Attach__No__1B_-_SLD_45_Env_Sampling_Plan_2021.pdf

ENVIRONMENTAL SAMPLING, ANALYSIS, AND MONITORING PLAN (ESAM)

FOR CAPE CANAVERAL SPACE FORCE STATION

AND PATRICK SPACE FORCE BASE

May 2021

Prepared by CTI-TPMC

Prepared by

Robin Carter Date Environmental Technician

Approved by

Richard B. Davis Date Project Manager

This Page Intentionally Left Blank

CCSFS/PSFB ESAM

i

TABLE OF CONTENTS

ACRONYMS ................................................................................................................................. iii

INTRODUCTION

CCAFS REGIONAL WWTF GROUNDWATER, RESIDUAL, AND EFFLUENT

MONITORING

CCAFS EOD RANGE CHEMICAL DISPOSAL SITE MONITORING WELLS AND SOIL

ANALYSIS

CCAFS LANDFILL ENVIRONMENTAL MONITORING

CCAFS STORMWATER MONITORING

PAFB STORMWATER MONITORING

PAFB LIFT STATION WASTEWATER SAMPLING

Figures

Figure 1 CCAFS RWWTF Monitoring Locations

Figure 2 CCAFS Regional WWTF

Figure 3 EOD Range Monitoring Well Sites

Figure 4 CCAFS Landfill Groundwater and Surface Water Monitoring Locations

Figure 5 CCAFS Landfill Gas Monitoring Well Locations

Figure 6 NPDES Field Sheet

Tables

Table 1: RWWTF Groundwater Parameters

Table 2: RWWTF Monitoring Well Information

Table 3: RWWTF Residuals Parameters

Table 4: RWWTF 24-hr Effluent Monitoring Parameters

Table 5: RWWTF Effluent Grab Sample Parameters

Table 6: EOD Range Sampling Parameters

Table 7: EOD Range Sampling Equipment

Table 8: CCAFS Landfill Surface Water Monitoring Sites

Table 9: CCAFS Landfill Surface Water Parameters

Table 10: CCAFS Landfill Surface Water Inorganic Constituents

Table 11: CCAFS Landfill Surface Water Organic Constituents

Table 12: CCAFS Landfill Groundwater Monitoring Sites ii

Table 13: CCAFS Landfill Groundwater Monitoring Parameters

Table 14: CCAFS Landfill Groundwater Inorganic Constituents

Table 15: CCAFS Landfill Groundwater Organic Constituents

Table 16: CCAFS Landfill Gas Vent Monitoring Sites

Table 17: CCAFS NPDES Sampling Sites and Parameters

Table 18: CCAFS NPDES Visual Examination Sites

Table 19: PAFB NPDES Sampling Sites and Parameters

Table 20: PAFB NPDES Visual Examination Sites

Table 21: PAFB 24-hr Wastewater Composite and Grab Sample Parameters iii

ACRONYMS

AFI Air Force Instruction

AFR Air Force Regulation

CAS RN Chemical Abstracts Service Registry Number

C&D Construction and Demolition

CCSFS Cape Canaveral Space Force Station

CFR Code of Federal Regulations

CTLs Cleanup Target Levels

CX Complex

EOD Explosive Ordnance Demolition

EPA U.S. Environmental Protection Agency

ESAM Environmental Sampling Analysis and Monitoring Plan

F2F Fence to Fence

FAC Florida Administrative Code

FDEP Florida Department of Environmental Protection

FDOH Florida Department of Health

IDW Investigation Derived Waste

LDR Land Disposal Restriction

LLC Limited Liability Corporation

MCL Maximum Contaminant Level

NELAP National Environmental Laboratory Accreditation Program

NGVD National Geodetic Vertical Datum

NOTU Naval Ordinance Test Unit

NPDES National Pollutant Discharge Elimination System

PSFB Patrick Space Force Base

PWQ/TRP Process Waste Questionnaire/Technical Response Package

RWWTF Regional Wastewater Treatment Facility

SJRWMD St. Johns River Water Management District

SWPPP Storm Water Pollution Prevention Plan

TOC Top of Casing iv

USSF United States Space Force

UTS Universal Treatment Standards

VOC Volatile Organic Compounds

INTRODUCTION

This plan outlines the environmental sampling, analysis, and monitoring conducted at Cape Canaveral Space Force Station (CCSFS) and Patrick Space Force Base (PSFB) in compliance with local, state and federal regulations, as well as Air Force requirements. Regulatory and permit compliance monitoring required by state and federal law is conducted by CTI / TPMC Companies, LLC under the Patrick Fence to Fence (F2F) contract.

This program is conducted in accordance with applicable Air Force Regulations (AFRs), Air Force Instructions (AFIs), Air Force Manual (AFMAN), Florida Department of Environmental Protection Standard Operating Procedures (FDEP SOPs) and/or United States Environmental Protection Agency (EPA) methods, as noted herein.

This plan describes those activities where sampling of surface water, groundwater, soils, air, wastewater and stormwater are performed, including frequency of sampling, justification for sampling efforts and rationale for the analyses of the parameters performed.

CCSFS REGIONAL WWTF GROUNDWATER, RESIDUAL, AND EFFLUENT

MONITORING

Description:

The CCSFS Regional Wastewater Treatment Facility (RWWTF) treats domestic wastewater from CCSFS and Kennedy Space Center. The Trident Industrial Wastewater Treatment Facility treats waste from the Port and Naval Ordinance Test Unit (NOTU) area; this waste is discharged to the RWWTF for additional treatment. The reclaimed water from the RWWTF is discharged to the south, central, northwest or the north site percolation ponds.

There are ten monitoring wells positioned around the percolation pond sites for the RWWTF.

The monitoring wells are used to determine the impact the effluent has on groundwater quality.

Two compliance wells and a background well monitor the south site and three compliance wells monitor the north site. The central site has two compliance wells and a background well that is shared with the south site. The northwest site has one compliance well and one background well.

There are seven piezometers in addition to the monitoring wells: six at the north and one at the central percolation pond. The piezometers measure groundwater levels and are recorded quarterly. The wells and piezometers will be monitored in accordance with the permit as specified by FDEP (Figure 1).

Permit Number:

FDEP permit No. FL0102920-012 expires 25 Apr 25

Groundwater Monitoring Requirement:

The monitoring requirement for the RWWTF involves quarterly sampling and analysis of groundwater from ten monitoring wells located at the facility. Samples are collected in accordance with the FDEP SOPs, latest revision. The samples are analyzed for the parameters in Table 1.

Table 1: RWWTF Groundwater Parameters

Parameters Units Groundwater Criteria* Total Dissolved Solids (TDS) mg/L 4160

Chloride (Cl) mg/L 1830 Nitrate mg/L 10 Nitrite mg/L 1

Turbidity (Field) NTU No MCL Fecal Coliform cfu/100 ml 4 pH (Field) s.u. 6.5-8.5 Sodium (Na) mg/L 1104

Manganese (Mn) mg/L 0.39 Water Level (Field) Ft. No MCL

* The Groundwater Criteria as listed in Chapter 62-777, F.A.C., Contamination Cleanup Criteria. FDEP has granted a variance (04/11/03) for TDS, Cl, Na, and Mn limits from FAC 62-777 due to elevated background conditions as noted in the permit documents.

Laboratory analyses results for the monitoring wells must be recorded on FDEP Form 62-

620.910 (10) or similar, to include facility test site identification number and type of well

(background, intermediate, or compliance). The wells and piezometers that require monitoring at the RWWTF percolation ponds are noted in Table 2.

Table 2: RWWTF Monitoring Well Information

FDEP Well No.

Top of Casing (TOC)

Elevation (ft.)

Well Type Pond Location WAFR No.

MW-1 13.04 Background South/Central Site 2168 MW-3 7.27 Compliance South Site 2166 MW-5 11.05 Piezometer Central Site 2164

MW-5R 9.26 Compliance Central Site 35545 MW-6 10.86 Compliance Central Site 2163 MW-7 7.69 Compliance North Site 2162 MW-9 8.39 Compliance North Site 2160 MW-10 9.12 Compliance North Site 106124 MW-11 7.82 Compliance South Site 106125 MW-12 13.00 Background Northwest Site 140557 MW-13 13.60 Compliance Northwest Site 140558

Piezometer No. TOC Elevation (ft.) Well Type Pond Location WAFR No.

P-1 8.15 Piezometer North Site 2159 P-2 7.50 Piezometer North Site 2158 P-3 9.22 Piezometer North Site 2157 P-4 10.29 Piezometer North Site 2156 P-5 11.77 Piezometer North Site 2155 P-6 7.81 Piezometer North Site 2154

Sampled By:

CTI / TPMC

Analyses By:

CTI / TPMC subcontracted laboratory

Report Sent To:

J. Burns, CLOIS cc: CCSFS Water Resources Group, F2F

S. Baker, 45 CES/CEIE

Quarterly Domestic Residuals Sampling and Analysis Requirement:

The non-permitted monitoring requirements of the Domestic Wastewater Residuals involve quarterly sampling and analysis of the residuals from the CCSFS RWWTF. Samples are collected in accordance with the FDEP SOPs. The samples are analyzed for the parameters in Table 3.

Table 3: RWWTF Residuals Parameters

Parameters Units (dry weight) MCL

Arsenic mg/kg 75 Cadmium mg/kg 85

Copper mg/kg 4300 Lead mg/kg 840

Mercury mg/kg 57 Molybdenum mg/kg 75

Nickel mg/kg 420 Selenium mg/kg 100

Zinc mg/kg 7500 PCB’s mg/kg 0.500 combined

Sampling Locations:

The residuals are collected from the CCSFS RWWTF dried sludge staging area.

Sampled By:

CTI / TPMC

Analysis By:

CTI / TPMC subcontracted laboratory

Report Sent To:

J. Burns, CLOIS cc: CCSFS Water Resources Group, F2F

Annual WWTF Effluent (Reclaimed) Monitoring:

Annual monitoring of the effluent produced by the CCSFS RWWTF is required by FDEP Domestic Waste Permit Number FL0102920-009-DW1P. A composite sampler is used to obtain a series of samples over a 24-hour period. The composite samples are analyzed for the parameters in Table 4.

Table 4: RWWTF 24-hr Effluent Monitoring Parameters

Aluminum Selenium Heptachlor epoxide Antimony Silver Hexachlorobenzene Arsenic Sodium Hexachlorocyclopentadiene Barium Thallium Oxamyl

Beryllium Dinoseb Pentachlorophenol Cadmium Diquat Picloram Chromium Endothall Polychlorinated Biphenyls Fluoride Glyphosate Simazine

Lead Heptachlor Alachlor Mercury 2,3,7,8-tetrachlorodibenzo-p-dioxin Atrazine Nickel Benzo(a)pyrene Endrin

Nitrate (as N) Carbofuran Lindane Nitrite (as N) Chlordane Methoxychlor

Total N (Nitrate plus Nitrite)

Dalapon Toxaphene

Manganese 2,4,5-TP (Silvex) 2,4-D

Sulfate Bis(2-ethylhexyl)adipate Gross alpha excl. radon and uranium

Zinc Bis(2-ethylhexyl)phthalate Radium-226 & Radium-228 combined TDS Chloride Para-dichlorobenzene

Foaming agents Copper Ethylene dibromide Iron

The grab samples are submitted for analyses for the parameters listed in Table 5.

Table 5: RWWTF Effluent Grab Sample Parameters

Cyanide 1,2-Dichloropropane Vinyl chloride Tetrachloroethene 1,2,4-Trichlorobenzene 1,1-Dichloroethane

Toluene Cis-1,2-Dichloroethene 1,2-Dichloroethane 1,2-trans-dichloroethylene Dichloromethane 1,1,2-Trichloroethane

Xylenes Ethylbenzene 1,1,1-Trichloroethane Benzene Monochlorobenzene Carbon tetrachloride

Total Trihalomethanes

(TTHM)

1,2-Dichlorobenzene Trichloroethene

1,4-Dichlorobenzene Styrene Dibromochloropropane pH

Sampling Locations:

The effluent samples are collected from the CCSFS RWWTF (Figure 2).

Sampled By:

CTI / TPMC

Analysis By:

CTI / TPMC subcontracted laboratory

Report Sent To:

J. Burns, CLOIS cc: CCSFS Water Resources Group, F2F

L. Fisher, 45 CES/CEIE

Figure 1 CCSFS RWWTF Monitoring Locations

Figure 2 CCSFS Regional WWTF

CCSFS EOD RANGE CHEMICAL DISPOSAL SITE MONITORING WELLS AND

SOIL ANALYSIS

Description:

There are six groundwater monitoring wells, including two background groundwater monitoring wells, at the Explosive Ordnance Demolition (EOD) range east of complex 17A and 17B, Pier Road, CCSFS (Figure 3). The wells are monitored in accordance with FDEP permit conditions for explosives and other analytes. The initial characterization sampling of the wells was performed on 22 Dec 97.

Permit Number:

FDEP Permit No. 0070725-HO-007, Expires 3 Mar 25

Monitoring Requirement:

The permit requires water analysis of the wells semiannually (May and November) for parameters listed below. In addition, field parameters include; conductivity, dissolved oxygen, pH, turbidity, temperature, and depth-to-water. Depth to water measurements are reported to the state annually in November. Well depths are taken prior to sampling for the creation of contour maps. Soil sample analysis is required annually in May for the constituents listed below in Table 6.

Table 6: EOD Range Sampling Parameters

Constituents Method

Water Analysis Soil Analysis

Aluminum EPA 6010C EPA 6010C Arsenic EPA 6010C EPA 6010C Barium EPA 6010C EPA 6010C

Cadmium EPA 6010C EPA 6010C Chromium EPA 6010C EPA 6010C

Copper EPA 6010C EPA 6010C Lead EPA 6010C EPA 6010C

Magnesium EPA 6010C EPA 6010C Potassium EPA 6010C EPA 6010C Selenium EPA 6010C EPA 6010C Titanium EPA 6010C EPA 6010C Vanadium EPA 6010C EPA 6010C

1,3,5-trinitrobenzene EPA 8330A/3535A EPA 8330A 1,3-dinitrobenzene EPA 8330A/3535A EPA 8330A

2,4,6-trinitrotoluene EPA 8330A/3535A EPA 8330A 2,4-dinitrotoluene EPA 8330A/3535A EPA 8330A 2,6-dinitrotoluene EPA 8330A/3535A EPA 8330A

2-amino-4,6-dinitrotoluene EPA 8330A/3535A EPA 8330A 2-nitrotoluene EPA 8330A/3535A EPA 8330A 3-nitrotoluene EPA 8330A/3535A EPA 8330A

Constituents Method

Water Analysis Soil Analysis

4-amino-2,6-dinitrotoluene EPA 8330A/3535A EPA 8330A 4-nitrotoluene EPA 8330A/3535A EPA 8330A

Diethyl phthalate EPA 8270D EPA 8270D Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) EPA 8330A/3535A EPA 8330A Methyl-2,4,6-trinitrophenylnitramine (Tetryl) EPA 8330A/3535A EPA 8330A

Nitrate-N EPA 300.0 EPA 9056A Nitrite-N EPA 300.0 EPA 9056A

Nitrobenzene EPA 8330A/3535A EPA 8330A Nitroglycerine EPA 8330A/3535A EPA 8330A

Octahydro-1,3,5,7-tetranitro-tetrazocine

(HMX)

EPA 8330A/3535A EPA 8330A

Pentaerythritol tetranitrate (PETN) EPA 8330A/3535A EPA 8330A Sulfate EPA 300.0 EPA 9056A

Perchlorate SW846 6850 SW846 6850

All purge waters are managed as a controlled waste until it has been determined that the groundwater does not either exhibit a characteristic of a hazardous waste as defined in 40 Code of Federal Regulations (CFR) 261 Subpart C or contaminant levels are below health based Cleanup Target Levels (CTLs) and Land Disposal Restriction Universal Treatment Standards (LDR/UTS) set forth in 40 CFR 268.40 and 268.48. If either of the above criteria is met, the purge water will continue to be managed as ‘hazardous groundwater’. The solid Investigation Derived Waste (IDW), including (but not limited to) silicone tubing and gloves, will be bagged and disposed of as a solid waste amenable to the municipal landfill. Current Process Waste Questionnaire/Technical Response Package (PWQ/TRP) analysis indicates this waste is not considered hazardous and may be placed into the regular trash that is collected from CCSFS.

Sampling Locations:

CCSFS EOD Range, Facility No. 1125 has 6 wells, 4 soil sampling sites at the 120’ x 60’ berm area in the center of the north side, center of the east side, center of the south side then in the overall center of the detonation pit if available.

Sampled By:

CTI / TPMC, using FDEP’s most recent SOP’s for sampling pursuant to Chapter 62-160, F.A.C.

The equipment (or equivalent) used to purge and sample the wells is listed in Table 7.

Table 7: EOD Range Sampling Equipment

Heron Water Level Meter Hanna model 93414 Turbidity meter

Geo pump II Peristaltic Pump Cooler with wet ice

Dedicated well tubing Sample containers (supplied by lab)

Disposable silicone pump head tubing Permanent markers

YSI Professional Plus meter Plastic scoops or spoons (for soil collection)

Analyses By:

CTI / TPMC subcontracted laboratory

Report Sent To:

Hazardous Waste Group, F2F

Figure 3 EOD Range Monitoring Well Sites

CCSFS LANDFILL ENVIRONMENTAL MONITORING

Description:

Monitor the quality of surface water, groundwater, and landfill gas for permit compliance in support of the operation and maintenance of the active Construction and Demolition Debris (C&D) landfill and the closure activity at the Closed Class I landfill at CCSFS.

Permits:

FDEP permits 0026050-014-SO (C&D), and 0026050-016-SF (Closure).

Surface Water Monitoring requirements:

There are four surface water quality monitoring sites at the landfill (Figure 4). These sites are sampled on a semiannual basis (March and October). The surface water monitoring sites are listed in Table 8.

Table 8: CCSFS Landfill Surface Water Monitoring Sites

Station Zone/Location Type CLF-SW-1 Upstream Compliance CLF-SW-2 Downstream Compliance CLF-SW-3 Upstream Compliance CLF-SW-4 Downstream Background

The parameters for surface water sampling are listed in Table 9. All analyses must use the detection limits at or below state standards and/or minimum criteria.

Table 9: CCSFS Landfill Surface Water Parameters

Field Parameters Units Criteria Temperature ⁰C *

Dissolved oxygen mg/L 7.5 pH s.u. 6.5-8.5

Specific conductance µmhos/cm <1275 Turbidity NTU ≤29 ^

Water elevation ft. 0.01

Laboratory Parameters Units Criteria Un-ionized ammonia as N mg/L ≤0.02

Biochemical oxygen demand (5 day) mg/L * Chemical oxygen demand mg/L *

Chlorophyll-a mg/m3 * Fecal Coliform cfu/100 mL *

Nitrate as N mg/L * Total nitrogen mg/L *

Total dissolved solids mg/L * Total hardness as CaCO3 mg/L *

Total organic carbon mg/L * Total phosphates as P mg/L * Total suspended solids mg/L *

*-No regulatory criteria established, ^-Value is number above the background value

The EPA 40 CFR, Part 258 Appendix I parameters, incorporated in the following section and listed in Tables 10 and 11.

40 CFR 258 - Appendix I (01/1999)

CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS

APPENDIX I: CONSTITUENTS FOR DETECTION MONITORING1

Table 10: CCSFS Landfill Surface Water Inorganic Constituents

Common Name2 CAS RN3 MCL (µg/L) Arsenic (Total) ≤50 Barium (Total) * Copper (Total) 30.5

Iron (Total) ≤1000 Mercury (Total) ≤0.012 Nickel (Total) 169 Zinc (Total) 4.6

Table 11: CCSFS Landfill Surface Water Organic Constituents

Common Name2 CAS RN3 MCL (µg/L) Acetone 67-64-1 1700

Chlorobenzene 108-90-7 17

1. This list contains 48 volatile organics for which possible analytical procedures are provided in EPA Report SW-846 "Test Methods for Evaluating Solid Waste," third edition, November 1986, Revision 6, February 2007 using Method 8260 and 17 metals for which SW-846 provides Method 6020A or Methods 7000B/7010.

2. Common names are those widely used in government regulations, scientific publications, and commerce; synonyms exist for many chemicals.

3. Chemical Abstracts Service (CAS) registry number. Where "Total" is entered, all species in the groundwater that contains this element is included.

* No regulatory criteria established

Surface water elevations must be taken the same day as groundwater elevations. All water depths must be taken prior to any sampling.

Groundwater Monitoring Requirements:

There are 22 groundwater monitoring wells associated with these landfills (Figure 4). The water levels in the monitoring wells are measured and sampled on a semiannual basis. The groundwater monitoring sites are listed in Table 12.

Table 12: CCSFS Landfill Groundwater Monitoring Sites

Monitoring Site/Well Zone/Location Type CLF-MW-A-S Upper Surficial Compliance CLF-MW-B-S Upper Surficial Compliance CLF-MW-C-S Upper Surficial Compliance CLF-MW-D-S Upper Surficial Compliance CLF-MW-H-S Upper Surficial Compliance CLF-MW-J-S Upper Surficial Compliance CLF-MW-L-S Upper Surficial Compliance CLF-MW-M-S Upper Surficial Compliance CLF-MW-N-S Upper Surficial Compliance CLF-MW-B-I Intermediate Surficial Compliance

Monitoring Site/Well Zone/Location Type CLF-MW-C-I Intermediate Surficial Compliance CLF-MW-H-I Intermediate Surficial Compliance CLF-MW-J-I Intermediate Surficial Compliance CLF-MW-L-I Intermediate Surficial Compliance CLF-MW-M-I Intermediate Surficial Compliance CLF-MW-A-D Deep Surficial Compliance CLF-MW-C-D Deep Surficial Compliance CLF-MW-D-D Deep Surficial Compliance CLF-MW-H-D Deep Surficial Compliance CLF-MW-J-D Deep Surficial Compliance CLF-MW-L-D Deep Surficial Compliance CLF-MW-N-D Deep Surficial Compliance

Groundwater samples are to be analyzed for the parameters in Table 13; all analyses must use the detection limits at or below current state standards and/or minimum criteria.

Table 13: CCSFS Landfill Groundwater Monitoring Parameters

Field Parameters Units Criteria Temperature ⁰C *

Dissolved oxygen mg/L * pH s.u. 6.5-8.5

Specific conductance µmhos/cm * Turbidity NTU *

Water elevation ft. 0.01

Laboratory Parameters Units Criteria Ammonia as N mg/L 2.8

Chloride mg/L 250 Nitrate as N mg/L 10

Sulfate as SO4 mg/L 250 Total dissolved solids mg/L 500

* No regulatory criteria established

The EPA 40 CFR, Part 258 Appendix I parameters, incorporated in the following section in Tables 14 and 15.

40 CFR 258 -Appendix I (01/1999)

CRITERIA FOR MUNICIPAL SOLID WASTE LANDFILLS

APPENDIX I: CONSTITUENTS FOR DETECTION MONITORING1

Table 14: CCSFS Landfill Groundwater Inorganic Constituents

Common Name2 CAS RN3 MCL (µg/L) Iron (Total) 300

Sodium (Total) 160

Table 15: CCSFS Landfill Groundwater Organic Constituents

Common Name2 CAS RN3 MCL (µg/L) Chlorobenzene 108-90-7 100

1. This list contains volatile organic analytes for which possible analytical procedures provided in EPA Report SW-846 “Test Methods for Evaluating Solid Waste,” third edition, November 1986, as revised December 1987, includes Method 8260; and metal analytes for which SW-846 provides either Method 6010 or a method from the 7000 series of methods.

2. Common names are those widely used in government regulations, scientific publications, and commerce; synonyms exist for many chemicals.

3. Chemical Abstracts Service (CAS) registry number. Where “Total” is entered, all species in the groundwater that contain this element are included.

* No regulatory criteria established

Sampling Locations:

CCSFS Landfill, 22 Wells, 4 Surface Water Locations

Sampled By:

CTI / TPMC

Analyses By:

CTI / TPMC subcontracted laboratory

Reports Sent To:

L. Dawe, 45 CES/CEIE cc: Solid Waste Group, F2F

Figure 4 CCSFS Landfill Groundwater and Surface Water Monitoring Locations

Gas Monitoring Requirements:

There are five gas vents located in the cover of the closed landfill (Figure 5). These vents are sampled for combustible gases on a semiannual basis during the months of March and October.

Ambient combustible gas sampling for the migration of landfill gas into the landfill structures is conducted as requested by FDEP. The gas vent monitoring sites are in Table 16.

Table 16: CCSFS Landfill Gas Vent Monitoring Sites

Station Zone/Location Type Background Station Adjacent to Site Trailer Background

CLF-GV-1 Closed Landfill Compliance CLF-GV-2 Closed Landfill Compliance CLF-GV-3 Closed Landfill Compliance CLF-GV-4 Closed Landfill Compliance CLF-GV-5 Closed Landfill Compliance

Landfill gas monitoring shall be conducted against the following criteria:

a) Not to exceed five percent of the lower explosive limit for combustible gases in structures on-or off-site, excluding gas control or recovery components; and

b) Not to exceed the lower explosive limit for combustible gases at or beyond the landfill property boundary in accordance with 62-701.530(1) (a) of the FAC.

Sampling Locations:

CCSFS Landfill Facility - 5 gas vents and 1 background station

Sampled By:

CTI / TPMC

Analyses By:

CTI / TPMC (in-field analysis)

Report Sent To:

L. Dawe, 45 CES/CEIE cc: Solid Waste Group, F2F

Figure 5 CCSFS Landfill Gas Monitoring Well Locations

CCSFS STORMWATER MONITORING

Description:

There are 8 storm water sites at CCSFS involved in the monitoring program. The stormwater program is designed to monitor the stormwater runoff quality from CCSFS.

Reference Documents:

National Pollutant Discharge Elimination System (NPDES) Permit – FLR05A947-004, Expires 9 Apr 21, Notice of Intent has been submitted to FDEP, awaiting invoice and final approval.

Stormwater Pollution Prevention Plan (SWPPP), CCSFS

Monitoring Requirements:

The monitoring program consists of three parts:

Stormwater sampling Visual examinations Outfall inspections

Stormwater Sampling:

Samples are to be collected at three specific sites quarterly. Grab samples are to be collected during daylight hours from the discharge resulting from a storm event that is greater than 0.1 inches and that occurs at least 72 hours from the previously measurable (greater than 0.1) storm event. The sample will be taken during the first 30 minutes of the discharge or as soon as practical, but not to exceed one hour. This is currently accomplished by Nalgene automatic samplers at all locations. The sample sites and monitored parameters are listed in Table 17.

Table 17: CCAFS NPDES Sampling Sites and Parameters

Site Facility Parameter Cut-off Concentration (mg/L)

Trident Wharf Poseidon Wharf Air Force Wharf

79100 90540 92050

Total Recoverable Aluminum 0.75 Total Recoverable Iron 1.00 Total Recoverable Lead 0.0816 Total Recoverable Zinc 0.117

Visual Examinations:

Visual examinations are to be conducted quarterly at all sites. Visual examinations are to be made during daylight hours and conducted in a well-lit area. The examinations are made of grab samples collected within the first 30 minutes of discharge or as soon thereafter as practical, but not to exceed one hour from when the runoff begins to flow from the site. The examinations will document observations of color, odor, clarity, floating solids, settled solids, suspended solids, foam, oil sheen, and any other indicators of storm water pollution. Analytical tests are required to be performed on the samples collected from the Trident Wharf, Poseidon Wharf and Air force Wharf. Analytical tests are not required for the Skid Strip:

An example of an appropriate visual examination form similar to Form B-4, from the Stormwater Pollution Prevention Plan, CCAFS, is shown in Figure 6. The visual examination sites are listed in Table 18.

Table 18: CCAFS NPDES Visual Examination Sites

Site Facility Trident Wharf 79100

Poseidon Wharf 90540 Air Force Wharf 92050

Skid Strip

Site Locations:

Exact stormwater sites are shown in the CCSFS SWPPP

Sampled By:

CTI / TPMC

Analyses By:

CTI / TPMC subcontracted laboratory

Report Sent To:

CCSFS Water Resources Group, F2F cc: C. Vanaman, CLOIS

J. Burns, CLOIS

L. Fisher, 45 CES/CEIE

M. Cardish, F2F

Figure 6 NPDES Field Sheet

PSFB STORMWATER MONITORING

Description:

There are four total stormwater sites at PSFB involved in the monitoring program. The stormwater program is designed to monitor the stormwater runoff quality from PSFB.

Reference Documents:

NPDES Permit – FLR05A948-004, Expires 1 Oct 25

SWPPP, PSFB

Monitoring Requirements:

The monitoring program consists of three parts:

Stormwater sampling Visual examinations Outfall inspections

Stormwater Sampling:

Samples are collected at three specific sites quarterly. Grab samples are collected during daylight hours from the discharge resulting from a storm event that is greater than 0.1 inches and that occurs at least 72 hours from the previously measurable (greater than 0.1) storm event. The sample will be taken during the first 30 minutes of the discharge or as soon after as practical, but not to exceed one hour. This is accomplished by Nalgene automatic samplers at all locations.

The sample sites and monitored parameters are listed in Table 19. Note that the Marina (Outfall

030) and Outdoor Rec (Outfall 011) locations are sampled for aluminum, iron, lead and zinc.

The Fuel Farm (Outfall 017) is sampled for aluminum, iron, lead, zinc, copper, total suspended solids and chemical oxygen demand.

Table 19: PSFB NPDES Sampling Sites and Parameters

Site Outfall Parameter Cut-off Concentration (mg/L)

Marina Outdoor Rec

Total Recoverable Aluminum 0.75 Total Recoverable Iron 1.00 Total Recoverable Lead 0.0816 Total Recoverable Zinc 0.117

Fuel Farm Above analytes plus:

Total Recoverable Copper 0.0636 Total Suspended Solids 100

Chemical Oxygen Demand 120

Visual Examinations:

Visual examinations are conducted quarterly at all four sites. Visual examinations are made during daylight hours and conducted in a well-lit area. The examinations are made of grab samples collected within the first 30 minutes of discharge or as soon thereafter as practical, but not to exceed one hour from when the runoff begins to flow from the site. The examinations will document observations of color, odor, clarity, floating solids, settled solids, suspended solids, foam, oil sheen, and any other indicators of storm water pollution. An example of an appropriate visual examination form similar to Form H-4, from the Stormwater Pollution Prevention Plan, PSFB, is shown in Figure 6. The visual examination sites are listed in Table 20.

Table 20: PSFB NPDES Visual Examination Sites

Site Outfall Fuel Farm 017

Marina 030 Outdoor Rec 011

Fuel Storage Area 022

Site Locations:

Exact stormwater sites are shown in the PSFB SWPPP

Sampled By:

CTI / TPMC

Analyses By:

CTI / TPMC subcontracted laboratory

Report Sent To:

S. Baker, 45 CES/CEIE cc: L. Fisher, 45 CES/CEIE

M. Cardish, F2F

PSFB LIFT STATION WASTEWATER SAMPLING

Description:

To provide annual operational monitoring at PSFB main lift station, Facility No. 650, as per the now expired City of Cocoa Beach, Florida Wastewater Discharge Permit No. 0004.

Permit:

City of Cocoa Beach, Florida Wastewater Discharge Permit No. 0004 – Expired

Monitoring Requirements:

Annual untreated wastewater samples are collected from the lift station as both 24-hour composite samples and grab samples. The sampling parameters are listed in Table 21.

Table 21: PSFB 24-hr Wastewater Composite and Grab Sample Parameters

Parameters Units Sample Type Discharge Limitations

Arsenic µg/L Composite 490 BOD5 mg/L Composite 1000

Cadmium µg/L Composite 440 Chromium (Total) µg/L Composite 8700

Copper µg/L Composite 100 Cyanide mg/L Grab 0.04

Lead µg/L Composite 37 Mercury µg/L Composite 0.6

Molybdenum µg/L Composite 440 Nickel µg/L Composite 70

Total Kjeldahl Nitrogen mg/L Composite Not Listed Oil & Grease mg/L Grab 100

Phenolic Compounds, Total mg/L Grab Not Listed Selenium µg/L Composite 550

Silver µg/L Composite 90 Total Phosphorus as P mg/L Composite Not Listed

Total Suspended Solids mg/L Composite 1000 VOCs (Total) µg/L Grab Not Listed

Zinc µg/L Composite 2200 Temperature °C Grab Not Listed pH s.u. Grab Not Listed

Sampling Locations:

Main lift station at PSFB, Facility No. 650

Sampled By:

CTI / TPMC

Analysis By:

CTI / TPMC subcontracted laboratory

Reports Sent To:

S. Baker, 45 CES/CEIE cc: J. Kelley, 45 CES/CEOFI

R. Burgdorf, 45 CES/CEOFI

L. Fisher, 45 CES/CEIE

T. Powers, F2F