J135508-1.pdf

ANALYTICAL REPORT

Eurofins Pittsburgh 301 Alpha Drive RIDC Park Pittsburgh, PA 15238 Tel: (412)963-7058

Laboratory Job ID: 180-135508-1 Client Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

For:

Battelle 141 Longwater Dr Suite 202 Norwell, Massachusetts 02061

Attn: Carole Peven McCarthy

Authorized for release by:

5/12/2022 12:26:57 PM

Carrie Gamber, Senior Project Manager (412)963-2428 Carrie.Gamber@et.eurofinsus.com

This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

PA Lab ID: 02-00416 https://secure.testamericainc.com/TotalAccess/login.aspx http://www.testamericainc.com/services-we-offer/ask-the-expert http://www.eurofinsus.com/Env mailto:Carrie.Gamber@et.eurofinsus.com

Table of Contents

Client: Battelle Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Laboratory Job ID: 180-135508-1

Eurofins Pittsburgh

5/12/2022

Cover Page

Table of Contents

Case Narrative

Definitions/Glossary

Certification Summary

Sample Summary

Method Summary

Lab Chronicle

Client Sample Results

QC Sample Results

QC Association Summary

Chain of Custody

Receipt Checklists

Case Narrative Client: Battelle Job ID: 180-135508-1 Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Job ID: 180-135508-1

Laboratory: Eurofins Pittsburgh

Narrative

CASE NARRATIVE

Client: Battelle

Project: RFP No: 22-0690 USACE-NYD Newark Bay

Report Number: 180-135508-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

RECEIPT

The samples were received on 03/22/2022; the samples arrived in good condition, properly preserved and on ice. The temperatures of the 5 coolers at receipt time were 2.1º C, 2.1º C, 2.3º C, 2.5º C and 2.6º C.

The dioxin reference method requires samples to be preserved to a pH of <9. The following SPLP samples was received with insufficient preservation at a pH of 11 due to the matrix: #20220312 AMENDED COMPOSITE A (180-135508-11), #20220313 AMENDED COMPOSITE B (180-135508-12), #20220314 AMENDED COMPOSITE C (180-135508-13), #20220315 AMENDED COMPOSITE D (180-135508-14).

VOLATILES

The following sample was diluted to bring the concentration of target analytes within the calibration range: #20220333 AMENDED DISCRETE D3 (180-135508-20). Elevated reporting limits (RLs) are provided.

Surrogate recovery for the following samples were outside control limits: #20220312 AMENDED COMPOSITE A (180-135508-11), #20220313 AMENDED COMPOSITE B (180-135508-12), #20220314 AMENDED COMPOSITE C (180-135508-13), #20220315 AMENDED COMPOSITE D (180-135508-14), #20220316 AMENDED COMPOSITE E (180-135508-15), #20220317 AMENDED COMPOSITE F

(180-135508-16), #20220318 AMENDED COMPOSITE G (180-135508-17), #20220331 AMENDED DISCRETE D1 (180-135508-18), #20220332 AMENDED DISCRETE D2 (180-135508-19) and #20220333 AMENDED DISCRETE D3 (180-135508-20). Evidence of matrix interference is present; therefore, re-extraction and/or re-analysis was not performed. The pH of the samples was 12. High pH often results in low recovery of Dibromofluoromethane surrogate.

Surrogate recovery for the following samples were outside control limits for Dibromofluoromethane: #20220312 AMENDED COMPOSITE A

(180-135508-11), #20220314 AMENDED COMPOSITE C (180-135508-13), #20220315 AMENDED COMPOSITE D (180-135508-14), #20220316 AMENDED COMPOSITE E (180-135508-15), #20220317 AMENDED COMPOSITE F (180-135508-16), #20220318 AMENDED

COMPOSITE G (180-135508-17), #20220331 AMENDED DISCRETE D1 (180-135508-18) and #20220333 AMENDED DISCRETE D3

(180-135508-20). These sample were SPLP sample with a high pH. High pH often results in low recovery of Dibromofluoromethane surrogate; therefore, re-extraction and/or re-analysis was not performed.

Chloroform was detected in method blank MB 180-392673/6 at a level that was above the method detection limit but below the reporting limit. The value should be considered an estimate, and has been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Methylene Chloride was detected in method blank LB 180-393515/1-A at a level exceeding the reporting limit. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. The associated method blank was non-detect for Methylene

Chloride.

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Job ID: 180-135508-1 (Continued)

Laboratory: Eurofins Pittsburgh (Continued)

Methylene Chloride was detected in method blank LB 180-393579/1-A at a level exceeding the reporting limit. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. The associated method blank was non-detect for Methylene

Chloride.

Acetone was detected in method blank LB 180-393579/1-A at a level that was above the method detection limit but below the reporting limit. The value should be considered an estimate, and has been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

The laboratory control sample (LCS) for analytical batch 180-395373 recovered outside control limits for the following analytes:

Chloroethane, Vinyl chloride and Bromomethane. These analytes were biased high in the LCS and were not detected in the associated samples; therefore, the data have been reported.

The continuing calibration verification (CCV) analyzed in batch 180-395373 was outside the method criteria for the following analyte(s):

Bromomethane, tert-Butyl alcohol, Chloroethane and Trichloroethene. (HIGH). As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

The continuing calibration verification (CCV) analyzed in batch 180-395373 was outside the method criteria for the following analyte:

Acrolein. (LOW) A Low Level standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

The continuing calibration verification (CCV) analyzed in batch 180-395373 was outside the method criteria for the following analyte:

1,2-Dibromo-3-Chloropropane. (LOW MINIMUM RRF). low-level LCS (LLCS), spiked at the reporting limit (RL), was prepared with this batch. The affected target analytes recovered within acceptance limits; therefore, the LLCS demonstrates the analytical system had sufficient sensitivity to detect the compound.

The continuing calibration verification (CCV) analyzed in batch 180-394680 was outside the method criteria for the following analyte(s):

Methyl acetate(RF). A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

The continuing calibration verification (CCV) analyzed in batch 180-394680 was outside the method criteria for the following analyte(s):

1,2-Dibromo-3-Chloropropane(RF). A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

The continuing calibration verification (CCV) analyzed in batch 180-394680 was outside the method criteria for the following analyte(s):

2-Butanone, Acetone, Bromoform, Bromomethane, Chloroethane, Dichlorodifluoromethane, Trichlorofluoromethane and Vinyl chloride. A

CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

The continuing calibration verification (CCV) analyzed in batch 180-394680 was outside the method criteria for the following analyte(s):

Acrolein. A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

The continuing calibration verification (CCV) analyzed in 180-392851 was outside the method criteria for the following analyte(s):

Chloroethane. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

The continuing calibration verification (CCV) analyzed in batch 180-392851 was outside the method criteria for the following analyte(s):

Trichlorofluoromethane and Dichlorodifluoro-methane. A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

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Job ID: 180-135508-1 (Continued)

Laboratory: Eurofins Pittsburgh (Continued)

The continuing calibration verification (CCV) analyzed in 180-392851 was outside the method criteria for the following analyte(s):

Chloroethane. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

The continuing calibration verification (CCV) analyzed in batch 180-392851 was outside the method criteria for the following analyte(s):

Trichlorofluoromethane and Dichlorodifluoro-methane. A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

The continuing calibration verification (CCV) analyzed in batch 180-392673 was outside the method criteria for the following analyte(s):

1,2-Dibromo-3-Chloropropane and Trichlorofluoromethane. A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte(s) is considered estimated.

SEMIVOLATILES

All bulk sediment samples were diluted due to the nature of the sample matrix. Elevated reporting limits (RLs) are provided.

Surrogate recovery for the following sample was outside control limits: #20220312 AMENDED COMPOSITE A (180-135508-11), #20220313 AMENDED COMPOSITE B (180-135508-12) and #20220333 AMENDED DISCRETE D3 (180-135508-20). Evidence of matrix interference is present and the sample was analyzed at a dilution; therefore, re-extraction and/or re-analysis was not performed.

Caprolactam and Di-n-butyl phthalate were detected in method blank LB 180-393202/1-G at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Di-n-butyl phthalate was detected in method blank LB 180-393330/1-F at a level exceeding the reporting limit. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. The associated method blank was non-detect for Di-n-butyl phthalate.

Caprolactam was detected in method blank LB 180-393330/1-F at a level that was above the method detection limit but below the reporting limit. The value should be considered an estimate, and has been flagged. If the associated sample reported a result above the

MDL and/or RL, the result has been flagged.

Di-n-butyl phthalate was detected in method blank LB 180-393576/1-E at a level exceeding the reporting limit. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. The associated method blank was non-detect for Di-n-butyl phthalate.

Phenanthrene was detected in method blank LB 180-393576/1-E at a level that was above the method detection limit but below the reporting limit. The value should be considered an estimate, and has been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Several analytes failed the recovery criteria low for the MS of sample #20220176 DISCRETE D2MS (180-135508-9) in batch 180-393446.

Bis(2-ethylhexyl) phthalate failed the recovery criteria high. For the MSD of sample #20220176 DISCRETE D2MSD (180-135508-9) in batch 180-393446, Several analytes failed the recovery criteria low. Bis(2-ethylhexyl) phthalate failed the recovery criteria high. Also, Hexachlorocyclopentadiene exceeded the RPD limit.

The continuing calibration verification (CCV) associated with batch 180-393584 recovered above the upper control limit for

Pentachlorophenol. The samples associated with this CCV were non-detects for the affected analytes; therefore, the data have been reported. The associated sample is impacted: (CCVIS 180-393584/3).

The continuing calibration verification (CCV) associated with batch 180-393446 recovered above the upper control limit for Butyl benzyl phthalate and N-Nitrosodimethylamine. The samples associated with this CCV were non-detects for the affected analytes; therefore, the data have been reported. The associated sample is impacted: (CCVIS 180-393446/3).

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Job ID: 180-135508-1 (Continued)

Laboratory: Eurofins Pittsburgh (Continued)

PESTICIDES

All bulk sediment samples were diluted due to the nature of the sample matrix. Elevated reporting limits (RLs) are provided.

The following sample was diluted to bring the concentration of target analytes within the calibration range: (LCSSRM 180-393138/24-B).

Elevated reporting limits (RLs) are provided and surrogates were reported as is.

Surrogate Tetrachloro-m-xylene (Surr) and DCB Decachlorobiphenyl (Surr) recovery for the following sample was outside the upper control limit on one or both columns: #20220313 AMENDED COMPOSITE B (180-135508-12). This sample did not contain any target analytes;

therefore, re-extraction and/or re-analysis was not performed.

The Tetrachloro-m-xylene (Surr) surrogate recovery for the following samples was outside acceptance limits (high biased) on the confirmation column due to matrix interference: #20220316 AMENDED COMPOSITE E (180-135508-15). The recovery is within acceptance limits on the other column, indicating that the extraction process was in control.

Surrogate DCB Decachlorobiphenyl (Surr) recovery for the following sample was outside control limits: #20220317 AMENDED COMPOSITE F (180-135508-16). Evidence of matrix interference is present; therefore, re-extraction and/or re-analysis was not performed.

The DCB Decachlorobiphenyl (Surr) surrogate recovery for the following samples was outside acceptance limits (high biased) on the confirmation column due to matrix interference: #20220187 COMPOSITE F (180-135508-6) and #20220317 AMENDED COMPOSITE F (180-135508-16). The recovery is within acceptance limits on the other column, indicating that the extraction process was in control.

Surrogate DCB Decachlorobiphenyl (Surr) recovery for the following sample was outside control limits: #20220177 DISCRETE D3

(180-135508-10). Evidence of matrix interference is present; therefore, re-extraction and/or re-analysis was not performed.

Tetrachloro-m-xylene (Surr) and DCB Decachlorobiphenyl (Surr) recover slightly high for LB 180-393330/1-C. There were no target compounds detected; therefore, the data was reported with this narrative note.

The following analyte recovered outside control limits for the LCS associated with batch 180-392978: Methoxychlor. This is not indicative of a systematic control problem because these were random marginal exceedances. Qualified results have been reported.

Methoxychlor failed the recovery criteria low for the MS of sample #20220316 AMENDED COMPOSITE EMS (180-135508-15) in batch 180-394873. Methoxychlor failed the recovery criteria low for the MSD of sample #20220316 AMENDED COMPOSITE EMSD

(180-135508-15) in batch 180-394873.

PCBs The following samples contained more than one Aroclor with insufficient separation to quantify individually. The PCBs present are quantified as the predominant Aroclor: #20220182 COMPOSITE A (180-135508-1), #20220183 COMPOSITE B (180-135508-2), #20220184 COMPOSITE C (180-135508-3), #20220185 COMPOSITE D (180-135508-4), #20220186 COMPOSITE E (180-135508-5), #20220187 COMPOSITE F (180-135508-6), #20220188 COMPOSITE G (180-135508-7), #20220175 DISCRETE D1 (180-135508-8), #20220176 DISCRETE D2 (180-135508-9), #20220177 DISCRETE D3 (180-135508-10), #20220312 AMENDED COMPOSITE A (180-135508-11), #20220313 AMENDED COMPOSITE B (180-135508-12), #20220314 AMENDED COMPOSITE C (180-135508-13), #20220315 AMENDED COMPOSITE D (180-135508-14), #20220316 AMENDED COMPOSITE E (180-135508-15), #20220317 AMENDED COMPOSITE F (180-135508-16), #20220318 AMENDED COMPOSITE G (180-135508-17), #20220331 AMENDED DISCRETE D1

(180-135508-18), #20220332 AMENDED DISCRETE D2 (180-135508-19), #20220333 AMENDED DISCRETE D3 (180-135508-20), (180-135508-A-1-M MS) and (180-135508-A-1-N MSD).

All bulk sediment samples were diluted due to the abundance of target analytes. The sample extracts were dark in color. Elevated reporting limits (RLs) are provided.

Surrogate recovery for the following samples were outside control limits: #20220182 COMPOSITE A (180-135508-1), #20220183 COMPOSITE B (180-135508-2), #20220184 COMPOSITE C (180-135508-3), #20220185 COMPOSITE D (180-135508-4), #20220186

COMPOSITE E (180-135508-5), #20220187 COMPOSITE F (180-135508-6), #20220188 COMPOSITE G (180-135508-7), #20220175 DISCRETE D1 (180-135508-8), #20220332 AMENDED DISCRETE D2 (180-135508-19), #20220333 AMENDED DISCRETE D3

(180-135508-20), (180-135508-A-1-M MS) and (180-135508-A-1-N MSD). Evidence of matrix interference is present; therefore, re-extraction and/or re-analysis was not performed.

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Job ID: 180-135508-1 (Continued)

Laboratory: Eurofins Pittsburgh (Continued)

First internal standard recovered high on the confirmation column. Results for this internal were reported from the passing column.

#20220314 AMENDED COMPOSITE C (180-135508-13)

PCB-1260 failed the recovery criteria low for the MS of sample #20220182 COMPOSITE AMS (180-135508-1) in batch 180-394493.

PCB-1016 failed the recovery criteria high for the MSD of sample #20220182 COMPOSITE AMSD (180-135508-1) in batch 180-394493.

PCB-1016 and PCB-1260 exceeded the RPD limit.

The continuing calibration verification (CCV) associated with batch 180-394492 recovered above the upper control limit for PCB-1016. The samples associated with this CCV were non-detects for the affected analytes; therefore, the data have been reported.

The continuing calibration verification (CCV) associated with batch 180-393674 recovered above the upper control limit for PCB-1260. The samples associated with this CCV were non-detects for the affected analytes; therefore, the data have been reported.

HERBICIDES

The continuing calibration verification (CCV) associated with 394018 recovered high and outside the control limits for surrogate DCAA on one column. Results are confirmed on both columns and reported from the passing column. The associated sample is: (CCVRT

180-394018/1).

The continuing calibration verification (CCV) associated with batch 394018 recovered outside acceptance criteria, low biased, for 2,4-D and 2,4,5 -T. A reporting limit (RL) standard was analyzed, and the target analytes are detected. Since the associated samples were non-detect for the analyte(s), the data are reported.

The continuing calibration verification (CCV) associated with 394039 recovered high and outside the control limits for all analytes on one column. Results are confirmed on both columns and reported from the passing column. The associated sample is: (CCVRT 180-394039/1).

DIOXINS

The following samples went through Gel-Permeation Cleanup procedure, based on EPA method 3640A: #20220182 COMPOSITE A (180-135508-1), #20220183 COMPOSITE B (180-135508-2), #20220184 COMPOSITE C (180-135508-3), #20220185 COMPOSITE D (180-135508-4), #20220186 COMPOSITE E (180-135508-5), #20220187 COMPOSITE F (180-135508-6), #20220188 COMPOSITE G (180-135508-7), #20220175 DISCRETE D1 (180-135508-8), #20220176 DISCRETE D2 (180-135508-9), #20220177 DISCRETE D3

(180-135508-10), #20220312 AMENDED COMPOSITE A (180-135508-11), #20220313 AMENDED COMPOSITE B (180-135508-12), #20220314 AMENDED COMPOSITE C (180-135508-13), #20220315 AMENDED COMPOSITE D (180-135508-14), #20220316 AMENDED COMPOSITE E (180-135508-15), #20220317 AMENDED COMPOSITE F (180-135508-16), #20220318 AMENDED COMPOSITE G (180-135508-17), #20220331 AMENDED DISCRETE D1 (180-135508-18), #20220332 AMENDED DISCRETE D2 (180-135508-19) and

#20220333 AMENDED DISCRETE D3 (180-135508-20).

One or more Isotope Dilution Analyte (IDA) recoveries are above the method recommended limit for the following sample: #20220318

AMENDED COMPOSITE G (180-135508-17). Quantitation by isotope dilution generally precludes any adverse effect on data quality due to elevated IDA recoveries.

The Isotope Dilution Analyte (IDA) recovery associated with the following sample is below the method recommended limit: #20220315 AMENDED COMPOSITE D (180-135508-14). Generally, data quality is not considered affected if the IDA signal-to-noise ratio is greater than 10:1, which is achieved for all IDA in the sample.

Several analytes were detected in method blank MB 140-60280/18-A at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Several analytes were detected in method blank MB 140-60689/22-A at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the

MDL and/or RL, the result has been flagged.

Several analytes were detected in method blank LB 140-60650/11-A at levels that were above the method detection limit but below the

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Laboratory: Eurofins Pittsburgh (Continued) reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the

MDL and/or RL, the result has been flagged.

Several analytes were detected in method blank MB 140-60650/18-A at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

METALS

The following samples were prepared/digested outside of the holding time for Mercury due to a laboratory oversight by 1 day: #20220182

COMPOSITE A (180-135508-1), #20220183 COMPOSITE B (180-135508-2), #20220184 COMPOSITE C (180-135508-3), #20220185 COMPOSITE D (180-135508-4), #20220313 AMENDED COMPOSITE B (180-135508-12), #20220314 AMENDED COMPOSITE C

(180-135508-13), #20220315 AMENDED COMPOSITE D (180-135508-14), (180-135508-B-1-E MS) and (180-135508-B-1-F MSD).

Barium and Zinc were detected in method blank LB 180-393576/1-F at levels exceeding the reporting limit. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. The leach blank for preparation batch 180-393576 and 180-394529 contained zinc above the reporting limit (RL). The sample associated with this leach blank contained Zinc below the reporting limit; therefore, re-extraction and/or re-analysis of samples were not performed.

Copper was detected in method blank LB 180-393576/1-F at a level that was above the method detection limit but below the reporting limit. The value should be considered an estimate, and has been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Antimony was detected in method blank MB 180-394529/1-A at a level that was above the method detection limit but below the reporting limit. The value should be considered an estimate, and has been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Several analytes failed the recovery criteria low for the MS of sample #20220313 AMENDED COMPOSITE BMS (180-135508-12) in batch

180-395526. Aluminum failed the recovery criteria high. Several analytes failed the recovery criteria low for the MSD of sample #20220313 AMENDED COMPOSITE BMSD (180-135508-12) in batch 180-395526. Aluminum failed the recovery criteria high. The presence of the '4' qualifier indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.

Antimony and Selenium failed the recovery criteria low for the MS of sample #20220182 COMPOSITE AMS (180-135508-1) in batch

180-395526. Aluminum, Manganese and Zinc failed the recovery criteria high. Antimony and Selenium failed the recovery criteria low for the MSD of sample #20220182 COMPOSITE AMSD (180-135508-1) in batch 180-395526. Aluminum, Manganese and Zinc failed the recovery criteria high. The presence of the '4' qualifier indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.

Mercury failed the recovery criteria high for the MSD of sample #20220182 COMPOSITE AMSD (180-135508-1) in batch 180-395345. The presence of the '4' qualifier indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.

GENERAL CHEMISTRY

The following samples were assumed to contain Sulfide due to sample matrix when digesting for Cyanide: #20220182 COMPOSITE A (180-135508-1), #20220183 COMPOSITE B (180-135508-2), #20220184 COMPOSITE C (180-135508-3), #20220185 COMPOSITE D

(180-135508-4), #20220186 COMPOSITE E (180-135508-5), #20220187 COMPOSITE F (180-135508-6), #20220188 COMPOSITE G

(180-135508-7), #20220175 DISCRETE D1 (180-135508-8), #20220176 DISCRETE D2 (180-135508-9), #20220177 DISCRETE D3 (180-135508-10), #20220312 AMENDED COMPOSITE A (180-135508-11), #20220313 AMENDED COMPOSITE B (180-135508-12), #20220314 AMENDED COMPOSITE C (180-135508-13), #20220315 AMENDED COMPOSITE D (180-135508-14), #20220316 AMENDED COMPOSITE E (180-135508-15), #20220317 AMENDED COMPOSITE F (180-135508-16), #20220318 AMENDED COMPOSITE G

(180-135508-17), #20220331 AMENDED DISCRETE D1 (180-135508-18), #20220332 AMENDED DISCRETE D2 (180-135508-19), #20220333 AMENDED DISCRETE D3 (180-135508-20), (180-135508-B-1 MS) and (180-135508-B-1 MSD). The sulfide was treated and removed prior to distillation with 200 uL of bismuth nitrate solution.

Cr (VI) failed the recovery criteria low for the MS of sample #20220313 AMENDED COMPOSITE BMS (180-135508-12) in batch

180-393512. Cr (VI) failed the recovery criteria low for the MSD of sample #20220313 AMENDED COMPOSITE BMSD (180-135508-12) in batch 180-393512.

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Job ID: 180-135508-1 (Continued)

Laboratory: Eurofins Pittsburgh (Continued)

Cyanide, Total failed the recovery criteria low for the MS of sample #20220182 COMPOSITE AMS (180-135508-1) in batch 180-393399.

Eurofins Pittsburgh Page 9 of 332 5/12/2022

Definitions/Glossary Job ID: 180-135508-1Client: Battelle

Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Qualifiers

GC/MS VOA

Qualifier Description

*+ LCS and/or LCSD is outside acceptance limits, high biased.

Qualifier

B Compound was found in the blank and sample.

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

S1- Surrogate recovery exceeds control limits, low biased.

U Indicates the analyte was analyzed for but not detected.

GC/MS Semi VOA Qualifier Description

B Compound was found in the blank and sample.

Qualifier

F1 MS and/or MSD recovery exceeds control limits.

F2 MS/MSD RPD exceeds control limits

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

S1- Surrogate recovery exceeds control limits, low biased.

U Indicates the analyte was analyzed for but not detected.

GC Semi VOA Qualifier Description

*- LCS and/or LCSD is outside acceptance limits, low biased.

Qualifier

*3 ISTD response or retention time outside acceptable limits.

F1 MS and/or MSD recovery exceeds control limits.

F2 MS/MSD RPD exceeds control limits

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

p The %RPD between the primary and confirmation column/detector is >40%. The lower value has been reported.

S1- Surrogate recovery exceeds control limits, low biased.

S1+ Surrogate recovery exceeds control limits, high biased.

U Indicates the analyte was analyzed for but not detected.

Dioxin Qualifier Description

*5- Isotope dilution analyte is outside acceptance limits, low biased.

Qualifier

*5+ Isotope dilution analyte is outside acceptance limits, high biased.

B Compound was found in the blank and sample.

I Value is EMPC (estimated maximum possible concentration).

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

q The reported result is the estimated maximum possible concentration of this analyte, quantitated using the theoretical ion ratio. The measured ion ratio does not meet qualitative identification criteria and indicates a possible interference.

S Ion suppression

U Indicates the analyte was analyzed for but not detected.

Metals Qualifier Description

4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable.

Qualifier

B Compound was found in the blank and sample.

F1 MS and/or MSD recovery exceeds control limits.

H Sample was prepped or analyzed beyond the specified holding time

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

U Indicates the analyte was analyzed for but not detected.

General Chemistry Qualifier Description

F1 MS and/or MSD recovery exceeds control limits.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

U Indicates the analyte was analyzed for but not detected.

Eurofins Pittsburgh

Page 10 of 332 5/12/2022

Definitions/Glossary

Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CFU Colony Forming Unit

CNF Contains No Free Liquid

DER Duplicate Error Ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL Detection Limit (DoD/DOE)

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision Level Concentration (Radiochemistry)

EDL Estimated Detection Limit (Dioxin)

LOD Limit of Detection (DoD/DOE)

LOQ Limit of Quantitation (DoD/DOE)

MCL EPA recommended "Maximum Contaminant Level"

MDA Minimum Detectable Activity (Radiochemistry)

MDC Minimum Detectable Concentration (Radiochemistry)

MDL Method Detection Limit

ML Minimum Level (Dioxin)

MPN Most Probable Number

MQL Method Quantitation Limit

NC Not Calculated

ND Not Detected at the reporting limit (or MDL or EDL if shown)

NEG Negative / Absent

POS Positive / Present

PQL Practical Quantitation Limit

PRES Presumptive

QC Quality Control

RER Relative Error Ratio (Radiochemistry)

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TNTC Too Numerous To Count

Eurofins Pittsburgh

Page 11 of 332 5/12/2022

Accreditation/Certification Summary

Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Laboratory: Eurofins Pittsburgh Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.

Authority Program Identification Number Expiration Date

New Jersey NELAP PA005 06-30-23

The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte

2540G Sediment Percent Moisture

2540G Sediment Percent Solids

7196A Sediment Cr (III)

EPA 8260D Sediment 1,2-Dichloroethene, Total

EPA 8260D 5035A Sediment 1,2-Dichloroethene, Total

New York NELAP 11182 04-01-23

The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte

2540G Sediment Percent Moisture

2540G Sediment Percent Solids

7196A Sediment Cr (III)

EPA 8260D Sediment 1,2-Dichloroethene, Total

EPA 8260D 5035A Sediment 1,2-Dichloroethene, Total

Laboratory: Eurofins Knoxville The accreditations/certifications listed below are applicable to this report.

Authority Program Identification Number Expiration Date

New Jersey NELAP TN001 06-30-22

New York NELAP 10781 03-31-23

The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte

1613B HRMS-Sepf Sediment 1,2,3,4,6,7,8-HpCDD

1613B HRMS-Sepf Sediment 1,2,3,4,6,7,8-HpCDF

1613B HRMS-Sepf Sediment 1,2,3,4,7,8,9-HpCDF

1613B HRMS-Sepf Sediment 1,2,3,4,7,8-HxCDD

1613B HRMS-Sepf Sediment 1,2,3,4,7,8-HxCDF

1613B HRMS-Sepf Sediment 1,2,3,6,7,8-HxCDD

1613B HRMS-Sepf Sediment 1,2,3,6,7,8-HxCDF

1613B HRMS-Sepf Sediment 1,2,3,7,8,9-HxCDD

1613B HRMS-Sepf Sediment 1,2,3,7,8,9-HxCDF

1613B HRMS-Sepf Sediment 1,2,3,7,8-PeCDD

1613B HRMS-Sepf Sediment 1,2,3,7,8-PeCDF

1613B HRMS-Sepf Sediment 2,3,4,6,7,8-HxCDF

1613B HRMS-Sepf Sediment 2,3,4,7,8-PeCDF

1613B HRMS-Sepf Sediment 2,3,7,8-TCDD

1613B HRMS-Sepf Sediment 2,3,7,8-TCDF

1613B HRMS-Sepf Sediment OCDD

1613B HRMS-Sepf Sediment OCDF

1613B HRMS-Sox Sediment 1,2,3,4,6,7,8-HpCDD

1613B HRMS-Sox Sediment 1,2,3,4,6,7,8-HpCDF

1613B HRMS-Sox Sediment 1,2,3,4,7,8,9-HpCDF

1613B HRMS-Sox Sediment 1,2,3,4,7,8-HxCDD

Eurofins Pittsburgh

Page 12 of 332 5/12/2022

Accreditation/Certification Summary

Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Laboratory: Eurofins Knoxville (Continued) Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.

Authority Program Identification Number Expiration Date

The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte

1613B HRMS-Sox Sediment 1,2,3,4,7,8-HxCDF

1613B HRMS-Sox Sediment 1,2,3,6,7,8-HxCDD

1613B HRMS-Sox Sediment 1,2,3,6,7,8-HxCDF

1613B HRMS-Sox Sediment 1,2,3,7,8,9-HxCDD

1613B HRMS-Sox Sediment 1,2,3,7,8,9-HxCDF

1613B HRMS-Sox Sediment 1,2,3,7,8-PeCDD

1613B HRMS-Sox Sediment 1,2,3,7,8-PeCDF

1613B HRMS-Sox Sediment 2,3,4,6,7,8-HxCDF

1613B HRMS-Sox Sediment 2,3,4,7,8-PeCDF

1613B HRMS-Sox Sediment 2,3,7,8-TCDD

1613B HRMS-Sox Sediment 2,3,7,8-TCDF

1613B HRMS-Sox Sediment OCDD

1613B HRMS-Sox Sediment OCDF

Eurofins Pittsburgh

Page 13 of 332 5/12/2022

Sample Summary

Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Lab Sample ID Client Sample ID Matrix Collected Received

180-135508-1 #20220182 COMPOSITE A Sediment 03/15/22 08:11 03/22/22 10:00

180-135508-2 #20220183 COMPOSITE B Sediment 03/15/22 10:42 03/22/22 10:00

180-135508-3 #20220184 COMPOSITE C Sediment 03/15/22 11:52 03/22/22 10:00

180-135508-4 #20220185 COMPOSITE D Sediment 03/15/22 12:43 03/22/22 10:00

180-135508-5 #20220186 COMPOSITE E Sediment 03/16/22 08:20 03/22/22 10:00

180-135508-6 #20220187 COMPOSITE F Sediment 03/16/22 10:32 03/22/22 10:00

180-135508-7 #20220188 COMPOSITE G Sediment 03/16/22 11:32 03/22/22 10:00

180-135508-8 #20220175 DISCRETE D1 Sediment 03/16/22 09:16 03/22/22 10:00

180-135508-9 #20220176 DISCRETE D2 Sediment 03/17/22 11:51 03/22/22 10:00

180-135508-10 #20220177 DISCRETE D3 Sediment 03/16/22 09:54 03/22/22 10:00

180-135508-11 #20220312 AMENDED COMPOSITE A Sediment 03/16/22 08:11 03/22/22 10:00

180-135508-12 #20220313 AMENDED COMPOSITE B Sediment 03/15/22 10:42 03/22/22 10:00

180-135508-13 #20220314 AMENDED COMPOSITE C Sediment 03/15/22 11:52 03/22/22 10:00

180-135508-14 #20220315 AMENDED COMPOSITE D Sediment 03/15/22 12:43 03/22/22 10:00

180-135508-15 #20220316 AMENDED COMPOSITE E Sediment 03/16/22 08:20 03/22/22 10:00

180-135508-16 #20220317 AMENDED COMPOSITE F Sediment 03/16/22 10:32 03/22/22 10:00

180-135508-17 #20220318 AMENDED COMPOSITE G Sediment 03/16/22 11:32 03/22/22 10:00

180-135508-18 #20220331 AMENDED DISCRETE D1 Sediment 03/16/22 09:16 03/22/22 10:00

180-135508-19 #20220332 AMENDED DISCRETE D2 Sediment 03/17/22 11:51 03/22/22 10:00

180-135508-20 #20220333 AMENDED DISCRETE D3 Sediment 03/16/22 09:54 03/22/22 10:00

Eurofins PittsburghPage 14 of 332 5/12/2022

Method Summary

Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Method Method Description LaboratoryProtocol

SW846EPA 8260D Volatile Organic Compounds by GC/MS TAL PIT

SW846EPA 8270E LL Semivolatile Organic Compounds (GC/MS) TAL PIT

SW846EPA 8081B LL Organochlorine Pesticides (GC) TAL PIT

SW846EPA 8082A Polychlorinated Biphenyls (PCBs) (GC) TAL PIT

SW846EPA 8151A Herbicides (GC) TAL PIT

EPA1613B Dioxins and Furans (HRGC/HRMS) TAL KNX

SW846EPA 6020B Metals (ICP/MS) TAL PIT

SW846EPA 7470A Mercury (CVAA) TAL PIT

SW846EPA 7471B Mercury (CVAA) TAL PIT

SM222540G SM 2540G TAL PIT

SW8467196A Chromium, Trivalent (Colorimetric) TAL PIT

SW846EPA 7196A Chromium, Hexavalent TAL PIT

SW846EPA 9014 Cyanide TAL PIT

SW8461312 SPLP Extraction TAL PIT

SW8463010A Preparation, Total Metals TAL PIT

SW8463050B Preparation, Metals TAL PIT

SW8463060A Alkaline Digestion (Chromium, Hexavalent) TAL PIT

SW8463510C Liquid-Liquid Extraction (Separatory Funnel) TAL PIT

SW8463520C Liquid-Liquid Extraction (Continuous) TAL PIT

SW8463541 Automated Soxhlet Extraction (Low Level) TAL PIT

SW8463640A Gel-Permeation Cleanup TAL PIT

SW8463660B Sulfur Cleanup TAL PIT

SW8463665A Sulfuric Acid/Permanganate Cleanup TAL PIT

SW8465030C Purge and Trap TAL PIT

SW8465035A Purge and Trap TAL PIT

SW8467470A Preparation, Mercury TAL PIT

SW8467471B Preparation, Mercury TAL PIT

SW8468151A Extraction (Herbicides) TAL PIT

SW8469010C Cyanide, Distillation TAL PIT

SW846EPA 1311 TCLP Extraction TAL PIT

SW846EPA 1312 SPLP Extraction TAL PIT

EPAHRMS-Sepf Separatory Funnel (Liquid-Liquid) Extraction TAL KNX

EPAHRMS-Sox Soxhlet Extraction TAL KNX

Protocol References:

EPA = US Environmental Protection Agency

SM22 = Standard Methods For The Examination Of Water And Wastewater, 22nd Edition

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL KNX = Eurofins Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000

TAL PIT = Eurofins Pittsburgh, 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238, TEL (412)963-7058

Eurofins Pittsburgh

Page 15 of 332 5/12/2022

Lab Chronicle

Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Client Sample ID: #20220182 COMPOSITE A Lab Sample ID: 180-135508-1 Matrix: SedimentDate Collected: 03/15/22 08:11

Date Received: 03/22/22 10:00

Leach EPA 1311 LWM04/14/22 12:00 TAL PIT395367

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

TCLP 100.4 g 2000 mL

Prep 3010A 395679 04/16/22 08:59 KFS TAL PITTCLP 5 mL 50 mL

Analysis EPA 6020B 1 396145 04/20/22 23:55 RSK TAL PITTCLP

AInstrument ID:

Analysis 2540G 1 392973 03/24/22 17:34 NAF TAL PITTotal/NA

NOEQUIPInstrument ID:

Analysis 7196A 1 395798 04/18/22 12:24 RSR TAL PITTotal/NA

NOEQUIPInstrument ID:

Client Sample ID: #20220182 COMPOSITE A Lab Sample ID: 180-135508-1 Matrix: SedimentDate Collected: 03/15/22 08:11

Percent Solids: 42.5Date Received: 03/22/22 10:00

Prep 5035A KLG03/23/22 07:30 TAL PIT392707

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 5.0009 g 5 mL

Analysis EPA 8260D 1 392673 03/23/22 12:50 KLG TAL PITTotal/NA 5 mL 5 mL

CHHP3Instrument ID:

Prep 3541 393355 03/28/22 18:30 CSC TAL PITTotal/NA 30.3 g 0.5 mL

Analysis EPA 8270E LL 10 393446 03/29/22 20:19 VVP TAL PITTotal/NA 1 mL 1 mL

CH731Instrument ID:

Prep 3541 393138 03/25/22 20:55 CSC TAL PITTotal/NA 30.3 g 10.0 mL

Cleanup 3640A 393746 03/31/22 09:42 VJC TAL PITTotal/NA 5.0 mL 0.5 mL

Analysis EPA 8081B LL 5 394077 04/04/22 20:26 DFE TAL PITTotal/NA

CHGC15Instrument ID:

Prep 3541 393139 03/25/22 23:22 CSC TAL PITTotal/NA 30.3 g 1.0 mL

Cleanup 3665A 393372 03/29/22 04:19 JMO TAL PITTotal/NA 2 mL 2 mL

Cleanup 3660B 393373 03/29/22 04:20 JMO TAL PITTotal/NA 2 mL 2 mL

Analysis EPA 8082A 10 394493 04/07/22 15:06 JMO TAL PITTotal/NA

CHGC8Instrument ID:

Prep 8151A 392926 03/24/22 08:20 CBY TAL PITTotal/NA 10.0 g 40.0 mL

Analysis EPA 8151A 1 393209 03/28/22 20:14 JMO TAL PITTotal/NA

CGC1Instrument ID:

Prep HRMS-Sox 60280 03/31/22 08:43 SSS TAL KNXTotal/NA 20.10 g 20 uL

Analysis 1613B 1 60834 04/19/22 05:45 LKM TAL KNXTotal/NA

D11AInstrument ID:

Prep HRMS-Sox 60280 03/31/22 08:43 SSS TAL KNXTotal/NA 20.10 g 20 uL

Analysis 1613B 1 60876 04/20/22 02:22 LKM TAL KNXTotal/NA

D12CInstrument ID:

Prep 3050B 395189 04/13/22 06:36 KFS TAL PITTotal/NA 2.02 g 100 mL

Analysis EPA 6020B 1 395526 04/14/22 15:50 RSK TAL PITTotal/NA

DORYInstrument ID:

Prep 7471B 395140 04/13/22 05:55 RJR TAL PITTotal/NA 1.22 g 100 mL

Analysis EPA 7471B 1 395345 04/13/22 12:20 RJR TAL PITTotal/NA

HGZInstrument ID:

Eurofins Pittsburgh

Page 16 of 332 5/12/2022

Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Client Sample ID: #20220182 COMPOSITE A Lab Sample ID: 180-135508-1 Matrix: SedimentDate Collected: 03/15/22 08:11

Percent Solids: 42.5Date Received: 03/22/22 10:00

Prep 3060A JCR03/28/22 20:35 TAL PIT393359

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 2.55 g 100 mL

Analysis EPA 7196A 1 393815 03/31/22 13:39 PMH TAL PITTotal/NA 4 mL 4 mL

RAPID-TInstrument ID:

Prep 9010C 393198 03/27/22 14:45 CMR TAL PITTotal/NA 0.50 g 10 mL

Analysis EPA 9014 1 393399 03/28/22 16:12 CMR TAL PITTotal/NA

SEAL1Instrument ID:

Client Sample ID: #20220183 COMPOSITE B Lab Sample ID: 180-135508-2 Matrix: SedimentDate Collected: 03/15/22 10:42

Date Received: 03/22/22 10:00

Leach EPA 1311 LWM04/14/22 12:00 TAL PIT395367

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

TCLP 100.3 g 2000 mL

Prep 3010A 395679 04/16/22 08:59 KFS TAL PITTCLP 5 mL 50 mL

Analysis EPA 6020B 1 396145 04/20/22 23:59 RSK TAL PITTCLP

AInstrument ID:

Analysis 2540G 1 392973 03/24/22 17:34 NAF TAL PITTotal/NA

NOEQUIPInstrument ID:

Analysis 7196A 1 395798 04/18/22 12:24 RSR TAL PITTotal/NA

NOEQUIPInstrument ID:

Client Sample ID: #20220183 COMPOSITE B Lab Sample ID: 180-135508-2 Matrix: SedimentDate Collected: 03/15/22 10:42

Percent Solids: 41.3Date Received: 03/22/22 10:00

Prep 5035A KLG03/23/22 07:30 TAL PIT392707

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 5.0016 g 5 mL

Analysis EPA 8260D 1 392673 03/23/22 15:10 KLG TAL PITTotal/NA 5 mL 5 mL

CHHP3Instrument ID:

Prep 3541 393355 03/28/22 18:30 CSC TAL PITTotal/NA 30.4 g 0.5 mL

Analysis EPA 8270E LL 10 393446 03/29/22 20:41 VVP TAL PITTotal/NA 1 mL 1 mL

CH731Instrument ID:

Prep 3541 393138 03/25/22 20:55 CSC TAL PITTotal/NA 30.1 g 10.0 mL

Cleanup 3640A 393746 03/31/22 09:42 VJC TAL PITTotal/NA 5.0 mL 0.5 mL

Analysis EPA 8081B LL 5 394077 04/04/22 20:42 DFE TAL PITTotal/NA

CHGC15Instrument ID:

Prep 3541 393139 03/25/22 23:22 CSC TAL PITTotal/NA 30.4 g 1.0 mL

Cleanup 3665A 393372 03/29/22 04:19 JMO TAL PITTotal/NA 2 mL 2 mL

Cleanup 3660B 393373 03/29/22 04:20 JMO TAL PITTotal/NA 2 mL 2 mL

Analysis EPA 8082A 10 394493 04/07/22 16:02 JMO TAL PITTotal/NA

CHGC8Instrument ID:

Prep 8151A 392926 03/24/22 08:20 CBY TAL PITTotal/NA 10.0 g 40.0 mL

Analysis EPA 8151A 1 393209 03/28/22 21:12 JMO TAL PITTotal/NA

CGC1Instrument ID:

Eurofins Pittsburgh

Page 17 of 332 5/12/2022

Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Client Sample ID: #20220183 COMPOSITE B Lab Sample ID: 180-135508-2 Matrix: SedimentDate Collected: 03/15/22 10:42

Percent Solids: 41.3Date Received: 03/22/22 10:00

Prep HRMS-Sox SSS03/31/22 08:43 TAL KNX60280

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 20.36 g 20 uL

Analysis 1613B 1 60834 04/19/22 06:46 LKM TAL KNXTotal/NA

D11AInstrument ID:

Prep HRMS-Sox 60280 03/31/22 08:43 SSS TAL KNXTotal/NA 20.36 g 20 uL

Analysis 1613B 1 60876 04/20/22 02:52 LKM TAL KNXTotal/NA

D12CInstrument ID:

Prep 3050B 395189 04/13/22 06:36 KFS TAL PITTotal/NA 2.01 g 100 mL

Analysis EPA 6020B 1 395526 04/14/22 16:08 RSK TAL PITTotal/NA

DORYInstrument ID:

Prep 7471B 395140 04/13/22 05:55 RJR TAL PITTotal/NA 1.58 g 100 mL

Analysis EPA 7471B 1 395345 04/13/22 12:26 RJR TAL PITTotal/NA

HGZInstrument ID:

Prep 3060A 393359 03/28/22 20:35 JCR TAL PITTotal/NA 2.52 g 100 mL

Analysis EPA 7196A 1 393815 03/31/22 13:40 PMH TAL PITTotal/NA 4 mL 4 mL

RAPID-TInstrument ID:

Prep 9010C 393198 03/27/22 14:45 CMR TAL PITTotal/NA 0.50 g 10 mL

Analysis EPA 9014 1 393399 03/28/22 16:21 CMR TAL PITTotal/NA

SEAL1Instrument ID:

Client Sample ID: #20220184 COMPOSITE C Lab Sample ID: 180-135508-3 Matrix: SedimentDate Collected: 03/15/22 11:52

Date Received: 03/22/22 10:00

Leach EPA 1311 LWM04/14/22 12:00 TAL PIT395367

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

TCLP 100.1 g 200 mL

Prep 3010A 395679 04/16/22 08:59 KFS TAL PITTCLP 5 mL 50 mL

Analysis EPA 6020B 1 396145 04/21/22 00:10 RSK TAL PITTCLP

AInstrument ID:

Analysis 2540G 1 392973 03/24/22 17:34 NAF TAL PITTotal/NA

NOEQUIPInstrument ID:

Analysis 7196A 1 395798 04/18/22 12:24 RSR TAL PITTotal/NA

NOEQUIPInstrument ID:

Client Sample ID: #20220184 COMPOSITE C Lab Sample ID: 180-135508-3 Matrix: SedimentDate Collected: 03/15/22 11:52

Percent Solids: 38.9Date Received: 03/22/22 10:00

Prep 5035A KLG03/24/22 07:00 TAL PIT392895

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 5.0017 g 5 mL

Analysis EPA 8260D 1 392851 03/24/22 13:14 KLG TAL PITTotal/NA 5 mL 5 mL

CHHP3Instrument ID:

Prep 3541 393355 03/28/22 18:30 CSC TAL PITTotal/NA 30.2 g 0.5 mL

Analysis EPA 8270E LL 10 393446 03/29/22 21:03 VVP TAL PITTotal/NA 1 mL 1 mL

CH731Instrument ID:

Eurofins Pittsburgh

Page 18 of 332 5/12/2022

Project/Site: RFP No: 22-0690 USACE-NYD Newark Bay

Client Sample ID: #20220184 COMPOSITE C Lab Sample ID: 180-135508-3 Matrix: SedimentDate Collected: 03/15/22 11:52

Percent Solids: 38.9Date Received: 03/22/22 10:00

Prep 3541 CSC03/25/22 20:55 TAL PIT393138

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 30.1 g 10.0 mL

Cleanup 3640A 393746 03/31/22 09:42 VJC TAL PITTotal/NA 5.0 mL 0.5 mL

Analysis EPA 8081B LL 5 394077 04/04/22 20:58 DFE TAL PITTotal/NA

CHGC15Instrument ID:

Prep 3541 393139 03/25/22 23:22 CSC TAL PITTotal/NA 30.2 g 1.0 mL

Cleanup 3665A 393372 03/29/22 04:19 JMO TAL PITTotal/NA 2 mL 2 mL

Cleanup 3660B 393373 03/29/22 04:20 JMO TAL PITTotal/NA 2 mL 2 mL

Analysis EPA 8082A 10 394493 04/07/22 16:21 JMO TAL PITTotal/NA

CHGC8Instrument ID:

Prep 8151A 392926 03/24/22 08:20 CBY TAL PITTotal/NA 10.0 g 40.0 mL

Analysis EPA 8151A 1 393209 03/28/22 21:32 JMO TAL PITTotal/NA

CGC1Instrument ID:

Prep HRMS-Sox 60280 03/31/22 08:43 SSS TAL KNXTotal/NA 20.13 g 20 uL

Analysis 1613B 1 60834 04/19/22 07:46 LKM TAL KNXTotal/NA

D11AInstrument ID:

Prep HRMS-Sox 60280 03/31/22 08:43 SSS TAL KNXTotal/NA 20.13 g 20 uL

Analysis 1613B 1 60876 04/20/22 03:21 LKM TAL KNXTotal/NA

D12CInstrument ID:

Prep 3050B 395189 04/13/22 06:36 KFS TAL PITTotal/NA 2.03 g 100 mL

Analysis EPA 6020B 1 395526 04/14/22 16:11 RSK TAL PITTotal/NA

DORYInstrument ID:

Prep 7471B 395140 04/13/22 05:55 RJR TAL PITTotal/NA 1.25 g 100 mL

Analysis EPA 7471B 1 395345 04/13/22 12:28 RJR TAL PITTotal/NA

HGZInstrument ID:

Prep 3060A 393359 03/28/22 20:35 JCR TAL PITTotal/NA 2.51 g 100 mL

Analysis EPA 7196A 1 393815 03/31/22 13:41 PMH TAL PITTotal/NA 4 mL 4 mL

RAPID-TInstrument ID:

Prep 9010C 393198 03/27/22 14:45 CMR TAL PITTotal/NA 0.48 g 10 mL

Analysis EPA 9014 1 393399 03/28/22 16:23 CMR TAL PITTotal/NA

SEAL1Instrument ID:

Client Sample ID: #20220185 COMPOSITE D Lab Sample ID: 180-135508-4 Matrix: SedimentDate…