J153025-1 Std_Tal_L4 Final Report_Part6.pdf

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Maintenance Dredging of Shrewsbury River, New Jersey Federal Navigation Channel - Upland
Solicitation number
W912DS23B0017
Issued by

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This file is related to a federal solicitation for maintenance dredging of the Shrewsbury River Federal Navigation Channel in New Jersey. The solicitation was issued by the Department of the Army Corps of Engineers Engineering District New York under number W912DS23B0017. It requests bids for dredging services to maintain the depth of the Shrewsbury River channel to accommodate commercial and recreational vessel traffic. The solicitation does not specify pricing terms but seeks bids from contractors with experience in dredging operations to remove sediment buildup from the navigation channel on an as-needed basis. The response deadline and anticipated award date are not stated in the associated file.

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J153025-1 Std_Tal_L4 Final Report_Part2.pdf PDF
J153025-1 Std_Tal_L4 Final Report_Part1.pdf PDF
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J152563-1 Std_Tal_L4 Final Report_Part5.pdf PDF
J152790-1 Std_Tal_L4 Final Report_Part6.pdf PDF
J152563-1 Std_Tal_L4 Final Report_Part2.pdf PDF
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J152790-1 Std_Tal_L4 Final Report_Part2.pdf PDF
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Report Date: 14-Mar-2023 08:02:02 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Eurofins Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Injection Date: 13-Mar-2023 10:39:51 Instrument ID: CGC1 Operator ID:

Lims ID: CCVRT Worklist Smp#: 1

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 1

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0313230000003.D

D a la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

M

C P

P

.2

D ic a m b a

.2

P

A

.6 ic h lo rp ro p

.9

,4 -D

.3

P e n ta c h lo ro p h e n o l(

.9

S ilv e x

,4

,5 -T

P

.0

,5

-T

.6 in o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0313230000003.D

la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n

.6 e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

FORM VII

Lab Name: Job No.:

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-153025-1

CGC1

03/13/2023 10:39

03/01/2023 08:51

03/01/2023 10:49

CCVRT 180-428960/1

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0313230000003.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 404179350375256434 0.0862 0.0800 7.7 15.0Ave

Dicamba 12335751251168485590 0.0422 0.0400 5.6 15.0Ave

MCPP 15881821506095 8.44 8.00 5.5 15.0Ave

MCPA 23559522278633 8.27 8.00 3.4 15.0Ave

Dichlorprop 355627400336258134 0.0846 0.0800 5.8 15.0Ave

2,4-D 397892988378375181 0.0841 0.0800 5.2 15.0Ave

Pentachlorophenol 43463414504053407968 0.0214 0.0200 7.2 15.0Ave

Silvex (2,4,5-TP) 19052769501734230344 0.0220 0.0200 9.9 15.0Ave

2,4,5-T 16502652501512853745 0.0218 0.0200 9.1 15.0Ave

2,4-DB 222555650210048987 0.0848 0.0800 6.0 15.0Ave

Dinoseb 1044161200987392817 0.0846 0.0800 5.7 15.0Ave

2,4-Dichlorophenylacetic acid

443191000403173549 0.0176 0.0160 9.9 15.0Ave

FORM VII EPA 8151A

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-153025-1

CGC1

03/13/2023 10:39

03/01/2023 08:51

03/01/2023 10:49

CCVRT 180-428960/1

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0313230000003.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.37 2.34 2.40 Dicamba 8.20 8.17 8.23

MCPP 8.36 8.33 8.39

MCPA 8.66 8.63 8.69

Dichlorprop 9.03 9.00 9.06 2,4-D 9.42 9.39 9.45 Pentachlorophenol 9.64 9.61 9.67 Silvex (2,4,5-TP) 10.19 10.16 10.22 2,4,5-T 10.65 10.62 10.68

2,4-DB 11.08 11.05 11.11

Dinoseb 11.71 11.68 11.74 2,4-Dichlorophenylacetic acid 7.93 7.90 7.96

Form VII EPA 8151A

Report Date: 14-Mar-2023 08:02:03 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Lims ID: CCVRT

Client ID:

Sample Type: CCVRT

Inject. Date: 13-Mar-2023 10:39:51 ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-001

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:02 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 13-Mar-2023 10:58:44

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.173 2.173 0.000 36775176H 0.0800 0.0863

2 2.365 2.365 0.000 32334348H 0.0800 0.0862

RPD = 0.15

$ 2 2,4-Dichlorophenylacetic acid

1 7.986 7.986 0.000 7494396H 0.0160 0.0155

2 7.933 7.933 0.000 7091056H 0.0160 0.0176

RPD = 12.75

3 MCPP M

1 8.202 8.202 0.000 11507737H 8.00 8.91

2 8.357 8.357 0.000 12705453H 8.00 8.44 M

RPD = 5.42

4 Dicamba

1 8.281 8.281 0.000 50590012H 0.0400 0.0381

2 8.197 8.197 0.000 49343005H 0.0400 0.0422

RPD = 10.29

5 MCPA

1 8.625 8.625 0.000 16532342H 8.00 7.97

2 8.663 8.663 0.000 18847615H 8.00 8.27

RPD = 3.73

6 Dichlorprop

1 8.905 8.905 0.000 28096666H 0.0800 0.0769

2 9.025 9.025 0.000 28450192H 0.0800 0.0846

RPD = 9.58

7 2,4-D

1 9.398 9.398 0.000 30653672H 0.0800 0.0775

2 9.421 9.421 0.000 31831439H 0.0800 0.0841

RPD = 8.14

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.925 9.925 0.000 79730457H 0.0200 0.0183

2 9.635 9.635 0.000 86926829H 0.0200 0.0214

RPD = 15.89

9 Silvex (2,4,5-TP)

1 10.082 10.082 0.000 34966248H 0.0200 0.0188

2 10.194 10.194 0.000 38105539H 0.0200 0.0220

RPD = 15.81

10 2,4,5-T

1 10.633 10.633 0.000 31719187H 0.0200 0.0189

2 10.645 10.645 0.000 33005305H 0.0200 0.0218

RPD = 14.35

11 Dinoseb

1 10.889 10.889 0.000 86635406H 0.0800 0.0770

2 11.714 11.714 0.000 83532896H 0.0800 0.0846

RPD = 9.40

12 2,4-DB

1 11.017 11.017 0.000 16294763H 0.0800 0.0753

2 11.075 11.075 0.000 17804452H 0.0800 0.0848

RPD = 11.80

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

GCHERBCALSL3_00044 Amount Added: 1.00 Units: mL

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Injection Date: 13-Mar-2023 10:39:51 Instrument ID: CGC1 Operator ID:

Lims ID: CCVRT Worklist Smp#: 1

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 1

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0313230000003.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.2

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

Manual Integration/User Assign Peak Report

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Injection Date: 13-Mar-2023 10:39:51 Instrument ID: CGC1

Lims ID: CCVRT

Client ID:

Operator ID: ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-1701 ( 0.53 mm) Detector GC ECD2B

3 MCPP, CAS: 93-65-2

Signal: 2

Processing Integration Results

RT: 8.36

Height: 2979085

Amount: 1.978019

Amount Units: ng

8.0 8.2 8.4 8.6 8.8 Min

Y

X

.3

Manual Integration Results

RT: 8.36

Height: 12705453

Amount: 8.436024

Amount Units: ng

8.0 8.2 8.4 8.6 8.8 Min

RT

Y

X

.3

Reviewer: WB9V, 13-Mar-2023 10:58:29

Audit Action: Manually Integrated Audit Reason: Incomplete Integration

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-153025-1

CGC1

03/13/2023 14:14

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428960/12

RTX-50

Eurofins Pittsburgh

Lab File ID: 0313230000014.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 522383925426136913 0.0981 0.0800 22.6* 15.0Ave

MCPP 16230731292107 10.0 8.00 25.6* 15.0Ave

Dicamba 14758088501328035766 0.0445 0.0400 11.1 15.0Ave

MCPA 23415512074591 9.03 8.00 12.9 15.0Ave

Dichlorprop 411135450365500443 0.0900 0.0800 12.5 15.0Ave

2,4-D 446770300395299965 0.0904 0.0800 13.0 15.0Ave

Pentachlorophenol 48458398004359687678 0.0222 0.0200 11.2 15.0Ave

Silvex (2,4,5-TP) 20567025501864583594 0.0221 0.0200 10.3 15.0Ave

2,4,5-T 18806471501678631374 0.0224 0.0200 12.0 15.0Ave

Dinoseb 13140491501125029965 0.0934 0.0800 16.8* 15.0Ave

2,4-DB 243201425216341182 0.0899 0.0800 12.4 15.0Ave

2,4-Dichlorophenylacetic acid

549014000484132325 0.0181 0.0160 13.4 15.0Ave

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-153025-1

CGC1

03/13/2023 14:14

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428960/12

RTX-50

Eurofins Pittsburgh

Lab File ID: 0313230000014.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.17 2.14 2.20

MCPP 8.20 8.17 8.23

Dicamba 8.28 8.25 8.31

MCPA 8.62 8.60 8.66

Dichlorprop 8.90 8.88 8.94 2,4-D 9.40 9.37 9.43 Pentachlorophenol 9.92 9.90 9.96 Silvex (2,4,5-TP) 10.08 10.05 10.11 2,4,5-T 10.63 10.60 10.66 Dinoseb 10.89 10.84 10.94

2,4-DB 11.02 10.99 11.05

2,4-Dichlorophenylacetic acid 7.98 7.96 8.02

Report Date: 14-Mar-2023 08:02:21 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000014.D

Lims ID: CCV

Client ID:

Sample Type: CCV

Inject. Date: 13-Mar-2023 14:14:46 ALS Bottle#: 12 Worklist Smp#: 12

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-012

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:21 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 14-Mar-2023 07:59:06

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.171 2.173 -0.002 41790714H 0.0800 0.0981

2 2.363 2.365 -0.002 35240436H 0.0800 0.0939

RPD = 4.33

$ 2 2,4-Dichlorophenylacetic acid

1 7.983 7.986 -0.003 8784224H 0.0160 0.0181

2 7.933 7.933 0.000 7127487H 0.0160 0.0177

RPD = 2.60

3 MCPP

1 8.200 8.202 -0.002 12984580H 8.00 10.0

2 8.355 8.357 -0.002 13545336H 8.00 8.99

RPD = 11.09

4 Dicamba

1 8.280 8.281 -0.001 59032354H 0.0400 0.0445

2 8.196 8.197 -0.001 54592366H 0.0400 0.0467

RPD = 4.98

5 MCPA

1 8.623 8.625 -0.002 18732411H 8.00 9.03

2 8.662 8.663 -0.001 19666213H 8.00 8.63

RPD = 4.52

6 Dichlorprop

1 8.903 8.905 -0.002 32890836H 0.0800 0.0900

2 9.025 9.025 0.000 31261604H 0.0800 0.0930

RPD = 3.26

7 2,4-D

1 9.396 9.398 -0.002 35741624H 0.0800 0.0904

2 9.419 9.421 -0.002 35112366H 0.0800 0.0928

RPD = 2.60

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000014.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.923 9.925 -0.002 96916796H 0.0200 0.0222

2 9.635 9.635 0.000 94934666H 0.0200 0.0234

RPD = 5.22

9 Silvex (2,4,5-TP)

1 10.081 10.082 -0.001 41134051H 0.0200 0.0221

2 10.191 10.194 -0.003 41475690H 0.0200 0.0239

RPD = 8.07

10 2,4,5-T

1 10.632 10.633 -0.001 37612943H 0.0200 0.0224

2 10.646 10.645 0.001 36480110H 0.0200 0.0241

RPD = 7.34

11 Dinoseb

1 10.888 10.889 -0.001 105123932H 0.0800 0.0934

2 11.715 11.714 0.001 93773052H 0.0800 0.0950

RPD = 1.62

12 2,4-DB

1 11.016 11.017 -0.001 19456114H 0.0800 0.0899

2 11.074 11.075 -0.001 20362988H 0.0800 0.0969

RPD = 7.50

QC Flag Legend Processing Flags

H - Response Measured by Height

Reagents:

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000014.D

Injection Date: 13-Mar-2023 14:14:46 Instrument ID: CGC1 Operator ID:

Lims ID: CCV Worklist Smp#: 12

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 12

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0313230000014.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.2

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0313230000014.D

la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-153025-1

CGC1

03/13/2023 14:14

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428960/12

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0313230000014.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 440505450375256434 0.0939 0.0800 17.4* 15.0Ave

Dicamba 13648091501168485590 0.0467 0.0400 16.8* 15.0Ave

MCPP 16931671506095 8.99 8.00 12.4 15.0Ave

MCPA 24582772278633 8.63 8.00 7.9 15.0Ave

Dichlorprop 390770050336258134 0.0930 0.0800 16.2* 15.0Ave

2,4-D 438904575378375181 0.0928 0.0800 16.0* 15.0Ave

Pentachlorophenol 47467333004053407968 0.0234 0.0200 17.1* 15.0Ave

Silvex (2,4,5-TP) 20737845001734230344 0.0239 0.0200 19.6* 15.0Ave

2,4,5-T 18240055001512853745 0.0241 0.0200 20.6* 15.0Ave

2,4-DB 254537350210048987 0.0969 0.0800 21.2* 15.0Ave

Dinoseb 1172163150987392817 0.0950 0.0800 18.7* 15.0Ave

2,4-Dichlorophenylacetic acid

445467938403173549 0.0177 0.0160 10.5 15.0Ave

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-153025-1

CGC1

03/13/2023 14:14

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428960/12

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0313230000014.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.36 2.34 2.40 Dicamba 8.20 8.17 8.23

MCPP 8.36 8.33 8.39

MCPA 8.66 8.63 8.69

Dichlorprop 9.03 9.00 9.06 2,4-D 9.42 9.39 9.45 Pentachlorophenol 9.64 9.61 9.67 Silvex (2,4,5-TP) 10.19 10.16 10.22 2,4,5-T 10.65 10.62 10.68

2,4-DB 11.07 11.05 11.11

Dinoseb 11.72 11.68 11.74 2,4-Dichlorophenylacetic acid 7.93 7.90 7.96

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000014.D

Lims ID: CCV

Client ID:

Sample Type: CCV

Inject. Date: 13-Mar-2023 14:14:46 ALS Bottle#: 12 Worklist Smp#: 12

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-012

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:21 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 14-Mar-2023 07:59:06

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.171 2.173 -0.002 41790714H 0.0800 0.0981

2 2.363 2.365 -0.002 35240436H 0.0800 0.0939

RPD = 4.33

$ 2 2,4-Dichlorophenylacetic acid

1 7.983 7.986 -0.003 8784224H 0.0160 0.0181

2 7.933 7.933 0.000 7127487H 0.0160 0.0177

RPD = 2.60

3 MCPP

1 8.200 8.202 -0.002 12984580H 8.00 10.0

2 8.355 8.357 -0.002 13545336H 8.00 8.99

RPD = 11.09

4 Dicamba

1 8.280 8.281 -0.001 59032354H 0.0400 0.0445

2 8.196 8.197 -0.001 54592366H 0.0400 0.0467

RPD = 4.98

5 MCPA

1 8.623 8.625 -0.002 18732411H 8.00 9.03

2 8.662 8.663 -0.001 19666213H 8.00 8.63

RPD = 4.52

6 Dichlorprop

1 8.903 8.905 -0.002 32890836H 0.0800 0.0900

2 9.025 9.025 0.000 31261604H 0.0800 0.0930

RPD = 3.26

7 2,4-D

1 9.396 9.398 -0.002 35741624H 0.0800 0.0904

2 9.419 9.421 -0.002 35112366H 0.0800 0.0928

RPD = 2.60

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000014.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.923 9.925 -0.002 96916796H 0.0200 0.0222

2 9.635 9.635 0.000 94934666H 0.0200 0.0234

RPD = 5.22

9 Silvex (2,4,5-TP)

1 10.081 10.082 -0.001 41134051H 0.0200 0.0221

2 10.191 10.194 -0.003 41475690H 0.0200 0.0239

RPD = 8.07

10 2,4,5-T

1 10.632 10.633 -0.001 37612943H 0.0200 0.0224

2 10.646 10.645 0.001 36480110H 0.0200 0.0241

RPD = 7.34

11 Dinoseb

1 10.888 10.889 -0.001 105123932H 0.0800 0.0934

2 11.715 11.714 0.001 93773052H 0.0800 0.0950

RPD = 1.62

12 2,4-DB

1 11.016 11.017 -0.001 19456114H 0.0800 0.0899

2 11.074 11.075 -0.001 20362988H 0.0800 0.0969

RPD = 7.50

QC Flag Legend Processing Flags

H - Response Measured by Height

Reagents:

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000014.D

Injection Date: 13-Mar-2023 14:14:46 Instrument ID: CGC1 Operator ID:

Lims ID: CCV Worklist Smp#: 12

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 12

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0313230000014.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.2

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0313230000014.D

la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

FORM I

HERBICIDES ORGANICS ANALYSIS DATA SHEET

Lab Name: Job No.: 180-153025-1Eurofins Pittsburgh

SDG No.:

Client Sample ID: Lab Sample ID: MB 180-428159/1-A

Matrix: 0313230000004.DLab File ID:

Date Collected:EPA 8151AAnalysis Method:

Sediment

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Extracted:

Date Analyzed:

Dilution Factor: 1

Extraction Method: 8151A 03/06/2023 00:45

03/13/2023 10:59

40.0(mL)

1(uL)

Sample wt/vol: 10.0(g)

% Moisture:

GC Column: ID: 0.53(mm)RTX-50

N% Solids:

Cleanup Factor:

Analysis Batch No.: 428960 ug/KgUnits:

CAS NO. COMPOUND NAME RESULT Q MDLRL

20 11U93-72-1 Silvex (2,4,5-TP) 20

%RECCAS NO. LIMITSQSURROGATE

S1-37 48-12719719-28-9 2,4-Dichlorophenylacetic acid

FORM I EPA 8151A

Report Date: 14-Mar-2023 08:02:04 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000004.D

Lims ID: MB 180-428159/1-A

Client ID:

Sample Type: MB

Inject. Date: 13-Mar-2023 10:59:21 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-002

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:02 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 14-Mar-2023 07:39:07

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.173 ND

2 2.365

$ 2 2,4-Dichlorophenylacetic acid

1 7.985 7.986 -0.001 8842899H 0.0500 0.0183

2 7.933 7.933 0.000 10748600H 0.0500 0.0267

RPD = 37.37

3 MCPP

1 8.202 ND

2 8.357

4 Dicamba U

1 8.281 ND

2 8.197

5 MCPA U

1 8.625 ND

2 8.663

6 Dichlorprop

1 8.905 ND

2 9.025

7 2,4-D

1 9.398 ND

2 9.421

8 Pentachlorophenol U

1 9.925 ND

2 9.635

9 Silvex (2,4,5-TP) U

1 10.082 ND

2 10.194

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000004.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

10 2,4,5-T

1 10.633 ND

2 10.645

11 Dinoseb

1 10.889 ND

2 11.714

12 2,4-DB

1 11.017 ND

2 11.075

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

U - Marked Undetected

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000004.D

Injection Date: 13-Mar-2023 10:59:21 Instrument ID: CGC1 Operator ID:

Lims ID: MB 180-428159/1-A Worklist Smp#: 2

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 2

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0313230000004.D

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0313230000004.D

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

Recovery Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000004.D

Lims ID: MB 180-428159/1-A

Client ID:

Sample Type: MB

Inject. Date: 13-Mar-2023 10:59:21 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-002

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:02 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 14-Mar-2023 07:39:07

Surrogate Recovery, Detector: GC ECD1A

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 0.0500 0.0183 36.53

Surrogate Recovery, Detector: GC ECD2B

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 0.0500 0.0267 53.32

User Disabled Compound Report

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000004.D

Injection Date: 13-Mar-2023 10:59:21 Instrument ID: CGC1

Lims ID: MB 180-428159/1-A

Client ID:

Operator ID: ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm) Detector GC ECD1A

9 Silvex (2,4,5-TP), CAS: 93-72-1, Signal: 1

RT: 10.07

Response: 217630

Amount: 0.000117

9.9 10.1 Min

RT

Y

X

GC ECD1A, 0313230000004.D

.0

Column: RTX-1701 ( 0.53 mm) Detector GC ECD2B

9 Silvex (2,4,5-TP), CAS: 93-72-1, Signal: 2

RT: 10.18

Response: 314355

Amount: 0.000181

10.0 10.2 Min

RT

Y

X

GC ECD2B, 0313230000004.D

.1

Reviewer: WB9V, 14-Mar-2023 07:39:07

Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID

Lab Name: Job No.: 180-153025-1Eurofins Pittsburgh

SDG No.:

Client Sample ID: Lab Sample ID: MB 180-428159/1-A

Matrix: 0313230000004.DLab File ID:

Date Collected:EPA 8151AAnalysis Method:

Sediment

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Extracted:

Date Analyzed:

Dilution Factor: 1

Extraction Method: 8151A 03/06/2023 00:45

03/13/2023 10:59

40.0(mL)

1(uL)

Sample wt/vol: 10.0(g)

% Moisture:

GC Column: ID: 0.53(mm)RTX-1701

N% Solids:

Cleanup Factor:

Analysis Batch No.: 428960 ug/KgUnits:

%RECCAS NO. LIMITSQSURROGATE

53 48-12719719-28-9 2,4-Dichlorophenylacetic acid

Report Date: 14-Mar-2023 08:02:05 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000004.D

Lims ID: MB 180-428159/1-A

Client ID:

Sample Type: MB

Inject. Date: 13-Mar-2023 10:59:21 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-002

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:02 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 14-Mar-2023 07:39:07

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.173 ND

2 2.365

$ 2 2,4-Dichlorophenylacetic acid

1 7.985 7.986 -0.001 8842899H 0.0500 0.0183

2 7.933 7.933 0.000 10748600H 0.0500 0.0267

RPD = 37.37

3 MCPP

1 8.202 ND

2 8.357

4 Dicamba U

1 8.281 ND

2 8.197

5 MCPA U

1 8.625 ND

2 8.663

6 Dichlorprop

1 8.905 ND

2 9.025

7 2,4-D

1 9.398 ND

2 9.421

8 Pentachlorophenol U

1 9.925 ND

2 9.635

9 Silvex (2,4,5-TP) U

1 10.082 ND

2 10.194

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000004.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

10 2,4,5-T

1 10.633 ND

2 10.645

11 Dinoseb

1 10.889 ND

2 11.714

12 2,4-DB

1 11.017 ND

2 11.075

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000004.D

Injection Date: 13-Mar-2023 10:59:21 Instrument ID: CGC1 Operator ID:

Lims ID: MB 180-428159/1-A Worklist Smp#: 2

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 2

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0313230000004.D

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0313230000004.D

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

Recovery Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000004.D

Lims ID: MB 180-428159/1-A

Client ID:

Sample Type: MB

Inject. Date: 13-Mar-2023 10:59:21 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-002

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:02 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 14-Mar-2023 07:39:07

Surrogate Recovery, Detector: GC ECD1A

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 0.0500 0.0183 36.53

Surrogate Recovery, Detector: GC ECD2B

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 0.0500 0.0267 53.32

User Disabled Compound Report

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000004.D

Injection Date: 13-Mar-2023 10:59:21 Instrument ID: CGC1

Lims ID: MB 180-428159/1-A

Client ID:

Operator ID: ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm) Detector GC ECD1A

9 Silvex (2,4,5-TP), CAS: 93-72-1, Signal: 1

RT: 10.07

Response: 217630

Amount: 0.000117

9.9 10.1 Min

RT

Y

X

GC ECD1A, 0313230000004.D

.0

Column: RTX-1701 ( 0.53 mm) Detector GC ECD2B

9 Silvex (2,4,5-TP), CAS: 93-72-1, Signal: 2

RT: 10.18

Response: 314355

Amount: 0.000181

10.0 10.2 Min

RT

Y

X

GC ECD2B, 0313230000004.D

.1

Reviewer: WB9V, 14-Mar-2023 07:39:07

Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID

Lab Name: Job No.: 180-153025-1Eurofins Pittsburgh

SDG No.:

Client Sample ID: Lab Sample ID: MB 180-428608/1-A

Matrix: 0310230000004.DLab File ID:

Date Collected:EPA 8151AAnalysis Method:

Sediment

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Extracted:

Date Analyzed:

Dilution Factor: 20

Extraction Method: 8151A 03/09/2023 04:30

03/10/2023 13:59

10.0(mL)

1(uL)

Sample wt/vol: 1000(mL)

% Moisture:

GC Column: ID: 0.53(mm)RTX-50

N% Solids:

Cleanup Factor:

Analysis Batch No.: 428810 ug/LUnits:

CAS NO. COMPOUND NAME RESULT Q MDLRL

4.0 2.0U94-75-7 2,4-D 4.0

1.0 0.64U93-72-1 Silvex (2,4,5-TP) 1.0

10 3.7U75-99-0 Dalapon 10

%RECCAS NO. LIMITSQSURROGATE

58 54-11619719-28-9 2,4-Dichlorophenylacetic acid

Report Date: 13-Mar-2023 07:40:18 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000004.D

Lims ID: MB 180-428608/1-A

Client ID:

Sample Type: MB

Inject. Date: 10-Mar-2023 13:59:29 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 20.0000

Sample Info: 180-0047019-002

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 13-Mar-2023 07:40:16 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 10-Mar-2023 14:24:41

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.175 ND

2 2.365

$ 2 2,4-Dichlorophenylacetic acid

1 7.987 7.986 0.001 13960832H 0.0500 0.0288

2 7.934 7.934 0.000 12673473H 0.0500 0.0314

RPD = 8.62

3 MCPP

1 8.202 ND

2 8.356

4 Dicamba

1 8.283 ND

2 8.197

5 MCPA

1 8.626 ND

2 8.663

6 Dichlorprop

1 8.906 ND

2 9.025

7 2,4-D

1 9.399 ND

2 9.420

8 Pentachlorophenol

1 9.927 ND

2 9.635

9 Silvex (2,4,5-TP)

1 10.084 ND

2 10.193

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000004.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

10 2,4,5-T

1 10.636 ND

2 10.645

11 Dinoseb

1 10.890 ND

2 11.715

12 2,4-DB

1 11.020 ND

2 11.076

QC Flag Legend Processing Flags

H - Response Measured by Height

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000004.D

Injection Date: 10-Mar-2023 13:59:29 Instrument ID: CGC1 Operator ID:

Lims ID: MB 180-428608/1-A Worklist Smp#: 2

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 20.0000 ALS Bottle#: 2

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0310230000004.D

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0310230000004.D

,4

-D ic h lo ro p h e n y la c e ti c a c id

.9

Recovery Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000004.D

Lims ID: MB 180-428608/1-A

Client ID:

Sample Type: MB

Inject. Date: 10-Mar-2023 13:59:29 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 20.0000

Sample Info: 180-0047019-002

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 13-Mar-2023 07:40:16 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 10-Mar-2023 14:24:41

Surrogate Recovery, Detector: GC ECD1A

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 1.00 0.0288 57.67

Surrogate Recovery, Detector: GC ECD2B

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 1.00 0.0314 62.87

Lab Name: Job No.: 180-153025-1Eurofins Pittsburgh

SDG No.:

Client Sample ID: Lab Sample ID: MB 180-428608/1-A

Matrix: 0310230000004.DLab File ID:

Date Collected:EPA 8151AAnalysis Method:

Sediment

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Extracted:

Date Analyzed:

Dilution Factor: 20

Extraction Method: 8151A 03/09/2023 04:30

03/10/2023 13:59

10.0(mL)

1(uL)

Sample wt/vol: 1000(mL)

% Moisture:

GC Column: ID: 0.53(mm)RTX-1701

N% Solids:

Cleanup Factor:

Analysis Batch No.: 428810 ug/LUnits:

%RECCAS NO. LIMITSQSURROGATE

63 54-11619719-28-9 2,4-Dichlorophenylacetic acid

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000004.D

Lims ID: MB 180-428608/1-A

Client ID:

Sample Type: MB

Inject. Date: 10-Mar-2023 13:59:29 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 20.0000

Sample Info: 180-0047019-002

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 13-Mar-2023 07:40:16 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 10-Mar-2023 14:24:41

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.175 ND

2 2.365

$ 2 2,4-Dichlorophenylacetic acid

1 7.987 7.986 0.001 13960832H 0.0500 0.0288

2 7.934 7.934 0.000 12673473H 0.0500 0.0314

RPD = 8.62

3 MCPP

1 8.202 ND

2 8.356

4 Dicamba

1 8.283 ND

2 8.197

5 MCPA

1 8.626 ND

2 8.663

6 Dichlorprop

1 8.906 ND

2 9.025

7 2,4-D

1 9.399 ND

2 9.420

8 Pentachlorophenol

1 9.927 ND

2 9.635

9 Silvex (2,4,5-TP)

1 10.084 ND

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000004.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

10 2,4,5-T

1 10.636 ND

2 10.645

11 Dinoseb

1 10.890 ND

2 11.715

12 2,4-DB

1 11.020 ND

2 11.076

QC Flag Legend Processing Flags

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000004.D

Injection Date: 10-Mar-2023 13:59:29 Instrument ID: CGC1 Operator ID:

Lims ID: MB 180-428608/1-A Worklist Smp#: 2

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 20.0000 ALS Bottle#: 2

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0310230000004.D

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0310230000004.D

,4

-D ic h lo ro p h e n y la c e ti c a c id

.9

Recovery Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000004.D

Lims ID: MB 180-428608/1-A

Client ID:

Sample Type: MB

Inject. Date: 10-Mar-2023 13:59:29 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 20.0000

Sample Info: 180-0047019-002

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 13-Mar-2023 07:40:16 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 10-Mar-2023 14:24:41

Surrogate Recovery, Detector: GC ECD1A

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 1.00 0.0288 57.67

Surrogate Recovery, Detector: GC ECD2B

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 1.00 0.0314 62.87

Lab Name: Job No.: 180-153025-1Eurofins Pittsburgh

SDG No.:

Client Sample ID: Lab Sample ID: LB 180-428411/1-E

Matrix: 0310230000012.DLab File ID:

Date Collected:EPA 8151AAnalysis Method:

Sediment (SPLP East)

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Extracted:

Date Analyzed:

Dilution Factor: 20

Extraction Method: 8151A 03/09/2023 04:30

03/10/2023 16:36

10.0(mL)

1(uL)

Sample wt/vol: 1060(mL)

% Moisture:

GC Column: ID: 0.53(mm)RTX-50

N% Solids:

Cleanup Factor:

Analysis Batch No.: 428810 ug/LUnits:

CAS NO. COMPOUND NAME RESULT Q MDLRL

3.8 1.9U94-75-7 2,4-D 3.8

0.94 0.60U93-72-1 Silvex (2,4,5-TP) 0.94

9.4 3.5U75-99-0 Dalapon 9.4

%RECCAS NO. LIMITSQSURROGATE

67 54-11619719-28-9 2,4-Dichlorophenylacetic acid

Report Date: 13-Mar-2023 07:40:30 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000012.D

Lims ID: LB 180-428411/1-E

Client ID:

Sample Type: LB

Inject. Date: 10-Mar-2023 16:36:03 ALS Bottle#: 10 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 20.0000

Sample Info: 180-0047019-010

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 13-Mar-2023 07:40:16 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 13-Mar-2023 07:38:42

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.175 ND

2 2.365

$ 2 2,4-Dichlorophenylacetic acid

1 7.987 7.986 0.001 16163921H 0.0500 0.0334

2 7.935 7.934 0.001 14594862H 0.0500 0.0362

RPD = 8.08

3 MCPP U

1 8.202 ND

2 8.356

4 Dicamba U

1 8.283 ND

2 8.197

5 MCPA

1 8.626 ND

2 8.663

6 Dichlorprop

1 8.906 ND

2 9.025

7 2,4-D

1 9.399 ND

2 9.420

8 Pentachlorophenol

1 9.927 ND

2 9.635

9 Silvex (2,4,5-TP)

1 10.084 ND

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000012.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

10 2,4,5-T

1 10.636 ND

2 10.645

11 Dinoseb

1 10.890 ND

2 11.715

12 2,4-DB

1 11.020 ND

2 11.076

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000012.D

Injection Date: 10-Mar-2023 16:36:03 Instrument ID: CGC1 Operator ID:

Lims ID: LB 180-428411/1-E Worklist Smp#: 10

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 20.0000 ALS Bottle#: 10

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0310230000012.D

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0310230000012.D

,4

-D ic h lo ro p h e n y la c e ti c a c id

.9

Recovery Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000012.D

Lims ID: LB 180-428411/1-E

Client ID:

Sample Type: LB

Inject. Date: 10-Mar-2023 16:36:03 ALS Bottle#: 10 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 20.0000

Sample Info: 180-0047019-010

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 13-Mar-2023 07:40:16 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 13-Mar-2023 07:38:42

Surrogate Recovery, Detector: GC ECD1A

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 1.00 0.0334 66.77

Surrogate Recovery, Detector: GC ECD2B

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 1.00 0.0362 72.40

Lab Name: Job No.: 180-153025-1Eurofins Pittsburgh

SDG No.:

Client Sample ID: Lab Sample ID: LB 180-428411/1-E

Matrix: 0310230000012.DLab File ID:

Date Collected:EPA 8151AAnalysis Method:

Sediment (SPLP East)

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Extracted:

Date Analyzed:

Dilution Factor: 20

Extraction Method: 8151A 03/09/2023 04:30

03/10/2023 16:36

10.0(mL)

1(uL)

Sample wt/vol: 1060(mL)

% Moisture:

GC Column: ID: 0.53(mm)RTX-1701

N% Solids:

Cleanup Factor:

Analysis Batch No.: 428810 ug/LUnits:

%RECCAS NO. LIMITSQSURROGATE

72 54-11619719-28-9 2,4-Dichlorophenylacetic acid

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000012.D

Lims ID: LB 180-428411/1-E

Client ID:

Sample Type: LB

Inject. Date: 10-Mar-2023 16:36:03 ALS Bottle#: 10 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 20.0000

Sample Info: 180-0047019-010

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 13-Mar-2023 07:40:16 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 13-Mar-2023 07:38:42

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.175 ND

2 2.365

$ 2 2,4-Dichlorophenylacetic acid

1 7.987 7.986 0.001 16163921H 0.0500 0.0334

2 7.935 7.934 0.001 14594862H 0.0500 0.0362

RPD = 8.08

3 MCPP U

1 8.202 ND

2 8.356

4 Dicamba U

1 8.283 ND

2 8.197

5 MCPA

1 8.626 ND

2 8.663

6 Dichlorprop

1 8.906 ND

2 9.025

7 2,4-D

1 9.399 ND

2 9.420

8 Pentachlorophenol

1 9.927 ND

2 9.635

9 Silvex (2,4,5-TP)

1 10.084 ND

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000012.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

10 2,4,5-T

1 10.636 ND

2 10.645

11 Dinoseb

1 10.890 ND

2 11.715

12 2,4-DB

1 11.020 ND

2 11.076

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000012.D

Injection Date: 10-Mar-2023 16:36:03 Instrument ID: CGC1 Operator ID:

Lims ID: LB 180-428411/1-E Worklist Smp#: 10

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 20.0000 ALS Bottle#: 10

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0310230000012.D

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0310230000012.D

,4

-D ic h lo ro p h e n y la c e ti c a c id

.9

Recovery Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\0310230000012.D

Lims ID: LB 180-428411/1-E

Client ID:

Sample Type: LB

Inject. Date: 10-Mar-2023 16:36:03 ALS Bottle#: 10 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 20.0000

Sample Info: 180-0047019-010

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230310-47019.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 13-Mar-2023 07:40:16 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 13-Mar-2023 07:38:42

Surrogate Recovery, Detector: GC ECD1A

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 1.00 0.0334 66.77

Surrogate Recovery, Detector: GC ECD2B

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 1.00 0.0362 72.40

Lab Name: Job No.: 180-153025-1Eurofins Pittsburgh

SDG No.:

Client Sample ID: Lab Sample ID: LCS 180-428159/2-A

Matrix: 0313230000013.DLab File ID:

Date Collected:EPA 8151AAnalysis Method:

Sediment

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Extracted:

Date Analyzed:

Dilution Factor: 1

Extraction Method: 8151A 03/06/2023 00:45

03/13/2023 13:55

40.0(mL)

1(uL)

Sample wt/vol: 10.0(g)

% Moisture:

GC Column: ID: 0.53(mm)RTX-50

N% Solids:

Cleanup Factor:

Analysis Batch No.: 428960 ug/KgUnits:

%RECCAS NO. LIMITSQSURROGATE

49 48-12719719-28-9 2,4-Dichlorophenylacetic acid

Report Date: 14-Mar-2023 08:02:19 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000013.D

Lims ID: LCS 180-428159/2-A

Client ID:

Sample Type: LCS

Inject. Date: 13-Mar-2023 13:55:15 ALS Bottle#: 11 Worklist Smp#: 11

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-011

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:02 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 14-Mar-2023 07:58:51

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.171 2.173 -0.002 14841876H 0.1000 0.0348

2 2.323 2.365 -0.042 91269626H 0.1000 0.2432

RPD = 149.90

$ 2 2,4-Dichlorophenylacetic acid M

1 7.982 7.986 -0.004 11926175H 0.0500 0.0246

2 7.933 7.933 0.000 14039294H 0.0500 0.0348 M

RPD = 34.27

3 MCPP

1 8.200 8.202 -0.002 8913288H 10.0 6.90

2 8.355 8.357 -0.002 9008448H 10.0 5.98

RPD = 14.24

4 Dicamba

1 8.280 8.281 -0.001 44547713H 0.0500 0.0335

2 8.195 8.197 -0.002 40801612H 0.0500 0.0349

RPD = 4.01

5 MCPA

1 8.624 8.625 -0.001 15412493H 10.0 7.43

2 8.662 8.663 -0.001 15219914H 10.0 6.68

RPD = 10.63

6 Dichlorprop

1 8.902 8.905 -0.003 24018385H 0.1000 0.0657

2 9.024 9.025 -0.001 23423198H 0.1000 0.0697

RPD = 5.83

7 2,4-D

1 9.395 9.398 -0.003 28041565H 0.1000 0.0709

2 9.418 9.421 -0.003 27945497H 0.1000 0.0739

RPD = 4.03

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000013.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.922 9.925 -0.003 63015728H 0.0250 0.0145

2 9.633 9.635 -0.002 62462324H 0.0250 0.0154

RPD = 6.40

9 Silvex (2,4,5-TP)

1 10.080 10.082 -0.002 31547892H 0.0250 0.0169

2 10.191 10.194 -0.003 31324141H 0.0250 0.0181

RPD = 6.53

10 2,4,5-T

1 10.631 10.633 -0.002 31262577H 0.0250 0.0186

2 10.643 10.645 -0.002 29976534H 0.0250 0.0198

RPD = 6.20

11 Dinoseb

1 10.886 10.889 -0.003 11157936H 0.1000 0.0099

2 11.716 11.714 0.002 10255673H 0.1000 0.0104

RPD = 4.62

12 2,4-DB

1 11.015 11.017 -0.002 15295411H 0.1000 0.0707

2 11.074 11.075 -0.001 16001125H 0.1000 0.0762

RPD = 7.46

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000013.D

Injection Date: 13-Mar-2023 13:55:15 Instrument ID: CGC1 Operator ID:

Lims ID: LCS 180-428159/2-A Worklist Smp#: 11

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 11

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0313230000013.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.2

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0313230000013.D

la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

Recovery Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000013.D

Lims ID: LCS 180-428159/2-A

Client ID:

Sample Type: LCS

Inject. Date: 13-Mar-2023 13:55:15 ALS Bottle#: 11 Worklist Smp#: 11

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-011

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:02 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 14-Mar-2023 07:58:51

Surrogate Recovery, Detector: GC ECD1A

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 0.0500 0.0246 49.27

Surrogate Recovery, Detector: GC ECD2B

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 0.0500 0.0348 69.64

Lab Name: Job No.: 180-153025-1Eurofins Pittsburgh

SDG No.:

Client Sample ID: Lab Sample ID: LCS 180-428159/2-A

Matrix: 0313230000013.DLab File ID:

Date Collected:EPA 8151AAnalysis Method:

Sediment

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Extracted:

Date Analyzed:

Dilution Factor: 1

Extraction Method: 8151A 03/06/2023 00:45

03/13/2023 13:55

40.0(mL)

1(uL)

Sample wt/vol: 10.0(g)

% Moisture:

GC Column: ID: 0.53(mm)RTX-1701

N% Solids:

Cleanup Factor:

Analysis Batch No.: 428960 ug/KgUnits:

CAS NO. COMPOUND NAME RESULT Q MDLRL

20 1193-72-1 Silvex (2,4,5-TP) 72.2

%RECCAS NO. LIMITSQSURROGATE

70 48-12719719-28-9 2,4-Dichlorophenylacetic acid

Report Date: 14-Mar-2023 08:02:20 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000013.D

Lims ID: LCS 180-428159/2-A

Client ID:

Sample Type: LCS

Inject. Date: 13-Mar-2023 13:55:15 ALS Bottle#: 11 Worklist Smp#: 11

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-011

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:02 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 14-Mar-2023 07:58:51

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.171 2.173 -0.002 14841876H 0.1000 0.0348

2 2.323 2.365 -0.042 91269626H 0.1000 0.2432

RPD = 149.90

$ 2 2,4-Dichlorophenylacetic acid M

1 7.982 7.986 -0.004 11926175H 0.0500 0.0246

2 7.933 7.933 0.000 14039294H 0.0500 0.0348 M

RPD = 34.27

3 MCPP

1 8.200 8.202 -0.002 8913288H 10.0 6.90

2 8.355 8.357 -0.002 9008448H 10.0 5.98

RPD = 14.24

4 Dicamba

1 8.280 8.281 -0.001 44547713H 0.0500 0.0335

2 8.195 8.197 -0.002 40801612H 0.0500 0.0349

RPD = 4.01

5 MCPA

1 8.624 8.625 -0.001 15412493H 10.0 7.43

2 8.662 8.663 -0.001 15219914H 10.0 6.68

RPD = 10.63

6 Dichlorprop

1 8.902 8.905 -0.003 24018385H 0.1000 0.0657

2 9.024 9.025 -0.001…

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