J126039-1 Std_Tal_L4 Final Report_Part3.pdf
PDF 20 MB Posted
- Attached to
- Maintenance Dredging of New York and New Jersey Harbor – Arthur Kill 50’ Reach, Federal Navigation Project
- Solicitation number
- W912DS23B0004
About this file
This document outlines a federal contract solicitation by the U.S. Army Corps of Engineers for maintenance dredging of portions of the New York and New Jersey Harbor. The solicitation seeks a contractor to dredge approximately 125,000 cubic yards of selected shoals from the Arthur Kill 50' Reach channel to a depth of -50 feet MLLW plus 1 foot allowable overdepth, using a mechanical dredge with an environmental clamshell bucket. Multiple barges and tugboats will be needed to perform the dredging, dewatering, and unloading operations, with the dredged material required to meet all applicable federal, state, and local placement criteria. The apparent low bidder must provide all required permits for transportation, processing, and final placement of the material within 35 days of notification. Work is estimated to cost between $10,000,000 to $25,000,000, with the contract anticipated to be awarded in June/July 2023 and work to take place from August to October 2023. Liquidated damages of $2,540 per calendar day will be assessed for delays in completion.
View the file
Other files
Show all 25
On GovTribe
Work with this file
- Download the original file
- Contacts named in this file
- Similar government files
- Ask GovTribe AI about this file
Text version
Report Date: 16-Sep-2021 14:15:34 Chrom Revision: 2.3 13-May-2021 07:57:40 Eurofins TestAmerica, Pittsburgh
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\Q0916210000023.D Injection Date: 16-Sep-2021 13:39:52 Instrument ID: CHGC15 Operator ID: 402331 Lims ID: 180-126039-B-11-B Lab Sample ID: 180-126039-11 Worklist Smp#: 23 Client ID: #20210953 AMENDED COMPOSITE U Injection Vol: 1.0 uL Dil. Factor: 5.0000 ALS Bottle#: 23 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD1A, Q0916210000023.D
1-
B ro m o-
2-ni tro be nz en e(
.8
Te tra ch lo ro
-m -x yl en e(
.8 c is
-C hl or da ne
6.
3)
,4 '-D
D E
7.
4)
E nd rin
7.
9)
,4 '-D
D D
7.
6)
,4
'-D D
T(
.7
M et ho xy ch lo r(
.2
D ib ut yl ch lo re nd at e
IS
TD
8.
1)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
2)
Column: MR-2 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD2B, Q0916210000023.D
1-
B ro m o-
2-ni tro be nz en e(
.3
Te tra ch lo ro
-m -x yl en e(
.1 c is
-C hl or da ne
7.
9)
,4 '-D
D E
7.
7)
E nd rin
7.
1)
,4 '-D
D D
7.
9)
,4
'-D D
T(
.1
D ib ut yl ch lo re nd at e
IS
TD
8.
4)
M et ho xy ch lo r(
.7
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
8)
Report Date: 16-Sep-2021 14:15:34 Chrom Revision: 2.3 13-May-2021 07:57:40
Recovery Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\Q0916210000023.D Lims ID: 180-126039-B-11-B Client ID: #20210953 AMENDED COMPOSITE U Sample Type: Client Inject. Date: 16-Sep-2021 13:39:52 ALS Bottle#: 23 Worklist Smp#: 23 Injection Vol: 1.0 uL Dil. Factor: 5.0000 Sample Info: 180-0039133-023 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 16-Sep-2021 14:14:58 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1654
First Level Reviewer: eppinged Date: 16-Sep-2021 14:14:58
Surrogate Recovery, Detector: GC ECD1A
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0400 0.004456 55.71
$ 39 DCB Decachlorobiphenyl (Surr) 0.0400 0.006583 82.29
Surrogate Recovery, Detector: GC ECD2B
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0400 0.002317 28.96
$ 39 DCB Decachlorobiphenyl (Surr) 0.0400 0.007617 95.21
FORM I
PESTICIDES ORGANICS ANALYSIS DATA SHEET
Client Sample ID:
Lab Name: Job No.:
#20210953 AMENDED
COMPOSITE U
SDG No.:
180-126039-1
Lab Sample ID: 180-126039-11
Eurofins TestAmerica, Pittsburgh
Matrix: Q0907210000017.DLab File ID:
Date Collected:EPA 8081B LLAnalysis Method:
Sediment (SPLP East)
08/16/2021 08:39
Con. Extract Vol.:
Injection Volume:
GPC Cleanup:(Y/N)
Date Extracted:
Date Analyzed:
Dilution Factor: 1
Extraction Method: 3510C 09/02/2021 06:45
09/07/2021 17:44
1.0(mL)
1(uL)
Sample wt/vol: 1000(mL)
% Moisture:
GC Column: ID: 0.53(mm)MR-1
N
Analysis Batch No.: 370468 ug/LUnits:
CAS NO. COMPOUND NAME RESULT Q MDLRL
0.0013 0.00036U309-00-2 Aldrin 0.0013
0.0013 0.00024U319-84-6 alpha-BHC 0.0013
0.0013 0.00037U319-85-7 beta-BHC 0.0013
0.0013 0.00064U319-86-8 delta-BHC 0.0013
0.0013 0.00029U58-89-9 gamma-BHC (Lindane) 0.0013
0.0013 0.00037U5103-71-9 cis-Chlordane 0.0013
0.0013 0.00053U72-54-8 4,4'-DDD 0.0013
0.0013 0.00030U72-55-9 4,4'-DDE 0.0013
0.0013 0.00030U50-29-3 4,4'-DDT 0.0013
0.0013 0.00027U60-57-1 Dieldrin 0.0013
0.0013 0.00069U959-98-8 Endosulfan I 0.0013
0.0013 0.00032U33213-65-9 Endosulfan II 0.0013
0.0013 0.00064U1031-07-8 Endosulfan sulfate 0.0013
0.0013 0.00023U72-20-8 Endrin 0.0013
0.0013 0.00045U76-44-8 Heptachlor 0.0013
0.0013 0.00034U1024-57-3 Heptachlor epoxide 0.0013
0.0013 0.00078U72-43-5 Methoxychlor 0.0013
0.0013 0.00021U2385-85-5 Mirex 0.0013
0.10 0.049U8001-35-2 Toxaphene 0.10
%RECCAS NO. LIMITSQSURROGATE
64 25-122877-09-8 Tetrachloro-m-xylene (Surr)
95 32-1352051-24-3 DCB Decachlorobiphenyl (Surr)
FORM I EPA 8081B LL
Report Date: 08-Sep-2021 06:59:24 Chrom Revision: 2.3 13-May-2021 07:57:40
Target Compound Quantitation Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000017.D Lims ID: 180-126039-A-11-K Client ID: #20210953 AMENDED COMPOSITE U Sample Type: Client Inject. Date: 07-Sep-2021 17:44:42 ALS Bottle#: 17 Worklist Smp#: 17 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Sample Info: 180-0038994-017 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 08-Sep-2021 06:59:07 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1636
First Level Reviewer: eppinged Date: 08-Sep-2021 06:53:32
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
* 43 1-Bromo-2-nitrobenzene 1 3.857 3.859 -0.002 567235541H 0.1000 2 4.316 4.314 0.002 486332297H 0.1000
$ 3 Tetrachloro-m-xylene 1 4.851 4.853 -0.002 84537520H 0.0127 2 5.184 5.181 0.003 52988889H 0.008721
RPD = 37.25
5 alpha-BHC 7
1 5.228 ND
2 5.642
7 gamma-BHC (Lindane)
1 5.497 ND
2 5.942
8 beta-BHC
1 5.665 ND
2 6.173
10 delta-BHC
1 5.865 ND
2 6.406
11 Heptachlor
1 5.968 ND
2 6.273
13 Aldrin
1 6.252 ND
2 6.542
16 Heptachlor epoxide
1 6.616 ND
2 6.983
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000017.D
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
18 trans-Chlordane a 1 6.847 6.836 0.011 369991004H 0.0797 a 2 7.204 7.209 -0.005 365945842H 0.0881 a
RPD = 9.92
20 cis-Chlordane
1 6.904 ND
2 7.270
21 Endosulfan I
1 6.950 ND
2 7.338
23 4,4'-DDE
1 7.054 ND
2 7.396
34 Toxaphene
1 7.098 ND
1 7.369 1 7.827 1 7.906 2 7.518 2 7.565 2 8.313 2 8.820
24 Dieldrin
1 7.192 ND
2 7.579
27 Endrin
1 7.396 ND
2 7.845
29 4,4'-DDD
1 7.517 ND
2 7.908
31 Endosulfan II
1 7.598 ND
2 8.106
33 4,4'-DDT
1 7.798 ND
2 8.162
35 Endosulfan sulfate M 1 7.929 7.926 0.003 1930324H 0.000623 M 2 8.520 8.518 0.002 3188828H 0.001792
RPD = 96.75
36 Methoxychlor
1 8.256 ND
2 8.758
* 44 Dibutylchlorendate ISTD 1 8.324 8.326 -0.002 277932914H 0.1000 2 8.576 8.577 -0.001 207488896H 0.1000
38 Mirex
1 8.934 ND
2 9.483
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
$ 39 DCB Decachlorobiphenyl (Surr) 1 10.210 10.209 0.001 32691963H 0.0191 2 10.992 10.991 0.001 23106088H 0.0184
RPD = 3.87
QC Flag Legend Processing Flags 7 - Failed Limit of Detection H - Response Measured by Height Review Flags M - Manually Integrated a - User Assigned ID Reagents:
GCPESTISSPK2_00024 Amount Added: 0.02 Units: mL Run Reagent
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000017.D Injection Date: 07-Sep-2021 17:44:42 Instrument ID: CHGC15 Operator ID: 402331 Lims ID: 180-126039-A-11-K Lab Sample ID: 180-126039-11 Worklist Smp#: 17 Client ID: #20210953 AMENDED COMPOSITE U Injection Vol: 1.0 uL Dil. Factor: 1.0000 ALS Bottle#: 17 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD1A, Q0907210000017.D
1-
B ro m o-
2-ni tro be nz en e(
.8
Te tra ch lo ro
-m -x yl en e(
.8 t ra ns -C hl or da ne
6.
7)
E nd os ul fa n su lfa te
7.
9)
D ib ut yl ch lo re nd at e
IS
TD
8.
4)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
0)
Column: MR-2 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD2B, Q0907210000017.D
1-
B ro m o-
2-ni tro be nz en e(
.3
Te tra ch lo ro
-m -x yl en e(
.1 t ra ns -C hl or da ne
7.
4)
E nd os ul fa n su lfa te
8.
0)
D ib ut yl ch lo re nd at e
IS
TD
8.
6)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
2)
Recovery Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000017.D Lims ID: 180-126039-A-11-K Client ID: #20210953 AMENDED COMPOSITE U Sample Type: Client Inject. Date: 07-Sep-2021 17:44:42 ALS Bottle#: 17 Worklist Smp#: 17 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Sample Info: 180-0038994-017 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 08-Sep-2021 06:59:07 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1636
First Level Reviewer: eppinged Date: 08-Sep-2021 06:53:32
Surrogate Recovery, Detector: GC ECD1A
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0200 0.0127 63.56
$ 39 DCB Decachlorobiphenyl (Surr) 0.0200 0.0191 95.44
Surrogate Recovery, Detector: GC ECD2B
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0200 0.008721 43.60
$ 39 DCB Decachlorobiphenyl (Surr) 0.0200 0.0184 91.82
Manual Integration/User Assign Peak Report
Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000017.D Injection Date: 07-Sep-2021 17:44:42 Instrument ID: CHGC15 Lims ID: 180-126039-A-11-K Lab Sample ID: 180-126039-11 Client ID: #20210953 AMENDED COMPOSITE U Operator ID: 402331 ALS Bottle#: 17 Worklist Smp#: 17 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm) Detector GC ECD1A
18 trans-Chlordane, CAS: 5103-74-2 Signal: 1
Processing Integration Results Not Detected Expected RT: 6.84
6.5 6.7 6.9 7.1 Min
Y (X
GC ECD1A, Q0907210000017.D
Manual Integration Results
RT: 6.85
Height: 369991004 Amount: 0.079733 Amount Units: ng
6.5 6.7 6.9 7.1 Min
RT
Y (X
GC ECD1A, Q0907210000017.D
.8
Reviewer: eppinged, 08-Sep-2021 06:53:01 Audit Action: Assigned Compound ID Audit Reason: Baseline Smoothing
Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000017.D Injection Date: 07-Sep-2021 17:44:42 Instrument ID: CHGC15 Lims ID: 180-126039-A-11-K Lab Sample ID: 180-126039-11 Client ID: #20210953 AMENDED COMPOSITE U Operator ID: 402331 ALS Bottle#: 17 Worklist Smp#: 17 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm) Detector GC ECD1A
35 Endosulfan sulfate, CAS: 1031-07-8 Signal: 1
Processing Integration Results
RT: 7.93
Height: 9272224 Amount: 0.002995 Amount Units: ng
7.6 7.8 8.0 8.2 Min
Y (X
0)
GC ECD1A, Q0907210000017.D
.9
Manual Integration Results
RT: 7.93
Height: 1930324 Amount: 0.000623 Amount Units: ng
7.6 7.8 8.0 8.2 Min
RT
Y (X
0)
GC ECD1A, Q0907210000017.D
.9
Reviewer: eppinged, 08-Sep-2021 06:52:54 Audit Action: Manually Integrated Audit Reason: Baseline Smoothing
Client Sample ID:
Lab Name: Job No.:
#20210953 AMENDED
COMPOSITE U
SDG No.:
180-126039-1
Lab Sample ID: 180-126039-11
Eurofins TestAmerica, Pittsburgh
Matrix: Q0907210000017.DLab File ID:
Date Collected:EPA 8081B LLAnalysis Method:
Sediment (SPLP East)
08/16/2021 08:39
Con. Extract Vol.:
Injection Volume:
GPC Cleanup:(Y/N)
Date Extracted:
Date Analyzed:
Dilution Factor: 1
Extraction Method: 3510C 09/02/2021 06:45
09/07/2021 17:44
1.0(mL)
1(uL)
Sample wt/vol: 1000(mL)
% Moisture:
GC Column: ID: 0.53(mm)MR-2
N
Analysis Batch No.: 370468 ug/LUnits:
CAS NO. COMPOUND NAME RESULT Q MDLRL
0.0013 0.000415103-74-2 trans-Chlordane 0.088
%RECCAS NO. LIMITSQSURROGATE
44 25-122877-09-8 Tetrachloro-m-xylene (Surr)
92 32-1352051-24-3 DCB Decachlorobiphenyl (Surr)
Target Compound Quantitation Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000017.D Lims ID: 180-126039-A-11-K Client ID: #20210953 AMENDED COMPOSITE U Sample Type: Client Inject. Date: 07-Sep-2021 17:44:42 ALS Bottle#: 17 Worklist Smp#: 17 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Sample Info: 180-0038994-017 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 08-Sep-2021 06:59:07 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1636
First Level Reviewer: eppinged Date: 08-Sep-2021 06:53:32
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
* 43 1-Bromo-2-nitrobenzene 1 3.857 3.859 -0.002 567235541H 0.1000 2 4.316 4.314 0.002 486332297H 0.1000
$ 3 Tetrachloro-m-xylene 1 4.851 4.853 -0.002 84537520H 0.0127 2 5.184 5.181 0.003 52988889H 0.008721
RPD = 37.25
5 alpha-BHC 7
1 5.228 ND
2 5.642
7 gamma-BHC (Lindane)
1 5.497 ND
2 5.942
8 beta-BHC
1 5.665 ND
2 6.173
10 delta-BHC
1 5.865 ND
2 6.406
11 Heptachlor
1 5.968 ND
2 6.273
13 Aldrin
1 6.252 ND
2 6.542
16 Heptachlor epoxide
1 6.616 ND
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
18 trans-Chlordane a 1 6.847 6.836 0.011 369991004H 0.0797 a 2 7.204 7.209 -0.005 365945842H 0.0881 a
RPD = 9.92
20 cis-Chlordane
1 6.904 ND
2 7.270
21 Endosulfan I
1 6.950 ND
2 7.338
23 4,4'-DDE
1 7.054 ND
2 7.396
34 Toxaphene
1 7.098 ND
1 7.369 1 7.827 1 7.906 2 7.518 2 7.565 2 8.313 2 8.820
24 Dieldrin
1 7.192 ND
2 7.579
27 Endrin
1 7.396 ND
2 7.845
29 4,4'-DDD
1 7.517 ND
2 7.908
31 Endosulfan II
1 7.598 ND
2 8.106
33 4,4'-DDT
1 7.798 ND
2 8.162
35 Endosulfan sulfate M 1 7.929 7.926 0.003 1930324H 0.000623 M 2 8.520 8.518 0.002 3188828H 0.001792
RPD = 96.75
36 Methoxychlor
1 8.256 ND
2 8.758
* 44 Dibutylchlorendate ISTD 1 8.324 8.326 -0.002 277932914H 0.1000 2 8.576 8.577 -0.001 207488896H 0.1000
38 Mirex
1 8.934 ND
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
$ 39 DCB Decachlorobiphenyl (Surr) 1 10.210 10.209 0.001 32691963H 0.0191 2 10.992 10.991 0.001 23106088H 0.0184
RPD = 3.87
QC Flag Legend Processing Flags 7 - Failed Limit of Detection H - Response Measured by Height Review Flags M - Manually Integrated a - User Assigned ID Reagents:
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000017.D Injection Date: 07-Sep-2021 17:44:42 Instrument ID: CHGC15 Operator ID: 402331 Lims ID: 180-126039-A-11-K Lab Sample ID: 180-126039-11 Worklist Smp#: 17 Client ID: #20210953 AMENDED COMPOSITE U Injection Vol: 1.0 uL Dil. Factor: 1.0000 ALS Bottle#: 17 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD1A, Q0907210000017.D
1-
B ro m o-
2-ni tro be nz en e(
.8
Te tra ch lo ro
-m -x yl en e(
.8 t ra ns -C hl or da ne
6.
7)
E nd os ul fa n su lfa te
7.
9)
D ib ut yl ch lo re nd at e
IS
TD
8.
4)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
0)
Column: MR-2 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD2B, Q0907210000017.D
1-
B ro m o-
2-ni tro be nz en e(
.3
Te tra ch lo ro
-m -x yl en e(
.1 t ra ns -C hl or da ne
7.
4)
E nd os ul fa n su lfa te
8.
0)
D ib ut yl ch lo re nd at e
IS
TD
8.
6)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
2)
Recovery Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000017.D Lims ID: 180-126039-A-11-K Client ID: #20210953 AMENDED COMPOSITE U Sample Type: Client Inject. Date: 07-Sep-2021 17:44:42 ALS Bottle#: 17 Worklist Smp#: 17 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Sample Info: 180-0038994-017 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 08-Sep-2021 06:59:07 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1636
First Level Reviewer: eppinged Date: 08-Sep-2021 06:53:32
Surrogate Recovery, Detector: GC ECD1A
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0200 0.0127 63.56
$ 39 DCB Decachlorobiphenyl (Surr) 0.0200 0.0191 95.44
Surrogate Recovery, Detector: GC ECD2B
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0200 0.008721 43.60
$ 39 DCB Decachlorobiphenyl (Surr) 0.0200 0.0184 91.82
Report Date: 08-Sep-2021 06:59:25 Chrom Revision: 2.3 13-May-2021 07:57:40
Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000017.D Injection Date: 07-Sep-2021 17:44:42 Instrument ID: CHGC15 Lims ID: 180-126039-A-11-K Lab Sample ID: 180-126039-11 Client ID: #20210953 AMENDED COMPOSITE U Operator ID: 402331 ALS Bottle#: 17 Worklist Smp#: 17 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-2 ( 0.53 mm) Detector GC ECD2B
18 trans-Chlordane, CAS: 5103-74-2 Signal: 2
Processing Integration Results Not Detected Expected RT: 7.21
6.9 7.1 7.3 7.5 Min
Y (X
GC ECD2B, Q0907210000017.D
Manual Integration Results
RT: 7.20
Height: 365945842 Amount: 0.088057 Amount Units: ng
6.9 7.1 7.3 7.5 Min
RT
Y (X
GC ECD2B, Q0907210000017.D
.2
Reviewer: eppinged, 08-Sep-2021 06:53:06
Client Sample ID:
Lab Name: Job No.:
#20210954 AMENDED
COMPOSITE V
SDG No.:
180-126039-1
Lab Sample ID: 180-126039-12
Eurofins TestAmerica, Pittsburgh
Matrix: Q0916210000024.DLab File ID:
Date Collected:EPA 8081B LLAnalysis Method:
Sediment
08/16/2021 09:57
Con. Extract Vol.:
Injection Volume:
GPC Cleanup:(Y/N)
Date Extracted:
Date Analyzed:
Dilution Factor: 5
Extraction Method: 3541 08/25/2021 09:32
09/16/2021 13:55
0.5(mL)
1(uL)
Sample wt/vol: 30.1(g)
% Moisture: 57.7
GC Column: ID: 0.53(mm)MR-1
Y
Analysis Batch No.: 371632 ug/KgUnits:
CAS NO. COMPOUND NAME RESULT Q MDLRL
0.49 0.15U309-00-2 Aldrin 0.49
0.49 0.12U319-84-6 alpha-BHC 0.49
0.49 0.14U319-85-7 beta-BHC 0.49
0.49 0.16U319-86-8 delta-BHC 0.49
0.49 0.13U58-89-9 gamma-BHC (Lindane) 0.49
0.49 0.11U5103-74-2 trans-Chlordane 0.49
0.49 0.2172-54-8 4,4'-DDD 2.6
0.49 0.1072-55-9 4,4'-DDE 2.7
0.49 0.35p50-29-3 4,4'-DDT 1.2
0.49 0.12U60-57-1 Dieldrin 0.49
0.49 0.13U959-98-8 Endosulfan I 0.49
0.49 0.11U33213-65-9 Endosulfan II 0.49
0.49 0.13U1031-07-8 Endosulfan sulfate 0.49
0.49 0.15U76-44-8 Heptachlor 0.49
0.49 0.19U72-43-5 Methoxychlor 0.49
0.49 0.092U2385-85-5 Mirex 0.49
20 13U8001-35-2 Toxaphene 20
%RECCAS NO. LIMITSQSURROGATE
36 20-137877-09-8 Tetrachloro-m-xylene (Surr)
57 46-1302051-24-3 DCB Decachlorobiphenyl (Surr)
Report Date: 16-Sep-2021 14:15:35 Chrom Revision: 2.3 13-May-2021 07:57:40
Target Compound Quantitation Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\Q0916210000024.D Lims ID: 180-126039-C-12-C Client ID: #20210954 AMENDED COMPOSITE V Sample Type: Client Inject. Date: 16-Sep-2021 13:55:26 ALS Bottle#: 24 Worklist Smp#: 24 Injection Vol: 1.0 uL Dil. Factor: 5.0000 Sample Info: 180-0039133-024 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 16-Sep-2021 14:14:58 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1654
First Level Reviewer: eppinged Date: 16-Sep-2021 14:15:28
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
* 43 1-Bromo-2-nitrobenzene 1 3.855 3.855 0.001 717300851H 0.1000 2 4.308 4.309 -0.001 604837550H 0.1000
$ 3 Tetrachloro-m-xylene 1 4.846 4.846 0.000 24537249H 0.002918 2 5.176 5.175 0.001 11818954H 0.001564
RPD = 60.42
5 alpha-BHC
1 5.221 ND
2 5.636
7 gamma-BHC (Lindane)
1 5.490 ND
2 5.936
8 beta-BHC
1 5.656 ND
2 6.168
10 delta-BHC
1 5.857 ND
2 6.400
11 Heptachlor
1 5.959 ND
2 6.266
13 Aldrin
1 6.243 ND
2 6.535
16 Heptachlor epoxide 1 6.598 6.607 -0.009 9235840H 0.001611 2 6.968 6.976 -0.008 2752114H 0.000534
RPD = 100.49
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\Q0916210000024.D
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
18 trans-Chlordane
1 6.825 ND
2 7.202
20 cis-Chlordane 1 6.893 6.894 -0.001 6221673H 0.001816 2 7.259 7.261 -0.002 2772006H 0.000547
RPD = 107.44
21 Endosulfan I
1 6.940 ND
2 7.330
23 4,4'-DDE
1 7.043 7.043 0.000 41822060H 0.006876 2 7.387 7.388 -0.001 29986573H 0.005870
RPD = 15.78
34 Toxaphene
1 7.085 ND
1 7.360 1 7.816 1 7.893 2 7.512 2 7.560 2 8.305 2 8.809
24 Dieldrin
1 7.182 ND
2 7.571
27 Endrin 1 7.380 7.385 -0.005 6263571H 0.001303 2 7.830 7.835 -0.005 7350435H 0.001903
RPD = 37.45
29 4,4'-DDD
1 7.506 7.507 -0.001 31169896H 0.006540 2 7.897 7.899 -0.002 21462575H 0.004973
RPD = 27.23
31 Endosulfan II
1 7.587 ND
2 8.097
33 4,4'-DDT
1 7.786 7.786 0.000 12040670H 0.003012 2 8.152 8.152 0.000 16404009H 0.004748
RPD = 44.76
35 Endosulfan sulfate
1 7.915 ND
2 8.506
36 Methoxychlor
1 8.243 ND
2 8.747
* 44 Dibutylchlorendate ISTD 1 8.311 8.312 -0.001 405602535H 0.1000 2 8.564 8.565 -0.001 334673967H 0.1000
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
38 Mirex
1 8.917 ND
2 9.468
$ 39 DCB Decachlorobiphenyl (Surr) 1 10.184 10.185 -0.001 11445099H 0.004579 2 10.967 10.970 -0.003 10500300H 0.005174
RPD = 12.20
QC Flag Legend Processing Flags H - Response Measured by Height Reagents:
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\Q0916210000024.D Injection Date: 16-Sep-2021 13:55:26 Instrument ID: CHGC15 Operator ID: 402331 Lims ID: 180-126039-C-12-C Lab Sample ID: 180-126039-12 Worklist Smp#: 24 Client ID: #20210954 AMENDED COMPOSITE V Injection Vol: 1.0 uL Dil. Factor: 5.0000 ALS Bottle#: 24 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD1A, Q0916210000024.D
1-
B ro m o-
2-ni tro be nz en e(
.8
Te tra ch lo ro
-m -x yl en e(
.8
H ep ta ch lo r e po xi de
6.
8) c is
-C hl or da ne
6.
3)
,4 '-D
D E
7.
3)
E nd rin
7.
0)
,4 '-D
D D
7.
6)
,4
'-D D
T(
.7
D ib ut yl ch lo re nd at e
IS
TD
8.
1)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
4)
Column: MR-2 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD2B, Q0916210000024.D
1-
B ro m o-
2-ni tro be nz en e(
.3
Te tra ch lo ro
-m -x yl en e(
.1
H ep ta ch lo r e po xi de
6.
8) c is
-C hl or da ne
7.
9)
,4 '-D
D E
7.
7)
E nd rin
7.
0)
,4 '-D
D D
7.
7)
,4
'-D D
T(
.1
D ib ut yl ch lo re nd at e
IS
TD
8.
4)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
7)
Recovery Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\Q0916210000024.D Lims ID: 180-126039-C-12-C Client ID: #20210954 AMENDED COMPOSITE V Sample Type: Client Inject. Date: 16-Sep-2021 13:55:26 ALS Bottle#: 24 Worklist Smp#: 24 Injection Vol: 1.0 uL Dil. Factor: 5.0000 Sample Info: 180-0039133-024 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 16-Sep-2021 14:14:58 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1654
First Level Reviewer: eppinged Date: 16-Sep-2021 14:15:28
Surrogate Recovery, Detector: GC ECD1A
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0400 0.002918 36.47
$ 39 DCB Decachlorobiphenyl (Surr) 0.0400 0.004579 57.24
Surrogate Recovery, Detector: GC ECD2B
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0400 0.001564 19.55
$ 39 DCB Decachlorobiphenyl (Surr) 0.0400 0.005174 64.68
Client Sample ID:
Lab Name: Job No.:
#20210954 AMENDED
COMPOSITE V
SDG No.:
180-126039-1
Lab Sample ID: 180-126039-12
Eurofins TestAmerica, Pittsburgh
Matrix: Q0916210000024.DLab File ID:
Date Collected:EPA 8081B LLAnalysis Method:
Sediment
08/16/2021 09:57
Con. Extract Vol.:
Injection Volume:
GPC Cleanup:(Y/N)
Date Extracted:
Date Analyzed:
Dilution Factor: 5
Extraction Method: 3541 08/25/2021 09:32
09/16/2021 13:55
0.5(mL)
1(uL)
Sample wt/vol: 30.1(g)
% Moisture: 57.7
GC Column: ID: 0.53(mm)MR-2
Y
Analysis Batch No.: 371632 ug/KgUnits:
CAS NO. COMPOUND NAME RESULT Q MDLRL
0.49 0.12J p5103-71-9 cis-Chlordane 0.21
0.49 0.09272-20-8 Endrin 0.75
0.49 0.13J p1024-57-3 Heptachlor epoxide 0.21
%RECCAS NO. LIMITSQSURROGATE
p20 20-137877-09-8 Tetrachloro-m-xylene (Surr)
65 46-1302051-24-3 DCB Decachlorobiphenyl (Surr)
Target Compound Quantitation Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\Q0916210000024.D Lims ID: 180-126039-C-12-C Client ID: #20210954 AMENDED COMPOSITE V Sample Type: Client Inject. Date: 16-Sep-2021 13:55:26 ALS Bottle#: 24 Worklist Smp#: 24 Injection Vol: 1.0 uL Dil. Factor: 5.0000 Sample Info: 180-0039133-024 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 16-Sep-2021 14:14:58 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1654
First Level Reviewer: eppinged Date: 16-Sep-2021 14:15:28
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
* 43 1-Bromo-2-nitrobenzene 1 3.855 3.855 0.001 717300851H 0.1000 2 4.308 4.309 -0.001 604837550H 0.1000
$ 3 Tetrachloro-m-xylene 1 4.846 4.846 0.000 24537249H 0.002918 2 5.176 5.175 0.001 11818954H 0.001564
RPD = 60.42
5 alpha-BHC
1 5.221 ND
2 5.636
7 gamma-BHC (Lindane)
1 5.490 ND
2 5.936
8 beta-BHC
1 5.656 ND
2 6.168
10 delta-BHC
1 5.857 ND
2 6.400
11 Heptachlor
1 5.959 ND
2 6.266
13 Aldrin
1 6.243 ND
2 6.535
16 Heptachlor epoxide 1 6.598 6.607 -0.009 9235840H 0.001611 2 6.968 6.976 -0.008 2752114H 0.000534
RPD = 100.49
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
18 trans-Chlordane
1 6.825 ND
2 7.202
20 cis-Chlordane 1 6.893 6.894 -0.001 6221673H 0.001816 2 7.259 7.261 -0.002 2772006H 0.000547
RPD = 107.44
21 Endosulfan I
1 6.940 ND
2 7.330
23 4,4'-DDE
1 7.043 7.043 0.000 41822060H 0.006876 2 7.387 7.388 -0.001 29986573H 0.005870
RPD = 15.78
34 Toxaphene
1 7.085 ND
1 7.360 1 7.816 1 7.893 2 7.512 2 7.560 2 8.305 2 8.809
24 Dieldrin
1 7.182 ND
2 7.571
27 Endrin 1 7.380 7.385 -0.005 6263571H 0.001303 2 7.830 7.835 -0.005 7350435H 0.001903
RPD = 37.45
29 4,4'-DDD
1 7.506 7.507 -0.001 31169896H 0.006540 2 7.897 7.899 -0.002 21462575H 0.004973
RPD = 27.23
31 Endosulfan II
1 7.587 ND
2 8.097
33 4,4'-DDT
1 7.786 7.786 0.000 12040670H 0.003012 2 8.152 8.152 0.000 16404009H 0.004748
RPD = 44.76
35 Endosulfan sulfate
1 7.915 ND
2 8.506
36 Methoxychlor
1 8.243 ND
2 8.747
* 44 Dibutylchlorendate ISTD 1 8.311 8.312 -0.001 405602535H 0.1000 2 8.564 8.565 -0.001 334673967H 0.1000
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
38 Mirex
1 8.917 ND
2 9.468
$ 39 DCB Decachlorobiphenyl (Surr) 1 10.184 10.185 -0.001 11445099H 0.004579 2 10.967 10.970 -0.003 10500300H 0.005174
RPD = 12.20
QC Flag Legend Processing Flags H - Response Measured by Height Reagents:
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\Q0916210000024.D Injection Date: 16-Sep-2021 13:55:26 Instrument ID: CHGC15 Operator ID: 402331 Lims ID: 180-126039-C-12-C Lab Sample ID: 180-126039-12 Worklist Smp#: 24 Client ID: #20210954 AMENDED COMPOSITE V Injection Vol: 1.0 uL Dil. Factor: 5.0000 ALS Bottle#: 24 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD1A, Q0916210000024.D
1-
B ro m o-
2-ni tro be nz en e(
.8
Te tra ch lo ro
-m -x yl en e(
.8
H ep ta ch lo r e po xi de
6.
8) c is
-C hl or da ne
6.
3)
,4 '-D
D E
7.
3)
E nd rin
7.
0)
,4 '-D
D D
7.
6)
,4
'-D D
T(
.7
D ib ut yl ch lo re nd at e
IS
TD
8.
1)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
4)
Column: MR-2 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD2B, Q0916210000024.D
1-
B ro m o-
2-ni tro be nz en e(
.3
Te tra ch lo ro
-m -x yl en e(
.1
H ep ta ch lo r e po xi de
6.
8) c is
-C hl or da ne
7.
9)
,4 '-D
D E
7.
7)
E nd rin
7.
0)
,4 '-D
D D
7.
7)
,4
'-D D
T(
.1
D ib ut yl ch lo re nd at e
IS
TD
8.
4)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
Recovery Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\Q0916210000024.D Lims ID: 180-126039-C-12-C Client ID: #20210954 AMENDED COMPOSITE V Sample Type: Client Inject. Date: 16-Sep-2021 13:55:26 ALS Bottle#: 24 Worklist Smp#: 24 Injection Vol: 1.0 uL Dil. Factor: 5.0000 Sample Info: 180-0039133-024 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 16-Sep-2021 14:14:58 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1654
First Level Reviewer: eppinged Date: 16-Sep-2021 14:15:28
Surrogate Recovery, Detector: GC ECD1A
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0400 0.002918 36.47
$ 39 DCB Decachlorobiphenyl (Surr) 0.0400 0.004579 57.24
Surrogate Recovery, Detector: GC ECD2B
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0400 0.001564 19.55
$ 39 DCB Decachlorobiphenyl (Surr) 0.0400 0.005174 64.68
Client Sample ID:
Lab Name: Job No.:
#20210954 AMENDED
COMPOSITE V
SDG No.:
180-126039-1
Lab Sample ID: 180-126039-12
Eurofins TestAmerica, Pittsburgh
Matrix: Q0907210000018.DLab File ID:
Date Collected:EPA 8081B LLAnalysis Method:
Sediment (SPLP East)
08/16/2021 09:57
Con. Extract Vol.:
Injection Volume:
GPC Cleanup:(Y/N)
Date Extracted:
Date Analyzed:
Dilution Factor: 1
Extraction Method: 3510C 09/02/2021 06:45
09/07/2021 18:00
1.0(mL)
1(uL)
Sample wt/vol: 1000(mL)
% Moisture:
GC Column: ID: 0.53(mm)MR-1
N
Analysis Batch No.: 370468 ug/LUnits:
CAS NO. COMPOUND NAME RESULT Q MDLRL
0.0013 0.00036U309-00-2 Aldrin 0.0013
0.0013 0.00024U319-84-6 alpha-BHC 0.0013
0.0013 0.00037U319-85-7 beta-BHC 0.0013
0.0013 0.00064U319-86-8 delta-BHC 0.0013
0.0013 0.00029U58-89-9 gamma-BHC (Lindane) 0.0013
0.0013 0.00037U5103-71-9 cis-Chlordane 0.0013
0.0013 0.00053U72-54-8 4,4'-DDD 0.0013
0.0013 0.00030U72-55-9 4,4'-DDE 0.0013
0.0013 0.00030U50-29-3 4,4'-DDT 0.0013
0.0013 0.00027U60-57-1 Dieldrin 0.0013
0.0013 0.00069U959-98-8 Endosulfan I 0.0013
0.0013 0.00032U33213-65-9 Endosulfan II 0.0013
0.0013 0.00023U72-20-8 Endrin 0.0013
0.0013 0.00045U76-44-8 Heptachlor 0.0013
0.0013 0.00034U1024-57-3 Heptachlor epoxide 0.0013
0.0013 0.00078U72-43-5 Methoxychlor 0.0013
0.0013 0.00021U2385-85-5 Mirex 0.0013
0.10 0.049U8001-35-2 Toxaphene 0.10
%RECCAS NO. LIMITSQSURROGATE
64 25-122877-09-8 Tetrachloro-m-xylene (Surr)
79 32-1352051-24-3 DCB Decachlorobiphenyl (Surr)
Report Date: 08-Sep-2021 06:59:26 Chrom Revision: 2.3 13-May-2021 07:57:40
Target Compound Quantitation Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Lims ID: 180-126039-A-12-M Client ID: #20210954 AMENDED COMPOSITE V Sample Type: Client Inject. Date: 07-Sep-2021 18:00:15 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Sample Info: 180-0038994-018 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 08-Sep-2021 06:59:07 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1636
First Level Reviewer: eppinged Date: 08-Sep-2021 06:54:19
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
* 43 1-Bromo-2-nitrobenzene 1 3.858 3.859 -0.001 575839072H 0.1000 2 4.314 4.314 0.000 484962037H 0.1000
$ 3 Tetrachloro-m-xylene 1 4.852 4.853 -0.001 86968303H 0.0129 2 5.181 5.181 0.000 54170629H 0.008941
RPD = 36.13
5 alpha-BHC U
1 5.228 ND
2 5.642
7 gamma-BHC (Lindane) U
1 5.497 ND
2 5.942
8 beta-BHC
1 5.665 ND
2 6.173
10 delta-BHC
1 5.865 ND
2 6.406
11 Heptachlor
1 5.968 ND
2 6.273
13 Aldrin
1 6.252 ND
2 6.542
16 Heptachlor epoxide
1 6.616 ND
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
18 trans-Chlordane a 1 6.847 6.836 0.011 275553434H 0.0585 a 2 7.204 7.209 -0.005 264343081H 0.0638 a
RPD = 8.66
20 cis-Chlordane
1 6.904 ND
2 7.270
21 Endosulfan I
1 6.950 ND
2 7.338
23 4,4'-DDE
1 7.054 ND
2 7.396
34 Toxaphene
1 7.098 ND
1 7.369 1 7.827 1 7.906 2 7.518 2 7.565 2 8.313 2 8.820
24 Dieldrin
1 7.192 ND
2 7.579
27 Endrin
1 7.396 ND
2 7.845
29 4,4'-DDD
1 7.517 ND
2 7.908
31 Endosulfan II
1 7.598 ND
2 8.106
33 4,4'-DDT
1 7.798 ND
2 8.162
35 Endosulfan sulfate M 1 7.930 7.926 0.004 2100403H 0.000667 M 2 8.522 8.518 0.004 1476554H 0.000809
RPD = 19.23
36 Methoxychlor
1 8.256 ND
2 8.758
* 44 Dibutylchlorendate ISTD 1 8.324 8.326 -0.002 282515563H 0.1000 2 8.576 8.577 -0.002 212709995H 0.1000
38 Mirex
1 8.934 ND
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
$ 39 DCB Decachlorobiphenyl (Surr) 1 10.206 10.209 -0.003 27446432H 0.0158 2 10.990 10.991 -0.001 23429782H 0.0182
RPD = 14.14
QC Flag Legend Processing Flags H - Response Measured by Height Review Flags M - Manually Integrated U - Marked Undetected a - User Assigned ID Reagents:
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Injection Date: 07-Sep-2021 18:00:15 Instrument ID: CHGC15 Operator ID: 402331 Lims ID: 180-126039-A-12-M Lab Sample ID: 180-126039-12 Worklist Smp#: 18 Client ID: #20210954 AMENDED COMPOSITE V Injection Vol: 1.0 uL Dil. Factor: 1.0000 ALS Bottle#: 18 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD1A, Q0907210000018.D
1-
B ro m o-
2-ni tro be nz en e(
.8
Te tra ch lo ro
-m -x yl en e(
.8 t ra ns -C hl or da ne
6.
7)
E nd os ul fa n su lfa te
7.
0)
D ib ut yl ch lo re nd at e
IS
TD
8.
4)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
6)
Column: MR-2 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD2B, Q0907210000018.D
1-
B ro m o-
2-ni tro be nz en e(
.3
Te tra ch lo ro
-m -x yl en e(
.1 t ra ns -C hl or da ne
7.
4)
E nd os ul fa n su lfa te
8.
2)
D ib ut yl ch lo re nd at e
IS
TD
8.
6)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
0)
Recovery Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Lims ID: 180-126039-A-12-M Client ID: #20210954 AMENDED COMPOSITE V Sample Type: Client Inject. Date: 07-Sep-2021 18:00:15 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Sample Info: 180-0038994-018 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 08-Sep-2021 06:59:07 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1636
First Level Reviewer: eppinged Date: 08-Sep-2021 06:54:19
Surrogate Recovery, Detector: GC ECD1A
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0200 0.0129 64.41
$ 39 DCB Decachlorobiphenyl (Surr) 0.0200 0.0158 78.83
Surrogate Recovery, Detector: GC ECD2B
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0200 0.008941 44.70
$ 39 DCB Decachlorobiphenyl (Surr) 0.0200 0.0182 90.82
User Disabled Compound Report
Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Injection Date: 07-Sep-2021 18:00:15 Instrument ID: CHGC15 Lims ID: 180-126039-A-12-M Lab Sample ID: 180-126039-12 Client ID: #20210954 AMENDED COMPOSITE V Operator ID: 402331 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS
Column: MR-1 ( 0.53 mm) Detector GC ECD1A 5 alpha-BHC, CAS: 319-84-6, Signal: 1
RT: 5.23
Response: 6180163 Amount: 0.000836
5.0 5.2 5.4 Min
RT
Y
(X
0)
GC ECD1A, Q0907210000018.D
.2
Column: MR-2 ( 0.53 mm) Detector GC ECD2B 5 alpha-BHC, CAS: 319-84-6, Signal: 2
RT: 5.64
Response: 591473 Amount: 0.000088
5.6 Min
RT
Y (X
GC ECD2B, Q0907210000018.D
.6
Reviewer: eppinged, 08-Sep-2021 06:54:19 Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID
Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Injection Date: 07-Sep-2021 18:00:15 Instrument ID: CHGC15 Lims ID: 180-126039-A-12-M Lab Sample ID: 180-126039-12 Client ID: #20210954 AMENDED COMPOSITE V Operator ID: 402331 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS
Column: MR-1 ( 0.53 mm) Detector GC ECD1A 7 gamma-BHC (Lindane), CAS: 58-89-9, Signal: 1
RT: 5.50
Response: 2494275 Amount: 0.000382
5.4 5.6 Min
RT
Y (X
GC ECD1A, Q0907210000018.D
.5
Column: MR-2 ( 0.53 mm) Detector GC ECD2B 7 gamma-BHC (Lindane), CAS: 58-89-9, Signal: 2
RT: 5.94
Response: 20265892 Amount: 0.003266
5.8 6.0 Min
RT
Y (X
0)
GC ECD2B, Q0907210000018.D
.9
Reviewer: eppinged, 08-Sep-2021 06:54:19
Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Injection Date: 07-Sep-2021 18:00:15 Instrument ID: CHGC15 Lims ID: 180-126039-A-12-M Lab Sample ID: 180-126039-12 Client ID: #20210954 AMENDED COMPOSITE V Operator ID: 402331 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm) Detector GC ECD1A
18 trans-Chlordane, CAS: 5103-74-2 Signal: 1
Processing Integration Results Not Detected Expected RT: 6.84
6.5 6.7 6.9 7.1 Min
Y (X
GC ECD1A, Q0907210000018.D
Manual Integration Results
RT: 6.85
Height: 275553434 Amount: 0.058494 Amount Units: ng
6.5 6.7 6.9 7.1 Min
RT
Y (X
GC ECD1A, Q0907210000018.D
.8
Reviewer: eppinged, 08-Sep-2021 06:54:00
Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Injection Date: 07-Sep-2021 18:00:15 Instrument ID: CHGC15 Lims ID: 180-126039-A-12-M Lab Sample ID: 180-126039-12 Client ID: #20210954 AMENDED COMPOSITE V Operator ID: 402331 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm) Detector GC ECD1A
35 Endosulfan sulfate, CAS: 1031-07-8 Signal: 1
Processing Integration Results
RT: 7.93
Height: 8249124 Amount: 0.002621 Amount Units: ng
7.6 7.8 8.0 8.2 Min
Y (X
0)
GC ECD1A, Q0907210000018.D
.9
Manual Integration Results
RT: 7.93
Height: 2100403 Amount: 0.000667 Amount Units: ng
7.6 7.8 8.0 8.2 Min
RT
Y (X
GC ECD1A, Q0907210000018.D
.9
Reviewer: eppinged, 08-Sep-2021 06:53:56
Client Sample ID:
Lab Name: Job No.:
#20210954 AMENDED
COMPOSITE V
SDG No.:
180-126039-1
Lab Sample ID: 180-126039-12
Eurofins TestAmerica, Pittsburgh
Matrix: Q0907210000018.DLab File ID:
Date Collected:EPA 8081B LLAnalysis Method:
Sediment (SPLP East)
08/16/2021 09:57
Con. Extract Vol.:
Injection Volume:
GPC Cleanup:(Y/N)
Date Extracted:
Date Analyzed:
Dilution Factor: 1
Extraction Method: 3510C 09/02/2021 06:45
09/07/2021 18:00
1.0(mL)
1(uL)
Sample wt/vol: 1000(mL)
% Moisture:
GC Column: ID: 0.53(mm)MR-2
N
Analysis Batch No.: 370468 ug/LUnits:
CAS NO. COMPOUND NAME RESULT Q MDLRL
0.0013 0.000415103-74-2 trans-Chlordane 0.064
0.0013 0.00064J1031-07-8 Endosulfan sulfate 0.00081
%RECCAS NO. LIMITSQSURROGATE
45 25-122877-09-8 Tetrachloro-m-xylene (Surr)
91 32-1352051-24-3 DCB Decachlorobiphenyl (Surr)
Target Compound Quantitation Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Lims ID: 180-126039-A-12-M Client ID: #20210954 AMENDED COMPOSITE V Sample Type: Client Inject. Date: 07-Sep-2021 18:00:15 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Sample Info: 180-0038994-018 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 08-Sep-2021 06:59:07 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1636
First Level Reviewer: eppinged Date: 08-Sep-2021 06:54:19
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
* 43 1-Bromo-2-nitrobenzene 1 3.858 3.859 -0.001 575839072H 0.1000 2 4.314 4.314 0.000 484962037H 0.1000
$ 3 Tetrachloro-m-xylene 1 4.852 4.853 -0.001 86968303H 0.0129 2 5.181 5.181 0.000 54170629H 0.008941
RPD = 36.13
5 alpha-BHC U
1 5.228 ND
2 5.642
7 gamma-BHC (Lindane) U
1 5.497 ND
2 5.942
8 beta-BHC
1 5.665 ND
2 6.173
10 delta-BHC
1 5.865 ND
2 6.406
11 Heptachlor
1 5.968 ND
2 6.273
13 Aldrin
1 6.252 ND
2 6.542
16 Heptachlor epoxide
1 6.616 ND
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
18 trans-Chlordane a 1 6.847 6.836 0.011 275553434H 0.0585 a 2 7.204 7.209 -0.005 264343081H 0.0638 a
RPD = 8.66
20 cis-Chlordane
1 6.904 ND
2 7.270
21 Endosulfan I
1 6.950 ND
2 7.338
23 4,4'-DDE
1 7.054 ND
2 7.396
34 Toxaphene
1 7.098 ND
1 7.369 1 7.827 1 7.906 2 7.518 2 7.565 2 8.313 2 8.820
24 Dieldrin
1 7.192 ND
2 7.579
27 Endrin
1 7.396 ND
2 7.845
29 4,4'-DDD
1 7.517 ND
2 7.908
31 Endosulfan II
1 7.598 ND
2 8.106
33 4,4'-DDT
1 7.798 ND
2 8.162
35 Endosulfan sulfate M 1 7.930 7.926 0.004 2100403H 0.000667 M 2 8.522 8.518 0.004 1476554H 0.000809
RPD = 19.23
36 Methoxychlor
1 8.256 ND
2 8.758
* 44 Dibutylchlorendate ISTD 1 8.324 8.326 -0.002 282515563H 0.1000 2 8.576 8.577 -0.002 212709995H 0.1000
38 Mirex
1 8.934 ND
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
$ 39 DCB Decachlorobiphenyl (Surr) 1 10.206 10.209 -0.003 27446432H 0.0158 2 10.990 10.991 -0.001 23429782H 0.0182
RPD = 14.14
QC Flag Legend Processing Flags H - Response Measured by Height Review Flags M - Manually Integrated U - Marked Undetected a - User Assigned ID Reagents:
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Injection Date: 07-Sep-2021 18:00:15 Instrument ID: CHGC15 Operator ID: 402331 Lims ID: 180-126039-A-12-M Lab Sample ID: 180-126039-12 Worklist Smp#: 18 Client ID: #20210954 AMENDED COMPOSITE V Injection Vol: 1.0 uL Dil. Factor: 1.0000 ALS Bottle#: 18 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-1 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD1A, Q0907210000018.D
1-
B ro m o-
2-ni tro be nz en e(
.8
Te tra ch lo ro
-m -x yl en e(
.8 t ra ns -C hl or da ne
6.
7)
E nd os ul fa n su lfa te
7.
0)
D ib ut yl ch lo re nd at e
IS
TD
8.
4)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
6)
Column: MR-2 ( 0.53 mm)
0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 Min
Y (X
GC ECD2B, Q0907210000018.D
1-
B ro m o-
2-ni tro be nz en e(
.3
Te tra ch lo ro
-m -x yl en e(
.1 t ra ns -C hl or da ne
7.
4)
E nd os ul fa n su lfa te
8.
2)
D ib ut yl ch lo re nd at e
IS
TD
8.
6)
D
C B
D ec ac hl or ob ip he ny l (
S ur
r) ( 1
0.
0)
Recovery Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Lims ID: 180-126039-A-12-M Client ID: #20210954 AMENDED COMPOSITE V Sample Type: Client Inject. Date: 07-Sep-2021 18:00:15 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Sample Info: 180-0038994-018 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 08-Sep-2021 06:59:07 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1636
First Level Reviewer: eppinged Date: 08-Sep-2021 06:54:19
Surrogate Recovery, Detector: GC ECD1A
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0200 0.0129 64.41
$ 39 DCB Decachlorobiphenyl (Surr) 0.0200 0.0158 78.83
Surrogate Recovery, Detector: GC ECD2B
Compound Amount Added
Amount Recovered % Rec.
$ 3 Tetrachloro-m-xylene 0.0200 0.008941 44.70
$ 39 DCB Decachlorobiphenyl (Surr) 0.0200 0.0182 90.82
Report Date: 08-Sep-2021 06:59:27 Chrom Revision: 2.3 13-May-2021 07:57:40
Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Injection Date: 07-Sep-2021 18:00:15 Instrument ID: CHGC15 Lims ID: 180-126039-A-12-M Lab Sample ID: 180-126039-12 Client ID: #20210954 AMENDED COMPOSITE V Operator ID: 402331 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS
Column: MR-1 ( 0.53 mm) Detector GC ECD1A 5 alpha-BHC, CAS: 319-84-6, Signal: 1
RT: 5.23
Response: 6180163 Amount: 0.000836
5.0 5.2 5.4 Min
RT
Y
(X
0)
GC ECD1A, Q0907210000018.D
.2
Column: MR-2 ( 0.53 mm) Detector GC ECD2B 5 alpha-BHC, CAS: 319-84-6, Signal: 2
RT: 5.64
Response: 591473 Amount: 0.000088
5.6 Min
RT
Y (X
GC ECD2B, Q0907210000018.D
.6
Reviewer: eppinged, 08-Sep-2021 06:54:19
Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Injection Date: 07-Sep-2021 18:00:15 Instrument ID: CHGC15 Lims ID: 180-126039-A-12-M Lab Sample ID: 180-126039-12 Client ID: #20210954 AMENDED COMPOSITE V Operator ID: 402331 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS
Column: MR-1 ( 0.53 mm) Detector GC ECD1A 7 gamma-BHC (Lindane), CAS: 58-89-9, Signal: 1
RT: 5.50
Response: 2494275 Amount: 0.000382
5.4 5.6 Min
RT
Y (X
GC ECD1A, Q0907210000018.D
.5
Column: MR-2 ( 0.53 mm) Detector GC ECD2B 7 gamma-BHC (Lindane), CAS: 58-89-9, Signal: 2
RT: 5.94
Response: 20265892 Amount: 0.003266
5.8 6.0 Min
RT
Y (X
0)
GC ECD2B, Q0907210000018.D
.9
Reviewer: eppinged, 08-Sep-2021 06:54:19
Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210907-38994.b\Q0907210000018.D Injection Date: 07-Sep-2021 18:00:15 Instrument ID: CHGC15 Lims ID: 180-126039-A-12-M Lab Sample ID: 180-126039-12 Client ID: #20210954 AMENDED COMPOSITE V Operator ID: 402331 ALS Bottle#: 18 Worklist Smp#: 18 Injection Vol: 1.0 uL Dil. Factor: 1.0000 Method: IS PEST_CHGC15 Limit Group: GCS 8081B ICAL with IS Column: MR-2 ( 0.53 mm) Detector GC ECD2B
18 trans-Chlordane, CAS: 5103-74-2 Signal: 2
Processing Integration Results Not Detected Expected RT: 7.21
6.9 7.1 7.3 7.5 Min
Y (X
GC ECD2B, Q0907210000018.D
Manual Integration Results
RT: 7.20
Height: 264343081 Amount: 0.063788 Amount Units: ng
6.9 7.1 7.3 7.5 Min
RT
Y (X
GC ECD2B, Q0907210000018.D
.2
Reviewer: eppinged, 08-Sep-2021 06:54:06
Client Sample ID:
Lab Name: Job No.:
#20210955 AMENDED
COMPOSITE W
SDG No.:
180-126039-1
Lab Sample ID: 180-126039-13
Eurofins TestAmerica, Pittsburgh
Matrix: Q0916210000025.DLab File ID:
Date Collected:EPA 8081B LLAnalysis Method:
Sediment
08/16/2021 10:55
Con. Extract Vol.:
Injection Volume:
GPC Cleanup:(Y/N)
Date Extracted:
Date Analyzed:
Dilution Factor: 5
Extraction Method: 3541 08/25/2021 09:32
09/16/2021 14:11
0.5(mL)
1(uL)
Sample wt/vol: 30.5(g)
% Moisture: 57.7
GC Column: ID: 0.53(mm)MR-1
Y
Analysis Batch No.: 371632 ug/KgUnits:
CAS NO. COMPOUND NAME RESULT Q MDLRL
0.48 0.15U309-00-2 Aldrin 0.48
0.48 0.12U319-84-6 alpha-BHC 0.48
0.48 0.13U319-85-7 beta-BHC 0.48
0.48 0.15U319-86-8 delta-BHC 0.48
0.48 0.13U58-89-9 gamma-BHC (Lindane) 0.48
0.48 0.11U5103-74-2 trans-Chlordane 0.48
0.48 0.2172-54-8 4,4'-DDD 2.2
0.48 0.09972-55-9 4,4'-DDE 2.4
0.48 0.35p50-29-3 4,4'-DDT 1.2
0.48 0.12U60-57-1 Dieldrin 0.48
0.48 0.13U959-98-8 Endosulfan I 0.48
0.48 0.11U33213-65-9 Endosulfan II 0.48
0.48 0.13U1031-07-8 Endosulfan sulfate 0.48
0.48 0.15U76-44-8 Heptachlor 0.48
0.48 0.19U72-43-5 Methoxychlor 0.48
0.48 0.091U2385-85-5 Mirex 0.48
19 13U8001-35-2 Toxaphene 19
%RECCAS NO. LIMITSQSURROGATE
38 20-137877-09-8 Tetrachloro-m-xylene (Surr)
60 46-1302051-24-3 DCB Decachlorobiphenyl (Surr)
Report Date: 16-Sep-2021 14:33:09 Chrom Revision: 2.3 13-May-2021 07:57:40
Target Compound Quantitation Report
Data File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\Q0916210000025.D Lims ID: 180-126039-B-13-B Client ID: #20210955 AMENDED COMPOSITE W Sample Type: Client Inject. Date: 16-Sep-2021 14:11:12 ALS Bottle#: 25 Worklist Smp#: 25 Injection Vol: 1.0 uL Dil. Factor: 5.0000 Sample Info: 180-0039133-025 Operator ID: 402331 Instrument ID: CHGC15
Method: \\chromfs\Pittsburgh\ChromData\CHGC15\20210916-39133.b\IS PEST_CHGC15.m Limit Group: GCS 8081B ICAL with IS Last Update: 16-Sep-2021 12:25:32 Calib Date: 01-Sep-2021 15:22:50 Integrator: Falcon Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CHGC15\20210901-38917.b\Q0901210000006.D
Column 1 : MR-1 ( 0.53 mm) Det: GC ECD1A Column 2 : MR-2 ( 0.53 mm) Det: GC ECD2B Process Host: CTX1654
First Level Reviewer: eppinged Date: 16-Sep-2021 14:33:06
Col
RT
(min.)
Exp RT (min.)
Dlt RT (min.) Response
OnCol Amt ng Flags
* 43 1-Bromo-2-nitrobenzene 1 3.855 3.855 0.001 678180799H 0.1000 2 4.308 4.309 -0.001 579058456H 0.1000
$ 3 Tetrachloro-m-xylene 1 4.848 4.846 0.002 24183558H 0.003042 2 5.177 5.175 0.002 11080370H 0.001532
RPD = 66.04
5 alpha-BHC
1 5.221 ND
2 5.636
7 gamma-BHC (Lindane) 7
1 5.490 ND
2 5.936
8 beta-BHC
1 5.656 ND
2 6.168
10 delta-BHC
1 5.857 ND
2 6.400
11 Heptachlor
1 5.959 ND
2 6.266
13 Aldrin
1 6.243 ND
2 6.535
16 Heptachlor epoxide 1 6.598 6.607 -0.009 11198641H 0.002066 2 6.967 6.976 -0.009 2972577H 0.000602
RPD = 109.76
Dat…
This is the start of the file's text. The full file is on GovTribe.
File details come from the government source that posted it. Updated .