B.08 GFI JBCA_Multi Site_Analytical Data.pdf

03/06/23

Technical Report for

FPM Remediations

Joint Base Charleston AFB; N Charleston, SC

1027-13-01

SGS Job Number: FC2733

Sampling Dates: 02/14/23 - 02/15/23

Report to:

FPM Remediations 181 Kenwood Avenue Oneida, NY 13421 l.coffey@fpm-remediations.com; m.milman-barris@fpm-remediations.com;

d.forse@fpm-remediations.com ATTN: Lisa Coffey

Total number of pages in report:

Certifications: FL(E83510), LA(03051), KS(E-10327), NC(573), NJ(FL002), NY(12022), SC(96038001)

DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177), AL, AK, AR, CT, IA, KY, MA, MI. MS, ND, NH, NV, OK, OR, IL, UT, VT, WA, WI, WV

This report shall not be reproduced, except in its entirety, without the written approval of SGS.

Test results relate only to samples analyzed.

SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: 407-425-6700 • fax: 407-425-0707

Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable.

Client Service contact: Ariel Hartney 407-425-6700

Norm Farmer Technical Director

Orlando, FL 03/06/23 e-Hardcopy 2.0 Automated Report

SGS is the sole authority for authorizing edits or modifications to this document.

Unauthorized modification of this report is strictly prohibited.

Review standard terms at: http://www.sgs.com/en/terms-and-conditions

The results set forth herein are provided by SGS North America Inc.

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FC2733

mailto:EHS.US.CustomerCare@sgs.com?subject=Customer care improvement idea (report FC2733)

Table of Contents -1-

Sections:

Section 1: Sample Summary Section 2: Case Narrative/Conformance Summary Section 3: Summary of Hits Section 4: Sample Results

4.1: FC2733-1: MW-6-FLD

4.2: FC2733-2: MW-17-FLD

4.3: FC2733-3: MW-217-FLD

4.4: FC2733-4: TU542-MW-5R

4.5: FC2733-5: MW-1-58

4.6: FC2733-6: MW-1-129

4.7: FC2733-7: MW-7-FLD

4.8: FC2733-8: EB20230214

4.9: FC2733-9: AB20230214

4.10: FC2733-10: TB20230214

4.11: FC2733-11: MW-2-FLD

4.12: FC2733-12: MW-15-FLD

4.13: FC2733-13: MW-14-FLD

4.14: FC2733-14: ST27-MW20-08R

4.15: FC2733-15: ST27-MW20-24

4.16: FC2733-16: ST27-MW20-224

Section 5: Misc. Forms 5.1: Chain of Custody 5.2: QC Evaluation: DOD QSM5.x Limits

Section 6: MS Volatiles - QC Data Summaries 6.1: Method Blank Summary 6.2: Blank Spike Summary 6.3: Matrix Spike/Matrix Spike Duplicate Summary 6.4: Instrument Performance Checks (BFB) 6.5: Internal Standard Area Summaries 6.6: Surrogate Recovery Summaries 6.7: Initial and Continuing Calibration Summaries 6.8: Run Sequence Reports

Section 7: MS Volatiles - Raw Data 7.1: Samples 7.2: Method Blanks 7.3: Blank Spikes 7.4: Matrix Spike/Matrix Spike Duplicates 7.5: Instrument Performance Checks (BFB) 7.6: Initial and Continuing Calibrations 7.7: Instrument Run Logs

SGS North America Inc.

Sample Summary

FPM Remediations Job No: FC2733

Joint Base Charleston AFB; N Charleston, SC Project No: 1027-13-01

Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID

FC2733-1 02/14/23 08:40 DSAM02/16/23 AQ Ground Water MW-6-FLD

FC2733-2 02/14/23 10:45 DSAM02/16/23 AQ Ground Water MW-17-FLD

FC2733-2D 02/14/23 10:45 DSAM02/16/23 AQ Water Dup/MSD MW-17-FLD

FC2733-2S 02/14/23 10:45 DSAM02/16/23 AQ Water Matrix Spike MW-17-FLD

FC2733-3 02/14/23 10:45 DSAM02/16/23 AQ Ground Water MW-217-FLD

FC2733-4 02/14/23 12:35 DSAM02/16/23 AQ Ground Water TU542-MW-5R

FC2733-5 02/14/23 12:55 DSAM02/16/23 AQ Ground Water MW-1-58

FC2733-6 02/14/23 15:40 DSAM02/16/23 AQ Ground Water MW-1-129

FC2733-7 02/15/23 08:18 DSAM02/16/23 AQ Ground Water MW-7-FLD

FC2733-8 02/14/23 08:25 DSAM02/16/23 AQ Equipment Blank EB20230214

FC2733-9 02/14/23 08:20 DSAM02/16/23 AQ Water AB20230214

FC2733-10 02/14/23 08:15 DSAM02/16/23 AQ Trip Blank Water TB20230214

FC2733-11 02/14/23 10:15 DSAM02/16/23 AQ Ground Water MW-2-FLD

Sample Summary (continued)

FPM Remediations Job No: FC2733

Joint Base Charleston AFB; N Charleston, SC Project No: 1027-13-01

Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID

FC2733-12 02/15/23 11:45 DSAM02/16/23 AQ Ground Water MW-15-FLD

FC2733-13 02/15/23 12:25 DSAM02/16/23 AQ Ground Water MW-14-FLD

FC2733-14 02/15/23 14:30 DSAM02/16/23 AQ Ground Water ST27-MW20-08R

FC2733-15 02/15/23 15:25 DSAM02/16/23 AQ Ground Water ST27-MW20-24

FC2733-16 02/15/23 15:25 DSAM02/16/23 AQ Ground Water ST27-MW20-224

SAMPLE DELIVERY GROUP CASE NARRATIVE

Client: FPM Remediations Job No: FC2733

Site: Joint Base Charleston AFB; N Charleston, SC Report Date: 3/6/2023 2:11:07 PM

On 02/16/2023, 15 Sample(s), 1 Trip Blank(s) and 0 Field Blank(s) were received at SGS North America Inc - Orlando. at a maximum corrected temperature of 2.2 C. Samples were intact and chemically preserved, unless noted below. A SGS North America Inc. - Orlando Job Number of FC2733 was assigned to the project.

Laboratory sample ID, client sample ID and dates of sample collection are detailed in the report’s Results Summary Section.

Specified quality control criteria were achieved for this job except as noted below. For more information, please refer to the analytical results and QC summary pages.

MS Volatiles By Method SW846 8260D Matrix: AQ Batch ID: V1A1749

Sample(s) FC3038-10MS, FC3038-10MSD were used as the QC samples indicated.

FC2733-11: Sample re-analyzed beyond hold time.

FC2733-14: Sample re-analyzed beyond hold time.

Matrix: AQ Batch ID: VI2823 Sample(s) FC2733-2MS, FC2733-2MSD were used as the QC samples indicated.

Matrix Spike /Matrix Spike Duplicate Recovery(s) for Benzene are outside control limits. Outside control limits due to high level in sample relative to spike amount.

FC2733-11: Confirmation run.

SGS North America Inc. - Orlando certifies that data reported for samples received, listed on the associated custody chain or analytical task order, were produced to specifications meeting the Quality System precision, accuracy and completeness objectives except as noted. Estimated non-standard method measurement uncertainty data is available on request, based on quality control bias and implicit for standard methods. Acceptable uncertainty requires tested parameter quality control data to meet method criteria.

SGS North America Inc.- Orlando is not responsible for data quality assumptions if partial reports are used and recommends that this report be used in its entirety.

Narrative prepared by:

Kim Benham, Client Services (Signature on File)

Summary of Hits Page 1 of 3 Job Number: FC2733 Account: FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC Collected: 02/14/23 thru 02/15/23

Lab Sample ID Client Sample ID Result/ Analyte Qual LOQ LOD Units Method

FC2733-1 MW-6-FLD

Benzene 5.1 1.0 0.50 ug/l SW846 8260D Toluene 1.5 1.0 0.50 ug/l SW846 8260D Ethylbenzene 14.6 1.0 0.50 ug/l SW846 8260D Methyl Tert Butyl Ether 0.25 J 1.0 0.50 ug/l SW846 8260D Naphthalene 7.1 5.0 2.0 ug/l SW846 8260D

FC2733-2 MW-17-FLD

Benzene 361 5.0 2.5 ug/l SW846 8260D Ethylbenzene 185 5.0 2.5 ug/l SW846 8260D Naphthalene 36.1 25 10 ug/l SW846 8260D

FC2733-3 MW-217-FLD

Benzene 415 5.0 2.5 ug/l SW846 8260D Ethylbenzene 185 5.0 2.5 ug/l SW846 8260D Naphthalene 34.0 25 10 ug/l SW846 8260D

FC2733-4 TU542-MW-5R

Benzene 6.7 1.0 0.50 ug/l SW846 8260D Toluene 0.87 J 1.0 0.50 ug/l SW846 8260D Ethylbenzene 17.2 1.0 0.50 ug/l SW846 8260D Xylene (total) 1.0 J 3.0 1.5 ug/l SW846 8260D Naphthalene 1.4 J 5.0 2.0 ug/l SW846 8260D

FC2733-5 MW-1-58

Naphthalene 22.0 5.0 2.0 ug/l SW846 8260D

FC2733-6 MW-1-129

Naphthalene 47.4 5.0 2.0 ug/l SW846 8260D

FC2733-7 MW-7-FLD

Benzene 1190 20 10 ug/l SW846 8260D Ethylbenzene 189 20 10 ug/l SW846 8260D Xylene (total) 61.3 60 30 ug/l SW846 8260D Naphthalene 54.1 J 100 40 ug/l SW846 8260D

Summary of Hits Page 2 of 3

Account: FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC Collected: 02/14/23 thru 02/15/23

Lab Sample ID Client Sample ID Result/ Analyte Qual LOQ LOD Units Method

FC2733-8 EB20230214

Toluene 23.6 1.0 0.50 ug/l SW846 8260D

FC2733-9 AB20230214

Toluene 24.1 1.0 0.50 ug/l SW846 8260D

FC2733-10 TB20230214

Toluene 3.7 1.0 0.50 ug/l SW846 8260D

FC2733-11 MW-2-FLD

Benzene a 1.9 J 2.0 1.0 ug/l SW846 8260D Toluene a 1.7 J 2.0 1.0 ug/l SW846 8260D Ethylbenzene a 32.0 2.0 1.0 ug/l SW846 8260D Xylene (total) a 265 6.0 3.0 ug/l SW846 8260D Naphthalene a 18.9 10 4.0 ug/l SW846 8260D

FC2733-12 MW-15-FLD

Toluene 0.55 J 1.0 0.50 ug/l SW846 8260D

FC2733-13 MW-14-FLD

Toluene 1.8 1.0 0.50 ug/l SW846 8260D

FC2733-14 ST27-MW20-08R

Toluene 1.2 1.0 0.50 ug/l SW846 8260D Ethylbenzene a 74.7 5.0 2.5 ug/l SW846 8260D Xylene (total) 162 3.0 1.5 ug/l SW846 8260D Naphthalene 45.9 5.0 2.0 ug/l SW846 8260D

FC2733-15 ST27-MW20-24

Benzene 6.3 1.0 0.50 ug/l SW846 8260D Toluene 0.88 J 1.0 0.50 ug/l SW846 8260D Naphthalene 24.3 5.0 2.0 ug/l SW846 8260D

FC2733-16 ST27-MW20-224

Benzene 6.3 1.0 0.50 ug/l SW846 8260D Toluene 1.6 1.0 0.50 ug/l SW846 8260D

Summary of Hits Page 3 of 3

Account: FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC Collected: 02/14/23 thru 02/15/23

Lab Sample ID Client Sample ID Result/ Analyte Qual LOQ LOD Units Method

Naphthalene 24.8 5.0 2.0 ug/l SW846 8260D

(a) Sample re-analyzed beyond hold time.

Sample Results

Report of Analysis

Orlando, FL Section 4

Report of Analysis Page 1 of 1

Client Sample ID: MW-6-FLD

Lab Sample ID: FC2733-1 Date Sampled: 02/14/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754411.D 1 02/17/23 11:41 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 5.1 1.0 0.50 0.31 ug/l

108-88-3 Toluene 1.5 1.0 0.50 0.30 ug/l

100-41-4 Ethylbenzene 14.6 1.0 0.50 0.36 ug/l

1330-20-7 Xylene (total) 1.5 U 3.0 1.5 0.72 ug/l

1634-04-4 Methyl Tert Butyl Ether 0.25 1.0 0.50 0.23 ug/l J

91-20-3 Naphthalene 7.1 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 96% 83-118%

17060-07-0 1,2-Dichloroethane-D4 98% 79-125%

2037-26-5 Toluene-D8 93% 85-112%

460-00-4 4-Bromofluorobenzene 98% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754411.D

FC2733

4.1

Client Sample ID: MW-17-FLD

Lab Sample ID: FC2733-2 Date Sampled: 02/14/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754410.D 5 02/17/23 11:17 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 361 5.0 2.5 1.6 ug/l

108-88-3 Toluene 2.5 U 5.0 2.5 1.5 ug/l

100-41-4 Ethylbenzene 185 5.0 2.5 1.8 ug/l

1330-20-7 Xylene (total) 7.5 U 15 7.5 3.6 ug/l

1634-04-4 Methyl Tert Butyl Ether 2.5 U 5.0 2.5 1.1 ug/l

91-20-3 Naphthalene 36.1 25 10 5.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 96% 83-118%

17060-07-0 1,2-Dichloroethane-D4 99% 79-125%

2037-26-5 Toluene-D8 94% 85-112%

460-00-4 4-Bromofluorobenzene 98% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754410.D

FC2733

4.2

Client Sample ID: MW-217-FLD

Lab Sample ID: FC2733-3 Date Sampled: 02/14/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754421.D 5 02/17/23 15:38 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 415 5.0 2.5 1.6 ug/l

108-88-3 Toluene 2.5 U 5.0 2.5 1.5 ug/l

100-41-4 Ethylbenzene 185 5.0 2.5 1.8 ug/l

1330-20-7 Xylene (total) 7.5 U 15 7.5 3.6 ug/l

1634-04-4 Methyl Tert Butyl Ether 2.5 U 5.0 2.5 1.1 ug/l

91-20-3 Naphthalene 34.0 25 10 5.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 97% 83-118%

17060-07-0 1,2-Dichloroethane-D4 103% 79-125%

2037-26-5 Toluene-D8 93% 85-112%

460-00-4 4-Bromofluorobenzene 98% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754421.D

FC2733

4.3

Client Sample ID: TU542-MW-5R

Lab Sample ID: FC2733-4 Date Sampled: 02/14/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754412.D 1 02/17/23 12:05 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 6.7 1.0 0.50 0.31 ug/l

108-88-3 Toluene 0.87 1.0 0.50 0.30 ug/l J

100-41-4 Ethylbenzene 17.2 1.0 0.50 0.36 ug/l

1330-20-7 Xylene (total) 1.0 3.0 1.5 0.72 ug/l J

1634-04-4 Methyl Tert Butyl Ether 0.50 U 1.0 0.50 0.23 ug/l

91-20-3 Naphthalene 1.4 5.0 2.0 1.0 ug/l J

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 95% 83-118%

17060-07-0 1,2-Dichloroethane-D4 96% 79-125%

2037-26-5 Toluene-D8 94% 85-112%

460-00-4 4-Bromofluorobenzene 98% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754412.D

FC2733

4.4

Client Sample ID: MW-1-58

Lab Sample ID: FC2733-5 Date Sampled: 02/14/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754413.D 1 02/17/23 12:28 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

CAS No. Compound Result LOQ LOD DL Units Q

91-20-3 Naphthalene 22.0 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 96% 83-118%

17060-07-0 1,2-Dichloroethane-D4 102% 79-125%

2037-26-5 Toluene-D8 93% 85-112%

460-00-4 4-Bromofluorobenzene 96% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754413.D

FC2733

4.5

Client Sample ID: MW-1-129

Lab Sample ID: FC2733-6 Date Sampled: 02/14/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754414.D 1 02/17/23 12:52 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

CAS No. Compound Result LOQ LOD DL Units Q

91-20-3 Naphthalene 47.4 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 95% 83-118%

17060-07-0 1,2-Dichloroethane-D4 99% 79-125%

2037-26-5 Toluene-D8 93% 85-112%

460-00-4 4-Bromofluorobenzene 94% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754414.D

FC2733

4.6

Client Sample ID: MW-7-FLD

Lab Sample ID: FC2733-7 Date Sampled: 02/15/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754423.D 20 02/17/23 16:25 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 1190 20 10 6.2 ug/l

108-88-3 Toluene 10 U 20 10 6.0 ug/l

100-41-4 Ethylbenzene 189 20 10 7.1 ug/l

1330-20-7 Xylene (total) 61.3 60 30 14 ug/l

1634-04-4 Methyl Tert Butyl Ether 10 U 20 10 4.6 ug/l

91-20-3 Naphthalene 54.1 100 40 20 ug/l J

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 95% 83-118%

17060-07-0 1,2-Dichloroethane-D4 99% 79-125%

2037-26-5 Toluene-D8 92% 85-112%

460-00-4 4-Bromofluorobenzene 96% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754423.D

FC2733

4.7

Client Sample ID: EB20230214

Lab Sample ID: FC2733-8 Date Sampled: 02/14/23

Matrix: AQ - Equipment Blank Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754407.D 1 02/17/23 10:06 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 0.50 U 1.0 0.50 0.31 ug/l

108-88-3 Toluene 23.6 1.0 0.50 0.30 ug/l

100-41-4 Ethylbenzene 0.50 U 1.0 0.50 0.36 ug/l

1330-20-7 Xylene (total) 1.5 U 3.0 1.5 0.72 ug/l

1634-04-4 Methyl Tert Butyl Ether 0.50 U 1.0 0.50 0.23 ug/l

91-20-3 Naphthalene 2.0 U 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 97% 83-118%

17060-07-0 1,2-Dichloroethane-D4 101% 79-125%

2037-26-5 Toluene-D8 94% 85-112%

460-00-4 4-Bromofluorobenzene 98% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754407.D

FC2733

4.8

Client Sample ID: AB20230214

Lab Sample ID: FC2733-9 Date Sampled: 02/14/23

Matrix: AQ - Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754420.D 1 02/17/23 15:15 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 0.50 U 1.0 0.50 0.31 ug/l

108-88-3 Toluene 24.1 1.0 0.50 0.30 ug/l

100-41-4 Ethylbenzene 0.50 U 1.0 0.50 0.36 ug/l

1330-20-7 Xylene (total) 1.5 U 3.0 1.5 0.72 ug/l

1634-04-4 Methyl Tert Butyl Ether 0.50 U 1.0 0.50 0.23 ug/l

91-20-3 Naphthalene 2.0 U 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 96% 83-118%

17060-07-0 1,2-Dichloroethane-D4 101% 79-125%

2037-26-5 Toluene-D8 94% 85-112%

460-00-4 4-Bromofluorobenzene 97% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754420.D

FC2733

4.9

Client Sample ID: TB20230214

Lab Sample ID: FC2733-10 Date Sampled: 02/14/23

Matrix: AQ - Trip Blank Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754408.D 1 02/17/23 10:30 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 0.50 U 1.0 0.50 0.31 ug/l

108-88-3 Toluene 3.7 1.0 0.50 0.30 ug/l

100-41-4 Ethylbenzene 0.50 U 1.0 0.50 0.36 ug/l

1330-20-7 Xylene (total) 1.5 U 3.0 1.5 0.72 ug/l

1634-04-4 Methyl Tert Butyl Ether 0.50 U 1.0 0.50 0.23 ug/l

91-20-3 Naphthalene 2.0 U 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 98% 83-118%

17060-07-0 1,2-Dichloroethane-D4 103% 79-125%

2037-26-5 Toluene-D8 92% 85-112%

460-00-4 4-Bromofluorobenzene 97% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754408.D

FC2733

4.10

Client Sample ID: MW-2-FLD

Lab Sample ID: FC2733-11 Date Sampled: 02/14/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 a 1A44187.D 2 03/03/23 11:38 JW n/a n/a V1A1749

Run #2 b I754422.D 5 02/17/23 16:02 JW n/a n/a VI2823

Purge Volume

Run #1 5.0 ml

Run #2 5.0 ml

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 1.9 2.0 1.0 0.62 ug/l J

108-88-3 Toluene 1.7 2.0 1.0 0.60 ug/l J

100-41-4 Ethylbenzene 32.0 2.0 1.0 0.71 ug/l

1330-20-7 Xylene (total) 265 6.0 3.0 1.4 ug/l

1634-04-4 Methyl Tert Butyl Ether 1.0 U 2.0 1.0 0.46 ug/l

91-20-3 Naphthalene 18.9 10 4.0 2.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 99% 95% 83-118%

17060-07-0 1,2-Dichloroethane-D4 94% 99% 79-125%

2037-26-5 Toluene-D8 98% 93% 85-112%

460-00-4 4-Bromofluorobenzene 101% 98% 83-118%

(a) Sample re-analyzed beyond hold time.

(b) Confirmation run.

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: 1A44187.D I754422.D

FC2733

4.11

Client Sample ID: MW-15-FLD

Lab Sample ID: FC2733-12 Date Sampled: 02/15/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754415.D 1 02/17/23 13:16 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 0.50 U 1.0 0.50 0.31 ug/l

108-88-3 Toluene 0.55 1.0 0.50 0.30 ug/l J

100-41-4 Ethylbenzene 0.50 U 1.0 0.50 0.36 ug/l

1330-20-7 Xylene (total) 1.5 U 3.0 1.5 0.72 ug/l

1634-04-4 Methyl Tert Butyl Ether 0.50 U 1.0 0.50 0.23 ug/l

91-20-3 Naphthalene 2.0 U 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 96% 83-118%

17060-07-0 1,2-Dichloroethane-D4 100% 79-125%

2037-26-5 Toluene-D8 93% 85-112%

460-00-4 4-Bromofluorobenzene 95% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754415.D

FC2733

4.12

Client Sample ID: MW-14-FLD

Lab Sample ID: FC2733-13 Date Sampled: 02/15/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754416.D 1 02/17/23 13:40 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, MTBE, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 0.50 U 1.0 0.50 0.31 ug/l

108-88-3 Toluene 1.8 1.0 0.50 0.30 ug/l

100-41-4 Ethylbenzene 0.50 U 1.0 0.50 0.36 ug/l

1330-20-7 Xylene (total) 1.5 U 3.0 1.5 0.72 ug/l

1634-04-4 Methyl Tert Butyl Ether 0.50 U 1.0 0.50 0.23 ug/l

91-20-3 Naphthalene 2.0 U 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 95% 83-118%

17060-07-0 1,2-Dichloroethane-D4 98% 79-125%

2037-26-5 Toluene-D8 95% 85-112%

460-00-4 4-Bromofluorobenzene 98% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754416.D

FC2733

4.13

Client Sample ID: ST27-MW20-08R

Lab Sample ID: FC2733-14 Date Sampled: 02/15/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754417.D 1 02/17/23 14:03 JW n/a n/a VI2823

Run #2 a 1A44189.D 5 03/03/23 12:12 JW n/a n/a V1A1749

Purge Volume

Run #1 5.0 ml

Run #2 5.0 ml

Purgeable Aromatics, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 0.50 U 1.0 0.50 0.31 ug/l

108-88-3 Toluene 1.2 1.0 0.50 0.30 ug/l

100-41-4 Ethylbenzene 74.7 b 5.0 2.5 1.8 ug/l

1330-20-7 Xylene (total) 162 3.0 1.5 0.72 ug/l

91-20-3 Naphthalene 45.9 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 95% 100% 83-118%

17060-07-0 1,2-Dichloroethane-D4 96% 95% 79-125%

2037-26-5 Toluene-D8 95% 97% 85-112%

460-00-4 4-Bromofluorobenzene 102% 98% 83-118%

(a) Sample re-analyzed beyond hold time.

(b) Result is from Run# 2

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754417.D 1A44189.D

FC2733

4.14

Client Sample ID: ST27-MW20-24

Lab Sample ID: FC2733-15 Date Sampled: 02/15/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754418.D 1 02/17/23 14:27 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 6.3 1.0 0.50 0.31 ug/l

108-88-3 Toluene 0.88 1.0 0.50 0.30 ug/l J

100-41-4 Ethylbenzene 0.50 U 1.0 0.50 0.36 ug/l

1330-20-7 Xylene (total) 1.5 U 3.0 1.5 0.72 ug/l

91-20-3 Naphthalene 24.3 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 97% 83-118%

17060-07-0 1,2-Dichloroethane-D4 101% 79-125%

2037-26-5 Toluene-D8 93% 85-112%

460-00-4 4-Bromofluorobenzene 97% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754418.D

FC2733

4.15

Client Sample ID: ST27-MW20-224

Lab Sample ID: FC2733-16 Date Sampled: 02/15/23

Matrix: AQ - Ground Water Date Received: 02/16/23

Method: SW846 8260D Percent Solids: n/a

Project: Joint Base Charleston AFB; N Charleston, SC

File ID DF Analyzed By Prep Date Prep Batch Analytical Batch

Run #1 I754419.D 1 02/17/23 14:51 JW n/a n/a VI2823

Run #2

Purge Volume

Run #1 5.0 ml

Run #2

Purgeable Aromatics, Naphthalene

CAS No. Compound Result LOQ LOD DL Units Q

71-43-2 Benzene 6.3 1.0 0.50 0.31 ug/l

108-88-3 Toluene 1.6 1.0 0.50 0.30 ug/l

100-41-4 Ethylbenzene 0.50 U 1.0 0.50 0.36 ug/l

1330-20-7 Xylene (total) 1.5 U 3.0 1.5 0.72 ug/l

91-20-3 Naphthalene 24.8 5.0 2.0 1.0 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

1868-53-7 Dibromofluoromethane 97% 83-118%

17060-07-0 1,2-Dichloroethane-D4 100% 79-125%

2037-26-5 Toluene-D8 95% 85-112%

460-00-4 4-Bromofluorobenzene 97% 83-118%

U = Not detected LOD = Limit of Detection J = Indicates an estimated value

LOQ = Limit of Quantitation DL = Detection Limit B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

Raw Data: I754419.D

FC2733

4.16

Misc. Forms

Custody Documents and Other Forms

Includes the following where applicable:

• Chain of Custody

• QC Evaluation: DOD QSM5.x Limits

Orlando, FL Section 5

FC2733: Chain of Custody

FC2733

5.1

FC2733: Chain of Custody

FC2733

Job Number: FC2733 Client: FPM REMEDIATIONS

Date / Time Received: 2/16/2023 11:10:00 AM Delivery Method: FEDEX

Project: JBCN

Airbill #'s: 5707 9050 7370

Cooler Information

1. Custody Seals Present

2. Custody Seals Intact

4. Cooler temp verification

3. Temp criteria achieved

5. Cooler media

IR Gun

Ice (Bag)

Trip Blank Information

1. Trip Blank present / cooler

2. Trip Blank listed on COC

2. Samples preserved properly

Sample Information

1. Sample labels present on bottles

5. Sample recvd within HT

4. Condition of sample

3. Sufficient volume/containers recvd for analysis:

Intact

Comments

SM001

Rev. Date 05/24/17

SGS Sample Receipt Summary

Cooler Temps (Raw Measured) °C:

Cooler Temps (Corrected) °C:

Cooler 1: (2.0);

Cooler 1: (2.2);

3. Type Of TB Received

W or S N/A

6. Dates/Times/IDs on COC match Sample Label

7. VOCs have headspace

8. Bottles received for unspecified tests

9. Compositing instructions clear

10. Voa Soil Kits/Jars received past 48hrs?

11. % Solids Jar received?

Misc. Information

25-Gram 5-GramNumber of Encores: Number of 5035 Field Kits: Number of Lab Filtered Metals:

Test Strip Lot #s: pH 0-3 230315 pH 10-12 219813A Other: (Specify)

Y or N N/A

Y or N

Therm ID: IR 1; Therm CF: 0.2; # of Coolers: 1

Y or N N/A

12. Residual Chlorine Present?

Residual Chlorine Test Strip Lot #:

Technician: Reviewer:CARLOSD Date:Date: 2/16/2023 11:10:00 A

FC2733: Chain of Custody

FC2733

QC Evaluation: DOD QSM5.x Limits Page 1 of 4

Account: FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC Collected: 02/14/23 thru 02/15/23

QC Sample ID CAS# Analyte Sample Result Result Units Limits Type Type

V1A1749 SW846 8260D

V1A1749-BS 71-43-2 Benzene BSP REC 95 % 79-120 V1A1749-BS 100-41-4 Ethylbenzene BSP REC 90 % 79-121 V1A1749-BS 1634-04-4 Methyl Tert Butyl Ether BSP REC 105 % 71-124 V1A1749-BS 91-20-3 Naphthalene BSP REC 88 % 61-128 V1A1749-BS 108-88-3 Toluene BSP REC 93 % 80-121 V1A1749-BS 1330-20-7 Xylene (total) BSP REC 94 % 79-121 V1A1749-BS 1868-53-7 Dibromofluoromethane BSP SURR 100 % 80-119 V1A1749-BS 17060-07-0 1,2-Dichloroethane-D4 BSP SURR 96 % 81-118 V1A1749-BS 2037-26-5 Toluene-D8 BSP SURR 99 % 89-112 V1A1749-BS 460-00-4 4-Bromofluorobenzene BSP SURR 98 % 85-114 FC3038-10MS* 71-43-2 Benzene MS REC 90 % 79-120 FC3038-10MS* 100-41-4 Ethylbenzene MS REC 81 % 79-121 FC3038-10MS* 1634-04-4 Methyl Tert Butyl Ether MS REC 105 % 71-124 FC3038-10MS* 91-20-3 Naphthalene MS REC 91 % 61-128 FC3038-10MS* 108-88-3 Toluene MS REC 89 % 80-121 FC3038-10MS* 1330-20-7 Xylene (total) MS REC 89 % 79-121 FC3038-10MS* 1868-53-7 Dibromofluoromethane MS SURR 98 % 80-119 FC3038-10MS* 17060-07-0 1,2-Dichloroethane-D4 MS SURR 95 % 81-118 FC3038-10MS* 2037-26-5 Toluene-D8 MS SURR 98 % 89-112 FC3038-10MS* 460-00-4 4-Bromofluorobenzene MS SURR 101 % 85-114 FC3038-10MSD* 71-43-2 Benzene MSD REC 95 % 79-120 FC3038-10MSD* 71-43-2 Benzene MSD RPD 4 % 20 FC3038-10MSD* 100-41-4 Ethylbenzene MSD REC 87 % 79-121 FC3038-10MSD* 100-41-4 Ethylbenzene MSD RPD 5 % 20 FC3038-10MSD* 1634-04-4 Methyl Tert Butyl Ether MSD REC 108 % 71-124 FC3038-10MSD* 1634-04-4 Methyl Tert Butyl Ether MSD RPD 2 % 20 FC3038-10MSD* 91-20-3 Naphthalene MSD REC 95 % 61-128 FC3038-10MSD* 91-20-3 Naphthalene MSD RPD 3 % 20 FC3038-10MSD* 108-88-3 Toluene MSD REC 95 % 80-121 FC3038-10MSD* 108-88-3 Toluene MSD RPD 6 % 20 FC3038-10MSD* 1330-20-7 Xylene (total) MSD REC 95 % 79-121 FC3038-10MSD* 1330-20-7 Xylene (total) MSD RPD 5 % 20 FC3038-10MSD* 1868-53-7 Dibromofluoromethane MSD SURR 99 % 80-119 FC3038-10MSD* 17060-07-0 1,2-Dichloroethane-D4 MSD SURR 94 % 81-118 FC3038-10MSD* 2037-26-5 Toluene-D8 MSD SURR 97 % 89-112 FC3038-10MSD* 460-00-4 4-Bromofluorobenzene MSD SURR 102 % 85-114 V1A1749-MB 1868-53-7 Dibromofluoromethane MB SURR 100 % 80-119 V1A1749-MB 17060-07-0 1,2-Dichloroethane-D4 MB SURR 95 % 81-118 V1A1749-MB 2037-26-5 Toluene-D8 MB SURR 97 % 89-112 V1A1749-MB 460-00-4 4-Bromofluorobenzene MB SURR 100 % 85-114 FC2733-11 1868-53-7 Dibromofluoromethane SAMP SURR 99 % 80-119 FC2733-11 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 94 % 81-118

* Sample used for QC is not from job FC2733

FC2733

5.2

QC Evaluation: DOD QSM5.x Limits Page 2 of 4

Account: FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC Collected: 02/14/23 thru 02/15/23

QC Sample ID CAS# Analyte Sample Result Result Units Limits Type Type

FC2733-11 2037-26-5 Toluene-D8 SAMP SURR 98 % 89-112 FC2733-11 460-00-4 4-Bromofluorobenzene SAMP SURR 101 % 85-114 FC2733-14 1868-53-7 Dibromofluoromethane SAMP SURR 100 % 80-119 FC2733-14 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 95 % 81-118 FC2733-14 2037-26-5 Toluene-D8 SAMP SURR 97 % 89-112 FC2733-14 460-00-4 4-Bromofluorobenzene SAMP SURR 98 % 85-114

VI2823 SW846 8260D

VI2823-BS 71-43-2 Benzene BSP REC 112 % 79-120 VI2823-BS 100-41-4 Ethylbenzene BSP REC 100 % 79-121 VI2823-BS 1634-04-4 Methyl Tert Butyl Ether BSP REC 112 % 71-124 VI2823-BS 91-20-3 Naphthalene BSP REC 91 % 61-128 VI2823-BS 108-88-3 Toluene BSP REC 100 % 80-121 VI2823-BS 1330-20-7 Xylene (total) BSP REC 100 % 79-121 VI2823-BS 1868-53-7 Dibromofluoromethane BSP SURR 102 % 80-119 VI2823-BS 17060-07-0 1,2-Dichloroethane-D4 BSP SURR 106 % 81-118 VI2823-BS 2037-26-5 Toluene-D8 BSP SURR 98 % 89-112 VI2823-BS 460-00-4 4-Bromofluorobenzene BSP SURR 99 % 85-114 FC2733-2MS 71-43-2 Benzene MS REC 73 a % 79-120 FC2733-2MS 100-41-4 Ethylbenzene MS REC 86 % 79-121 FC2733-2MS 1634-04-4 Methyl Tert Butyl Ether MS REC 117 % 71-124 FC2733-2MS 91-20-3 Naphthalene MS REC 98 % 61-128 FC2733-2MS 108-88-3 Toluene MS REC 106 % 80-121 FC2733-2MS 1330-20-7 Xylene (total) MS REC 104 % 79-121 FC2733-2MS 1868-53-7 Dibromofluoromethane MS SURR 103 % 80-119 FC2733-2MS 17060-07-0 1,2-Dichloroethane-D4 MS SURR 100 % 81-118 FC2733-2MS 2037-26-5 Toluene-D8 MS SURR 98 % 89-112 FC2733-2MS 460-00-4 4-Bromofluorobenzene MS SURR 100 % 85-114 FC2733-2MSD 71-43-2 Benzene MSD REC 62 a % 79-120 FC2733-2MSD 71-43-2 Benzene MSD RPD 3 % 20 FC2733-2MSD 100-41-4 Ethylbenzene MSD REC 75 % 79-121 FC2733-2MSD 100-41-4 Ethylbenzene MSD RPD 5 % 20 FC2733-2MSD 1634-04-4 Methyl Tert Butyl Ether MSD REC 114 % 71-124 FC2733-2MSD 1634-04-4 Methyl Tert Butyl Ether MSD RPD 3 % 20 FC2733-2MSD 91-20-3 Naphthalene MSD REC 92 % 61-128 FC2733-2MSD 91-20-3 Naphthalene MSD RPD 5 % 20 FC2733-2MSD 108-88-3 Toluene MSD REC 99 % 80-121 FC2733-2MSD 108-88-3 Toluene MSD RPD 6 % 20 FC2733-2MSD 1330-20-7 Xylene (total) MSD REC 99 % 79-121 FC2733-2MSD 1330-20-7 Xylene (total) MSD RPD 5 % 20 FC2733-2MSD 1868-53-7 Dibromofluoromethane MSD SURR 104 % 80-119 FC2733-2MSD 17060-07-0 1,2-Dichloroethane-D4 MSD SURR 108 % 81-118 FC2733-2MSD 2037-26-5 Toluene-D8 MSD SURR 96 % 89-112 FC2733-2MSD 460-00-4 4-Bromofluorobenzene MSD SURR 100 % 85-114

* Sample used for QC is not from job FC2733

FC2733

QC Evaluation: DOD QSM5.x Limits Page 3 of 4

Account: FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC Collected: 02/14/23 thru 02/15/23

QC Sample ID CAS# Analyte Sample Result Result Units Limits Type Type

VI2823-MB 1868-53-7 Dibromofluoromethane MB SURR 94 % 80-119 VI2823-MB 17060-07-0 1,2-Dichloroethane-D4 MB SURR 100 % 81-118 VI2823-MB 2037-26-5 Toluene-D8 MB SURR 93 % 89-112 VI2823-MB 460-00-4 4-Bromofluorobenzene MB SURR 100 % 85-114 FC2733-1 1868-53-7 Dibromofluoromethane SAMP SURR 96 % 80-119 FC2733-1 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 98 % 81-118 FC2733-1 2037-26-5 Toluene-D8 SAMP SURR 93 % 89-112 FC2733-1 460-00-4 4-Bromofluorobenzene SAMP SURR 98 % 85-114 FC2733-2 1868-53-7 Dibromofluoromethane SAMP SURR 96 % 80-119 FC2733-2 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 99 % 81-118 FC2733-2 2037-26-5 Toluene-D8 SAMP SURR 94 % 89-112 FC2733-2 460-00-4 4-Bromofluorobenzene SAMP SURR 98 % 85-114 FC2733-3 1868-53-7 Dibromofluoromethane SAMP SURR 97 % 80-119 FC2733-3 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 103 % 81-118 FC2733-3 2037-26-5 Toluene-D8 SAMP SURR 93 % 89-112 FC2733-3 460-00-4 4-Bromofluorobenzene SAMP SURR 98 % 85-114 FC2733-4 1868-53-7 Dibromofluoromethane SAMP SURR 95 % 80-119 FC2733-4 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 96 % 81-118 FC2733-4 2037-26-5 Toluene-D8 SAMP SURR 94 % 89-112 FC2733-4 460-00-4 4-Bromofluorobenzene SAMP SURR 98 % 85-114 FC2733-5 1868-53-7 Dibromofluoromethane SAMP SURR 96 % 80-119 FC2733-5 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 102 % 81-118 FC2733-5 2037-26-5 Toluene-D8 SAMP SURR 93 % 89-112 FC2733-5 460-00-4 4-Bromofluorobenzene SAMP SURR 96 % 85-114 FC2733-6 1868-53-7 Dibromofluoromethane SAMP SURR 95 % 80-119 FC2733-6 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 99 % 81-118 FC2733-6 2037-26-5 Toluene-D8 SAMP SURR 93 % 89-112 FC2733-6 460-00-4 4-Bromofluorobenzene SAMP SURR 94 % 85-114 FC2733-7 1868-53-7 Dibromofluoromethane SAMP SURR 95 % 80-119 FC2733-7 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 99 % 81-118 FC2733-7 2037-26-5 Toluene-D8 SAMP SURR 92 % 89-112 FC2733-7 460-00-4 4-Bromofluorobenzene SAMP SURR 96 % 85-114 FC2733-8 1868-53-7 Dibromofluoromethane SAMP SURR 97 % 80-119 FC2733-8 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 101 % 81-118 FC2733-8 2037-26-5 Toluene-D8 SAMP SURR 94 % 89-112 FC2733-8 460-00-4 4-Bromofluorobenzene SAMP SURR 98 % 85-114 FC2733-9 1868-53-7 Dibromofluoromethane SAMP SURR 96 % 80-119 FC2733-9 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 101 % 81-118 FC2733-9 2037-26-5 Toluene-D8 SAMP SURR 94 % 89-112 FC2733-9 460-00-4 4-Bromofluorobenzene SAMP SURR 97 % 85-114 FC2733-10 1868-53-7 Dibromofluoromethane SAMP SURR 98 % 80-119 FC2733-10 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 103 % 81-118 FC2733-10 2037-26-5 Toluene-D8 SAMP SURR 92 % 89-112 FC2733-10 460-00-4 4-Bromofluorobenzene SAMP SURR 97 % 85-114 FC2733-11 1868-53-7 Dibromofluoromethane SAMP SURR 95 % 80-119

* Sample used for QC is not from job FC2733

FC2733

QC Evaluation: DOD QSM5.x Limits Page 4 of 4

Account: FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC Collected: 02/14/23 thru 02/15/23

QC Sample ID CAS# Analyte Sample Result Result Units Limits Type Type

FC2733-11 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 99 % 81-118 FC2733-11 2037-26-5 Toluene-D8 SAMP SURR 93 % 89-112 FC2733-11 460-00-4 4-Bromofluorobenzene SAMP SURR 98 % 85-114 FC2733-12 1868-53-7 Dibromofluoromethane SAMP SURR 96 % 80-119 FC2733-12 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 100 % 81-118 FC2733-12 2037-26-5 Toluene-D8 SAMP SURR 93 % 89-112 FC2733-12 460-00-4 4-Bromofluorobenzene SAMP SURR 95 % 85-114 FC2733-13 1868-53-7 Dibromofluoromethane SAMP SURR 95 % 80-119 FC2733-13 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 98 % 81-118 FC2733-13 2037-26-5 Toluene-D8 SAMP SURR 95 % 89-112 FC2733-13 460-00-4 4-Bromofluorobenzene SAMP SURR 98 % 85-114 FC2733-14 1868-53-7 Dibromofluoromethane SAMP SURR 95 % 80-119 FC2733-14 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 96 % 81-118 FC2733-14 2037-26-5 Toluene-D8 SAMP SURR 95 % 89-112 FC2733-14 460-00-4 4-Bromofluorobenzene SAMP SURR 102 % 85-114 FC2733-15 1868-53-7 Dibromofluoromethane SAMP SURR 97 % 80-119 FC2733-15 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 101 % 81-118 FC2733-15 2037-26-5 Toluene-D8 SAMP SURR 93 % 89-112 FC2733-15 460-00-4 4-Bromofluorobenzene SAMP SURR 97 % 85-114 FC2733-16 1868-53-7 Dibromofluoromethane SAMP SURR 97 % 80-119 FC2733-16 17060-07-0 1,2-Dichloroethane-D4 SAMP SURR 100 % 81-118 FC2733-16 2037-26-5 Toluene-D8 SAMP SURR 95 % 89-112 FC2733-16 460-00-4 4-Bromofluorobenzene SAMP SURR 97 % 85-114

(a) Outside control limits due to high level in sample relative to spike amount.

* Sample used for QC is not from job FC2733

FC2733

MS Volatiles

QC Data Summaries

Includes the following where applicable:

• Method Blank Summaries

• Blank Spike Summaries

• Matrix Spike and Duplicate Summaries

• Instrument Performance Checks (BFB)

• Internal Standard Area Summaries

• Surrogate Recovery Summaries

• Initial and Continuing Calibration Summaries

• Run Sequence Reports

Orlando, FL Section 6

Method Blank Summary Page 1 of 1

Account: FPMRNYR FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VI2823-MB I754402.D 1 02/17/23 JW n/a n/a VI2823

The QC reported here applies to the following samples: Method: SW846 8260D

FC2733-1, FC2733-2, FC2733-3, FC2733-4, FC2733-5, FC2733-6, FC2733-7, FC2733-8, FC2733-9, FC2733-10, FC2733-12, FC2733-13, FC2733-14, FC2733-15, FC2733-16

CAS No. Compound Result RL MDL Units Q

71-43-2 Benzene ND 1.0 0.31 ug/l 100-41-4 Ethylbenzene ND 1.0 0.36 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 1.0 0.23 ug/l 91-20-3 Naphthalene ND 5.0 1.0 ug/l 108-88-3 Toluene ND 1.0 0.30 ug/l 1330-20-7 Xylene (total) ND 3.0 0.72 ug/l

CAS No. Surrogate Recoveries Limits

1868-53-7 Dibromofluoromethane 94% 83-118% 17060-07-0 1,2-Dichloroethane-D4 100% 79-125% 2037-26-5 Toluene-D8 93% 85-112% 460-00-4 4-Bromofluorobenzene 100% 83-118%

Raw Data: I754402.D

FC2733

6.1.1

Method Blank Summary Page 1 of 1

Account: FPMRNYR FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1A1749-MB 1A44181.D 1 03/03/23 JW n/a n/a V1A1749

The QC reported here applies to the following samples: Method: SW846 8260D

FC2733-11, FC2733-14

CAS No. Compound Result RL MDL Units Q

71-43-2 Benzene ND 1.0 0.31 ug/l 100-41-4 Ethylbenzene ND 1.0 0.36 ug/l 1634-04-4 Methyl Tert Butyl Ether ND 1.0 0.23 ug/l 91-20-3 Naphthalene ND 5.0 1.0 ug/l 108-88-3 Toluene ND 1.0 0.30 ug/l 1330-20-7 Xylene (total) ND 3.0 0.72 ug/l

CAS No. Surrogate Recoveries Limits

1868-53-7 Dibromofluoromethane 100% 83-118% 17060-07-0 1,2-Dichloroethane-D4 95% 79-125% 2037-26-5 Toluene-D8 97% 85-112% 460-00-4 4-Bromofluorobenzene 100% 83-118%

Raw Data: 1A44181.D

FC2733

6.1.2

Blank Spike Summary Page 1 of 1

Account: FPMRNYR FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch VI2823-BS I754401.D 1 02/17/23 JW n/a n/a VI2823

The QC reported here applies to the following samples: Method: SW846 8260D

FC2733-1, FC2733-2, FC2733-3, FC2733-4, FC2733-5, FC2733-6, FC2733-7, FC2733-8, FC2733-9, FC2733-10, FC2733-12, FC2733-13, FC2733-14, FC2733-15, FC2733-16

Spike BSP BSP CAS No. Compound ug/l ug/l % Limits

71-43-2 Benzene 25 28.1 112 81-122 100-41-4 Ethylbenzene 25 25.0 100 81-121 1634-04-4 Methyl Tert Butyl Ether 25 27.9 112 72-117 91-20-3 Naphthalene 25 22.7 91 63-132 108-88-3 Toluene 25 25.0 100 80-120 1330-20-7 Xylene (total) 75 74.8 100 80-126

CAS No. Surrogate Recoveries BSP Limits

1868-53-7 Dibromofluoromethane 102% 83-118% 17060-07-0 1,2-Dichloroethane-D4 106% 79-125% 2037-26-5 Toluene-D8 98% 85-112% 460-00-4 4-Bromofluorobenzene 99% 83-118%

* = Outside of Control Limits.

Raw Data: I754401.D

FC2733

6.2.1

Blank Spike Summary Page 1 of 1

Account: FPMRNYR FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1A1749-BS 1A44179.D 1 03/03/23 JW n/a n/a V1A1749

The QC reported here applies to the following samples: Method: SW846 8260D

FC2733-11, FC2733-14

Spike BSP BSP CAS No. Compound ug/l ug/l % Limits

71-43-2 Benzene 25 23.7 95 81-122 100-41-4 Ethylbenzene 25 22.6 90 81-121 1634-04-4 Methyl Tert Butyl Ether 25 26.3 105 72-117 91-20-3 Naphthalene 25 21.9 88 63-132 108-88-3 Toluene 25 23.3 93 80-120 1330-20-7 Xylene (total) 75 70.4 94 80-126

CAS No. Surrogate Recoveries BSP Limits

1868-53-7 Dibromofluoromethane 100% 83-118% 17060-07-0 1,2-Dichloroethane-D4 96% 79-125% 2037-26-5 Toluene-D8 99% 85-112% 460-00-4 4-Bromofluorobenzene 98% 83-118%

* = Outside of Control Limits.

Raw Data: 1A44179.D

FC2733

6.2.2

Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1

Account: FPMRNYR FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch FC2733-2MS I754424.D 5 02/17/23 JW n/a n/a VI2823 FC2733-2MSD I754425.D 5 02/17/23 JW n/a n/a VI2823 FC2733-2 I754410.D 5 02/17/23 JW n/a n/a VI2823

The QC reported here applies to the following samples: Method: SW846 8260D

FC2733-1, FC2733-2, FC2733-3, FC2733-4, FC2733-5, FC2733-6, FC2733-7, FC2733-8, FC2733-9, FC2733-10, FC2733-12, FC2733-13, FC2733-14, FC2733-15, FC2733-16

FC2733-2 Spike MS MS Spike MSD MSD Limits CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

71-43-2 Benzene 361 125 452 73* a 125 438 62* a 3 81-122/14 100-41-4 Ethylbenzene 185 125 293 86 125 279 75* 5 81-121/14 1634-04-4 Methyl Tert Butyl Ether 5.0 U 125 146 117 125 142 114 3 72-117/14 91-20-3 Naphthalene 36.1 125 158 98 125 151 92 5 63-132/25 108-88-3 Toluene 5.0 U 125 132 106 125 124 99 6 80-120/14 1330-20-7 Xylene (total) 15 U 375 390 104 375 371 99 5 80-126/15

CAS No. Surrogate Recoveries MS MSD FC2733-2 Limits

1868-53-7 Dibromofluoromethane 103% 104% 96% 83-118% 17060-07-0 1,2-Dichloroethane-D4 100% 108% 99% 79-125% 2037-26-5 Toluene-D8 98% 96% 94% 85-112% 460-00-4 4-Bromofluorobenzene 100% 100% 98% 83-118%

(a) Outside control limits due to high level in sample relative to spike amount.

* = Outside of Control Limits.

Raw Data: I754424.D I754425.D

FC2733

6.3.1

Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1

Account: FPMRNYR FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch FC3038-10MS 1A44213.D 20 03/03/23 JW n/a n/a V1A1749 FC3038-10MSD 1A44215.D 20 03/03/23 JW n/a n/a V1A1749 FC3038-10 1A44191.D 20 03/03/23 JW n/a n/a V1A1749

The QC reported here applies to the following samples: Method: SW846 8260D

FC2733-11, FC2733-14

FC3038-10 Spike MS MS Spike MSD MSD Limits CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

71-43-2 Benzene 97.2 500 547 90 500 570 95 4 81-122/14 100-41-4 Ethylbenzene 153 500 557 81 500 588 87 5 81-121/14 1634-04-4 Methyl Tert Butyl Ether ND 500 525 105 500 538 108 2 72-117/14 91-20-3 Naphthalene 170 500 625 91 500 646 95 3 63-132/25 108-88-3 Toluene ND 500 447 89 500 473 95 6 80-120/14 1330-20-7 Xylene (total) 200 1500 1540 89 1500 1620 95 5 80-126/15

CAS No. Surrogate Recoveries MS MSD FC3038-10 Limits

1868-53-7 Dibromofluoromethane 98% 99% 99% 83-118% 17060-07-0 1,2-Dichloroethane-D4 95% 94% 95% 79-125% 2037-26-5 Toluene-D8 98% 97% 97% 85-112% 460-00-4 4-Bromofluorobenzene 101% 102% 100% 83-118%

* = Outside of Control Limits.

Raw Data: 1A44213.D 1A44215.D

FC2733

6.3.2

Instrument Performance Check (BFB) Page 1 of 1

Account: FPMRNYR FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC

Sample: V1A1730-BFB Injection Date: 02/07/23 Lab File ID: 1A43422.D Injection Time: 06:50 Instrument ID: GCMS1A

Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail

50 15.0 - 40.0% of mass 95 7900 24.5 Pass 75 30.0 - 60.0% of mass 95 16396 50.9 Pass 95 Base peak, 100% relative abundance 32221 100.0 Pass 96 5.0 - 9.0% of mass 95 2224 6.90 Pass 173 Less than 2.0% of mass 174 194 0.60 (0.72) a Pass 174 50.0 - 100.0% of mass 95 26835 83.3 Pass 175 5.0 - 9.0% of mass 174 2005 6.22 (7.47) a Pass 176 95.0 - 101.0% of mass 174 27018 83.9 (100.7) a Pass 177 5.0 - 9.0% of mass 176 1728 5.36 (6.40) b Pass

(a) Value is % of mass 174

(b) Value is % of mass 176

This check applies to the following Samples, MS, MSD, Blanks, and Standards:

Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID

V1A1730-IC1730 1A43424.D 02/07/23 07:26 00:36 Initial cal 1 V1A1730-IC1730 1A43426.D 02/07/23 08:30 01:40 Initial cal 2 V1A1730-IC1730 1A43428.D 02/07/23 09:04 02:14 Initial cal 3 V1A1730-IC1730 1A43430.D 02/07/23 09:38 02:48 Initial cal 4 V1A1730-ICC1730 1A43432.D 02/07/23 10:12 03:22 Initial cal 5 V1A1730-IC1730 1A43434.D 02/07/23 10:46 03:56 Initial cal 6 V1A1730-IC1730 1A43436.D 02/07/23 11:20 04:30 Initial cal 7 V1A1730-ICV1730 1A43440.D 02/07/23 13:26 06:36 Initial cal verification 5

Raw Data: 1A43422.D

FC2733

6.4.1

Account: FPMRNYR FPM Remediations Project: Joint Base Charleston AFB; N Charleston, SC

Sample: V1A1749-BFB Injection Date: 03/03/23 Lab File ID: 1A44177.D Injection Time: 08:34 Instrument ID: GCMS1A

Raw % Relative m/e Ion Abundance Criteria Abundance Abundance Pass/Fail

50 15.0 - 40.0% of mass 95 6455 21.6 Pass 75 30.0 - 60.0% of mass 95 14780 49.5 Pass 95 Base peak, 100% relative abundance 29835 100.0 Pass 96 5.0 - 9.0% of mass 95 1919 6.43 Pass 173 Less than 2.0% of mass 174 228 0.76 (0.86) a Pass 174 50.0 - 100.0% of mass 95 26549 89.0 Pass 175 5.0 - 9.0% of mass 174 1837 6.16 (6.92) a Pass 176 95.0 - 101.0% of mass 174 25579 85.7 (96.3) a Pass 177 5.0 - 9.0% of mass 176 1669 5.59 (6.52) b Pass

(a) Value is % of mass 174

(b) Value is % of mass 176

This check applies to the following Samples, MS, MSD, Blanks, and Standards:

Lab Lab Date Time Hours Client Sample ID File ID Analyzed Analyzed Lapsed Sample ID

V1A1749-CC1730 1A44177.D 03/03/23 08:34 00:00 Continuing cal 5 V1A1749-BS 1A44179.D 03/03/23 09:19 00:45 Blank Spike V1A1749-MB 1A44181.D 03/03/23 09:54 01:20 Method Blank ZZZZZZ 1A44185.D 03/03/23 11:03 02:29 (unrelated sample)

FC2733-11 1A44187.D 03/03/23 11:38 03:04 MW-2-FLD

FC2733-14 1A44189.D 03/03/23 12:12 03:38 ST27-MW20-08R

FC3038-10 1A44191.D 03/03/23 12:47 04:13 (used for QC only; not part of job FC2733) ZZZZZZ 1A44193.D 03/03/23 13:22 04:48 (unrelated sample) ZZZZZZ 1A44195.D 03/03/23 13:56 05:22 (unrelated sample) ZZZZZZ 1A44197.D 03/03/23 14:31 05:57 (unrelated sample) ZZZZZZ 1A44199.D 03/03/23 15:06 06:32 (unrelated sample) ZZZZZZ 1A44201.D 03/03/23 15:40 07:06 (unrelated sample) ZZZZZZ 1A44203.D 03/03/23 16:15 07:41 (unrelated sample) ZZZZZZ 1A44205.D 03/03/23 16:50 08:16 (unrelated sample) ZZZZZZ 1A44207.D 03/03/23 17:24 08:50…