J152564-2 Std_Tal_L4 Final Report (1).pdf

ANALYTICAL REPORT

PREPARED FOR

Attn: Carole Peven McCarthy

Battelle 141 Longwater Dr

Suite 202 Norwell MA 02061

Generated 4/26/2023 10:59 AM

JOB DESCRIPTION

Shrewsberry NJ

JOB NUMBER

180-152564-2

See page two for job notes and contact information.

Pittsburgh PA 15238 RIDC Park 301 Alpha Drive Eurofins Pittsburgh https://eol.et.eurofinsus.com/myEOL/ http://

Eurofins Pittsburgh

Eurofins Pittsburgh is a laboratory within Eurofins Environment Testing Northeast LLC, a company within Eurofins Environment Testing Group of Companies

Job Notes The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available.

Any exceptions to the NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory. This report is confidential and is intended for the sole use of Eurofins Environment Testing Northeast, LLC Pittsburgh and its client. All questions regarding this report should be directed to the Eurofins Environment Testing Northeast, LLC Pittsburgh Project Manager or designee who has signed this report.

PA Lab ID: 02-00416

The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Pittsburgh Project Manager.

Authorization

Generated

4/26/2023 10:59 AM

Authorized for release by Carrie L Gamber, Senior Project Manager Carrie.Gamber@et.eurofinsus.com 412 963-2428

Table of Contents Cover Title Page

Data Summaries

Definitions

Case Narrative

Detection Summary

Client Sample Results

Default Detection Limits

QC Sample Results

QC Association

Chronicle

Certification Summary

Method Summary

Sample Summary

Reagent Traceability

COAs

Inorganic Sample Data

Metals Data

Met Cover Page

Met Sample Data

Met QC Data Met ICV/CCV Met Blanks Met ICSA/ICSAB Met LCS/LCSD Met Serial Dilution

Met MDL

Table of Contents Met Linear Ranges

Met Preparation Log

Met Analysis Run Log

Met Internal Standards

Met Prep Data

Met Raw Data

General Chemistry Data

Gen Chem Cover Page

Gen Chem Sample Data

Gen Chem QC Data Gen Chem ICV/CCV Gen Chem Blanks Gen Chem LCS/LCSD

Gen Chem MDL

Gen Chem Analysis Run Log

Gen Chem Prep Data

Gen Chem Raw Data

Shipping and Receiving Documents

Client Chain of Custody

Sample Receipt Checklist

Definitions/Glossary Job ID: 180-152564-2Client: Battelle

Project/Site: Shrewsberry NJ

Qualifiers

Metals Qualifier Description

B Compound was found in the blank and sample.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

U Indicates the analyte was analyzed for but not detected.

General Chemistry Qualifier Description

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

Qualifier

U Indicates the analyte was analyzed for but not detected.

Glossary These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CFU Colony Forming Unit

CNF Contains No Free Liquid

DER Duplicate Error Ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL Detection Limit (DoD/DOE)

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision Level Concentration (Radiochemistry)

EDL Estimated Detection Limit (Dioxin)

LOD Limit of Detection (DoD/DOE)

LOQ Limit of Quantitation (DoD/DOE)

MCL EPA recommended "Maximum Contaminant Level"

MDA Minimum Detectable Activity (Radiochemistry)

MDC Minimum Detectable Concentration (Radiochemistry)

MDL Method Detection Limit

ML Minimum Level (Dioxin)

MPN Most Probable Number

MQL Method Quantitation Limit

NC Not Calculated

ND Not Detected at the reporting limit (or MDL or EDL if shown)

NEG Negative / Absent

POS Positive / Present

PQL Practical Quantitation Limit

PRES Presumptive

QC Quality Control

RER Relative Error Ratio (Radiochemistry)

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TNTC Too Numerous To Count

CASE NARRATIVE

Client: Battelle

Project: Shrewsberry NJ

Report Number: 180-152564-2

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

RECEIPT

The samples were received on 02/24/2023; the samples arrived in good condition, properly preserved and on ice. The temperatures of the 4 coolers at receipt time were 1.9º C, 2.1º C, 2.1º C and 2.6º C.

METALS

Nickel and Sodium were detected in method blank LB 180-427647/1-I at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

Iron was detected in method blank MB 180-430702/1-A at a level that was above the method detection limit but below the reporting limit.

The value should be considered an estimate, and has been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

CHROMIUM, HEXAVALENT

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

CHROMIUM, TRIVALENT

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

Detection Summary

Project/Site: Shrewsberry NJ

Client Sample ID: #20230098 AMENDED COMP 2 Lab Sample ID: 180-152564-2

Aluminum

RL

30 ug/L

MDL

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

SPLP East1800 EPA 6020B

Arsenic 1.0 ug/L0.28 SPLP East12.0 EPA 6020B

Barium 10 ug/L3.1 SPLP East117 EPA 6020B

Chromium 2.0 ug/L1.5 SPLP East16.0 EPA 6020B

Cobalt 0.50 ug/L0.26 SPLP East13.5 EPA 6020B

Copper 2.0 ug/L1.1 SPLP East179 EPA 6020B

Iron 50 ug/L28 SPLP East153 B EPA 6020B

Molybdenum 5.0 ug/L0.61 SPLP East1160 EPA 6020B

Sodium 500 ug/L180 SPLP East1240000 B EPA 6020B

Nickel 1.0 ug/L0.52 SPLP East120 B EPA 6020B

Selenium 5.0 ug/L0.74 SPLP East11.3 J EPA 6020B

Strontium 5.0 ug/L1.7 SPLP East12300 EPA 6020B

Vanadium 1.0 ug/L0.78 SPLP East19.1 EPA 6020B

☼Cr (III) 10 ug/L3.2 SPLP East16.0 J 7196A

Eurofins Pittsburgh

This Detection Summary does not include radiochemical test results.

Client Sample Results

Project/Site: Shrewsberry NJ

Method: SW846 EPA 6020B - Metals (ICP/MS) - SPLP East

Lab Sample ID: 180-152564-2Client Sample ID: #20230098 AMENDED COMP 2 Matrix: SedimentDate Collected: 02/20/23 09:46

Date Received: 02/24/23 09:49

RL MDL

800 30 16 ug/L 03/29/23 10:53 04/25/23 00:36 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Aluminum

1.0 0.28 ug/L 03/29/23 10:53 04/25/23 00:36 12.0Arsenic

10 3.1 ug/L 03/29/23 10:53 04/25/23 00:36 117Barium

1.0 0.27 ug/L 03/29/23 10:53 04/25/23 00:36 11.0 UBeryllium

1.0 0.22 ug/L 03/29/23 10:53 04/25/23 00:36 11.0 UCadmium

2.0 1.5 ug/L 03/29/23 10:53 04/25/23 00:36 16.0Chromium

0.50 0.26 ug/L 03/29/23 10:53 04/25/23 00:36 13.5Cobalt

2.0 1.1 ug/L 03/29/23 10:53 04/25/23 00:36 179Copper

50 28 ug/L 03/29/23 10:53 04/25/23 00:36 153 BIron

1.0 0.22 ug/L 03/29/23 10:53 04/25/23 00:36 11.0 USilver

5.0 1.3 ug/L 03/29/23 10:53 04/25/23 00:36 15.0 UManganese

5.0 0.61 ug/L 03/29/23 10:53 04/25/23 00:36 1160Molybdenum

500 180 ug/L 03/29/23 10:53 04/25/23 00:36 1240000 BSodium

1.0 0.52 ug/L 03/29/23 10:53 04/25/23 00:36 120 BNickel

1.0 0.38 ug/L 03/29/23 10:53 04/25/23 00:36 11.0 ULead

2.0 0.97 ug/L 03/29/23 10:53 04/25/23 00:36 12.0 UAntimony

5.0 0.74 ug/L 03/29/23 10:53 04/25/23 00:36 11.3 JSelenium

5.0 1.7 ug/L 03/29/23 10:53 04/25/23 00:36 12300Strontium

1.0 0.47 ug/L 03/29/23 10:53 04/25/23 00:36 11.0 UThallium

1.0 0.78 ug/L 03/29/23 10:53 04/25/23 00:36 19.1Vanadium

15 6.0 ug/L 03/29/23 10:53 04/25/23 00:36 115 UZinc

Project/Site: Shrewsberry NJ

General Chemistry - SPLP

Lab Sample ID: 180-152564-2Client Sample ID: #20230098 AMENDED COMP 2 Matrix: SedimentDate Collected: 02/20/23 09:46

Date Received: 02/24/23 09:49

RL MDL

0.010 U 0.010 0.0060 mg/L 03/02/23 09:00 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Cr (VI) (SW846 EPA 7196A)

Project/Site: Shrewsberry NJ

General Chemistry - SPLP East

Lab Sample ID: 180-152564-2Client Sample ID: #20230098 AMENDED COMP 2 Matrix: SedimentDate Collected: 02/20/23 09:46

Date Received: 02/24/23 09:49

RL MDL

6.0 J 10 3.2 ug/L ☼ 04/26/23 06:21 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Cr (III) (SW846 7196A)

Default Detection Limits Client: Battelle Job ID: 180-152564-2 Project/Site: Shrewsberry NJ

Method: EPA 6020B - Metals (ICP/MS) - SPLP East Prep: 3010A Leach: EPA 1312

30Aluminum ug/L

Analyte UnitsMDLRL

2.0Antimony ug/L0.97

1.0Arsenic ug/L0.28

10Barium ug/L3.1

1.0Beryllium ug/L0.27

1.0Cadmium ug/L0.22

2.0Chromium ug/L1.5

0.50Cobalt ug/L0.26

2.0Copper ug/L1.1

50Iron ug/L28

1.0Lead ug/L0.38

5.0Manganese ug/L1.3

5.0Molybdenum ug/L0.61

1.0Nickel ug/L0.52

5.0Selenium ug/L0.74

1.0Silver ug/L0.22

500Sodium ug/L180

5.0Strontium ug/L1.7

1.0Thallium ug/L0.47

1.0Vanadium ug/L0.78

15Zinc ug/L6.0

General Chemistry - SPLP Leach: 1312

0.010Cr (VI) mg/L

Analyte UnitsMDLRL

0.0060

General Chemistry - SPLP East

10Cr (III) ug/L

Analyte UnitsMDLRL

3.2

QC Sample Results

Project/Site: Shrewsberry NJ

Method: EPA 6020B - Metals (ICP/MS)

Client Sample ID: Method BlankLab Sample ID: MB 180-430702/1-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 433286 Prep Batch: 430702

RL MDL

Aluminum 30 U 30 16 ug/L 03/29/23 10:53 04/25/23 00:14 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

1.0 U 0.281.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Arsenic

10 U 3.110 ug/L 03/29/23 10:53 04/25/23 00:14 1Barium

1.0 U 0.271.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Beryllium

1.0 U 0.221.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Cadmium

2.0 U 1.52.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Chromium

0.50 U 0.260.50 ug/L 03/29/23 10:53 04/25/23 00:14 1Cobalt

2.0 U 1.12.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Copper

49.6 J 2850 ug/L 03/29/23 10:53 04/25/23 00:14 1Iron

1.0 U 0.221.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Silver

5.0 U 1.35.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Manganese

5.0 U 0.615.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Molybdenum

500 U 180500 ug/L 03/29/23 10:53 04/25/23 00:14 1Sodium

1.0 U 0.521.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Nickel

1.0 U 0.381.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Lead

2.0 U 0.972.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Antimony

5.0 U 0.745.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Selenium

5.0 U 1.75.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Strontium

1.0 U 0.471.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Thallium

1.0 U 0.781.0 ug/L 03/29/23 10:53 04/25/23 00:14 1Vanadium

15 U 6.015 ug/L 03/29/23 10:53 04/25/23 00:14 1Zinc

Client Sample ID: Lab Control SampleLab Sample ID: LCS 180-430702/2-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 433286 Prep Batch: 430702

Aluminum 5000 4590 ug/L 92 80 - 120

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec

Limits

Arsenic 1000 925 ug/L 93 80 - 120

Barium 1000 959 ug/L 96 80 - 120

Beryllium 500 403 ug/L 81 80 - 120

Cadmium 500 481 ug/L 96 80 - 120

Chromium 500 499 ug/L 100 80 - 120

Cobalt 500 475 ug/L 95 80 - 120

Copper 500 485 ug/L 97 80 - 120

Iron 5000 4550 ug/L 91 80 - 120

Silver 250 238 ug/L 95 80 - 120

Manganese 500 484 ug/L 97 80 - 120

Molybdenum 500 522 ug/L 104 80 - 120

Sodium 25000 26000 ug/L 104 80 - 120

Nickel 500 487 ug/L 97 80 - 120

Lead 500 490 ug/L 98 80 - 120

Antimony 250 261 ug/L 104 80 - 120

Selenium 1000 901 ug/L 90 80 - 120

Strontium 500 479 ug/L 96 80 - 120

Thallium 1000 981 ug/L 98 80 - 120

Vanadium 500 505 ug/L 101 80 - 120

Zinc 250 233 ug/L 93 80 - 120

Project/Site: Shrewsberry NJ

Method: EPA 6020B - Metals (ICP/MS) (Continued)

Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 180-430702/3-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 433286 Prep Batch: 430702

Aluminum 5000 4280 ug/L 86 80 - 120 7 20

Analyte

LCSD LCSD

DUnitResult Qualifier %Rec

Spike

Added

%Rec

Limits LimitRPD

RPD

Arsenic 1000 876 ug/L 88 80 - 120 6 20

Barium 1000 897 ug/L 90 80 - 120 7 20

Beryllium 500 407 ug/L 81 80 - 120 1 20

Cadmium 500 455 ug/L 91 80 - 120 6 20

Chromium 500 463 ug/L 93 80 - 120 7 20

Cobalt 500 446 ug/L 89 80 - 120 6 20

Copper 500 451 ug/L 90 80 - 120 7 20

Iron 5000 4160 ug/L 83 80 - 120 9 20

Silver 250 228 ug/L 91 80 - 120 4 20

Manganese 500 452 ug/L 90 80 - 120 7 20

Molybdenum 500 472 ug/L 94 80 - 120 10 20

Sodium 25000 24200 ug/L 97 80 - 120 7 20

Nickel 500 452 ug/L 90 80 - 120 7 20

Lead 500 465 ug/L 93 80 - 120 5 20

Antimony 250 238 ug/L 95 80 - 120 9 20

Selenium 1000 842 ug/L 84 80 - 120 7 20

Strontium 500 449 ug/L 90 80 - 120 6 20

Thallium 1000 945 ug/L 95 80 - 120 4 20

Vanadium 500 469 ug/L 94 80 - 120 7 20

Zinc 250 222 ug/L 89 80 - 120 5 20

Client Sample ID: Method BlankLab Sample ID: LB 180-427647/1-I Matrix: Sediment Prep Type: SPLP East Analysis Batch: 433286 Prep Batch: 430702

RL MDL

Aluminum 30 U 30 16 ug/L 03/29/23 10:53 04/25/23 00:25 1

LB LB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

1.0 U 0.281.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Arsenic

10 U 3.110 ug/L 03/29/23 10:53 04/25/23 00:25 1Barium

1.0 U 0.271.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Beryllium

1.0 U 0.221.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Cadmium

2.0 U 1.52.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Chromium

0.50 U 0.260.50 ug/L 03/29/23 10:53 04/25/23 00:25 1Cobalt

2.0 U 1.12.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Copper

50 U 2850 ug/L 03/29/23 10:53 04/25/23 00:25 1Iron

1.0 U 0.221.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Silver

5.0 U 1.35.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Manganese

5.0 U 0.615.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Molybdenum

344 J 180500 ug/L 03/29/23 10:53 04/25/23 00:25 1Sodium

0.650 J 0.521.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Nickel

1.0 U 0.381.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Lead

2.0 U 0.972.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Antimony

5.0 U 0.745.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Selenium

5.0 U 1.75.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Strontium

1.0 U 0.471.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Thallium

1.0 U 0.781.0 ug/L 03/29/23 10:53 04/25/23 00:25 1Vanadium

15 U 6.015 ug/L 03/29/23 10:53 04/25/23 00:25 1Zinc

Project/Site: Shrewsberry NJ

Method: EPA 7196A - Chromium, Hexavalent

Client Sample ID: Method BlankLab Sample ID: MB 180-428120/3 Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428120

RL MDL

Cr (VI) 0.010 U 0.010 0.0060 mg/L 03/02/23 08:52 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

Client Sample ID: Lab Control SampleLab Sample ID: LCS 180-428120/4 Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428120

Cr (VI) 0.500 0.511 mg/L 102 85 - 115

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec

Limits

Client Sample ID: Method BlankLab Sample ID: LB 180-427901/1-A Matrix: Sediment Prep Type: SPLP Analysis Batch: 428120

RL MDL

Cr (VI) 0.010 U 0.010 0.0060 mg/L 03/02/23 08:59 1

LB LB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

QC Association Summary

Project/Site: Shrewsberry NJ

Metals

Leach Batch: 427647

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment EPA 1312180-152564-2 #20230098 AMENDED COMP 2 SPLP East

Sediment EPA 1312LB 180-427647/1-I Method Blank SPLP East

Prep Batch: 430702

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 3010A 427647180-152564-2 #20230098 AMENDED COMP 2 SPLP East

Sediment 3010A 427647LB 180-427647/1-I Method Blank SPLP East

Sediment 3010AMB 180-430702/1-A Method Blank Total/NA

Sediment 3010ALCS 180-430702/2-A Lab Control Sample Total/NA

Sediment 3010ALCSD 180-430702/3-A Lab Control Sample Dup Total/NA

Analysis Batch: 433286

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment EPA 6020B 430702180-152564-2 #20230098 AMENDED COMP 2 SPLP East

Sediment EPA 6020B 430702LB 180-427647/1-I Method Blank SPLP East

Sediment EPA 6020B 430702MB 180-430702/1-A Method Blank Total/NA

Sediment EPA 6020B 430702LCS 180-430702/2-A Lab Control Sample Total/NA

Sediment EPA 6020B 430702LCSD 180-430702/3-A Lab Control Sample Dup Total/NA

General Chemistry

Leach Batch: 427901

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 1312180-152564-2 #20230098 AMENDED COMP 2 SPLP

Sediment 1312LB 180-427901/1-A Method Blank SPLP

Analysis Batch: 428120

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment EPA 7196A 427901180-152564-2 #20230098 AMENDED COMP 2 SPLP

Sediment EPA 7196A 427901LB 180-427901/1-A Method Blank SPLP

Sediment EPA 7196AMB 180-428120/3 Method Blank Total/NA

Sediment EPA 7196ALCS 180-428120/4 Lab Control Sample Total/NA

Analysis Batch: 430518

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 7196A180-152564-2 #20230098 AMENDED COMP 2 SPLP East

Lab Chronicle

Project/Site: Shrewsberry NJ

Client Sample ID: #20230098 AMENDED COMP 2 Lab Sample ID: 180-152564-2 Matrix: SedimentDate Collected: 02/20/23 09:46

Date Received: 02/24/23 09:49

Leach EPA 1312 MJC02/28/23 16:30 EET PIT427647

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

SPLP East 100.36 g 2000 mL

Prep 3010A 430702 03/29/23 10:53 RJR EET PITSPLP East 25 mL 25 mL

Analysis EPA 6020B 1 433286 04/25/23 00:36 DSH EET PITSPLP East

DORYInstrument ID:

Analysis 7196A 1 430518 04/26/23 06:21 RJR EET PITSPLP East

NOEQUIPInstrument ID:

Leach 1312 427901 02/28/23 18:30 MJC EET PITSPLP 1.0 g 750 mL

Analysis EPA 7196A 1 428120 03/02/23 09:00 SNR EET PITSPLP 4 mL 4 mL

RAPID-TInstrument ID:

¹ Completion dates and times are reported or not reported per method requirements or individual lab discretion.

Laboratory References:

EET PIT = Eurofins Pittsburgh, 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238, TEL (412)963-7058

Analyst References:

Lab: EET PIT

Batch Type: Leach

MJC = Mathew Catanzariti

Batch Type: Prep

RJR = Ron Rosenbaum

Batch Type: Analysis

DSH = David Heakin

RJR = Ron Rosenbaum

SNR = Sabra Richart

Accreditation/Certification Summary

Project/Site: Shrewsberry NJ

Laboratory: Eurofins Pittsburgh Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.

Authority Program Identification Number Expiration Date

New Jersey NELAP PA005 06-30-23

The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte

7196A Sediment Cr (III)

New York NELAP 11182 04-01-24

The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte

7196A Sediment Cr (III)

Method Summary

Project/Site: Shrewsberry NJ

Method Method Description LaboratoryProtocol

SW846EPA 6020B Metals (ICP/MS) EET PIT

SW8467196A Chromium, Trivalent (Colorimetric) EET PIT

SW846EPA 7196A Chromium, Hexavalent EET PIT

SW8461312 SPLP Extraction EET PIT

SW8463010A Preparation, Total Metals EET PIT

SW846EPA 1312 SPLP Extraction EET PIT

Protocol References:

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

EET PIT = Eurofins Pittsburgh, 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238, TEL (412)963-7058

Sample Summary

Project/Site: Shrewsberry NJ

Lab Sample ID Client Sample ID Matrix Collected Received

180-152564-2 #20230098 AMENDED COMP 2 Sediment 02/20/23 09:46 02/24/23 09:49

REAGENT TRACEABILITY SUMMARY

Lab Name:

SDG No.:

Job No.: 180-152564-2Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

03/07/24 (Purchased Reagent) Aluminum 1000 mg/LInorganic Ventures, Lot U2-MEB730243EUROPITTSP-1_00002 Arsenic 200 mg/L B 250 mg/L Barium 200 mg/L Beryllium 100 mg/L Ca 5000 mg/L Cadmium 100 mg/L Chromium 100 mg/L Cobalt 100 mg/L Copper 100 mg/L Iron 1000 mg/L K 5000 mg/L Lead 100 mg/L Li 100 mg/L Manganese 100 mg/L Mg 5000 mg/L Nickel 100 mg/L P 100 mg/L Selenium 200 mg/L Silver 50 mg/L Sodium 5000 mg/L Strontium 100 mg/L Thallium 200 mg/L Vanadium 100 mg/L Zinc 50 mg/L

03/07/24 (Purchased Reagent) Antimony 50 ug/mLInorganic Ventures, Lot U2-MEB730242EUROPITTSP-2_00001 Molybdenum 100 ug/mL Si 200 ug/mL SiO2 428 ug/mL Sn 200 ug/mL Ti 100 ug/mL

03/07/24 (Purchased Reagent) Th 5 ug/mLInorganic Ventures, Lot U2-MEB730241EUROPITTSP-3_00001 U 5 ug/mL

TA-CAL1_00008 Antimony 0.2 ppm1000 mL 2 mL06/28/23 04/05/23MCCV2 uthp_00027 2% Nitric Acid, Lot 5125799

Arsenic 0.2 ppm Barium 0.2 ppm Beryllium 0.2 ppm Cadmium 0.2 ppm Chromium 0.2 ppm Cobalt 0.2 ppm Copper 0.2 ppm Lead 0.2 ppm Manganese 0.2 ppm Molybdenum 0.2 ppm Nickel 0.2 ppm Selenium 0.2 ppm

SDG No.:

Job No.: 180-152564-2Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

Strontium 0.2 ppm Thallium 0.2 ppm Vanadium 0.2 ppm Aluminum 50 ppmTA-CAL2_00010 25 mL Iron 50 ppm Sodium 50 ppm Silver 0.1 ppmTA-CAL3 REV2_00003 2 mL Zinc 0.1 ppm

01/29/24 (Purchased Reagent) Antimony 100 ppmCPI International, Lot 1208138-1.TA-CAL1_00008 Arsenic 100 ppm Barium 100 ppm Beryllium 100 ppm Cadmium 100 ppm Chromium 100 ppm Cobalt 100 ppm Copper 100 ppm Lead 100 ppm Manganese 100 ppm Molybdenum 100 ppm Nickel 100 ppm Selenium 100 ppm Strontium 100 ppm Thallium 100 ppm Vanadium 100 ppm

11/30/23 (Purchased Reagent) Aluminum 2000 ppmCPI International, Lot 1208136-1.TA-CAL2_00010 Iron 2000 ppm Sodium 2000 ppm

12/31/23 (Purchased Reagent) Silver 50 mg/LCPI International, Lot 10103959-3.TA-CAL3 REV2_00003 Zinc 50 mg/L

MUICPMS-CRI-1_00003 Aluminum 0.03 ppm500 mL 2 mL06/23/23 04/05/23MCRIX A_uthp_00032 2% Nitric Acid, Lot 5125799

Arsenic 0.001 ppm Barium 0.01 ppm Beryllium 0.001 ppm Cadmium 0.001 ppm Chromium 0.002 ppm Cobalt 0.0005 ppm Copper 0.002 ppm Iron 0.05 ppm Lead 0.001 ppm Manganese 0.005 ppm Nickel 0.001 ppm Selenium 0.005 ppm Silver 0.001 ppm Sodium 0.5 ppm Strontium 0.005 ppm Thallium 0.001 ppm Vanadium 0.001 ppm

SDG No.:

Job No.: 180-152564-2Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

Zinc 0.005 ppm Antimony 0.002 ppmMUICPMS-CRI-2_00004 2 mL Molybdenum 0.005 ppm

04/30/24 (Purchased Reagent) Aluminum 7.5 ppmCPI INTERNATIONAL, Lot 1299722.MUICPMS-CRI-1_00003 Arsenic 0.25 ppm Barium 2.5 ppm Beryllium 0.25 ppm Cadmium 0.25 ppm Chromium 0.5 ppm Cobalt 0.125 ppm Copper 0.5 ppm Iron 12.5 ppm Lead 0.25 ppm Manganese 1.25 ppm Nickel 0.25 ppm Selenium 1.25 ppm Silver 0.25 ppm Sodium 125 ppm Strontium 1.25 ppm Thallium 0.25 ppm Vanadium 0.25 ppm Zinc 1.25 ppm

04/30/24 (Purchased Reagent) Antimony 0.5 ppmCPI INT., Lot 1299723.MUICPMS-CRI-2_00004 Molybdenum 1.25 ppm

M6020ICSA-MIX_00010 Aluminum 100 ppm250 mL 25 mL06/28/23 04/04/23MICSAB A_uthp_00042 2% Nitric Acid, Lot 5125799

Ca 100 ppm Iron 100 ppm K 100 ppm Mg 100 ppm Molybdenum 2 ppm P 100 ppm Sodium 100 ppm Ti 2 ppm Arsenic 0.02 ppmMICSAB-1_00003 2.5 mL Cadmium 0.02 ppm Chromium 0.02 ppm Cobalt 0.02 ppm Copper 0.02 ppm Manganese 0.022 ppm Nickel 0.02 ppm Silver 0.02 ppm Zinc 0.022 ppm Antimony 0.022 ppmMICSAB-2_00015 0.5 mL B 0.05 ppm Barium 0.028 ppm Beryllium 0.02 ppm Lead 0.02 ppm

SDG No.:

Job No.: 180-152564-2Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

Li 0.02 ppm Selenium 0.05 ppm Si 0.5 ppm Sn 0.1 ppm Strontium 0.02 ppm Thallium 0.02 ppm U 0.02 ppm Vanadium 0.02 ppm

MICSAB-3_00002 0.5 mL Th 0.02 ppm 04/30/24 (Purchased Reagent) Aluminum 1000 ppmCPI INT., Lot 1267033-1.M6020ICSA-MIX_00010

Ca 1000 ppm Iron 1000 ppm K 1000 ppm Mg 1000 ppm Molybdenum 20 ppm P 1000 ppm Sodium 1000 ppm Ti 20 ppm

01/29/24 (Purchased Reagent) Arsenic 2 ug/mLCPI, Lot 1275484.MICSAB-1_00003 Cadmium 2 ug/mL Chromium 2 ug/mL Cobalt 2 ug/mL Copper 2 ug/mL Manganese 2.2 ug/mL Nickel 2 ug/mL Silver 2 ug/mL Zinc 2.2 ug/mL

04/30/24 (Purchased Reagent) Antimony 11 ppmCPI, Lot 1299720.MICSAB-2_00015 B 25 ppm Barium 14 ppm Beryllium 10 ppm Lead 10 ppm Li 10 ppm Selenium 25 ppm Si 250 ppm Sn 50 ppm Strontium 10 ppm Thallium 10 ppm U 10 ppm Vanadium 10 ppm

09/30/23 (Purchased Reagent) Th 10 ppmCPI, Lot 12133297.MICSAB-3_00002

M6020ICSA-MIX_00010 Aluminum 100 ppm250 mL 25 mL07/05/23 04/05/23MICSAX_00227 2% Nitric Acid, Lot 5125799

Ca 100 ppm Iron 100 ppm K 100 ppm Mg 100 ppm Molybdenum 2 ppm

SDG No.:

Job No.: 180-152564-2Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

P 100 ppm Sodium 100 ppm Ti 2 ppm

04/30/24 (Purchased Reagent) Aluminum 1000 ppmCPI INT., Lot 1267033-1.M6020ICSA-MIX_00010 Ca 1000 ppm Iron 1000 ppm K 1000 ppm Mg 1000 ppm Molybdenum 20 ppm P 1000 ppm Sodium 1000 ppm Ti 20 ppm

MICPMSICV_00031 Aluminum 0.4 mg/L250 mg/L 10 mg/L06/28/23 04/05/23MICVX A_uthp_00023 2% Nitric Acid, Lot 5125799

Antimony 0.08 mg/L Arsenic 0.08 mg/L Barium 0.08 mg/L Beryllium 0.08 mg/L Cadmium 0.08 mg/L Chromium 0.08 mg/L Cobalt 0.08 mg/L Copper 0.08 mg/L Iron 20 mg/L Lead 0.08 mg/L Manganese 0.4 mg/L Molybdenum 0.08 mg/L Nickel 0.08 mg/L Selenium 0.08 mg/L Silver 0.08 mg/L Sodium 40 mg/L Strontium 0.08 mg/L Thallium 0.08 mg/L Vanadium 0.08 mg/L Zinc 0.08 mg/L

11/30/23 (Purchased Reagent) Aluminum 10 ppmCPI International, Lot 220504.MICPMSICV_00031 Antimony 2 ppm Arsenic 2 ppm Barium 2 ppm Beryllium 2 ppm Cadmium 2 ppm Chromium 2 ppm Cobalt 2 ppm Copper 2 ppm Iron 500 ppm Lead 2 ppm Manganese 10 ppm Molybdenum 2 ppm Nickel 2 ppm

SDG No.:

Job No.: 180-152564-2Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

Selenium 2 ppm Silver 2 ppm Sodium 1000 ppm Strontium 2 ppm Thallium 2 ppm Vanadium 2 ppm Zinc 2 ppm

TA-CAL2_00010 Aluminum 100 ppm250 mL 12.5 mL06/28/23 04/05/23MSTD2X_uthp_00023 2% Nitric Acid, Lot 5125796

Iron 100 ppm Sodium 100 ppm Silver 0.2 ppmTA-CAL3 REV2_00003 1 mL Zinc 0.2 ppm

11/30/23 (Purchased Reagent) Aluminum 2000 ppmCPI International, Lot 1208136-1.TA-CAL2_00010 Iron 2000 ppm Sodium 2000 ppm

12/31/23 (Purchased Reagent) Silver 50 mg/LCPI International, Lot 10103959-3.TA-CAL3 REV2_00003 Zinc 50 mg/L

TA-CAL1_00010 Antimony 0.4 ppm250 mL 1 mL07/05/23 04/05/23MSTD3X A New_00062 2% Nitric Acid, Lot 5125799

Arsenic 0.4 ppm Barium 0.4 ppm Beryllium 0.4 ppm Cadmium 0.4 ppm Chromium 0.4 ppm Cobalt 0.4 ppm Copper 0.4 ppm Lead 0.4 ppm Manganese 0.4 ppm Molybdenum 0.4 ppm Nickel 0.4 ppm Selenium 0.4 ppm Strontium 0.4 ppm Thallium 0.4 ppm Vanadium 0.4 ppm

07/29/24 (Purchased Reagent) Antimony 100 ppmCPI International, Lot 1321095-1.TA-CAL1_00010 Arsenic 100 ppm Barium 100 ppm Beryllium 100 ppm Cadmium 100 ppm Chromium 100 ppm Cobalt 100 ppm Copper 100 ppm Lead 100 ppm Manganese 100 ppm Molybdenum 100 ppm Nickel 100 ppm

SDG No.:

Job No.: 180-152564-2Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

Selenium 100 ppm Strontium 100 ppm Thallium 100 ppm Vanadium 100 ppm

03/04/23 02/25/23 50 mL WCR+6 1000 P_00028 0.025 mL Cr (VI) 0.499976 mg/LWCRTCR6CCV_00061 05/01/23 11/01/22 250 mL WK2CrO7P_00018 0.7072 g Cr (VI) 999.953 mg/L.WCR+6 1000 P_00028 DI Water, Lot NA 10/31/23 (Purchased Reagent) Cr (VI) 0.35349 g/gSTREM CHEMICALS, Lot 35854200..WK2CrO7P_00018

03/04/23 02/25/23 50 mL WCr1000S_00012 0.025 mL Cr (VI) 0.5 mg/LWCRTCR6ICV_00066 0.25 N H2SO4, Lot 4791891

02/20/24 (Purchased Reagent) Cr (VI) 1000 ppmLabChem, Inc., Lot M032-21.WCr1000S_00012

Reagent

EUROPITTSP-1_00002

1.0 ACCREDITATION / REGISTRATION

INORGANIC VENTURES is accredited to ISO 17034, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General

Requirements for the Competence of Testing and Calibration Laboratories".

Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate

Number QSR-1034).

Testing Laboratory

Certificate 883.01

Reference Material Producer

Certificate 883.02

2.0 PRODUCT DESCRIPTION

Product Code: Multi Analyte Custom Grade Solution

Catalog Number: EUROPITTSP-1

Lot Number: U2-MEB730243

Matrix: 5% (v/v) HNO3

5 000 µg/mL ea:

Calcium, Potassium, Sodium, Magnesium, 1 000 µg/mL ea:

Iron, Aluminum, 250 µg/mL ea:

Boron, 200 µg/mL ea:

Barium, Arsenic, Selenium, Thallium, 100 µg/mL ea:

Vanadium, Strontium, Manganese, Beryllium, Cadmium, Cobalt, Chromium, Copper, Lithium, Nickel, Phosphorus, Lead, 50 µg/mL ea:

Silver, Zinc

Value / Analyte(s):

3.0 CERTIFIED VALUES AND UNCERTAINTIES

ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE

Aluminum, Al 1 000 ± 4 µg/mL Arsenic, As 200.0 ± 1.6 µg/mL

Barium, Ba 199.9 ± 0.9 µg/mL Beryllium, Be 100.0 ± 0.6 µg/mL

Boron, B 250.0 ± 1.5 µg/mL Cadmium, Cd 100.0 ± 0.4 µg/mL

Calcium, Ca 5 000 ± 22 µg/mL Chromium, Cr 100.0 ± 0.6 µg/mL

Cobalt, Co 100.2 ± 0.5 µg/mL Copper, Cu 100.1 ± 0.4 µg/mL

Iron, Fe 1 000 ± 4 µg/mL Lead, Pb 100.0 ± 0.6 µg/mL

Lithium, Li 100.2 ± 0.4 µg/mL Magnesium, Mg 5 000 ± 23 µg/mL

Manganese, Mn 100.0 ± 0.5 µg/mL Nickel, Ni 100.0 ± 0.5 µg/mL

Phosphorus, P 100.1 ± 0.5 µg/mL Potassium, K 5 000 ± 22 µg/mL

Selenium, Se 200.0 ± 1.3 µg/mL Silver, Ag 50.00 ± 0.22 µg/mL

Sodium, Na 5 000 ± 22 µg/mL Strontium, Sr 100.0 ± 0.4 µg/mL

Thallium, Tl 200.1 ± 1.4 µg/mL Vanadium, V 100.0 ± 0.5 µg/mL

Zinc, Zn 49.85 ± 0.23 µg/mL

Density: 1.101 g/mL (measured at 20 ± 4 ºC)

Assay Information:

METHOD NIST SRM# SRM LOT#ANALYTE

3151ICP Assay 160729Ag

999cVolhard 999cAg

3101aICP Assay 140903Al

928EDTA 928Al

3103aICP Assay 100818As

3107ICP Assay 190605B

3104aICP Assay 140909Ba

Gravimetric See Sec. 4.2Ba

3105aICP Assay 090514Be

3109aICP Assay 130213Ca

928EDTA 928Ca

3108ICP Assay 130116Cd

928EDTA 928Cd

3113ICP Assay 190630Co

928EDTA 928Co

3112aICP Assay 170630Cr

3114ICP Assay 121207Cu

928EDTA 928Cu

3126aICP Assay 140812Fe

928EDTA 928Fe

3141aICP Assay 140813K

Gravimetric See Sec. 4.2K

3129aICP Assay 100714Li

Gravimetric See Sec. 4.2Li

3131aICP Assay 140110Mg

928EDTA 928Mg

3132ICP Assay 050429Mn

928EDTA 928Mn

Traceable to 3152AICP Assay S2-NA700842Na

Gravimetric See Sec. 4.2Na

3136ICP Assay 120619Ni

928EDTA 928Ni

3139aICP Assay 060717P

84LAcidimetric 84LP

3149ICP Assay 100901Se

928EDTA 928Sr

Traceable to 3153aICP Assay K2-SR650985Sr

3158ICP Assay 151215Tl

3165ICP Assay 160906V

928EDTA 928V

3168aICP Assay 120629Zn

928EDTA 928Zn

The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.

4.0 TRACEABILITY TO NIST

- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is specified.

4.1 Thermometer Calibration

- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights used for testing are annually compared to master weights and are traceable to NIST.

4.2 Balance Calibration

- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration laboratory.

4.3 Glassware Calibration

- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality control of CRM/RMs.

TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (µg/mL)5.0

N/A

INTENDED USE6.0

6.1 This standard is intended for the calibration of analytical instruments and validation of analytical methods as appropriate. This CRM may be used in connection with EPA Methods 6010, 6020 (all versions), Standard

Methods 3120 B and USP <232> / ICH Q3D.

6.2 For products attaining traceability through Inorganic Ventures’ Primary Certified Reference Materials (PCRM™) see the Limited License to Use PCRM™ in the Inorganic Ventures Terms and Conditions of Sale, https://www.inorganicventures.com/terms-and-conditions-sale. The Terms and Conditions contain information on the use of materials traceable to PCRM™ certified reference materials. This Limited License agreement is especially pertinent for laboratories accredited under ISO:17034.

INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL7.0

7.1 Storage and Handling Recommendations

www.inorganicventures.com/TCT- For more information, visit

- Store between approximately 4° - 30° C while in sealed TCT bag.

- While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is the responsibility of the user to account for this effect. When the bottle is weighed both before and after being placed in storage, the mass difference observed will be a measure of transpiration mass loss.

- After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4° - 24° C to minimize the effects of transpiration. Use at 20° ± 4° C to minimize volumetric dilution error when using the reported density. Do not pipette from the container. Do not return removed aliquots to container.

HAZARDOUS INFORMATION 8.0

- Please refer to the Safety Data Sheet for information regarding this CRM/RM.

HOMOGENEITY9.0

- This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous.

Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure homogeneity.

QUALITY STANDARD DOCUMENTATION10.0

10.1 ISO 9001 Quality Management System Registration

- QSR Certificate Number QSR-1034

- Chemical Testing - Accredited / A2LA Certificate Number 883.01

10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories"

- Reference Material Producer - Accredited / A2LA Certificate Number 883.02

10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers"

Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: 800.669.6799; 540.585.3030, Fax: 540.585.3012; inorganicventures.com;

info@inorganicventures.com

CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY11.0

11.1 Certification Issue Date

11.2 Lot Expiration Date

- The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1 are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified.

February 28, 2023

- The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by transpiration (loss of water from the solution) and infrequently by chemical stability.

- February 28, 2028

- The date after which this CRM/RM should not be used.

11.3 Period of Validity

- This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1.

- Sealed TCT Bag Open Date: __________________________

12.0 NAMES AND SIGNATURES OF CERTIFYING OFFICERS

Certificate Approved By:

Paul Gaines

Chairman / Senior Technical Director

Certifying Officer:

Thomas Kozikowski

Manager, Quality Control

EUROPITTSP-2_00001

the Competence of Reference Material Producers" and ISO/IEC 17025, "General

Requirements for the Competence of Testing and Calibration Laboratories".

Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate

Number QSR-1034).

Testing Laboratory

Certificate 883.01

Reference Material Producer

Certificate 883.02

2.0 PRODUCT DESCRIPTION

Product Code: Multi Analyte Custom Grade Solution

Catalog Number: EUROPITTSP-2

Lot Number: U2-MEB730242

Matrix: 5% (v/v) HNO3

tr. HF

200 µg/mL ea:

Silicon, Tin, 100 µg/mL ea:

Titanium, Molybdenum, 50 µg/mL ea:

Antimony

Value / Analyte(s):

3.0 CERTIFIED VALUES AND UNCERTAINTIES

ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE

Antimony, Sb 50.00 ± 0.40 µg/mL Molybdenum, Mo 100.0 ± 0.4 µg/mL

Silicon, Si 200.0 ± 1.3 µg/mL Tin, Sn 200.0 ± 1.0 µg/mL

Titanium, Ti 100.0 ± 0.6 µg/mL

Density: 1.025 g/mL (measured at 20 ± 4 ºC)

Assay Information:

METHOD NIST SRM# SRM LOT#ANALYTE

3134ICP Assay 130418Mo

Calculated See Sec. 4.2Mo

3102aICP Assay 140911Sb

Traceable to 3150ICP Assay S2-SI702546Si

3161aICP Assay 140917Sn

Calculated See Sec. 4.2Sn

3162aICP Assay 130925Ti

Calculated See Sec. 4.2Ti

The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.

4.0 TRACEABILITY TO NIST

- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is specified.

4.1 Thermometer Calibration

- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights used for testing are annually compared to master weights and are traceable to NIST.

4.2 Balance Calibration

- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration laboratory.

4.3 Glassware Calibration

- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality control of CRM/RMs.

TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (µg/mL)5.0

N/A

INTENDED USE6.0

6.1 This standard is intended for the calibration of analytical instruments and validation of analytical methods as appropriate. This CRM may be used in connection with EPA Methods 6010, 6020 (all versions), Standard

Methods 3120 B and USP <232> / ICH Q3D.

6.2 For products attaining traceability through Inorganic Ventures’ Primary Certified Reference Materials (PCRM™) see the Limited License to Use PCRM™ in the Inorganic Ventures Terms and Conditions of Sale, https://www.inorganicventures.com/terms-and-conditions-sale. The Terms and Conditions contain information on the use of materials traceable to PCRM™ certified reference materials. This Limited License agreement is especially pertinent for laboratories accredited under ISO:17034.

INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL7.0

7.1 Storage and Handling Recommendations

www.inorganicventures.com/TCT- For more information, visit

- Store between approximately 4° - 30° C while in sealed TCT bag.

- While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is the responsibility of the user to account for this effect. When the bottle is weighed both before and after being placed in storage, the mass difference observed will be a measure of transpiration mass loss.

- After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4° - 24° C to minimize the effects of transpiration. Use at 20° ± 4° C to minimize volumetric dilution error when using the reported density. Do not pipette from the container. Do not return removed aliquots to container.

HF Note: This standard should not be prepared or stored in glass.

HAZARDOUS INFORMATION 8.0

- Please refer to the Safety Data Sheet for information regarding this CRM/RM.

HOMOGENEITY9.0

- This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous.

Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure homogeneity.

QUALITY STANDARD DOCUMENTATION10.0

10.1 ISO 9001 Quality Management System Registration

- QSR Certificate Number QSR-1034

- Chemical Testing - Accredited / A2LA Certificate Number 883.01

10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories"

- Reference Material Producer - Accredited / A2LA Certificate Number 883.02

10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers"

Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: 800.669.6799; 540.585.3030, Fax: 540.585.3012; inorganicventures.com;

info@inorganicventures.com

CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY11.0

11.1 Certification Issue Date

11.2 Lot Expiration Date

- The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1 are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified.

February 28, 2023

- The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by transpiration (loss of water from the solution) and infrequently by chemical stability.

- February 28, 2028

- The date after which this CRM/RM should not be used.

11.3 Period of Validity

- This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1.

- Sealed TCT Bag Open Date: __________________________

12.0 NAMES AND SIGNATURES OF CERTIFYING OFFICERS

Certificate Approved By:

Paul Gaines

Chairman / Senior Technical Director

Certifying Officer:

Thomas Kozikowski

Manager, Quality Control

EUROPITTSP-3_00001

the Competence of Reference Material Producers" and ISO/IEC 17025, "General

Requirements for the Competence of Testing and Calibration Laboratories".

Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate

Number QSR-1034).

Testing Laboratory

Certificate 883.01

Reference Material Producer

Certificate 883.02

2.0 PRODUCT DESCRIPTION

Product Code: Multi Analyte Custom Grade Solution

Catalog Number: EUROPITTSP-3

Lot Number: U2-MEB730241

Matrix: 5% (v/v) HNO3

5 µg/mL ea:

Thorium, Uranium

Value / Analyte(s):

3.0 CERTIFIED VALUES AND UNCERTAINTIES

ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE

Thorium, Th 5.002 ± 0.026 µg/mL Uranium, U 5.002 ± 0.025 µg/mL

Density: 1.026 g/mL (measured at 20 ± 4 ºC)

Assay Information:

METHOD NIST SRM# SRM LOT#ANALYTE

928EDTA 928Th

Calculated See Sec. 4.2Th

3164ICP Assay 080521U

Calculated See Sec. 4.2U

The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.

Certified Abundance:

IV's Certified Abundance

Isotope Atom %

Uranium 238U

Uranium 235U

99.8 ± 0.1

0.19 ± 0.05

4.0 TRACEABILITY TO NIST

- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is specified.

4.1 Thermometer Calibration

- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights used for testing are annually compared to master weights and are traceable to NIST.

4.2 Balance Calibration

- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration laboratory.

4.3 Glassware Calibration

- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality control of CRM/RMs.

TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (µg/mL)5.0

N/A

INTENDED USE6.0

6.1 This standard is intended for the calibration of analytical instruments and validation of analytical methods as appropriate. This CRM may be used in connection with EPA Methods 6010, 6020 (all versions), Standard

Methods 3120 B and USP <232> / ICH Q3D.

6.2 For products attaining traceability through Inorganic Ventures’ Primary Certified Reference Materials (PCRM™) see the Limited License to Use PCRM™ in the Inorganic Ventures Terms and Conditions of Sale, https://www.inorganicventures.com/terms-and-conditions-sale. The Terms and Conditions contain information on the use of materials traceable to PCRM™ certified reference materials. This Limited License agreement is especially pertinent for laboratories accredited under ISO:17034.

INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL7.0

7.1 Storage and Handling Recommendations

www.inorganicventures.com/TCT- For more information, visit

- Store between approximately 4° - 30° C while in sealed TCT bag.

- While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is the responsibility of the user to account for this effect. When the bottle is weighed both before and after being placed in storage, the mass difference observed will be a measure of transpiration mass loss.

- After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4° - 24° C to minimize the effects of transpiration. Use at 20° ± 4° C to minimize volumetric dilution error when using the reported density. Do not pipette from the container. Do not return removed aliquots to container.

HAZARDOUS INFORMATION 8.0

- Please refer to the Safety Data Sheet for information regarding this CRM/RM.

HOMOGENEITY9.0

- This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous.

Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure homogeneity.

QUALITY STANDARD DOCUMENTATION10.0

10.1 ISO 9001 Quality Management System Registration

- QSR Certificate Number QSR-1034

- Chemical Testing - Accredited / A2LA Certificate Number 883.01

10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories"

- Reference Material Producer - Accredited / A2LA Certificate Number 883.02

10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers"

Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: 800.669.6799; 540.585.3030, Fax: 540.585.3012; inorganicventures.com;

info@inorganicventures.com

CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY11.0

11.1 Certification Issue Date

11.2 Lot Expiration Date

- The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1 are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified.

February 28, 2023

- The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by transpiration (loss of water from the solution) and infrequently by chemical stability.

- February 28, 2028

- The date after which this CRM/RM should not be used.

11.3 Period of Validity

- This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1.

- Sealed TCT Bag Open Date: __________________________

12.0 NAMES AND SIGNATURES OF CERTIFYING OFFICERS

Certificate Approved By:

Paul Gaines

Chairman / Senior Technical Director

Certifying Officer:

Thomas Kozikowski

Manager, Quality Control

M6020ICSA-MIX_00010

P ag e o f 3

MICPMSICV_00031

e o

MICSAB-1_00003

e o

MICSAB-3_00002

e o

MUICPMS-CRI-1_00003

e o

MUICPMS-CRI-2_00004

e o

TA-CAL1_00008

e o

TA-CAL1_00010

e o

TA-CAL2_00010

CERTIFICATE OF ANALYSIS

USA Europe 5580 Skylane Boulevard P: 707.525.5788 Nieuwe Hemweg 7P P: +31 20 638 05 97 Santa Rosa, CA 95403 P: 800.878.7654 1013BG Amsterdam F: +31 20 420 28 36 F: 707.545.7901 www.cpiinternational.com The Netherlands Rev. 2 Page 1 of 2

Multi-Element Aqueous CRM Product #: TA-CAL2

ICP ICPMS CAL Mix # 2 Lot #: 1208136-1

Matrix: 5% HNO3

Element Certified Concentration

& Uncertainty Element

Certified Concentration & Uncertainty

Element Certified Concentration

& Uncertainty

Al 2000 ± 10 mg/L Fe 2000 ± 10 mg/L Mg 2000 ± 10 mg/L

Ca 2000 ± 10 mg/L K 2000 ± 10 mg/L Na 2000 ± 10 mg/L

Source Material Lot # Chart

Element Source Material Lot # Element Source Material Lot # Element Source Material Lot #

Al 1077624 Fe 1114543 Mg 1075231

Ca 1121798 K 1156013 Na 1122654

Intended Use: This solution is intended for use as a certified…