Attachment 0030 - 900-20 Inert Molding Powder.pdf

AMERICAN ORDNANCE LLC

SAFETY DATA SHEET

Creation Date 28 May 2019 Revision Date N/A Revision Number 0

1. Identification

Product Name 900-20 Inert Molding Powder

Cat No. : N/A

Synonyms None

Recommended Use Inert molding powder

Uses advised against No Information available

Details of the supplier of the safety data sheet

Company Emergency Telephone Number American Ordnance LLC 319-753-7807 17575 State Highway 79 Middletown, Iowa 52638 Tel: (319) 753-7404

NOTE: THIS MATERIAL IS COMPRISED OF AN INTIMATE BLEND OF THE CHEMICALS LISTED IN

SECTION 3. IT IS ANTICIPATED THAT EXPOSURE HAZARDS PRESENTED BY THE MOST

HAZARDOUS COMPONENT (BARIUM NITRATE) WILL BE REDUCED SOMEWHAT BY ITS COATING

WITH ESTANE, BUT IN THE INTEREST OF SAFETY, HAZARD DATA IS LISTED HEREWITH FOR THE

MOST HAZARDOUS COMPONENT

2. Hazard(s) identification

Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Oxidizing solids Category 2 Acute oral toxicity Category 3 Acute Inhalation Toxicity - Dusts and Mists Category 4 Serious Eye Damage/Eye Irritation Category 2

900-20 Inert Molding Powder Revision Date 28 May 2019

Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep/Store away from clothing/ other combustible materials Take any precaution to avoid mixing with combustibles Response IF exposed or concerned: Get medical attention/advice Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Fire In case of fire: Use CO2, dry chemical, or foam for extinction Storage Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) None identified

3. Composition / information on ingredients Component CAS-No Weight %

Barium nitrate 10022-31-8 44 Pentaerythritol 115-77-5 50

Estane 5703 N/A 4

Tris (Beta-Chloroethyl) Phosphate

115-96-8 1

4. First-aid measures

Eye Contact Rinse immediately with copious amounts of water, also under the eyelids, for at least 15 minutes. Obtain medical attention.

Skin Contact Wash off immediately with copious amounts of water for at least 15 minutes. If irritation persists, get medical attention.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with a respiratory medical device. Immediate medical attention is required.

Ingestion Do not induce vomiting. Call a physician or Poison Control Center immediately.

Most important symptoms/effects No information available.

Notes to Physician Treat symptomatically

5. Fire-fighting measures

Suitable Extinguishing Media Substance is nonflammable; use agent most appropriate to extinguish surrounding fire. Use water spray to cool unopened containers.

Unsuitable Extinguishing Media No information available

Flash Point No information available

Method - No information available

Autoignition Temperature Explosion Limits

Not applicable

Upper No data available Lower No data available

Oxidizing Properties Oxidizer Sensitivity to Mechanical Impact No information available Sensitivity to Static Discharge No information available

Specific Hazards Arising from the Chemical Non-combustible. Oxidizer: Contact with combustible/organic material may cause fire. Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition.

Hazardous Combustion Products Nitrogen oxides (NOx) Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA

Health

Flammability Instability 0 2

Physical hazards

OX

6. Accidental release measures

Personal Precautions Use personal protective equipment. Ensure adequate ventilation. Avoid dust formation.

Avoid contact with skin, eyes and clothing.

Environmental Precautions Avoid release to the environment.

Methods for Containment and Clean Up Keep combustibles (wood, paper, oil, etc) away from spilled material. Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust formation.

7. Handling and storage

Handling Wear personal protective equipment. Ensure adequate ventilation. Avoid dust formation, clean up spills in manner that does not disperse dust in air. Do not get in eyes, on skin, or on clothing. Do not breathe dust. Do not ingest. Keep away from clothing and other combustible materials.

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Do not store with any combustible materials.

8. Exposure controls / personal protection

Exposure Guidelines

Component ACGIH TLV OSHA PEL NIOSH IDLH Barium nitrate TWA: 0.5 mg/m3 (Vacated) TWA: 0.5 mg/m3 IDLH: 50 mg/m3

TWA: 0.5 mg/m3

Component Quebec Mexico OEL (TWA) Ontario TWAEV

Barium nitrate TWA: 0.5 mg/m3 TWA: 0.5 mg/m3 TWA: 0.5 mg/m3 Legend

ACGIH - American Conference of Governmental Industrial Hygienists OSHA - Occupational Safety and Health Administration NIOSH IDLH: The National Institute for Occupational Safety and Health Immediately Dangerous to Life or Health

Engineering Measures Ensure adequate ventilation, especially in confined areas. Ensure that eyewash stations and safety showers are close to the workstation location.

Personal Protective Equipment Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by

OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European

Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.

9. Physical and chemical properties

Physical State Solid Appearance Pink Odor Odorless Odor Threshold No information available pH No Information Available Melting Point/Range No Information Available Boiling Point/Range No information available Flash Point No information available Evaporation Rate Not applicable Flammability (solid,gas) No information available Flammability or explosive limits

Upper No data available Lower No data available

Vapor Pressure No information available Vapor Density Not applicable Relative Density No information available Solubility No information available Partitioncoefficient; n-octanol/water No data available Autoignition Temperature Not applicable Decomposition temperature No information available Viscosity Not applicable Molecular Formula Not Applicable Molecular Weight Not Applicable

10. Stability and reactivity

Reactive Hazard Yes Stability Oxidizer: Contact with combustible/organic material may cause fire.

Conditions to Avoid Avoid dust formation. Incompatible products. Excess heat. Combustible material.

Incompatible Materials Organic materials, Acids, Bases, Acid anhydrides, Metals, reducing agents, Combustible material

Hazardous Decomposition Products Nitrogen oxides (NOx)

Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing.

11. Toxicological information

Acute Toxicity

Product Information Component Information

Component LD50 Oral LD50 Dermal LC50 Inhalation Barium nitrate 50-300 mg/kg (Rat ) Not listed Not listed Pentaerythritol 19500 mg/kg (Rat) Not Listed Not Listed

Toxicologically Synergistic Products No information available Delayed and immediate effects as well as chronic effects from short and long-term exposure

Irritation Irritating to eyes

Sensitization No information available

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Component CAS-No IARC NTP ACGIH OSHA Mexico Barium nitrate 10022-31-8 Not listed Not listed Not listed Not listed Not listed

Mutagenic Effects No information available

Reproductive Effects No information available.

Developmental Effects No information available.

Teratogenicity No information available.

STOT - single exposure None known STOT - repeated exposure None known

Aspiration hazard No information available

Symptoms/effects (both acute and No information available delayed)

Endocrine Disruptor Information No information available

Other Adverse Effects The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information.

12. Ecological information

Ecotoxicity Do not empty into drains.

Persistence and Degradability Soluble in water. Persistence is unlikely based on information available.

Bioaccumulation/ Accumulation No information available.

Mobility Will likely be mobile in the environment due to its water solubility.

13. Disposal considerations

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

14. Transport information

DOT

UN-No UN1479 Proper Shipping Name OXIDIZING

SOLID, N.O. S.

Hazard Class 5.1 Subsidiary Hazard Class 6.1 Packing Group

TDG

II

UN-No UN1479 Proper Shipping Name OXIDIZING

SOLID, N.O. S.

Hazard Class 5.1 Subsidiary Hazard Class 6.1 Packing Group

IATA

II

UN-No UN1479 Proper Shipping Name OXIDIZING

SOLID, N.O. S.

Hazard Class 5.1 Subsidiary Hazard Class 6.1 Packing Group II

IMDG/IMO

UN-No UN1479 Proper Shipping Name OXIDIZING SOLID, N.O.S.

Hazard Class 5.1 Subsidiary Hazard Class 6.1 Packing Group II

15. Regulatory information

International Inventories

Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Barium nitrate X X - 233-020-

- X X X X X

Legend:

X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.

F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.

N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used.

P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.

S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA.

XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B).

Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.

Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule.

U.S. Federal Regulations

TSCA 12(b) Not applicable

SARA 313

Component CAS-No Weight % SARA 313 - Threshold

Values % Barium nitrate 10022-31-8 44 1.0

Pentaerythritol 115-77-5 50 N/A

Estane 5703 N/A 3 N/A

Tris (Beta-Chloroethyl) Phosphate

115-96-8 1 N/A

SARA 311/312 Hazardous Categorization Acute Health Hazard

Yes

Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard Yes

Clean Water Act Not applicable

Clean Air Act Not applicable

OSHA Occupational Safety and Health Administration Not applicable

CERCLA Not applicable

California Proposition 65 This product does not contain any Proposition 65 materials

State Right-to-Know oduct does no

Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island Barium nitrate X X X X X

U.S. Department of Transportation

Reportable Quantity (RQ): N DOT Marine Pollutant N DOT Severe Marine Pollutant N U.S. Department of Homeland Security This product does not contain any DHS chemicals.

Other International Regulations

Mexico - Grade No information available

Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by the CPR

WHMIS Hazard Class C Oxidizing materials D1B Toxic materials

16. Other information

Prepared By Steve Stewart American Ordnance LLC Email: steve.stewart@aollc.biz

Creation Date 28 May 2019 Revision Date 28 May 2019 Print Date 28 May 2019 Revision Summary This document has been updated to comply with the US OSHA HazCom 2012

Standard replacing the current legislation under 29 CFR 1910.1200 to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)

Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.

End of SDS