Auburn_Anode and Cathode Contaminant Removal.ppt

Anode and Cathode Contaminant Removal Bruce J. Tatarchuk Department of Chemical Engineering Auburn University, AL 36849 334·844·2023, brucet@eng.auburn.edu

Outline

Center for Microfibrous Materials Manufacturing Organization

Bruce J. Tatarchuk Director Megan Schumacher Admstr I, Acad Programs Dwight Cahela Engineering Tech

Adsorption Vivekandand Gaur Post Doctoral Fellow Group Leader Primary Members Hongyun Yang ShirishPunde Ranjeeth Kalluri Priyanka Dhage Sachin Nair Symon Sheng Secondary Members Don Cahela Alex Smaokhvalov Abhijeet Phalle Zenda Davis Catalysis Donald Cahela Research Fellow III Group Leader Primary Members Shirish Punde Bob Henderson Secondary Members Alex Samokhvalov Symon Sheng Qiang Gu Divya Repala Joy Zhu Naren Pari Pallavie Chitta Ron Putt

Physiochem Modeling Donald Cahela Research Fellow III Group Leader Primary Members Ravi Duggirala, Ranjeeth Kalluri

Secondary Members Shirish Punde Priyanka Dhage Sachin Nair Ron Putt Fuel Cells/Elec Chem Wenhua Zhu Research Fellow IV Group Leader Primary Members Robert Payne, Naren Pari Joy Zhu Secondary Members Don Cahela Ron Putt Surface Science Alexandr Samokhvalov Post Doctoral Fellow Group Leader Primary Members Dwight Cahela Divya Repala Zenda Davis Bob Henderson Secondary Members

Student Workers

Filtration Ron Putt Research Professor Group Leader Primary Members Ryan Sothen Abhijeet Phalle Pallavi Chitta Amogh Karwa Qiang Gu Secondary Members Vivek Gaur Don Cahela

Liquid Phase Desulfurization of Log Fuels Sorbent evaluation Sorbent scale-up Microfibrous entrapped sorbents System level design of continuous desulfurizers Antek 9000VS Total Sulfur Analyzer Varian CP3800 GC w/PFPD BET/Chemsorb station Sulfur quantification to the ppbw levels Characterization of sorbent/catalytic materials

X-Ray Photoelectron Spectroscopy (XPS) Temperature Programmed Desorption (TPD) V-Blender Tumbler Sorbent Scale-up

Sorbent Evaluation for JP5

Saturation Tests Multi-cycle performance of Ag/TiO2

Test conditions: Particle size: 0.8-2.0 mm; Bed weight: 10 g; Feed Stream: JP5 (1172 ppmw Sulfur) ;JP5 flow rate: 0.5 cc/min LHSV: 2.13 (h-1) Composition: Ag(4%)/TiO2; Ag(8%)/Al2O3; Cu-Y (Ion Exchanged); PdCl2 (8%)/Al2O3

B. J. Tatarchuk, H. Yang and S. Nair, Silver-based adsorbents, Final Patent Application to be submitted in May, 2008 Nair, Sachin; Yang, Hongyun; Tatarchuk, Bruce. American Institute of Chemical Engineers Annual Meeting, Salt Lake City (2007) Nair, Sachin; Yang Hongyun; Tatarchuk, Bruce. American Institute of Chemical Engineers Annual Meeting, Salt Lake City (2007)

Chart1

0.1 0.1 0.1 0.1 0.1

0.25 0.25 0.5 0.4 0.5

0.5 0.5 1 0.9 1.05

1 0.75 1.4 1.5 1.5

1.5 1 2 2.15 2.15

2 2 3.15 3.05 2.5

2.6 2.5 4.2 4.65 3.55

3.1 3 5 5.6 5

3.5 4.55 6 6

4.15 5.65

5.05

10.5

Fresh

Cycle 1

Cycle 4

Cycle 5

Cycle 9

Vol of JP5 (cc)/Weight of adsorbent (g)

Exit sulfur conc. (ppmw)

3.566550434

12.8668727217

31.7350268633

10.4379646472

6.2915034406

9.304594059

7.7434555887

13.9536796976

12.504094685

19.2506396365

12.2750655234

7.1849022136

32.0810836564

25.4645827201

62.4923726188

21.8413828247

9.2852767194

28.0675036965

31.5398869161

48.6805910522

27.9745972581

21.1868768537

40.9776363015

52.4244105951

93.6330214023

34.1304610144

21.7450487947

102.2857233032

103.5947052836

110.4514424686

51.9891350564

25.0324556286

489.3626666662

193.6137529919

780.910411159

84.2623173182

31.5201834863

641.5687092415

892.7319979307

1162.782219794

241.5165333326

147.1973000143

770.0945355496

1264.5833808031

386.7587255932

603.3489886885

583.7481941288

645.4207815443

804.5754746196

909.5113900197

BT Data

ATITANF28 Fresh

Time Volume cc/gm Area Response Split

1 0 1 0.1 549 23.4307490277 0 3.566550434 Batch No G11

2 5 2.5 0.25 3254.5 57.0482252134 0 9.304594059 Titania Grade 1/8 Pellets-Gobain

3 10 5 0.5 5543 74.4513263817 0 12.2750655234 Surface Area [Support] 153 m2/g

4 20 10 1 17029.6 130.4975095548 0 21.8413828247 Final Surface Area m2/g

5 30 15 1.5 7929.8 89.0494244788 20 27.9745972581 Pore Diameter 158 A

6 40 20 2 12353 111.144050673 20 34.1304610144 Pore Volume 0.46 cc/g

7 52 26 2.6 30709.9 175.2424035443 20 51.9891350564 Particle Size 1.4-0.8 mm

8 62 31 3.1 84726 291.0773093183 20 84.2623173182 Silver Loading 2.5 %

9 70 35 3.5 11683.7 108.0911652264 60 241.5165333326 Percentage Wetness 91 %

10 83 41.5 4.15 25758.5 160.494548194 60 386.7587255932 Batch Weight 100 g

11 101 50.5 5.05 53623.9 231.5683484417 60 583.7481941288 Imp-Dry-Crush-Calcine

12 120 60 6 64424.5 253.8198179812 60 645.4207815443

13 180 90 9 96872.1 311.2428312427 60 804.5754746196

14 210 105 10.5 121873.4 349.1037095191 60 909.5113900197

ATITANF28R1

Time Volume cc/gm Area Response Split

1 0 1 0.1 6071.3 77.9185472144 0 12.8668727217

2 5 2.5 0.25 2294.6 47.9019832575 0 7.7434555887

3 10 5 0.5 1991.8 44.629586599 0 7.1849022136

4 15 7.5 0.75 3241.6 56.9350507157 0 9.2852767194

5 20 10 1 4184.4 64.6869384034 20 21.1868768537

6 40 20 2 4447.6 66.690329134 20 21.7450487947

7 50 25 2.5 6160.6 78.4894897423 20 25.0324556286

8 60 30 3 10358.2 101.7752425691 20 31.5201834863

9 91 45.5 4.55 5485 74.0607858451 60 147.1973000143

10 113 56.5 5.65 56949.2 238.6403151188 60 603.3489886885

ATITANF28R4

Time Volume cc/gm Area Response Split

11 0 1 0.1 35517.7 188.4614018838 0 31.7350268633

12 10 5 0.5 7104.1 84.2858232445 0 13.9536796976

13 20 10 1 36286 190.4888448177 0 32.0810836564

14 28 14 1.4 7989.3 89.3828842676 20 28.0675036965

15 40 20 2 18419.9 135.7199322134 20 40.9776363015

16 63 31.5 3.15 126570.1 355.7669180798 20 102.2857233032

17 84 42 4.2 39011.8 197.5140501331 60 489.3626666662

18 100 50 5 63720.9 252.4299902943 60 641.5687092415

19 120 60 6 89282.7 298.8021084263 60 770.0945355496

ATITANF28R5

Time Volume cc/gm Area Response Split

1 0 1 0.1 4056.2 63.6883034787 0 10.4379646472

2 8 4 0.4 5744.6 75.7931395312 0 12.504094685

3 18 9 0.9 23020.4 151.7247507825 0 25.4645827201

4 30 15 1.5 10372.6 101.8459621193 20 31.5398869161

5 43 21.5 2.15 31259.9 176.8046945078 20 52.4244105951

6 61 30.5 3.05 129935.1 360.4651162041 20 103.5947052836

7 93 46.5 4.65 467256.3 683.5614822384 20 193.6137529919

8 112 56 5.6 117683.1 343.0497048534 60 892.7319979307

ATITANF28R9

Time Volume cc/gm Area Response Split

1 0 1 0.1 1552 39.3954312072 0 6.2915034406

2 10 5 0.5 13298.5 115.3191224386 0 19.2506396365

3 21 10.5 1.05 135909.8 368.6594634619 0 62.4923726188 0 y = 5.8587x + 2.5354

4 30 15 1.5 26688.9 163.3673774044 20 48.6805910522 20 y = 3.5892x - 11.357

5 43 21.5 2.15 105437 324.710640417 20 93.6330214023 40 y = 0.4716x + 13.975

6 50 25 2.5 148283 385.0753173082 20 110.4514424686 60 y = 0.3377x + 12.455

7 71 35.5 3.55 91630 302.7044763462 60 780.910411159 80 y = 0.2916x - 6.5145

8 100 50 5 194026 440.4838249017 60 1162.782219794

9 120 60 6 227732.9 477.2136837937 60 1264.5833808031

F28R12

Time Volume cc/gm Area Response Split

1 0 1 0.1 1552 39.3954312072 20 14.1403185131

2 6 3 0.3 13298.5 115.3191224386 40 214.8942375712

3 11 5.5 0.55 135909.8 368.6594634619 40 62.4923726188

4 21 10.5 1.05 26688.9 163.3673774044 60 446.882965367

5 31 15.5 1.55 105437 324.710640417 60 924.6539544477

6 41 20.5 2.05 148283 385.0753173082 80 1342.9006080528

7 65 32.5 3.25 91630 302.7044763462 80 1060.4217295821

F28R12

Time Volume cc/gm Area Response Split

1 1 1 0.1 528.8 22.9956517629 20 9.5711166173

2 13 6.5 0.65 2656.9 51.5451258607 20 17.5253889058

3 23 11.5 1.15 3675.9 60.6292008854 40 9.9158176533

4 33 16.5 1.65 8776.3 93.6819086057 40 15.5574630218

5 43 21.5 2.15 12649.7 112.4708851214 60 296.1678564449

6 53 26.5 2.65 19306.3 138.9471122406 80 498.8395481502

7 68 34 3.4 51114 226.0840551653 80 797.6630835574

8 83 41.5 4.15 70270.6 265.0860237734 80 931.414690581

Microfibrous Entrapped Supported Ag Sorbent

1ppmw@0.75 1ppmw @ 0.25 Test conditions: Packed Bed: Ag (5.6 wt%)/SiO2 Particle size: 2.0-0.8 mm; Bed weight: 10 g Feed Stream: JP5 (1172 ppmw Sulfur) JP5 flow rate: 0.5 cc/min; LHSV: 2.13 (h-1) Face Velocity: 0.25 cm/min

Polishing layer Weight 1.0g; Thickness 0.7cm; Particle size 100-200um 10µm E-Type Glass filbers Glass fiber entrapped SiO2 particles Polishing Filter Individual data pts removed for visual clarity

1 1

Packed Bed

Composite Bed cc of fuel /g of adsorbent

C/C0

Breakthrough Test

BT TEST 472.3

Area *40 Resp

Time Volume cc/gm Area Split Act Area Blank Corr Area Response C/C0 JP5 NewB 210935.7 8437428 2904.7251160824 116189.004643297

1 1 0.5 0.0311683778 507 0 507 472.3 0 0 0

2 3 1.5 0.0935051334 363.6 0 363.6 472.3 0 0 0

3 8 4 0.2493470225 576 0 576 472.3 0 0 0

4 12 6 0.3740205337 565.8 0 565.8 472.3 93.5 9.6695398029 0.0031161907

5 18 9 0.5610308006 2648.7 20 2648.7 472.3 43528 208.6336502101 0.0672361103

6 23 11.5 0.7168726896 2800.2 20 56004 472.3 46558 215.7730288984 0.0695369091

7 28 14 0.8727145787 4326.9 20 86538 472.3 77092 277.6544615165 0.0894793624

8 33 16.5 1.0285564678 752.9 40 30116 472.3 11224 105.9433811052 0.0341422433

9 41 20.5 1.2779034902 647.5 40 25900 472.3 7008 83.7137981458 0.0269783429

10 60 30 1.8701026686 869.4 40 34776 472.3 15884 126.0317420335 0.0406160948

11 76 38 2.3687967136 2772.2 40 110888 472.3 91996 303.3084238857 0.0977468334

12 86 43 2.6804804917 7405.8 40 296232 472.3 277340 526.6308004665 0.1697166614

Time Volume cc/gm Area Split Act Area Blank Corr Area Response C/C0

1 1 0.5 0.0311683778 507 0 507 472.3 0 0 0 0.5726988223

2 3 1.5 0.0935051334 363.6 0 363.6 472.3 0 0 0 0

3 8 4 0.2493470225 576 0 576 472.3 0 0 0 1.3053953427

4 12 6 0.3740205337 4283 0 4283 472.3 3810.7 61.7308674814 0.0212518801 10.1038570812

5 18 9 0.5610308006 2648 20 2648 472.3 43514 208.6000958773 0.0718140602 67.2791195129

6 23 11.5 0.7168726896 5192.2 20 103844 472.3 94398 307.2425751747 0.1057733779 92.9434611808

7 28 14 0.8727145787 4326.9 20 86538 472.3 77092 277.6544615165 0.0955871766 85.1216995218

8 33 16.5 1.0285564678 9143 40 365720 472.3 346828 588.92104734 0.2027458872 122.3006924517

9 41 20.5 1.2779034902 9612.9 40 384516 472.3 365624 604.6685042236 0.2081672118 125.3238196464

10 60 30 1.8701026686 7230 40 289200 472.3 270308 519.9115309358 0.1789882109 109.1065371018

11 76 38 2.3687967136 18902.3 40 756092 472.3 737200 858.6035173466 0.2955885729 174.4644101836

12 86 43 2.6804804917 48340.5 40 1933620 472.3 1914728 1383.736969225 0.4763745171 277.1046986565

ASIL2B Grade 20 Blank 445 409.2

Time Volume cc/gm Area Split Act Area Blank Corr Area Response C/C0

1 2 1 0.1 330.4 0 330.4 445 0 0 0

2 5 2.5 0.25 1803.6 0 1803.6 445 1358.6 36.8591915267 0.0118785664 0

3 10 5 0.5 320328 0 320328 445 319883 565.582001128 0.1822694171 96.1043578145

4 15 7.5 0.75 396839 20 396839 445 396394 629.5982846228 0.2028998661 107.0310622873

5 20 10 1 550950.2 20 550950.2 445 550505.2 741.9603763005 0.2391106595 927.9836742661

6 25 12.5 1.25 640982 20 12819640 445 12819195 3580.3903418482 1.1538479993 1000.6890290927

7 30 15 1.5 754147.5 20 15082950 445 15082505 3883.6200895556 1.2515694778 1085.1684060159

8 35 17.5 1.75 190934.5 40 7637380 445 7636935 2763.5004975574 0.8905899122 547.5953457922

9 40 20 2 204317.6 40 8172704 445 8172259 2858.7163203088 0.9212749985 566.3525342604

10 45 22.5 2.25 194457.5 40 7778300 445 7777855 2788.8805998106 0.8987691266 552.595134817

11 50 25 2.5 193730.7 40 7749228 445 7748783 2783.6635931808 0.8970878483 551.567403026

12 55 27.5 2.75 212599 40 8503960 445 8503515 2916.0787026416 0.939761103 577.6527422595

13 60 30 3 222899 40 8915960 445 8915515 2985.8859656725 0.962257804 591.4045680501

ATITANF Blank 378 10g

Time Volume cc/gm Area Split Act Area Blank Corr Area Response C/C0

1 2 1 0.1 263.3 0 263.3 378 0 0 0

2 5 2.5 0.25 481.7 0 481.7 378 0 0 0 0

3 10 5 0.5 294.3 0 294.3 378 -83.7 0 0 0

4 15 7.5 0.75 1116.3 0 1116.3 378 738.3 27.1716764297 0.009354383 4.205075602

5 20 10 1 1266.2 20 1266.2 378 888.2 29.8026844428 0.0102601592 47.4996313674

6 25 12.5 1.25 2744.2 20 54884 378 54506 233.465200833 0.0803749788 68.4333570757

7 30 15 1.5 5331.2 20 106624 378 106246 325.9539844825 0.1122160583 94.1372625695

9 40 20 2 6975.6 40 279024 378 278646 527.8693020057 0.1817293703 107.2259624611

10 45 22.5 2.25 4728.9 40 189156 378 188778 434.4859031085 0.149580302 88.8443781444

11 50 25 2.5 7053.9 40 282156 378 281778 530.8276556473 0.1827478417 107.8083716295

12 55 27.5 2.75 5739.6 40 229584 378 229206 478.7546344423 0.1648206818 97.5574979256

13 60 30 3 7968.8 40 318752 378 318374 564.2464000771 0.1942529005 114.3877839676

8 35 17.5 1.75 4001.8 40 160072 378 159694 399.6173169421 0.1375761066 81.9826586747 EXCL

ATITANR1 Blank 517.9 10g

Time Volume cc/gm Area Split Act Area Blank Corr Area Response C/C0

1 2 1 0.1 832.7 0 832.7 517.9 0 0 0 0

2 5 2.5 0.25 484.5 0 484.5 517.9 0 0 0 0

3 10 5 0.5 697.5 0 697.5 517.9 179.6 0 0 0

4 15 7.5 0.75 3511.3 0 3511.3 517.9 2993.4 54.7119730955 0.0188356708 8.9058277597

5 20 10 1 2385.5 20 2385.5 517.9 1867.6 43.2157378741 0.0148778662 64.0182913606

6 25 12.5 1.25 3196.6 20 63932 517.9 63414.1 251.8215638106 0.0866945171 73.6082512708

7 30 15 1.5 6671.1 20 133422 517.9 132904.1 364.5601459293 0.1255069873 104.9293572043

8 35 17.5 1.75 7940.7 20 158814 517.9 158296.1 397.8644241447 0.1369726389 114.1915093813

9 40 20 2 3369.4 40 134776 517.9 134258.1 366.4124724951 0.1261446871 75.4872078963

10 45 22.5 2.25 5032.5 40 201300 517.9 200782.1 448.0871567006 0.1542628005 91.5519755676

11 50 25 2.5 7172 40 286880 517.9 286362.1 535.1281155013 0.1842283594 108.6807393957

12 60 30 3 7244.3 40 289772 517.9 289254.1 537.823484054 0.1851562929 109.211255539

13 70 35 3.5 15160.3 40 606412 517.9 605894.1 778.3919963617 0.2679767261 156.5744705104

14 80 40 4 23172.1 40 926884 517.9 926366.1 962.4791426312 0.3313523402 192.8274960487

15 90 45 4.5 35556.9 40 1422276 517.9 1421758.1 1192.3749829647 0.4104984966 238.1072430593

16 100 50 5 46064.5 40 1842580 517.9 1842062.1 1357.2258839265 0.4672516556 270.5780209601

17 120 60 6 58058.2 40 2322328 517.9 2321810.1 1523.7486997533 0.5245804041 303.3792579769

ATITANR2 Blank 433.7

ATITANR3 ATITANR4

Time Volume cc/gm Area Split Act Area Blank Corr Area Response C/C0

1 2 1 0.1 473.1 0 473.1 433.7 0 0 0 0 SAT

2 5 2.5 0.25 515.7 0 515.7 433.7 0 0 0 0 2D OVEN

3 10 5 0.5 448.9 0 448.9 433.7 15.2 3.8987177379 0.001256435 29.5623726927 200C 2HR

4 20 10 1 3486.9 0 3486.9 433.7 3053.2 55.2557689296 0.0190228832 76.737451821 450C 500C

5 25 12.5 1.25 2844.3 0 2844.3 433.7 2410.6 49.0978614606 0.0169029027 69.6131063412

6 30 15 1.5 6052.4 20 121048 433.7 120614.3 347.2956953376 0.1195633612 100.0955297597

7 35 17.5 1.75 6496 20 129920 433.7 129486.3 359.8420486825 0.1238826897 103.5849323679

8 40 20 2 7916 20 158320 433.7 157886.3 397.3490908509 0.1367952253 114.0186963346

9 50 25 2.5 18599.8 20 371996 433.7 371562.3 609.5591029589 0.209852688 173.088193038

10 60 30 3 6574.8 40 262992 433.7 262558.3 512.4044301136 0.1764052846 104.1921759767

11 70 35 3.5 11755.9 40 470236 433.7 469802.3 685.4212573301 0.235969724 138.2558288046

12 80 40 4 19443.4 40 777736 433.7 777302.3 881.647491915 0.3035244576 176.8989442509

13 90 45 4.5 30847.2 40 1233888 433.7 1233454.3 1110.6098774997 0.3823492538 221.9950283434

14 100 50 5 36120.2 40 1444808 433.7 1444374.3 1201.8212429475 0.413750557 239.9609400207

15 120 60 6 55925 40 2237000 433.7 2236566.3 1495.5153961093 0.514860535 297.8123247043

Scale-up of Ag/TiO2 and Other Sorbents Larger batches tested for consistent performance

Extended bed tests Test conditions: Ag(4%)/TiO2 Particle size: 0.8-2.0 mm; Bed weight: 10 g; Feed Stream: JP5 (1172 ppmw Sulfur) ;JP5 flow rate: 0.5 cc/min LHSV: 2.13 (h-1)

10 1 1

20 10 15

30 20 30

40 35 45

70 52 60

83 65 75

101 82 90

120 104 105

155 122

182 160

207 180

10g

20g

50g

Time (min)

Outlet sulfur conc. (ppmw)

11.501256062

7.351923347

7.0521828902

50.1603515094

12.2024120066

7.5534653711

60.4402226468

23.9873202211

12.3528898928

382.6342387505

34.3193971549

12.7201714122

519.2437691394

51.1144199852

19.4358198458

797.2458376216

285.2519755083

26.7547443696

828.0668102482

473.0191654564

28.8786066958

944.2811020447

647.0405765501

31.4649683329

831.3270169927

37.5249672573

865.0218227524

54.5526067631

1030.0412813972

65.6164378751

73.7115268535

516.6520924829

635.8377219323

794.9926212649

835.9300505243

848.0378511465

938.3835344917

1186.5144759073 cc-g

0.25 0.025 0.01

0.5 0.25 0.15

0.75 0.5 0.3

1 0.875 0.45

1.75 1.3 0.6

2.075 1.625 0.75

2.525 2.05 0.9

3 2.6 1.05

3.875 1.22

4.55 1.6

5.175 1.8

2.01

2.43

2.64

3.02

3.55

4.2

4.72

5.89

10g

20g

50g

Vol of JP5 (cc)/Weight of adsorbent (g)

Outlet sulfur conc. (ppmw)

11.501256062

7.351923347

7.0521828902

50.1603515094

12.2024120066

7.5534653711

60.4402226468

23.9873202211

12.3528898928

382.6342387505

34.3193971549

12.7201714122

519.2437691394

51.1144199852

19.4358198458

797.2458376216

285.2519755083

26.7547443696

828.0668102482

473.0191654564

28.8786066958

944.2811020447

647.0405765501

31.4649683329

831.3270169927

37.5249672573

865.0218227524

54.5526067631

1030.0412813972

65.6164378751

73.7115268535

516.6520924829

635.8377219323

794.9926212649

835.9300505243

848.0378511465

Vol

5 0.5 0.5

10 5 7.5

15 10 15

20 17.5 22.5

35 26 30

41.5 32.5 37.5

50.5 41 45

60 52 52.5

77.5 61

91 80

103.5 90

100.5

121.5

177.5

294.5

1X

2X

5X cc ppmw S

11.501256062

7.351923347

7.0521828902

50.1603515094

12.2024120066

7.5534653711

60.4402226468

23.9873202211

12.3528898928

382.6342387505

34.3193971549

12.7201714122

519.2437691394

51.1144199852

19.4358198458

797.2458376216

285.2519755083

26.7547443696

828.0668102482

473.0191654564

28.8786066958

944.2811020447

647.0405765501

31.4649683329

831.3270169927

37.5249672573

865.0218227524

54.5526067631

1030.0412813972

65.6164378751

73.7115268535

516.6520924829

635.8377219323

794.9926212649

835.9300505243

848.0378511465

Sheet1

ATVD13-2X 20g

Time cc/gm Area Split

1 1 0.5 0.025 2080.1 45.6081133133 0 7.351923347

2 10 5 0.25 5479.8 74.0256712229 0 12.2024120066

3 20 10 0.5 20469 143.0699129796 0 23.9873202211

4 35 17.5 0.875 12504.2 111.8221802685 20 34.3193971549

5 52 26 1.3 29619.4 172.1028762107 20 51.1144199852

6 65 32.5 1.625 22052.2 148.4998316497 40 285.2519755083

7 82 41 2.05 56193.1 237.0508384292 40 473.0191654564

8 104 52 2.6 53342.8 230.960602701 60 647.0405765501

9 155 77.5 3.875 85962.8 293.1941336384 60 831.3270169927

10 182 91 4.55 60381.2 245.7258635146 80 865.0218227524

11 207 103.5 5.175 86345.2 293.8455376554 80 1030.0412813972

ATVD11-1X

1 10 5 0.25 4888.5 69.9178088902 0 11.501256062

2 20 10 0.5 87858.8 296.4098513882 0 50.1603515094

3 30 15 0.75 42261.1 205.5750471239 20 60.4402226468

4 40 20 1 37801.2 194.4253069947 40 382.6342387505

5 70 35 1.75 35270.2 187.8036208384 60 519.2437691394

6 83 41.5 2.075 51059 225.9623862505 80 797.2458376216

7 101 50.5 2.525 55201.4 234.9497818684 80 828.0668102482

8 120 60 3 72273.8 268.8378693562 80 944.2811020447

ATVD135X

Time cc/gm Area Split

1 1 0.5 0.01 1923 43.8520238986 0 7.0521828902

2 15 7.5 0.15 2189.2 46.7888875696 0 7.5534653711

3 30 15 0.3 5611.1 74.9072760151 0 12.3528898928

4 45 22.5 0.45 5938.1 77.0590682529 0 12.7201714122

5 60 30 0.6 13549.9 116.4040377307 0 19.4358198458

6 75 37.5 0.75 7169.2 84.6711284914 20 26.7547443696

7 90 45 0.9 8518.2 92.2940951524 20 28.8786066958

8 105 52.5 1.05 10317.9 101.5770643403 20 31.4649683329

9 122 61 1.22 15209.7 123.3276124799 20 37.5249672573

11 160 80 1.6 34019.3 184.443216194 20 54.5526067631

12 180 90 1.8 50244.8 224.1535188214 20 65.6164378751

13 201 100.5 2.01 64114.5 253.2084121825 20 73.7115268535

14 243 121.5 2.43 20776.7 144.141250168 80 516.6520924829

15 264 132 2.64 32003.7 178.8957797155 80 635.8377219323

16 302 151 3.02 50762.5 225.3053483608 80 794.9926212649

17 355 177.5 3.55 56284.1 237.2427027329 80 835.9300505243

18 420 210 4.2 57971.8 240.7733373943 80 848.0378511465

19 472 236 4.72 71352.1 267.1181386578 80 938.3835344917

20 589 294.5 5.89 115242 339.4731211746 80 1186.5144759073

9 122 61 1.22 15209.7 123.3276124799 20 37.5249672573 REANALYZE

10 143 71.5 1.43 32554.2 180.4278249051 60 497.40250194

0.1 0.1 0.1

0.25 0.25 0.25

0.5 0.5 0.5

0.75 0.75 0.75

1 1 1

1.5 1.5 1.5

2.05 2 2

2.5 2.5 3

3 3 4

3.5 3.75 5.2

5 4.5

6 6

7.5 7.5

15g Batch

500g Batch

6kg Batch

Vol of JP5 processed(cc)/ Weight of adsorbent(g)

Outlet Sulfur Concentration (ppmw)

7.1929294566

23.0602171284

13.5156677559

7.0084611542

11.5146753512

11.8202142078

10.1423585963

13.3799744511

15.9287530404

27.6089678243

25.8875426036

28.493395582

21.7849032921

26.6445831685

22.6781106365

22.651041716

27.3471707904

29.5795190068

11.8140313678

32.4212981661

36.7179017738

24.6078179663

37.5478898227

78.1300745735

19.2772347034

48.6187267307

115.2229101522

33.9022561468

184.0581319083

640.0320524265

172.0485144353

272.7574613529

251.7248509184

648.5510272403

362.7279392705

754.9931845084

CBT on ATITAN

0.1 0.1

0.25 0.25

0.5 0.5

0.75 0.75

1 1

1.4 1.25

1.75 1.5

2.15 2

2.5 2.5

2.85 3.1

4.4 4.5

5.6

Flow Rate=0.5cc/min Bed Dimensions:

Diameter=1.905cm Length=8cm Bed weight=10g Polishing layer Weight=0.7g Adsorbent Wt.=0.175g

Packed Bed

Composite Bed

Vol of JP5(cc)/Weight of adsorbent(g)

Total outlet sulfur concentration(ppmw)

Composite Bed Test #1 Ag/TiO2

25.3221441842

18.9715827307

28.6773737127

53.5195410567

29.6913919152

51.6601146189

46.1080554391

76.0112073996

43.9944418466

88.507570466

83.7036055105

97.6041074603

107.3016914532

110.991068972

415.7842457638

130.0483370305

499.7251276805

140.2876580776

556.4544632473

773.41648189

707.4017414808

802.606557566

866.4377431461

848.4216525701

Ag Loading-TiO2

0.1 0.1 0.1 0.1

0.75 0.25 0.3 0.25

1 0.6 0.5 0.5

1.3 1 0.75 0.75

1.6 1.5 1 1

2 2.35 1.5 1.5

2.75 3.25 2.15 2

3.15 3.8 3.9 2.55

3.45 4.5 4.3 3.1

3.9 7.5 5.9 3.7

4.5 8.75 4.5

6 6

7.75

Ag/TiO2(F6)[4%Ag]

Ag/TiO2(F7)[2%Ag]

TiO2

Ag/TiO2[8%Ag](F8)

Vol of JP5(cc)/Weight of adsorbent (g)

Exit Sulfur Concentration(ppmw)

Desulfurization Performance with varying Ag Loading Ag/TiO2

3.6129039824

3.6129039824

41.4854901247

6.861361967

9.029332132

9.029332132

98.982878861

6.2908535127

10.6997335292

10.6997335292

134.6801082579

7.81052576

23.6846327556

23.6846327556

168.1052696107

23.4303634168

21.1918293473

21.1918293473

111.3014789128

21.6104564689

23.5035815128

7.1013302322

142.9569425668

1.6076557493

4.8505564636

4.8505564636

171.7398907731

5.8490694314

8.785931468

8.785931468

246.1666536504

12.2548429818

16.419973689

68.9272149265

771.8226629894

100.6317451109

23.208539447

148.3392844557

798.4013580423

148.3578918747

148.3392844557

405.8677043885

280.4161980955

405.8677043885

577.7645766753

689.2187999101

828.6759293153

CBT2

0.1 0.1

0.25 0.25

0.5 0.5

0.75 0.75

1 1

1.5 1.5

2.05 2

2.5 2.5

3 3

3.5 3.5

5 4

6 4.5

7.5 5.15

7.5 6

7.5

Diameter=1.905cm Length=8cm Bed weight=10g Polishing layer Weight=0.7g Adsorbent Wt.=0.175g

PB

CBT

Vol of JP5(cc)/Weight of adsorbent(gm)

Outlet Total Sulfur(ppmw)

Composite Bed Test #2 Ag/TiO2

7.1929294566

7.1929294566

7.0084611542

7.0084611542

10.1423585963

10.1423585963

27.6089678243

27.6089678243

21.7849032921

21.7849032921

22.651041716

22.651041716

11.8140313678

26.7359808373

24.6078179663

35.5111240024

19.2772347034

19.2772347034

33.9022561468

33.9022561468

172.0485144353

48.4473090306

251.7248509184

172.0485144353

362.7279392705

251.7248509184

592.9338243581

362.7279392705

592.9338243581

759.0034395139

CBT3

0.1 0.1

0.25 0.25

0.5 0.5

0.75 0.75

1 1

1.5 1.5

2 2.05

2.5 2.5

3 3

3.5 3.5

4 5

4.55 6

5.5 7.5

6.5 7.5

7.5

8.5

Diameter=1.905cm Length=8cm Bed weight=10g Polishing layer Weight=0.7g Adsorbent Wt.=0.175g

CBT

PBT

Vol of JP5(cc)/Weight of adsorbent(g)

Total Outlet Sulfur(ppmw)

Composite Bed Test #3 Ag/TiO2

22.7695984671

7.1929294566

9.4285697981

7.0084611542

10.9297476473

10.1423585963

14.3006363162

27.6089678243

23.1627735879

21.7849032921

22.9088604604

22.651041716

26.852271769

11.8140313678

32.9353544164

24.6078179663

19.8064149387

19.2772347034

30.3599497793

33.9022561468

44.5466925621

172.0485144353

60.3450468289

251.7248509184

248.8449830953

362.7279392705

402.0269213413

592.9338243581

565.4354427654

716.9838366779

Sat Tests

Calibration Split y = 5.8587x + 2.5354 0 y = 3.5892x - 11.357 20 y = 2.4618x + 55.52 40 y = 0.3608x + 20.952 60

MF

0 20 40

ATITAN 0 0 0

ASIL 101471.3 66559 INTERR

JP5

ATITAN 1433321.9 224587.2 127954.8

ASIL 1102912 236519.2 120390.9

Ag Loading-SiO2

0.1 0.1

0.25 0.25

0.5 0.5

0.75 1

1 1.6

1.5 2.1

2 2.75

2.5 4

3 5.15

3.5 6

5 7.5

6.2

7.5

Ag/SiO2[4%Ag]

Ag/SiO2[18%Ag]

Vol of Fuel(cc)/Weight of adsorbent(g)

Total Outlet Sulfur(ppmw)

Effect of Ag loading Ag/SiO2

38.1511122956

6.2828325645

71.7898298822

9.6323818819

114.4551060653

20.151758488

84.3560190478

33.8773700723

92.2585597327

61.9395390612

94.9106684136

63.794301888

106.6453117269

83.3900028553

115.2554241583

101.1133312384

122.4717148986

408.4485324644

129.7204116045

443.6693414701

574.9548482308

449.0595220501

679.7946228537

744.2927726747

776.6796575565

Regen ATITAN2PC

0.1 0.1 0.1 0.1 0.1

0.25 0.25 0.3 0.3 0.25

0.6 0.6 0.5 0.5 0.5

1 1 0.75 0.75 0.75

1.5 1.5 1 1 1

2.35 2 1.25 1.25 1.25

3.25 2.5 1.5 1.5 1.5

3.8 3 2.1 2.1 2

4.5 4.5 2.5 2.5 2.5

7.5 3 3 3

8.75 3.5 3.5 3.5

4.5 4.5 4.5

6 6 6

Fresh

R1

R2

R2 Repeat

ATITANF14

cc/gm ppmw

Regen ATITANF7

3.6129039824

22.7695984671

14.3337304953

14.3337304953

21.4940917085

9.029332132

9.4285697981

7.5291691468

7.5291691468

28.8401713603

10.6997335292

10.9297476473

12.4356781026

12.4356781026

25.1507826367

23.6846327556

27.2137350902

20.5299136239

20.5299136239

21.4549935827

21.1918293473

23.1627735879

21.1327413458

21.1327413458

23.7309203946

7.1013302322

22.9088604604

25.1376286115

25.1376286115

22.5540013276

4.8505564636

11.9835786146

7.480342303

35.3780221924

20.3558265805

8.785931468

20.8524551432

27.4318040403

50.640907455

21.6592072152

68.9272149265

19.8064149387

42.8608249461

64.6009500685

19.4305741576

148.3392844557

209.1553430066

92.4499037579

21.248148986

405.8677043885

279.2806924152

279.2806924152

117.438390266

471.7506074468

471.7506074468

210.0120582184

769.4273391719

769.4273391719

1062.2641275562

PBT 10G RT 2904.7251160824

Time Volume cc/gm Area Split Act Area Resp C/C0

1 0 1 0.1 6324.9 20 2149.3 46.3605435689 0.0159603899

2 5 2.5 0.25 8385.4 20 167708 409.5216721982 0.140984662

3 10 5 0.5 9065.2 20 181304 425.7980742089 0.1465880847

4 15 7.5 0.75 23757.3 20 475146 689.3083489992 0.2373058892

5 20 10 1 26838.8 40 1073552 1036.1235447571 0.3567028014

6 28 14 1.4 68424.9 40 2736996 1654.3868954994 0.5695502657

7 35 17.5 1.75 102192.3 40 4087692 2021.8041448172 0.6960397782

8 43 21.5 2.15 29229.7 60 1753782 1324.3043456849 0.4559138458

9 50 25 2.5 40502.7 60 2430162 1558.8976874702 0.5366765141

10 57 28.5 2.85 49160.1 60 2949606 1717.4417020673 0.5912579339

11 88 44 4.4 76276.8 60 4576608 2139.3008203616 0.7364899673

CBT

Time Volume cc/gm Area Split Act Area Resp C/C0

1 0 1 0.1 12924.1 0 12924.1 113.6842117446 0.0391376849

2 5 2.5 0.25 99913.1 0 99913.1 316.0903351892 0.1088193668

3 10 5 0.5 30297.4 20 605948 778.4266182499 0.2679863389

4 15 7.5 0.75 68362.6 20 1367252 1169.2955144017 0.4025494718

5 20 10 1 74751.9 40 2990076 1729.1836224068 0.5953002857

6 25 12.5 1.25 87498.7 40 3499948 1870.8147957508 0.644059178

7 30 15 1.5 108081.7 40 4323268 2079.2469790768 0.7158154314

8 40 20 2 141130.2 40 5645208 2375.9646462016 0.8179654343

9 50 25 2.5 160704.9 40 6428196 2535.3887275919 0.8728498318

10 62 31 3.1 90000.4 60 5400024 2323.7951716965 0.8000052231

11 75 37.5 3.75 76276.8 60 4576608 2139.3008203616 0.7364899673

12 90 45 4.5 96430.4 60 5785824 2405.3739833964 0.8280900889

13 112 56 5.6 111264.1 60 6675846 2583.7658562648 0.8895044647

14 120 60 6 106969.9 60 6418194 2533.4154811243 0.8721705088

PBT 10G RT

Time Volume cc/gm Area Response Split

1 0 1 0.1 6324.9 79.5292399058 20 25.3221441842

2 5 2.5 0.25 8385.4 91.5718297295 20 28.6773737127

3 10 5 0.5 9065.2 95.211343862 20 29.6913919152

4 15 7.5 0.75 23757.3 154.134032582 20 46.1080554391

5 20 10 1 26838.8 163.825516938 40 43.9944418466

6 28 14 1.4 68424.9 261.5815360456 40 83.7036055105

7 35 17.5 1.75 102192.3 319.6753040196 40 107.3016914532

8 43 21.5 2.15 29229.7 170.9669558716 60 415.7842457638

9 50 25 2.5 40502.7 201.2528260671 60 499.7251276805

10 57 28.5 2.85 49160.1 221.7207703396 60 556.4544632473

11 88 44 4.4 76276.8 276.1825483263 60 707.4017414808

CBT Calibration Split y = 5.8587x + 2.5354 0

Time Volume cc/gm Area Response Split ppmw y = 3.5892x - 11.357 20

1 0 1 0.1 12924.1 113.6842117446 0 18.9715827307 y = 2.4618x + 55.52 40

2 5 2.5 0.25 99913.1 316.0903351892 0 53.5195410567 y = 0.3608x + 20.952 60

3 10 5 0.5 30297.4 174.0614833902 20 51.6601146189

4 15 7.5 0.75 68362.6 261.4624255988 20 76.0112073996

5 20 10 1 74751.9 273.4079369733 40 88.507570466

6 25 12.5 1.25 87498.7 295.8017917458 40 97.6041074603

7 30 15 1.5 108081.7 328.7578135954 40 110.991068972

8 40 20 2 141130.2 375.6729961017 40 130.0483370305

9 50 25 2.5 160704.9 400.8801566553 40 140.2876580776

10 62 31 3.1 90000.4 300.0006666659 60 773.41648189

12 90 45 4.5 96430.4 310.5324459698 60 802.606557566

13 112 56 5.6 111264.1 333.5627377271 60 866.4377431461

14 120 60 6 106969.9 327.0625322473 60 848.4216525701

11 75 37.5 3.75 76276.8 276.1825483263 60 707.4017414808

ATITANF6 4PCAG 10G

Time Volume cc/gm Area Response Split

1 0 1 0.1 561.8 23.7023205615 0 3.6129039824

2 15 7.5 0.75 3073.1 55.4355481618 0 9.029332132

3 20 10 1 4253.9 65.2219288277 0 10.6997335292

4 26 13 1.3 5424.6 73.6518838863 20 23.6846327556

5 32 16 1.6 4186.7 64.7047138932 20 21.1918293473

6 40 20 2 5329.3 73.0020547656 20 23.5035815128

7 55 27.5 2.75 4551 67.4610999021 40 4.8505564636

8 63 31.5 3.15 5952 77.1492060879 40 8.785931468

9 69 34.5 3.45 9205 95.9426912276 40 16.419973689

10 78 39 3.9 12691.1 112.6547824107 40 23.208539447

11 90 45 4.5 5546.2 74.4728138316 60 148.3392844557

12 120 60 6 28019.1 167.3890677434 60 405.8677043885

13 155 77.5 7.75 72696.1 269.6221430076 60 689.2187999101

14 180 90 9 102360.5 319.938275297 60 828.6759293153

ATITANF7 2PCAG 10G

Time Volume cc/gm Area Response Split

1 0 1 0.1 561.8 23.7023205615 0 3.6129039824

2 5 2.5 0.25 3073.1 55.4355481618 0 9.029332132

3 12 6 0.6 4253.9 65.2219288277 0 10.6997335292

4 20 10 1 5424.6 73.6518838863 20 23.6846327556

5 30 15 1.5 4186.7 64.7047138932 20 21.1918293473

6 47 23.5 2.35 5329.3 73.0020547656 40 7.1013302322

7 65 32.5 3.25 4551 67.4610999021 40 4.8505564636

8 76 38 3.8 5952 77.1492060879 40 8.785931468

9 90 45 4.5 50717.3 225.2050177061 40 68.9272149265 9 90 45 4.5 9205 95.9426912276 60 207.8455965289

11 150 75 7.5 5546.2 74.4728138316 60 148.3392844557 10 123 61.5 6.15 12691.1 112.6547824107 60 254.1651397192

12 175 87.5 8.75 28019.1 167.3890677434 60 405.8677043885 11 150 75 7.5 5546.2 74.4728138316 60 148.3392844557

10 123 61.5 6.15 12691.1 112.6547824107 60 254.1651397192

ASILF2 GR21 6IN BED 10G 20PC AG

Time Volume cc/gm Area Response Split

4 0 1 0.1 1548 39.3446311458 0 6.2828325645

5 5 2.5 0.25 3477.3 58.9686357312 0 9.6323818819

6 10 5 0.5 14544 120.5985074535 0 20.151758488

7 20 10 1 12151.9 110.2356566633 20 33.8773700723

8 32 16 1.6 44502.6 210.9563935983 20 61.9395390612

9 42 21 2.1 45185.5 212.5688123879 40 63.794301888

10 55 27.5 2.75 68021.6 260.8095090291 40 83.3900028553

11 80 40 4 92684.2 304.4407988427 40 101.1133312384

12 103 51.5 5.15 28331.7 168.3202305131 60 408.4485324644

13 120 60 6 32771.1 181.0278984024 60 443.6693414701

14 150 75 7.5 33479 182.9726755557 60 449.0595220501

TITANF

Time Volume cc/gm Area Response Split

1 0 1 0.1 60312.7 245.5864409938 0 41.4854901247

2 6 3 0.3 339243.8 582.446392383 0 98.982878861

3 10 5 0.5 626608 791.5857502507 0 134.6801082579

4 15 7.5 0.75 974985.9 987.4137430682 0 168.1052696107

5 20 10 1 150642 388.1262681139 20 111.3014789128

6 30 15 1.5 251747.1 501.7440582608 20 142.9569425668

7 43 21.5 2.15 366087.7 605.0518159629 20 171.7398907731

10 78 39 3.9 437626 661.5330679565 40 246.1666536504

11 86 43 4.3 89655.7 299.4256168066 60 771.8226629894

12 118 59 5.9 95490.4 309.0152099816 60 798.4013580423

8 54 27 2.7 3316474.7 1821.1190790281 40 717.1984235226

9 66 33 3.3 374535 611.9926470147 40 226.0429957814

ATITANF8 8PCAG

Time Volume cc/gm Area Response Split

14 0 1 0.1 1826.2 42.7340613563 0 6.861361967

15 5 2.5 0.25 1551.7 39.391623475 0 6.2908535127

16 10 5 0.5 2332.4 48.2949272698 0 7.81052576

17 15 7.5 0.75 5291 72.7392603757 20 23.4303634168

18 20 10 1 4383.4 66.2072503582 20 21.6104564689

19 30 15 1.5 3537.6 59.4777269236 40 1.6076557493

20 40 20 2 4888.7 69.9192391263 40 5.8490694314

21 51 25.5 2.55 7342.6 85.6889724527 40 12.2548429818

22 62 31 3.1 3278.7 57.259933636 60 100.6317451109

23 74 37 3.7 5547.2 74.4795273884 60 148.3578918747

24 90 45 4.5 14914.8 122.1261642729 60 280.4161980955

25 120 60 6 52628.7 229.4094592644 60 577.7645766753

ATITANF9 CBT 0.9GPL 10GBED

Time Volume cc/gm Area Response Split

1 0 1 0.1 1996 44.6766158074 0 7.1929294566

2 5 2.5 0.25 1900.6 43.5958713642 0 7.0084611542

3 10 5 0.5 3838.6 61.9564363081 0 10.1423585963

4 15 7.5 0.75 7697.8 87.737107315 20 27.6089678243

5 20 10 1 4466.7 66.8333748961 20 21.7849032921

6 30 15 1.5 4891.9 69.942118927 20 22.651041716

7 40 20 2 7157.8 84.6037824214 20 26.7359808373

8 50 25 2.5 13479.1 116.0995262695 20 35.5111240024

9 60 30 3 10604.2 102.9766963929 40 19.2772347034

10 70 35 3.5 19315.6 138.9805741822 40 33.9022561468

11 80 40 4 30550.7 174.7875853715 40 48.4473090306

12 90 45 4.5 6893.5 83.0271040083 60 172.0485144353

13 103 51.5 5.15 12493.5 111.7743262113 60 251.7248509184

14 120 60 6 23050.6 151.8242404888 60 362.7279392705

15 150 75 7.5 55169.8 234.8825238284 60 592.9338243581

16 180 90 9 86907.3 294.8004409766 60 759.0034395139

17 205 102.5 10.25 95342.2 308.7753228482 60 797.7364823952

ATITANF10 2PCAG PBT 10G

Time Volume cc/gm Area Response Split

1 0 1 0.1 1996 44.6766158074 0 7.1929294566

2 5 2.5 0.25 1900.6 43.5958713642 0 7.0084611542

3 10 5 0.5 3838.6 61.9564363081 0 10.1423585963

4 15 7.5 0.75 7697.8 87.737107315 20 27.6089678243

5 20 10 1 4466.7 66.8333748961 20 21.7849032921

6 30 15 1.5 4891.9 69.942118927 20 22.651041716

7 41 20.5 2.05 7157.8 84.6037824214 40 11.8140313678

8 50 25 2.5 13479.1 116.0995262695 40 24.6078179663

9 60 30 3 10604.2 102.9766963929 40 19.2772347034

10 70 35 3.5 19315.6 138.9805741822 40 33.9022561468

12 100 50 5 6893.5 83.0271040083 60 172.0485144353

13 120 60 6 12493.5 111.7743262113 60 251.7248509184

14 150 75 7.5 23050.6 151.8242404888 60 362.7279392705

15 150 75 7.5 55169.8 234.8825238284 60 592.9338243581

11 80 40 4 30550.7 174.7875853715 60 426.3735736461

ASILF3 10G APROX4PCAG PBT

Time Volume cc/gm Area Response Split

1 0 1 0.1 51099.2 226.0513216064 0 38.1511122956

2 5 2.5 0.25 179039.4 423.1304763309 0 71.7898298822

3 10 5 0.5 453054.9 673.093529905 0 114.4551060653

4 15 7.5 0.75 84921.9 291.4136235662 20 84.3560190478

5 20 10 1 102257.6 319.7774225927 20 92.2585597327

6 30 15 1.5 108436.1 329.2963710702 20 94.9106684136

7 40 20 2 101161.8 318.0594284092 40 106.6453117269

8 50 25 2.5 115094.5 339.2558031928 40 115.2554241583

9 60 30 3 127463.9 357.0208677374 40 122.4717148986

10 70 35 3.5 140524.3 374.865709288 40 129.7204116045

11 100 50 5 52164.6 228.3957092417 60 574.9548482308

12 124 62 6.2 70874.1 266.2218999256 60 679.7946228537

13 150 75 7.5 83806.1 289.492832381 60 744.2927726747

14 180 90 9 90708.2 301.1780204464 60 776.6796575565

ATITANF11CBT

Time Volume cc/gm Area Response Split

1 0 1 0.1 18478.5 135.9356465391 0 22.7695984671

2 5 2.5 0.25 3337.9 57.7745618763 0 9.4285697981

3 10 5 0.5 4431.5 66.5695125414 0 10.9297476473

4 15 7.5 0.75 7450.89 86.3185379858 0 14.3006363162

5 20 10 1 5152.2 71.7788269617 20 23.1627735879

6 30 15 1.5 5022.2 70.8674819646 20 22.9088604604

7 40 20 2 7228.6 85.0211738333 20 26.852271769

8 50 25 2.5 11417.9 106.8545740715 20 32.9353544164

9 60 30 3 10874.2 104.2794322961 40 19.8064149387

10 70 35 3.5 16967.7 130.2601243666 40 30.3599497793

11 80 40 4 27286.1 165.1850477495 40 44.5466925621

12 91 45.5 4.55 41647.6 204.0774362834 40 60.3450468289

13 110 55 5.5 12262.3 110.7352699008 60 248.8449830953

14 130 65 6.5 27557.1 166.0033132199 60 402.0269213413

15 150 75 7.5 50607.5 224.9611077498 60 565.4354427654

16 170 85 8.5 78198.4 279.6397682734 60 716.9838366779

ATITANF7R1

Time Volume cc/gm Area Response Split

1 0 1 0.1 18478.5 135.9356465391 0 22.7695984671

2 5 2.5 0.25 3337.9 57.7745618763 0 9.4285697981

3 12 6 0.6 4431.5 66.5695125414 0 10.9297476473

4 20 10 1 7450.89 86.3185379858 20 27.2137350902

5 30 15 1.5 5152.2 71.7788269617 20 23.1627735879

6 40 20 2 5022.2 70.8674819646 20 22.9088604604

7 50 25 2.5 7228.6 85.0211738333 40 11.9835786146

8 60 30 3 11417.9 106.8545740715 40 20.8524551432

9 90 45 4.5 10874.2 104.2794322961 40 19.8064149387

ATITANF7R2

Time Volume cc/gm Area Response Split

1 0 1 0.1 7484.4 86.512426853 0 14.3337304953

2 6 3 0.3 2175.9 46.6465432803 0 7.5291691468

3 10 5 0.5 5684 75.3923072999 0 12.4356781026

4 15 7.5 0.75 3884.9 62.3289659789 20 20.5299136239

5 20 10 1 4159.3 64.4926352385 20 21.1327413458

6 25 12.5 1.25 6220 78.8669766125 20 25.1376286115

7 30 15 1.5 5466.4 73.9351066815 40 7.480342303

8 42 21 2.1 15141.7 123.0516151865 40 27.4318040403

9 50 25 2.5 25932.2 161.0347788523 40 42.8608249461

10 60 30 3 9295.9 96.4152477568 60 209.1553430066

11 70 35 3.5 14814.9 121.7164738234 60 279.2806924152

12 90 45 4.5 36542 191.1596191668 60 471.7506074468

13 120 60 6 89138.9 298.5613839732 60 769.4273391719 y = 1.8591x + 628.98

ATITANF7R2 REPEAT

Time Volume cc/gm Area Response Split

1 0 1 0.1 7484.4 86.512426853 0 14.3337304953

2 6 3 0.3 2175.9 46.6465432803 0 7.5291691468

3 10 5 0.5 5684 75.3923072999 0 12.4356781026

4 15 7.5 0.75 3884.9 62.3289659789 20 20.5299136239

5 20 10 1 4159.3 64.4926352385 20 21.1327413458

6 25 12.5 1.25 6220 78.8669766125 20 25.1376286115

7 30 15 1.5 13368.4 115.6217972529 20 35.3780221924

8 42 21 2.1 29037.3 170.4033450376 20 50.640907455 9000000

9 50 25 2.5 48624.1 220.5087299859 20 64.6009500685

10 60 30 3 102697.3 320.4641945678 20 92.4499037579

11 70 35 3.5 14814.9 121.7164738234 40 279.2806924152

12 90 45 4.5 36542 191.1596191668 40 471.7506074468

13 120 60 6 89138.9 298.5613839732 40 769.4273391719

ATITANF14 300-500um 10G

Time Volume cc/gm Area Response Split

1 0 1 0.1 16502.7 128.4628350925 0 21.4940917085

2 5 2.5 0.25 29412.7 171.5013119483 0 28.8401713603

3 10 5 0.5 22465.9 149.8862902336 0 25.1507826367

4 15 7.5 0.75 16443.9 128.233770903 0 21.4549935827

5 20 10 1 5449.1 73.8180194803 20 23.7309203946

6 25 12.5 1.25 4843.3 69.5938215648 20 22.5540013276

7 30 15 1.5 3807.4 61.7041327627 20 20.3558265805

8 40 20 2 4406.6 66.3822265369 20 21.6592072152

9 50 25 2.5 3408.6 58.3832167665 20 19.4305741576

10 60 30 3 4212.9 64.9068563405 20 21.248148986

11 70 35 3.5 4009.9 63.323771208 40 117.438390266

12 90 45 4.5 9355.6 96.7243506052 40 210.0120582184

13 120 60 6 163391.3 404.2168972223 40 1062.2641275562

14 150 75 7.5 272410.4 521.9294971545 40 1388.5185619583

ATITANF15 FOR REGEN TESTS

Time Volume cc/gm Area Response Split

1 0 1 0.1 237478 487.317145194 0 82.7456168082

2 5 2.5 0.25 561880 749.5865527076 0 127.5114193776

3 10 5 0.5 532950 730.0342457721 0 124.174107869

4 15 7.5 0.75 294231 542.4306407275 0 92.1527370795

5 20 10 1 356535 597.1055183131 20 169.5259440302

6 31 15.5 1.55 72669 269.5718828068 20 78.2706126175

7 40 20 2 60837 246.651576115 20 71.8847030299

8 50 25 2.5 68441 261.6123085789 20 76.0529668391

9 60 30 3 44498 210.9454905894 40 526.589497199

10 70 35 3.5 65401 255.7361921981 40 650.732240017

11 80 40 4 99246 315.0333315699 40 815.0812959253

12 93 46.5 4.65 23518 153.3557954562 60 366.9728255438

13 120 60 6 53184.3 230.6172153158 60 581.1120158419

ATITANF16 TROYS SAMPLE NO3 1.4-0.5MM FROM1/16

Time Volume cc/gm Area Response Split

1 0 1 0.1 60394.5 245.7529247028 0 41.513906618

2 5 2.5 0.25 15431.5 124.2235887422 0 20.7705103081

3 13 6.5 0.65 17013.5 130.435807967 20 39.5054073239

4 20 10 1 19387.5 139.2390031564 20 41.9580973912

5 30 15 1.5 55624.1 235.8476202975 20 68.8745738041

9 70 35 3.5 41010 202.5092590476 60 503.2074807305

10 94 47 4.7 57672 240.1499531543 60 607.533129585

11 120 60 6 62731.9 250.4633705754 60 636.1179893997

6 44 22 2.2 73814 271.6873202783 40 694.9426836982

7 50 25 2.5 86570.5 294.2286525816 40 757.4186601486

8 60 30 3 109910 331.5267711664 40 860.7948203059

ATITANF14R1

Time Volume cc/gm Area Response Split

1 0 1 0.1 10107.4 100.5355658461 0 16.7272886214

2 5 2.5 0.25 1740.9 41.7240937589 0 6.6889743047

3 10 5 0.5 2693.5 51.8989402589 0 8.4256815094

4 15 7.5 0.75 4734.6 68.8084297161 0 11.3119002025

5 20 10 1 3656.6 60.4698271868 20 20.0119322375

6 30 15 1.5 4097.5 64.0117176773 20 20.9987511639

7 40 20 2 5218.7 72.2405703189 20 23.2914215755

8 50 25 2.5 25187 158.7041272305 20 47.3813460466

9 60 30 3 132002.3 363.3212077487 20 104.3904512841

12 120 60 6 53335.6 230.945015101 60 582.020551832

13 153 76.5 7.65 97916 312.9153240095 60 809.2109867227

14 180 90 9 112330.2 335.1569781461 60 870.8563695844

10 80 40 4 127591.9 357.2000839866 40 931.9514522909

11 100 50 5 221254.8 470.3772953704 40 1245.6355193194

ATITANF14R2 300-500um 10G

Time Volume cc/gm Area Response Split

1 0 1 0.1 8089 89.9388681272 0 14.9185771805

2 5 2.5 0.25 4690 68.4835746731 0 11.2564518875

3 12 6 0.6 8426.1 91.7937906397 0 15.2351870961

4 20 10 1 18309.4 135.312231524 20 40.8640453371

5 24 12 1.2 12813.1 113.1949645523 20 34.7018735519

6 30 15 1.5 12638.2 112.4197491547 20 34.4858879847

7 39 19.5 1.95 17857.4 133.6315830932 20 40.3957937962

10 150 75 7.5 111743.8 334.2810195031 60 868.4285462945

11 187 93.5 9.35 110827 332.9068938908 60 864.619994154

8 48 24 2.4 43854.7 209.4151379438 40 522.3479433031

9 83 41.5 4.15 259131.2 509.0493099887 40 1352.8195953124

ATITANF17 TROYS SAMPLE NO 8

Time Volume cc/gm Area Response Split

1 0 1 0.1 57632 240.06665741 0 40.5433385239

2 5 2.5 0.25 149174.4 386.2310189511 0 65.491596933

3 10 5 0.5 319818.6 565.5250657575 0 96.0946397251

4 21 10.5 1.05 89223.1 298.7023602183 20 86.3867603417

5 31 15.5 1.55 115788.7 340.2773868478 20 97.9701289557

6 40 20 2 148440.8 385.2801578073 20 110.5085138213

7 50 25 2.5 191761.7 437.9060401502 20 125.1708013346

8 60 30 3 200913.3 448.2335328821 20 128.0481814561

9 83 41.5 4.15 193181.1 439.5237194965 40 1160.1211737707

10 120 60 6 341219.9 584.1403084876 40 1560.9432053426

ATITANF18

Time Volume cc/gm Area Response Split

1 0 1 0.1 6872.5 82.9005428209 0 13.7172312665

2 5 2.5 0.25 7354 85.7554662981 0 14.2045276765

3 10 5 0.5 8502.5 92.2090017298 20 28.8548985094

4 15 7.5 0.75 6651.8 81.5585679129 20 25.8875426036

5 26 13 1.3 13590.1 116.5765842697 20 35.6440388582

6 35 17.5 1.75 24999.1 158.1110369329 20 47.2161030126

7 43 21.5 2.15 55121.1 234.7788320952 20 68.5767948555

8 52 26 2.6 10196 100.9752444909 60 221.7939148861

9 70 35 3.5 30146.6 173.627762757 60 423.1589876857

ATITANF19

Time Volume cc/gm Area Response Split

1 0 1 0.1 18944.3 137.63829409 0 23.0602171284

2 5 2.5 0.25 4899.5 69.9964284803 0 11.5146753512

3 10 5 0.5 6548.8 80.9246563168 0 13.3799744511

4 15 7.5 0.75 6651.8 81.5585679129 20 25.8875426036

5 20 10 1 7102.4 84.2757379084 20 26.6445831685

6 30 15 1.5 7533.8 86.7974654008 20 27.3471707904

7 40 20 2 11027 105.0095233776 20 32.4212981661

8 50 25 2.5 15230 123.4098861518 20 37.5478898227

9 60 30 3 26616.4 163.1453339817 20 48.6187267307

10 75 37.5 3.75 7631.8 87.3601739925 60 184.0581319083

11 90 45 4.5 14247.5 119.3628920561 60 272.7574613529

12 120 60 6 64999.1 254.9492106283 60 648.5510272403

13 150 75 7.5 86056.3 293.3535409706 60 754.9931845084

ATITANF20

Time Volume cc/gm Area Response Split

1 0 1 0.1 6678.1 81.7196426815 0 13.5156677559

2 5 2.5 0.25 5153.3 71.7864889795 0 11.8202142078

3 10 5 0.5 9188.6 95.8571854375 0 15.9287530404

4 15 7.5 0.75 8264.9 90.9114954227 20 28.493395582

5 20 10 1 4905.5 70.0392746964 20 22.6781106365

6 30 15 1.5 8988.9 94.809809619 20 29.5795190068

7 40 20 2 14503.6 120.4308930466 20 36.7179017738

8 60 30 3 72397.3 269.0674636592 20 78.1300745735

9 80 40 4 161765.7 402.2010691184 20 115.2229101522

10 104 52 5.2 63441.3 251.8755645155 60 640.0320524265

F14 Fresh

Cycle 1

Cycle 2

500KWe Liquid-Phase Continuous Desulfurizer

Shell and Tube Design Parameters for a Desulfurizer Using 10cm Tubes (other cases possible)

0.12 0.12 0.12

0.32 0.24 0.24

0.44 0.36 0.36

0.51 0.48 0.48

0.63 0.6 0.6

0.1~0.25 mm particle

0.8~1.4 mm particle

1.5 mm cylindric extraduate

Face Velocity (cm/min)

Pressure Drop Per Unit Bed Thickness (psi/cm)

3.4054054054

0.0428571429

0.03

5.372972973

0.0428571429

0.03

6.6

0.0442857143

0.03

7.6837837838

0.0457142857

0.03

9.4594594595

0.0462

0.03

BT test with 2000 ppmw BT in n-octane

Sorbents weight: 7.7 g

Sorbents Volume: 17.8128303459 cm^3

Flow rate 34.8 cm^3/h

LHSV: 1.9536479787

File Name: LDS_Particle Size

Ws= 7.7 g A0= 9581 t W dW dV v Vt Vt/Ws A C

0 77.8196 0 0 0 0 0 0

68 97.82 20.0004 28.2491525424 0.4154287139 0.4154287139 0.053951781 544 113.5580837073

122 117.309 19.489 27.5268361582 0.5097562252 0.925184939 0.1201538882 2088 435.8626448179

222.5 156.968 39.659 56.0155367232 0.5573685246 1.4825534636 0.1925394109 3027 631.8755870995

75.76 272 96.8147370492 21.0547370492 29.7383291656 0.6007743266 2.0833277902 0.2705620507 3748.5 782.4861705459

416 153.27 56.4552629508 79.7390719644 0.5537435553 2.6370713455 0.3424767981 5500 1148.1056257176

3.2

35.2 0.7773279352

247 123.5 0.8502024291

58 85 0.6823529412 extrudate 1 mm fine powder

V/W C V/W C V/W C

0 0 0 0 0 0 0 0 0 0 1.3846153846 1.3846153846 0.1524166054 V/m ppmw

9.592806945 2.9019152641 4.2214512924 14.2214512924 0.561534862 37.0800376648 3.7607959356 5.7774590758 5.7774590758 0 16.4795016659 16.4795016659 0.40109633 0 0

10.9702700841 6.4306442252 7.8805420473 7.8805420473 1.2059629654 39.0291902072 13.7377696867 10.1885846733 10.1885846733 0 20.7874112705 20.7874112705 0.5347951066 37.08003766 3.760795936

13.1497175141 9.6111433546 11.790580639 11.790580639 0.441205963 40.8804143126 13.8731583404 15.4918151528 15.4918151528 0 23.0980008692 23.0980008692 0.5882746173 39.02919021 13.73776969

15.2828303707 5.0725478816 16.9197509512 16.9197509512 0.3021592352 44.6657250471 2.3400508044 17.4251484862 17.4251484862 0 27.5145588874 27.5145588874 0.8556721706 40.88041431 13.87315834

17.4214551468 39.5629715612 20.2702436907 20.2702436907 0.2326358714 48.8775894539 3.0086367485 19.1053962045 19.1053962045 0 32.1303056642 32.1303056642 0.6417541279 44.66572505 2.340050804

22.7957489321 26.9092280905 32.9600653821 32.9600653821 0.3101811618 53.3286252354 2.0057578323 24.2207446038 24.2207446038 0 40.5686657975 40.5686657975 0.1524166054 48.87758945 3.008636749

25.9974851867 56.8473592571 34.9286494259 34.9286494259 0.5347951066 57.9048964218 4.9141066892 37.0822830653 37.0822830653 0 44.9997102709 44.9997102709 0.7219733939 53.32862524 2.005757832

30.319519085 121.099245502 38.7488215625 38.7488215625 0.3128551374 59.4830508475 3.1590685859 41.9053599884 41.9053599884 0 48.291757207 48.291757207 0.5909485928 57.90489642 4.914106689

34.6367300537 145.0748694138 38.7488215625 38.7488215625 15.1935289792 63.1252354049 4.1118035563 47.6823772273 47.6823772273 0 53.5141242938 53.5141242938 0.7647570025 59.48305085 3.159068586

38.9467066281 152.3099245502 38.7488215625 38.7488215625 2.5482986831 65.0320150659 6.8530059272 52.1025568593 52.1025568593 0 57.4073591192 57.4073591192 0.4385319874 63.1252354 4.111803556

50.3457007028 150.7243180499 41.052793999 41.052793999 2.3504244936 66.8192090395 14.6905046571 56.0338186296 56.0338186296 0 62.0212950891 62.0212950891 0.7861488067 65.03201507 6.853005927

55.106475627 215.0922809054 44.9263773306 44.9263773306 3.6205628718 68.6657250471 23.101315834 58.6739750833 58.6739750833 0 66.6366797045 66.6366797045 4.6553914032 66.81920904 14.69050466

59.8863433409 245.0145095763 49.8044302467 49.8044302467 7.5753726853 70.5065913371 38.6999273497 63.3965594669 63.3965594669 0.1 71.6833985224 71.6833985224 1.9546761147 68.66572505 23.10131583

66.536818744 380.8821822403 54.3905019635 54.3905019635 11.9179089511 72.7306967985 67.1594580864 68.0340359264 68.0340359264 0 76.3154425612 76.3154425612 8.5406778528 70.50659134 38.69992735

69.3294672213 464.1671503192 58.8884028188 58.8884028188 28.7719767364 74.1996233522 97.1505520745 75.6086411705 75.6086411705 0.2 81.4907286687 81.4907286687 25.83060365 72.7306968 67.15945809

76.7037265571 624.9367382472 63.4410713438 63.4410713438 93.161307574 76.0301318267 150.2357745978 84.9988881646 84.9988881646 3.1938211043 89.0399826163 89.0399826163 134.2603115181 74.19962335 97.15055207

81.536818744 718.0754497969 67.0933797248 67.0933797248 67.1702653921 77.8502824859 200.5724403048 91.774746487 91.774746487 60.5364784469 94.696943358 94.696943358 308.0954609265 76.03013183 150.2357746

85.7179541994 725.515960534 71.7579574203 71.7579574203 74.2295607995 79.7015065913 299.055149873 95.252419238 95.252419238 90.1784782382 99.6241489208 99.6241489208 492.5409452504 77.85028249 200.5724403

89.7723155057 812.5362739408 76.2957725463 76.2957725463 278.2538939769 81.4990583804 400.817273497 104.8182348254 104.8182348254 298.2987162092 102.7876285673 102.7876285673 622.6352028879 79.70150659 299.0551499

90.8065837984 834.4538595473 80.8637014128 80.8637014128 718.4170064844 83.5065913371 503.4936883997 109.4491127046 109.4491127046 161.0687819643 119.2876285673 119.2876285673 1451.1665218263 81.49905838 400.8172735

91.8244803121 903.88972722 85.4303280634 85.4303280634 1005.8426365399 85.147834275 638.6466655377 111.6496921628 111.6496921628 252.1657447031 83.50659134 503.4936884

92.8557260059 928.6128845038 87.143126177 643.8716646909 119.4806062581 119.4806062581 841.