CPS ExpValue Rec QC Flag

Be 9 6 No Gas 1075.042 0.9 2357842.50 1000 107.5

Sr 88 72 No Gas 993.056 0.3 71608295.60 1000 99.31

Mo 95 115 No Gas 1028.484 0.3 13313838.91 1000 102.85

Cd 111 115 No Gas 950.446 0.6 7912409.69 1000 95.04

Sb 121 115 No Gas 1035.185 0.3 37272199.63 1000 103.52

Ba 137 115 No Gas 990.374 0.2 13847611.39 1000 99.04

Tl 205 209 No Gas 1004.541 0.3 87424412.03 1000 100.45

Pb 208 209 No Gas 994.771 0.5 119509105.72 1000 99.48

Na 23 45 He 97788.569 1.6 29031219.57 100000 97.79

Mg 24 45 He 95744.354 1.2 11769506.08 100000 95.74

Al 27 45 He 19346.886 0.5 522917.50 20000 96.73

K 39 45 He 99409.863 1.9 9301626.11 100000 99.41

Ca 44 45 He 491572.928 1.7 2318274.13 500000 98.31

Ti 47 45 He 973.884 1.3 47167.35 1000 97.39

V 51 72 He 1015.739 1.0 2506303.30 1000 101.57

Cr 52 72 He 992.746 1.0 3261106.95 1000 99.27

Mn 55 72 He 4962.447 1.3 5360977.70 5000 99.25

Fe 57 72 He 98165.699 1.5 5834800.74 100000 98.17

Co 59 72 He 969.929 1.6 6603500.57 1000 96.99

Ni 60 72 He 1935.152 1.5 3803410.26 2000 96.76

Cu 63 45 He 918.595 1.5 5422069.23 1000 91.86

Zn 66 72 He 18993.366 1.5 12364095.62 20000 94.97

As 75 72 He 993.583 1.3 601288.89 1000 99.36

Sn 120 115 He 1019.043 1.8 3308151.54 1000 101.9

Recovery Limits: 30 - 120% DOD 6020B / 70-130% 6020B / 60-125% 200.8QC ISTD Table

Name Mass Mode CPS Ref CPS Rec Flag

Bi 209 He 3713148.38 4372390.87 84.92

Ge 72 He 94003.41 101592.94 92.53

In 115 He 848938.41 973424.783333333 87.21

Lu 175 He 2305489.70 2521338.45333333 91.44

Rh 103 He 3601114.44 4157890.11333333 86.61

Sc…