J152790-3 Std_Tal_L4 Final Report.pdf

ANALYTICAL REPORT

PREPARED FOR

Attn: Carole Peven McCarthy

Battelle 141 Longwater Dr

Suite 202 Norwell MA 02061

Generated 5/8/2023 7:43 AM

JOB DESCRIPTION

Shrewsberry NJ

JOB NUMBER

180-152790-3

See page two for job notes and contact information.

Pittsburgh PA 15238 RIDC Park 301 Alpha Drive Eurofins Pittsburgh https://eol.et.eurofinsus.com/myEOL/ http://

Eurofins Pittsburgh

Eurofins Pittsburgh is a laboratory within Eurofins Environment Testing Northeast LLC, a company within Eurofins Environment Testing Group of Companies

Job Notes The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available.

Any exceptions to the NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory. This report is confidential and is intended for the sole use of Eurofins Environment Testing Northeast, LLC Pittsburgh and its client. All questions regarding this report should be directed to the Eurofins Environment Testing Northeast, LLC Pittsburgh Project Manager or designee who has signed this report.

PA Lab ID: 02-00416

The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be directed to the Eurofins Pittsburgh Project Manager.

Authorization

Generated

5/8/2023 7:43 AM

Authorized for release by Carrie L Gamber, Senior Project Manager Carrie.Gamber@et.eurofinsus.com 412 963-2428

Table of Contents Cover Title Page

Data Summaries

Definitions

Case Narrative

Detection Summary

Client Sample Results

Default Detection Limits

QC Sample Results

QC Association

Chronicle

Certification Summary

Method Summary

Sample Summary

Reagent Traceability

COAs

Inorganic Sample Data

Metals Data

Met Cover Page

Met Sample Data

Met QC Data Met ICV/CCV Met Blanks Met ICSA/ICSAB Met MS/MSD/PDS Met LCS/LCSD Met Serial Dilution

Table of Contents Met MDL

Met Linear Ranges

Met Preparation Log

Met Analysis Run Log

Met Internal Standards

Met Prep Data

Met Raw Data

General Chemistry Data

Gen Chem Cover Page

Gen Chem Sample Data

Gen Chem QC Data Gen Chem ICV/CCV Gen Chem Blanks Gen Chem MS/MSD/PDS Gen Chem Duplicates Gen Chem LCS/LCSD

Gen Chem MDL

Gen Chem Preparation Log

Gen Chem Analysis Run Log

Gen Chem Prep Data

Gen Chem Raw Data

Shipping and Receiving Documents

Client Chain of Custody

Sample Receipt Checklist

Definitions/Glossary Job ID: 180-152790-3Client: Battelle

Project/Site: Shrewsberry NJ

Qualifiers

Metals Qualifier Description

4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable.

Qualifier

B Compound was found in the blank and sample.

F1 MS and/or MSD recovery exceeds control limits.

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

U Indicates the analyte was analyzed for but not detected.

General Chemistry Qualifier Description

F1 MS and/or MSD recovery exceeds control limits.

Qualifier

U Indicates the analyte was analyzed for but not detected.

W PS: Post-digestion spike was outside control limits

Glossary These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CFU Colony Forming Unit

CNF Contains No Free Liquid

DER Duplicate Error Ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL Detection Limit (DoD/DOE)

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision Level Concentration (Radiochemistry)

EDL Estimated Detection Limit (Dioxin)

LOD Limit of Detection (DoD/DOE)

LOQ Limit of Quantitation (DoD/DOE)

MCL EPA recommended "Maximum Contaminant Level"

MDA Minimum Detectable Activity (Radiochemistry)

MDC Minimum Detectable Concentration (Radiochemistry)

MDL Method Detection Limit

ML Minimum Level (Dioxin)

MPN Most Probable Number

MQL Method Quantitation Limit

NC Not Calculated

ND Not Detected at the reporting limit (or MDL or EDL if shown)

NEG Negative / Absent

POS Positive / Present

PQL Practical Quantitation Limit

PRES Presumptive

QC Quality Control

RER Relative Error Ratio (Radiochemistry)

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TNTC Too Numerous To Count

CASE NARRATIVE

Client: Battelle

Project: Shrewsberry NJ

Report Number: 180-152790-3

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

RECEIPT

The samples were received on 03/01/2023; the samples arrived in good condition, properly preserved and on ice. The temperature of the coolers at receipt was 2.1 C.

METALS

Zinc was detected in method blank MB 180-433890/1-A at a level exceeding the reporting limit. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. Associated samples were not re-extracted and/or re-analyzed because results were greater than 10X the value found in the method blank.

Antimony failed the recovery criteria low for the MS of sample #20230099 AMENDED COMPOSITE 3MS (180-152790-2) in batch 180-434332. Aluminum and Zinc failed the recovery criteria high. Antimony and Zinc failed the recovery criteria low for the MSD of sample #20230099 AMENDED COMPOSITE 3MSD (180-152790-2) in batch 180-434332. Aluminum failed the recovery criteria high.

The presence of the '4' qualifier indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.

HEXAVALENT CHROMIUM

Sample #20230095 COMPOSITE 3 (180-152790-1) required dilution prior to analysis. The reporting limits have been adjusted accordingly.

Cr (VI) and Cr (VI) failed the recovery criteria low for the MSI/MSS of sample #20230099 AMENDED COMPOSITE 3MS (180-152790-2) in batch 180-428700.

The sample soluble, insoluble, and post-digestion spike (PDS) recoveries were outside criteria. Acceptable laboratory control sample (LCS) soluble and insoluble analysis data demonstrate that the analytical system was operating in control; therefore, this condition is most likely due to a matrix effect. An oxidation reduction potential (ORP) test was performed for the following samples: #20230099 AMENDED COMPOSITE 3 (180-152790-2), (180-152790-B-2-I MSI), (180-152790-B-2-H MSS) and (180-152790-B-2-F PDS).

The associated ORP chart is included in the report. A re-analysis was performed in accordance with the standard operating procedure

(SOP).

TRIVALENT CHROMIUM

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

Detection Summary

Project/Site: Shrewsberry NJ

Client Sample ID: #20230095 COMPOSITE 3 Lab Sample ID: 180-152790-1

☼Aluminum

RL

17 mg/Kg

MDL

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA118000 EPA 6020B

☼Arsenic 0.28 mg/Kg0.16 Total/NA131 EPA 6020B

☼Barium 2.8 mg/Kg1.7 Total/NA144 EPA 6020B

☼Beryllium 0.28 mg/Kg0.20 Total/NA11.5 EPA 6020B

☼Cadmium 0.28 mg/Kg0.16 Total/NA12.7 EPA 6020B

☼Chromium 0.57 mg/Kg0.51 Total/NA1130 EPA 6020B

☼Copper 0.85 mg/Kg0.58 Total/NA1160 EPA 6020B

☼Antimony 0.57 mg/Kg0.30 Total/NA10.74 EPA 6020B

☼Lead 0.28 mg/Kg0.19 Total/NA1280 EPA 6020B

☼Manganese 1.4 mg/Kg1.2 Total/NA1170 EPA 6020B

☼Nickel 0.28 mg/Kg0.27 Total/NA135 EPA 6020B

☼Selenium 1.4 mg/Kg0.35 Total/NA12.1 EPA 6020B

☼Silver 0.28 mg/Kg0.079 Total/NA11.0 EPA 6020B

☼Zinc 4.3 mg/Kg1.4 Total/NA1500 B EPA 6020B

☼Cobalt 0.14 mg/Kg0.10 Total/NA19.8 EPA 6020B

☼Vanadium 0.28 mg/Kg0.27 Total/NA180 EPA 6020B

☼Cr (III) 500 ug/Kg210 Total/NA1130000 7196A

Client Sample ID: #20230099 AMENDED COMPOSITE 3 Lab Sample ID: 180-152790-2

☼Aluminum

RL

16 mg/Kg

MDL

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA118000 EPA 6020B

☼Arsenic 0.27 mg/Kg0.16 Total/NA129 EPA 6020B

☼Barium 2.7 mg/Kg1.7 Total/NA161 EPA 6020B

☼Beryllium 0.27 mg/Kg0.20 Total/NA11.3 EPA 6020B

☼Cadmium 0.27 mg/Kg0.15 Total/NA12.1 EPA 6020B

☼Chromium 0.54 mg/Kg0.48 Total/NA1110 EPA 6020B

☼Copper 0.81 mg/Kg0.56 Total/NA1120 EPA 6020B

☼Antimony 0.54 mg/Kg0.29 Total/NA10.90 F1 EPA 6020B

☼Lead 0.27 mg/Kg0.18 Total/NA1210 EPA 6020B

☼Manganese 1.4 mg/Kg1.2 Total/NA1220 EPA 6020B

☼Nickel 0.27 mg/Kg0.25 Total/NA130 EPA 6020B

☼Selenium 1.4 mg/Kg0.33 Total/NA11.6 EPA 6020B

☼Silver 0.27 mg/Kg0.076 Total/NA10.84 EPA 6020B

☼Zinc 4.1 mg/Kg1.3 Total/NA1500 B EPA 6020B

☼Cobalt 0.14 mg/Kg0.098 Total/NA19.6 EPA 6020B

☼Vanadium 0.27 mg/Kg0.25 Total/NA167 EPA 6020B

☼Cr (III) 500 ug/Kg210 Total/NA1110000 7196A

Eurofins Pittsburgh

This Detection Summary does not include radiochemical test results.

Client Sample Results

Project/Site: Shrewsberry NJ

Method: SW846 EPA 6020B - Metals (ICP/MS)

Lab Sample ID: 180-152790-1Client Sample ID: #20230095 COMPOSITE 3 Matrix: SedimentDate Collected: 02/27/23 10:19

Percent Solids: 28.0Date Received: 03/01/23 12:07

RL MDL

18000 17 12 mg/Kg ☼ 05/01/23 12:40 05/04/23 18:03 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Aluminum

0.28 0.16 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼31Arsenic

2.8 1.7 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼44Barium

0.28 0.20 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼1.5Beryllium

0.28 0.16 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼2.7Cadmium

0.57 0.51 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼130Chromium

0.85 0.58 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼160Copper

0.57 0.30 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼0.74Antimony

0.28 0.19 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼280Lead

1.4 1.2 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼170Manganese

0.28 0.27 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼35Nickel

1.4 0.35 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼2.1Selenium

0.28 0.079 mg/Kg 05/01/23 12:40 05/05/23 19:06 1☼1.0Silver

4.3 1.4 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼500 BZinc

0.14 0.10 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼9.8Cobalt

0.28 0.27 mg/Kg 05/01/23 12:40 05/04/23 18:03 1☼80Vanadium

Project/Site: Shrewsberry NJ

Method: SW846 EPA 6020B - Metals (ICP/MS)

Lab Sample ID: 180-152790-2Client Sample ID: #20230099 AMENDED COMPOSITE 3 Matrix: SedimentDate Collected: 02/27/23 10:19

Percent Solids: 36.9Date Received: 03/01/23 12:07

RL MDL

18000 16 11 mg/Kg ☼ 05/01/23 12:40 05/04/23 17:44 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Aluminum

0.27 0.16 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼29Arsenic

2.7 1.7 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼61Barium

0.27 0.20 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼1.3Beryllium

0.27 0.15 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼2.1Cadmium

0.54 0.48 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼110Chromium

0.81 0.56 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼120Copper

0.54 0.29 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼0.90 F1Antimony

0.27 0.18 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼210Lead

1.4 1.2 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼220Manganese

0.27 0.25 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼30Nickel

1.4 0.33 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼1.6Selenium

0.27 0.076 mg/Kg 05/01/23 12:40 05/05/23 18:47 1☼0.84Silver

4.1 1.3 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼500 BZinc

0.14 0.098 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼9.6Cobalt

0.27 0.25 mg/Kg 05/01/23 12:40 05/04/23 17:44 1☼67Vanadium

Project/Site: Shrewsberry NJ

General Chemistry

Lab Sample ID: 180-152790-1Client Sample ID: #20230095 COMPOSITE 3 Matrix: SedimentDate Collected: 02/27/23 10:19

Date Received: 03/01/23 12:07

RL MDL

130000 500 210 ug/Kg ☼ 03/28/23 06:21 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Cr (III) (SW846 7196A)

Project/Site: Shrewsberry NJ

General Chemistry

Lab Sample ID: 180-152790-1Client Sample ID: #20230095 COMPOSITE 3 Matrix: SedimentDate Collected: 02/27/23 10:19

Percent Solids: 28.0Date Received: 03/01/23 12:07

RL MDL

7200 U 7200 3800 ug/Kg ☼ 03/07/23 15:28 03/09/23 12:01 5

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Cr (VI) (SW846 EPA 7196A)

Project/Site: Shrewsberry NJ

General Chemistry

Lab Sample ID: 180-152790-2Client Sample ID: #20230099 AMENDED COMPOSITE 3 Matrix: SedimentDate Collected: 02/27/23 10:19

Date Received: 03/01/23 12:07

RL MDL

110000 500 210 ug/Kg ☼ 03/28/23 06:21 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Cr (III) (SW846 7196A)

Project/Site: Shrewsberry NJ

General Chemistry

Lab Sample ID: 180-152790-2Client Sample ID: #20230099 AMENDED COMPOSITE 3 Matrix: SedimentDate Collected: 02/27/23 10:19

Percent Solids: 36.9Date Received: 03/01/23 12:07

RL MDL

1100 U F1 1100 580 ug/Kg ☼ 03/07/23 15:28 03/09/23 11:55 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Cr (VI) (SW846 EPA 7196A)

1100 580 ug/Kg 03/07/23 15:29 03/09/23 12:27 1☼1100 U F1Cr (VI) (SW846 EPA 7196A)

Default Detection Limits Client: Battelle Job ID: 180-152790-3 Project/Site: Shrewsberry NJ

Method: EPA 6020B - Metals (ICP/MS) Prep: 3050B

3.0Aluminum mg/Kg

Analyte UnitsMDLRL

2.1

0.10Antimony mg/Kg0.053

0.050Arsenic mg/Kg0.029

0.50Barium mg/Kg0.31

0.050Beryllium mg/Kg0.036

0.050Cadmium mg/Kg0.028

0.10Chromium mg/Kg0.089

0.025Cobalt mg/Kg0.018

0.15Copper mg/Kg0.10

0.050Lead mg/Kg0.033

0.25Manganese mg/Kg0.22

0.050Nickel mg/Kg0.047

0.25Selenium mg/Kg0.061

0.050Silver mg/Kg0.014

0.050Vanadium mg/Kg0.047

0.75Zinc mg/Kg0.24

General Chemistry

500Cr (III) ug/Kg

Analyte UnitsMDLRL

General Chemistry Prep: 3060A

400Cr (VI) ug/Kg

Analyte UnitsMDLRL

QC Sample Results

Project/Site: Shrewsberry NJ

Method: EPA 6020B - Metals (ICP/MS)

Client Sample ID: Method BlankLab Sample ID: MB 180-433890/1-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 434332 Prep Batch: 433890

RL MDL

Aluminum 6.0 U 6.0 4.2 mg/Kg 05/01/23 12:40 05/04/23 17:37 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

0.10 U 0.0580.10 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Arsenic

1.0 U 0.611.0 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Barium

0.10 U 0.0720.10 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Beryllium

0.10 U 0.0560.10 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Cadmium

0.20 U 0.180.20 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Chromium

0.30 U 0.210.30 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Copper

0.20 U 0.110.20 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Antimony

0.10 U 0.0660.10 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Lead

0.50 U 0.430.50 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Manganese

0.10 U 0.0940.10 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Nickel

0.50 U 0.120.50 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Selenium

2.70 0.481.5 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Zinc

0.050 U 0.0360.050 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Cobalt

0.10 U 0.0940.10 mg/Kg 05/01/23 12:40 05/04/23 17:37 1Vanadium

Client Sample ID: Method BlankLab Sample ID: MB 180-433890/1-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 434437 Prep Batch: 433890

RL MDL

Silver 0.10 U 0.10 0.028 mg/Kg 05/01/23 12:40 05/05/23 18:40 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

Client Sample ID: Lab Control SampleLab Sample ID: LCS 180-433890/2-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 434332 Prep Batch: 433890

Aluminum 500 492 mg/Kg 98 80 - 120

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec

Limits

Arsenic 100 96.9 mg/Kg 97 80 - 120

Barium 100 102 mg/Kg 102 80 - 120

Beryllium 50.0 50.6 mg/Kg 101 80 - 120

Cadmium 50.0 50.1 mg/Kg 100 80 - 120

Chromium 50.0 51.2 mg/Kg 102 80 - 120

Copper 50.0 47.3 mg/Kg 95 80 - 120

Antimony 25.0 27.0 mg/Kg 108 80 - 120

Lead 50.0 51.5 mg/Kg 103 80 - 120

Manganese 50.0 51.2 mg/Kg 102 80 - 120

Nickel 50.0 48.4 mg/Kg 97 80 - 120

Selenium 100 98.1 mg/Kg 98 80 - 120

Zinc 25.0 25.9 mg/Kg 104 80 - 120

Cobalt 50.0 47.9 mg/Kg 96 80 - 120

Vanadium 50.0 51.0 mg/Kg 102 80 - 120

Project/Site: Shrewsberry NJ

Method: EPA 6020B - Metals (ICP/MS) (Continued)

Client Sample ID: Lab Control SampleLab Sample ID: LCS 180-433890/2-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 434437 Prep Batch: 433890

Silver 25.0 25.7 mg/Kg 103 80 - 120

Analyte

LCS LCS

DUnitResult Qualifier %Rec

Spike

Added

%Rec

Limits

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 MS Matrix: Sediment Prep Type: Total/NA Analysis Batch: 434332 Prep Batch: 433890

Aluminum 18000 1330 23300 4 mg/Kg 422 75 - 125☼

Analyte

MS MS

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec

Limits

Arsenic 29 266 299 mg/Kg 102 75 - 125☼

Barium 61 266 336 mg/Kg 104 75 - 125☼

Beryllium 1.3 133 127 mg/Kg 95 75 - 125☼

Cadmium 2.1 133 136 mg/Kg 100 75 - 125☼

Chromium 110 133 255 mg/Kg 107 75 - 125☼

Copper 120 133 282 mg/Kg 120 75 - 125☼

Antimony 0.90 F1 66.5 26.0 F1 mg/Kg 38 75 - 125☼

Lead 210 133 363 mg/Kg 117 75 - 125☼

Manganese 220 133 365 mg/Kg 108 75 - 125☼

Nickel 30 133 166 mg/Kg 102 75 - 125☼

Selenium 1.6 266 245 mg/Kg 91 75 - 125☼

Zinc 500 B 66.5 598 4 mg/Kg 153 75 - 125☼

Cobalt 9.6 133 142 mg/Kg 99 75 - 125☼

Vanadium 67 133 201 mg/Kg 101 75 - 125☼

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 MS Matrix: Sediment Prep Type: Total/NA Analysis Batch: 434437 Prep Batch: 433890

Silver 0.84 66.5 59.2 mg/Kg 88 75 - 125☼

Analyte

MS MS

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec

Limits

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 MSD Matrix: Sediment Prep Type: Total/NA Analysis Batch: 434332 Prep Batch: 433890

Aluminum 18000 1330 21400 4 mg/Kg 277 75 - 125 9 20☼

Analyte

MSD MSD

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec

Limits LimitRPD

RPD

Arsenic 29 266 284 mg/Kg 96 75 - 125 5 20☼

Barium 61 266 314 mg/Kg 95 75 - 125 7 20☼

Beryllium 1.3 133 120 mg/Kg 89 75 - 125 6 20☼

Cadmium 2.1 133 129 mg/Kg 95 75 - 125 5 20☼

Chromium 110 133 242 mg/Kg 98 75 - 125 5 20☼

Copper 120 133 250 mg/Kg 96 75 - 125 12 20☼

Antimony 0.90 F1 66.5 26.2 F1 mg/Kg 38 75 - 125 1 20☼

Lead 210 133 345 mg/Kg 103 75 - 125 5 20☼

Manganese 220 133 331 mg/Kg 82 75 - 125 10 20☼

Nickel 30 133 157 mg/Kg 95 75 - 125 6 20☼

Selenium 1.6 266 230 mg/Kg 86 75 - 125 6 20☼

Zinc 500 B 66.5 542 4 mg/Kg 68 75 - 125 10 20☼

Cobalt 9.6 133 133 mg/Kg 93 75 - 125 6 20☼

Project/Site: Shrewsberry NJ

Method: EPA 6020B - Metals (ICP/MS) (Continued)

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 MSD Matrix: Sediment Prep Type: Total/NA Analysis Batch: 434332 Prep Batch: 433890

Vanadium 67 133 189 mg/Kg 92 75 - 125 6 20☼

Analyte

MSD MSD

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec

Limits LimitRPD

RPD

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 MSD Matrix: Sediment Prep Type: Total/NA Analysis Batch: 434437 Prep Batch: 433890

Silver 0.84 66.5 58.9 mg/Kg 87 75 - 125 0 20☼

Analyte

MSD MSD

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec

Limits LimitRPD

RPD

Method: EPA 7196A - Chromium, Hexavalent

Client Sample ID: Method BlankLab Sample ID: MB 180-428416/1-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428416

RL MDL

Cr (VI) 400 U 400 210 ug/Kg 03/07/23 15:28 03/09/23 11:52 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

Client Sample ID: Lab Control SampleLab Sample ID: LCSI 180-428416/3-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428416

Cr (VI) 708000 674000 ug/Kg 95 80 - 120

Analyte

LCSI LCSI

DUnitResult Qualifier %Rec

Spike

Added

%Rec

Limits

Client Sample ID: Lab Control SampleLab Sample ID: LCSS 180-428416/2-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428416

Cr (VI) 20000 21400 ug/Kg 107 80 - 120

Analyte

LCSS LCSS

DUnitResult Qualifier %Rec

Spike

Added

%Rec

Limits

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 MSI Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428416

Cr (VI) 1100 U F1 1940000 258000 F1 ug/Kg 13 75 - 125☼

Analyte

MSI MSI

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec

Limits

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 MSS Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428416

Cr (VI) 1100 U F1 55100 1100 U F1 ug/Kg -1 75 - 125☼

Analyte

MSS MSS

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec

Limits

Project/Site: Shrewsberry NJ

Method: EPA 7196A - Chromium, Hexavalent (Continued)

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 DU Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428416

Cr (VI) 1100 U F1 1100 U ug/Kg NC 20☼

Analyte

DU DU

DUnitResult Qualifier

Sample

Result

Sample

Qualifier LimitRPD

RPD

Client Sample ID: Method BlankLab Sample ID: MB 180-428417/1-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428417

RL MDL

Cr (VI) 400 U 400 210 ug/Kg 03/07/23 15:29 03/09/23 12:23 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

Client Sample ID: Lab Control SampleLab Sample ID: LCSI 180-428417/3-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428417

Cr (VI) 708000 675000 ug/Kg 95 80 - 120

Analyte

LCSI LCSI

DUnitResult Qualifier %Rec

Spike

Added

%Rec

Limits

Client Sample ID: Lab Control SampleLab Sample ID: LCSS 180-428417/2-A Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428417

Cr (VI) 20000 21700 ug/Kg 109 80 - 120

Analyte

LCSS LCSS

DUnitResult Qualifier %Rec

Spike

Added

%Rec

Limits

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 MSI Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428417

Cr (VI) 1100 U F1 1950000 115000 F1 ug/Kg 6 75 - 125☼

Analyte

MSI MSI

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec

Limits

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 MSS Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428417

Cr (VI) 1100 U F1 55100 1100 U F1 ug/Kg -0.6 75 - 125☼

Analyte

MSS MSS

DUnitResult Qualifier %Rec

Spike

Added

Sample

Result

Sample

Qualifier

%Rec

Limits

Client Sample ID: #20230099 AMENDED COMPOSITE 3Lab Sample ID: 180-152790-2 DU Matrix: Sediment Prep Type: Total/NA Analysis Batch: 428700 Prep Batch: 428417

Cr (VI) 1100 U F1 1100 U ug/Kg NC 20☼

Analyte

DU DU

DUnitResult Qualifier

Sample

Result

Sample

Qualifier LimitRPD

RPD

QC Association Summary

Project/Site: Shrewsberry NJ

Metals

Prep Batch: 433890

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 3050B180-152790-1 #20230095 COMPOSITE 3 Total/NA

Sediment 3050B180-152790-2 #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment 3050BMB 180-433890/1-A Method Blank Total/NA

Sediment 3050BLCS 180-433890/2-A Lab Control Sample Total/NA

Sediment 3050B180-152790-2 MS #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment 3050B180-152790-2 MSD #20230099 AMENDED COMPOSITE 3 Total/NA

Analysis Batch: 434332

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment EPA 6020B 433890180-152790-1 #20230095 COMPOSITE 3 Total/NA

Sediment EPA 6020B 433890180-152790-2 #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 6020B 433890MB 180-433890/1-A Method Blank Total/NA

Sediment EPA 6020B 433890LCS 180-433890/2-A Lab Control Sample Total/NA

Sediment EPA 6020B 433890180-152790-2 MS #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 6020B 433890180-152790-2 MSD #20230099 AMENDED COMPOSITE 3 Total/NA

Analysis Batch: 434437

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment EPA 6020B 433890180-152790-1 #20230095 COMPOSITE 3 Total/NA

Sediment EPA 6020B 433890180-152790-2 #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 6020B 433890MB 180-433890/1-A Method Blank Total/NA

Sediment EPA 6020B 433890LCS 180-433890/2-A Lab Control Sample Total/NA

Sediment EPA 6020B 433890180-152790-2 MS #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 6020B 433890180-152790-2 MSD #20230099 AMENDED COMPOSITE 3 Total/NA

General Chemistry

Prep Batch: 428416

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 3060A180-152790-1 #20230095 COMPOSITE 3 Total/NA

Sediment 3060A180-152790-2 #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment 3060AMB 180-428416/1-A Method Blank Total/NA

Sediment 3060ALCSI 180-428416/3-A Lab Control Sample Total/NA

Sediment 3060ALCSS 180-428416/2-A Lab Control Sample Total/NA

Sediment 3060A180-152790-2 MSI #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment 3060A180-152790-2 MSS #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment 3060A180-152790-2 DU #20230099 AMENDED COMPOSITE 3 Total/NA

Prep Batch: 428417

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 3060A180-152790-2 #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment 3060AMB 180-428417/1-A Method Blank Total/NA

Sediment 3060ALCSI 180-428417/3-A Lab Control Sample Total/NA

Sediment 3060ALCSS 180-428417/2-A Lab Control Sample Total/NA

Sediment 3060A180-152790-2 MSI #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment 3060A180-152790-2 MSS #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment 3060A180-152790-2 DU #20230099 AMENDED COMPOSITE 3 Total/NA

Analysis Batch: 428700

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment EPA 7196A 428416180-152790-1 #20230095 COMPOSITE 3 Total/NA

QC Association Summary

Project/Site: Shrewsberry NJ

General Chemistry (Continued)

Analysis Batch: 428700 (Continued)

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment EPA 7196A 428416180-152790-2 #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 7196A 428417180-152790-2 #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 7196A 428416MB 180-428416/1-A Method Blank Total/NA

Sediment EPA 7196A 428417MB 180-428417/1-A Method Blank Total/NA

Sediment EPA 7196A 428416LCSI 180-428416/3-A Lab Control Sample Total/NA

Sediment EPA 7196A 428417LCSI 180-428417/3-A Lab Control Sample Total/NA

Sediment EPA 7196A 428416LCSS 180-428416/2-A Lab Control Sample Total/NA

Sediment EPA 7196A 428417LCSS 180-428417/2-A Lab Control Sample Total/NA

Sediment EPA 7196A 428416180-152790-2 MSI #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 7196A 428417180-152790-2 MSI #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 7196A 428416180-152790-2 MSS #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 7196A 428417180-152790-2 MSS #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 7196A 428416180-152790-2 DU #20230099 AMENDED COMPOSITE 3 Total/NA

Sediment EPA 7196A 428417180-152790-2 DU #20230099 AMENDED COMPOSITE 3 Total/NA

Analysis Batch: 430518

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Sediment 7196A180-152790-1 #20230095 COMPOSITE 3 Total/NA

Sediment 7196A180-152790-2 #20230099 AMENDED COMPOSITE 3 Total/NA

Lab Chronicle

Project/Site: Shrewsberry NJ

Client Sample ID: #20230095 COMPOSITE 3 Lab Sample ID: 180-152790-1 Matrix: SedimentDate Collected: 02/27/23 10:19

Date Received: 03/01/23 12:07

Analysis 7196A RJR03/28/23 06:211 EET PIT430518

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA

Instrument ID: NOEQUIP

Client Sample ID: #20230095 COMPOSITE 3 Lab Sample ID: 180-152790-1 Matrix: SedimentDate Collected: 02/27/23 10:19

Percent Solids: 28.0Date Received: 03/01/23 12:07

Prep 3050B HCY05/01/23 12:40 EET PIT433890

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 0.63 g 50 mL

Analysis EPA 6020B 1 434332 05/04/23 18:03 RJR EET PITTotal/NA

DORYInstrument ID:

Prep 3050B 433890 05/01/23 12:40 HCY EET PITTotal/NA 0.63 g 50 mL

Analysis EPA 6020B 1 434437 05/05/23 19:06 RJR EET PITTotal/NA

DORYInstrument ID:

Prep 3060A 428416 03/07/23 15:28 BAC EET PITTotal/NA 2.49 g 100 mL

Analysis EPA 7196A 5 428700 03/09/23 12:01 BAC EET PITTotal/NA 4 mL 4 mL

RAPID-TInstrument ID:

Client Sample ID: #20230099 AMENDED COMPOSITE 3 Lab Sample ID: 180-152790-2 Matrix: SedimentDate Collected: 02/27/23 10:19

Date Received: 03/01/23 12:07

Analysis 7196A RJR03/28/23 06:211 EET PIT430518

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA

Instrument ID: NOEQUIP

Client Sample ID: #20230099 AMENDED COMPOSITE 3 Lab Sample ID: 180-152790-2 Matrix: SedimentDate Collected: 02/27/23 10:19

Percent Solids: 36.9Date Received: 03/01/23 12:07

Prep 3050B HCY05/01/23 12:40 EET PIT433890

Type

Batch

Method

Batch

Prep Type LabAnalystRun

Prepared or Analyzed

Initial

Amount Amount

Final Batch

NumberFactor

Dil

Total/NA 0.50 g 50 mL

Analysis EPA 6020B 1 434332 05/04/23 17:44 RJR EET PITTotal/NA

DORYInstrument ID:

Prep 3050B 433890 05/01/23 12:40 HCY EET PITTotal/NA 0.50 g 50 mL

Analysis EPA 6020B 1 434437 05/05/23 18:47 RJR EET PITTotal/NA

DORYInstrument ID:

Prep 3060A 428416 03/07/23 15:28 BAC EET PITTotal/NA 2.48 g 100 mL

Analysis EPA 7196A 1 428700 03/09/23 11:55 BAC EET PITTotal/NA 4 mL 4 mL

RAPID-TInstrument ID:

Prep 3060A 428417 03/07/23 15:29 BAC EET PITTotal/NA 2.48 g 100 mL

Analysis EPA 7196A 1 428700 03/09/23 12:27 BAC EET PITTotal/NA 4 mL 4 mL

RAPID-TInstrument ID:

Laboratory References:

EET PIT = Eurofins Pittsburgh, 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238, TEL (412)963-7058

Lab Chronicle

Project/Site: Shrewsberry NJ

Analyst References:

Lab: EET PIT

Batch Type: Prep

BAC = Blase Cindric

HCY = Harrison Yaeger

Batch Type: Analysis

BAC = Blase Cindric

RJR = Ron Rosenbaum

Accreditation/Certification Summary

Project/Site: Shrewsberry NJ

Laboratory: Eurofins Pittsburgh Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.

Authority Program Identification Number Expiration Date

New Jersey NELAP PA005 06-30-23

The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte

7196A Sediment Cr (III)

New York NELAP 11182 04-01-24

The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification.

Analysis Method Prep Method Matrix Analyte

7196A Sediment Cr (III)

Method Summary

Project/Site: Shrewsberry NJ

Method Method Description LaboratoryProtocol

SW846EPA 6020B Metals (ICP/MS) EET PIT

SW8467196A Chromium, Trivalent (Colorimetric) EET PIT

SW846EPA 7196A Chromium, Hexavalent EET PIT

SW8463050B Preparation, Metals EET PIT

SW8463060A Alkaline Digestion (Chromium, Hexavalent) EET PIT

Protocol References:

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

EET PIT = Eurofins Pittsburgh, 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238, TEL (412)963-7058

Sample Summary

Project/Site: Shrewsberry NJ

Lab Sample ID Client Sample ID Matrix Collected Received

180-152790-1 #20230095 COMPOSITE 3 Sediment 02/27/23 10:19 03/01/23 12:07

180-152790-2 #20230099 AMENDED COMPOSITE 3 Sediment 02/27/23 10:19 03/01/23 12:07

REAGENT TRACEABILITY SUMMARY

Lab Name:

SDG No.:

Job No.: 180-152790-3Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

04/06/24 (Purchased Reagent) Aluminum 1000 mg/LInorganic Ventures, Lot U2-MEB731627EUROPITTSP-1_00003 Arsenic 200 mg/L Barium 200 mg/L Beryllium 100 mg/L Cadmium 100 mg/L Chromium 100 mg/L Cobalt 100 mg/L Copper 100 mg/L Lead 100 mg/L Manganese 100 mg/L Nickel 100 mg/L Selenium 200 mg/L Silver 50 mg/L Vanadium 100 mg/L Zinc 50 mg/L

04/06/24 (Purchased Reagent) Aluminum 1000 mg/LInorganic Ventures, Lot U2-MEB731627EUROPITTSP-1_00004 Arsenic 200 mg/L B 250 mg/L Barium 200 mg/L Beryllium 100 mg/L Ca 5000 mg/L Cadmium 100 mg/L Chromium 100 mg/L Cobalt 100 mg/L Copper 100 mg/L Fe 1000 mg/L K 5000 mg/L Lead 100 mg/L Li 100 mg/L Manganese 100 mg/L Mg 5000 mg/L Na 5000 mg/L Nickel 100 mg/L P 100 mg/L Selenium 200 mg/L Silver 50 mg/L Sr 100 mg/L Tl 200 mg/L Vanadium 100 mg/L Zinc 50 mg/L

04/06/24 (Purchased Reagent) Antimony 50 ug/mLInorganic Ventures, Lot U2-MEB731628EUROPITTSP-2_00003

04/06/24 (Purchased Reagent) Antimony 50 ug/mLInorganic Ventures, Lot U2-MEB731628EUROPITTSP-2_00004 Mo 100 ug/mL Si 200 ug/mL SiO2 428 ug/mL Sn 200 ug/mL

SDG No.:

Job No.: 180-152790-3Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

Ti 100 ug/mL

04/06/24 (Purchased Reagent) Th 5 ug/mLInorganic Ventures, Lot U2-MEB731629EUROPITTSP-3_00002 U 5 ug/mL

TA-CAL1_00010 Antimony 0.2 ppm1000 mL 2 mL06/28/23 05/01/23MCCV2 uthp_00028 2% Nitric Acid, Lot 5125799

Arsenic 0.2 ppm Barium 0.2 ppm Beryllium 0.2 ppm Cadmium 0.2 ppm Chromium 0.2 ppm Cobalt 0.2 ppm Copper 0.2 ppm Lead 0.2 ppm Manganese 0.2 ppm Nickel 0.2 ppm Selenium 0.2 ppm Vanadium 0.2 ppm Aluminum 50 ppmTA-CAL2_00012 25 mL Silver 0.1 ppmTA-CAL3 REV2_00005 2 mL Zinc 0.1 ppm

07/29/24 (Purchased Reagent) Antimony 100 ppmCPI International, Lot 1321095-1.TA-CAL1_00010 Arsenic 100 ppm Barium 100 ppm Beryllium 100 ppm Cadmium 100 ppm Chromium 100 ppm Cobalt 100 ppm Copper 100 ppm Lead 100 ppm Manganese 100 ppm Nickel 100 ppm Selenium 100 ppm Vanadium 100 ppm

09/24/24 (Purchased Reagent) Aluminum 2000 ppmCPI International, Lot 1274823-1.TA-CAL2_00012 08/30/24 (Purchased Reagent) Silver 50 mg/LCPI International, Lot 1344455.TA-CAL3 REV2_00005

Zinc 50 mg/L

MUICPMS-CRI-1_00003 Aluminum 0.03 ppm500 mL 2 mL06/23/23 04/05/23MCRIX A_uthp_00032 2% Nitric Acid, Lot 5125799

Arsenic 0.001 ppm Barium 0.01 ppm Beryllium 0.001 ppm Cadmium 0.001 ppm Chromium 0.002 ppm Cobalt 0.0005 ppm Copper 0.002 ppm Lead 0.001 ppm Manganese 0.005 ppm

SDG No.:

Job No.: 180-152790-3Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

Nickel 0.001 ppm Selenium 0.005 ppm Silver 0.001 ppm Vanadium 0.001 ppm Zinc 0.005 ppm

MUICPMS-CRI-2_00004 2 mL Antimony 0.002 ppm 04/30/24 (Purchased Reagent) Aluminum 7.5 ppmCPI INTERNATIONAL, Lot 1299722.MUICPMS-CRI-1_00003

Arsenic 0.25 ppm Barium 2.5 ppm Beryllium 0.25 ppm Cadmium 0.25 ppm Chromium 0.5 ppm Cobalt 0.125 ppm Copper 0.5 ppm Lead 0.25 ppm Manganese 1.25 ppm Nickel 0.25 ppm Selenium 1.25 ppm Silver 0.25 ppm Vanadium 0.25 ppm Zinc 1.25 ppm

04/30/24 (Purchased Reagent) Antimony 0.5 ppmCPI INT., Lot 1299723.MUICPMS-CRI-2_00004

M6020ICSA-MIX_00010 Aluminum 100 ppm250 mL 25 mL06/28/23 04/04/23MICSAB A_uthp_00042 2% Nitric Acid, Lot 5125799

Ca 100 ppm Fe 100 ppm K 100 ppm Mg 100 ppm Mo 2 ppm Na 100 ppm P 100 ppm Ti 2 ppm Arsenic 0.02 ppmMICSAB-1_00003 2.5 mL Cadmium 0.02 ppm Chromium 0.02 ppm Cobalt 0.02 ppm Copper 0.02 ppm Manganese 0.022 ppm Nickel 0.02 ppm Silver 0.02 ppm Zinc 0.022 ppm Antimony 0.022 ppmMICSAB-2_00015 0.5 mL B 0.05 ppm Barium 0.028 ppm Beryllium 0.02 ppm Lead 0.02 ppm Li 0.02 ppm Selenium 0.05 ppm

SDG No.:

Job No.: 180-152790-3Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

Si 0.5 ppm Sn 0.1 ppm Sr 0.02 ppm Tl 0.02 ppm U 0.02 ppm Vanadium 0.02 ppm

MICSAB-3_00002 0.5 mL Th 0.02 ppm 04/30/24 (Purchased Reagent) Aluminum 1000 ppmCPI INT., Lot 1267033-1.M6020ICSA-MIX_00010

Ca 1000 ppm Fe 1000 ppm K 1000 ppm Mg 1000 ppm Mo 20 ppm Na 1000 ppm P 1000 ppm Ti 20 ppm

01/29/24 (Purchased Reagent) Arsenic 2 ug/mLCPI, Lot 1275484.MICSAB-1_00003 Cadmium 2 ug/mL Chromium 2 ug/mL Cobalt 2 ug/mL Copper 2 ug/mL Manganese 2.2 ug/mL Nickel 2 ug/mL Silver 2 ug/mL Zinc 2.2 ug/mL

04/30/24 (Purchased Reagent) Antimony 11 ppmCPI, Lot 1299720.MICSAB-2_00015 B 25 ppm Barium 14 ppm Beryllium 10 ppm Lead 10 ppm Li 10 ppm Selenium 25 ppm Si 250 ppm Sn 50 ppm Sr 10 ppm Tl 10 ppm U 10 ppm Vanadium 10 ppm

09/30/23 (Purchased Reagent) Th 10 ppmCPI, Lot 12133297.MICSAB-3_00002

M6020ICSA-MIX_00010 Aluminum 100 ppm250 mL 25 mL07/05/23 04/05/23MICSAX_00227 2% Nitric Acid, Lot 5125799

Ca 100 ppm Fe 100 ppm K 100 ppm Mg 100 ppm Mo 2 ppm Na 100 ppm P 100 ppm

SDG No.:

Job No.: 180-152790-3Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

Ti 2 ppm 04/30/24 (Purchased Reagent) Aluminum 1000 ppmCPI INT., Lot 1267033-1.M6020ICSA-MIX_00010

Ca 1000 ppm Fe 1000 ppm K 1000 ppm Mg 1000 ppm Mo 20 ppm Na 1000 ppm P 1000 ppm Ti 20 ppm

MICPMSICV_00031 Aluminum 0.4 mg/L250 mg/L 10 mg/L06/28/23 04/05/23MICVX A_uthp_00023 2% Nitric Acid, Lot 5125799

Antimony 0.08 mg/L Arsenic 0.08 mg/L Barium 0.08 mg/L Beryllium 0.08 mg/L Cadmium 0.08 mg/L Chromium 0.08 mg/L Cobalt 0.08 mg/L Copper 0.08 mg/L Lead 0.08 mg/L Manganese 0.4 mg/L Nickel 0.08 mg/L Selenium 0.08 mg/L Silver 0.08 mg/L Vanadium 0.08 mg/L Zinc 0.08 mg/L

11/30/23 (Purchased Reagent) Aluminum 10 ppmCPI International, Lot 220504.MICPMSICV_00031 Antimony 2 ppm Arsenic 2 ppm Barium 2 ppm Beryllium 2 ppm Cadmium 2 ppm Chromium 2 ppm Cobalt 2 ppm Copper 2 ppm Lead 2 ppm Manganese 10 ppm Nickel 2 ppm Selenium 2 ppm Silver 2 ppm Vanadium 2 ppm Zinc 2 ppm

TA-CAL2_00010 Aluminum 100 ppm250 mL 12.5 mL06/28/23 04/05/23MSTD2X_uthp_00023 2% Nitric Acid, Lot 5125796

Silver 0.2 ppmTA-CAL3 REV2_00003 1 mL Zinc 0.2 ppm

SDG No.:

Job No.: 180-152790-3Eurofins Pittsburgh

Reagent ID Exp Date Date

Prep Dilutant Used

Reagent Final Volume

Parent Reagent

Reagent ID Volume Added ConcentrationAnalyte

11/30/23 (Purchased Reagent) Aluminum 2000 ppmCPI International, Lot 1208136-1.TA-CAL2_00010 12/31/23 (Purchased Reagent) Silver 50 mg/LCPI International, Lot 10103959-3.TA-CAL3 REV2_00003

Zinc 50 mg/L

TA-CAL1_00010 Antimony 0.4 ppm250 mL 1 mL07/05/23 04/05/23MSTD3X A New_00062 2% Nitric Acid, Lot 5125799

Arsenic 0.4 ppm Barium 0.4 ppm Beryllium 0.4 ppm Cadmium 0.4 ppm Chromium 0.4 ppm Cobalt 0.4 ppm Copper 0.4 ppm Lead 0.4 ppm Manganese 0.4 ppm Nickel 0.4 ppm Selenium 0.4 ppm Vanadium 0.4 ppm

07/29/24 (Purchased Reagent) Antimony 100 ppmCPI International, Lot 1321095-1.TA-CAL1_00010 Arsenic 100 ppm Barium 100 ppm Beryllium 100 ppm Cadmium 100 ppm Chromium 100 ppm Cobalt 100 ppm Copper 100 ppm Lead 100 ppm Manganese 100 ppm Nickel 100 ppm Selenium 100 ppm Vanadium 100 ppm

10/31/24 (Purchased Reagent) Cr (VI) 0.160909 g/gSigma Aldrich, Lot BCBZ6842WCr6InsolSP_00004 Lead (II) Chromate 1 g/g

WCR+6 1000 P_00028 Cr (VI) 49.9976 mg/L200 mL 10 mL05/01/23 11/01/22WCr6S50SP_00090 DI Water, Lot NA Potassium Dichromate 49.9976 mg/L

WK2CrO7P_00018 Cr (VI) 999.953 mg/L250 mL 0.7072 g05/01/23 11/01/22.WCR+6 1000 P_00028 DI Water, Lot NA Potassium Dichromate 999.953 mg/L

10/31/23 (Purchased Reagent) Cr (VI) 0.35349 g/gSTREM CHEMICALS, Lot 35854200..WK2CrO7P_00018 Potassium Dichromate 0.35349 g/g

03/14/23 03/07/23 50 mL WCR+6 1000 P_00028 0.025 mL Cr (VI) 0.499976 mg/LWCRTCR6CCV_00062 05/01/23 11/01/22 250 mL WK2CrO7P_00018 0.7072 g Cr (VI) 999.953 mg/L.WCR+6 1000 P_00028 DI Water, Lot NA 10/31/23 (Purchased Reagent) Cr (VI) 0.35349 g/gSTREM CHEMICALS, Lot 35854200..WK2CrO7P_00018

03/14/23 03/07/23 50 mL WCr1000S_00012 0.025 mL Cr (VI) 0.5 mg/LWCRTCR6ICV_00067 0.25 N H2SO4, Lot 4791891

02/20/24 (Purchased Reagent) Cr (VI) 1000 ppmLabChem, Inc., Lot M032-21.WCr1000S_00012

Reagent

EUROPITTSP-1_00003

1.0 ACCREDITATION / REGISTRATION

INORGANIC VENTURES is accredited to ISO 17034, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General

Requirements for the Competence of Testing and Calibration Laboratories".

Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate

Number QSR-1034).

Testing Laboratory

Certificate 883.01

Reference Material Producer

Certificate 883.02

2.0 PRODUCT DESCRIPTION

Product Code: Multi Analyte Custom Grade Solution

Catalog Number: EUROPITTSP-1

Lot Number: U2-MEB731627

Matrix: 5% (v/v) HNO3

5 000 µg/mL ea:

Calcium, Potassium, Sodium, Magnesium, 1 000 µg/mL ea:

Iron, Aluminum, 250 µg/mL ea:

Boron, 200 µg/mL ea:

Barium, Arsenic, Selenium, Thallium, 100 µg/mL ea:

Vanadium, Strontium, Manganese, Beryllium, Cadmium, Cobalt, Chromium, Copper, Lithium, Nickel, Phosphorus, Lead, 50 µg/mL ea:

Silver, Zinc

Value / Analyte(s):

3.0 CERTIFIED VALUES AND UNCERTAINTIES

ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE

Aluminum, Al 1 000 ± 4 µg/mL Arsenic, As 200.0 ± 1.0 µg/mL

Barium, Ba 200.0 ± 0.9 µg/mL Beryllium, Be 100.0 ± 0.5 µg/mL

Boron, B 250.0 ± 1.5 µg/mL Cadmium, Cd 100.0 ± 0.4 µg/mL

Calcium, Ca 5 000 ± 16 µg/mL Chromium, Cr 100.0 ± 0.6 µg/mL

Cobalt, Co 100.0 ± 0.4 µg/mL Copper, Cu 100.0 ± 0.4 µg/mL

Iron, Fe 1 000 ± 4 µg/mL Lead, Pb 100.0 ± 0.4 µg/mL

Lithium, Li 100.0 ± 0.4 µg/mL Magnesium, Mg 5 000 ± 22 µg/mL

Manganese, Mn 100.0 ± 0.4 µg/mL Nickel, Ni 100.0 ± 0.4 µg/mL

Phosphorus, P 100.0 ± 0.4 µg/mL Potassium, K 5 000 ± 22 µg/mL

Selenium, Se 200.0 ± 1.4 µg/mL Silver, Ag 49.99 ± 0.22 µg/mL

Sodium, Na 5 000 ± 22 µg/mL Strontium, Sr 100.0 ± 0.4 µg/mL

Thallium, Tl 200.0 ± 1.1 µg/mL Vanadium, V 100.0 ± 0.4 µg/mL

Zinc, Zn 49.99 ± 0.22 µg/mL

Density: 1.101 g/mL (measured at 20 ± 4 ºC)

Assay Information:

METHOD NIST SRM# SRM LOT#ANALYTE

3151ICP Assay 160729Ag

999cVolhard 999cAg

Calculated See Sec. 4.2Ag

3101aICP Assay 140903Al

928EDTA 928Al

3103aICP Assay 100818As

Calculated See Sec. 4.2As

3107ICP Assay 190605B

3104aICP Assay 140909Ba

3105aICP Assay 090514Be

Calculated See Sec. 4.2Be

3109aICP Assay 130213Ca

928EDTA 928Ca

3108ICP Assay 130116Cd

928EDTA 928Cd

Calculated See Sec. 4.2Cd

3113ICP Assay 190630Co

928EDTA 928Co

Calculated See Sec. 4.2Co

3112aICP Assay 170630Cr

3114ICP Assay 120618Cu

928EDTA 928Cu

3126aICP Assay 140812Fe

928EDTA 928Fe

3141aICP Assay 140813K

Gravimetric See Sec. 4.2K

3129aICP Assay 100714Li

Calculated See Sec. 4.2Li

Gravimetric See Sec. 4.2Li

3131aICP Assay 140110Mg

928EDTA 928Mg

3132ICP Assay 050429Mn

928EDTA 928Mn

Traceable to 3152AICP Assay S2-NA700842Na

Gravimetric See Sec. 4.2Na

3136ICP Assay 120619Ni

928EDTA 928Ni

Calculated See Sec. 4.2Ni

3139aICP Assay 060717P

84LAcidimetric 84LP

Calculated See Sec. 4.2P

3128ICP Assay 101026Pb

928EDTA 928Pb

Calculated See Sec. 4.2Pb

3149ICP Assay 100901Se

928EDTA 928Sr

Traceable to 3153aICP Assay K2-SR650985Sr

Calculated See Sec. 4.2Sr

3158ICP Assay 151215Tl

Calculated See Sec. 4.2Tl

3165ICP Assay 160906V

928EDTA 928V

3168aICP Assay 120629Zn

928EDTA 928Zn

The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.

4.0 TRACEABILITY TO NIST

- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is specified.

4.1 Thermometer Calibration

- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights used for testing are annually compared to master weights and are traceable to NIST.

4.2 Balance Calibration

- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration laboratory.

4.3 Glassware Calibration

- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality control of CRM/RMs.

TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (µg/mL)5.0

N/A

INTENDED USE6.0

6.1 This standard is intended for the calibration of analytical instruments and validation of analytical methods as appropriate. This CRM may be used in connection with EPA Methods 6010, 6020 (all versions), Standard

Methods 3120 B and USP <232> / ICH Q3D.

6.2 For products attaining traceability through Inorganic Ventures’ Primary Certified Reference Materials (PCRM™) see the Limited License to Use PCRM™ in the Inorganic Ventures Terms and Conditions of Sale, https://www.inorganicventures.com/terms-and-conditions-sale. The Terms and Conditions contain information on the use of materials traceable to PCRM™ certified reference materials. This Limited License agreement is especially pertinent for laboratories accredited under ISO:17034.

INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL7.0

7.1 Storage and Handling Recommendations

www.inorganicventures.com/TCT- For more information, visit

- Store between approximately 4° - 30° C while in sealed TCT bag.

- While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is the responsibility of the user to account for this effect. When the bottle is weighed both before and after being placed in storage, the mass difference observed will be a measure of transpiration mass loss.

- After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4° - 24° C to minimize the effects of transpiration. Use at 20° ± 4° C to minimize volumetric dilution error when using the reported density. Do not pipette from the container. Do not return removed aliquots to container.

HAZARDOUS INFORMATION 8.0

- Please refer to the Safety Data Sheet for information regarding this CRM/RM.

HOMOGENEITY9.0

- This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous.

Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure homogeneity.

QUALITY STANDARD DOCUMENTATION10.0

10.1 ISO 9001 Quality Management System Registration

- QSR Certificate Number QSR-1034

- Chemical Testing - Accredited / A2LA Certificate Number 883.01

10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories"

- Reference Material Producer - Accredited / A2LA Certificate Number 883.02

10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers"

Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: 800.669.6799; 540.585.3030, Fax: 540.585.3012; inorganicventures.com;

info@inorganicventures.com

CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY11.0

11.1 Certification Issue Date

11.2 Lot Expiration Date

- The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1 are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified.

March 30, 2023

- The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by transpiration (loss of water from the solution) and infrequently by chemical stability.

- March 30, 2028

- The date after which this CRM/RM should not be used.

11.3 Period of Validity

- This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1.

- Sealed TCT Bag Open Date: __________________________

12.0 NAMES AND SIGNATURES OF CERTIFYING OFFICERS

Certificate Approved By:

Paul Gaines

Chairman / Senior Technical Director

Certifying Officer:

Thomas Kozikowski

Manager, Quality Control

EUROPITTSP-2_00003

the Competence of Reference Material Producers" and ISO/IEC 17025, "General

Requirements for the Competence of Testing and Calibration Laboratories".

Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate

Number QSR-1034).

Testing Laboratory

Certificate 883.01

Reference Material Producer

Certificate 883.02

2.0 PRODUCT DESCRIPTION

Product Code: Multi Analyte Custom Grade Solution

Catalog Number: EUROPITTSP-2

Lot Number: U2-MEB731628

Matrix: 5% (v/v) HNO3

tr. HF

200 µg/mL ea:

Silicon, Tin, 100 µg/mL ea:

Titanium, Molybdenum, 50 µg/mL ea:

Antimony

Value / Analyte(s):

3.0 CERTIFIED VALUES AND UNCERTAINTIES

ANALYTE CERTIFIED VALUE ANALYTE CERTIFIED VALUE

Antimony, Sb 50.01 ± 0.37 µg/mL Molybdenum, Mo 100.0 ± 0.6 µg/mL

Silicon, Si 200.0 ± 1.3 µg/mL Tin, Sn 200.0 ± 1.0 µg/mL

Titanium, Ti 100.0 ± 0.7 µg/mL

Density: 1.026 g/mL (measured at 20 ± 4 ºC)

Assay Information:

METHOD NIST SRM# SRM LOT#ANALYTE

3134ICP Assay 130418Mo

3102aICP Assay 140911Sb

Traceable to 3150ICP Assay S2-SI702546Si

3161aICP Assay 140917Sn

3162aICP Assay 130925Ti

The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2.

4.0 TRACEABILITY TO NIST

- This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is specified.

4.1 Thermometer Calibration

- All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights used for testing are annually compared to master weights and are traceable to NIST.

4.2 Balance Calibration

- All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration laboratory.

4.3 Glassware Calibration

- An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality control of CRM/RMs.

TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (µg/mL)5.0

N/A

INTENDED USE6.0

6.1 This standard is intended for the calibration of analytical instruments and validation of analytical methods as appropriate.