J126039-1 Std_Tal_L4 Final Report_Part2.pdf

PDF 20 MB Posted Apr 12, 2023

Attached to: Maintenance Dredging of New York and New Jersey Harbor – Arthur Kill 50’ Reach, Federal Navigation Project
Solicitation number: W912DS23B0004
Issued by: Department of the Army Corps of Engineers Engineering District New York

About this file

Written by GovTribe AI · Dec 27, 2023

This document summarizes a federal contract solicitation for maintenance dredging services. The U.S. Army Corps of Engineers is seeking a contractor to dredge approximately 125,000 cubic yards of material from the Arthur Kill 50' Reach of the New York and New Jersey Harbor. The dredged material consists primarily of silt and clay and must be mechanically dredged, transported via barge, dewatered, processed, and placed at a contractor-furnished upland site permitted by the state. Bidders must be able to commence work within five days of notice to proceed and maintain a production rate of at least 2,500 cubic yards per day to minimize channel closure time for ship traffic. The solicitation number is W912DS23B0004 and the estimated value is between $10-25 million. The apparent low bidder must provide all required permits within 35 days of notification. The period of performance is anticipated to be August through October 2023 with $2,540 in liquidated damages per day for delays beyond acceptance. This is an unrestricted procurement conducted by the New York District of the U.S. Army Corps of Engineers.

View the file

Other files

File	Type	Posted
Bid Abstract - W912DS23B0004.pdf	PDF	Jun 6, 2023
AK50_23-B-0004_Contract Volume Breakdown.pdf	PDF	Jun 1, 2023
W912DS23B0004-0006.pdf	PDF	Jun 1, 2023
AK50 5.23.2023 - FY23 Plans_AllSheets.pdf	PDF	May 30, 2023
W912DS23B0004-Amendment 0005.pdf	PDF	May 30, 2023
AK50 5.23.2023 - FY23 Tech Specs.pdf	PDF	May 30, 2023
W912DS23B0004-Amendment 0004.pdf	PDF	May 18, 2023
W912DS23B0004-Amendment 0003.pdf	PDF	May 3, 2023
Arthur Kill 50-foot Channel Upland Final Report Tables.pdf	PDF	Apr 21, 2023
AK50 ASI Upland Report.pdf	PDF	Apr 21, 2023
Arthur Kill 50-foot Channel Upland Final Report Tables.xlsx	XLSX spreadsheet	Apr 21, 2023
W912DS23B0004 - Amendment 0002.pdf	PDF	Apr 21, 2023
J126039-1 Std_Tal_L4 Final Report_Part5.pdf	PDF	Apr 12, 2023
W912DS23B0004 - Amendment 0001.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part6.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part3.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part7.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part8.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part1.pdf	PDF	Apr 12, 2023
J126039-1 Std_Tal_L4 Final Report_Part4.pdf	PDF	Apr 12, 2023
W912DS23B0004.pdf	PDF	Apr 7, 2023
NYSDEC WQC No. 2-6500-00053-00001 w 2023 Conditions.pdf	PDF	Apr 7, 2023
AK50 FY23 Plans-5242-Final.pdf	PDF	Apr 7, 2023
AK50 Tech Specs 13MARCH2023 - Final.pdf	PDF	Apr 7, 2023
NJDEP FCD-WQC No. 0000-03-0035.1 CDT230001.pdf	PDF	Apr 7, 2023

Show all 25

On GovTribe

Work with this file

Download the original file
Contacts named in this file
Similar government files
Ask GovTribe AI about this file

Try for free Login

Text version

The file's text, extracted by GovTribe without its formatting.

Report Date: 30-Aug-2021 05:33:41 Chrom Revision: 2.3 13-May-2021 07:57:40 Eurofins TestAmerica, Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CH733\20210827-38846.b\N08270025.D Injection Date: 27-Aug-2021 17:31:30 Instrument ID: CH733 Lims ID: 180-126039-A-4-C Lab Sample ID: 180-126039-4 Client ID: #20210943 COMPOSITE V Operator ID: 03200 ALS Bottle#: 24 Worklist Smp#: 25 Injection Vol: 2.0 ul Dil. Factor: 10.0000 Method: BNA_CH733 Limit Group: BNA 8270E ICAL Column: Rxi-5SilMS ( 0.32 mm) Detector MS SCAN 142 Bis(2-ethylhexyl) phthalate, CAS: 117-81-7

30 70 110 150 190 230 270 310 350 390 m/z

Y (X

Raw Spec:Scan 2026(13.00)

149 236 24157

69 167120

30 70 110 150 190 230 270 310 350 390 m/z

Y (X

Amdis Enhanced Spec: Scan 2026(13.00), Qvalue=93 Sig Qvalue=98

71 104

235 279

30 70 110 150 190 230 270 310 350 390

Ref Spec: 142 Bis(2-ethylhexyl) phthalate (NIST98.L)

57 167

113 279112

30 70 110 150 190 230 270 310 350 390 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 13.000 min.(Qvalue: 93)

104 167

12.5 12.8 13.1 13.4 Min

Y (X m/z 149.0

12.5 12.8 13.1 13.4 Min

Y (X m/z 167.0

12.5 12.8 13.1 13.4 Min

Y (X

0) m/z 279.0

12.5 12.8 13.1 13.4 Min

Y (X

0) m/z 149.0 m/z 167.0 m/z 279.0

30 50 70 90 110 130 150 170 190 210 230 250 270 m/z

Y (X

Raw Spec:Scan 1546(10.18)

69 95

167111

179 205 227 260

30 70 110 150 190 230 270 m/z

Y (X

Amdis Enhanced Spec: Scan 1546(10.18), Qvalue=94 Sig Qvalue=96

64 139 166 58 214128 168 25714086

30 50 70 90 110 130 150 170 190 210 230 250 270

Ref Spec: 121 Carbazole (NIST98.L)

139 16884

30 50 70 90 110 130 150 170 190 210 230 250 270 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 10.180 min.(Qvalue: 94)

64 214128 139

9.6 9.9 10.2 10.5 Min

Y (X

0) m/z 167.0

9.6 9.9 10.2 10.5 Min

Y (X

0) m/z 166.0

9.6 9.9 10.2 10.5 Min

Y (X

0) m/z 168.0

9.6 9.9 10.2 10.5 Min

Y (X

0) m/z 167.0 m/z 166.0 m/z 168.0

30 70 110 150 190 230 270 310 350 m/z

Y (X

Raw Spec:Scan 2032(13.04)

95 97

226 229

30 70 110 150 190 230 270 310 350 m/z

Y (X

Amdis Enhanced Spec: Scan 2032(13.04), Qvalue=93 Sig Qvalue=97

224114

30 70 110 150 190 230 270 310 350

Ref Spec: 144 Chrysene (NIST98.L)

226 229114

30 70 110 150 190 230 270 310 350 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 13.040 min.(Qvalue: 93)

12.5 12.8 13.1 13.4 Min

Y (X m/z 228.0

12.5 12.8 13.1 13.4 Min

Y (X m/z 226.0

12.5 12.8 13.1 13.4 Min

Y (X m/z 229.0

12.5 12.8 13.1 13.4 Min

Y (X m/z 228.0 m/z 226.0 m/z 229.0

30 70 110 150 190 230 270 310 350 390 430 470 510 m/z

Y (X

Raw Spec:Scan 2663(16.75)

276109

30 70 110 150 190 230 270 310 350 390 430 470 510 m/z

Y (X

Amdis Enhanced Spec: Scan 2663(16.75), Qvalue=84 Sig Qvalue=93

191 192

30 70 110 150 190 230 270 310 350 390 430 470 510

Ref Spec: 157 Dibenz(a,h)anthracene (NIST98.L)

139 279276 137 274 280149

30 70 110 150 190 230 270 310 350 390 430 470 510 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 16.750 min.(Qvalue: 84)

111 192

16.2 16.5 16.8 17.1 Min

Y (X m/z 278.0

16.2 16.5 16.8 17.1 Min

Y (X

0) m/z 139.0

16.2 16.5 16.8 17.1 Min

Y (X

0) m/z 279.0

16.2 16.5 16.8 17.1 Min

Y (X m/z 278.0 m/z 139.0

30 70 110 150 190 230 270 310 m/z

Y (X

Raw Spec:Scan 1708(11.13)

20069 20355

123 199

30 70 110 150 190 230 270 310 m/z

Y (X

Amdis Enhanced Spec: Scan 1708(11.13), Qvalue=97 Sig Qvalue=98

30 70 110 150 190 230 270 310

Ref Spec: 128 Fluoranthene (NIST98.L)

200 203101

30 70 110 150 190 230 270 310 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 11.130 min.(Qvalue: 97)

10.6 10.9 11.2 11.5 Min

Y (X

0) m/z 202.0

10.6 10.9 11.2 11.5 Min

Y (X m/z 101.0

10.6 10.9 11.2 11.5 Min

Y (X m/z 203.0

10.6 10.9 11.2 11.5 Min

Y (X

0) m/z 202.0 m/z 101.0 m/z 203.0

30 50 70 90 110 130 150 170 190 210 230 m/z

Y (X

Raw Spec:Scan 1365(9.12)

64 166

95 165

128 192

194 224

30 50 70 90 110 130 150 170 190 210 230 m/z

Y (X

Amdis Enhanced Spec: Scan 1365(9.12), Qvalue=95 Sig Qvalue=92

164 16712197 20313178

30 50 70 90 110 130 150 170 190 210 230

Ref Spec: 98 Fluorene (NIST98.L)

16716383 139

30 50 70 90 110 130 150 170 190 210 230 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 9.120 min.(Qvalue: 95)

16497 167

8.6 8.9 9.2 9.5 Min

Y (X

0) m/z 166.0

8.6 8.9 9.2 9.5 Min

Y (X m/z 165.0

8.6 8.9 9.2 9.5 Min

Y (X

0) m/z 167.0

8.6 8.9 9.2 9.5 Min

Y (X m/z 166.0 m/z 165.0 m/z 167.0

30 70 110 150 190 230 270 310 350 390 430 470 510 m/z

Y (X

Raw Spec:Scan 2660(16.73)

69 276

277138 274

30 70 110 150 190 230 270 310 350 390 430 470 510 m/z

Y (X

Amdis Enhanced Spec: Scan 2660(16.73), Qvalue=97 Sig Qvalue=97

274138

30 70 110 150 190 230 270 310 350 390 430 470 510

Ref Spec: 156 Indeno[1,2,3-cd]pyrene (NIST98.L)

277274138

30 70 110 150 190 230 270 310 350 390 430 470 510 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 16.730 min.(Qvalue: 97)

16.2 16.5 16.8 17.1 Min

Y (X m/z 276.0

16.2 16.5 16.8 17.1 Min

Y (X

0) m/z 138.0

16.2 16.5 16.8 17.1 Min

Y (X m/z 277.0

16.2 16.5 16.8 17.1 Min

Y (X m/z 276.0 m/z 138.0 m/z 277.0

Report Date: 30-Aug-2021 05:33:40 Chrom Revision: 2.3 13-May-2021 07:57:40

30 40 50 60 70 80 90 100 110 120 130 140 m/z

Y (X

Raw Spec:Scan 1006(7.00)

43 57 12777 85 10239 108

30 50 70 90 110 130 m/z

Y (X

Amdis Enhanced Spec: Scan 1006(7.00), Qvalue=93 Sig Qvalue=99

57 127 12943 7763

30 40 50 60 70 80 90 100 110 120 130 140

Ref Spec: 53 Naphthalene (NIST98.L)

102 12951 63 74 75

30 40 50 60 70 80 90 100 110 120 130 140 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 7.010 min.(Qvalue: 93)

6.5 6.8 7.1 7.4 Min

Y (X m/z 128.0

6.5 6.8 7.1 7.4 Min

Y (X

0) m/z 129.0

6.5 6.8 7.1 7.4 Min

Y (X

0) m/z 127.0

6.5 6.8 7.1 7.4 Min

Y (X m/z 128.0 m/z 129.0 m/z 127.0

30 50 70 90 110 130 150 170 190 210 230 250 270 m/z

Y (X

Raw Spec:Scan 1515(10.00)

55 95

97 123 176 179

30 70 110 150 190 230 270 m/z

Y (X

Amdis Enhanced Spec: Scan 1515(10.00), Qvalue=95 Sig Qvalue=100

179152109

30 50 70 90 110 130 150 170 190 210 230 250 270

Ref Spec: 118 Phenanthrene (NIST98.L)

17976 15289

30 50 70 90 110 130 150 170 190 210 230 250 270 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 10.000 min.(Qvalue: 95)

109 177

9.4 9.7 10.0 10.3 Min

Y (X m/z 178.0

9.4 9.7 10.0 10.3 Min

Y (X m/z 179.0

9.4 9.7 10.0 10.3 Min

Y (X m/z 176.0

9.4 9.7 10.0 10.3 Min

Y (X m/z 178.0 m/z 179.0 m/z 176.0

30 70 110 150 190 230 270 310 350 m/z

Y (X

Raw Spec:Scan 1748(11.37)

69 20320195 123 165

30 70 110 150 190 230 270 310 350 m/z

Y (X

Amdis Enhanced Spec: Scan 1748(11.37), Qvalue=98 Sig Qvalue=97

200 203

30 70 110 150 190 230 270 310 350

Ref Spec: 131 Pyrene (NIST98.L)

203200

30 70 110 150 190 230 270 310 350 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 11.370 min.(Qvalue: 98)

10.8 11.1 11.4 11.7 Min

Y (X

0) m/z 202.0

10.8 11.1 11.4 11.7 Min

Y (X m/z 200.0

10.8 11.1 11.4 11.7 Min

Y (X m/z 203.0

10.8 11.1 11.4 11.7 Min

Y (X

0) m/z 202.0 m/z 200.0

Manual Integration/User Assign Peak Report

Eurofins TestAmerica, Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CH733\20210827-38846.b\N08270025.D Injection Date: 27-Aug-2021 17:31:30 Instrument ID: CH733 Lims ID: 180-126039-A-4-C Lab Sample ID: 180-126039-4 Client ID: #20210943 COMPOSITE V Operator ID: 03200 ALS Bottle#: 24 Worklist Smp#: 25 Injection Vol: 2.0 ul Dil. Factor: 10.0000 Method: BNA_CH733 Limit Group: BNA 8270E ICAL Column: Rxi-5SilMS ( 0.32 mm) Detector MS SCAN

71 1,1'-Biphenyl, CAS: 92-52-4 Signal: 1

Processing Integration Results

RT: 8.24

Area: 606 Amount: 0.012626 Amount Units: ng

7.8 8.0 8.2 8.4 Min

Y (X

0) m/z 154.0

Manual Integration Results

RT: 8.09

Area: 2625 Amount: 0.054690 Amount Units: ng

7.8 8.0 8.2 8.4 Min

Y (X

0) m/z 154.0

Reviewer: piccolinov, 30-Aug-2021 03:54:44 Audit Action: Assigned Compound ID Audit Reason: Peak assignment corrected

User Disabled Compound Report

103 1,2-Diphenylhydrazine, CAS: 122-66-7 Processing Results

30 50 70 90 110 130 150 170 190 210 230 m/z

Y (X

Raw Spec:Scan 1391(9.27)

55 64

160123 165 224191

30 50 70 90 110 130 150 170 190 210 230 m/z

Y (X

Amdis Enhanced Spec: Scan 1391(9.27), Qvalue=28

22484 113 142

30 50 70 90 110 130 150 170 190 210 230

Ref Spec: 103 1,2-Diphenylhydrazine (DATA)

18251

15250

9.1 Min

Y (X

0) m/z 77.0

9.1 Min

Y (X

0) m/z 105.0

9.1 Min

Y (X

0) m/z 182.0

RT Mass Response Amount

9.27 77.00 1131 0.025892

9.27 105.00 1559

9.26 182.00 4316 Reviewer: piccolinov, 30-Aug-2021 03:54:58 Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID

87 2,4-Dinitrotoluene, CAS: 121-14-2 Processing Results

30 50 70 90 110 130 150 170 190 210 m/z

Y (X

Raw Spec:Scan 1280(8.62)

80 158 1658266

30 50 70 90 110 130 150 170 190 210 m/z

Y (X

Amdis Enhanced Spec: Scan 1280(8.62), Qvalue=53

80 158 1658266

30 50 70 90 110 130 150 170 190 210

Ref Spec: 87 2,4-Dinitrotoluene (NIST98.L)

63 90

11978 18291

8.5 8.8 Min

Y (X m/z 165.0

8.5 8.8

Min

Y (X

0) m/z 63.0

8.5 8.8 Min

Y (X

0) m/z 89.0

RT Mass Response Amount

8.62 165.00 37314 2.821858

8.62 63.00 1374

8.62 89.00 956 Reviewer: piccolinov, 30-Aug-2021 03:54:50

79 2,6-Dinitrotoluene, CAS: 606-20-2 Processing Results

30 50 70 90 110 130 150 170 190 210 m/z

Y (X

Raw Spec:Scan 1214(8.23)

41 55 69 11595

30 50 70 90 110 130 150 170 190 210 m/z

Y (X

Enhanced Spec:Scan 1214(8.23) Bgrd 1211( 8.21), Qvalue=1

7663 1577851 111

30 50 70 90 110 130 150 170 190 210

Ref Spec: 79 2,6-Dinitrotoluene (NIST98.L)

7751 91 121 148 166104

8.3 Min

Y (X

0) m/z 165.0

8.3 Min

Y (X

0) m/z 63.0

8.3 Min

Y (X

S) m/z 89.0

RT Mass Response Amount

8.23 165.00 698 0.068514

8.23 63.00 1556

8.23 89.00 689 Reviewer: piccolinov, 30-Aug-2021 03:54:47

75 2-Nitroaniline, CAS: 88-74-4 Processing Results

30 50 70 90 110 130 150 170 190 210 m/z

Y (X

Raw Spec:Scan 1228(8.31)

40 156123 165

208193

30 50 70 90 110 130 150 170 190 210 m/z

Y (X

Amdis Enhanced Spec: Scan 1228(8.31), Qvalue=34

109 165

55 156 79 14140 208

30 50 70 90 110 130 150 170 190 210

Ref Spec: 75 2-Nitroaniline (NIST98.L)

65 92

44 7752 104 139

8.0 8.3 Min

Y (X

0) m/z 65.0

8.0 8.3 Min

Y (X

0) m/z 92.0

8.0 8.3 Min

Y (X

0) m/z 138.0

RT Mass Response Amount

8.31 65.00 761 0.070631

8.32 92.00 749

8.32 138.00 602 Reviewer: piccolinov, 30-Aug-2021 03:54:46

22 Benzaldehyde, CAS: 100-52-7 Signal: 2

Processing Integration Results

RT: 5.30

Area: 2678 Amount: 0.132485 Amount Units: ng

5.0 5.2 5.4 5.6 Min

Y (X

0) m/z 105.0

Manual Integration Results

RT: 5.30

Area: 2678 Amount: 0.132485 Amount Units: ng

5.0 5.2 5.4 5.6 Min

Y (X

0) m/z 105.0

Reviewer: piccolinov, 30-Aug-2021 03:54:35

22 Benzaldehyde, CAS: 100-52-7 Signal: 3

Processing Integration Results

RT: 5.30

Area: 1800 Amount: 0.132485 Amount Units: ng

5.0 5.2 5.4 5.6 Min

Y (X

0) m/z 106.0

Manual Integration Results

RT: 5.30

Area: 1800 Amount: 0.132485 Amount Units: ng

5.0 5.2 5.4 5.6 Min

Y (X

0) m/z 106.0

Reviewer: piccolinov, 30-Aug-2021 03:54:35

129 Benzidine, CAS: 92-87-5 Processing Results

30 70 110 150 190 230 270 310 m/z

Y (X

Raw Spec:Scan 1700(11.09)

55 69

165 226179

30 70 110 150 190 230 270 310 m/z

Y (X

Amdis Enhanced Spec: Scan 1700(11.09), Qvalue=56

161 202 272

30 70 110 150 190 230 270 310

Ref Spec: 129 Benzidine (NIST98.L)

18592 183156

11.0 11.3 Min

Y (X

0) m/z 184.0

11.0 11.3 Min

Y (X

0) m/z 92.0

11.0 11.3 Min

Y (X

0) m/z 185.0

RT Mass Response Amount

11.09 184.00 1924 0.038018

11.08 92.00 2311

11.08 185.00 831 Reviewer: piccolinov, 30-Aug-2021 03:55:05

149 Benzo[b]fluoranthene, CAS: 205-99-2 Signal: 1

Processing Integration Results

RT: 14.59

Area: 254951 Amount: 2.477885 Amount Units: ng

14.2 14.4 14.6 14.8 15.0 Min

Y (X m/z 252.0

Manual Integration Results

RT: 14.59

Area: 193911 Amount: 1.884633 Amount Units: ng

14.2 14.4 14.6 14.8 15.0 Min

Y (X m/z 252.0

Reviewer: piccolinov, 30-Aug-2021 03:55:19 Audit Action: Split an Integrated Peak Audit Reason: Poor chromatography

150 Benzo[k]fluoranthene, CAS: 207-08-9 Signal: 1

Processing Integration Results

RT: 14.73

Area: 31788 Amount: 0.317893 Amount Units: ng

14.3 14.5 14.7 14.9 15.1 Min

Y (X m/z 252.0

Manual Integration Results

RT: 14.61

Area: 78428 Amount: 0.784311 Amount Units: ng

14.3 14.5 14.7 14.9 15.1 Min

Y (X m/z 252.0

Reviewer: piccolinov, 30-Aug-2021 03:55:26 Audit Action: Split an Integrated Peak Audit Reason: Poor chromatography

152 Benzo[a]pyrene, CAS: 50-32-8 Signal: 1

Processing Integration Results

RT: 14.98

Area: 103882 Amount: 1.120261 Amount Units: ng

14.6 14.8 15.0 15.2 Min

Y (X m/z 252.0

Manual Integration Results

RT: 15.05

Area: 131869 Amount: 1.422072 Amount Units: ng

14.6 14.8 15.0 15.2 Min

Y (X m/z 252.0

Reviewer: piccolinov, 30-Aug-2021 03:55:28 Audit Action: Assigned Compound ID Audit Reason: Poor chromatography

137 Butyl benzyl phthalate, CAS: 85-68-7 Processing Results

30 70 110 150 190 230 270 310 350 m/z

Y (X

Raw Spec:Scan 1882(12.16)

64 69

95 97

207 219

30 70 110 150 190 230 270 310 350 m/z

Y (X

Enhanced Spec:Scan 1882(12.16) Bgrd 1879(12.14), Qvalue=1

110 206 223 31767 324284

30 70 110 150 190 230 270 310 350

Ref Spec: 137 Butyl benzyl phthalate (NIST98.L)

20665 104

12.0 12.3 Min

Y (X

0) m/z 149.0

12.0 12.3 Min

Y (X

0) m/z 91.0

12.0 12.3 Min

Y (X

0) m/z 206.0

RT Mass Response Amount

12.16 149.00 4261 0.125014

12.16 91.00 4827

12.16 206.00 2080 Reviewer: piccolinov, 30-Aug-2021 03:55:07

147 Di-n-octyl phthalate, CAS: 117-84-0 Processing Results

30 70 110 150 190 230 270 310 350 390 430 m/z

Y (X

Raw Spec:Scan 2189(13.96)

55 57

151 207

30 70 110 150 190 230 270 310 350 390 430 m/z

Y (X

Enhanced Spec:Scan 2189(13.96) Bgrd 2185(13.94), Qvalue=1

71 81

253145

167 365 384311

30 70 110 150 190 230 270 310 350 390 430

Ref Spec: 147 Di-n-octyl phthalate (NIST98.L)

15057 279

13.8 14.1 Min

Y (X

0) m/z 149.0

13.8 14.1 Min

Y (X

0) m/z 167.0

13.8 14.1 Min

Y (X

0) m/z 43.0

RT Mass Response Amount

13.96 149.00 1771 0.019477

13.97 167.00 1299

13.96 43.00 9370 Reviewer: piccolinov, 30-Aug-2021 03:55:10

101 N-Nitrosodiphenylamine, CAS: 86-30-6 Processing Results

30 50 70 90 110 130 150 170 190 210 230 m/z

Y (X

Raw Spec:Scan 1383(9.22)

160 169128 224191

30 50 70 90 110 130 150 170 190 210 230 m/z

Y (X

Amdis Enhanced Spec: Scan 1383(9.22), Qvalue=42

166119 18795 224

30 50 70 90 110 130 150 170 190 210 230

Ref Spec: 101 N-Nitrosodiphenylamine (DATA)

17051 77 83

9.1 Min

Y (X

0) m/z 169.0

9.1 Min

Y (X

0) m/z 168.0

9.1 Min

Y (X

0) m/z 167.0

RT Mass Response Amount

9.22 169.00 1218 0.036392

9.23 168.00 1330

9.22 167.00 1150 Reviewer: piccolinov, 30-Aug-2021 03:54:57

141 3,3'-Dichlorobenzidine, CAS: 91-94-1 Processing Results

30 70 110 150 190 230 270 310 350 m/z

Y (X

Raw Spec:Scan 1988(12.78)

165 230 231

30 70 110 150 190 230 270 310 350 m/z

Y (X

Amdis Enhanced Spec: Scan 1988(12.78), Qvalue=52

123 163 231

196 292 326 329

30 70 110 150 190 230 270 310 350

Ref Spec: 141 3,3'-Dichlorobenzidine (NIST98.L)

12691 127

256215 216

12.8 Min

Y (X

0) m/z 252.0

12.8 Min

Y (X m/z 254.0

12.8 Min

Y (X

0) m/z 126.0

RT Mass Response Amount

12.78 252.00 628 0.019523

12.78 254.00 1400

12.78 126.00 654 Reviewer: piccolinov, 30-Aug-2021 03:55:08

FORM I

GC/MS SEMI VOA ORGANICS ANALYSIS DATA SHEET

Client Sample ID:

Lab Name: Job No.:

#20210944 COMPOSITE W

SDG No.:

180-126039-1

Lab Sample ID: 180-126039-5

Eurofins TestAmerica, Pittsburgh

Matrix: N08270026.DLab File ID:

Date Collected:EPA 8270E LLAnalysis Method:

Sediment

08/16/2021 10:55

Level: (low/med)

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Analyzed:

Date Extracted:

Dilution Factor:

Extract. Method: 08/26/2021 15:18

08/27/2021 17:53

Low2(uL)

0.5(mL)

% Moisture: 65.4

Sample wt/vol: 30.2(g)

Analysis Batch No.: 369409 ug/KgUnits:

CAS NO. COMPOUND NAME RESULT Q MDLRL

470 170U92-52-4 1,1'-Biphenyl 470

470 210U122-66-7 1,2-Diphenylhydrazine(as Azobenzene) 470

96 22U91-58-7 2-Chloronaphthalene 96

470 180U95-57-8 2-Chlorophenol 470

96 37U120-83-2 2,4-Dichlorophenol 96

470 160U105-67-9 2,4-Dimethylphenol 470

4700 3000U51-28-5 2,4-Dinitrophenol 4700

470 290U121-14-2 2,4-Dinitrotoluene 470

470 190U606-20-2 2,6-Dinitrotoluene 470

96 23J91-57-6 2-Methylnaphthalene 46

470 140U95-48-7 2-Methylphenol 470

470 140U106-44-5 Methylphenol, 3 & 4 470

2400 220U88-74-4 2-Nitroaniline 2400

96 36U108-60-1 2,2'-oxybis[1-chloropropane] 96

470 170U95-95-4 2,4,5-Trichlorophenol 470

470 160U88-06-2 2,4,6-Trichlorophenol 470

2400 830U534-52-1 4,6-Dinitro-2-methylphenol 2400

96 28J83-32-9 Acenaphthene 38

96 21208-96-8 Acenaphthylene 140

960 170U98-86-2 Acetophenone 960

96 25120-12-7 Anthracene 140

960 210U1912-24-9 Atrazine 960

960 59U100-52-7 Benzaldehyde 960

9600 3600U92-87-5 Benzidine 9600

96 4356-55-3 Benzo[a]anthracene 350

96 24205-99-2 Benzo[b]fluoranthene 580

96 29207-08-9 Benzo[k]fluoranthene 160

96 21191-24-2 Benzo[g,h,i]perylene 360

96 4250-32-8 Benzo[a]pyrene 420

96 17U111-44-4 Bis(2-chloroethyl)ether 96

4700 510J117-81-7 Bis(2-ethylhexyl) phthalate 810

470 330U85-68-7 Butyl benzyl phthalate 470

2400 310U105-60-2 Caprolactam 2400

96 22J86-74-8 Carbazole 26

FORM I EPA 8270E LL

FORM I

GC/MS SEMI VOA ORGANICS ANALYSIS DATA SHEET

Client Sample ID:

Lab Name: Job No.:

#20210944 COMPOSITE W

SDG No.:

180-126039-1

Lab Sample ID: 180-126039-5

Eurofins TestAmerica, Pittsburgh

Matrix: N08270026.DLab File ID:

Date Collected:EPA 8270E LLAnalysis Method:

Sediment

08/16/2021 10:55

Level: (low/med)

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Analyzed:

Date Extracted:

Dilution Factor:

Extract. Method: 08/26/2021 15:18

08/27/2021 17:53

Low2(uL)

0.5(mL)

% Moisture: 65.4

Sample wt/vol: 30.2(g)

Analysis Batch No.: 369409 ug/KgUnits:

CAS NO. COMPOUND NAME RESULT Q MDLRL

96 53218-01-9 Chrysene 400

96 61J53-70-3 Dibenz(a,h)anthracene 85

470 180U132-64-9 Dibenzofuran 470

470 210U84-74-2 Di-n-butyl phthalate 470

470 280U117-84-0 Di-n-octyl phthalate 470

470 170J84-66-2 Diethyl phthalate 190

96 25206-44-0 Fluoranthene 590

96 19J86-73-7 Fluorene 64

96 34U118-74-1 Hexachlorobenzene 96

96 28U87-68-3 Hexachlorobutadiene 96

470 49U77-47-4 Hexachlorocyclopentadiene 470

470 170U67-72-1 Hexachloroethane 470

96 48193-39-5 Indeno[1,2,3-cd]pyrene 290

470 180U78-59-1 Isophorone 470

96 19J91-20-3 Naphthalene 67

960 180U98-95-3 Nitrobenzene 960

470 180U62-75-9 N-Nitrosodimethylamine 470

470 160U86-30-6 N-Nitrosodiphenylamine 470

96 32U621-64-7 N-Nitrosodi-n-propylamine 96

2400 770U87-86-5 Pentachlorophenol 2400

96 2685-01-8 Phenanthrene 220

470 150U108-95-2 Phenol 470

96 23129-00-0 Pyrene 650

470 450U91-94-1 3,3'-Dichlorobenzidine 470

%RECCAS NO. LIMITSQSURROGATE

89 37-107321-60-8 2-Fluorobiphenyl

79 38-106367-12-4 2-Fluorophenol (Surr)

58 22-116118-79-6 2,4,6-Tribromophenol (Surr)

82 41-1124165-60-0 Nitrobenzene-d5 (Surr)

89 40-1104165-62-2 Phenol-d5 (Surr)

96 32-1151718-51-0 Terphenyl-d14 (Surr)

FORM I EPA 8270E LL

Report Date: 30-Aug-2021 05:33:43 Chrom Revision: 2.3 13-May-2021 07:57:40

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CH733\20210827-38846.b\N08270026.D Lims ID: 180-126039-A-5-B Client ID: #20210944 COMPOSITE W Sample Type: Client Inject. Date: 27-Aug-2021 17:53:30 ALS Bottle#: 25 Worklist Smp#: 26 Injection Vol: 2.0 ul Dil. Factor: 10.0000 Sample Info: 180-0038846-026 Operator ID: 03200 Instrument ID: CH733

Method: \\chromfs\Pittsburgh\ChromData\CH733\20210827-38846.b\BNA_CH733.m Limit Group: BNA 8270E ICAL Last Update: 30-Aug-2021 05:33:39 Calib Date: 16-Jul-2021 07:37:30 Integrator: RTE ID Type: Deconvolution ID Quant Method: Internal Standard Quant By: Initial Calibration Last ICal File: \\chromfs\Pittsburgh\ChromData\CH733\20210716-38233.b\N07160011.D

Column 1 : Rxi-5SilMS ( 0.32 mm) Det: MS SCAN Process Host: CTX1681

First Level Reviewer: piccolinov Date: 30-Aug-2021 03:56:57

Compound Sig

(min.)

Adj RT (min.)

Dlt RT (min.) Q Response

OnCol Amt ng Flags

* 1 1,4-Dichlorobenzene-d4 152 5.757 5.757 0.000 96 109701 8.00

* 2 Naphthalene-d8 136 6.986 6.981 0.006 100 411930 8.00

* 3 Acenaphthene-d10 164 8.616 8.598 0.018 94 269088 8.00

* 4 Phenanthrene-d10 188 9.974 9.951 0.023 96 558612 8.00

* 5 Chrysene-d12 240 13.004 12.962 0.042 99 576418 8.00

* 6 Perylene-d12 264 15.139 15.098 0.041 99 604216 8.00 $ 7 2-Fluorophenol 112 4.357 4.351 0.006 91 42079 3.15 $ 8 Phenol-d5 99 5.428 5.422 0.006 99 64978 3.55 $ 9 Nitrobenzene-d5 82 6.298 6.298 0.000 90 56009 3.28 $ 10 2-Fluorobiphenyl 172 7.992 7.980 0.012 99 153180 3.54 $ 11 2,4,6-Tribromophenol 330 9.339 9.316 0.023 88 15882 2.31 $ 12 Terphenyl-d14 244 11.533 11.498 0.035 98 257639 3.82 14 N-Nitrosodimethylamine 74 1.798 ND 22 Benzaldehyde 77 5.304 5.304 0.000 81 3221 0.2433 24 Phenol 94 5.434 ND U 26 Bis(2-chloroethyl)ether 93 5.504 ND 27 2-Chlorophenol 128 5.545 ND 33 2-Methylphenol 108 6.028 ND 35 2,2'-oxybis[1-chloropropane] 45 6.045 ND 39 Acetophenone 105 6.157 ND 38 N-Nitrosodi-n-propylamine 70 6.163 ND 40 4-Methylphenol 108 6.175 ND U 41 Hexachloroethane 117 6.257 ND 42 Nitrobenzene 77 6.316 ND 44 Isophorone 82 6.545 ND 47 2,4-Dimethylphenol 107 6.675 ND 51 2,4-Dichlorophenol 162 6.851 ND 53 Naphthalene 128 7.010 6.998 0.012 95 13811 0.2804 57 Hexachlorobutadiene 225 7.133 ND 61 Caprolactam 113 7.339 ND 65 2-Methylnaphthalene 142 7.657 7.645 0.012 91 6979 0.1941 67 Hexachlorocyclopentadiene 237 7.798 ND

Data File: \\chromfs\Pittsburgh\ChromData\CH733\20210827-38846.b\N08270026.D

Compound Sig

(min.)

Adj RT (min.)

Dlt RT (min.) Q Response

OnCol Amt ng Flags

69 2,4,6-Trichlorophenol 196 7.904 ND 70 2,4,5-Trichlorophenol 196 7.933 ND 71 1,1'-Biphenyl 154 8.069 ND U 73 2-Chloronaphthalene 162 8.092 ND 75 2-Nitroaniline 65 8.175 ND 79 2,6-Dinitrotoluene 165 8.392 ND 80 Acenaphthylene 152 8.486 8.469 0.017 98 33901 0.5806 83 Acenaphthene 153 8.645 8.627 0.018 85 5756 0.1572 82 2,4-Dinitrophenol 184 8.639 ND 87 2,4-Dinitrotoluene 165 8.757 ND U 88 Dibenzofuran 168 8.804 8.786 0.018 94 7351 0.1357 93 Diethyl phthalate 149 8.998 8.980 0.018 97 33665 0.8124 98 Fluorene 166 9.122 9.098 0.024 89 11584 0.2686 99 4,6-Dinitro-2-methylphenol 198 9.133 ND 101 N-Nitrosodiphenylamine 169 9.192 ND U 103 1,2-Diphenylhydrazine 77 9.233 ND U 109 Hexachlorobenzene 284 9.610 ND 111 Atrazine 200 9.669 ND U 115 Pentachlorophenol 266 9.780 ND 118 Phenanthrene 178 9.998 9.974 0.024 95 62635 0.9288 119 Anthracene 178 10.045 10.021 0.024 96 39050 0.5701 121 Carbazole 167 10.180 10.157 0.023 91 6657 0.1068 122 Di-n-butyl phthalate 149 10.480 10.451 0.029 93 7077 0.0971 128 Fluoranthene 202 11.133 11.086 0.047 97 206857 2.45 129 Benzidine 184 11.210 ND U 131 Pyrene 202 11.374 11.339 0.035 97 228139 2.71 137 Butyl benzyl phthalate 149 12.121 ND U 141 3,3'-Dichlorobenzidine 252 12.898 ND U 143 Benzo[a]anthracene 228 12.986 12.951 0.035 95 125240 1.46 142 Bis(2-ethylhexyl) phthalate 149 13.004 12.968 0.036 93 152889 3.40 144 Chrysene 228 13.039 13.004 0.035 96 142778 1.68 147 Di-n-octyl phthalate 149 13.951 ND U 149 Benzo[b]fluoranthene 252 14.592 14.545 0.047 95 240669 2.43 150 Benzo[k]fluoranthene 252 14.627 14.586 0.041 1 63404 0.6577 a 152 Benzo[a]pyrene 252 15.056 15.015 0.041 75 155357 1.74 156 Indeno[1,2,3-cd]pyrene 276 16.745 16.686 0.059 97 117478 1.20 157 Dibenz(a,h)anthracene 278 16.756 16.709 0.047 59 30437 0.3567 158 Benzo[g,h,i]perylene 276 17.203 17.139 0.064 97 129883 1.51

QC Flag Legend Processing Flags Review Flags U - Marked Undetected a - User Assigned ID Reagents:

SVTAPITINTRNi_00027 Amount Added: 1.00 Units: uL Run Reagent

Data File: \\chromfs\Pittsburgh\ChromData\CH733\20210827-38846.b\N08270026.D Injection Date: 27-Aug-2021 17:53:30 Instrument ID: CH733 Operator ID: 03200 Lims ID: 180-126039-A-5-B Lab Sample ID: 180-126039-5 Worklist Smp#: 26 Client ID: #20210944 COMPOSITE W Injection Vol: 2.0 ul Dil. Factor: 10.0000 ALS Bottle#: 25 Method: BNA_CH733 Limit Group: BNA 8270E ICAL Column: Rxi-5SilMS ( 0.32 mm)

1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 18.0 Min

Y (X

N08270026[MS SCAN Chro]:Total

Fl uo ro ph en ol

P he no l-d 5(

1, 4- D ic hl or ob en ze ne -d

N itr ob en ze ne -d

N ap ht ha le ne -d

Fl uo ro bi ph en yl

A ce na ph th yl en e(

A ce na ph th en e-d1 0(

D ib en zo fu ra n(

D ie th yl p ht ha la te

F lu or en e(

2, 4, 6-

Tr ib ro m op he no l(

P he na nt hr en e-d1 0(

P he na nt hr en e(

A nt hr ac en e(

C ar ba zo le ( 1

D i-n

-b ut yl p ht ha la te

( 1 0.

3) F lu or an th en e(

P yr en e(

Te rp he ny l-d

( 1

C hr ys en e-d1 2(

C hr ys en e(

+ B en zo [b

]fl uo ra nt he ne

( 1 4.

B en zo [a

]p yr en e(

P er yl en e-d1

D ib en z( a, h) an th ra ce ne ( 1

Recovery Report

Column 1 : Rxi-5SilMS ( 0.32 mm) Det: MS SCAN Process Host: CTX1681

First Level Reviewer: piccolinov Date: 30-Aug-2021 03:56:57

Compound Amount Added

Amount Recovered % Rec.

$ 7 2-Fluorophenol 40.0 3.15 78.73

$ 8 Phenol-d5 40.0 3.55 88.80

$ 9 Nitrobenzene-d5 40.0 3.28 82.10

$ 10 2-Fluorobiphenyl 40.0 3.54 88.54

$ 11 2,4,6-Tribromophenol 40.0 2.31 57.73

$ 12 Terphenyl-d14 40.0 3.82 95.54

Data File: \\chromfs\Pittsburgh\ChromData\CH733\20210827-38846.b\N08270026.D Injection Date: 27-Aug-2021 17:53:30 Instrument ID: CH733 Lims ID: 180-126039-A-5-B Lab Sample ID: 180-126039-5 Client ID: #20210944 COMPOSITE W Operator ID: 03200 ALS Bottle#: 25 Worklist Smp#: 26 Injection Vol: 2.0 ul Dil. Factor: 10.0000 Method: BNA_CH733 Limit Group: BNA 8270E ICAL Column: Rxi-5SilMS ( 0.32 mm) Detector MS SCAN 65 2-Methylnaphthalene, CAS: 91-57-6

30 50 70 90 110 130 150 170 190 m/z

Y (X

Raw Spec:Scan 1117(7.66)

41 11569 55 81

95 109 13940 143 187163

30 50 70 90 110 130 150 170 190 m/z

Y (X

Amdis Enhanced Spec: Scan 1117(7.66), Qvalue=91 Sig Qvalue=84

13941 70 14381 85 109

30 50 70 90 110 130 150 170 190

Ref Spec: 65 2-Methylnaphthalene (NIST98.L)

14371 13939 51

30 50 70 90 110 130 150 170 190 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 7.660 min.(Qvalue: 91)

11541 70

7.1 7.4 7.7 8.0 Min

Y (X

0) m/z 142.0

7.1 7.4 7.7 8.0 Min

Y (X

0) m/z 141.0

7.1 7.4 7.7 8.0 Min

Y (X

0) m/z 115.0

7.1 7.4 7.7 8.0 Min

Y (X

0) m/z 142.0 m/z 141.0 m/z 115.0

30 50 70 90 110 130 150 170 190 210 m/z

Y (X

Raw Spec:Scan 1285(8.65)

55 153 154 6941 81 152

155 179

30 50 70 90 110 130 150 170 190 210 m/z

Y (X

Amdis Enhanced Spec: Scan 1285(8.65), Qvalue=85 Sig Qvalue=80

155139 204

30 50 70 90 110 130 150 170 190 210

Ref Spec: 83 Acenaphthene (NIST98.L)

63 15577

30 50 70 90 110 130 150 170 190 210 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 8.650 min.(Qvalue: 85)

152 168

8.1 8.4 8.7 9.0 Min

Y (X

0) m/z 153.0

8.1 8.4 8.7 9.0 Min

Y (X

0) m/z 154.0

8.1 8.4 8.7 9.0 Min

Y (X m/z 152.0

8.1 8.4 8.7 9.0 Min

Y (X m/z 153.0 m/z 154.0 m/z 152.0

30 50 70 90 110 130 150 170 190 210 m/z

Y (X

Raw Spec:Scan 1258(8.49)

41 55 69 15395 109 123

30 50 70 90 110 130 150 170 190 210 m/z

Y (X

Amdis Enhanced Spec: Scan 1258(8.49), Qvalue=98 Sig Qvalue=100

15376

30 50 70 90 110 130 150 170 190 210

Ref Spec: 80 Acenaphthylene (NIST98.L)

15176 153

30 50 70 90 110 130 150 170 190 210 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 8.490 min.(Qvalue: 98)

7.9 8.2 8.5 8.8 Min

Y (X m/z 152.0

7.9 8.2 8.5 8.8 Min

Y (X m/z 151.0

7.9 8.2 8.5 8.8 Min

Y (X

0) m/z 153.0

7.9 8.2 8.5 8.8 Min

Y (X m/z 152.0 m/z 151.0 m/z 153.0

30 50 70 90 110 130 150 170 190 210 230 250 270 m/z

Y (X

Raw Spec:Scan 1523(10.05)

69 95

176 179111 151

30 70 110 150 190 230 270 m/z

Y (X

Amdis Enhanced Spec: Scan 1523(10.05), Qvalue=96 Sig Qvalue=100

17915289

30 50 70 90 110 130 150 170 190 210 230 250 270

Ref Spec: 119 Anthracene (NIST98.L)

17989 152

30 50 70 90 110 130 150 170 190 210 230 250 270 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 10.040 min.(Qvalue: 96)

9.5 9.8 10.1 10.4 Min

Y (X m/z 178.0

9.5 9.8 10.1 10.4 Min

Y (X m/z 176.0

9.5 9.8 10.1 10.4 Min

Y (X m/z 179.0

9.5 9.8 10.1 10.4 Min

Y (X m/z 178.0 m/z 176.0 m/z 179.0

30 70 110 150 190 230 270 310 350 390 m/z

Y (X

Raw Spec:Scan 2023(12.99)

228 240

95 226

149 241

30 70 110 150 190 230 270 310 350 390 m/z

Y (X

Amdis Enhanced Spec: Scan 2023(12.99), Qvalue=95 Sig Qvalue=93

67 113 125 224165

30 70 110 150 190 230 270 310 350 390

Ref Spec: 143 Benzo[a]anthracene (NIST98.L)

30 70 110 150 190 230 270 310 350 390 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 12.990 min.(Qvalue: 95)

93 125 226 229

12.4 12.7 13.0 13.3 Min

Y (X m/z 228.0

12.4 12.7 13.0 13.3 Min

Y (X m/z 229.0

12.4 12.7 13.0 13.3 Min

Y (X m/z 226.0

12.4 12.7 13.0 13.3 Min

Y (X m/z 228.0 m/z 229.0 m/z 226.0

Report Date: 30-Aug-2021 05:33:44 Chrom Revision: 2.3 13-May-2021 07:57:40

30 70 110 150 190 230 270 310 350 390 430 470 510 550 m/z

Y (X

Raw Spec:Scan 2296(14.59)

250 253

30 70 110 150 190 230 270 310 350 390 430 470 510 550 m/z

Y (X

Amdis Enhanced Spec: Scan 2296(14.59), Qvalue=95 Sig Qvalue=97

250 253

30 70 110 150 190 230 270 310 350 390 430 470 510 550

Ref Spec: 149 Benzo[b]fluoranthene (NIST98.L)

126 253250

30 70 110 150 190 230 270 310 350 390 430 470 510 550 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 14.590 min.(Qvalue: 95)

14.0 14.3 14.6 14.9 Min

Y (X

0) m/z 252.0

14.0 14.3 14.6 14.9 Min

Y (X m/z 253.0

14.0 14.3 14.6 14.9 Min

Y (X m/z 125.0

14.0 14.3 14.6 14.9 Min

Y (X

0) m/z 252.0 m/z 253.0 m/z 125.0

30 70 110 150 190 230 270 310 350 390 430 470 m/z

Y (X

Raw Spec:Scan 2302(14.63)

57 69 25281

253250207

30 70 110 150 190 230 270 310 350 390 430 470 m/z

Y (X

Enhanced Spec:Scan 2302(14.63) Bgrd 2300(14.62), Qvalue=1

25169

173115

458418336

30 70 110 150 190 230 270 310 350 390 430 470

Ref Spec: 150 Benzo[k]fluoranthene (NIST98.L)

253250126

30 70 110 150 190 230 270 310 350 390 430 470 m/z

-100

-75

-50

-25

Differenc Spec:Scan 2302 @ 14.627 min.(Qvalue: 1)

57 25169 12381

229173115 261 458418

14.1 14.4 14.7 15.0 Min

Y (X

0) m/z 252.0

14.1 14.4 14.7 15.0 Min

Y (X m/z 253.0

14.1 14.4 14.7 15.0 Min

Y (X m/z 125.0

14.1 14.4 14.7 15.0 Min

Y (X

0) m/z 252.0 m/z 253.0

30 70 110 150 190 230 270 310 350 390 430 470 510 m/z

Y (X

Raw Spec:Scan 2740(17.20)

27657 69

109 207

277138 274

233 283

30 70 110 150 190 230 270 310 350 390 430 470 510 m/z

Y (X

Amdis Enhanced Spec: Scan 2740(17.20), Qvalue=97 Sig Qvalue=98

277274138

30 70 110 150 190 230 270 310 350 390 430 470 510

Ref Spec: 158 Benzo[g,h,i]perylene (NIST98.L)

277138

30 70 110 150 190 230 270 310 350 390 430 470 510 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 17.200 min.(Qvalue: 97)

16.7 17.0 17.3 17.6 Min

Y (X m/z 276.0

16.7 17.0 17.3 17.6 Min

Y (X m/z 138.0

16.7 17.0 17.3 17.6 Min

Y (X m/z 277.0

16.7 17.0 17.3 17.6 Min

Y (X m/z 276.0 m/z 138.0

30 70 110 150 190 230 270 310 350 390 430 470 m/z

Y (X

Raw Spec:Scan 2375(15.06)

109 253250 126 207

30 70 110 150 190 230 270 310 350 390 430 470 m/z

Y (X

Amdis Enhanced Spec: Scan 2375(15.06), Qvalue=75 Sig Qvalue=84

253250

254224

30 70 110 150 190 230 270 310 350 390 430 470

Ref Spec: 152 Benzo[a]pyrene (NIST98.L)

113 250

24899

30 70 110 150 190 230 270 310 350 390 430 470 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 15.060 min.(Qvalue: 75)

251 253

14.5 14.8 15.1 15.4 Min

Y (X

0) m/z 252.0

14.5 14.8 15.1 15.4 Min

Y (X m/z 253.0

14.5 14.8 15.1 15.4 Min

Y (X m/z 125.0

14.5 14.8 15.1 15.4 Min

Y (X

0) m/z 252.0 m/z 253.0

30 70 110 150 190 230 270 310 350 m/z

Y (X

Raw Spec:Scan 2026(13.00)

149 236 24157 69 120 167

30 70 110 150 190 230 270 310 350 m/z

Y (X

Amdis Enhanced Spec: Scan 2026(13.00), Qvalue=93 Sig Qvalue=97

16757

235104 240

30 70 110 150 190 230 270 310 350

Ref Spec: 142 Bis(2-ethylhexyl) phthalate (NIST98.L)

57 167

113 279112

30 70 110 150 190 230 270 310 350 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 13.000 min.(Qvalue: 93)

23597 24065 104 167

12.5 12.8 13.1 13.4 Min

Y (X

0) m/z 149.0

12.5 12.8 13.1 13.4 Min

Y (X m/z 167.0

12.5 12.8 13.1 13.4 Min

Y (X m/z 279.0

12.5 12.8 13.1 13.4 Min

Y (X

0) m/z 149.0 m/z 167.0

30 50 70 90 110 130 150 170 190 210 230 250 270 m/z

Y (X

Raw Spec:Scan 1546(10.18)

69 95

167123

179 205 231 278

30 70 110 150 190 230 270 m/z

Y (X

Amdis Enhanced Spec: Scan 1546(10.18), Qvalue=91 Sig Qvalue=95

95 166 18165 205110 27472 253

30 50 70 90 110 130 150 170 190 210 230 250 270

Ref Spec: 121 Carbazole (NIST98.L)

139 16884

30 50 70 90 110 130 150 170 190 210 230 250 270 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 10.180 min.(Qvalue: 91)

18165 205151110

9.6 9.9 10.2 10.5 Min

Y (X

0) m/z 167.0

9.6 9.9 10.2 10.5 Min

Y (X

0) m/z 166.0

9.6 9.9 10.2 10.5 Min

Y (X

0) m/z 168.0

9.6 9.9 10.2 10.5 Min

Y (X

0) m/z 167.0 m/z 166.0 m/z 168.0

30 70 110 150 190 230 270 310 350 m/z

Y (X

Raw Spec:Scan 2032(13.04)

55 57

97 226

123 165 225 230

30 70 110 150 190 230 270 310 350 m/z

Y (X

Amdis Enhanced Spec: Scan 2032(13.04), Qvalue=96 Sig Qvalue=94

11383 114 225

30 70 110 150 190 230 270 310 350

Ref Spec: 144 Chrysene (NIST98.L)

226 229114

30 70 110 150 190 230 270 310 350 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 13.040 min.(Qvalue: 96)

12.5 12.8 13.1 13.4 Min

Y (X m/z 228.0

12.5 12.8 13.1 13.4 Min

Y (X m/z 226.0

12.5 12.8 13.1 13.4 Min

Y (X m/z 229.0

12.5 12.8 13.1 13.4 Min

Y (X m/z 228.0 m/z 226.0 m/z 229.0

30 70 110 150 190 230 270 310 350 390 430 470 510 550 m/z

Y (X

Raw Spec:Scan 2664(16.76)

123 278 274 281

30 70 110 150 190 230 270 310 350 390 430 470 510 550 m/z

Y (X

Amdis Enhanced Spec: Scan 2664(16.76), Qvalue=59 Sig Qvalue=96

13869 139 191 279271

30 70 110 150 190 230 270 310 350 390 430 470 510 550

Ref Spec: 157 Dibenz(a,h)anthracene (NIST98.L)

139 279276 137 274 280149

30 70 110 150 190 230 270 310 350 390 430 470 510 550 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 16.750 min.(Qvalue: 59)

27727485

16.2 16.5 16.8 17.1 Min

Y (X m/z 278.0

16.2 16.5 16.8 17.1 Min

Y (X

0) m/z 139.0

16.2 16.5 16.8 17.1 Min

Y (X

0) m/z 279.0

16.2 16.5 16.8 17.1 Min

Y (X m/z 278.0 m/z 139.0

30 50 70 90 110 130 150 170 190 210 230 m/z

Y (X

Raw Spec:Scan 1345(9.00)

64 149 192

69 12855 19441 17796

207176130

30 50 70 90 110 130 150 170 190 210 230 m/z

Y (X

Amdis Enhanced Spec: Scan 1345(9.00), Qvalue=97 Sig Qvalue=97

17712364 76 93 194176 20750

30 50 70 90 110 130 150 170 190 210 230

Ref Spec: 93 Diethyl phthalate (NIST98.L)

15065 10576 178121

30 50 70 90 110 130 150 170 190 210 230 m/z

-100

-75

-50

-25

Differenc Spec:Scan 1 @ 9.000 min.(Qvalue: 97)

64 76 93 150

8.4 8.7 9.0 9.3 Min

Y (X m/z 149.0

8.4 8.7 9.0 9.3 Min

Y (X m/z 177.0

8.4 8.7 9.0 9.3 Min

Y (X

0) m/z 150.0

8.4 8.7 9.0 9.3 Min

Y (X m/z 149.0 m/z 177.0 m/z 150.0

This is the start of the file's text. The full file is on GovTribe.

File details come from the government source that posted it. Updated Apr 12, 2023.