J126039-1 Std_Tal_L4 Final Report_Part8.pdf

PDF 20 MB Posted Apr 12, 2023

Attached to: Maintenance Dredging of New York and New Jersey Harbor – Arthur Kill 50’ Reach, Federal Navigation Project
Solicitation number: W912DS23B0004
Issued by: Department of the Army Corps of Engineers Engineering District New York

About this file

Written by GovTribe AI · Dec 27, 2023

This document outlines a federal contract solicitation for maintenance dredging services. The U.S. Army Corps of Engineers Engineering District New York is seeking a contractor to dredge approximately 125,000 cubic yards of material from the Arthur Kill 50' Reach of the New York and New Jersey Harbor federal navigation project. The dredged material consists primarily of silt and clay and must be mechanically dredged, transported via barge, dewatered, processed, and placed at a contractor-provided upland site meeting all necessary permit requirements. Bidders must be prepared to commence work within five days of notice and maintain a production rate of at least 2,500 cubic yards per day to minimize channel closure impacts. The solicitation period closes in June/July 2023, with work expected to take place from August to October 2023 at an estimated cost between $10,000,000 to $25,000,000. Liquidated damages of $2,540 per day will be assessed for delays in contract completion.

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Other files

File	Type	Posted
Bid Abstract - W912DS23B0004.pdf	PDF	Jun 6, 2023
AK50_23-B-0004_Contract Volume Breakdown.pdf	PDF	Jun 1, 2023
W912DS23B0004-0006.pdf	PDF	Jun 1, 2023
AK50 5.23.2023 - FY23 Plans_AllSheets.pdf	PDF	May 30, 2023
W912DS23B0004-Amendment 0005.pdf	PDF	May 30, 2023
AK50 5.23.2023 - FY23 Tech Specs.pdf	PDF	May 30, 2023
W912DS23B0004-Amendment 0004.pdf	PDF	May 18, 2023
W912DS23B0004-Amendment 0003.pdf	PDF	May 3, 2023
Arthur Kill 50-foot Channel Upland Final Report Tables.pdf	PDF	Apr 21, 2023
AK50 ASI Upland Report.pdf	PDF	Apr 21, 2023
Arthur Kill 50-foot Channel Upland Final Report Tables.xlsx	XLSX spreadsheet	Apr 21, 2023
W912DS23B0004 - Amendment 0002.pdf	PDF	Apr 21, 2023
J126039-1 Std_Tal_L4 Final Report_Part5.pdf	PDF	Apr 12, 2023
W912DS23B0004 - Amendment 0001.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part6.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part3.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part7.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part2.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part1.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part4.pdf	PDF	Apr 12, 2023
W912DS23B0004.pdf	PDF	Apr 7, 2023
NYSDEC WQC No. 2-6500-00053-00001 w 2023 Conditions.pdf	PDF	Apr 7, 2023
AK50 FY23 Plans-5242-Final.pdf	PDF	Apr 7, 2023
AK50 Tech Specs 13MARCH2023 - Final.pdf	PDF	Apr 7, 2023
NJDEP FCD-WQC No. 0000-03-0035.1 CDT230001.pdf	PDF	Apr 7, 2023

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Report Date: 03-May-2019 13:48:21 Chrom Revision: 2.3 18-Apr-2019 13:31:50 Manual Integration/User Assign Peak Report

Eurofins TestAmerica, Knoxville Data File: \\chromna\Knoxville\ChromData\D12C\20190502-11646.b\icl5_190503061437.d Injection Date: 03-May-2019 06:14:00 Instrument ID: D12C Lims ID: IC L5 Client ID:

Operator ID: Xcalibur_System ALS Bottle#: 0 Worklist Smp#: 12 Injection Vol: 1.0 ul Dil. Factor: 1.0000 Method: TCDD_TCDF_D12C Limit Group: HR - 1613B - ICAL Column: DB225 ( 0.32 mm) Detector F1(8.07 :27.50 )

2,3,7,8-TCDF, CAS: 51207-31-9

Signal: 2

Processing Integration Results

RT: 21.31

Area: 147355 Amount: 1.991937 Amount Units: pg/ul

20.9 21.5 22.1 22.7 23.3 23.9 24.5 Min

Y (X

F1:m/z 305.8987

Manual Integration Results

RT: 24.31

Area: 16739996 Amount: 188.9962 Amount Units: pg/ul

20.9 21.5 22.1 22.7 23.3 23.9 24.5 Min

Y (X

F1:m/z 305.8987

Reviewer: reynoldk, 03-May-2019 09:34:10 Audit Action: Split an Integrated Peak Audit Reason: Split Peak

Report Date: 03-May-2019 13:48:21 Chrom Revision: 2.3 18-Apr-2019 13:31:50

Eurofins TestAmerica, Knoxville Data File: \\chromna\Knoxville\ChromData\D12C\20190502-11646.b\icl5_190503061437.d Injection Date: 03-May-2019 06:14:00 Instrument ID: D12C Lims ID: IC L5 Client ID:

13C-2,3,7,8-TCDF, CAS: 89059-46-1

Signal: 1

Processing Integration Results Not Detected Expected RT: 24.31

23.8 24.0 24.2 24.4 24.6 24.8 Min

Y (X

F1:m/z 315.9419

Manual Integration Results

RT: 24.27

Area: 6432836 Amount: 99.097972 Amount Units: pg/ul

23.8 24.0 24.2 24.4 24.6 24.8 Min

Y (X

F1:m/z 315.9419

Reviewer: reynoldk, 03-May-2019 09:16:47 Audit Action: Assigned Compound ID Audit Reason: Peak assignment corrected

FORM VI

Lab Name: Job No.:

Calibration ID:

SDG No.:

Instrument ID: GC Column: Heated Purge: (Y/N)

DIOXIN BY ISOTOPIC DILUTION - INITIAL CALIBRATION DATA

Eurofins TestAmerica, Knoxville 180-126039-1

D3A

Analy Batch No.: 44574

2767Calibration Start Date: Calibration End Date:11/18/2020 11:32

11/18/2020 15:41

0.32(mm)RTX-5 ID:

CURVE EVALUATION

Calibration Files

LEVEL: LAB SAMPLE ID: LAB FILE ID:

1Level IC 140-44574/2 icl1.d 2Level IC 140-44574/3 icl2.d 3Level IC 140-44574/4 icl3.d 4Level IC 140-44574/5 icl4.d 5Level IC 140-44574/6 icl5.d

ANALYTE RRF

LVL 1 LVL 2 LVL 3 LVL 4 LVL 5

CURVE

TYPE

COEFFICIENT

B M1 M2

# %RSD # MAX

%RSD

R^2

OR COD

# MIN R^2

OR COD

MIN RRF

2,3,7,8-TCDF 1.2685 1.1968 1.1536 1.1437 1.1511 AveID 4.4 20.01.1827

2,3,7,8-TCDD 1.1884 1.1580 1.1627 1.1651 1.1943 AveID 1.4 20.01.1737

1,2,3,7,8-PeCDF 1.0450 1.0817 1.0664 1.0766 1.0609 AveID 1.3 20.01.0661

2,3,4,7,8-PeCDF 1.1247 1.1184 1.0889 1.0694 1.0582 AveID 2.7 20.01.0919

1,2,3,7,8-PeCDD 1.0604 1.0761 1.0504 1.0428 1.0316 AveID 1.6 20.01.0523

1,2,3,4,7,8-HxCDF 1.4198 1.3903 1.4166 1.3626 1.3949 AveID 1.7 20.01.3968

1,2,3,6,7,8-HxCDF 1.2773 1.3073 1.2757 1.2111 1.2680 AveID 2.8 20.01.2679

2,3,4,6,7,8-HxCDF 1.2888 1.2957 1.2502 1.2441 1.2619 AveID 1.8 20.01.2681

1,2,3,4,7,8-HxCDD 1.1216 1.1261 1.1120 1.1252 1.0596 AveID 2.5 20.01.1089

1,2,3,6,7,8-HxCDD 1.1791 1.1249 1.1384 1.1694 1.1503 AveID 1.9 20.01.1524

1,2,3,7,8,9-HxCDD 1.2068 1.2187 1.1864 1.1921 1.1606 AveID 1.8 35.01.1929

1,2,3,7,8,9-HxCDF 1.2744 1.2915 1.2864 1.2612 1.2324 AveID 1.9 20.01.2692

1,2,3,4,6,7,8-HpCDF 1.5043 1.5025 1.4871 1.4492 1.4367 AveID 2.1 20.01.4760

1,2,3,4,6,7,8-HpCDD 1.0105 1.1047 1.0723 1.0869 1.0532 AveID 3.4 20.01.0655

1,2,3,4,7,8,9-HpCDF 1.4634 1.4618 1.4531 1.4404 1.4139 AveID 1.4 20.01.4465

OCDD 1.3143 1.1851 1.1517 1.1389 1.1234 AveID 6.5 20.01.1827

OCDF 1.0175 0.9816 0.9821 0.9484 0.9795 AveID 2.5 35.00.9818

13C-2,3,7,8-TCDF 1.7757 1.8103 1.7963 1.9074 1.8801 Ave 3.1 35.01.8340

13C-2,3,7,8-TCDD 1.0728 1.1026 1.0864 1.1151 1.1492 Ave 2.7 35.01.1052

13C-1,2,3,7,8-PeCDF 1.3074 1.2998 1.3125 1.4536 1.5934 Ave 9.2 35.01.3933

13C-2,3,4,7,8-PeCDF 1.3017 1.3202 1.2890 1.3316 1.5686 Ave 8.6 35.01.3622

13C-1,2,3,7,8-PeCDD 0.8067 0.8149 0.8005 0.8259 0.9865 Ave 9.3 35.00.8469

13C-1,2,3,4,7,8-HxCDF 1.1960 1.2072 1.1855 1.1895 1.1088 Ave 3.3 35.01.1774

13C-1,2,3,6,7,8-HxCDF 1.4776 1.4526 1.5101 1.5269 1.3560 Ave 4.6 35.01.4646

13C-2,3,4,6,7,8-HxCDF 1.4491 1.3670 1.4130 1.3695 1.3697 Ave 2.6 35.01.3937

13C-1,2,3,4,7,8-HxCDD 0.9016 0.8768 0.8656 0.8747 0.9021 Ave 1.9 35.00.8842

13C-1,2,3,6,7,8-HxCDD 0.9067 0.9015 0.9243 0.9053 0.8873 Ave 1.5 35.00.9050

13C-1,2,3,7,8,9-HxCDF 1.2373 1.2554 1.2450 1.2405 1.1495 Ave 3.5 35.01.2255

FORM VI 1613B

Note: The M1 coefficient is the same as Ave RRF for an Ave curve type.

Calibration ID:

SDG No.:

Instrument ID: GC Column: Heated Purge: (Y/N)

DIOXIN BY ISOTOPIC DILUTION - INITIAL CALIBRATION DATA

Eurofins TestAmerica, Knoxville 180-126039-1

D3A

Analy Batch No.: 44574

2767Calibration Start Date: Calibration End Date:11/18/2020 11:32

11/18/2020 15:41

0.32(mm)RTX-5 ID:

CURVE EVALUATION

ANALYTE RRF

LVL 1 LVL 2 LVL 3 LVL 4 LVL 5

CURVE

TYPE

COEFFICIENT

B M1 M2

# %RSD # MAX

%RSD

R^2

OR COD

# MIN R^2

OR COD

MIN RRF

13C-1,2,3,4,6,7,8-HpCDF 1.0325 0.9926 1.0372 1.0452 0.9286 Ave 4.8 35.01.0072

13C-1,2,3,4,6,7,8-HpCDD 0.7725 0.7722 0.7574 0.7863 0.6991 Ave 4.5 35.00.7575

13C-1,2,3,4,7,8,9-HpCDF 0.8607 0.8468 0.8593 0.8860 0.8010 Ave 3.7 35.00.8508

13C-OCDD 0.6082 0.5648 0.5660 0.6137 0.6275 Ave 4.8 35.00.5960

13C-OCDF 1.0530 1.0176 1.0115 1.2030 1.1012 Ave 7.3 35.01.0773

37Cl4-2,3,7,8-TCDD 1.3515 1.3022 1.2686 1.3072 1.3691 Ave 3.11.3197

FORM VI 1613B

Note: The M1 coefficient is the same as Ave RRF for an Ave curve type.

Calibration ID:

SDG No.:

Instrument ID: Heated Purge: (Y/N)

DIOXIN BY ISOTOPIC DILUTION - INITIAL CALIBRATION DATA

Eurofins TestAmerica, Knoxville 180-126039-1

D3A

Analy Batch No.: 44574

2767Calibration Start Date: Calibration End Date:11/18/2020 11:32

11/18/2020 15:41

GC Column: RTX-5 ID: 0.32(mm)

RESPONSE AND CONCENTRATION

Calibration Files

LEVEL: LAB SAMPLE ID: LAB FILE ID:

Level 1 IC 140-44574/2 icl1.d

Level 2 IC 140-44574/3 icl2.d

Level 3 IC 140-44574/4 icl3.d

Level 4 IC 140-44574/5 icl4.d

Level 5 IC 140-44574/6 icl5.d

ANALYTE CURVE

TYPE

REF

RESPONSE

LVL 1 LVL 2 LVL 3 LVL 4 LVL 5

CONCENTRATION (PG/UL)

LVL 1 LVL 2 LVL 3 LVL 4 LVL 5

2,3,7,8-TCDF AveI

41430 156570 753592 3120759 15131665 0.500 2.00 10.0 40.0 200

2,3,7,8-TCDD AveI

23451 92268 459362 1858521 9596494 0.500 2.00 10.0 40.0 200

1,2,3,7,8-PeCDF AveI

125646 508052 2544704 11192972 59098669 2.50 10.0 50.0 200 1000

2,3,4,7,8-PeCDF AveI

134646 533507 2552128 10185215 58031793 2.50 10.0 50.0 200 1000

1,2,3,7,8-PeCDD AveI

78672 316828 1528917 6160558 35578785 2.50 10.0 50.0 200 1000

1,2,3,4,7,8-HxCDF AveI

151278 593339 2962719 11715265 73169659 2.50 10.0 50.0 200 1000

1,2,3,6,7,8-HxCDF AveI

168134 671394 3398491 13366908 81343714 2.50 10.0 50.0 200 1000

2,3,4,6,7,8-HxCDF AveI

166370 626195 3116603 12314615 81771879 2.50 10.0 50.0 200 1000

1,2,3,4,7,8-HxCDD AveI

90086 349068 1698197 7113342 45219935 2.50 10.0 50.0 200 1000

1,2,3,6,7,8-HxCDD AveI

95243 358531 1856246 7651819 48289113 2.50 10.0 50.0 200 1000

1,2,3,7,8,9-HxCDD AveI

97206 383104 1873237 7668324 49123383 2.50 10.0 50.0 200 1000

1,2,3,7,8,9-HxCDF AveI

140474 573226 2825454 11308973 67019860 2.50 10.0 50.0 200 1000

1,2,3,4,6,7,8-HpCDF AveI

138369 527245 2721119 10948164 63122040 2.50 10.0 50.0 200 1000

1,2,3,4,6,7,8-HpCDD AveI

69543 301563 1432725 6177057 34832315 2.50 10.0 50.0 200 1000

FORM VI 1613B Page 7596 of 9555

Calibration ID:

SDG No.:

Instrument ID: Heated Purge: (Y/N)

DIOXIN BY ISOTOPIC DILUTION - INITIAL CALIBRATION DATA

Eurofins TestAmerica, Knoxville 180-126039-1

D3A

Analy Batch No.: 44574

2767Calibration Start Date: Calibration End Date:11/18/2020 11:32

11/18/2020 15:41

GC Column: RTX-5 ID: 0.32(mm)

RESPONSE AND CONCENTRATION

ANALYTE CURVE

TYPE

REF

RESPONSE

LVL 1 LVL 2 LVL 3 LVL 4 LVL 5

CONCENTRATION (PG/UL)

LVL 1 LVL 2 LVL 3 LVL 4 LVL 5

1,2,3,4,7,8,9-HpCDF AveI

112216 437591 2202705 9224286 53582678 2.50 10.0 50.0 200 1000

OCDD AveI

142419 473305 2299807 10104800 66700942 5.00 20.0 100 400 2000

OCDF AveI

190902 706289 3504982 16494490 102053482 5.00 20.0 100 400 2000

13C-2,3,7,8-TCDF Ave13CT

CDD

6532246 6541186 6532260 6821549 6572848 100 100 100 100 100

13C-2,3,7,8-TCDD Ave13CT

CDD

3946556 3984079 3950690 3987929 4017665 100 100 100 100 100

13C-1,2,3,7,8-PeCDF Ave13CT

CDD

4809632 4696709 4772690 5198450 5570548 100 100 100 100 100

13C-2,3,4,7,8-PeCDF Ave13CT

CDD

4788659 4770379 4687550 4762316 5483964 100 100 100 100 100

13C-1,2,3,7,8-PeCDD Ave13CT

CDD

2967746 2944345 2910987 2953820 3448835 100 100 100 100 100

13C-1,2,3,4,7,8-HxCDF Ave13CH xCD

4261815 4267844 4182755 4298882 5245517 100 100 100 100 100

13C-1,2,3,6,7,8-HxCDF Ave13CH xCD

5265387 5135667 5328226 5518294 6415166 100 100 100 100 100

13C-2,3,4,6,7,8-HxCDF Ave13CH xCD

5163740 4832851 4985593 4949371 6480093 100 100 100 100 100

13C-1,2,3,4,7,8-HxCDD Ave13CH xCD

3212833 3099870 3054281 3161063 4267628 100 100 100 100 100

13C-1,2,3,6,7,8-HxCDD Ave13CH xCD

3230964 3187212 3261282 3271765 4197811 100 100 100 100 100

13C-1,2,3,7,8,9-HxCDF Ave13CH xCD

4408934 4438465 4392849 4483260 5438189 100 100 100 100 100

13C-1,2,3,4,6,7,8-HpCDF Ave13CH xCD

3679341 3509143 3659576 3777363 4393414 100 100 100 100 100

13C-1,2,3,4,6,7,8-HpCDD Ave13CH xCD

2752840 2729931 2672222 2841703 3307356 100 100 100 100 100

13C-1,2,3,4,7,8,9-HpCDF Ave13CH xCD

3067207 2993604 3031771 3201999 3789650 100 100 100 100 100

13C-OCDD Ave13CH xCD

4334357 3993723 3993880 4436220 5937596 200 200 200 200 200

FORM VI 1613B Page 7597 of 9555

Calibration ID:

SDG No.:

Instrument ID: Heated Purge: (Y/N)

DIOXIN BY ISOTOPIC DILUTION - INITIAL CALIBRATION DATA

Eurofins TestAmerica, Knoxville 180-126039-1

D3A

Analy Batch No.: 44574

2767Calibration Start Date: Calibration End Date:11/18/2020 11:32

11/18/2020 15:41

GC Column: RTX-5 ID: 0.32(mm)

RESPONSE AND CONCENTRATION

ANALYTE CURVE

TYPE

REF

RESPONSE

LVL 1 LVL 2 LVL 3 LVL 4 LVL 5

CONCENTRATION (PG/UL)

LVL 1 LVL 2 LVL 3 LVL 4 LVL 5

13C-OCDF Ave13CH xCD

7504901 7195108 7137665 8695807 10419168 200 200 200 200 200

37Cl4-2,3,7,8-TCDD Ave13CT

CDD

24858 94106 461311 1870061 9572781 0.500 2.00 10.0 40.0 200

Curve Type Legend Ave = Average ISTD AveID = Average isotope dilution

FORM VI 1613B Page 7598 of 9555

Report Date: 19-Nov-2020 08:14:10 Chrom Revision: 2.3 12-Nov-2020 21:52:08

Eurofins TestAmerica, Knoxville Target Compound Quantitation Report

Data File: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\icl1.d Lims ID: IC L1 Client ID:

Sample Type: IC Calib Level: 1 Inject. Date: 18-Nov-2020 11:32:00 ALS Bottle#: 0 Worklist Smp#: 2 Injection Vol: 1.0 ul Dil. Factor: 1.0000 Sample Info:

Misc. Info.: 140-0017337-002 Operator ID: Xcalibur_System Instrument ID: D3A Sublist: chrom-D3A_Dioxin*sub1

Method: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\D3A_Dioxin.m Limit Group: HR - 1613B - ICAL Last Update: 19-Nov-2020 08:14:10 Calib Date: 18-Nov-2020 15:41:00 Integrator: Picker Quant Method: Isotopic Dilution Quant By: Initial Calibration Last ICal File: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\icl5.d

Column 1 : Det: F1(12.07 :34.29 ) Process Host: CTX1622

First Level Reviewer: layk Date: 18-Nov-2020 12:35:02

Compound

(min.) Area Ratio Ical

RRF

Amount pg/ul

EMPC

pg/ul

Noise

EDL

Final EDL %Rec Flags

2,3,7,8-TCDD 30:18 23451 0.80 1.1737 0.5063 0.5063 0.0257 0.0257 101

S Total TCDD 0.5063 0.5063 0.0257 0.0257

2,3,7,8-TCDF 28:21 41430 0.73 1.1827 0.5362 0.5362 0.0127 0.0127 107

S Total TCDF 0.5362 0.5362 0.0127 0.0127

1,2,3,7,8-PeCDD 40:25 78672 1.54 1.0523 2.519 2.519 0.008632 0.008632 101 S Total PeCDD 2.519 2.519 0.008632 0.008632

1,2,3,7,8-PeCDF 38:33 125646 1.52 1.0661 2.450 2.450 0.0184 0.0184 98.02 2,3,4,7,8-PeCDF 39:52 134646 1.56 1.0919 2.575 2.575 0.0161 0.0161 103 S Total PeCDF 5.025 5.025 0.0172 0.0172

1,2,3,4,7,8-HxCDD 44:45 90086 1.27 1.1089 2.529 2.529 0.0148 0.0148 101 1,2,3,6,7,8-HxCDD 44:52 95243 1.21 1.1524 2.558 2.558 0.0146 0.0146 102 1,2,3,7,8,9-HxCDD 45:16 97206 1.23 1.1929 2.529 2.529 0.0139 0.0139 101 S Total HxCDD 7.616 7.616 0.0145 0.0145

1,2,3,4,7,8-HxCDF 43:43 151278 1.23 1.3968 2.541 2.541 0.0222 0.0222 102 1,2,3,6,7,8-HxCDF 43:52 168134 1.26 1.2679 2.519 2.519 0.0207 0.0207 101 2,3,4,6,7,8-HxCDF 44:35 166370 1.29 1.2681 2.541 2.541 0.0207 0.0207 102 1,2,3,7,8,9-HxCDF 45:31 140474 1.23 1.2692 2.510 2.510 0.0276 0.0276 100 S Total HxCDF 10.1 10.1 0.0228 0.0228

1,2,3,4,6,7,8-HpCDD 49:33 69543 1.02 1.0655 2.371 2.371 0.0179 0.0179 94.84 S Total HpCDD 2.371 2.371 0.0179 0.0179

1,2,3,4,6,7,8-HpCDF 47:53 138369 1.02 1.4760 2.548 2.548 0.0115 0.0115 102 1,2,3,4,7,8,9-HpCDF 50:11 112216 1.15 1.4465 2.529 2.529 0.0165 0.0165 101 S Total HpCDF 5.077 5.077 0.0140 0.0140

OCDD 53:51 142419 0.93 1.1827 5.557 5.557 0.006287 0.006287 111

OCDF 54:00 190902 0.90 0.9818 5.182 5.182 0.004985 0.004985 104

D 13C-2,3,7,8-TCDD 30:15 3946556 0.78 1.1052 97.1 97.1 0.2787 0.2787 97.07

D 13C-2,3,7,8-TCDF 28:20 6532246 0.79 1.8340 96.8 96.8 0.1913 0.1913 96.82

D 13C-1,2,3,7,8-PeCDD 40:24 2967746 1.59 0.8469 95.3 95.3 0.5389 0.5389 95.26 D 13C-1,2,3,7,8-PeCDF 38:32 4809632 1.59 1.3933 93.8 93.8 1.232 1.232 93.83

Data File: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\icl1.d

Compound

(min.) Area Ratio Ical

RRF

Amount pg/ul

EMPC

pg/ul

Noise

EDL

Final EDL %Rec Flags

D 13C-2,3,4,7,8-PeCDF 39:50 4788659 1.60 1.3622 95.6 95.6 1.260 1.260 95.56 D 13C-1,2,3,4,7,8-HxCDD 44:44 3212833 1.29 0.8842 102.0 102.0 0.2203 0.2203 102 D 13C-1,2,3,6,7,8-HxCDD 44:51 3230964 1.26 0.9050 100.2 100.2 0.2152 0.2152 100 D 13C-1,2,3,4,7,8-HxCDF 43:42 4261815 0.55 1.1774 101.6 101.6 0.3622 0.3622 102 D 13C-1,2,3,6,7,8-HxCDF 43:51 5265387 0.53 1.4646 100.9 100.9 0.2912 0.2912 101 D 13C-2,3,4,6,7,8-HxCDF 44:34 5163740 0.55 1.3937 104.0 104.0 0.3060 0.3060 104 D 13C-1,2,3,7,8,9-HxCDF 45:30 4408934 0.53 1.2255 101.0 101.0 0.3480 0.3480 101 D 13C-1,2,3,4,6,7,8-HpCDD 49:31 2752840 1.03 0.7575 102.0 102.0 0.0649 0.0649 102 D 13C-1,2,3,4,6,7,8-HpCDF 47:52 3679341 0.46 1.0072 102.5 102.5 0.3417 0.3417 103 D 13C-1,2,3,4,7,8,9-HpCDF 50:10 3067207 0.46 0.8508 101.2 101.2 0.4046 0.4046 101

D 13C-OCDD 53:50 4334357 0.91 0.5960 204.1 204.1 0.3874 0.3874 102

D 13C-OCDF 53:59 7504901 0.88 1.0773 195.5 195.5 0.1810 0.1810 97.75

$ 37Cl4-2,3,7,8-TCDD 30:19 24858 1.3197 0.5120 0.5120 0.0113 0.0113 102

* 13C-1,2,3,4-TCDD 29:47 3678710 0.80 3.6E+04 100.0 100.0

* 13C-1,2,3,7,8,9-HxCDD 45:15 3563467 1.27 3.8E+04 100.0 100.0

QC Flag Legend Processing Flags Reagents:

61L11613OP_00005 Amount Added: 20.00 Units: uL

Target Compound Quantitation Worksheet Report

Data File: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\icl1.d Lims ID: IC L1 Client ID:

Sample Type: IC Calib Level: 1 Inject. Date: 18-Nov-2020 11:32:00 ALS Bottle#: 0 Worklist Smp#: 2 Injection Vol: 1.0 ul Dil. Factor: 1.0000 Sample Info:

Misc. Info.: 140-0017337-002 Operator ID: Xcalibur_System Instrument ID: D3A Sublist: chrom-D3A_Dioxin*sub1

Column 1 : Det: F1(12.07 :34.29 ) Process Host: CTX1622

First Level Reviewer: layk Date: 18-Nov-2020 12:35:02

Signal

(min.)

Adj RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

2,3,7,8-TCDD

319.8965 30:18 30:20 -1 1.002 10390 1020 30 75 34

321.8936 30:19 30:20 0 1.002 13061 1339 22 55 61 0.80(0.65-0.89)

2,3,7,8-TCDF

303.9016 28:21 28:23 -2 1.001 17525 2107 15 37 140

305.8987 28:21 28:23 -2 1.001 23905 2806 31 77 91 0.73(0.65-0.89)

1,2,3,7,8-PeCDD

355.8546 40:25 40:26 -1 1.000 47726 11210 11 27 1019

357.8516 40:25 40:26 -1 1.000 30946 7244 14 35 517 1.54(1.32-1.78)

1,2,3,7,8-PeCDF

339.8597 38:33 38:35 -1 1.000 75727 15274 22 55 694

341.8567 38:33 38:35 -1 1.000 49919 9281 51 127 182 1.52(1.32-1.78)

2,3,4,7,8-PeCDF

339.8597 39:52 39:52 0 1.001 82105 17784 22 55 808

341.8567 39:51 39:52 -1 1.000 52541 11984 51 127 235 1.56(1.32-1.78)

1,2,3,4,7,8-HxCDD

389.8158 44:45 44:47 -1 1.000 50368 13101 25 62 524

391.8127 44:45 44:47 -1 1.000 39718 10614 29 72 366 1.27(1.05-1.43)

1,2,3,6,7,8-HxCDD

389.8158 44:52 44:54 -1 1.000 52235 12964 25 62 519

391.8127 44:52 44:54 -1 1.000 43008 10478 29 72 361 1.21(1.05-1.43)

1,2,3,7,8,9-HxCDD

389.8158 45:16 45:16 0 1.012 53645 13368 25 62 535

391.8127 45:16 45:16 0 1.012 43561 10220 29 72 352 1.23(1.05-1.43)

Signal

(min.)

Adj RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

1,2,3,4,7,8-HxCDF

373.8208 43:43 43:45 -1 1.000 83435 22439 56 140 401

375.8178 43:43 43:45 -1 1.000 67843 18025 87 217 207 1.23(1.05-1.43)

1,2,3,6,7,8-HxCDF

373.8208 43:52 43:53 -1 1.000 93586 24609 56 140 439

375.8178 43:52 43:53 -1 1.000 74548 20797 87 217 239 1.26(1.05-1.43)

2,3,4,6,7,8-HxCDF

373.8208 44:35 44:35 0 1.000 93700 25643 56 140 458

375.8178 44:35 44:35 0 1.000 72670 18882 87 217 217 1.29(1.05-1.43)

1,2,3,7,8,9-HxCDF

373.8208 45:31 45:32 -1 1.000 77501 18381 56 140 328

375.8178 45:31 45:32 -1 1.000 62973 15596 87 217 179 1.23(1.05-1.43)

1,2,3,4,6,7,8-HpCDD

423.7767 49:33 49:33 0 1.000 35078 7139 9 22 793

425.7737 49:31 49:33 -1 1.000 34465 6986 31 77 225 1.02(0.88-1.20)

1,2,3,4,6,7,8-HpCDF

407.7817 47:53 47:53 0 1.000 69768 15182 29 72 524

409.7788 47:53 47:53 0 1.000 68601 15118 25 62 605 1.02(0.88-1.20)

1,2,3,4,7,8,9-HpCDF

407.7817 50:11 50:12 -1 1.000 60000 11339 29 72 391

409.7788 50:11 50:12 -1 1.000 52216 10237 25 62 409 1.15(0.88-1.20)

OCDD

457.7377 53:51 53:53 -1 1.000 68604 15501 1 2 15501

459.7348 53:51 53:53 -1 1.000 73815 17322 14 35 1237 0.93(0.76-1.02)

OCDF

441.7428 54:00 54:00 0 1.000 90381 20733 13 32 1595

443.7399 54:00 54:00 0 1.000 100521 25378 4 10 6345 0.90(0.76-1.02)

13C-2,3,7,8-TCDD

331.9368 30:15 30:18 -2 1.016 1732471 190861 305 762 626

333.9338 30:15 30:18 -2 1.016 2214085 239479 191 477 1254 0.78(0.65-0.89)

13C-2,3,7,8-TCDF

315.9419 28:20 28:21 -1 0.951 2891376 335209 236 590 1420

317.9389 28:20 28:21 -1 0.951 3640870 429663 329 822 1306 0.79(0.65-0.89)

13C-1,2,3,7,8-PeCDD

367.8949 40:24 40:25 -1 1.357 1822542 421033 374 935 1126

369.8919 40:24 40:25 -1 1.357 1145204 261591 361 902 725 1.59(1.32-1.78)

13C-1,2,3,7,8-PeCDF

351.9000 38:32 38:33 -1 1.294 2951194 563195 1675 4187 336

353.8970 38:32 38:33 -1 1.294 1858438 365361 1088 2720 336 1.59(1.32-1.78)

13C-2,3,4,7,8-PeCDF

351.9000 39:50 39:51 -1 1.337 2948220 637430 1675 4187 381

353.8970 39:50 39:51 -1 1.337 1840439 399200 1088 2720 367 1.60(1.32-1.78)

13C-1,2,3,4,7,8-HxCDD

401.8559 44:44 44:46 -1 0.989 1806830 455670 409 1022 1114

403.8529 44:44 44:46 -1 0.989 1406003 365245 249 622 1467 1.29(1.05-1.43)

Signal

(min.)

Adj RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

13C-1,2,3,6,7,8-HxCDD

401.8559 44:51 44:53 -1 0.991 1799658 447771 409 1022 1095

403.8529 44:51 44:53 -1 0.991 1431306 354230 249 622 1423 1.26(1.05-1.43)

13C-1,2,3,4,7,8-HxCDF

383.8639 43:42 43:44 -1 0.966 1513659 406739 426 1065 955

385.8610 43:42 43:44 -1 0.966 2748156 743858 1015 2537 733 0.55(0.43-0.59)

13C-1,2,3,6,7,8-HxCDF

383.8639 43:51 43:52 -1 0.969 1830332 472575 426 1065 1109

385.8610 43:51 43:52 -1 0.969 3435055 887226 1015 2537 874 0.53(0.43-0.59)

13C-2,3,4,6,7,8-HxCDF

383.8639 44:34 44:34 0 0.985 1828356 478276 426 1065 1123

385.8610 44:34 44:34 0 0.985 3335384 880245 1015 2537 867 0.55(0.43-0.59)

13C-1,2,3,7,8,9-HxCDF

383.8639 45:30 45:31 -1 1.006 1531594 357147 426 1065 838

385.8610 45:30 45:31 -1 1.006 2877340 663523 1015 2537 654 0.53(0.43-0.59)

13C-1,2,3,4,6,7,8-HpCDD

435.8169 49:31 49:32 0 1.095 1399249 269541 103 257 2617

437.8140 49:31 49:32 0 1.095 1353591 254746 63 157 4044 1.03(0.88-1.20)

13C-1,2,3,4,6,7,8-HpCDF

417.8250 47:52 47:52 0 1.058 1160719 255467 379 947 674

419.8220 47:52 47:52 0 1.058 2518622 541103 784 1960 690 0.46(0.37-0.51)

13C-1,2,3,4,7,8,9-HpCDF

417.8250 50:10 50:11 -1 1.109 961563 172300 379 947 455

419.8220 50:10 50:11 -1 1.109 2105644 394783 784 1960 504 0.46(0.37-0.51)

13C-OCDD

469.7780 53:50 53:52 -1 1.190 2069595 474027 426 1065 1113

471.7750 53:51 53:52 0 1.190 2264762 521169 354 885 1472 0.91(0.76-1.02)

13C-OCDF

453.7830 53:59 54:00 -1 1.193 3518899 810898 271 677 2992

455.7801 53:59 54:00 -1 1.193 3986002 905514 388 970 2334 0.88(0.76-1.02)

37Cl4-2,3,7,8-TCDD

327.8847 30:19 30:21 -1 1.018 24858 2532 24 60 106

13C-1,2,3,4-TCDD

331.9368 29:47 29:49 -2 1631690 176833 305 762 580

333.9338 29:47 29:49 -2 2047020 225685 191 477 1182 0.80(0.65-0.89)

13C-1,2,3,7,8,9-HxCDD

401.8559 45:15 45:15 0 1994311 467963 409 1022 1144

403.8529 45:15 45:15 0 1569156 376618 249 622 1513 1.27(1.05-1.43)

QC Flag Legend Processing Flags Reagents:

61L11613OP_00005 Amount Added: 20.00 Units: uL

Data File: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\icl1.d Injection Date: 18-Nov-2020 11:32:00 Injection Vol: 1.0 ul Instrument ID: D3A Operator ID: Xcalibur_System Method: D3A_Dioxin Limit Group: HR - 1613B - ICAL Client ID:

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

TCDD

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 319.8965

F 2,3,7,8-TCDD

30.30

28.36

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 321.8936

F 2,3,7,8-TCDD

30.31

TCDD Standards

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 331.9368

13C-2,3,7,8-TCDD

30.2513C-1,2,3,4-TCDD

29.77

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 333.9338

13C-2,3,7,8-TCDD

30.2513C-1,2,3,4-TCDD

29.77

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

TCDD

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 319.8965

F 2,3,7,8-TCDD

30.30

28.36

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 321.8936

F 2,3,7,8-TCDD

30.31

TCDD Lock Mass

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

F1:m/z 313.9834

Report Date: 19-Nov-2020 08:14:11 Chrom Revision: 2.3 12-Nov-2020 21:52:08

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

37Cl4-TCDD

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 327.8847

37Cl4-2,3,7,8-TCDD 30.31

27.9726.3724.4325.0913.84 30.1120.2717.61 30.87

37Cl4-TCDD Standards

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 331.9368

13C-2,3,7,8-TCDD

30.2513C-1,2,3,4-TCDD

29.77

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 333.9338

13C-2,3,7,8-TCDD

30.2513C-1,2,3,4-TCDD

29.77

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

37Cl4-TCDD

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 327.8847

37Cl4-2,3,7,8-TCDD 30.31

27.9726.3724.4325.0913.84 30.1120.2717.61 30.87

37Cl4-TCDD Lock Mass

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

TCDF

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 303.9016

F 2,3,7,8-TCDF

28.34

20.0917.54 33.1825.80 27.75 32.8315.30 19.85 24.75 28.09 30.35

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 305.8987

F 2,3,7,8-TCDF

28.34

25.38 27.1519.38

TCDF Standards

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 315.9419

13C-2,3,7,8-TCDF

28.33

28.6327.28

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 317.9389

13C-2,3,7,8-TCDF

28.33

27.28 28.88

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

TCDF

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 303.9016

F 2,3,7,8-TCDF

28.34

20.0917.54 33.1825.80 27.75 32.8315.30 19.85 24.75 28.09 30.35

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 305.8987

F 2,3,7,8-TCDF

28.34

25.38 27.1519.38

TCDF Lock Mass

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

TCDF

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 303.9016

F 2,3,7,8-TCDF

28.34

20.0917.54 33.1825.80 27.75 32.8315.30 19.85 24.75 28.09 30.35

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 305.8987

F 2,3,7,8-TCDF

28.34

25.38 27.1519.38

TCDF Interference Mass

12.0 14.0 16.0 18.0 20.0 22.0 24.0 26.0 28.0 30.0 32.0 34.0 Min

Y ( X

F1:m/z 375.8364 31.33

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

PeCDD

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 355.8546

F 1,2,3,7,8-PeCDD 40.41

38.53 39.82Non-2,3,7,8-sub-PeCDD 41.1035.60

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 357.8516

F 1,2,3,7,8-PeCDD 40.41

Non-2,3,7,8-sub-PeCDD 41.1234.92

PeCDD Standards

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 367.8949

13C-1,2,3,7,8-PeCDD 40.39

38.94

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 369.8919

13C-1,2,3,7,8-PeCDD 40.39

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

PeCDD

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 355.8546

F 1,2,3,7,8-PeCDD 40.41

38.53 39.82Non-2,3,7,8-sub-PeCDD 41.1035.60

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 357.8516

F 1,2,3,7,8-PeCDD 40.41

Non-2,3,7,8-sub-PeCDD 41.1234.92

PeCDD Lock Mass

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

F2:m/z 313.9834

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

PeCDF

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 339.8597

L 2,3,4,7,8-PeCDF 39.86F 1,2,3,7,8-PeCDF

38.55

39.1038.05 38.91

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 341.8567

L 2,3,4,7,8-PeCDF 39.84

F 1,2,3,7,8-PeCDF 38.55

PeCDF Standards

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 351.9000

13C-2,3,4,7,8-PeCDF 39.8213C-1,2,3,7,8-PeCDF

38.53

41.20

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 353.8970

13C-2,3,4,7,8-PeCDF 39.8213C-1,2,3,7,8-PeCDF

38.53

41.20

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

PeCDF

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 339.8597

L 2,3,4,7,8-PeCDF 39.86

F 1,2,3,7,8-PeCDF 38.55

39.1038.05 38.91

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 341.8567

L 2,3,4,7,8-PeCDF 39.84

F 1,2,3,7,8-PeCDF 38.55

PeCDF Lock Mass

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

PeCDF

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 339.8597

L 2,3,4,7,8-PeCDF 39.86

F 1,2,3,7,8-PeCDF 38.55

39.1038.05 38.91

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 341.8567

L 2,3,4,7,8-PeCDF 39.84

F 1,2,3,7,8-PeCDF 38.55

PeCDF Interference Mass

34.1 34.8 35.5 36.2 36.9 37.6 38.3 39.0 39.7 40.4 41.1 41.8 Min

Y ( X

F2:m/z 409.7974 40.44

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

HxCDD

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 389.8158

L 1,2,3,7,8,9-HxCDD 45.25

F 1,2,3,4,7,8-HxCDD 44.75

44.56 45.5343.82

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 391.8127

F 1,2,3,4,7,8-HxCDD 44.75

L 1,2,3,7,8,9-HxCDD 45.25

45.46

HxCDD Standards

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 401.8559

13C-1,2,3,7,8,9-HxCDD 45.24

13C-1,2,3,4,7,8-HxCDD 44.73

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 403.8529

13C-1,2,3,7,8,9-HxCDD 45.24

13C-1,2,3,4,7,8-HxCDD 44.73

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

HxCDD

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 389.8158

L 1,2,3,7,8,9-HxCDD 45.25

F 1,2,3,4,7,8-HxCDD 44.75

44.56 45.5343.82

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 391.8127

F 1,2,3,4,7,8-HxCDD

44.75 L 1,2,3,7,8,9-HxCDD

45.25

45.46

HxCDD Lock Mass

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

F3:m/z 375.9802

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

HxCDF

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 373.8208 2,3,4,6,7,8-HxCDF 44.58

F 1,2,3,4,7,8-HxCDF 43.72

L 1,2,3,7,8,9-HxCDF 45.51

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 375.8178

2,3,4,6,7,8-HxCDF 44.58F 1,2,3,4,7,8-HxCDF

43.72 L 1,2,3,7,8,9-HxCDF

45.51

HxCDF Standards

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 383.8639 13C-2,3,4,6,7,8-HxCDF 44.56

13C-1,2,3,4,7,8-HxCDF

43.70 13C-1,2,3,7,8,9-HxCDF

45.49

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 385.8610 13C-2,3,4,6,7,8-HxCDF 44.56

13C-1,2,3,4,7,8-HxCDF

43.70 13C-1,2,3,7,8,9-HxCDF

45.49

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

HxCDF

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 373.8208

2,3,4,6,7,8-HxCDF 44.58

F 1,2,3,4,7,8-HxCDF 43.72

L 1,2,3,7,8,9-HxCDF 45.51

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 375.8178

2,3,4,6,7,8-HxCDF 44.58F 1,2,3,4,7,8-HxCDF

43.72 L 1,2,3,7,8,9-HxCDF 45.51

HxCDF Lock Mass

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

HxCDF

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 373.8208

2,3,4,6,7,8-HxCDF 44.58

F 1,2,3,4,7,8-HxCDF 43.72

L 1,2,3,7,8,9-HxCDF 45.51

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

Y ( X

F3:m/z 375.8178

2,3,4,6,7,8-HxCDF 44.58F 1,2,3,4,7,8-HxCDF

43.72 L 1,2,3,7,8,9-HxCDF 45.51

HxCDF Interference Mass

41.8 42.3 42.8 43.3 43.8 44.3 44.8 45.3 45.8 46.3 46.8 Min

F3:m/z 445.7555

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

HpCDD

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 423.7767

L 1,2,3,4,6,7,8-HpCDD 49.53

Non-2,3,7,8-sub-HpCDD

48.35 49.65 50.1949.87 51.76

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 425.7737

L 1,2,3,4,6,7,8-HpCDD 49.52

Non-2,3,7,8-sub-HpCDD

48.38 50.1649.79

HpCDD Standards

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 435.8169

13C-1,2,3,4,6,7,8-HpCDD 49.52

48.35 49.89 51.9051.6051.27

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 437.8140

13C-1,2,3,4,6,7,8-HpCDD 49.52

48.33 50.14 51.5451.7550.31

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

HpCDD

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 423.7767

L 1,2,3,4,6,7,8-HpCDD 49.53

Non-2,3,7,8-sub-HpCDD

48.35 49.65 50.1949.87 51.76

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 425.7737

L 1,2,3,4,6,7,8-HpCDD 49.52

Non-2,3,7,8-sub-HpCDD

48.38 50.1649.79

HpCDD Lock Mass

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

F4:m/z 413.9770

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

HpCDF

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 407.7817

F 1,2,3,4,6,7,8-HpCDF 47.88

L 1,2,3,4,7,8,9-HpCDF 50.18

Non-2,3,7,8-sub-HpCDF 48.30

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 409.7788

F 1,2,3,4,6,7,8-HpCDF 47.88

L 1,2,3,4,7,8,9-HpCDF 50.18

50.34Non-2,3,7,8-sub-HpCDF 48.28

HpCDF Standards

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 417.8250 13C-1,2,3,4,6,7,8-HpCDF 47.86

13C-1,2,3,4,7,8,9-HpCDF 50.16

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 419.8220 13C-1,2,3,4,6,7,8-HpCDF 47.86

13C-1,2,3,4,7,8,9-HpCDF 50.16

48.22

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

HpCDF

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 407.7817

F 1,2,3,4,6,7,8-HpCDF 47.88

L 1,2,3,4,7,8,9-HpCDF 50.18

Non-2,3,7,8-sub-HpCDF 48.30

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 409.7788

F 1,2,3,4,6,7,8-HpCDF 47.88

L 1,2,3,4,7,8,9-HpCDF 50.18

50.34Non-2,3,7,8-sub-HpCDF 48.28

HpCDF Lock Mass

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

HpCDF

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 407.7817

F 1,2,3,4,6,7,8-HpCDF 47.88

L 1,2,3,4,7,8,9-HpCDF 50.18

Non-2,3,7,8-sub-HpCDF 48.30

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

Y ( X

F4:m/z 409.7788

F 1,2,3,4,6,7,8-HpCDF 47.88

L 1,2,3,4,7,8,9-HpCDF 50.18

50.34Non-2,3,7,8-sub-HpCDF 48.28

HpCDF Interference Mass

46.9 47.4 47.9 48.4 48.9 49.4 49.9 50.4 50.9 51.4 51.9 Min

F4:m/z 479.7165

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

OCDD

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 457.7377

OCDD

53.85

54.14

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 459.7348

OCDD

53.85

OCDD Standards

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 469.7780

13C-OCDD

53.83

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 471.7750

13C-OCDD

53.85

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

OCDD

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 457.7377

OCDD

53.85

54.14

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 459.7348

OCDD

53.85

OCDD Lock Mass

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

F5:m/z 425.9770

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

OCDF

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 441.7428

OCDF

53.99

54.35

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 443.7399

OCDF

53.99

54.31

OCDF Standards

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 453.7830

13C-OCDF

53.97

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 455.7801

13C-OCDF

53.97

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

OCDF

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 441.7428

OCDF

53.99

54.35

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 443.7399

OCDF

53.99

54.31

OCDF Lock Mass

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Worklist#: 44574 Sample Line#: 2 Column Type: Column Dia:

OCDF

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 441.7428

OCDF

53.99

54.35

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 443.7399

OCDF

53.99

54.31

OCDF Interference Mass

52.2 52.6 53.0 53.4 53.8 54.2 54.6 55.0 55.4 55.8 56.2 56.6 57.0 Min

Y ( X

F5:m/z 513.6775

Report Date: 19-Nov-2020 08:14:17 Chrom Revision: 2.3 12-Nov-2020 21:52:08

Target Compound Quantitation Report

Data File: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\icl2.d Lims ID: IC L2 Client ID:

Sample Type: IC Calib Level: 2 Inject. Date: 18-Nov-2020 12:35:00 ALS Bottle#: 0 Worklist Smp#: 3 Injection Vol: 1.0 ul Dil. Factor: 1.0000 Sample Info:

Misc. Info.: 140-0017337-003 Operator ID: Xcalibur_System Instrument ID: D3A Sublist: chrom-D3A_Dioxin*sub1

Method: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\D3A_Dioxin.m Limit Group: HR - 1613B - ICAL Last Update: 19-Nov-2020 08:14:17 Calib Date: 18-Nov-2020 15:41:00 Integrator: Picker Quant Method: Isotopic Dilution Quant By: Initial Calibration Last ICal File: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\icl5.d

Column 1 : Det: F1(12.07 :34.29 ) Process Host: CTX1622

First Level Reviewer: davidsonm Date: 18-Nov-2020 15:16:50

Compound

(min.) Area Ratio Ical

RRF

Amount pg/ul

EMPC

pg/ul

Noise

EDL

Final EDL %Rec Flags

2,3,7,8-TCDD 30:21 92268 0.76 1.1737 1.973 1.973 0.0226 0.0226 98.66 M

S Total TCDD 1.973 1.973 0.0226 0.0226

2,3,7,8-TCDF 28:23 156570 0.75 1.1827 2.024 2.024 0.0151 0.0151 101

S Total TCDF 2.024 2.024 0.0151 0.0151

1,2,3,7,8-PeCDD 40:25 316828 1.61 1.0523 10.2 10.2 0.0154 0.0154 102 S Total PeCDD 10.2 10.2 0.0154 0.0154

1,2,3,7,8-PeCDF 38:34 508052 1.57 1.0661 10.1 10.1 0.0295 0.0295 101 2,3,4,7,8-PeCDF 39:52 533507 1.57 1.0919 10.2 10.2 0.0257 0.0257 102 S Total PeCDF 20.4 20.4 0.0276 0.0276

1,2,3,4,7,8-HxCDD 44:45 349068 1.30 1.1089 10.2 10.2 0.0149 0.0149 102 1,2,3,6,7,8-HxCDD 44:52 358531 1.30 1.1524 9.761 9.761 0.0142 0.0142 97.61 1,2,3,7,8,9-HxCDD 45:16 383104 1.24 1.1929 10.2 10.2 0.0138 0.0138 102 S Total HxCDD 30.1 30.1 0.0143 0.0143

1,2,3,4,7,8-HxCDF 43:43 593339 1.26 1.3968 9.953 9.953 0.0389 0.0389 99.53 1,2,3,6,7,8-HxCDF 43:51 671394 1.23 1.2679 10.3 10.3 0.0364 0.0364 103 2,3,4,6,7,8-HxCDF 44:35 626195 1.26 1.2681 10.2 10.2 0.0385 0.0385 102 1,2,3,7,8,9-HxCDF 45:31 573226 1.23 1.2692 10.2 10.2 0.0471 0.0471 102 S Total HxCDF 40.7 40.7 0.0402 0.0402

1,2,3,4,6,7,8-HpCDD 49:32 301563 1.03 1.0655 10.4 10.4 0.0380 0.0380 104 S Total HpCDD 10.4 10.4 0.0380 0.0380

1,2,3,4,6,7,8-HpCDF 47:53 527245 1.07 1.4760 10.2 10.2 0.0230 0.0230 102 1,2,3,4,7,8,9-HpCDF 50:12 437591 1.08 1.4465 10.1 10.1 0.0326 0.0326 101 S Total HpCDF 20.3 20.3 0.0278 0.0278

OCDD 53:51 473305 0.90 1.1827 20.0 20.0 0.004163 0.004163 100

OCDF 53:59 706289 0.93 0.9818 20.0 20.0 0.003679 0.003679 99.98

D 13C-2,3,7,8-TCDD 30:16 3984079 0.80 1.1052 99.8 99.8 0.2629 0.2629 99.76

D 13C-2,3,7,8-TCDF 28:20 6541186 0.81 1.8340 98.7 98.7 0.1399 0.1399 98.71

D 13C-1,2,3,7,8-PeCDD 40:24 2944345 1.53 0.8469 96.2 96.2 0.5788 0.5788 96.22 D 13C-1,2,3,7,8-PeCDF 38:32 4696709 1.58 1.3933 93.3 93.3 1.277 1.277 93.29

Data File: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\icl2.d

Compound

(min.) Area Ratio Ical

RRF

Amount pg/ul

EMPC

pg/ul

Noise

EDL

Final EDL %Rec Flags

D 13C-2,3,4,7,8-PeCDF 39:51 4770379 1.55 1.3622 96.9 96.9 1.306 1.306 96.92 D 13C-1,2,3,4,7,8-HxCDD 44:44 3099870 1.26 0.8842 99.2 99.2 0.2437 0.2437 99.17 D 13C-1,2,3,6,7,8-HxCDD 44:51 3187212 1.29 0.9050 99.6 99.6 0.2381 0.2381 99.61 D 13C-1,2,3,4,7,8-HxCDF 43:42 4267844 0.54 1.1774 102.5 102.5 0.3683 0.3683 103 D 13C-1,2,3,6,7,8-HxCDF 43:50 5135667 0.54 1.4646 99.2 99.2 0.2961 0.2961 99.18 D 13C-2,3,4,6,7,8-HxCDF 44:34 4832851 0.55 1.3937 98.1 98.1 0.3112 0.3112 98.09 D 13C-1,2,3,7,8,9-HxCDF 45:30 4438465 0.53 1.2255 102.4 102.4 0.3538 0.3538 102 D 13C-1,2,3,4,6,7,8-HpCDD 49:31 2729931 1.08 0.7575 101.9 101.9 0.0408 0.0408 102 D 13C-1,2,3,4,6,7,8-HpCDF 47:52 3509143 0.48 1.0072 98.5 98.5 0.5333 0.5333 98.55 D 13C-1,2,3,4,7,8,9-HpCDF 50:10 2993604 0.46 0.8508 99.5 99.5 0.6314 0.6314 99.53

D 13C-OCDD 53:51 3993723 0.90 0.5960 189.5 189.5 0.4296 0.4296 94.76

D 13C-OCDF 53:59 7195108 0.92 1.0773 188.9 188.9 0.2484 0.2484 94.46

$ 37Cl4-2,3,7,8-TCDD 30:20 94106 1.3197 1.973 1.973 0.0137 0.0137 98.67

* 13C-1,2,3,4-TCDD 29:48 3613278 0.80 3.6E+04 100.0 100.0

* 13C-1,2,3,7,8,9-HxCDD 45:15 3535379 1.25 3.8E+04 100.0 100.0

QC Flag Legend Processing Flags Review Flags M - Manually Integrated Reagents:

61L21613OP_00002 Amount Added: 20.00 Units: uL

Target Compound Quantitation Worksheet Report

Data File: \\chromfs\Knoxville\ChromData\D3A\20201118-17337.b\icl2.d Lims ID: IC L2 Client ID:

Sample Type: IC Calib Level: 2 Inject. Date: 18-Nov-2020 12:35:00 ALS Bottle#: 0 Worklist Smp#: 3 Injection Vol: 1.0 ul Dil. Factor: 1.0000 Sample Info:

Misc. Info.: 140-0017337-003 Operator ID: Xcalibur_System Instrument ID: D3A Sublist: chrom-D3A_Dioxin*sub1

Column 1 : Det: F1(12.07 :34.29 ) Process Host: CTX1622

First Level Reviewer: davidsonm Date: 18-Nov-2020 15:16:50

Signal

(min.)

Adj RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

2,3,7,8-TCDD M

319.8965 30:21 30:20 2 1.003 39869 4059 23 57 176 M

321.8936 30:18 30:20 -1 1.001 52399 5906 22 55 268 0.76(0.65-0.89)

2,3,7,8-TCDF

303.9016 28:23 28:23 0 1.002 67304 7673 16 40 480

305.8987 28:22 28:23 -1 1.001 89266 9617 38 95 253 0.75(0.65-0.89)

1,2,3,7,8-PeCDD

355.8546 40:25 40:26 -1 1.000 195347 43324 17 42 2548

357.8516 40:25 40:26 -1 1.000 121481 28040 27 67 1039 1.61(1.32-1.78)

1,2,3,7,8-PeCDF

339.8597 38:34 38:35 0 1.001 310415 58710 67 167 876

341.8567 38:33 38:35 -1 1.000 197637 38686 47 117 823 1.57(1.32-1.78)

2,3,4,7,8-PeCDF

339.8597 39:52 39:52 0 1.000 326215 70771 67 167 1056

341.8567 39:52 39:52 0 1.000 207292 44688 47 117 951 1.57(1.32-1.78)

1,2,3,4,7,8-HxCDD

389.8158 44:45 44:47 -1 1.000 196970 50110 23 57 2179

391.8127 44:45 44:47 -1 1.000 152098 39140 29 72 1350 1.30(1.05-1.43)

1,2,3,6,7,8-HxCDD

389.8158 44:52 44:54 -1 1.000 202652 49915 23 57 2170

391.8127 44:52 44:54 -1 1.000 155879 40834 29 72 1408 1.30(1.05-1.43)

1,2,3,7,8,9-HxCDD

389.8158 45:16 45:16 0 1.012 212400 51432 23 57 2236

391.8127 45:16 45:16 0 1.012 170704 39451 29 72 1360 1.24(1.05-1.43)

Signal

(min.)

Adj RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

1,2,3,4,7,8-HxCDF

373.8208 43:43 43:45 -1 1.000 330808 87297 116 290 753

375.8178 43:43 43:45 -1 1.000 262531 71316 128 320 557 1.26(1.05-1.43)

1,2,3,6,7,8-HxCDF

373.8208 43:51 43:53 -1 1.000 370582 97598 116 290 841

375.8178 43:51 43:53 -1 1.000 300812 78823 128 320 616 1.23(1.05-1.43)

2,3,4,6,7,8-HxCDF

373.8208 44:35 44:35 0 1.000 349028 91517 116 290 789

375.8178 44:35 44:35 0 1.000 277167 72312 128 320 565 1.26(1.05-1.43)

1,2,3,7,8,9-HxCDF

373.8208 45:31 45:32 -1 1.000 316516 73284 116 290 632

375.8178 45:31 45:32 -1 1.000 256710 60996 128 320 477 1.23(1.05-1.43)

1,2,3,4,6,7,8-HpCDD

423.7767 49:32 49:33 0 1.000 153066 28706 40 100 718

425.7737 49:32 49:33 0 1.000 148497 29208 45 112 649 1.03(0.88-1.20)

1,2,3,4,6,7,8-HpCDF

407.7817 47:53 47:53 0 1.000 273037 59564 64 160 931

409.7788 47:53 47:53 0 1.000 254208 55036 40 100 1376 1.07(0.88-1.20)

1,2,3,4,7,8,9-HpCDF

407.7817 50:12 50:12 -1 1.001 227076 41677 64 160 651

409.7788 50:11 50:12 -2 1.000 210515 39188 40 100 980 1.08(0.88-1.20)

OCDD

457.7377 53:51 53:53 -2 1.000 224363 52114 5 12 10423

459.7348 53:51 53:53 -2 1.000 248942 60098 4 10 15025 0.90(0.76-1.02)

OCDF

441.7428 53:59 54:00 -1 1.000 340315 80190 4 10 20048

443.7399 53:59 54:00 -1 1.000 365974 91499 8 20 11437 0.93(0.76-1.02)

13C-2,3,7,8-TCDD

331.9368 30:16 30:18 -1 1.016 1770375 186592 284 710 657

333.9338 30:16 30:18 -1 1.016 2213704 235433 179 447 1315 0.80(0.65-0.89)

13C-2,3,7,8-TCDF

315.9419 28:20 28:21 -1 0.951 2931503 341062 215 537 1586

317.9389 28:20 28:21 -1 0.951 3609683 416938 194 485 2149 0.81(0.65-0.89)

13C-1,2,3,7,8-PeCDD

367.8949 40:24 40:25 -1 1.356 1781897 408738 456 1140 896

369.8919 40:24 40:25 -1 1.356 1162448 268351 325 812 826 1.53(1.32-1.78)

13C-1,2,3,7,8-PeCDF

351.9000 38:32 38:33 -1 1.293 2875217 556018 1896 4740 293

353.8970 38:32 38:33 -1 1.293 1821492 350752 938 2345 374 1.58(1.32-1.78)

13C-2,3,4,7,8-PeCDF

351.9000 39:51 39:51 0 1.337 2897896 618935 1896 4740 326

353.8970 39:51 39:51 0 1.337 1872483 395221 938 2345 421 1.55(1.32-1.78)

13C-1,2,3,4,7,8-HxCDD

401.8559 44:44 44:46 -1 0.989 1729884 436120 319 797 1367

403.8529 44:44 44:46 -1 0.989 1369986 349120 393 982 888 1.26(1.05-1.43)

Signal

(min.)

Adj RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

13C-1,2,3,6,7,8-HxCDD

401.8559 44:51 44:53 -1 0.991 1794054 443843 319 797 1391

403.8529 44:51 44:53 -1 0.991 1393158 350198 393 982 891 1.29(1.05-1.43)

13C-1,2,3,4,7,8-HxCDF

383.8639 43:42 43:44 -1 0.966 1501313 391396 421 1052 930

385.8610 43:42 43:44 -1 0.966 2766531 732051 1012 2530 723 0.54(0.43-0.59)

13C-1,2,3,6,7,8-HxCDF

383.8639 43:50 43:52 -1 0.969 1800199 469082 421 1052 1114

385.8610 43:50 43:52 -1 0.969 3335468 853199 1012 2530 843 0.54(0.43-0.59)

13C-2,3,4,6,7,8-HxCDF

383.8639 44:34 44:34 0 0.985 1705730 438692 421 1052 1042

385.8610 44:34 44:34 0 0.985 3127121 811645 1012 2530 802 0.55(0.43-0.59)

13C-1,2,3,7,8,9-HxCDF

383.8639 45:30 45:31 -1 1.006 1532606 357646 421 1052 850

385.8610 45:30 45:31 -1 1.006 2905859 662654 1012 2530 655 0.53(0.43-0.59)

13C-1,2,3,4,6,7,8-HpCDD

435.8169 49:31 49:32 0 1.095 1420568 278973 26 65 10730

437.8140 49:31 49:32 0 1.095 1309363 245280 76 190 3227 1.08(0.88-1.20)

13C-1,2,3,4,6,7,8-HpCDF

417.8250 47:52 47:52 0 1.058 1132306 243304 857 2142 284

419.8220 47:52 47:52 0 1.058 2376837 521576 918 2295 568 0.48(0.37-0.51)

13C-1,2,3,4,7,8,9-HpCDF

417.8250 50:10 50:11 -2 1.109 948357 172994 857 2142 202

419.8220 50:10 50:11 -2 1.109 2045247 377618 918 2295 411 0.46(0.37-0.51)

13C-OCDD

469.7780 53:51 53:52 -1 1.190 1889553 423136 485 1212 872

471.7750 53:50 53:52 -2 1.190 2104170 470502 361 902 1303 0.90(0.76-1.02)

13C-OCDF

453.7830 53:59 54:00 -1 1.193 3445991 790959 360 900 2197

455.7801 53:59 54:00 -1 1.193 3749117 870218 524 1310 1661 0.92(0.76-1.

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File details come from the government source that posted it. Updated Apr 12, 2023.