864709_polyester resin SDS.pdf

MSDS CC-1105-HTC Page 1 of 7

MATERIAL SAFETY DATA SHEET

John C Dolph (a Company)

DOLPHON®

CC-1105-HTC

Solventless Polyester Resin

SECTION 1: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Manufacturer Name: John C Dolph (a Von Roll Company)

Address: 320 New Road, Monmouth Junction, New Jersey 08852

Business Phone: 732-329-2333

Business Fax: 732-329-1143

CHEMTREC: For transportation emergencies 703-527-3887 (US call 800-424-9300)

24-Hour Emergency: 518-395-3310

Manufacturer MSDS Creation Date: 09/2004

Manufacturer MSDS Revision Date: 06/2013

SECTION 2: COMPOSITION, INFORMATION ON INGREDIENTS

Chemical Name Diallyl Phthalate (DAP)

CAS#

131-17-9

% Weight 40-60

OSHA PEL

Not Established

ACGIH TLV

Not Established

Chemical Name Additives

CAS#

Not Applicable

% Weight 1-3

OSHA PEL

ACGIH TLV

Not Established

Chemical Name Dicumyl Peroxide

CAS#

80-43-3

% Weight 0.1-1

OSHA PEL

Not Established

ACGIH TLV

SECTION 3: HAZARDS IDENTIFICATION

Emergency Overview:

Irritant. Harmful. May undergo hazardous polymerization.

Applies to All Ingredients:

Route of Exposure:

Eyes, Skin, Inhalation, and Ingestion.

Potential Health Effects:

Eye Contact:

Can cause eye irritation, including burning sensation, tearing, redness or swelling.

Skin Contact:

Can cause skin irritation and blistering. Effects may be delayed. May cause allergic reaction.

Skin Absorption:

May be toxic if absorbed through the skin.

Inhalation:

Can cause respiratory irritation. Overexposure may cause coughing, shortness of breath, dizziness, intoxication and collapse.

Ingestion:

Small amounts (a tablespoonful) swallowed during normal handling operations are not likely to cause injury, swallowing amounts larger than that may cause injury.

Chronic Health Effects:

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Repeated or prolonged exposure may result in liver damage.

Target Organs:

Liver, eyes, skin, Respiratory System, and digestive tract

Aggravation of Pre-Existing Conditions:

May aggravate pre-existing liver disease.

SECTION 4: FIRST AID MEASURES

Eye Contact:

Immediately flush eyes with plenty of water for at least 20 minutes. Assure adequate flushing of the eyes by separating the eyelids with fingers. Get immediate medical attention if irritation persists, or symptoms of overexposure become apparent.

Skin Contact:

Immediately wash skin with plenty of water and soap for at least 20 minutes, while removing contaminated clothing and shoes. Get medical attention especially, if irritation develops, persists, or symptoms of overexposure become apparent.

Inhalation:

Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Keep warm. Get immediate medical attention.

Ingestion:

If swallowed, call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Do not induce vomiting unless instructed by medical personnel. Get medical attention.

SECTION 5: FIRE FIGHTING MEASURES

Flash Point:

>200°F (93.3°C)

Upper Flammable or Explosive Limit:

Not Established

Lower Flammable or Explosive Limit:

Not Established

Extinguishing Media:

In the event of a fire involving this material, alone or in combination with other materials, use dry chemicals, carbon dioxide, universal foam extinguishing media or water fog.

Hazardous Combustion Byproducts:

Oxides of carbon and oxides of nitrogen, methanol, formaldehyde, and acrid fumes of allylic compounds.

Fire Fighting Instructions:

Evacuate area and fight fire from a safe distance. Containers can build up pressure if exposed to heat (fire). Use water spray to cool fire-exposed containers. DO NOT extinguish a fire resulting from the flow of this flammable liquid until the flow of liquid is effectively shut off. Explosive vapor-air mixture could form after the initial fire is extinguished. Use water spray to disperse vapors if a spill or leak has not ignited. Water runoff can cause environmental damage. Dike and collect water used to fight fire. See Section 13 for disposal considerations.

Protective Equipment:

Wear self-contained breathing apparatus pressure-demand, NIOSH (approved or equivalent) and full protective gear.

Special Properties:

This material may polymerize (react) when its container is exposed to heat (as during a fire). This polymerization increases pressure inside a closed container and may result in the violent rupture of the container. Heat from a fire can generate

MSDS CC-1105-HTC Page 3 of 7 flammable vapor. Vapor can travel to a source of ignition and flash back. Burning liquid may float on water. Avoid frothing/steam explosion.

NFPA

Health: 2 Flammability: 1

Instability: 1

Other: NONE

SECTION 6: ACCIDENTIAL RELEASE MEASURES

Spill Cleanup Measures:

Remove all sources of ignition. Absorb spill with dry inert material (e.g., dry sand or earth), then place in a chemical waste container. Clean up spills immediately observing precautions in the protective equipment section.

Environmental Precautions:

Contain liquid to prevent contamination of soil, surface water or ground water. Avoid runoff into storm sewers and ditches, which lead to waterways. Do not flush to sewer.

Spill/Release Reporting:

Immediately notify authorities of any reportable spill as may be required pursuant to regulations. See Section 15 for applicable CERCLA reportable quantities.

SECTION 7: HANDLING and STORAGE Handling:

This product should be handled only by, or under the close supervision of, those properly qualified in the handling and use of potentially hazardous chemicals, who should take into account the fire, health and chemical hazard data.

Use with adequate ventilation.

When normal handling requires heating, do not heat higher than 28C or 50F below the flash point temperature unless in an air free closed system sealed off from the atmosphere.

"Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition.

Containers may explode and cause injury or death. Empty drums or containers should be completely drained, properly bunged and promptly returned to a drum reconditioner, or properly disposed of.

Storage:

Store in a cool, dry, well ventilated area away from sources of heat and incompatible substances. Do not store at or below freezing point (32F or 0C). Keep container tightly closed when not in use. Consult manufacturer for shelf life.

Hygiene Practices:

Wash thoroughly after handling. Avoid contact with eyes and skin. Avoid inhaling vapor or mist.

Special Handling Procedures:

High temperature, radiation, oxidizers, impurities and/or depletion of inhibitor may cause spontaneous polymerization reaction generating heat and pressure. Closed containers may rupture or explode during rapid polymerization.

SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION

Engineering Controls:

Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended and or regulated exposure limits. Where such systems are not

MSDS CC-1105-HTC Page 4 of 7 effective wear suitable personal protective equipment, which performs satisfactorily and meets OSHA or other recognized standards. Consult with local procedures for selection, training, inspection and maintenance of the personal protective equipment.

Skin Protection Description:

Wear suitable protective clothing to prevent contact with skin.

Hand Protection Description:

Wear appropriate protective gloves such as neoprene or viton. Consult glove manufacturers for glove permeability data.

Eye/Face Protection:

Wear appropriate protective glasses or splash goggles as described by 29 CFR

1910.133, OSHA eye and face protection regulation, or the European standard EN

166.

Protective Clothing/Body Protection:

If splashing is likely, wear impervious clothing and boots to prevent repeated or prolonged skin contact. Consult your supplier of personal protective equipment for additional instructions on proper usage.

Respiratory Protection:

A NIOSH approved air-purifying respirator with an appropriate cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited to airborne concentrations that are typically within 10 times the exposure limit. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air-purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirators use.

Other Protective:

Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Physical State/Appearance:

Liquid

Color:

Clear/Amber

Odor:

Aromatic pH:

No data.

Decomposition Temperature:

No data.

Vapor Pressure:

No data.

Vapor Density:

No data.

Boiling Point:

No data.

Freezing Point:

No data.

Solubility in Water:

No data.

Specific Gravity:

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1.15-1.25

Percent Volatile:

No data

Viscosity:

300-800 cps

Molecular Weight:

Mixture

Flashpoint:

>200°F (93.3°F)

Auto Ignition Temp:

Not Established

Upper Flammable Explosive Limit:

Not Established

Lower Flammable Explosive Limit:

SECTION 10: STABILITY AND REACTIVITY

Chemical Stability:

Stable at normal temperatures and storage conditions.

Conditions to Avoid:

Flames, heat, sparks and high temperatures and pressures. Do not distill at atmospheric conditions. Oxidizing conditions. Freezing conditions. Direct sunlight and ultraviolet radiation.

Incompatibilities with Other Materials:

Strong oxidizers, strong alkalies, strong acids, and ultraviolet light.

Hazardous Polymerization:

Hazardous polymerization will occur if contaminated with peroxides and polymerization catalysts. Raising the temperature and/or pressure will cause polymerization especially if inhibitor concentration is reduced.

Hazardous Decomposition Products:

When heated to decomposition it emits acrid smoke and irritating fumes, which may include allylic compounds, carbon monoxide, methanol, formaldehyde, and various hydrocarbons.

SECTION 11: TOXICOLOGICAL INFORMATION

Diallyl Phthalate (DAP):

Eye Effect:

Standard Draize test - rabbit, 500 mg, Moderate

Skin Effects:

Standard Draize test - rabbit, 500 mg, Mild

Ingestion Effects:

LD50 - rat, 656 mg/kg

Inhalation Effects:

LC50 - rat, 5200 gm/m3/1H

Carcinogenicity:

Not listed by the International Agency for Research on Cancer (IARC) Monographs, or by the Occupational Safety and Health Administration (OSHA). The National

Toxicology Program (NTP) Annual Report on Carcinogens, inadequate studies:

mouse, rat.

Irritation:

Primary irritant

Additives:

Acute Health Effects:

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The primary hazard of these components is skin and eye irritation.

Carcinogenicity:

Not listed by the National Toxicology Program (NTP) Annual Report on Carcinogens or by the International Agency for Research on Cancer (IARC) Monographs, or by the

Occupational Safety and Health Administration (OSHA).

Mutagenicity:

Contains less than 1% Benzotriazole (CAS 95-14-7) which has been listed as a mutagen by RTECS.

Dicumyl peroxide:

Acute Health Effects:

The primary hazard of these components is skin, ingestion and inhalation.

Carcinogenicity:

Not listed by the National Toxicology Program (NTP) Annual Report on Carcinogens or by the International Agency for Research on Cancer (IARC) Monographs, or by the

Occupational Safety and Health Administration (OSHA).

Mutagenicity / Genotoxicity:

No mutagenicity or genotoxicity studies have been carried out with this product.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity:

Dicumyl peroxide:

Toxicity to fish:

LC50: 108 mg/l / 96h

Toxicity to algae:

EC50: 1000 mg/l / 72h

Chronic toxicity in daphnia:

Daphnia magna: 1740 mg/l / 48 d

General Ecological Information:

The data is based on the pure substance.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal:

Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the classifications of hazardous waste prior to disposal. Furthermore, consult with your state and local waste requirements or guidelines, if applicable, to ensure compliance. Arrange disposal in accordance to the EPA and/or state and local guidelines, by a licensed disposal company.

SECTION 14: TRANSPORT INFORMATION

FOR DOMESTIC NON-BULK SHIPMENT

DOT Shipping Name:

RESIN COMPOUND, LIQUID, NOT REGULATED

DOT UN Number:

NOT REGULATED

DOT Hazard Class: NOT REGULATED

DOT Packing Group: NOT REGULATED

FOR DOMESTIC BULK SHIPMENT AND OCEAN TRANSPORT

Shipping Name:

ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.

MSDS CC-1105-HTC Page 7 of 7

(CONTAINS DIALLYL PHTHALATE)

UN Number:

UN3082

Hazard Class: CLASS 9

Packing Group: III

Marine Pollutant: DIALLYL PHTHALATE

SECTION 15: REGULATORY INFORMATION

All Ingredients:

TSCA 8(b): Inventory Status Listed or Exempt

Diallyl Phthalate (DAP):

Section 312 Hazard Category:

Acute: Yes Chronic: Yes Reactive: Yes Section 112(r): Clean Air Act Not listed

Section 116.4 part 117: Clean Water Act Not listed

State:

Listed in Pennsylvania and Massachusetts

Dicumyl Peroxide:

Section 312 Hazard Category:

Acute: Yes Chronic: Yes Reactive: Yes Section 112(r): Clean Air Act Not listed

Section 116.4 part 117: Clean Water Act Not listed

State:

Not Available

SECTION 16: ADDITIONAL INFORMATION

HMIS:

Health Hazard: 2* Fire Hazard: 1 Physical Hazard: 1

Disclaimer:

While John C Dolph (a Von Roll Company) believes the data set forth herein are accurate as of the date hereof, it is furnished without warranty of any kind and specially disclaims all liability for reliance on the information provided. The data is furnished solely for your consideration, investigation and verification.