W051 81 MC-Prebond 100 (NA) April 13.pdf

Material Safety Data Sheet

NFPA Protective Clothing

Product Name Synonym

Chemical Family

MC-Prepbond 100 W051.81

Not applicable. (Paint)

Section 1. Chemical Product and Company Identification

EMERGENCY PHONE NUMBERS:

USA and Canada: 1-800 424-9300 International: 1-703 527-3887

Manufacturer

SUPPLIER:

Wasser Corporation 4118 B PL NW, Suite B Auburn, WA 98001, US Phone# 253-850-2967

HCS Risk Phrases HCS CLASS: Toxic.

HCS CLASS: Irritating substance.

HCS CLASS: Sensitizing substance.

HCS CLASS: Target organ effects.

HCS CLASS: Flammable liquid having a flash point lo wer than 37.8°C (100°F).

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Section 2. Composition and Information on Ingredients

Date Originated: 4/16/2013

In case of Emergency

Modified MDI Not disclosed 30-60 Not available. Not available.

Tert Butyl Acetate 540-88-5 10-30 TWA: 200 (ppm) from

ACGIH (TLV)

TWA: 200 (ppm) from

OSHA

ORAL (LD50): Acute: 4100 mg/kg [Rat]. DERMAL (LD50): Acute: 2000 mg/kg [Rabbit].

Aluminum 7429-90-5 10-30 TWA: 1 (mg/m3) from

ACGIH (TLV)

Not available.

Isocyanic acid, polymethylene polyphenylene ester

9016-87-9 10-30 Not available. ORAL (LD50): Acute: 10000 mg/kg [Rat]. DERMAL (LD50): Acute: 6000 mg/kg [Rabbit]. VAPOR (LC50):

Acute: 103 ppm 4 hour(s) [Rat].

Light aromatic solvent naphtha (petroleum)

64742-95-6 5-10 Not available. ORAL (LD50): Acute: 5000 mg/kg [Rat]. DERMAL (LD50): Acute: 3000 mg/kg [Rabbit].

Diphenylmethane-4,4'-diisocyanate 101-68-8 1-5 TWA: 0.05 (mg/m3) from

ACGIH

ORAL (LD50): Acute: 10000 mg/kg [Rat]. DERMAL (LD50): Acute: 10000 mg/kg [Rabbit]. VAPOR (LC50):

Acute: 48 ppm 4 hour(s) [Rat].

Name CAS # TLV/PEL% by Weight

LC50/LD50

Section 3. Hazards Identification

Potential Chronic Health Effects

Potential Acute Health Effects

Routes of Entry: Inhalation. Skin contact (absorption). Eye contact. Ingestion.

Liquid or spray mist may severely irritate eyes. Inflammation of the eye is characterized by redness, watering, and itching.

This product may irritate skin upon contact. Harmful if absorbed through the skin. May cause skin sensitization. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Harmful if swallowed. Irritation or chemical burns of the mouth, pharynx, esophagus and stomach can develop following ingestion of this product. May cause headaches, weakness, nausea, vomiting and diarrhea. Even small amounts of liquid aspirated into lungs during ingestion or from vomiting may cause mild to severe pulmonary injury and possibly death.

Harmful if inhaled (irritant, sensitizer). Over-exposure by inhalation of the vapors/spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. May cause nausea, vomiting and headaches. May cause sensitization by inhalation. Severe overexposure may cause unconciousness and death.

Eyes:

Skin:

Ingestion:

Inhalation:

Repeated or prolonged contact with spray mist may produce chronic eye irritation.

Repeated skin exposure can produce local skin destruction, or dermatitis, possibly sensitization.

May be fatal if swallowed.

Repeated or prolonged inhalation of vapors/spray mist may lead to chronic respiratory irritation. May cause sensitization by inhalation.

Eyes:

Skin:

Ingestion:

Inhalation:

DO NOT induce vomiting. Have conscious person drink several glasses of water. Seek immediate medical attention.

Eye Contact

Skin Contact

Hazardous Inhalation

Inhalation

Ingestion

Hazardous Ingestion

Check for and remove any contact lenses. IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. DO NOT use an eye ointment. Seek medical attention.

Wash gently and thoroughly the contaminated skin with running water and non-abrasive soap. Rinse with plenty of running water (15-30 minutes). If irritation persists, seek medical attention.

If the product gets onto the clothed portion of the body, remove the contaminated clothes as quickly as possible, protecting your own hands and body. Place the person under shower. Wash gently and thoroughly the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Rinse with plenty of running water (15-30 minutes). Seek medical attention. Wash contaminated clothing before reusing.

Allow the person to rest in a well ventilated area. Loosen tight clothing around the person's neck and waist. If symptoms persist, seek medical advice immediately (show the label when possible).

Evacuate the person to a safe area as soon as possible. Loosen tight clothing around the person's neck and waist. If the person is not breathing, administer mouth-to-mouth resuscitation. Warning: It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation if the inhaled material is toxic, infectious or corrosive. Oxygen may be administered if breathing is difficult. Seek medical attention.

DO NOT induce vomiting. Have conscious person drink several glasses of water. Never give an unconscious person anything to ingest. Even small amounts of liquid aspirated into lungs during ingestion or from vomiting may cause mild to severe pulmonary injury and possibly death. If breathing is difficult, administer oxygen. If the person is not breathing, administer mouth-to-mouth resuscitation. WARNING: It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation when the material is toxic, infectious or corrosive.

Avoid mouth-to-mouth contact by using mouth guards or shields. Seek immediate medical attention.

Section 4. First Aid Measures

Hazardous Skin Contact

Material Safety Data Sheet Product Name: MC-Prepbond 100

Other chronic effects on Humans

The substance is toxic to mucous membranes, upper respiratory tract, lungs, blood, kidney, liver.

Exposure may cause asthma, dermatitis and pulmonary oedema; effects may be delayed. Sensitive individuals may develop eczema and/or asthma on inhalation of this material. However, in light of good industrial hygiene, exposure to any chemical should be kept to a minimum.

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Flammability of the Product

Auto-Ignition Temperature Not available.

Flammable.

Carbon oxides (CO, CO2), and other toxic compounds (nitrogen oxides, isocyanate vapors and traces of hydrogen cyanide).

The lowest known value is CLOSED CUP:15.8 °C (60.4F ).

The greatest known range is LOWER: 0.9% UPPER: 6% (Light aromatic solvent naphtha (petroleum))

Flammable liquid, insoluble in water.

SMALL FIRE: Use DRY chemicals, CO2, soda ash, lime. LARGE FIRE: Use DRY chemicals, CO2, soda ash, lime and water spray or fog. Never direct a water jet in the container in order to prevent any splashing of the product which could cause spreading of the fire. Cool the containers with water spray or fog in order to prevent pressure build-up, autoignition or explosion. Firefighters should be equipped with self-contained breathing apparatus to protect against toxic and irritating fumes. During a fire, isocyanate vapors and other irritating, highly toxic gases may be generated by thermal decomposition or combustion.

Flammable in presence of open flames and sparks.

Vapor may travel considerable distance to source of ignition and flash back. When heated to decomposition it emits highly toxic fumes.

Risks of explosion of the product in presence of mechanical impact: Not available.

Risks of explosion of the product in presence of static discharge: Yes

Container explosion may occur under fire conditions or when heated (due to pressure build-up). Vapor forms explosive mixture with air between upper and lower flammable limits.

Section 5. Fire and Explosion Data

Health

Flammability

Reactivity

Special Hazard

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Section 6. Accidental Release Measures

Small Spill

Large Spill

Absorb with an inert material and place in an appropriate waste disposal container. Treat with a neutralizing solution (5% ammonia water, or 5-10 % sodium carbonate in water). Wear suitable protective clothing and respirator.

Flammable, poisonous liquid, insoluble or very slightly soluble in water. Ventilate. Eliminate all sources of ignition. Wear suitable protective clothing, gloves and eye/face protection. A self-contained breathing apparatus should be used to avoid inhalation of the product. Warn personnel to move away. Stop leak if without risk. DO NOT touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed.

Cover with WET earth, sand or other non-combustible material, or with DRY absorbent wetted with a neutralizing solution (5% ammonia water, or 5-10% sodium carbonate in water). After 15 minutes transfer it to waste container, or put in open drums - fill the drums half way. Do not seal - evolution of CO2 can cause pressure build-up. Keep drums (not sealed) outside, or in safe ventilated area for a few days. After clean-up monitor the vapors concentration. Use the neutralizing solution to decontaminate the surface and the tools. The spilled material, clean-up residues, and spent decontamination solution are hazardous wastes. Call for assistance on disposal.

Material Safety Data Sheet Product Name: MC-Prepbond 100

Flash Points

Flammable Limits

Products of Combustion

Fire Hazards in Presence of Various Substances

Explosion Hazards in Presence of Various Substances

Fire Fighting Media and Instructions

Special Remarks on Fire Hazards

Special Remarks on Explosion Hazards

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The lowest known value is 154°C (309.2°F) (Light aromatic solvent naphtha (petroleum)).

Weighted average: 186.62°C (367.9°F)

Section 9. Physical and Chemical Properties

Volatility

Odor Threshold

Water/Oil Dist. Coeff.

Ionicity (in Water)

Dispersion Properties

Solubility

Liquid.

34-38% (v/v). 27-31% (w/w).

Neutral.

May start to solidify at -10°C (14°F) based on data for:

Isocyanic acid, polymethylene polyphenylene ester.

1.09-1.12 (Water = 1)

The highest known value is 4.3 (Air = 1) (Light aromatic solvent naphtha (petroleum)).

Weighted average: 4.3 (Air = 1)

The highest known value is 34 mm of Hg (@ 20°C) (Tert Butyl Acetate). Weighted average: 24.86 mm of Hg (@ 20°C)

Not available.

Not available.

Is not dispersed water.

Insoluble in water.

ATTENTION: ISOCYANATE VAPORS CANNOT

BE SMELLED UNTIL CONCENTRATIONS ARE

WELL ABOVE THE SAFE EXPOSURE LIMIT!

Not available.

Not applicable.

Aromatic.

Not available.

Silver

Instability Temperature

Conditions of Instability

Stability

Corrosivity

Special Remarks on Reactivity

The product is stable.

Not considered to be corrosive for glass and metals according to our data base.

Incompatible with water, strong oxidizing agents, amines, strong bases, strong acids, alcohols. Absorbs moisture from the air. Reacts slowly with water to liberate CO2 gas.

No additional remarks.

Section 10. Stability and Reactivity Data

Not available.

Not available.

Incompatibility with various substances

Material Safety Data Sheet Product Name: MC-Prepbond 100

Physical state and appearance

Molecular Weight pH (1% soln/water)

Boiling Point

Melting Point

Critical Temperature

Specific Gravity

Vapor Pressure

Vapor Density

Color

Taste

Odor

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Evaporation rate 0.42 (Light aromatic solvent naphtha (petroleum)).compared to Butyl acetate.

Not available.Viscosity

Storage Keep away from heat. Keep away from sources of ignition. Keep container tightly closed and in a well-ventilated place. Contains moisture sensitive material; store in a dry place. Keep away from incompatibles.

Keep locked up and out of reach of children. Manipulate in a well ventilated area. In case of insufficient ventilation, wear suitable respiratory equipment. Do not breathe gas/fumes/vapor/spray. Avoid contact with skin and eyes. Contact lenses should not be worn. Keep away from foodstuff, drinks and tobacco.

Eating, drinking and smoking should be prohibited in area where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Ensure that eyewash station and safety shower are proximal to the work-station location. In case of accident or if you feel unwell, seek medical advice immediately (show the label when possible). Individuals with respiratory problems (asthma, chronic bronchitis), or allergic to isocyanates or solvents, should avoid any contact with this product. ATTENTION: Isocyanate vapors cannot be smelled until concentrations are well above the safe exposure limit! Ground all equipment containing material (during handling, mixing, and spraying).

Precautions

Section 7. Handling and Storage

Engineering Controls

Personal Protection

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash station and safety shower are proximal to the work-station location. Do air monitoring if possible.

During mixing, handling and application: Splash goggles. Full protective clothing. Gloves (impervious). Suitable respiratory equipment. When air concentrations are not known or above the TLV, an air-supplied respirator, or self-contained breathing apparatus is required.

Refer to OSHA Respiratory Protection Standard (29 CFR 1910.134). When welding, refer to OSHA Standard (29 CFR 1926.354): Welding, Cutting and Heating in Way of Preservative Coatings. ATTN: Air-purifying (cartridge type) respirators are not approved for protection against isocyanates due to their low warning properties.

Personal Protection in Case of a Large Spill

Splash goggles. Full suit. Boots. Gloves (impervious). Self-contained breathing apparatus (for above TLV, or unknown vapor concentrations), must be used to avoid inhalation af the product. NOTE: Air-purifying (cartridge type) respirators are not approved for protection against isocyanates.

Section 8. Exposure Controls/Personal Protection

Section 12. Ecological Information

Ecotoxicity Not available.

BOD5 and COD

Products of Biodegradation

Toxicity of the Products of Biodegradation

Special Remarks on the Products of Biodegradation

Not available.

Not available.

Not available.

No additional remarks.

Section 13. Disposal Considerations

Waste Disposal In accordance with municipal, state, and federal regulations. Consult your local or regional authorities. Empty containers must be handled with care due to product residue. Do not heat or cut empty containers with electric or gas torch.

Section 14. Transport Information

DOT Classification

DOT Identification number

DOT CLASS 3: Flammable liquid PG: II

Special Provisions for Transport

No specific remarks.

PIN: UN1263 - Paint.

DOT (Pictograms)

Material Safety Data Sheet Product Name: MC-Prepbond 100

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Toxicity to Animals

Other Toxic Effects on Humans

Special Remarks on Chronic Effects on Humans

Special Remarks on Toxicity to Animals

Special Remarks on other Toxic Effects on Humans

Routes of Entry

Chronic Effects on Humans

Inhalation. Skin contact (absorption). Eye contact. Ingestion.

See: Section 2

No additional remarks

The substance is toxic to mucous membranes, upper respiratory tract, lungs, blood, kidney, liver. Exposure may cause asthma, dermatitis and pulmonary oedema; effects may be delayed. Sensitive individuals may develop eczema and/or asthma on inhalation of this material. However, in light of good industrial hygiene, exposure to any chemical should be kept to a minimum.

No additional remark.

Exposure can cause nausea, headache and vomiting. Over-exposure can cause lung irritation, chest pain and oedema which may be fatal. Sensitizer - skin and inhalation. Medical supervision of all employees who come in contact with this product is recommended (preemployment and periodic medical examinations).

Isocyanates are not known to cause cancer in humans, but may cause skin and respiratory sensitization in humans. Sensitive individuals may develop eczema and/or asthma on inhalation of this material. Exposure may cause asthma, dermatitis and pulmonary oedema; effects may be delayed. Reports have associated repeated and prolonged occupational exposure to solvents with permanent brain and nervous system damage, and other systemic effects. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal.

Section 11. Toxicological Information

Section 15. Other Regulatory Information and Pictograms

Other Regulations

Other Classifications

WHMIS (Canada) (Pictograms)

TSCA (Toxic Substance Control Act): All components of this product are either reported in EPA TSCA Inventory, or exempt. OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): All components of this product are either on the Domestic Substances List (DSL), or exempt, and acceptable for use under the provisions of CEPA.

DSCL (Europe) (Pictograms)

TDG (Canada) (Pictograms)

ADR (Europe) (Pictograms)

Protective Clothing (Pictograms)

National Fire Protection Association (U.S.A.)

Hazardous Material Information System (U.S.A.) 0

2Health

Fire Hazard

Reactivity

Specific hazard

Health Hazard

Fire Hazard

Personal Protection

Reactivity x

WHMIS CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F).

WHMIS CLASS D-2A: Material causing other toxic effects (VERY TOXIC).

WHMIS CLASS D-2B: Material causing other toxic effects (TOXIC).

Validated by HS Reg.Depart.SS on 4/16/2013. Verified by HS Reg.Depart.SS.

Printed 4/16/2013.

Medical supervision of all employees who come in contact with this product is recommended (pre-employment and periodic medical examination). Individuals with respiratory problems (asthma, chronic bronchitis), or allergic to isocyanates or solvents, should avoid any contact with this product.

References Manufacturer's MSDS, RTESC, NIOSH, CCOHS.

Other Special Considerations

Section 16. Other Information

EMERGENCY PHONE NUMBERS:

USA and Canada: 1-800 424-9300 International: 1-703 527-3887

Notice to Reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Material Safety Data Sheet Product Name: MC-Prepbond 100

DSCL (EEC)

WHMIS (Canada)

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