ATTACHMENT R - Geo Inv Analytical Rep.pdf

L2232418

Terracon Consultants, Inc.

JD195305A

NEW LONDON NAVY BASE

Client:

Project Name:

Project Number:

07/14/22

Eight Walkup Drive, Westborough, MA 01581-1019

Lab Number:

Report Date:

508-898-9220 (Fax) 508-898-9193 800-624-9220 - www.alphalab.com

19955 Highland Vista Drive

Suite 170

Katie FordneyATTN:

ANALYTICAL REPORT

Certifications & Approvals: MA (M-MA086), NH NELAP (2064), CT (PH-0574), IL (200077), ME (MA00086), MD (348), NJ (MA935), NY (11148), NC (25700/666), PA (68-03671), RI (LAO00065), TX (T104704476), VT (VT-0935), VA (460195), USDA (Permit #P330-17-00196).

Asburn, VA 20147

(703) 726-8030Phone:

The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in its entirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original.

Serial_No:07142217:43

Page 1 of 43 APPENDIX C5

L2232418-01

L2232418-02

Alpha Sample ID

MB-212

MB-216

Client ID

GROTON, CT

GROTON, CT

Sample Location

NEW LONDON NAVY BASE

JD195305A

Project Name:

Project Number:

Lab Number:

Report Date:

L2232418 07/14/22

06/16/22 10:00

06/16/22 10:10

Collection Date/TimeMatrix Receive Date

SOIL

SOIL

06/17/22

06/17/22

Serial_No:07142217:43

APPEN

D

IX C

Project Name:

Project Number:

Lab Number:

Report Date:

For each analytical method referenced in this laboratory report package, were all specified QA/QC performance criteria followed (including the requirement to explain any criteria falling outside of acceptable guidelines, as specified in the CT DEP method-specific Reasonable Confidence Protocol documents)?

Were the method specified preservation and holding time requirements met?

VPH & EPH Methods Only: Was the VPH or EPH Method conducted without significant modifications (see Section 11.3 of respective Methods)?

Were all samples received by the laboratory in a condition consistent with that described on the associated chain-of-custody document(s)?

Were all samples received at an appropriate temperature (<6°C)?

Were all QA/QC performance criteria specified in the CT DEP Reasonable Confidence Protocol documents achieved?

Were reporting limits specified or referenced on the chain-of-custody?

Were these reporting limits met?

For each analytical method referenced in this laboratory report package, were results reported for all constituents identified in the method-specific analyte lists presented in the Reasonable Confidence Protocol documents?

Are project-specific matrix spikes and laboratory duplicates included in this data set?

YES

YES

N/A

YES

YES

YES

NO

N/A

NO

NO

1a

1b

5a

5b

CT DEP Reasonable Confidence Protocols Laboratory Analysis

QA/QC Certification Form

L2232418NEW LONDON NAVY BASE

JD195305A

Note: For all questions to which the response was "No" (with the exception of question #7), additional information must be provided in an attached narrative. If the answer to question #1, #1A or question B is "No", the data package does not meet the requirements for "Reasonable Confidence".

07/14/22

Page 3 of 43 APPENDIX C5

NEW LONDON NAVY BASE

JD195305A

Project Name:

Project Number:

Lab Number:

Report Date:

L2232418

07/14/22

Case Narrative

The samples were received in accordance with the Chain of Custody and no significant deviations were encountered during the preparation or analysis unless otherwise noted. Sample Receipt, Container Information, and the Chain of Custody are located at the back of the report.

Results contained within this report relate only to the samples submitted under this Alpha Lab Number and meet NELAP requirements for all

NELAP accredited parameters unless otherwise noted in the following narrative. The data presented in this report is organized by parameter

(i.e. VOC, SVOC, etc.). Sample specific Quality Control data (i.e. Surrogate Spike Recovery) is reported at the end of the target analyte list for each individual sample, followed by the Laboratory Batch Quality Control at the end of each parameter. Tentatively Identified

Compounds (TICs), if requested, are reported for compounds identified to be present and are not part of the method/program Target

Compound List, even if only a subset of the TCL are being reported. If a sample was re-analyzed or re-extracted due to a required quality control corrective action and if both sets of data are reported, the Laboratory ID of the re-analysis or re-extraction is designated with an "R" or "RE", respectively.

When multiple Batch Quality Control elements are reported (e.g. more than one LCS), the associated samples for each element are noted in the grey shaded header line of each data table. Any Laboratory Batch, Sample Specific % recovery or RPD value that is outside the listed

Acceptance Criteria is bolded in the report. In reference to questions H (CAM) or 4 (RCP) when "NO" is checked, the performance criteria for CAM and RCP methods allow for some quality control failures to occur and still be within method compliance. In these instances, the specific failure is not narrated but noted in the associated QC Outlier Summary Report, located directly after the Case Narrative. QC information is also incorporated in the Data Usability Assessment table (Format 11) of our Data Merger tool, where it can be reviewed in conjunction with the sample result, associated regulatory criteria and any associated data usability implications.

Soil/sediments, solids and tissues are reported on a dry weight basis unless otherwise noted. Definitions of all data qualifiers and acronyms used in this report are provided in the Glossary located at the back of the report.

HOLD POLICY - For samples submitted on hold, Alpha's policy is to hold samples (with the exception of Air canisters) free of charge for 21 calendar days from the date the project is completed. After 21 calendar days, we will dispose of all samples submitted including those put on hold unless you have contacted your Alpha Project Manager and made arrangements for Alpha to continue to hold the samples. Air canisters will be disposed after 3 business days from the date the project is completed.

Please contact Project Management at 800-624-9220 with any questions.

Page 4 of 43 APPENDIX C5

Case Narrative (continued)

JD195305A

Project Name:

Project Number:

Lab Number:

Report Date:

L2232418

07/14/22

Report Submission

July 14, 2022: This final report includes the results of all requested analyses.

July 01, 2022: This is a preliminary report.

RCP Related Narratives

Report Submission

In reference to question 5a:

Reporting limits were not specified.

Sample Receipt

L2232418-01: The collection date and time on the chain of custody was 16-JUN-22 10:10; however, the collection date/time on the container label was 16-JUN-22 10:00. At the client's request, the collection date/time is reported as 16-JUN-22 10:00.

Volatile Organics

L2232418-01 and -02: Initial calibration utilized a quadratic fit for: 1,1-dichloropropene, trichloroethene

TCLP Metals

In reference to question 6:

At the client's request, all submitted samples were not analyzed for the full RCP list of constituents identified in the method specific analyte list presented in the RCP documents.

I, the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and belief and based upon my personal inquiry of those responsible for providing the information contained in this analytical report, such information is accurate and complete. This certificate of analysis is not complete unless this page accompanies any and all pages of this report.

Authorized Signature:

Title: Technical Director/Representative Date: 07/14/22

Page 5 of 43 APPENDIX C5

JD195305A

Project Name:

Project Number:

L2232418Lab Number:

Report Date:

QC OUTLIER SUMMARY REPORT

07/14/22

Method Client ID (Native ID) Lab ID Parameter QC Type Recovery/RPD

QC Limits

Data Quality Assessment

Associated Samples

There are no QC Outliers associated with this report.

Serial_No:07142217:43

APPEN

D

ORGANICS

Page 7 of 43 APPENDIX C5

VOLATILES

Page 8 of 43 APPENDIX C5

FF

Methylene chloride

1,1-Dichloroethane

Chloroform

Carbon tetrachloride

1,2-Dichloropropane

Dibromochloromethane

1,1,2-Trichloroethane

Tetrachloroethene

Chlorobenzene

Trichlorofluoromethane

1,2-Dichloroethane

1,1,1-Trichloroethane

Bromodichloromethane trans-1,3-Dichloropropene cis-1,3-Dichloropropene

1,3-Dichloropropene, Total

1,1-Dichloropropene

Bromoform

1,1,2,2-Tetrachloroethane

Benzene

Toluene

Ethylbenzene

Chloromethane

Bromomethane

Vinyl chloride

Chloroethane

1,1-Dichloroethene trans-1,2-Dichloroethene

Parameter Result Dilution Factor

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

1.5

1.0

ND

ND

ND

ND

ND

ND

ND

ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg

Qualifier Units RL

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

4.5

0.90

1.4

0.90

0.90

0.90

0.90

0.45

0.45

3.6

0.90

0.45

0.45

0.90

0.45

0.45

0.45

3.6

0.45

0.45

0.90

0.90

3.6

1.8

0.90

1.8

0.90

1.4

07/14/22

MB-212Client ID:

06/16/22 10:00Date Collected:

06/17/22Date Received:

GROTON, CTSample Location:

L2232418-01Lab ID:

Field Prep: Not Specified

Matrix: Soil Analytical Method:

Analytical Date:

Analyst:

79,8260C 06/29/22 13:32

JC

87%Percent Solids:

MDL

Sample Depth:

Page 9 of 43 APPENDIX C5

Trichloroethene

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Methyl tert butyl ether p/m-Xylene o-Xylene

Xylenes, Total cis-1,2-Dichloroethene

1,2-Dichloroethene, Total

Dibromomethane

1,2,3-Trichloropropane

Styrene

Dichlorodifluoromethane

Acetone

Carbon disulfide

2-Butanone

4-Methyl-2-pentanone

2-Hexanone

Acrylonitrile

Tetrahydrofuran

2,2-Dichloropropane

1,2-Dibromoethane

1,3-Dichloropropane

1,1,1,2-Tetrachloroethane

Bromobenzene n-Butylbenzene sec-Butylbenzene tert-Butylbenzene o-Chlorotoluene p-Chlorotoluene

1,2-Dibromo-3-chloropropane

Hexachlorobutadiene

Isopropylbenzene p-Isopropyltoluene

Naphthalene n-Propylbenzene

Parameter Result Dilution Factor

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg

Qualifier Units RL

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

0.45

1.8

1.8

1.8

1.8

1.8

0.90

0.90

0.90

0.90

1.8

1.8

0.90

9.0

9.0

9.0

9.0

9.0

3.6

3.6

1.8

0.90

1.8

0.45

1.8

0.90

0.90

1.8

1.8

1.8

2.7

3.6

0.90

0.90

3.6

0.90

07/14/22

MB-212Client ID:

06/16/22 10:00Date Collected:

06/17/22Date Received:

GROTON, CTSample Location:

L2232418-01Lab ID:

Field Prep: Not Specified

MDL

Sample Depth:

Page 10 of 43 APPENDIX C5

1,2,3-Trichlorobenzene

1,2,4-Trichlorobenzene

1,3,5-Trimethylbenzene

1,2,4-Trimethylbenzene trans-1,4-Dichloro-2-butene

1,1,2-Trichloro-1,2,2-Trifluoroethane

Parameter Result Dilution Factor

ND

ND

ND

ND

ND

ND

ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg

Qualifier Units RL

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

1.8

1.8

1.8

1.8

4.5

3.6

1,2-Dichloroethane-d4

Toluene-d8

4-Bromofluorobenzene

Dibromofluoromethane

70-130

70-130

70-130

70-130

Acceptance CriteriaSurrogate % Recovery Qualifier

07/14/22

MB-212Client ID:

06/16/22 10:00Date Collected:

06/17/22Date Received:

GROTON, CTSample Location:

L2232418-01Lab ID:

Field Prep: Not Specified

MDL

Sample Depth:

Page 11 of 43 APPENDIX C5

1,1-Dichloroethane

Chloroform

Carbon tetrachloride

1,2-Dichloropropane

Dibromochloromethane

1,1,2-Trichloroethane

Tetrachloroethene

Chlorobenzene

Trichlorofluoromethane

1,2-Dichloroethane

1,1,1-Trichloroethane

Bromodichloromethane trans-1,3-Dichloropropene cis-1,3-Dichloropropene

1,3-Dichloropropene, Total

1,1-Dichloropropene

Bromoform

1,1,2,2-Tetrachloroethane

Benzene

Toluene

Ethylbenzene

Chloromethane

Bromomethane

Vinyl chloride

Chloroethane

1,1-Dichloroethene trans-1,2-Dichloroethene

Parameter Result Dilution Factor

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg

Qualifier Units RL

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

2.8

0.56

0.84

0.56

0.56

0.56

0.56

0.28

0.28

2.2

0.56

0.28

0.28

0.56

0.28

0.28

0.28

2.2

0.28

0.28

0.56

0.56

2.2

1.1

0.56

1.1

0.56

0.84

07/14/22

MB-216Client ID:

06/16/22 10:10Date Collected:

06/17/22Date Received:

GROTON, CTSample Location:

L2232418-02Lab ID:

Field Prep: Not Specified

Matrix: Soil Analytical Method:

Analytical Date:

Analyst:

79,8260C 06/29/22 13:59

JC

93%Percent Solids:

MDL

Sample Depth:

Page 12 of 43 APPENDIX C5

Trichloroethene

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Methyl tert butyl ether p/m-Xylene o-Xylene

Xylenes, Total cis-1,2-Dichloroethene

1,2-Dichloroethene, Total

Dibromomethane

1,2,3-Trichloropropane

Styrene

Dichlorodifluoromethane

Acetone

Carbon disulfide

2-Butanone

4-Methyl-2-pentanone

2-Hexanone

Acrylonitrile

Tetrahydrofuran

2,2-Dichloropropane

1,2-Dibromoethane

1,3-Dichloropropane

1,1,1,2-Tetrachloroethane

Bromobenzene n-Butylbenzene sec-Butylbenzene tert-Butylbenzene o-Chlorotoluene p-Chlorotoluene

1,2-Dibromo-3-chloropropane

Hexachlorobutadiene

Isopropylbenzene p-Isopropyltoluene

Naphthalene n-Propylbenzene

Parameter Result Dilution Factor

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

6.3

ND

ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg

Qualifier Units RL

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

0.28

1.1

1.1

1.1

1.1

1.1

0.56

0.56

0.56

0.56

1.1

1.1

0.56

5.6

5.6

5.6

5.6

5.6

2.2

2.2

1.1

0.56

1.1

0.28

1.1

0.56

0.56

1.1

1.1

1.1

1.7

2.2

0.56

0.56

2.2

0.56

07/14/22

MB-216Client ID:

06/16/22 10:10Date Collected:

06/17/22Date Received:

GROTON, CTSample Location:

L2232418-02Lab ID:

Field Prep: Not Specified

MDL

Sample Depth:

Page 13 of 43 APPENDIX C5

1,2,3-Trichlorobenzene

1,2,4-Trichlorobenzene

1,3,5-Trimethylbenzene

1,2,4-Trimethylbenzene trans-1,4-Dichloro-2-butene

1,1,2-Trichloro-1,2,2-Trifluoroethane

Parameter Result Dilution Factor

ND

ND

ND

ND

ND

ND

ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg

Qualifier Units RL

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

1.1

1.1

1.1

1.1

2.8

2.2

1,2-Dichloroethane-d4

Toluene-d8

4-Bromofluorobenzene

Dibromofluoromethane

70-130

70-130

70-130

70-130

Acceptance CriteriaSurrogate % Recovery Qualifier

07/14/22

MB-216Client ID:

06/16/22 10:10Date Collected:

06/17/22Date Received:

GROTON, CTSample Location:

L2232418-02Lab ID:

Field Prep: Not Specified

MDL

Sample Depth:

Page 14 of 43 APPENDIX C5

Method Blank Analysis Batch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

06/29/22 09:01 79,8260CAnalytical Method:

Analytical Date:

07/14/22

Analyst: NLK

Methylene chloride

1,1-Dichloroethane

Chloroform

Carbon tetrachloride

1,2-Dichloropropane

Dibromochloromethane

1,1,2-Trichloroethane

Tetrachloroethene

Chlorobenzene

Trichlorofluoromethane

1,2-Dichloroethane

1,1,1-Trichloroethane

Bromodichloromethane trans-1,3-Dichloropropene cis-1,3-Dichloropropene

1,3-Dichloropropene, Total

1,1-Dichloropropene

Bromoform

1,1,2,2-Tetrachloroethane

Benzene

Toluene

Ethylbenzene

Chloromethane

Bromomethane

Vinyl chloride

Chloroethane

1,1-Dichloroethene trans-1,2-Dichloroethene

Trichloroethene

Parameter Result

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

RL

5.0

1.0

1.5

1.0

1.0

1.0

1.0

0.50

0.50

4.0

1.0

0.50

0.50

1.0

0.50

0.50

0.50

4.0

0.50

0.50

1.0

1.0

4.0

2.0

1.0

2.0

1.0

1.5

0.50 ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg

UnitsQualifier

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab for sample(s): 01-02 Batch:

WG1657430-5

MDL

Page 15 of 43 APPENDIX C5

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

06/29/22 09:01 79,8260CAnalytical Method:

Analytical Date:

07/14/22

Analyst: NLK

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Methyl tert butyl ether p/m-Xylene o-Xylene

Xylenes, Total cis-1,2-Dichloroethene

1,2-Dichloroethene, Total

Dibromomethane

1,2,3-Trichloropropane

Styrene

Dichlorodifluoromethane

Acetone

Carbon disulfide

2-Butanone

4-Methyl-2-pentanone

2-Hexanone

Acrylonitrile

Tetrahydrofuran

2,2-Dichloropropane

1,2-Dibromoethane

1,3-Dichloropropane

1,1,1,2-Tetrachloroethane

Bromobenzene n-Butylbenzene sec-Butylbenzene tert-Butylbenzene o-Chlorotoluene

Parameter Result

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

RL

2.0

2.0

2.0

2.0

2.0

1.0

1.0

1.0

1.0

2.0

2.0

1.0

4.0

4.0

2.0

1.0

2.0

0.50

2.0

1.0

1.0

2.0

2.0 ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg

UnitsQualifier

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab for sample(s): 01-02 Batch:

WG1657430-5

MDL

Page 16 of 43 APPENDIX C5

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

06/29/22 09:01 79,8260CAnalytical Method:

Analytical Date:

07/14/22

Analyst: NLK p-Chlorotoluene

1,2-Dibromo-3-chloropropane

Hexachlorobutadiene

Isopropylbenzene p-Isopropyltoluene

Naphthalene n-Propylbenzene

1,2,3-Trichlorobenzene

1,2,4-Trichlorobenzene

1,3,5-Trimethylbenzene

1,2,4-Trimethylbenzene trans-1,4-Dichloro-2-butene

1,1,2-Trichloro-1,2,2-Trifluoroethane

Parameter Result

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

RL

2.0

3.0

4.0

1.0

1.0

4.0

1.0

2.0

2.0

2.0

2.0

5.0

4.0 ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg

UnitsQualifier

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab for sample(s): 01-02 Batch:

WG1657430-5

1,2-Dichloroethane-d4

Toluene-d8

4-Bromofluorobenzene

Dibromofluoromethane

70-130

70-130

70-130

70-130

Surrogate %Recovery Qualifier Acceptance

Criteria

MDL

Page 17 of 43 APPENDIX C5

1,1-Dichloroethane

Chloroform

Carbon tetrachloride

1,2-Dichloropropane

Dibromochloromethane

1,1,2-Trichloroethane

Tetrachloroethene

Chlorobenzene

Trichlorofluoromethane

1,2-Dichloroethane

1,1,1-Trichloroethane

Bromodichloromethane trans-1,3-Dichloropropene cis-1,3-Dichloropropene

1,1-Dichloropropene

Bromoform

1,1,2,2-Tetrachloroethane

Benzene

Toluene

Ethylbenzene

Chloromethane

Bromomethane

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

52-130

57-147

Parameter

LCS

%Recovery

LCSD

%Recovery %Recovery

Limits RPD

RPD

Limits

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab Associated sample(s): 01-02 Batch: WG1657430-3 WG1657430-4

Lab Control Sample Analysis Batch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

07/14/22

Qual Qual Qual

Serial_No:07142217:43

APPEN

D

Vinyl chloride

Chloroethane

1,1-Dichloroethene trans-1,2-Dichloroethene

Trichloroethene

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Methyl tert butyl ether p/m-Xylene o-Xylene cis-1,2-Dichloroethene

Dibromomethane

1,2,3-Trichloropropane

Styrene

Dichlorodifluoromethane

Acetone

Carbon disulfide

2-Butanone

4-Methyl-2-pentanone

2-Hexanone

Acrylonitrile

Tetrahydrofuran

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

30-146

54-140

59-130

70-130

70-130

70-130

70-130

70-130

Parameter

LCS

%Recovery

LCSD

%Recovery %Recovery

Limits RPD

RPD

Limits

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab Associated sample(s): 01-02 Batch: WG1657430-3 WG1657430-4

Lab Control Sample Analysis Batch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

07/14/22

Qual Qual Qual

Serial_No:07142217:43

APPEN

D

2,2-Dichloropropane

1,2-Dibromoethane

1,3-Dichloropropane

1,1,1,2-Tetrachloroethane

Bromobenzene n-Butylbenzene sec-Butylbenzene tert-Butylbenzene o-Chlorotoluene p-Chlorotoluene

1,2-Dibromo-3-chloropropane

Hexachlorobutadiene

Isopropylbenzene p-Isopropyltoluene

Naphthalene n-Propylbenzene

1,2,3-Trichlorobenzene

1,2,4-Trichlorobenzene

1,3,5-Trimethylbenzene

1,2,4-Trimethylbenzene trans-1,4-Dichloro-2-butene

1,1,2-Trichloro-1,2,2-Trifluoroethane

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

68-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

Parameter

LCS

%Recovery

LCSD

%Recovery %Recovery

Limits RPD

RPD

Limits

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab Associated sample(s): 01-02 Batch: WG1657430-3 WG1657430-4

Lab Control Sample Analysis Batch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

07/14/22

Qual Qual Qual

Serial_No:07142217:43

APPEN

D

Parameter

LCS

%Recovery

LCSD

%Recovery %Recovery

Limits RPD

RPD

Limits

CT RCP Volatile Organics by EPA 5035 Low - Westborough Lab Associated sample(s): 01-02 Batch: WG1657430-3 WG1657430-4

Lab Control Sample Analysis Batch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene Dibromofluoromethane

70-130 70-130 70-130 70-130

Surrogate Qual%Recovery Qual%Recovery

LCS LCSD

07/14/22

Acceptance Criteria

Qual Qual Qual

Serial_No:07142217:43

APPEN

D

PETROLEUM

HYDROCARBONS

Page 22 of 43 APPENDIX C5

Gasoline Range Organics

Parameter Result Dilution Factor

ND ug/kg 1

Qualifier Units RL

Gasoline Range Organics - Westborough Lab

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

1,1,1-Trifluorotoluene

4-Bromofluorobenzene

70-130

70-130

Acceptance CriteriaSurrogate % Recovery Qualifier

07/14/22

MB-212Client ID:

06/16/22 10:00Date Collected:

06/17/22Date Received:

GROTON, CTSample Location:

L2232418-01Lab ID:

Field Prep: Not Specified

Matrix: Soil Extraction Method:

Analytical Method:

Analytical Date:

Analyst:

1,8015D(M) 06/24/22 18:58

BAD

87%Percent Solids:

MDL

Sample Depth:

Page 23 of 43 APPENDIX C5

Gasoline Range Organics

Parameter Result Dilution Factor

ND ug/kg 1

Qualifier Units RL

Gasoline Range Organics - Westborough Lab

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

1,1,1-Trifluorotoluene

4-Bromofluorobenzene

70-130

70-130

Acceptance CriteriaSurrogate % Recovery Qualifier

07/14/22

MB-216Client ID:

06/16/22 10:10Date Collected:

06/17/22Date Received:

GROTON, CTSample Location:

L2232418-02Lab ID:

Field Prep: Not Specified

Matrix: Soil Extraction Method:

Analytical Method:

Analytical Date:

Analyst:

1,8015D(M) 06/24/22 19:29

BAD

93%Percent Solids:

MDL

Sample Depth:

Page 24 of 43 APPENDIX C5

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

06/24/22 10:50 1,8015D(M)Analytical Method:

Analytical Date:

07/14/22

Analyst: BAD

Gasoline Range Organics

Parameter Result

ND

RL

2500ug/kg

UnitsQualifier

Gasoline Range Organics - Westborough Lab for sample(s): 01-02 Batch: WG1655338-4

1,1,1-Trifluorotoluene

4-Bromofluorobenzene

70-130

70-130

Surrogate %Recovery Qualifier Acceptance

Criteria

MDL

Page 25 of 43 APPENDIX C5

Gasoline Range Organics 102 101 80-120 1 20

LCS

%Recovery

LCSD

%Recovery %Recovery

Limits RPD

RPD

Limits

Gasoline Range Organics - Westborough Lab Associated sample(s): 01-02 Batch: WG1655338-2 WG1655338-3

Lab Control Sample Analysis Batch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

1,1,1-Trifluorotoluene 4-Bromofluorobenzene

70-130 70-130

Surrogate Qual%Recovery Qual%Recovery

LCS LCSD

07/14/22

Acceptance Criteria

Qual Qual Qual

Serial_No:07142217:43

APPEN

D

METALS

Page 27 of 43 APPENDIX C5

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

07/14/22

SAMPLE RESULTS

MB-212Client ID:

06/16/22 10:00Date Collected:

06/17/22Date Received:

Matrix: Soil

GROTON, CTSample Location:

L2232418-01Lab ID:

Field Prep: Not Specified

Parameter Result Dilution FactorQualifier Units RL

Date Analyzed

Analytical Method Analyst

Date Prepared

TCLP Metals by EPA 1311 - Mansfield Lab

Arsenic, TCLP

Barium, TCLP

Cadmium, TCLP

Chromium, TCLP

Lead, TCLP

Mercury, TCLP

Selenium, TCLP

Silver, TCLP

ND

ND

ND

ND

ND

ND

ND

ND

mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l

1.00

0.500

0.100

0.200

0.500

0.0010

0.500

0.100

07/14/22 00:23

07/14/22 00:23

07/14/22 00:23

07/14/22 00:23

07/14/22 00:23

06/26/22 12:15

07/14/22 00:23

07/14/22 00:23

1,6010D

1,6010D

1,6010D

1,6010D

1,6010D

1,7470A

1,6010D

1,6010D

NB

NB

NB

NB

NB

AW

NB

NB

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

06/23/22 15:47

07/07/22 09:13

07/07/22 09:13

EPA 3015

EPA 3015

EPA 3015

EPA 3015

EPA 3015

EPA 7470A

EPA 3015

EPA 3015

Prep Method

06/21/22 07:00TCLP/SPLP Ext. Date:

Percent Solids: 87%

MDL

Sample Depth:

Page 28 of 43 APPENDIX C5

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

07/14/22

SAMPLE RESULTS

MB-216Client ID:

06/16/22 10:10Date Collected:

06/17/22Date Received:

Matrix: Soil

GROTON, CTSample Location:

L2232418-02Lab ID:

Field Prep: Not Specified

Parameter Result Dilution FactorQualifier Units RL

Date Analyzed

Analytical Method Analyst

Date Prepared

TCLP Metals by EPA 1311 - Mansfield Lab

Arsenic, TCLP

Barium, TCLP

Cadmium, TCLP

Chromium, TCLP

Lead, TCLP

Mercury, TCLP

Selenium, TCLP

Silver, TCLP

ND

ND

ND

ND

ND

ND

ND

ND

mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l

1.00

0.500

0.100

0.200

0.500

0.0010

0.500

0.100

07/14/22 00:19

07/14/22 00:19

07/14/22 00:19

07/14/22 00:19

07/14/22 00:19

06/26/22 12:19

07/14/22 00:19

07/14/22 00:19

1,6010D

1,6010D

1,6010D

1,6010D

1,6010D

1,7470A

1,6010D

1,6010D

NB

NB

NB

NB

NB

AW

NB

NB

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

06/23/22 15:47

07/07/22 09:13

07/07/22 09:13

EPA 3015

EPA 3015

EPA 3015

EPA 3015

EPA 3015

EPA 7470A

EPA 3015

EPA 3015

Prep Method

06/21/22 07:00TCLP/SPLP Ext. Date:

Percent Solids: 93%

MDL

Sample Depth:

Page 29 of 43 APPENDIX C5

Parameter

Result

Result

Dilution Factor

Dilution Factor

Qualifier

Qualifier

Units

Units

RL

RL

Method Blank Analysis Batch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

Date Analyzed

Date Analyzed

Analytical Method

Analytical Method

Analyst

Analyst

Date Prepared

Date Prepared

07/14/22

Mercury, TCLP

Arsenic, TCLP

Barium, TCLP

Cadmium, TCLP

Chromium, TCLP

Lead, TCLP

Selenium, TCLP

Silver, TCLP

ND

ND

ND

ND

ND

ND

ND

ND

mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l

0.0010

1.00

0.500

0.100

0.200

0.500

0.500

0.100

06/26/22 11:25

07/14/22 00:05

07/14/22 00:05

07/14/22 00:05

07/14/22 00:05

07/14/22 00:05

07/14/22 00:05

07/14/22 00:05

1,7470A

1,6010D

1,6010D

1,6010D

1,6010D

1,6010D

1,6010D

1,6010D

AW

NB

NB

NB

NB

NB

NB

NB

06/23/22 15:47

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

07/07/22 09:13

TCLP Metals by EPA 1311 - Mansfield Lab for sample(s): 01-02 Batch: WG1654544-1

TCLP Metals by EPA 1311 - Mansfield Lab for sample(s): 01-02 Batch: WG1659702-1

EPA 7470A

EPA 3015

Digestion Method:

Digestion Method:

Prep Information

Prep Information

06/19/22 08:35

06/21/22 16:38

TCLP/SPLP Extraction Date:

TCLP/SPLP Extraction Date:

MDL

MDL

Page 30 of 43 APPENDIX C5

Mercury, TCLP

Arsenic, TCLP

Barium, TCLP

Cadmium, TCLP

Chromium, TCLP

Lead, TCLP

Selenium, TCLP

Silver, TCLP

80-120

75-125

75-125

75-125

75-125

75-125

75-125

75-125

Parameter

LCS

%Recovery

LCSD

%Recovery %Recovery

Limits RPD RPD Limits

TCLP Metals by EPA 1311 - Mansfield Lab Associated sample(s): 01-02 Batch: WG1654544-2

TCLP Metals by EPA 1311 - Mansfield Lab Associated sample(s): 01-02 Batch: WG1659702-2

Lab Control Sample Analysis Batch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

07/14/22

Qual Qual Qual

Serial_No:07142217:43

APPEN

D

Barium, TCLP

Cadmium, TCLP

Chromium, TCLP

Lead, TCLP

Selenium, TCLP

Silver, TCLP

ND

ND

ND

ND

ND

ND

ND

1.28

18.7

0.528

1.90

4.98

1.33

0.468

75-125

75-125

75-125

75-125

75-125

75-125

75-125

Parameter Native Sample

MS

Found

MS

%Recovery

MSD

Found

MSD

%Recovery

Recovery Limits RPD

RPD

Limits

TCLP Metals by EPA 1311 - Mansfield Lab Associated sample(s): 01-02 QC Batch ID: WG1659702-3 QC Sample: L2232418-01 Client ID: MB-212

1.2

0.53

5.3

1.2

0.5

MS

Added

Matrix Spike Analysis Batch Quality Control

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

07/14/22

Qual Qual Qual

Serial_No:07142217:43

APPEN

D

Barium, TCLP

Cadmium, TCLP

Chromium, TCLP

Lead, TCLP

Selenium, TCLP

Silver, TCLP

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

ND

mg/l mg/l mg/l mg/l mg/l mg/l mg/l

NC

NC

NC

NC

NC

NC

NC

Units RPDParameter Native Sample Duplicate Sample RPD Limits

TCLP Metals by EPA 1311 - Mansfield Lab Associated sample(s): 01-02 QC Batch ID: WG1659702-4 QC Sample: L2232418-01 Client ID: MB-212

NEW LONDON NAVY BASE

JD195305A

Project Name:

Project Number:

L2232418Lab Number:

Report Date:

Lab Duplicate Analysis Batch Quality Control

07/14/22

Qual

Serial_No:07142217:43

APPEN

D

INORGANICS

MISCELLANEOUS

Page 34 of 43 APPENDIX C5

MB-212Client ID:

06/16/22 10:00Date Collected:

06/17/22Date Received:

Parameter Result Dilution Factor

Matrix: Soil

GROTON, CTSample Location:

L2232418-01Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

Field Prep:

Date Analyzed

Analytical Method Analyst

Not Specified

General Chemistry - Westborough Lab Solids, Total 87.2 % 10.100 06/18/22 08:32 121,2540G RI

Date Prepared

07/14/22

MDL

NA

Sample Depth:

Page 35 of 43 APPENDIX C5

MB-216Client ID:

06/16/22 10:10Date Collected:

06/17/22Date Received:

Parameter Result Dilution Factor

Matrix: Soil

GROTON, CTSample Location:

L2232418-02Lab ID:

Qualifier Units RL

SAMPLE RESULTS

Project Name:

Project Number:

Lab Number:

Report Date:

NEW LONDON NAVY BASE

JD195305A

L2232418

Field Prep:

Date Analyzed

Analytical Method Analyst

Not Specified

General Chemistry - Westborough Lab Solids, Total 92.6 % 10.100 06/18/22 08:32 121,2540G RI

Date Prepared

07/14/22

MDL

NA

Sample Depth:

Page 36 of 43 APPENDIX C5

*Values in parentheses indicate holding time in days

L2232418-01A

L2232418-01B

L2232418-01C

L2232418-01D

L2232418-01E

L2232418-01F

L2232418-01X

L2232418-01X9

L2232418-02A

L2232418-02B

L2232418-02C

L2232418-02D

L2232418-02E

L2232418-02F

L2232418-02X

L2232418-02X9

Vial MeOH preserved

Vial MeOH preserved

Vial water preserved

Vial water preserved

Plastic 120ml unpreserved

Glass 250ml/8oz unpreserved

Plastic 120ml HNO3 preserved Extracts

Tumble Vessel

Vial MeOH preserved

Vial MeOH preserved

Vial water preserved

Vial water preserved

Plastic 120ml unpreserved

Glass 250ml/8oz unpreserved

Plastic 120ml HNO3 preserved Extracts

Tumble Vessel

A

A

A

A

A

A

A

A

A

A

A

A

A

A

A

A

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

3.2

3.2

3.2

3.2

3.2

3.2

3.2

3.2

3.2

3.2

3.2

3.2

3.2

3.2

3.2

3.2

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Y

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

Absent

A Absent Cooler Custody Seal Cooler Information

NEW LONDON NAVY BASE

JD195305A

TPH-GRO(14),CT-8260HLW(14)

TPH-GRO(14),CT-8260HLW(14)

CT-8260HLW(14)

CT-8260HLW(14)

TS(7)

CD-CI(180),AS-CI(180),BA-CI(180),HG-

C(28),PB-CI(180),CR-CI(180),SE-CI(180),AG-

CI(180)

TPH-GRO(14),CT-8260HLW(14)

TPH-GRO(14),CT-8260HLW(14)

CT-8260HLW(14)

CT-8260HLW(14)

TS(7)

CD-CI(180),AS-CI(180),BA-CI(180),HG-

C(28),PB-CI(180),SE-CI(180),CR-CI(180),AG-

CI(180)

Project Name:

Project Number:

L2232418Lab Number:

Report Date:

Sample Receipt and Container Information

Container ID Container Type Cooler Temp deg C Pres Seal

Container Information

Analysis(*)

07/14/22

Were project specific reporting limits specified? NO

18-JUN-22 01:50

18-JUN-22 01:50

18-JUN-22 01:50

18-JUN-22 01:50

Frozen Date/Time

Final pH

Initial pH

Serial_No:07142217:43

APPEN

D

Report Format: Data Usability Report

GLOSSARY

Project Name:

Project Number:

Lab Number:

Report Date:

L2232418NEW LONDON NAVY BASE

JD195305A 07/14/22

Acronyms

DL

EDL

EMPC

EPA

LCS

LCSD

LFB

LOD

LOQ

MDL

MS

MSD

NA

NC

NDPA/DPA

NI

NP

NR

RL

RPD

SRM

STLP

TEF

TEQ

TIC

Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when those target analyte concentrations are quantified below the limit of quantitation (LOQ). The DL includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.)

Estimated Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when those target analyte concentrations are quantified below the reporting limit (RL). The EDL includes any adjustments from dilutions, concentrations or moisture content, where applicable. The use of EDLs is specific to the analysis of PAHs using Solid-Phase Microextraction (SPME).

Estimated Maximum Possible Concentration: The concentration that results from the signal present at the retention time of an analyte when the ions meet all of the identification criteria except the ion abundance ratio criteria. An EMPC is a worst-case estimate of the concentration.

Environmental Protection Agency.

Laboratory Control Sample: A sample matrix, free from the analytes of interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of analytes.

Laboratory Control Sample Duplicate: Refer to LCS.

Laboratory Fortified Blank: A sample matrix, free from the analytes of interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of analytes.

Limit of Detection: This value represents the level to which a target analyte can reliably be detected for a specific analyte in a specific matrix by a specific method. The LOD includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.)

Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.)

Limit of Quantitation: The value at which an instrument can accurately measure an analyte at a specific concentration. The LOQ includes any adjustments from dilutions, concentrations or moisture content, where applicable. (DoD report formats only.)

Method Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when those target analyte concentrations are quantified below the reporting limit (RL). The MDL includes any adjustments from dilutions, concentrations or moisture content, where applicable.

Matrix Spike Sample: A sample prepared by adding a known mass of target analyte to a specified amount of matrix sample for which an independent estimate of target analyte concentration is available. For Method 332.0, the spike recovery is calculated using the native concentration, including estimated values.

Matrix Spike Sample Duplicate: Refer to MS.

Not Applicable.

Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the parameter's reporting unit.

N-Nitrosodiphenylamine/Diphenylamine.

Not Ignitable.

Non-Plastic: Term is utilized for the analysis of Atterberg Limits in soil.

No Results: Term is utilized when 'No Target Compounds Requested' is reported for the analysis of Volatile or Semivolatile Organic TIC only requests.

Reporting Limit: The value at which an instrument can accurately measure an analyte at a specific concentration. The RL includes any adjustments from dilutions, concentrations or moisture content, where applicable.

Relative Percent Difference: The results from matrix and/or matrix spike duplicates are primarily designed to assess the precision of analytical results in a given matrix and are expressed as relative percent difference (RPD). Values which are less than five times the reporting limit for any individual parameter are evaluated by utilizing the absolute difference between the values; although the RPD value will be provided in the report.

Standard Reference Material: A reference sample of a known or certified value that is of the same or similar matrix as the associated field samples.

Semi-dynamic Tank Leaching Procedure per EPA Method 1315.

Toxic Equivalency Factors: The values assigned to each dioxin and furan to evaluate their toxicity relative to 2,3,7,8-TCDD.

Toxic Equivalent: The measure of a sample's toxicity derived by multiplying each dioxin and furan by its corresponding TEF and then summing the resulting values.

Tentatively Identified Compound: A compound that has been identified to be present and is not part of the target compound list (TCL) for the method and/or program. All TICs are qualitatively identified and reported as estimated concentrations.

Page 38 of 43 APPENDIX C5

Project Number:

Lab Number:

Report Date:

L2232418NEW LONDON NAVY BASE

JD195305A 07/14/22

Terms

Analytical Method: Both the document from which the method originates and the analytical reference method. (Example: EPA 8260B is shown as 1,8260B.) The codes for the reference method documents are provided in the References section of the Addendum.

Chlordane: The target compound Chlordane (CAS No. 57-74-9) is reported for GC ECD analyses. Per EPA,this compound "refers to a mixture of chlordane isomers, other chlorinated hydrocarbons and numerous other components." (Reference: USEPA Toxicological Review of Chlordane, In Support of Summary Information on the Integrated Risk Information System (IRIS), December 1997.)

Difference: With respect to Total Oxidizable Precursor (TOP) Assay analysis, the difference is defined as the Post-Treatment value minus the Pre-Treatment value.

Final pH: As it pertains to Sample Receipt & Container Information section of the report, Final pH reflects pH of container determined after adjustment at the laboratory, if applicable. If no adjustment required, value reflects Initial pH.

Frozen Date/Time: With respect to Volatile Organics in soil, Frozen Date/Time reflects the date/time at which associated Reagent Water-preserved vials were initially frozen. Note: If frozen date/time is beyond 48 hours from sample collection, value will be reflected in 'bold'.

Gasoline Range Organics (GRO): Gasoline Range Organics (GRO) results include all chromatographic peaks eluting from Methyl tert butyl ether through Naphthalene, with the exception of GRO analysis in support of State of Ohio programs, which includes all chromatographic peaks eluting from Hexane through Dodecane.

Initial pH: As it pertains to Sample Receipt & Container Information section of the report, Initial pH reflects pH of container determined upon receipt, if applicable.

PAH Total: With respect to Alkylated PAH analyses, the 'PAHs, Total' result is defined as the summation of results for all or a subset of the following compounds: Naphthalene, C1-C4 Naphthalenes, 2-Methylnaphthalene, 1-Methylnaphthalene, Biphenyl, Acenaphthylene, Acenaphthene, Fluorene, C1-C3 Fluorenes, Phenanthrene, C1-C4 Phenanthrenes/Anthracenes, Anthracene, Fluoranthene, Pyrene, C1-C4 Fluoranthenes/Pyrenes, Benz(a)anthracene, Chrysene, C1-C4 Chrysenes, Benzo(b)fluoranthene, Benzo(j)+(k)fluoranthene, Benzo(e)pyrene, Benzo(a)pyrene, Perylene, Indeno(1,2,3-cd)pyrene, Dibenz(ah)+(ac)anthracene, Benzo(g,h,i)perylene. If a 'Total' result is requested, the results of its individual components will also be reported.

PFAS Total: With respect to PFAS analyses, the 'PFAS, Total (5)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA, PFNA and PFOS. In addition, the 'PFAS, Total (6)' result is defined as the summation of results for: PFHpA, PFHxS, PFOA, PFNA, PFDA and PFOS. For MassDEP DW compliance analysis only, the 'PFAS, Total (6)' result is defined as the summation of results at or above the RL. Note: If a 'Total' result is requested, the results of its individual components will also be reported.

Total: With respect to Organic analyses, a 'Total' result is defined as the summation of results for individual isomers or Aroclors. If a 'Total' result is requested, the results of its individual components will also be reported. This is applicable to 'Total' results for methods 8260, 8081 and 8082.

Data Qualifiers

A

B

C

D

E

F

G

H

I

J

M

Spectra identified as "Aldol Condensates" are byproducts of the extraction/concentration procedures when acetone is introduced in the process.

The analyte was detected above the reporting limit in the associated method blank. Flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For MCP-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For DOD-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank AND the analyte was detected above one-half the reporting limit (or above the reporting limit for common lab contaminants) in the associated method blank. For NJ- Air-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte above the reporting limit. For NJ-related projects (excluding Air), flag only applies to associated field samples that have detectable concentrations of the analyte, which was detected above the reporting limit in the associated method blank or above five times the reporting limit for common lab contaminants (Phthalates, Acetone, Methylene Chloride, 2-Butanone).

Co-elution: The target analyte co-elutes with a known lab standard (i.e. surrogate, internal standards, etc.) for co-extracted analyses.

Concentration of analyte was quantified from diluted analysis. Flag only applies to field samples that have detectable concentrations of the analyte.

Concentration of analyte exceeds the range of the calibration curve and/or linear range of the instrument.

The ratio of quantifier ion response to qualifier ion response falls outside of the laboratory criteria. Results are considered to be an estimated maximum concentration.

The concentration may be biased high due to matrix interferences (i.e, co-elution) with non-target compound(s). The result should be considered estimated.

The analysis of pH was performed beyond the regulatory-required holding time of 15 minutes from the time of sample collection.

The lower value for the two columns has been reported due to obvious interference.

Estimated value. This represents an estimated concentration for Tentatively Identified Compounds (TICs).

Reporting Limit (RL) exceeds the MCP CAM Reporting Limit for this analyte.

1 The reference for this analyte should be considered modified since this analyte is absent from the target analyte list of the original method.

Footnotes

Page 39 of 43 APPENDIX C5

Project Number:

Lab Number:

Report Date:

L2232418NEW LONDON NAVY BASE

JD195305A 07/14/22

Data Qualifiers

ND

NJ

P

Q

R

RE

S

V

Z

Not detected at the reporting limit (RL) for the sample.

Presumptive evidence of compound. This represents an estimated concentration for Tentatively Identified Compounds (TICs), where the identification is based on a mass spectral library search.

The RPD between the results for the two columns exceeds the method-specified criteria.

The quality control sample exceeds the associated acceptance criteria. For DOD-related projects, LCS and/or Continuing Calibration Standard exceedences are also qualified on all associated sample results. Note: This flag is not applicable for matrix spike recoveries when the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the sample concentrations are less than 5x the RL. (Metals only.)

Analytical results are from sample re-analysis.

Analytical results are from sample re-extraction.

Analytical results are from modified screening analysis.

The surrogate associated with this target analyte has a recovery outside the QC acceptance limits. (Applicable to MassDEP DW Compliance samples only.)

The batch matrix spike and/or duplicate associated with this target analyte has a recovery/RPD outside the QC acceptance limits.

(Applicable to MassDEP DW Compliance samples only.)

Page 40 of 43 APPENDIX C5

Alpha Analytical performs services with reasonable care and diligence normal to the analytical testing laboratory industry. In the event of an error, the sole and exclusive responsibility of Alpha Analytical shall be to re-perform the work at it's own expense. In no event shall Alpha Analytical be held liable for any incidental, consequential or special damages, including but not limited to, damages in any way connected with the use of, interpretation of, information or analysis provided by Alpha Analytical.

We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling, containers, sampling procedures, holding time and splitting of samples in the field.

LIMITATION OF LIABILITIES

Test Methods for Evaluating Solid Waste: Physical/Chemical Methods. EPA SW-846.

Third Edition. Updates I - VI, 2018.

Connecticut DEP Quality Assurance and Quality Control Requirements for SW-846 Methods. CTDEP Reasonable Confidence Protocols (RCPs). Versions 2.0 and 3.0, July and December 2006.

Standard Methods for the Examination of Water and Wastewater. APHA-AWWA-WEF.

Standard Methods Online.

Project Name:

Project Number:

Lab Number:

Report Date:

L2232418NEW LONDON NAVY BASE

JD195305A

REFERENCES

07/14/22

Page 41 of 43 APPENDIX C5

Alpha Analytical, Inc. ID No.:17873 Facility: Company-wide Revision 19 Department: Quality Assurance Published Date: 4/2/2021 1:14:23 PM Title: Certificate/Approval Program Summary Page 1 of 1

Document Type: Form Pre-Qualtrax Document ID: 08-113

Certification Information

The following analytes are not included in our Primary NELAP Scope of Accreditation:

Westborough Facility EPA 624/624.1: m/p-xylene, o-xylene, Naphthalene EPA 625/625.1: alpha-Terpineol EPA 8260C/8260D: NPW: 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene, Azobenzene; SCM: Iodomethane (methyl iodide), 1,2,4,5-Tetramethylbenzene;

4-Ethyltoluene.

EPA 8270D/8270E: NPW: Dimethylnaphthalene,1,4-Diphenylhydrazine, alpha-Terpineol; SCM: Dimethylnaphthalene,1,4-Diphenylhydrazine.

SM4500: NPW: Amenable Cyanide; SCM: Total Phosphorus, TKN, NO2, NO3.

Mansfield Facility

SM 2540D: TSS

EPA 8082A: NPW: PCB: 1, 5, 31, 87,101, 110, 141, 151, 153, 180, 183, 187.

EPA TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene, 3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 1-Methylnaphthalene.

Biological Tissue Matrix: EPA 3050B

The following analytes are included in our Massachusetts DEP Scope of Accreditation

Westborough Facility:

Drinking Water EPA 300.0: Chloride, Nitrate-N, Fluoride, Sulfate; EPA 353.2: Nitrate-N, Nitrite-N; SM4500NO3-F: Nitrate-N, Nitrite-N; SM4500F-C, SM4500CN-CE, EPA 180.1, SM2130B, SM4500Cl-D, SM2320B, SM2540C, SM4500H-B, SM4500NO2-B EPA 332: Perchlorate; EPA 524.2: THMs and VOCs; EPA 504.1: EDB, DBCP.

Microbiology: SM9215B; SM9223-P/A, SM9223B-Colilert-QT,SM9222D.

Non-Potable Water SM4500H,B, EPA 120.1, SM2510B, SM2540C, SM2320B, SM4500CL-E, SM4500F-BC, SM4500NH3-BH: Ammonia-N and Kjeldahl-N, EPA 350.1:

Ammonia-N, LACHAT 10-107-06-1-B: Ammonia-N, EPA 351.1, SM4500NO3-F, EPA 353.2: Nitrate-N, SM4500P-E, SM4500P-B, E, SM4500SO4-E, SM5220D, EPA 410.4, SM5210B, SM5310C, SM4500CL-D, EPA 1664, EPA 420.1, SM4500-CN-CE, SM2540D, EPA 300: Chloride, Sulfate, Nitrate.

EPA 624.1: Volatile Halocarbons & Aromatics, EPA 608.3: Chlordane, Toxaphene, Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD, DDE, DDT, Endosulfan I, Endosulfan II, Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs EPA 625.1: SVOC (Acid/Base/Neutral Extractables), EPA 600/4-81-045: PCB-Oil.

Microbiology: SM9223B-Colilert-QT; Enterolert-QT, SM9221E, EPA 1600, EPA 1603, SM9222D.

Mansfield Facility:

Drinking Water EPA 200.7: Al, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Na, Ag, Ca, Zn. EPA 200.8: Al, Sb, As, Ba, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg.

EPA 522, EPA 537.1.

Non-Potable Water EPA 200.7: Al, Sb, As, Be, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Ag, Na, Sr, TL, Ti, V, Zn.

EPA 200.8: Al, Sb, As, Be, Cd, Cr, Cu, Fe, Pb, Mn, Ni, K, Se, Ag, Na, TL, Zn.

EPA 245.1 Hg.

SM2340B

For a complete listing of analytes and methods, please contact your Alpha Project Manager.

Page 42 of 43 APPENDIX C5