J152790-1 Std_Tal_L4 Final Report_Part6.pdf

Report Date: 02-Mar-2023 07:48:37 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Eurofins Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000010.D

Injection Date: 01-Mar-2023 11:08:37 Instrument ID: CGC1 Operator ID:

Lims ID: ICV Worklist Smp#: 8

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 8

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0301230000010.D

D a la p o n

.1

M

C P

P

.1

D ic a m b a

.2

P

A

.6 ic h lo rp ro p

.8

,4 -D

.3

P e n ta c h lo ro p h e n o l(

.9

S ilv e x

,4

,5 -T

P

.0

,5

-T

.6 in o s e b

.8

-D

B

.9

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0301230000010.D

la p o n

.3 a m b a

.2

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n

.6 e x

,4

,5 -T

P

.2

,5

-T

.6

-D

B

.0 o s e b

.7

FORM VII

Lab Name: Job No.:

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-152790-1

CGC1

03/08/2023 11:20

03/01/2023 08:51

03/01/2023 10:49

CCVRT 180-428497/1

RTX-50

Eurofins Pittsburgh

Lab File ID: 0308230000003.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 384860800426136913 0.0723 0.0800 -9.7 15.0Ave

MCPP 13354521292107 8.27 8.00 3.4 15.0Ave

Dicamba 12557653001328035766 0.0378 0.0400 -5.4 15.0Ave

MCPA 20201792074591 7.79 8.00 -2.6 15.0Ave

Dichlorprop 345861363365500443 0.0757 0.0800 -5.4 15.0Ave

2,4-D 377215538395299965 0.0763 0.0800 -4.6 15.0Ave

Pentachlorophenol 40120425504359687678 0.0184 0.0200 -8.0 15.0Ave

Silvex (2,4,5-TP) 17198418001864583594 0.0184 0.0200 -7.8 15.0Ave

2,4,5-T 15608462001678631374 0.0186 0.0200 -7.0 15.0Ave

Dinoseb 10661162251125029965 0.0758 0.0800 -5.2 15.0Ave

2,4-DB 199387625216341182 0.0737 0.0800 -7.8 15.0Ave

2,4-Dichlorophenylacetic acid

466221750484132325 0.0154 0.0160 -3.7 15.0Ave

FORM VII EPA 8151A

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-152790-1

CGC1

03/08/2023 11:20

03/01/2023 08:51

03/01/2023 10:49

CCVRT 180-428497/1

RTX-50

Eurofins Pittsburgh

Lab File ID: 0308230000003.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.17 2.14 2.20

MCPP 8.20 8.17 8.23

Dicamba 8.28 8.25 8.31

MCPA 8.62 8.59 8.65

Dichlorprop 8.90 8.87 8.93 2,4-D 9.39 9.36 9.42 Pentachlorophenol 9.92 9.89 9.95 Silvex (2,4,5-TP) 10.08 10.05 10.11 2,4,5-T 10.63 10.60 10.66 Dinoseb 10.89 10.84 10.94

2,4-DB 11.01 10.98 11.04

2,4-Dichlorophenylacetic acid 7.98 7.95 8.01

Form VII EPA 8151A

Report Date: 09-Mar-2023 07:33:40 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000003.D

Lims ID: CCVRT

Client ID:

Sample Type: CCVRT

Inject. Date: 08-Mar-2023 11:20:45 ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046969-001

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 09-Mar-2023 07:33:40 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 08-Mar-2023 11:45:26

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.173 2.173 0.000 30788864H 0.0800 0.0723

2 2.364 2.364 0.000 28014818H 0.0800 0.0747

RPD = 3.27

$ 2 2,4-Dichlorophenylacetic acid

1 7.981 7.981 0.000 7459548H 0.0160 0.0154

2 7.926 7.926 0.000 6489841H 0.0160 0.0161

RPD = 4.37

3 MCPP M

1 8.198 8.198 0.000 10683612H 8.00 8.27

2 8.349 8.349 0.000 11756978H 8.00 7.81 M

RPD = 5.75

4 Dicamba

1 8.278 8.278 0.000 50230612H 0.0400 0.0378

2 8.190 8.190 0.000 46036664H 0.0400 0.0394

RPD = 4.08

5 MCPA

1 8.621 8.621 0.000 16161428H 8.00 7.79

2 8.655 8.655 0.000 17385465H 8.00 7.63

RPD = 2.08

6 Dichlorprop

1 8.901 8.901 0.000 27668909H 0.0800 0.0757

2 9.016 9.016 0.000 25964229H 0.0800 0.0772

RPD = 1.98

7 2,4-D

1 9.394 9.394 0.000 30177243H 0.0800 0.0763

2 9.411 9.411 0.000 29141261H 0.0800 0.0770

RPD = 0.88

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000003.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.921 9.921 0.000 80240851H 0.0200 0.0184

2 9.626 9.626 0.000 78174156H 0.0200 0.0193

RPD = 4.67

9 Silvex (2,4,5-TP)

1 10.078 10.078 0.000 34396836H 0.0200 0.0184

2 10.184 10.184 0.000 34382595H 0.0200 0.0198

RPD = 7.20

10 2,4,5-T M

1 10.629 10.629 0.000 31216924H 0.0200 0.0186

2 10.636 10.636 0.000 29463349H 0.0200 0.0195 M

RPD = 4.62

11 Dinoseb

1 10.885 10.885 0.000 85289298H 0.0800 0.0758

2 11.705 11.705 0.000 75824234H 0.0800 0.0768

RPD = 1.29

12 2,4-DB

1 11.013 11.013 0.000 15951010H 0.0800 0.0737

2 11.065 11.065 0.000 15677454H 0.0800 0.0746

RPD = 1.22

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

GCHERBCALSL3_00044 Amount Added: 1.00 Units: mL

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000003.D

Injection Date: 08-Mar-2023 11:20:45 Instrument ID: CGC1 Operator ID:

Lims ID: CCVRT Worklist Smp#: 1

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 1

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0308230000003.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.1

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0308230000003.D

la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-152790-1

CGC1

03/08/2023 11:20

03/01/2023 08:51

03/01/2023 10:49

CCVRT 180-428497/1

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0308230000003.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 350185225375256434 0.0747 0.0800 -6.7 15.0Ave

Dicamba 11509166001168485590 0.0394 0.0400 -1.5 15.0Ave

MCPP 14696221506095 7.81 8.00 -2.4 15.0Ave

MCPA 21731832278633 7.63 8.00 -4.6 15.0Ave

Dichlorprop 324552863336258134 0.0772 0.0800 -3.5 15.0Ave

2,4-D 364265763378375181 0.0770 0.0800 -3.7 15.0Ave

Pentachlorophenol 39087078004053407968 0.0193 0.0200 -3.6 15.0Ave

Silvex (2,4,5-TP) 17191297501734230344 0.0198 0.0200 -0.9 15.0Ave

2,4,5-T 14731674501512853745 0.0195 0.0200 -2.6 15.0Ave

2,4-DB 195968175210048987 0.0746 0.0800 -6.7 15.0Ave

Dinoseb 947802925987392817 0.0768 0.0800 -4.0 15.0Ave

2,4-Dichlorophenylacetic acid

405615063403173549 0.0161 0.0160 0.6 15.0Ave

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-152790-1

CGC1

03/08/2023 11:20

03/01/2023 08:51

03/01/2023 10:49

CCVRT 180-428497/1

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0308230000003.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.36 2.33 2.39 Dicamba 8.19 8.16 8.22

MCPP 8.35 8.32 8.38

MCPA 8.66 8.63 8.69

Dichlorprop 9.02 8.99 9.05 2,4-D 9.41 9.38 9.44 Pentachlorophenol 9.63 9.60 9.66 Silvex (2,4,5-TP) 10.18 10.15 10.21 2,4,5-T 10.64 10.61 10.67

2,4-DB 11.07 11.04 11.10

Dinoseb 11.71 11.68 11.74 2,4-Dichlorophenylacetic acid 7.93 7.90 7.96

Report Date: 09-Mar-2023 07:33:41 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000003.D

Lims ID: CCVRT

Client ID:

Sample Type: CCVRT

Inject. Date: 08-Mar-2023 11:20:45 ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046969-001

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 09-Mar-2023 07:33:40 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 08-Mar-2023 11:45:26

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.173 2.173 0.000 30788864H 0.0800 0.0723

2 2.364 2.364 0.000 28014818H 0.0800 0.0747

RPD = 3.27

$ 2 2,4-Dichlorophenylacetic acid

1 7.981 7.981 0.000 7459548H 0.0160 0.0154

2 7.926 7.926 0.000 6489841H 0.0160 0.0161

RPD = 4.37

3 MCPP M

1 8.198 8.198 0.000 10683612H 8.00 8.27

2 8.349 8.349 0.000 11756978H 8.00 7.81 M

RPD = 5.75

4 Dicamba

1 8.278 8.278 0.000 50230612H 0.0400 0.0378

2 8.190 8.190 0.000 46036664H 0.0400 0.0394

RPD = 4.08

5 MCPA

1 8.621 8.621 0.000 16161428H 8.00 7.79

2 8.655 8.655 0.000 17385465H 8.00 7.63

RPD = 2.08

6 Dichlorprop

1 8.901 8.901 0.000 27668909H 0.0800 0.0757

2 9.016 9.016 0.000 25964229H 0.0800 0.0772

RPD = 1.98

7 2,4-D

1 9.394 9.394 0.000 30177243H 0.0800 0.0763

2 9.411 9.411 0.000 29141261H 0.0800 0.0770

RPD = 0.88

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000003.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.921 9.921 0.000 80240851H 0.0200 0.0184

2 9.626 9.626 0.000 78174156H 0.0200 0.0193

RPD = 4.67

9 Silvex (2,4,5-TP)

1 10.078 10.078 0.000 34396836H 0.0200 0.0184

2 10.184 10.184 0.000 34382595H 0.0200 0.0198

RPD = 7.20

10 2,4,5-T M

1 10.629 10.629 0.000 31216924H 0.0200 0.0186

2 10.636 10.636 0.000 29463349H 0.0200 0.0195 M

RPD = 4.62

11 Dinoseb

1 10.885 10.885 0.000 85289298H 0.0800 0.0758

2 11.705 11.705 0.000 75824234H 0.0800 0.0768

RPD = 1.29

12 2,4-DB

1 11.013 11.013 0.000 15951010H 0.0800 0.0737

2 11.065 11.065 0.000 15677454H 0.0800 0.0746

RPD = 1.22

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000003.D

Injection Date: 08-Mar-2023 11:20:45 Instrument ID: CGC1 Operator ID:

Lims ID: CCVRT Worklist Smp#: 1

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 1

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0308230000003.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.1

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

Manual Integration/User Assign Peak Report

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000003.D

Injection Date: 08-Mar-2023 11:20:45 Instrument ID: CGC1

Lims ID: CCVRT

Client ID:

Operator ID: ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-1701 ( 0.53 mm) Detector GC ECD2B

3 MCPP, CAS: 93-65-2

Signal: 2

Processing Integration Results

RT: 8.35

Height: 2712825

Amount: 1.801231

Amount Units: ng

8.0 8.2 8.4 8.6 8.8 Min

Y

X

.3

Manual Integration Results

RT: 8.35

Height: 11756978

Amount: 7.806266

Amount Units: ng

8.0 8.2 8.4 8.6 8.8 Min

RT

Y

X

Reviewer: WB9V, 08-Mar-2023 11:45:14

Audit Action: Manually Integrated Audit Reason: Incomplete Integration

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000003.D

Injection Date: 08-Mar-2023 11:20:45 Instrument ID: CGC1

Lims ID: CCVRT

Client ID:

Operator ID: ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-1701 ( 0.53 mm) Detector GC ECD2B

10 2,4,5-T, CAS: 93-76-5

Signal: 2

Processing Integration Results

RT: 10.63

Height: 7711208

Amount: 0.005097

Amount Units: ng

10.3 10.5 10.7 10.9 Min

Y

X

GC ECD2B, 0308230000003.D

.6

Manual Integration Results

RT: 10.64

Height: 29463349

Amount: 0.019475

Amount Units: ng

10.3 10.5 10.7 10.9 Min

RT

Y

X

GC ECD2B, 0308230000003.D

.6

Reviewer: WB9V, 08-Mar-2023 11:45:21

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-152790-1

CGC1

03/08/2023 14:36

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428497/11

RTX-50

Eurofins Pittsburgh

Lab File ID: 0308230000013.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 391837000426136913 0.0736 0.0800 -8.0 15.0Ave

MCPP 13877781292107 8.59 8.00 7.4 15.0Ave

Dicamba 13201436501328035766 0.0398 0.0400 -0.6 15.0Ave

MCPA 20222872074591 7.80 8.00 -2.5 15.0Ave

Dichlorprop 360134425365500443 0.0788 0.0800 -1.5 15.0Ave

2,4-D 396551425395299965 0.0803 0.0800 0.3 15.0Ave

Pentachlorophenol 42493942504359687678 0.0195 0.0200 -2.5 15.0Ave

Silvex (2,4,5-TP) 18132380001864583594 0.0194 0.0200 -2.8 15.0Ave

2,4,5-T 16438042001678631374 0.0196 0.0200 -2.1 15.0Ave

Dinoseb 11139334751125029965 0.0792 0.0800 -1.0 15.0Ave

2,4-DB 209412938216341182 0.0774 0.0800 -3.2 15.0Ave

2,4-Dichlorophenylacetic acid

469652125484132325 0.0155 0.0160 -3.0 15.0Ave

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-152790-1

CGC1

03/08/2023 14:36

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428497/11

RTX-50

Eurofins Pittsburgh

Lab File ID: 0308230000013.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.18 2.14 2.20

MCPP 8.20 8.17 8.23

Dicamba 8.28 8.25 8.31

MCPA 8.62 8.59 8.65

Dichlorprop 8.90 8.87 8.93 2,4-D 9.40 9.36 9.42 Pentachlorophenol 9.92 9.89 9.95 Silvex (2,4,5-TP) 10.08 10.05 10.11 2,4,5-T 10.63 10.60 10.66 Dinoseb 10.89 10.84 10.94

2,4-DB 11.01 10.98 11.04

2,4-Dichlorophenylacetic acid 7.98 7.95 8.01

Report Date: 09-Mar-2023 07:33:56 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000013.D

Lims ID: CCV

Client ID:

Sample Type: CCV

Inject. Date: 08-Mar-2023 14:36:36 ALS Bottle#: 11 Worklist Smp#: 11

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046969-011

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 09-Mar-2023 07:33:56 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 08-Mar-2023 14:58:40

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.176 2.173 0.003 31346960H 0.0800 0.0736

2 2.366 2.364 0.002 28330389H 0.0800 0.0755

RPD = 2.60

$ 2 2,4-Dichlorophenylacetic acid

1 7.984 7.981 0.003 7514434H 0.0160 0.0155

2 7.929 7.926 0.003 6164966H 0.0160 0.0153

RPD = 1.50

3 MCPP

1 8.201 8.198 0.003 11102225H 8.00 8.59

2 8.351 8.349 0.002 11706364H 8.00 7.77

RPD = 10.02

4 Dicamba

1 8.282 8.278 0.004 52805746H 0.0400 0.0398

2 8.193 8.190 0.003 46896357H 0.0400 0.0401

RPD = 0.93

5 MCPA

1 8.623 8.621 0.002 16178299H 8.00 7.80

2 8.658 8.655 0.003 17015261H 8.00 7.47

RPD = 4.34

6 Dichlorprop M

1 8.902 8.901 0.001 28810754H 0.0800 0.0788

2 9.018 9.016 0.002 26465559H 0.0800 0.0787 M

RPD = 0.15

7 2,4-D

1 9.395 9.394 0.001 31724114H 0.0800 0.0803

2 9.415 9.411 0.004 29465126H 0.0800 0.0779

RPD = 3.01

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000013.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.923 9.921 0.002 84987885H 0.0200 0.0195

2 9.629 9.626 0.003 80357011H 0.0200 0.0198

RPD = 1.68

9 Silvex (2,4,5-TP)

1 10.080 10.078 0.002 36264760H 0.0200 0.0194

2 10.185 10.184 0.001 34220345H 0.0200 0.0197

RPD = 1.44

10 2,4,5-T

1 10.631 10.629 0.002 32876084H 0.0200 0.0196

2 10.638 10.636 0.002 29769852H 0.0200 0.0197

RPD = 0.47

11 Dinoseb

1 10.886 10.885 0.001 89114678H 0.0800 0.0792

2 11.709 11.705 0.004 76000210H 0.0800 0.0770

RPD = 2.87

12 2,4-DB

1 11.014 11.013 0.001 16753035H 0.0800 0.0774

2 11.068 11.065 0.003 16162292H 0.0800 0.0769

RPD = 0.64

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000013.D

Injection Date: 08-Mar-2023 14:36:36 Instrument ID: CGC1 Operator ID:

Lims ID: CCV Worklist Smp#: 11

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 11

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0308230000013.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.2

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0308230000013.D

la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-152790-1

CGC1

03/08/2023 14:36

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428497/11

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0308230000013.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 354129863375256434 0.0755 0.0800 -5.6 15.0Ave

Dicamba 11724089251168485590 0.0401 0.0400 0.3 15.0Ave

MCPP 14632961506095 7.77 8.00 -2.8 15.0Ave

MCPA 21269082278633 7.47 8.00 -6.7 15.0Ave

Dichlorprop 330819488336258134 0.0787 0.0800 -1.6 15.0Ave

2,4-D 368314075378375181 0.0779 0.0800 -2.7 15.0Ave

Pentachlorophenol 40178505504053407968 0.0198 0.0200 -0.9 15.0Ave

Silvex (2,4,5-TP) 17110172501734230344 0.0197 0.0200 -1.3 15.0Ave

2,4,5-T 14884926001512853745 0.0197 0.0200 -1.6 15.0Ave

2,4-DB 202028650210048987 0.0769 0.0800 -3.8 15.0Ave

Dinoseb 950002625987392817 0.0770 0.0800 -3.8 15.0Ave

2,4-Dichlorophenylacetic acid

385310375403173549 0.0153 0.0160 -4.4 15.0Ave

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-152790-1

CGC1

03/08/2023 14:36

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428497/11

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0308230000013.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.37 2.33 2.39 Dicamba 8.19 8.16 8.22

MCPP 8.35 8.32 8.38

MCPA 8.66 8.63 8.69

Dichlorprop 9.02 8.99 9.05 2,4-D 9.42 9.38 9.44 Pentachlorophenol 9.63 9.60 9.66 Silvex (2,4,5-TP) 10.19 10.15 10.21 2,4,5-T 10.64 10.61 10.67

2,4-DB 11.07 11.04 11.10

Dinoseb 11.71 11.68 11.74 2,4-Dichlorophenylacetic acid 7.93 7.90 7.96

Report Date: 09-Mar-2023 07:33:57 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000013.D

Lims ID: CCV

Client ID:

Sample Type: CCV

Inject. Date: 08-Mar-2023 14:36:36 ALS Bottle#: 11 Worklist Smp#: 11

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046969-011

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 09-Mar-2023 07:33:56 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 08-Mar-2023 14:58:40

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.176 2.173 0.003 31346960H 0.0800 0.0736

2 2.366 2.364 0.002 28330389H 0.0800 0.0755

RPD = 2.60

$ 2 2,4-Dichlorophenylacetic acid

1 7.984 7.981 0.003 7514434H 0.0160 0.0155

2 7.929 7.926 0.003 6164966H 0.0160 0.0153

RPD = 1.50

3 MCPP

1 8.201 8.198 0.003 11102225H 8.00 8.59

2 8.351 8.349 0.002 11706364H 8.00 7.77

RPD = 10.02

4 Dicamba

1 8.282 8.278 0.004 52805746H 0.0400 0.0398

2 8.193 8.190 0.003 46896357H 0.0400 0.0401

RPD = 0.93

5 MCPA

1 8.623 8.621 0.002 16178299H 8.00 7.80

2 8.658 8.655 0.003 17015261H 8.00 7.47

RPD = 4.34

6 Dichlorprop M

1 8.902 8.901 0.001 28810754H 0.0800 0.0788

2 9.018 9.016 0.002 26465559H 0.0800 0.0787 M

RPD = 0.15

7 2,4-D

1 9.395 9.394 0.001 31724114H 0.0800 0.0803

2 9.415 9.411 0.004 29465126H 0.0800 0.0779

RPD = 3.01

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000013.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.923 9.921 0.002 84987885H 0.0200 0.0195

2 9.629 9.626 0.003 80357011H 0.0200 0.0198

RPD = 1.68

9 Silvex (2,4,5-TP)

1 10.080 10.078 0.002 36264760H 0.0200 0.0194

2 10.185 10.184 0.001 34220345H 0.0200 0.0197

RPD = 1.44

10 2,4,5-T

1 10.631 10.629 0.002 32876084H 0.0200 0.0196

2 10.638 10.636 0.002 29769852H 0.0200 0.0197

RPD = 0.47

11 Dinoseb

1 10.886 10.885 0.001 89114678H 0.0800 0.0792

2 11.709 11.705 0.004 76000210H 0.0800 0.0770

RPD = 2.87

12 2,4-DB

1 11.014 11.013 0.001 16753035H 0.0800 0.0774

2 11.068 11.065 0.003 16162292H 0.0800 0.0769

RPD = 0.64

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000013.D

Injection Date: 08-Mar-2023 14:36:36 Instrument ID: CGC1 Operator ID:

Lims ID: CCV Worklist Smp#: 11

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 11

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0308230000013.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.2

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000013.D

Injection Date: 08-Mar-2023 14:36:36 Instrument ID: CGC1

Lims ID: CCV

Client ID:

Operator ID: ALS Bottle#: 11 Worklist Smp#: 11

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-1701 ( 0.53 mm) Detector GC ECD2B

6 Dichlorprop, CAS: 120-36-5 Signal: 2

Processing Integration Results

RT: 9.02

Height: 6767849

Amount: 0.020127

Amount Units: ng

8.7 8.9 9.1 9.3 Min

Y

X

.0

Manual Integration Results

RT: 9.02

Height: 26465559

Amount: 0.078706

Amount Units: ng

8.7 8.9 9.1 9.3 Min

RT

Y

X

.0

Reviewer: WB9V, 08-Mar-2023 14:58:32

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-152790-1

CGC1

03/08/2023 17:13

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428497/19

RTX-50

Eurofins Pittsburgh

Lab File ID: 0308230000021.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 438616813426136913 0.0823 0.0800 2.9 15.0Ave

MCPP 14649971292107 9.07 8.00 13.4 15.0Ave

Dicamba 13950246751328035766 0.0420 0.0400 5.0 15.0Ave

MCPA 21597882074591 8.33 8.00 4.1 15.0Ave

Dichlorprop 381198963365500443 0.0834 0.0800 4.3 15.0Ave

2,4-D 415831088395299965 0.0842 0.0800 5.2 15.0Ave

Pentachlorophenol 45343856504359687678 0.0208 0.0200 4.0 15.0Ave

Silvex (2,4,5-TP) 19197047501864583594 0.0206 0.0200 3.0 15.0Ave

2,4,5-T 17256306001678631374 0.0206 0.0200 2.8 15.0Ave

Dinoseb 11687999501125029965 0.0831 0.0800 3.9 15.0Ave

2,4-DB 224751263216341182 0.0831 0.0800 3.9 15.0Ave

2,4-Dichlorophenylacetic acid

517953188484132325 0.0171 0.0160 7.0 15.0Ave

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-152790-1

CGC1

03/08/2023 17:13

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428497/19

RTX-50

Eurofins Pittsburgh

Lab File ID: 0308230000021.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.17 2.14 2.20

MCPP 8.20 8.17 8.23

Dicamba 8.28 8.25 8.31

MCPA 8.62 8.59 8.65

Dichlorprop 8.90 8.87 8.93 2,4-D 9.40 9.36 9.42 Pentachlorophenol 9.92 9.89 9.95 Silvex (2,4,5-TP) 10.08 10.05 10.11 2,4,5-T 10.63 10.60 10.66 Dinoseb 10.89 10.84 10.94

2,4-DB 11.02 10.98 11.04

2,4-Dichlorophenylacetic acid 7.98 7.95 8.01

Report Date: 09-Mar-2023 07:34:10 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000021.D

Lims ID: CCV

Client ID:

Sample Type: CCV

Inject. Date: 08-Mar-2023 17:13:13 ALS Bottle#: 19 Worklist Smp#: 19

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046969-019

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 09-Mar-2023 07:34:09 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 09-Mar-2023 07:31:38

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.173 2.173 0.000 35089345H 0.0800 0.0823

2 2.365 2.364 0.001 31008078H 0.0800 0.0826

RPD = 0.35

$ 2 2,4-Dichlorophenylacetic acid

1 7.984 7.981 0.003 8287251H 0.0160 0.0171

2 7.928 7.926 0.002 6481844H 0.0160 0.0161

RPD = 6.27

3 MCPP

1 8.200 8.198 0.002 11719974H 8.00 9.07

2 8.350 8.349 0.001 12351204H 8.00 8.20

RPD = 10.07

4 Dicamba

1 8.280 8.278 0.002 55800987H 0.0400 0.0420

2 8.192 8.190 0.002 49260830H 0.0400 0.0422

RPD = 0.33

5 MCPA

1 8.623 8.621 0.002 17278300H 8.00 8.33

2 8.657 8.655 0.002 17961410H 8.00 7.88

RPD = 5.50

6 Dichlorprop

1 8.904 8.901 0.003 30495917H 0.0800 0.0834

2 9.019 9.016 0.003 27877993H 0.0800 0.0829

RPD = 0.64

7 2,4-D

1 9.396 9.394 0.002 33266487H 0.0800 0.0842

2 9.413 9.411 0.002 31301581H 0.0800 0.0827

RPD = 1.71

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000021.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.922 9.921 0.001 90687713H 0.0200 0.0208

2 9.628 9.626 0.002 84911779H 0.0200 0.0209

RPD = 0.70

9 Silvex (2,4,5-TP)

1 10.080 10.078 0.002 38394095H 0.0200 0.0206

2 10.184 10.184 0.000 36263949H 0.0200 0.0209

RPD = 1.54

10 2,4,5-T

1 10.630 10.629 0.001 34512612H 0.0200 0.0206

2 10.637 10.636 0.001 31820562H 0.0200 0.0210

RPD = 2.28

11 Dinoseb

1 10.886 10.885 0.001 93503996H 0.0800 0.0831

2 11.706 11.705 0.001 80540273H 0.0800 0.0816

RPD = 1.87

12 2,4-DB M

1 11.015 11.013 0.002 17980101H 0.0800 0.0831

2 11.065 11.065 0.000 17230114H 0.0800 0.0820 M

RPD = 1.31

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000021.D

Injection Date: 08-Mar-2023 17:13:13 Instrument ID: CGC1 Operator ID:

Lims ID: CCV Worklist Smp#: 19

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 19

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0308230000021.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.2

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0308230000021.D

la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-152790-1

CGC1

03/08/2023 17:13

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428497/19

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0308230000021.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 387600975375256434 0.0826 0.0800 3.3 15.0Ave

Dicamba 12315207501168485590 0.0422 0.0400 5.4 15.0Ave

MCPP 15439011506095 8.20 8.00 2.5 15.0Ave

MCPA 22451762278633 7.88 8.00 -1.5 15.0Ave

Dichlorprop 348474913336258134 0.0829 0.0800 3.6 15.0Ave

2,4-D 391269763378375181 0.0827 0.0800 3.4 15.0Ave

Pentachlorophenol 42455889504053407968 0.0209 0.0200 4.7 15.0Ave

Silvex (2,4,5-TP) 18131974501734230344 0.0209 0.0200 4.6 15.0Ave

2,4,5-T 15910281001512853745 0.0210 0.0200 5.2 15.0Ave

2,4-DB 215376425210048987 0.0820 0.0800 2.5 15.0Ave

Dinoseb 1006753413987392817 0.0816 0.0800 2.0 15.0Ave

2,4-Dichlorophenylacetic acid

405115250403173549 0.0161 0.0160 0.5 15.0Ave

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-152790-1

CGC1

03/08/2023 17:13

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428497/19

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0308230000021.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.37 2.33 2.39 Dicamba 8.19 8.16 8.22

MCPP 8.35 8.32 8.38

MCPA 8.66 8.63 8.69

Dichlorprop 9.02 8.99 9.05 2,4-D 9.41 9.38 9.44 Pentachlorophenol 9.63 9.60 9.66 Silvex (2,4,5-TP) 10.18 10.15 10.21 2,4,5-T 10.64 10.61 10.67

2,4-DB 11.07 11.04 11.10

Dinoseb 11.71 11.68 11.74 2,4-Dichlorophenylacetic acid 7.93 7.90 7.96

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000021.D

Lims ID: CCV

Client ID:

Sample Type: CCV

Inject. Date: 08-Mar-2023 17:13:13 ALS Bottle#: 19 Worklist Smp#: 19

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046969-019

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 09-Mar-2023 07:34:09 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1625

First Level Reviewer: WB9V Date: 09-Mar-2023 07:31:38

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.173 2.173 0.000 35089345H 0.0800 0.0823

2 2.365 2.364 0.001 31008078H 0.0800 0.0826

RPD = 0.35

$ 2 2,4-Dichlorophenylacetic acid

1 7.984 7.981 0.003 8287251H 0.0160 0.0171

2 7.928 7.926 0.002 6481844H 0.0160 0.0161

RPD = 6.27

3 MCPP

1 8.200 8.198 0.002 11719974H 8.00 9.07

2 8.350 8.349 0.001 12351204H 8.00 8.20

RPD = 10.07

4 Dicamba

1 8.280 8.278 0.002 55800987H 0.0400 0.0420

2 8.192 8.190 0.002 49260830H 0.0400 0.0422

RPD = 0.33

5 MCPA

1 8.623 8.621 0.002 17278300H 8.00 8.33

2 8.657 8.655 0.002 17961410H 8.00 7.88

RPD = 5.50

6 Dichlorprop

1 8.904 8.901 0.003 30495917H 0.0800 0.0834

2 9.019 9.016 0.003 27877993H 0.0800 0.0829

RPD = 0.64

7 2,4-D

1 9.396 9.394 0.002 33266487H 0.0800 0.0842

2 9.413 9.411 0.002 31301581H 0.0800 0.0827

RPD = 1.71

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000021.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.922 9.921 0.001 90687713H 0.0200 0.0208

2 9.628 9.626 0.002 84911779H 0.0200 0.0209

RPD = 0.70

9 Silvex (2,4,5-TP)

1 10.080 10.078 0.002 38394095H 0.0200 0.0206

2 10.184 10.184 0.000 36263949H 0.0200 0.0209

RPD = 1.54

10 2,4,5-T

1 10.630 10.629 0.001 34512612H 0.0200 0.0206

2 10.637 10.636 0.001 31820562H 0.0200 0.0210

RPD = 2.28

11 Dinoseb

1 10.886 10.885 0.001 93503996H 0.0800 0.0831

2 11.706 11.705 0.001 80540273H 0.0800 0.0816

RPD = 1.87

12 2,4-DB M

1 11.015 11.013 0.002 17980101H 0.0800 0.0831

2 11.065 11.065 0.000 17230114H 0.0800 0.0820 M

RPD = 1.31

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000021.D

Injection Date: 08-Mar-2023 17:13:13 Instrument ID: CGC1 Operator ID:

Lims ID: CCV Worklist Smp#: 19

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 19

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0308230000021.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.2

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0308230000021.D

la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

Report Date: 09-Mar-2023 07:34:11 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230308-46969.b\0308230000021.D

Injection Date: 08-Mar-2023 17:13:13 Instrument ID: CGC1

Lims ID: CCV

Client ID:

Operator ID: ALS Bottle#: 19 Worklist Smp#: 19

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-1701 ( 0.53 mm) Detector GC ECD2B

12 2,4-DB, CAS: 94-82-6

Signal: 2

Processing Integration Results

RT: 11.07

Height: 4664857

Amount: 0.022208

Amount Units: ng

10.7 10.9 11.1 11.3 11.5 Min

Y

X

GC ECD2B, 0308230000021.D

.0

Manual Integration Results

RT: 11.07

Height: 17230114

Amount: 0.082029

Amount Units: ng

10.7 10.9 11.1 11.3 11.5 Min

RT

Y

X

GC ECD2B, 0308230000021.D

.0

Reviewer: WB9V, 09-Mar-2023 07:31:35

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-152790-1

CGC1

03/13/2023 10:39

03/01/2023 08:51

03/01/2023 10:49

CCVRT 180-428960/1

RTX-50

Eurofins Pittsburgh

Lab File ID: 0313230000003.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 459689700426136913 0.0863 0.0800 7.9 15.0Ave

MCPP 14384671292107 8.91 8.00 11.3 15.0Ave

Dicamba 12647503001328035766 0.0381 0.0400 -4.8 15.0Ave

MCPA 20665432074591 7.97 8.00 -0.4 15.0Ave

Dichlorprop 351208325365500443 0.0769 0.0800 -3.9 15.0Ave

2,4-D 383170900395299965 0.0775 0.0800 -3.1 15.0Ave

Pentachlorophenol 39865228504359687678 0.0183 0.0200 -8.6 15.0Ave

Silvex (2,4,5-TP) 17483124001864583594 0.0188 0.0200 -6.2 15.0Ave

2,4,5-T 15859593501678631374 0.0189 0.0200 -5.5 15.0Ave

Dinoseb 10829425751125029965 0.0770 0.0800 -3.7 15.0Ave

2,4-DB 203684538216341182 0.0753 0.0800 -5.9 15.0Ave

2,4-Dichlorophenylacetic acid

468399750484132325 0.0155 0.0160 -3.2 15.0Ave

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-152790-1

CGC1

03/13/2023 10:39

03/01/2023 08:51

03/01/2023 10:49

CCVRT 180-428960/1

RTX-50

Eurofins Pittsburgh

Lab File ID: 0313230000003.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.17 2.14 2.20

MCPP 8.20 8.17 8.23

Dicamba 8.28 8.25 8.31

MCPA 8.63 8.60 8.66

Dichlorprop 8.91 8.88 8.94 2,4-D 9.40 9.37 9.43 Pentachlorophenol 9.93 9.90 9.96 Silvex (2,4,5-TP) 10.08 10.05 10.11 2,4,5-T 10.63 10.60 10.66 Dinoseb 10.89 10.84 10.94

2,4-DB 11.02 10.99 11.05

2,4-Dichlorophenylacetic acid 7.99 7.96 8.02

Report Date: 14-Mar-2023 08:02:02 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Lims ID: CCVRT

Client ID:

Sample Type: CCVRT

Inject. Date: 13-Mar-2023 10:39:51 ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-001

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:02 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 13-Mar-2023 10:58:44

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.173 2.173 0.000 36775176H 0.0800 0.0863

2 2.365 2.365 0.000 32334348H 0.0800 0.0862

RPD = 0.15

$ 2 2,4-Dichlorophenylacetic acid

1 7.986 7.986 0.000 7494396H 0.0160 0.0155

2 7.933 7.933 0.000 7091056H 0.0160 0.0176

RPD = 12.75

3 MCPP M

1 8.202 8.202 0.000 11507737H 8.00 8.91

2 8.357 8.357 0.000 12705453H 8.00 8.44 M

RPD = 5.42

4 Dicamba

1 8.281 8.281 0.000 50590012H 0.0400 0.0381

2 8.197 8.197 0.000 49343005H 0.0400 0.0422

RPD = 10.29

5 MCPA

1 8.625 8.625 0.000 16532342H 8.00 7.97

2 8.663 8.663 0.000 18847615H 8.00 8.27

RPD = 3.73

6 Dichlorprop

1 8.905 8.905 0.000 28096666H 0.0800 0.0769

2 9.025 9.025 0.000 28450192H 0.0800 0.0846

RPD = 9.58

7 2,4-D

1 9.398 9.398 0.000 30653672H 0.0800 0.0775

2 9.421 9.421 0.000 31831439H 0.0800 0.0841

RPD = 8.14

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.925 9.925 0.000 79730457H 0.0200 0.0183

2 9.635 9.635 0.000 86926829H 0.0200 0.0214

RPD = 15.89

9 Silvex (2,4,5-TP)

1 10.082 10.082 0.000 34966248H 0.0200 0.0188

2 10.194 10.194 0.000 38105539H 0.0200 0.0220

RPD = 15.81

10 2,4,5-T

1 10.633 10.633 0.000 31719187H 0.0200 0.0189

2 10.645 10.645 0.000 33005305H 0.0200 0.0218

RPD = 14.35

11 Dinoseb

1 10.889 10.889 0.000 86635406H 0.0800 0.0770

2 11.714 11.714 0.000 83532896H 0.0800 0.0846

RPD = 9.40

12 2,4-DB

1 11.017 11.017 0.000 16294763H 0.0800 0.0753

2 11.075 11.075 0.000 17804452H 0.0800 0.0848

RPD = 11.80

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Injection Date: 13-Mar-2023 10:39:51 Instrument ID: CGC1 Operator ID:

Lims ID: CCVRT Worklist Smp#: 1

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 1

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0313230000003.D

la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

P

P

.2

D ic a m b a

.2

P

A

.6 h lo rp ro p

.9

-D

.3 n ta c h lo ro p h e n e x

,4

,5 -T

P

.0

,5

-T

.6 o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD2B, 0313230000003.D

la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4 n ta c h lo ro p h e n e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 o s e b

.7

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-152790-1

CGC1

03/13/2023 10:39

03/01/2023 08:51

03/01/2023 10:49

CCVRT 180-428960/1

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0313230000003.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 404179350375256434 0.0862 0.0800 7.7 15.0Ave

Dicamba 12335751251168485590 0.0422 0.0400 5.6 15.0Ave

MCPP 15881821506095 8.44 8.00 5.5 15.0Ave

MCPA 23559522278633 8.27 8.00 3.4 15.0Ave

Dichlorprop 355627400336258134 0.0846 0.0800 5.8 15.0Ave

2,4-D 397892988378375181 0.0841 0.0800 5.2 15.0Ave

Pentachlorophenol 43463414504053407968 0.0214 0.0200 7.2 15.0Ave

Silvex (2,4,5-TP) 19052769501734230344 0.0220 0.0200 9.9 15.0Ave

2,4,5-T 16502652501512853745 0.0218 0.0200 9.1 15.0Ave

2,4-DB 222555650210048987 0.0848 0.0800 6.0 15.0Ave

Dinoseb 1044161200987392817 0.0846 0.0800 5.7 15.0Ave

2,4-Dichlorophenylacetic acid

443191000403173549 0.0176 0.0160 9.9 15.0Ave

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-152790-1

CGC1

03/13/2023 10:39

03/01/2023 08:51

03/01/2023 10:49

CCVRT 180-428960/1

RTX-1701

Eurofins Pittsburgh

Lab File ID: 0313230000003.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.37 2.34 2.40 Dicamba 8.20 8.17 8.23

MCPP 8.36 8.33 8.39

MCPA 8.66 8.63 8.69

Dichlorprop 9.03 9.00 9.06 2,4-D 9.42 9.39 9.45 Pentachlorophenol 9.64 9.61 9.67 Silvex (2,4,5-TP) 10.19 10.16 10.22 2,4,5-T 10.65 10.62 10.68

2,4-DB 11.08 11.05 11.11

Dinoseb 11.71 11.68 11.74 2,4-Dichlorophenylacetic acid 7.93 7.90 7.96

Report Date: 14-Mar-2023 08:02:03 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Lims ID: CCVRT

Client ID:

Sample Type: CCVRT

Inject. Date: 13-Mar-2023 10:39:51 ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-001

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:02 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 13-Mar-2023 10:58:44

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.173 2.173 0.000 36775176H 0.0800 0.0863

2 2.365 2.365 0.000 32334348H 0.0800 0.0862

RPD = 0.15

$ 2 2,4-Dichlorophenylacetic acid

1 7.986 7.986 0.000 7494396H 0.0160 0.0155

2 7.933 7.933 0.000 7091056H 0.0160 0.0176

RPD = 12.75

3 MCPP M

1 8.202 8.202 0.000 11507737H 8.00 8.91

2 8.357 8.357 0.000 12705453H 8.00 8.44 M

RPD = 5.42

4 Dicamba

1 8.281 8.281 0.000 50590012H 0.0400 0.0381

2 8.197 8.197 0.000 49343005H 0.0400 0.0422

RPD = 10.29

5 MCPA

1 8.625 8.625 0.000 16532342H 8.00 7.97

2 8.663 8.663 0.000 18847615H 8.00 8.27

RPD = 3.73

6 Dichlorprop

1 8.905 8.905 0.000 28096666H 0.0800 0.0769

2 9.025 9.025 0.000 28450192H 0.0800 0.0846

RPD = 9.58

7 2,4-D

1 9.398 9.398 0.000 30653672H 0.0800 0.0775

2 9.421 9.421 0.000 31831439H 0.0800 0.0841

RPD = 8.14

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.925 9.925 0.000 79730457H 0.0200 0.0183

2 9.635 9.635 0.000 86926829H 0.0200 0.0214

RPD = 15.89

9 Silvex (2,4,5-TP)

1 10.082 10.082 0.000 34966248H 0.0200 0.0188

2 10.194 10.194 0.000 38105539H 0.0200 0.0220

RPD = 15.81

10 2,4,5-T

1 10.633 10.633 0.000 31719187H 0.0200 0.0189

2 10.645 10.645 0.000 33005305H 0.0200 0.0218

RPD = 14.35

11 Dinoseb

1 10.889 10.889 0.000 86635406H 0.0800 0.0770

2 11.714 11.714 0.000 83532896H 0.0800 0.0846

RPD = 9.40

12 2,4-DB

1 11.017 11.017 0.000 16294763H 0.0800 0.0753

2 11.075 11.075 0.000 17804452H 0.0800 0.0848

RPD = 11.80

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Injection Date: 13-Mar-2023 10:39:51 Instrument ID: CGC1 Operator ID:

Lims ID: CCVRT Worklist Smp#: 1

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 1

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0313230000003.D

la p o n

.1

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Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

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Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000003.D

Injection Date: 13-Mar-2023 10:39:51 Instrument ID: CGC1

Lims ID: CCVRT

Client ID:

Operator ID: ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-1701 ( 0.53 mm) Detector GC ECD2B

3 MCPP, CAS: 93-65-2

Signal: 2

Processing Integration Results

RT: 8.36

Height: 2979085

Amount: 1.978019

Amount Units: ng

8.0 8.2 8.4 8.6 8.8 Min

Y

X

Manual Integration Results

RT: 8.36

Height: 12705453

Amount: 8.436024

Amount Units: ng

8.0 8.2 8.4 8.6 8.8 Min

RT

Y

X

Reviewer: WB9V, 13-Mar-2023 10:58:29

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION DATA

0.53(mm)

180-152790-1

CGC1

03/13/2023 14:14

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428960/12

RTX-50

Eurofins Pittsburgh

Lab File ID: 0313230000014.D Conc. Units: ng/uL

ANALYTE CURVE CALC SPIKE %D MAX

TYPE AMOUNT AMOUNT %D

AVE CF CF MIN CF

Dalapon 522383925426136913 0.0981 0.0800 22.6* 15.0Ave

MCPP 16230731292107 10.0 8.00 25.6* 15.0Ave

Dicamba 14758088501328035766 0.0445 0.0400 11.1 15.0Ave

MCPA 23415512074591 9.03 8.00 12.9 15.0Ave

Dichlorprop 411135450365500443 0.0900 0.0800 12.5 15.0Ave

2,4-D 446770300395299965 0.0904 0.0800 13.0 15.0Ave

Pentachlorophenol 48458398004359687678 0.0222 0.0200 11.2 15.0Ave

Silvex (2,4,5-TP) 20567025501864583594 0.0221 0.0200 10.3 15.0Ave

2,4,5-T 18806471501678631374 0.0224 0.0200 12.0 15.0Ave

Dinoseb 13140491501125029965 0.0934 0.0800 16.8* 15.0Ave

2,4-DB 243201425216341182 0.0899 0.0800 12.4 15.0Ave

2,4-Dichlorophenylacetic acid

549014000484132325 0.0181 0.0160 13.4 15.0Ave

SDG No.:

Instrument ID:

Calibration Date:

Calib Start Date:

Lab Sample ID:

Calib End Date:GC Column: ID:

HERBICIDES CONTINUING CALIBRATION RETENTION TIME SUMMARY

0.53(mm)

180-152790-1

CGC1

03/13/2023 14:14

03/01/2023 08:51

03/01/2023 10:49

CCV 180-428960/12

RTX-50

Eurofins Pittsburgh

Lab File ID: 0313230000014.D

Analyte RT

TOFROM

RT WINDOW

Dalapon 2.17 2.14 2.20

MCPP 8.20 8.17 8.23

Dicamba 8.28 8.25 8.31

MCPA 8.62 8.60 8.66

Dichlorprop 8.90 8.88 8.94 2,4-D 9.40 9.37 9.43 Pentachlorophenol 9.92 9.90 9.96 Silvex (2,4,5-TP) 10.08 10.05 10.11 2,4,5-T 10.63 10.60 10.66 Dinoseb 10.89 10.84 10.94

2,4-DB 11.02 10.99 11.05

2,4-Dichlorophenylacetic acid 7.98 7.96 8.02

Report Date: 14-Mar-2023 08:02:21 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000014.D

Lims ID: CCV

Client ID:

Sample Type: CCV

Inject. Date: 13-Mar-2023 14:14:46 ALS Bottle#: 12 Worklist Smp#: 12

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0047043-012

Operator ID: Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 14-Mar-2023 08:02:21 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1622

First Level Reviewer: WB9V Date: 14-Mar-2023 07:59:06

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.171 2.173 -0.002 41790714H 0.0800 0.0981

2 2.363 2.365 -0.002 35240436H 0.0800 0.0939

RPD = 4.33

$ 2 2,4-Dichlorophenylacetic acid

1 7.983 7.986 -0.003 8784224H 0.0160 0.0181

2 7.933 7.933 0.000 7127487H 0.0160 0.0177

RPD = 2.60

3 MCPP

1 8.200 8.202 -0.002 12984580H 8.00 10.0

2 8.355 8.357 -0.002 13545336H 8.00 8.99

RPD = 11.09

4 Dicamba

1 8.280 8.281 -0.001 59032354H 0.0400 0.0445

2 8.196 8.197 -0.001 54592366H 0.0400 0.0467

RPD = 4.98

5 MCPA

1 8.623 8.625 -0.002 18732411H 8.00 9.03

2 8.662 8.663 -0.001 19666213H 8.00 8.63

RPD = 4.52

6 Dichlorprop

1 8.903 8.905 -0.002 32890836H 0.0800 0.0900

2 9.025 9.025 0.000 31261604H 0.0800 0.0930

RPD = 3.26

7 2,4-D

1 9.396 9.398 -0.002 35741624H 0.0800 0.0904

2 9.419 9.421 -0.002 35112366H 0.0800 0.0928

RPD = 2.60

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000014.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.923 9.925 -0.002 96916796H 0.0200 0.0222

2 9.635 9.635 0.000 94934666H 0.0200 0.0234

RPD = 5.22

9 Silvex (2,4,5-TP)

1 10.081 10.082 -0.001 41134051H 0.0200 0.0221

2 10.191 10.194 -0.003 41475690H 0.0200 0.0239

RPD = 8.07

10 2,4,5-T

1 10.632 10.633 -0.001 37612943H 0.0200 0.0224

2 10.646 10.645 0.001 36480110H 0.0200 0.0241

RPD = 7.34

11 Dinoseb

1 10.888 10.889 -0.001 105123932H 0.0800 0.0934

2 11.715 11.714 0.001 93773052H 0.0800 0.0950

RPD = 1.62

12 2,4-DB

1 11.016 11.017 -0.001 19456114H 0.0800 0.0899

2 11.074 11.075 -0.001 20362988H 0.0800 0.0969

RPD = 7.50

QC Flag Legend Processing Flags

H - Response Measured by Height

Reagents:

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230313-47043.b\0313230000014.D

Injection Date: 13-Mar-2023 14:14:46 Instrument ID: CGC1 Operator ID:

Lims ID: CCV Worklist Smp#: 12

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 12

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0313230000014.D

la p o n

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