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MSDS No: CEM090E8 Issue Date: 25 July 2008 Page: 1 of 5

MATERIAL SAFETY DATA SHEET

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Trade Name: OATEY PVC HEAVY DUTY GRAY CEMENT Product No: 31093, 31094, 31095, 31105, 31118, 31510, 31511, 31512, 31513, 31514, 31554, 31555, 31556, 31978, 31979, 31980, 31981, 32050, 32051, 32052, 32210, 32211

Product Use: Cement for PVC Plastic Pipe Formula: PVC Resin in Solvent Solution Synonyms: PVC Plastic Pipe Cement Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland, Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com Oatey Phone Number: (216) 267-7100 or (800) 321-9532 Emergency Phone For Emergency First Aid call 1-303-623-5716 COLLECT. For Numbers: chemical transportation emergencies ONLY, call Chemtrec at 1-800-424-9300. Outside the U.S. 1-703-527-3887.

Prepared By: Corporate Director – Safety and Environmental Compliance Preparation Date: July 25, 2008

SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENTS: %wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER:

Tetrahydrofuran 40 - 60% 109-99-9 50 ppm(skin) 200 ppm 25 ppm (Mfg) 100 ppm STEL Methyl Ethyl Ketone 0 – 28% 78-93-3 200 ppm 200 ppm None 300 ppm Acetone 0 - 20% 67-64-1 500 ppm 1000 ppm None 750 ppm STEL PVC Resin 12 - 20% 9002-86-2 10 mg/m3 15 mg/m3 None (Non-hazardous) Cyclohexanone 10 - 20% 108-94-1 20 ppm(skin) 50 ppm None 50 ppm STEL Amorphous Fumed Silica 1 - 4% 112945-52-5 10 mg/m3 None None (Non-hazardous) Established

OSHA Hazard Classification: Flammable, irritant, organ effects

SECTION 3 HAZARDS IDENTIFICATION

Emergency Overview:

Gray liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors may cause flash fire. May cause eye and skin irritation. Inhalation of vapors or mist may cause respiratory irritation and central nervous system effects. Swallowing may cause irritation, nausea, vomiting, diarrhea and kidney or liver disorders.

Aspiration hazard. May be fatal if swallowed. Symptoms may be delayed.

SECTION 4 FIRST AID MEASURES

CALL 1-303-623-5716 COLLECT

Skin: Remove contaminated clothing immediately. Wash all exposed areas with soap and water. Get medical attention if irritation develops. Remove dried cement with Oatey Plumber's Hand Cleaner or baby oil.

Eyes: If material gets into eyes or if fumes cause irritation, immediately flush eyes with plenty of water until chemical is removed. If irritation persists, get medical attention immediately.

Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing becomes difficult, administer oxygen. Administer artificial respiration if breathing has stopped. Seek immediate medical attention.

Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to a person who is unconscious or drowsy. Get immediate medical attention by calling a Poison Control Center, or hospital emergency room. If medical advice cannot be obtained, then take the person and product to the nearest medical emergency treatment center or hospital.

Page: 2 of 5

SECTION 5 FIRE FIGHTING MEASURES

Flashpoint / Method: 0 - 5 Degrees F. (-18 to -15 Degrees C) / PMCC Flammability: LEL = 1.8 % Volume, UEL = 11.8 % Volume Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire Media: exposed container with water. Water may be ineffective as an extinguishing agent.

Special Fire Firefighters should wear positive pressure self-contained Fighting breathing apparatus and full protective clothing for fires in Procedure: areas where chemicals are used or stored Unusual Fire and Extremely flammable liquid. Keep away from heat and all Explosion sources of ignition including sparks, flames, lighted Hazards: cigarettes and pilot lights. Containers may rupture or explode in the heat of a fire. Vapors are heavier than air and may travel to a remote ignition source and flash back.

This product contains tetrahydrofuran that may form explosive organic peroxide when exposed to air or light or with age.

Hazardous Combustion will produce toxic and irritating vapors including Decomposition carbon monoxide, carbon dioxide and hydrogen chloride.

Products:

SECTION 6 ACCIDENTAL RELEASE MEASURES

Spill or Remove all sources of ignition and ventilate area. Stop leak if it Leak can be done without risk. Personnel cleaning up the spill should Procedures: wear appropriate personal protective equipment, including respirators if vapor concentrations are high. Soak up spill with an inert absorbent such as sand, earth or other non-combusting material. Put absorbent material in covered, labeled metal containers. Prevent liquid from entering watercourses, sewers and natural waterways.

Report releases to authorities as required. See Section 13 for disposal information.

SECTION 7 HANDLING AND STORAGE

Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists. Use with adequate ventilation (equivalent to outdoors).

Wash thoroughly after handling. Do not eat, drink or smoke in the work area. Keep product away from heat, sparks, flames and all other sources of ignition. No smoking in storage or use areas. Keep containers closed when not in use.

Storage: Store in a cool, dry, well-ventilated area away from incompatible materials. Keep containers closed when not in use.

Other: "Empty" containers retain product residue and can be hazardous.

Follow all MSDS precautions in handling empty containers. Do not cut or weld on or near empty or full containers.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Ventilation: Open doors & windows. Provide ventilation capable of maintaining emissions at the point of use below recommended exposure limits. If used in enclosed area, use exhaust fans. Exhaust fans should be explosion-proof or set up in a way that flammable concentrations of solvent vapors are not exposed to electrical fixtures or hot surfaces.

Respiratory For operations where the exposure limit may be exceeded, a NIOSH Protection: approved organic vapor respirator or supplied air respirator is recommended. Equipment selection depends on contaminant type and concentration, select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus.

Skin Rubber gloves are suitable for normal use of the product. For long Protection: exposures chemical resistant gloves may be required such as 4H(tm) or Silver Shield(tm) to avoid prolonged skin contact.

SECTION 8 (Continued) Eye Safety glasses with side shields or safety goggles.

Protection:

Page: 3 of 5 Other: Eye wash and safety shower should be available.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point: 151 Degrees F / 66 Degrees C Melting Point: Not applicable Vapor Pressure: 145 mmHg @ 20 Degrees C Vapor Density: (Air = 1) 2.5 Volatile Components: 86-90% Solubility In Water: Negligible pH: Not applicable Specific Gravity: 0.91 +/- 0.02 @ 20 Degrees C Evaporation Rate: (BUAC = 1) = 5.5 - 8.0 Appearance: Gray Liquid Odor: Sharp-penetrating odor Will Dissolve In: Tetrahydrofuran Material Is: Liquid

SECTION 10 STABILITY AND REACTIVITY

Stability: Stable.

Conditions To Avoid: Avoid heat, sparks, flames and other sources of ignition.

Hazardous Combustion will produce toxic and irritating vapors Decomposition including carbon monoxide, carbon dioxide and hydrogen Products: chloride.

Incompatibility/ Oxidizing agents, alkalis, amines, ammonia, acids, chlorine Materials To Avoid: compounds, chlorinated inorganics (potassium, calcium and sodium hypochlorite) and hydrogen peroxides. May attack plastic, resins and rubber.

Hazardous Will not occur.

Polymerization:

SECTION 11 TOXICOLOGICAL INFORMATION

Inhalation: Vapors or mists may cause mucous membrane and respiratory irritation, coughing, headache, dizziness, dullness, nausea, shortness of breath and vomiting. High concentrations may cause central nervous system depression, narcosis and unconsciousness.

May cause kidney, liver and lung damage.

Skin: May cause irritation with redness, itching and pain. Methyl ethyl ketone and cyclohexanone may be absorbed through the skin causing effects similar to those listed under inhalation.

Eye: Vapors may cause irritation. Direct contact may cause irritation with redness, stinging and tearing of the eyes. May cause eye damage.

Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and diarrhea.

Aspiration during swallowing or vomiting can cause chemical pneumonia and lung damage. May cause kidney and liver damage.

Chronic Prolonged or repeated overexposure cause dermatitis and damage Toxicity: to the kidney, liver, lungs and central nervous system.

Toxicity Data: Acetone: Oral rat LD50: 5,800 mg/kg

Inhalation rat LC50: 50,100 mg/m3/8 hours Cyclohexanone: Oral rat LD50: 1,620 mg/kg

Inhalation rat LC50: 8,000 ppm/4 hours Skin rabbit LD50: 1 mL/kg Tetrahydrofuran: Oral rat LD50: 1,650 mg/kg Inhalation rat LC50: 21,000 ppm/3 hours Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg Inhalation rat LC50: 23,500 mg/m3/8 hours Skin rabbit LD50: 6,480 mg/kg Sensitization: None of the components are known to cause sensitization.

Page: 4 of 5 SECTION 11 (Continued) Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by NTP, IARC or OSHA. The National Toxicology Program has reported that exposure of mice and rats to tetrahydrofuran (THF) vapor levels up to 1800 ppm 6 hr/day, 5 days/week for their lifetime caused an increased incidence of kidney tumors in male rats and liver tumors in female mice. The significance of these findings for human health is unclear at this time, and may be related to "species specific" effects. Elevated incidences of tumors in humans have not been reported for THF. ACGIH has classified cyclohexanone (CYH) and tetrahydrofuran as “A3,” Confirmed Animal Carcinogens with Unknown Relevance to Humans.

Mutagenicity: Cyclohexanone has been positive in bacterial and mammalian assays. Acetone, methyl ethyl ketone and tetrahydrofuran are generally thought not to be mutagenic.

Reproductive Cyclohexanone has been shown to cause embryofetal toxicity and Toxicity: birth defects in laboratory animals. Acetone and tetrahydrofuran have been found to cause adverse developmental effects only when exposure levels cause other toxic effects to the mother.

Medical Persons with pre-existing skin, lung, kidney or liver disorders Conditions may be at increased risk from exposure to this product.

Aggravated By Exposure:

SECTION 12 ECOLOGICAL INFORMATION

This product is not expected to be toxic to aquatic organisms.

Cyclohexanone: 96 hour LC50 values for fish is over 100 mg/l.

Tetrahydrofuran: 96 hour LC50 fathead minnow: 2160 mg/L.

Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L.

Acetone: 96 hour LC50 for fish is greater than 100 mg/L.

VOC This product emits VOC's (volatile organic compounds) in its use.

Information: Make sure that use of this product complies with local VOC emission regulations, where they exist.

VOC Level: 650 g/l per SCAQMD Test Method 316A.

SECTION 13 DISPOSAL CONSIDERATIONS

Waste Disposal: Dispose in accordance with current local, state and federal regulations.

RCRA Hazardous Waste Number: U057, U159, U213 EPA Hazardous Waste ID Number: D001, D035, F005 EPA Hazard Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)

SECTION 14 TRANSPORT INFORMATION

DOT Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal) UN/NA Number: None UN1133 Proper Shipping Name: Consumer Commodity Adhesives Hazard Class: ORM-D 3 Packing Group: None PGII Hazard Labels: None Flammable Liquid

IMDG

UN Number: UN1133 UN1133 Proper Shipping Name: Adhesives Adhesives Hazard Class: 3 3 Packing Group: II II Label: None (Limited Quantities Class 3 (Flammable are excepted Liquid) from labeling) Flashpoint (deg C) -18 to -15 Degrees C -18 to -15 Degrees C

2004 North American Emergency Response Guidebook Number: 127 or 128

Page: 5 of 5

SECTION 15 REGULATORY INFORMATION

Hazard Category for Section Acute Health, Chronic Health, Flammable 311/312:

Section 302 Extremely This product does not contain chemicals regulated Hazardous Substances (TPQ): under SARA Section 302.

Section 313 Toxic Chemicals: This product does not contain chemicals subject to SARA Title III Section 313 Reporting requirements.

CERCLA 103 Reportable Spills of this product over the RQ (reportable Quantity: quantity) must be reported to the National Response Center. The RQ for the product, based on the RQ for Tetrahydrofuran (60% maximum) of 1,000 lbs, is 1,667 lbs. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations.

California Proposition 65: This product contains trace amounts of chemicals known to the State of to cause cancer. Under normal Use conditions, exposure to these chemicals at levels above the State of California “No Significant Risk Level” (NSRL) are unlikely. Oatey strongly encourages the use of proper personal protective equipment (PPE) and ventilation guidelines noted in Section 8 to minimize exposure to these chemicals.

TSCA Inventory: All of the components of this product are listed on the TSCA inventory.

Canadian WHIMS Classification: Class B, Division 2; Class D, Division 2, Subdivision B; Class D, Division 2, Subdivision A.

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

SECTION 16 OTHER INFORMATION

NFPA and HMIS:

NFPA Hazard Signal: Health: 2 Flammability: 3 Reactivity: 1 Special: None HMIS Hazard Signal: Health: 2* Flammability: 3 Reactivity: 1 PPE: G

DISCLAIMER:

The information herein has been compiled from sources believed to be reliable, up-to-date, and is accurate to the best of our knowledge. However, Oatey cannot give any guarantees regarding information from other sources, and expressly does not make warranties, nor assumes any liability for its use.

MSDS 0011

Section 1 -- PRODUCT AND COMPANY IDENTIFICATION

HMIS CODES

PRODUCT NAME Health

RectorSeal No. 5 Flammability

Reactivity

PRODUCT CODES PPI

B

25112, 25191, 25271, 25300, 25431, 25551, 25552, 25631, 25633, 25780, 25790, 25793

CHEMICAL FAMILY

Organic

USE

Pipe Thread Sealant

MANUFACTURER'S NAME EMERGENCY TELEPHONE NO.

The RectorSeal Corporation Chemtrec 24 Hours

2601 Spenwick Drive (800)424-9300 USA

Houston, Texas 77055 USA (703)527-3887

International

DATE OF VALIDATION TECHNICAL SERVICE

TELEPHONE NO.

January 9, 2013 (800)231-3345 or

(713)263-8001

DATE OF PREPARATION

January 9, 2013

Section 2 -- HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW

OSHA Hazards

Combustable

TARGET ORGANS

Not Classified

GHS CLASSIFICATION

PHYSICAL HAZARDS

Combustable liquid (Category 4)

HEALTH HAZARDS

Acute Toxicity:

Oral: Not Classified

Dermal: Not Classified

Inhalation: Not Classified

Skin Corrosion/Irritation: Not Classified

Serious Eye Damage/Eye Irritation: Not Classified

Skin Sensitization: Not Classified

Respiratory Sensitization: Not Classified

Germ Cell Mutagenicity: Not Classified

Carcinogenicity: See Section 11

Reproductive Toxicology: Not Classified

Target Organ Systemic Toxicity - Single Exposure: Not Classified

Target Organ Systemic Toxicity - Repeated Exposure: Not Classified

Aspiration Toxicity: Not Classified

GHS Label elements, including precautionary statements

Pictogram: Harmful / Irritant

Signal Word: Warning

Hazard Statements

H303 - May be harmful if swallowed.

H313 - May be harmful in contact with skin.

H335 + H336 - May cause respiratory irritation, and drowsiness or dizziness.

Precautionary Statements

P102 - Keep out of reach of children.

P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P240 - Ground/Bond container and receiving equipment

P261 - Avoid breathing dust/fume/gas/mist/vapors/spray

P262 - Do not get in eyes, on skin, or on clothing.

P264 - Wash hands thoroughly after handling.

P280 - Wear protective gloves/protective clothing/eye protection/face protection.

P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

P362 - Take off contaminated clothing and wash before reuse.

EUH066 - Repeated exposure may cause skin dryness or cracking

Precautionary Statements - EU No. 1272/2008

SUMMARY OF ACUTE HAZARDS

Irritation to eyes, nose and throat; drowsiness, narcosis, tremors and other CNS effects at high concentration.

ROUTE OF EXPOSURE, SIGNS AND SYMPTOMS

INHALATION

Nasal and respiratory irritation, dizziness, narcosis, headache, nausea, CNS depression and unconsciousness.

EYE CONTACT

Watering, blurred vision, inflammation and irritation which can result in corneal injury.

SKIN CONTACT

Irritation, dermatitis.

INGESTION

Nausea, vomiting; CNS depression; irritation of gastrointestinal tract, liver and peritoneal wall; lung congestion.

SUMMARY OF CHRONIC HAZARDS

Skin irritation and dermatitis. Possible liver and kidney damage.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

Individuals with pre-existing or chronic diseases of the eyes, skin, respiratory system, cardiovascular system, gastrointestinal system, liver or kidneys may have increased susceptibility to excessive exposures.

Section 3 -- COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENT: Diacetone Alcohol

PERCENTAGE BY WEIGHT: 20-30

CAS NUMBER: 123-42-2

EC# : 204-626-7

Section 4 -- FIRST AID MEASURES

If INHALED: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial respiration as needed. Obtain emergency medical attention. Prompt action is essential.

If on SKIN: Wash with soap and water. If irritation occurs, seek medical attention.

If in EYES: Flush eyes with large amounts of water for 15 minutes.

Get medical attention.

If SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person.

Section 5 -- FIRE FIGHTING MEASURES

EXTINGUSING MEDIA

Foam, dry chemical, carbon dioxide or water fog.

SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained breathing apparatus

(SCBA) and other protective clothing. Hazardous decomposition products possible (see Section 10).

UNUSUAL FIRE AND EXPLOSION HAZARDS: Combustible - moderate flash point.

Vapors heavier than air and may travel along the ground or to low spots at considerable distances to a source of ignition resulting in potential flashback. Burning liquid may float on water. Heat may build up pressure and rupture containers.

Section 6 -- ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition. Use absorbent materials to prevent footing hazard and to contain. Ventilate area with natural or explosion-proof, forced air ventilation. Avoid flushing into sewers, drains, waterways, and soil.

Wear protective clothing and respiratory protection during cleanup.

Section 7 -- HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep container closed upright when not in use. Do not store near heat, sparks, or open flames.

OTHER PRECAUTIONS: Avoid prolonged or repeated contact with skin or clothing. Empty containers may contain residues; treat as if full observe all products precautions. Do not reuse empty containers.

KEEP OUT OF REACH OF CHILDREN.

Section 8 -- EXPOSURE CONTROLS/PERSONAL PROTECTION

INGREDIENT UNITS

Diacetone Alcohol

ACGIH TLV 50 ppm

OSHA PEL 50 ppm

RESPIRATORY PROTECTION (SPECIFY TYPE): In confined poorly ventilated areas, use NIOSH/MSHA approved air purifying or supplied air purifying or supplied air respirators.

VENTILATION - LOCAL EXHAUST: Acceptable

SPECIAL: Explosion-proof equipment.

MECHANICAL (GENERAL): Preferable

OTHER: N/A

PROTECTIVE GLOVES: Wear rubber gloves.

EYE PROTECTION: Chemical splash goggles (ANSI Z-87.1 or equivalent)

OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls recommended.

WORK/HYGIENIC PRACTICES: Where use can result in skin contact, wash exposed areas thoroughly before eating, drinking, smoking, or leaving work area.

Launder contaminated clothing before reuse.

Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES

BOILING POINT: 322 F (161 C) @ 760mm Hg

SPECIFIC GRAVITY (H20 = 1): 1.38

VAPOR PRESSURE (mm Hg): 0.3 @ 68 F (20 C)

MELTING POINT: N/A

VAPOR DENSITY (AIR = 1): 1.1

EVAPORATION RATE (ETHYL ACETATE = 1): 0.14

APPEARANCE/ODOR: Yellow Paste/Mild Odor

SOLUBILITY IN WATER: 23%

VOLATILE ORGANIC COMPOUNDS(VOC)Content

(Theoretical Percentage By Weight): 23% or (317 g/L)

Flash POINT 150 F (65 C) SETA CC

LOWER EXPLOSION LIMIT N/D

UPPER EXPLOSION LIMIT N/D

Section 10 -- STABILITY AND REACTIVITY

STABILITY: Stable

CONDITIONS TO AVOID: Heat, sparks, open flames, and strong oxidizing.

Temperatures above 500 F (260 C).

INCOMPATIBILITY (MATERIALS TO AVOID): Gaseous oxygen, strong oxidizing materials, molten alkali metals.

HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2 and fragmented hydrocarbons.

HAZARDOUS POLYMERIZATION: Will not occur.

Section 11 -- TOXICOLOGY INFORMATION

CHRONIC HEALTH HAZARDS

No ingredients in this product is an IARC, NTP or OSHA Lister carcinogen.

TOXICOLOGY DATA

Ingredient Name

Oral-Rat LD50:4000 mg/kg

Inhalation-Human TCLo: 100 ppm

Section 12 -- Ecological Information

ECOLOGICAL DATA

Food Chain Concentration Potential N/A

WATERFOWL TOXICITY N/A

BOD N/A

AQUATIC TOXICITY N/A

Section 13 -- DISPOSAL CONSIDERATIONS

Waste Classification: Non-regulated solid waste

Disposal Method: Approved landfill

Waste from this product is not considered hazardous as defined under the

Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Dispose of in accordance with Federal, State, and Local regulation regarding pollution.

Section 14 -- TRANSPORTATION INFORMATION

DOT: Non-Regulated

OCEAN (IMDG): Non-Regulated

AIR (IATA): Non-Regulated

WHMIS (CANADA): Non-Regulated

Section 15 -- REGULATORY INFORMATION

REGULATORY DATA

SARA 313 N/A

TSCA Inventory Yes

CERCLA RQ N/A

RCRA Code N/A

Section 16 -- OTHER INFORMATION

This document is prepared pursuant to the OSHA Hazard Communication

Standard (29 CFR 1910.1200). The information herein is given in good faith, but no warranty, expressed or implied is made. Consult RectorSeal for further information: (713) 263-8001

MSDS: Lafarge Ready Mix Concrete

Page 1 of 6 Revised: 03/01/11

Material Safety Data Sheet

Section 1: PRODUCT AND COMPANY INFORMATION

Product Name(s): Lafarge Ready Mix Concrete (Concrete)

Product Identifiers: Ready Mix Concrete, Concrete Ready Mix, Portland Cement Concrete, Ready Mix Stucco, Ready Mix Grout, Ready Mix, Concrete, Freshly Mixed Concrete, Colloidal Concrete, Permeable Concrete, Shotcrete, Gunite, Polymer-Portland Cement Concrete, Colored Concrete, Flowable Fill, Roller-Compacted Concrete, Fiber Reinforced Concrete, Weathermix, UltraCurbTM, UltraDriveTM, UltraFlo-FilTM, UltraHorizontalTM, UltraFootingTM, UltraPatioTM, UltraStampTM, UltraTiltTM, UltraVerticalTM, AgrifargeTM Plus, AgrifargeTM RP, AgrifargeTM 20, 25, 30, 32, ArteviaColorTM, ChronoliaTM, ExtensiaTM, Agilia® Screed C.

Manufacturer: Information Telephone Number:

Lafarge North America Inc. 703-480-3600 (9am to 5pm EST) 12018 Sunrise Valley Drive, Suite 500 Emergency Telephone Number:

Reston, VA 20191 1-800-451-8346 (3E Hotline)

Product Use: Concrete is widely used as a structural component in construction applications.

Note: This MSDS covers many types of Concrete. Individual composition of hazardous constituents will vary between types of Concrete.

Section 2: COMPOSITION/INFORMATION ON INGREDIENTS

Component Percent (By Weight) CAS Number OSHA PEL -TWA

(mg/m3)

ACGIH TLV-

TWA (mg/m3) LD50 (mouse) LC50

Crystalline Silica 0-90 14808-60-7 [(10) / (%SiO2+2)] (R);

[(30) / (%SiO2+2)] (T) 0.025 (R) NA NA

Calcium Carbonate* 25-65 1317-65-3 15 (T); 5 (R) 3 (R); 10 (T) NA NA Portland Cement* 10-30 65997-15-1 15 (T); 5 (R) 1 (R) NA NA Calcium Hydroxide 15-25 1305-62-0 15 (T); 5 (R) 5 (T) 7300 mg/kg (oral) NA Fly Ash 0-20 68131-74-8 NA NA NA NA

Calcium Oxide 0-5 1305-78-8 5 (T) 2 (T) 3059 mg/kg (intraperitoneal) NA

Magnesium Oxide 0-4 1309-48-4 15 (T) 10 (I) NA NA Calcium Sulfate* 0-2 13397-24-5 15 (T); 5 (R) 10 (I) NA NA Particulate Not Otherwise Regulated - NA 15 (T); 5 (R) 10 (T); 3 (R) NA NA

Note: Exposure limits for components noted with an * contain no asbestos and <1% crystalline silica

Concrete contains cement which is manufactured from materials mined from the earth and is processed using energy provided by fuels. Trace amounts of chemicals may be detected during chemical analysis such as:

potassium and sodium sulfate compounds, chromium compounds, nickel compounds, and other trace compounds.

Section 3: HAZARD IDENTIFICATION

WARNING

Corrosive - Causes severe burns.

Toxic - Harmful by inhalation.

(Contains crystalline silica)

Use proper engineering controls, work practices, and personal protective equipment to prevent exposure to wet or dry product.

Read MSDS for details.

Respiratory Protection

Eye Protection

Waterproof Waterproof Boots Gloves

Page 2 of 6 Revised: 03/01/11

Section 3: HAZARD IDENTIFICATION (continued)

Emergency Overview: Unhardened concrete is an odorless semi-fluid, flowable, granular paste of varying color and texture. It is not combustible or explosive. Exposure of sufficient duration to wet concrete can cause serious, potentially irreversible tissue (skin, eye, respiratory tract) damage due to chemical (caustic) burns, including third degree burns.

Potential Health Effects:

Eye Contact (acute): Concrete may cause immediate or delayed irritation or inflammation. Eye contact with wet concrete can cause moderate eye irritation, chemical burns and blindness. Eye exposures require immediate first aid and medical attention to prevent significant damage to the eye.

Skin Contact (acute): Concrete may cause dry skin, discomfort, irritation, severe burns, and dermatitis.

Burns: Exposure of sufficient duration to wet concrete can cause serious, potentially irreversible damage to skin, eye, respiratory and digestive tracts due to chemical (caustic) burns, including third degree burns. A skin exposure may be hazardous even if there is no pain or discomfort.

Dermatitis: Unhardened concrete is capable of causing dermatitis by irritation and allergy. Skin affected by dermatitis may include symptoms such as, redness, itching, rash, scaling, and cracking.

Irritant dermatitis is caused by the physical properties of concrete including alkalinity and abrasion.

Sensitization: Allergic contact dermatitis is caused by sensitization to hexavalent chromium (chromate) present in concrete. The reaction can range from a mild rash to severe skin ulcers. Persons already sensitized may react to the first contact with wet concrete. Others may develop allergic dermatitis after years of repeated contact with wet concrete.

Inhalation (acute): Breathing dust may cause nose, throat lung or mucous membrane irritation, including choking, depending on the degree of exposure. Inhalation of high levels of dust can cause chemical burns to the nose, throat and lungs.

Inhalation (chronic): Risk of injury depends on duration and level of exposure.

Silicosis: This product contains crystalline silica. Prolonged or repeated inhalation of respirable crystalline silica from this product can cause silicosis, a seriously disabling and fatal lung disease. See Note to Physicians in Section 4 for further information.

Carcinogenicity: Concrete is not listed as a carcinogen by IARC or NTP; however, concrete contains trace amounts of crystalline silica and hexavalent chromium which are classified by IARC and NTP as known human carcinogens.

Autoimmune Some studies show that exposure to respirable crystalline silica (without silicosis) or Disease: that the disease silicosis may be associated with the increased incidence of several autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid arthritis and diseases affecting the kidneys.

Tuberculosis: Silicosis increases the risk of tuberculosis.

Renal Disease: Some studies show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica.

Page 3 of 6 Revised: 03/01/11

Section 3: HAZARD IDENTIFICATION (continued)

Ingestion: Do not ingest concrete. Although ingestion of small quantities of concrete is not known to be harmful, large quantities can cause chemical burns in the mouth, throat, stomach, and digestive tract.

Medical Conditions Individuals with lung disease (e.g. bronchitis, emphysema, COPD, pulmonary Aggravated by Exposure: disease) or sensitivity to hexavalent chromium can be aggravated by exposure.

Section 4: FIRST AID MEASURES

Eye Contact: Rinse eyes thoroughly with water for at least 15 minutes, including under lids, to remove all particles. Seek medical attention for abrasions and burns.

Skin Contact: Wash with cool water and a pH neutral soap or a mild skin detergent. Seek medical attention for rash, burns, irritation, dermatitis, and prolonged unprotected exposures to wet concrete.

Inhalation: Move person to fresh air. Seek medical attention for discomfort or if coughing or other symptoms do not subside.

Ingestion: Do not induce vomiting. If conscious, have person drink plenty of water. Seek medical attention or contact poison control center immediately.

Note to Physician: The three types of silicosis include:

• Simple chronic silicosis – which results from long-term exposure (more than 20 years) to low amounts of respirable crystalline silica. Nodules of chronic inflammation and scarring provoked by the respirable crystalline silica form in the lungs and chest lymph nodes. This disease may feature breathlessness and may resemble chronic obstructive pulmonary disease (COPD).

• Accelerated silicosis – occurs after exposure to larger amounts of respirable crystalline silica over a shorter period of time (5-15 years). Inflammation, scarring, and symptoms progress faster in accelerated silicosis than in simple silicosis.

• Acute silicosis – results from short-term exposure to very large amounts of respirable crystalline silica. The lungs become very inflamed and may fill with fluid, causing severe shortness of breath and low blood oxygen levels.

Progressive massive fibrosis may occur in simple or accelerated silicosis, but is more common in the accelerated form. Progressive massive fibrosis results from severe scarring and leads to the destruction of normal lung structures.

Section 5: FIREFIGHTING MEASURES

Flashpoint & Method: Non-combustible

General Hazard:

Avoid breathing dust.

Wet concrete is caustic.

Firefighting Equipment: Concrete poses no fire-related hazard. A SCBA is recommended to limit exposures to combustion products when fighting any fire. Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Combustion Products: None.

Page 4 of 6 Revised: 03/01/11

Section 6: ACCIDENTAL RELEASE MEASURES

General: Place spilled material into a container. Avoid contact with skin. Wear appropriate protective equipment as described in Section 8. Scrape wet concrete and place in container. Allow material to dry or solidify before disposal. Do not wash concrete down sewage and drainage systems or into bodies of water (e.g. streams).

Waste Disposal Method: Dispose of concrete according to Federal, State, Provincial and Local regulations.

Section 7: HANDLING AND STORAGE

Usage: Cutting, crushing or grinding hardened cement, concrete or other crystalline silica-bearing materials will release respirable crystalline silica. Use all appropriate measures of dust control or suppression, and Personal Protective Equipment (PPE) described in Section 8 below.

Storage Temperature: Unlimited. Storage Pressure: Unlimited.

Clothing: Promptly remove and launder clothing that is wet with concrete. Thoroughly wash skin after exposure to wet concrete.

Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION

Engineering Controls: Use local exhaust or general dilution ventilation or other suppression methods to maintain dust levels below exposure limits.

Personal Protective Equipment (PPE):

Respiratory Under ordinary conditions no respiratory protection is required. Wear a NIOSH Protection: approved respirator that is properly fitted and is in good condition when exposed to dust above exposure limits.

Eye Protection: Wear ANSI approved glasses or safety goggles when handling wet concrete to prevent contact with eyes. Wearing contact lenses, when using concrete, is not recommended.

Skin Protection: Wear gloves, boot covers and protective clothing impervious to water to prevent skin contact. Do not rely on barrier creams, in place of impervious gloves. Remove clothing and protective equipment that becomes saturated with wet cement and immediately wash exposed areas.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Semi-fluid, Flowable, granular paste.

Evaporation Rate: NA.

Appearance: Variety of color (usually gray) pH (in water): 12 – 13 Odor: None. Boiling Point: NA Vapor Pressure: NA. Freezing Point: NA.

Vapor Density: NA. Viscosity: Varies.

Specific Gravity: 1.9 – 2.4 Solubility in Water: Slightly (0.1 - 1.0%)

Page 5 of 6 Revised: 03/01/11

Section 10: STABILITY AND REACTIVITY

Stability: Hardened concrete is stable. Avoid contact with incompatible materials.

Incompatibility: Wet concrete is alkaline and is incompatible with acids, ammonium salts and aluminum metal. Cement dissolves in hydrofluoric acid, producing corrosive silicon tetrafluoride gas. Cement reacts with water to form silicates and calcium hydroxide.

Silicates react with powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese trifluoride, and oxygen difluoride.

Hazardous Polymerization: None. Hazardous Decomposition: None.

Section 11 and 12: TOXICOLOGICAL AND ECOLOGICAL INFORMATION

For questions regarding toxicological and ecological information refer to contact information in Section 1.

Section 13: DISPOSAL CONSIDERATIONS

Dispose of waste and containers in compliance with applicable Federal, State, Provincial and Local regulations.

Section 14: TRANSPORT INFORMATION

This product is not classified as a Hazardous Material under U.S. DOT or Canadian TDG regulations.

Section 15: REGULATORY INFORMATION

OSHA/MSHA Hazard This product is considered by OSHA/MSHA to be a hazardous chemical and should Communication: be included in the employer's hazard communication program.

CERCLA/SUPERFUND: This product is not listed as a CERCLA hazardous substance.

EPCRA This product has been reviewed according to the EPA Hazard Categories SARA Title III: promulgated under Sections 311 and 312 of the Superfund Amendment and

Reauthorization Act of 1986 and is considered a hazardous chemical and a delayed health hazard.

EPRCA This product contains none of the substances subject to the reporting requirements of SARA Section 313: Section 313 of Title III of the Superfund Amendments and Reauthorization Act of

1986 and 40 CFR Part 372.

RCRA: If discarded in its purchased form, this product would not be a hazardous waste either by listing or characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing the product or derived from the product should be classified as a hazardous waste.

TSCA: Portland cement and crystalline silica are exempt from reporting under the inventory update rule.

California Crystalline silica (airborne particulates of respirable size) and Chromium (hexavalent Proposition 65: compounds) are substances known by the State of California to cause cancer.

WHMIS/DSL: Products containing crystalline silica and calcium carbonate are classified as D2A, E and are subject to WHMIS requirements.

Page 6 of 6 Revised: 03/01/11

Section 16: OTHER INFORMATION

Abbreviations:

> Greater than NA Not Applicable

ACGIH American Conference of Governmental Industrial Hygienists NFPA National Fire Protection Association

CAS No Chemical Abstract Service number NIOSH National Institute for Occupational Safety and Health

NTP National Toxicology Program

CERCLA

Comprehensive Environmental Response, Compensation and Liability Act OSHA Occupational Safety and Health

Administration CFR Code for Federal Regulations PEL Permissible Exposure Limit CL Ceiling Limit pH Negative log of hydrogen ion DOT U.S. Department of Transportation PPE Personal Protective Equipment EST Eastern Standard Time R Respirable Particulate HEPA High-Efficiency Particulate Air RCRA Resource Conservation and Recovery Act

HMIS Hazardous Materials Identification System SARA Superfund Amendments and

Reauthorization Act T Total Particulate IARC International Agency for Research on

Cancer TDG Transportation of Dangerous Goods LC50 Lethal Concentration TLV Threshold Limit Value LD50 Lethal Dose TWA Time Weighted Average (8 hour) mg/m3 Milligrams per cubic meter MSHA Mine Safety and Health Administration

WHMIS Workplace Hazardous Materials Information System

This MSDS (Section 1) was revised on March 1, 2011.

An electronic version of this MSDS is available at: www.lafarge-na.com under the Sustainability section.

Lafarge North America Inc. (LNA) believes the information contained herein is accurate; however, LNA makes no guarantees with respect to such accuracy and assumes no liability in connection with the use of the information contained herein which is not intended to be and should not be construed as legal advice or as insuring compliance with any federal, state or local laws or regulations. Any party using this product should review all such laws, rules, or regulations prior to use, including but not limited to US and Canada Federal, Provincial and State regulations.

NO WARRANTY IS MADE, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR

PURPOSE, OR OTHERWISE.

WARNING

Silver-Copper-Phosphorus Alloys

Safety Data Sheet

1. Product and Company Identification Manufacturers and Suppliers Lucas Milhaupt, Inc. Lucas-Milhaupt Toronto 5656 South Pennsylvania Avenue 290 Carlingview Drive Cudahy, WI 53110 USA Rexdale, ON M9W 5G1 Canada Telephone: 414-769-6000 Telephone: 416-675-1860 www.lucasmilhaupt.com www.lucasmilhaupt.com

Emergency Phone Number Chemtrec: 800-424-9300

Issue Date: 05/01/2013 Product Name: Silver-Copper-Phosphorus Alloys SDS Number: 77 Product Codes: 15-996; 21-015; 24-863; 67-150; 71-017; 71-020; 71-050; 71-052;

71-060; 71-061; 71-062; 71-063; 71-100; 71-150; 71-180; 71-181

2. Composition/Information on Ingredients Ingredient Name CAS Number % Copper 7440-50-8 <1-93 Phosphorus 7723-14-0 <0.1-8 Silver 7440-22-4 <1-99.8

3. Hazards Identification Primary Routes(s) of Entry Ingestion; inhalation

Eye Hazards Eye contact with these products in finely-divided forms may cause irritation, conjunctivitis, ulceration of the cornea, and/or argyria, a permanent gray discoloration of the eyes, skin, mucous membranes, and respiratory tract.

Skin Hazards Skin contact with these products, particularly in finely-divided forms, may cause irritation, argyria, discoloration, and/or contact dermatitis.

Ingestion Hazards Ingestion of these products in finely-divided forms may cause nausea, vomiting, and gastrointestinal irritation.

Inhalation Hazards Inhalation of the components of these products is not known to present a significant risk to health when used according to instructions and with appropriate protective measures (see Section #8). Inhalation of component elements has been reported to cause one or more of the following symptoms and effects upon excessively high or prolonged exposure:

COPPER: Acute exposure may cause respiratory tract irritation, fever, muscle ache, chills, cough, weakness, and a metallic taste. Chronic exposure may damage the liver, kidney, spleen, pancreas, and brain.

PHOSPHORUS: The red form of phosphorus is stable and relatively non-toxic at room temperature. When heated in the presence of air, it is converted to phosphorus pentoxide, which is corrosive and irritating to the eyes, nose, throat, and mucous membranes.

SILVER: Chronic exposure via inhalation may cause argyria.

4. First Aid Measures Eye Flush affected areas with water for at least fifteen minutes. Seek medical assistance if necessary.

Skin Remove contaminated clothing. Wash affected area with large quantities of water for at least five minutes. Seek medical attention if necessary. Launder or dry-clean clothing before reuse.

Ingestion If subject is conscious, induce vomiting. If unconscious or convulsive, seek immediate medical assistance.

Inhalation If signs and symptoms of toxicity are observed, remove subject from area, administer oxygen, and seek medical attention. Keep the subject warm and at rest. Perform artificial respiration if breathing has stopped.

Note to Physician None of the components are acutely toxic by ingestion, nor are they absorbed through the skin. Prolonged skin contact may cause dermatitis and/or argyria.

5. Fire Fighting Measures

Flash Point: Not Applicable (N/Appl.)

Autoignition Point: N/Appl.

Flammability Class: N/Appl.

Lower Explosive Limit: N/Appl.

Upper Explosive Limit: N/Appl.

Fire and Explosion Hazards In finely-divided form, these products may ignite when exposed to flame or by reaction with incompatible materials (see Section #10). If present in a fire or explosion, they may emit fumes of the constituent metals, metal oxides, and/or phosphorus pentoxide.

Extinguishing Media Use dry chemical. Do not use water.

Fire Fighting Instructions If fighting a fire in which these products are present, wear a self-contained breathing apparatus with full facepiece operated in pressure-demand or other positive pressure mode.

6. Accidental Release Measures If a finely-divided form of product is spilled, clean up spillage so as to minimize dispersion of dust. Wet sweeping or vacuuming using HEPA filtration are recommended.

7. Handling and Storage Handling Precautions No special handling precautions are required.

Storage Precautions Do not store in proximity to incompatible materials (see Section #10).

Work/Hygienic Practices To minimize ingestion, wash hands and face before eating, drinking, applying cosmetics, or using tobacco.

8. Exposure Controls/Personal Protection Engineering Controls Use appropriate ventilation (e.g., dilution, local exhaust) adequate to maintain concentrations of all components to within their applicable standards.

Eye/Face Protection Wear eye protection adequate to prevent eye contact with finely-divided product and eye injury if products are used with a flame. Plastic-frame spectacles with side shields and filter lenses (shade #3/#4) are recommended.

Skin Protection Wear appropriate protective gloves and clothing to prevent skin injury if these products are used with a flame and/or for prolonged or repeated contact with finely-divided forms of product. Avoid flammable fabrics.

Respiratory Protection If an exposure level exceeds an applicable exposure standard, use a NIOSH-approved respirator having a configuration (type of facepiece, filter media, assigned protection factor, etc.) appropriate to the concentration of the contaminant(s) generated. For guidance on selection and use of respirators, consult American National Standard Z88.2 (ANSI, New York, NY 10036 USA).

Ingredient(s) - Exposure Limits Copper ACGIH TLVs: 0.2 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and mists) OSHA PELs: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and mists) Phosphorus No applicable ACGIH TLV(s) No applicable OSHA PEL(s) Silver ACGIH TLV: 0.1 mg/m3 TWA (metal) OSHA PEL: 0.01 mg/m3 TWA

9. Physical and Chemical Properties

Appearance: light-copper metals, various forms.

Odor: no odor Chemical Type: alloy Physical State: solid Melting Point: >1190oF./645oC.

Specific Gravity: 7.8-10.5 Solubility: insoluble

Other physical properties (odor threshold, evaporation rate, vapor pressure, vapor density, evaporation rate, boiling point, freezing point, pH, oil-water distribution coefficient, percent volatiles, percent VOCs) are not applicable to these products.

10. Stability and Reactivity Stability: stable Hazardous Polymerization: will not occur

Conditions to Avoid Silver and copper can form unstable acetylides if in contact with acetylene gas.

Incompatible Materials Strong oxidizers; ammonia; azides; nitric acid; ethylene imine; sulfuric acid;

chlorine trifluoride; inorganic and organic peroxides; peroxyformic acid; oxalic acid; bromates, chlorates, and iodates of alkali and alkali earth metals;

tartaric acid; 1-bromo-2-propyne; permonosulfuric acid; alkaline hydroxides.

Hazardous Decomposition Products Heating to elevated temperatures may liberate metal/metal oxide fumes and/or phosphorus pentoxide.

11. Toxicological Information Carcinogenicity These products contain no chemicals classified as potential or demonstrated carcinogens by IARC, NTP, or OSHA.

Conditions Aggravated by Overexposure Pre-existing pulmonary diseases (e.g., bronchitis, asthma) may be aggravated by inhalation overexposure, particularly as fume. Chronic overexposure by inhalation and/or ingestion may aggravate pre-existing diseases of the liver, kidneys, gastrointestinal system, and nervous system.

Ingredient(s) - Toxicological Data Copper LD50: No data available LC50: No data available Phosphorus LD50: >15,000 mg/kg (oral/rat) LC50: 4,300 mg/m3 for 1 hr (rat) Silver LD50: >2,000 mg/kg (oral/rat) LC50: No data available

12. Ecological Information

In their intended manner of use, these products should not be released into the environment, and adverse effects on ecosystems are not anticipated under recommended conditions of use, storage, and disposal.

13. Disposal Considerations Dispose of unused or unusable product in accordance with applicable Federal, State/Provincial, and local regulations.

14. Transport Information

These products are not Hazardous Substances or Dangerous Goods per USDOT, TDG (Canada), IATA, or IMO regulations.

15. Regulatory Information

TSCA Information All components of these products are listed on the EPA's TSCA registry.

SARA Hazard Classes Acute Health Hazard; Chronic Health Hazard

Ingredient(s) - U.S. Regulatory Information These products contain the following components subject to the requirements of Section 313 of the Emergency Planning and Community Right-to-Know Act of 1986 and of 40CFR, Part 372:

1. Copper (CASRN 7440-50-8)

2. Phosphorus (CASRN 7723-14-0)

3. Silver (CASRN 7440-22-4)

Canadian Regulatory Information All components of these products are listed on either the Domestic Substances List (DSL) or the Nondomestic Substances List (NDSL).

WHMIS Class(es) and Division(s): none applicable Components on Ingredients Disclosure List:

1. Copper, elemental (CASRN 7440-50-8)

2. Phosphorus (CASRN 7723-14-0)

3. Silver, elemental (CASRN 7440-22-4)

16. Other Information HMIS Ratings Health - 2* Flammability - 1 Physical Hazard - 0 PPE - see Note

Note: Lucas-Milhaupt, Inc. and Lucas-Milhaupt Toronto recommend use of protective eyewear and gloves (Personal Protection Index "B") as standard PPE.

HMIS recommends that its ratings be used only in conjunction with a fully implemented HMIS program, and that specific PPE codes be created by the user, who is familiar with the actual conditions under which the product is used. We cannot anticipate every condition of the product's use, and it is the user's responsibility to evaluate the hazards pertinent to its specific operations, and to determine the specific PPE required.

NFPA Ratings Health - 2 Flammability - 1 Reactivity - 0

Revision Information This MSDS supersedes a previous MSDS dated 05/10/2010.

Disclaimer Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s).

Lucas Milhaupt, Inc. Lucas-Milhaupt Toronto

STEEL PRODUCTS

Code No._____N/A______

Original Issue Date: ____1/11/02___ Revised: __________

I. IDENTIFICATION INFORMATION AND EMERGENCY TELEPHONE NUMBERS

(708) 339-1610

PRODUCT NAME: Mechanical Product Raw – Carbon Steel Painted

COMMON NAME(S): MECHANICAL

MANUFACTURER:

Allied Tube & Conduit Corp.

16100 South Lathrop Avenue

Harvey, IL 60426

II. INGREDIENTS AND RECOMMENDED OCCUPATIONAL EXPOSURE LIMITS

NOTE: Steel products under normal conditions do not present an inhalation, ingestion or contact health hazard (See Section VI).

EXPOSURE LIMITS BASE METAL ALLOYING

ELEMENTS AND

METALLIC COATINGS

% WEIGHT

OSHA PEL ACGIH TLV (1992-1993)

Base Metal: Iron 98.8

15 mg/M3 for total particulate as iron oxide total dust

5 mg/M3 for total particulate respirable fraction

5 mg/M3 for iron oxide fumes

Alloying Elements: Carbon 0.25 max. None Established None Established

Manganese 0.95 max.

(c) 5 mg/M3 – compounds

(b) 3 mg/M3 – fume 1 mg/M3 - fume

5 mg/M3 – dust & compounds 1 mg/M3 – fume

(b) 3 mg/M3 - fume

Phosphorus 0.035 max. None for inorganic phosphates None for inorganic phosphates

Sulfur 0.035 max. 5 mg/M3 as sulfur dioxide

(b) 10 mg/M3 as sulfur dioxide

5.2 mg/M3 as sulfur dioxide

(b) 13 mg/M3 as sulfur dioxide

Polymeric O.D. Coatings < 0.50 n/a n/a

Polymeric I.D. coatings 0.1 max. n/a n/a

(b) denotes short term exposure limit (STEL).

(c) Denotes “ceiling limit” which is not to be exceeded at any time.

* Subject to Section EPCRA 313 reporting.

NOTE: These products contain trace quantities of various elements but not at reportable levels under the OSHA Hazard Communication Standard Limit (29

CFR 1910.1200)

III. PHYSICAL DATA

Melting Point Base Metal: @ 2750° Metallic Coating: N/A

Appearance: Black Odor: No Odor

IV. FIRE AND EXPLOSION HAZARD DATA

Steel products sold in the solid state present no fire or explosion hazard.

V. REACTIVITY DATA

Stable under normal conditions of use, storage and transport. Will react with strong acid to liberate hydrogen.

VI. HEALTH HAZARD DATA

NOTE: Steel products under normal conditions do not present an inhalation, ingestion, or contact health hazard. However, operations such as burning, welding, sawing, brazing, grinding, and possibly machining, etc.

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