Att 14 - Bentonite Specification.pdf

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WASTEWATER PRETREATMENT PLANT OPERATION AND MAINTENANCE SERVICES
Solicitation number
2031ZA26R00023
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About this file

This is a product specification document for bentonite material required by the Bureau of Engraving and Printing. The specification establishes requirements for bentonite material or equivalent to Baroid Minerals and Chemicals for use as a "detackifier" in the Bureau's wastewater pretreatment plant chemical process. The bentonite prevents ink sludge from precipitating and forming non-pumpable tar-like material when treated with sulfuric acid.

The material must meet specific physical and chemical property requirements. Physical characteristics include montmorillonite content of 92%, with screen analysis requirements (80% minimum through 200 mesh dry, 1.5% typical wet), and foundry properties such as moisture content of 8-10% maximum, Fann viscosity of 21 at 600 RPM, green compression strength of 7.0 psi, and specific gravity of 2.79. Chemical composition specifications include silicon dioxide at 63.59%, aluminum oxide at 21.43%, iron oxide at 3.78%, magnesium oxide at 2.03%, sodium oxide at 2.70%, and bound water at 5.50%. The supplier must provide a safety data sheet two weeks before first delivery and upon any material changes. All material must comply with environmental and safety regulations including 40 CFR 720, 40 CFR 761 (PCB restrictions), 40 CFR Part 268, SARA Title III, EPA test methods, and District of Columbia and California environmental laws. Shipping, marking, and labeling must conform to DOT, OSHA, HMIS, and freight classification standards per 29 CFR 1910 Part 1200 and applicable motor freight rules.

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Attachment 14

Page 1 of 4 Pages

SPECIFICATION FOR BENTONITE

(a) SCOPE AND CLASSIFICATION

This specification covers bentonite material or equivalent to Baroid Minerals and Chemicals.

(b) PRODUCT SPECIFICATIONS

The physical and chemical properties of the material shall meet the following requirements:

(1) Physical Characteristics:

PROPERTY REQUIREMENT

X-RAY ANALYSIS

Montmorillonite 92%

Quartz 3%

Feldspar 5%

SCREEN ANALYSIS

Dry Screen % - 200 Mesh 80% Typical, 70% Minimum

Wet Screen % + 200 Mesh 1.5% Typical, 4.0 % Minimum

FOUNDRY PROPERTIES Typical

Moisture Content 8 - 10 Max

Fann Viscosity @ 600 RPM 21

Calcium Oxide Present (CaO) % 0.75

Methylene Blue Capacity, Meq/100 gr 100

Liquid Limit Number 747

Green Compression Strength, psi

(AFS)

7.0

Dry Compression Strength, psi (AFS) 96

Hot Strength 1500° F (5 %) 280

Compactibility, percent 60

Moldability Index 9 pH of 6 % suspension 8.2 - 9.6 Max

Specific Gravity 2.79

Fusion Temperature, ° F 2,444

Bulk Density, Ibs/ft3 61

Refractory Index 1.557

(2) Chemical Characteristics: typical

Page 2 of 4 Pages

PROPERTY REQUIREMENT

SiO 63.59 %

Al2O3 21.43 %

Fe2O3 3.78 %

CaO 0.66 %

MgO 2.03 %

Na2O 2.70 %

K2O 0.31 %

Bound Water 5.50 %

(c) RELATIVE ENVIRONMENTAL CONDITIONS

A safety data sheet of the product shall be forwarded by the Supplier and received by the Bureau of Engraving and Printing two weeks before the first delivery and upon any material changes. The following specifications, standards and handbooks form a part of this document to the extent specified herein.

(1) Certification of Compliance with Environmental and Safety

Regulations

Certificates are required to show that the material complies with the following regulations:

a. 40 CFR 720 – Pre-manufacture Notification: Pre-manufacture Notification Requirements and Review Procedures.

b. 40 CFR 761 - Polychlorinated Biphenyl (PCB's)

Manufacturing, Processing, Distribution in Commerce, and use Prohibitions.

c. 40 CFR Part 268, Subpart B - Schedule for Land Disposal

Prohibitions and Establishments of Treatment Standards.

d. Superfund Amendment and Reauthorization Act (SARA), Title III.

e. Test Methods for Evaluation of Solid Waste; EPA Procedure

1030 and Number 7420 SW - 846, Third Edition, November, 2004.

f. District of Columbia Air Pollution Control Act of 1984.

(Copies may be obtained from the District of Columbia Office

Page 3 of 4 Pages of Documents, Room 523, the District Building, Washington, D.C. 20004.)

g. District of Columbia Rules and Regulations - Title 8 - Health regulations, Chapter 2, Part 7. (Published by the Office of Air and Water Quality, Environmental Control Division, Department of Consumer and Regulatory Affairs, Government of the District, 510 Overlook Avenue, S. W., Washington, D. C. 20032.)

h. California's "Safe Drinking Water and Toxic Enforcement

Act" of 1986. Request for copies should be addressed to the State of California Health and Welfare Agency, 1600 Ninth Street, Room 450, Sacramento, California, 95814.

(2) Compliance with Shipping, Marking and Labeling Regulations

The shipping, marking and labeling shall conform to the applicable requirements of DOT, OSHA, HMIS, Uniform Freight Classification Rules, Motor Freight Classification Rules listed below:

a. 29 CFR 1910, Part 1200 - Hazard Communication Standard

(Occupational Safety and Health Administration). See also Federal register Volume 77, number 58, March 26, 2012.

b. Hazardous Material information System (HMIS) for Labeling.

(Request for copies should be addressed to the National Paint and Coating Association 1500 Rhode Island Avenue, Washington, D.C. 20005).

c. National Motor Freight Classification Rules and Container

Specification. (Request for copies should be addressed to the American trucking Association, Inc., 2000 Mill Road, Alexandria, Virginia 22314.

d. Uniform Freight Classification Rules. (Request for copies should be addressed to the Uniform Classification Committee, 222 South Riverside Plaza, Chicago, IL 60600.)

(c) ORDER OF PREFERENCE

In the event of a conflict between the text of this document and the references cited herein, the text of this document takes precedence.

Nothing in this document, however, supersedes applicable laws and regulations unless a specific exemption has been obtained.

Page 4 of 4 Pages

(d) INTENDED USE

This material will be used in the chemical process as a "detackifier" for the ink sludge in the Bureau's Wastewater Pretreatment Plant. Without the "detackifier" added prior to the sulfuric acid, the sludge will precipitate to the bottom of the tank and form a tar like material, which is non-pumpable through the system.

END OF SPECIFICATION FOR BENTONITE

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