J152564-1 Std_Tal_L4 Final Report_Part6.pdf

Report Date: 10-Mar-2023 09:44:46 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Eurofins Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230309-46992.b\0309230000020.D

Injection Date: 09-Mar-2023 17:26:35 Instrument ID: CGC1 Operator ID:

Lims ID: LCSD 180-427988/3-A Worklist Smp#: 18

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 20.0000 ALS Bottle#: 18

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: RTX-50 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0309230000020.D

D a la p o n

.1

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9

M

C P

P

.1

D ic a m b a

.2

P

A

.6 ic h lo rp ro p

.9

,4 -D

.3

P e n ta c h lo ro p h e n o l(

.9

S ilv e x

,4

,5 -T

P

.0

,5

-T

.6

D in o s e b

.8

-D

B

.0

Column: RTX-1701 ( 0.53 mm)

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0309230000020.D

a la p o n

.3

,4 -D ic h lo ro p h e n y la c e ti c a c id

.9 a m b a

.1

M

C P

P

.3

P

A

.6 h lo rp ro p

.0

-D

.4

P e n ta c h lo ro p h e n o l(

.6 ilv e x

,4

,5 -T

P

.1

,5

-T

.6

-D

B

.0 in o s e b

.7

Report Date: 10-Mar-2023 09:44:46 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Recovery Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20230309-46992.b\0309230000020.D

Lims ID: LCSD 180-427988/3-A

Client ID:

Sample Type: LCSD

Inject. Date: 09-Mar-2023 17:26:35 ALS Bottle#: 18 Worklist Smp#: 18

Injection Vol: 1.0 ul Dil. Factor: 20.0000

Sample Info: 180-0046992-018

Operator ID: Instrument ID: CGC1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20230309-46992.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 10-Mar-2023 09:44:28 Calib Date: 01-Mar-2023 10:49:06

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20230301-46862.b\0301230000009.D

Column 1 : RTX-50 ( 0.53 mm) Det: GC ECD1A

Column 2 : RTX-1701 ( 0.53 mm) Det: GC ECD2B

Process Host: CTX1617

First Level Reviewer: WB9V Date: 10-Mar-2023 09:42:59

Surrogate Recovery, Detector: GC ECD1A

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 1.00 0.0352 70.46

Surrogate Recovery, Detector: GC ECD2B

Compound Amount Added

Amount Recovered % Rec.

$ 2 2,4-Dichlorophenylacetic acid 1.00 0.0365 72.95

Lab Name: Job No.:

SDG No.:

Instrument ID:

Analysis Batch Number:

HERBICIDES ANALYSIS RUN LOG

DILUTION

FACTOR

COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID

Eurofins Pittsburgh 180-152564-1

CGC1

427726

Start Date:

End Date: 03/01/2023 22:53

03/01/2023 08:51

IC 180-427726/1 RTX-50 0.53(mm)103/01/2023 08:51 0301230000003.D

IC 180-427726/1 RTX-1701 0.53(mm)103/01/2023 08:51 0301230000003.D

IC 180-427726/2 RTX-50 0.53(mm)103/01/2023 09:11 0301230000004.D

IC 180-427726/2 RTX-1701 0.53(mm)103/01/2023 09:11 0301230000004.D

IC 180-427726/3 RTX-50 0.53(mm)103/01/2023 09:30 0301230000005.D

IC 180-427726/3 RTX-1701 0.53(mm)103/01/2023 09:30 0301230000005.D

ICRT 180-427726/4 RTX-50 0.53(mm)103/01/2023 09:50 0301230000006.D

ICRT 180-427726/4 RTX-1701 0.53(mm)103/01/2023 09:50 0301230000006.D

IC 180-427726/5 RTX-50 0.53(mm)103/01/2023 10:09 0301230000007.D

IC 180-427726/5 RTX-1701 0.53(mm)103/01/2023 10:09 0301230000007.D

IC 180-427726/6 RTX-50 0.53(mm)103/01/2023 10:29 0301230000008.D

IC 180-427726/6 RTX-1701 0.53(mm)103/01/2023 10:29 0301230000008.D

IC 180-427726/7 RTX-50 0.53(mm)103/01/2023 10:49 0301230000009.D

IC 180-427726/7 RTX-1701 0.53(mm)103/01/2023 10:49 0301230000009.D

ICV 180-427726/8 RTX-50 0.53(mm)103/01/2023 11:08 0301230000010.D

ICV 180-427726/8 RTX-1701 0.53(mm)103/01/2023 11:08 0301230000010.D

ZZZZZ RTX-50 0.53(mm)103/01/2023 11:28

ZZZZZ RTX-1701 0.53(mm)103/01/2023 11:28

ZZZZZ RTX-50 0.53(mm)103/01/2023 11:47

ZZZZZ RTX-1701 0.53(mm)103/01/2023 11:47

ZZZZZ RTX-50 0.53(mm)2003/01/2023 12:07

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 12:07

ZZZZZ RTX-50 0.53(mm)2003/01/2023 12:26

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 12:26

ZZZZZ RTX-50 0.53(mm)2003/01/2023 12:46

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 12:46

ZZZZZ RTX-50 0.53(mm)2003/01/2023 13:06

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 13:06

ZZZZZ RTX-50 0.53(mm)2003/01/2023 13:25

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 13:25

ZZZZZ RTX-50 0.53(mm)2003/01/2023 13:45

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 13:45

ZZZZZ RTX-50 0.53(mm)2003/01/2023 14:04

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 14:04

ZZZZZ RTX-50 0.53(mm)2003/01/2023 14:24

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 14:24

CCV 180-427726/19 RTX-50 0.53(mm)103/01/2023 14:43

CCV 180-427726/19 RTX-1701 0.53(mm)103/01/2023 14:43

ZZZZZ RTX-50 0.53(mm)2003/01/2023 15:03

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 15:03

ZZZZZ RTX-50 0.53(mm)2003/01/2023 15:23

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 15:23

ZZZZZ RTX-50 0.53(mm)2003/01/2023 15:42

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 15:42

ZZZZZ RTX-50 0.53(mm)2003/01/2023 16:02

EPA 8151A

Instrument ID:

Analysis Batch Number:

HERBICIDES ANALYSIS RUN LOG

DILUTION

FACTOR

COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID

Eurofins Pittsburgh 180-152564-1

CGC1

427726

Start Date:

End Date: 03/01/2023 22:53

03/01/2023 08:51

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 16:02

ZZZZZ RTX-50 0.53(mm)2003/01/2023 16:21

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 16:21

ZZZZZ RTX-50 0.53(mm)2003/01/2023 16:41

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 16:41

ZZZZZ RTX-50 0.53(mm)2003/01/2023 17:00

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 17:00

ZZZZZ RTX-50 0.53(mm)2003/01/2023 17:20

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 17:20

ZZZZZ RTX-50 0.53(mm)2003/01/2023 17:40

ZZZZZ RTX-1701 0.53(mm)2003/01/2023 17:40

CCV 180-427726/29 RTX-50 0.53(mm)103/01/2023 17:59

CCV 180-427726/29 RTX-1701 0.53(mm)103/01/2023 17:59

ZZZZZ RTX-50 0.53(mm)4003/01/2023 18:19

ZZZZZ RTX-1701 0.53(mm)4003/01/2023 18:19

ZZZZZ RTX-50 0.53(mm)4003/01/2023 18:38

ZZZZZ RTX-1701 0.53(mm)4003/01/2023 18:38

ZZZZZ RTX-50 0.53(mm)4003/01/2023 18:58

ZZZZZ RTX-1701 0.53(mm)4003/01/2023 18:58

ZZZZZ RTX-50 0.53(mm)4003/01/2023 19:17

ZZZZZ RTX-1701 0.53(mm)4003/01/2023 19:17

ZZZZZ RTX-50 0.53(mm)4003/01/2023 19:37

ZZZZZ RTX-1701 0.53(mm)4003/01/2023 19:37

ZZZZZ RTX-50 0.53(mm)4003/01/2023 19:57

ZZZZZ RTX-1701 0.53(mm)4003/01/2023 19:57

ZZZZZ RTX-50 0.53(mm)4003/01/2023 20:16

ZZZZZ RTX-1701 0.53(mm)4003/01/2023 20:16

ZZZZZ RTX-50 0.53(mm)103/01/2023 20:36

ZZZZZ RTX-1701 0.53(mm)103/01/2023 20:36

ZZZZZ RTX-50 0.53(mm)103/01/2023 20:55

ZZZZZ RTX-1701 0.53(mm)103/01/2023 20:55

ZZZZZ RTX-50 0.53(mm)103/01/2023 21:15

ZZZZZ RTX-1701 0.53(mm)103/01/2023 21:15

CCV 180-427726/40 RTX-50 0.53(mm)103/01/2023 21:35

CCV 180-427726/40 RTX-1701 0.53(mm)103/01/2023 21:35

ZZZZZ RTX-50 0.53(mm)103/01/2023 21:54

ZZZZZ RTX-1701 0.53(mm)103/01/2023 21:54

ZZZZZ RTX-50 0.53(mm)103/01/2023 22:14

ZZZZZ RTX-1701 0.53(mm)103/01/2023 22:14

CCV 180-427726/43 RTX-50 0.53(mm)103/01/2023 22:33

CCV 180-427726/43 RTX-1701 0.53(mm)103/01/2023 22:33

CCVL 180-427726/44 RTX-50 0.53(mm)103/01/2023 22:53

CCVL 180-427726/44 RTX-1701 0.53(mm)103/01/2023 22:53

Instrument ID:

Analysis Batch Number:

HERBICIDES ANALYSIS RUN LOG

DILUTION

FACTOR

COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID

Eurofins Pittsburgh 180-152564-1

CGC1

428666

Start Date:

End Date: 03/09/2023 18:05

03/09/2023 11:54

CCVRT 180-428666/1 RTX-50 0.53(mm)103/09/2023 11:54 0309230000003.D

CCVRT 180-428666/1 RTX-1701 0.53(mm)103/09/2023 11:54 0309230000003.D

ZZZZZ RTX-50 0.53(mm)103/09/2023 12:13

ZZZZZ RTX-1701 0.53(mm)103/09/2023 12:13

ZZZZZ RTX-50 0.53(mm)103/09/2023 12:33

ZZZZZ RTX-1701 0.53(mm)103/09/2023 12:33

ZZZZZ RTX-50 0.53(mm)103/09/2023 12:52

ZZZZZ RTX-1701 0.53(mm)103/09/2023 12:52

ZZZZZ RTX-50 0.53(mm)103/09/2023 13:12

ZZZZZ RTX-1701 0.53(mm)103/09/2023 13:12

ZZZZZ RTX-50 0.53(mm)103/09/2023 13:31

ZZZZZ RTX-1701 0.53(mm)103/09/2023 13:31

ZZZZZ RTX-50 0.53(mm)103/09/2023 13:51

ZZZZZ RTX-1701 0.53(mm)103/09/2023 13:51

ZZZZZ RTX-50 0.53(mm)103/09/2023 14:11

ZZZZZ RTX-1701 0.53(mm)103/09/2023 14:11

ZZZZZ RTX-50 0.53(mm)103/09/2023 14:30

ZZZZZ RTX-1701 0.53(mm)103/09/2023 14:30

CCV 180-428666/10 RTX-50 0.53(mm)103/09/2023 14:50 0309230000012.D

CCV 180-428666/10 RTX-1701 0.53(mm)103/09/2023 14:50 0309230000012.D

MB 180-427988/1-A RTX-50 0.53(mm)2003/09/2023 15:09 0309230000013.D

MB 180-427988/1-A RTX-1701 0.53(mm)2003/09/2023 15:09 0309230000013.D

LB 180-427647/1-D RTX-50 0.53(mm)2003/09/2023 15:29 0309230000014.D

LB 180-427647/1-D RTX-1701 0.53(mm)2003/09/2023 15:29 0309230000014.D

ZZZZZ RTX-50 0.53(mm)2003/09/2023 15:48

ZZZZZ RTX-1701 0.53(mm)2003/09/2023 15:48

180-152564-2 #20230098 AMENDED

COMP 2

RTX-50 0.53(mm)2003/09/2023 16:08 0309230000016.D

180-152564-2 #20230098 AMENDED

COMP 2

RTX-1701 0.53(mm)2003/09/2023 16:08 0309230000016.D

ZZZZZ RTX-50 0.53(mm)2003/09/2023 16:28

ZZZZZ RTX-1701 0.53(mm)2003/09/2023 16:28

ZZZZZ RTX-50 0.53(mm)2003/09/2023 16:47

ZZZZZ RTX-1701 0.53(mm)2003/09/2023 16:47

LCS 180-427988/2-A RTX-50 0.53(mm)2003/09/2023 17:07 0309230000019.D

LCS 180-427988/2-A RTX-1701 0.53(mm)2003/09/2023 17:07 0309230000019.D

LCSD 180-427988/3-A RTX-50 0.53(mm)2003/09/2023 17:26 0309230000020.D

LCSD 180-427988/3-A RTX-1701 0.53(mm)2003/09/2023 17:26 0309230000020.D

CCV 180-428666/19 RTX-50 0.53(mm)103/09/2023 17:46 0309230000021.D

CCV 180-428666/19 RTX-1701 0.53(mm)103/09/2023 17:46 0309230000021.D

CCVL 180-428666/20 RTX-50 0.53(mm)103/09/2023 18:05

CCVL 180-428666/20 RTX-1701 0.53(mm)103/09/2023 18:05

Instrument ID:

Analysis Batch Number:

HERBICIDES ANALYSIS RUN LOG

DILUTION

FACTOR

COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID

Eurofins Pittsburgh 180-152564-1

CGC1

428960

Start Date:

End Date: 03/13/2023 16:11

03/13/2023 10:39

CCVRT 180-428960/1 RTX-50 0.53(mm)103/13/2023 10:39 0313230000003.D

CCVRT 180-428960/1 RTX-1701 0.53(mm)103/13/2023 10:39 0313230000003.D

MB 180-428159/1-A RTX-50 0.53(mm)103/13/2023 10:59 0313230000004.D

MB 180-428159/1-A RTX-1701 0.53(mm)103/13/2023 10:59 0313230000004.D

180-152564-1 #20230094 COMPOSITE 2 RTX-50 0.53(mm)103/13/2023 11:18 0313230000005.D

180-152564-1 #20230094 COMPOSITE 2 RTX-1701 0.53(mm)103/13/2023 11:18 0313230000005.D

ZZZZZ RTX-50 0.53(mm)103/13/2023 11:38

ZZZZZ RTX-1701 0.53(mm)103/13/2023 11:38

ZZZZZ RTX-50 0.53(mm)103/13/2023 11:57

ZZZZZ RTX-1701 0.53(mm)103/13/2023 11:57

ZZZZZ RTX-50 0.53(mm)103/13/2023 12:17

ZZZZZ RTX-1701 0.53(mm)103/13/2023 12:17

ZZZZZ RTX-50 0.53(mm)103/13/2023 12:37

ZZZZZ RTX-1701 0.53(mm)103/13/2023 12:37

ZZZZZ RTX-50 0.53(mm)103/13/2023 12:56

ZZZZZ RTX-1701 0.53(mm)103/13/2023 12:56

ZZZZZ RTX-50 0.53(mm)103/13/2023 13:16

ZZZZZ RTX-1701 0.53(mm)103/13/2023 13:16

ZZZZZ RTX-50 0.53(mm)103/13/2023 13:35

ZZZZZ RTX-1701 0.53(mm)103/13/2023 13:35

LCS 180-428159/2-A RTX-50 0.53(mm)103/13/2023 13:55 0313230000013.D

LCS 180-428159/2-A RTX-1701 0.53(mm)103/13/2023 13:55 0313230000013.D

CCV 180-428960/12 RTX-50 0.53(mm)103/13/2023 14:14 0313230000014.D

CCV 180-428960/12 RTX-1701 0.53(mm)103/13/2023 14:14 0313230000014.D

ZZZZZ RTX-50 0.53(mm)4003/13/2023 14:34

ZZZZZ RTX-1701 0.53(mm)4003/13/2023 14:34

ZZZZZ RTX-50 0.53(mm)4003/13/2023 14:53

ZZZZZ RTX-1701 0.53(mm)4003/13/2023 14:53

ZZZZZ RTX-50 0.53(mm)4003/13/2023 15:13

ZZZZZ RTX-1701 0.53(mm)4003/13/2023 15:13

ZZZZZ RTX-50 0.53(mm)4003/13/2023 15:32

ZZZZZ RTX-1701 0.53(mm)4003/13/2023 15:32

CCV 180-428960/17 RTX-50 0.53(mm)103/13/2023 15:52

CCV 180-428960/17 RTX-1701 0.53(mm)103/13/2023 15:52

CCVL 180-428960/18 RTX-50 0.53(mm)103/13/2023 16:11

CCVL 180-428960/18 RTX-1701 0.53(mm)103/13/2023 16:11

Instrument ID:

Analysis Batch Number:

HERBICIDES ANALYSIS RUN LOG

DILUTION

FACTOR

COLUMN IDDATE ANALYZEDLAB SAMPLE ID CLIENT SAMPLE ID LAB FILE ID

Eurofins Pittsburgh 180-152564-1

CGC1

429231

Start Date:

End Date: 03/15/2023 16:39

03/15/2023 10:47

CCVRT 180-429231/1 RTX-50 0.53(mm)103/15/2023 10:47 0315230000003.D

CCVRT 180-429231/1 RTX-1701 0.53(mm)103/15/2023 10:47 0315230000003.D

ZZZZZ RTX-50 0.53(mm)103/15/2023 11:07

ZZZZZ RTX-1701 0.53(mm)103/15/2023 11:07

180-152564-2 #20230098 AMENDED

COMP 2

RTX-50 0.53(mm)103/15/2023 11:26 0315230000005.D

180-152564-2 #20230098 AMENDED

COMP 2

RTX-1701 0.53(mm)103/15/2023 11:26 0315230000005.D

ZZZZZ RTX-50 0.53(mm)103/15/2023 11:46

ZZZZZ RTX-1701 0.53(mm)103/15/2023 11:46

ZZZZZ RTX-50 0.53(mm)103/15/2023 12:05

ZZZZZ RTX-1701 0.53(mm)103/15/2023 12:05

ZZZZZ RTX-50 0.53(mm)103/15/2023 12:25

ZZZZZ RTX-1701 0.53(mm)103/15/2023 12:25

ZZZZZ RTX-50 0.53(mm)103/15/2023 12:44

ZZZZZ RTX-1701 0.53(mm)103/15/2023 12:44

ZZZZZ RTX-50 0.53(mm)103/15/2023 13:04

ZZZZZ RTX-1701 0.53(mm)103/15/2023 13:04

ZZZZZ RTX-50 0.53(mm)103/15/2023 13:23

ZZZZZ RTX-1701 0.53(mm)103/15/2023 13:23

ZZZZZ RTX-50 0.53(mm)103/15/2023 13:43

ZZZZZ RTX-1701 0.53(mm)103/15/2023 13:43

CCV 180-429231/11 RTX-50 0.53(mm)103/15/2023 14:02 0315230000013.D

CCV 180-429231/11 RTX-1701 0.53(mm)103/15/2023 14:02 0315230000013.D

ZZZZZ RTX-50 0.53(mm)2003/15/2023 14:22

ZZZZZ RTX-1701 0.53(mm)2003/15/2023 14:22

ZZZZZ RTX-50 0.53(mm)2003/15/2023 14:42

ZZZZZ RTX-1701 0.53(mm)2003/15/2023 14:42

ZZZZZ RTX-50 0.53(mm)2003/15/2023 15:01

ZZZZZ RTX-1701 0.53(mm)2003/15/2023 15:01

ZZZZZ RTX-50 0.53(mm)2003/15/2023 15:21

ZZZZZ RTX-1701 0.53(mm)2003/15/2023 15:21

ZZZZZ RTX-50 0.53(mm)2003/15/2023 15:40

ZZZZZ RTX-1701 0.53(mm)2003/15/2023 15:40

ZZZZZ RTX-50 0.53(mm)2003/15/2023 16:00

ZZZZZ RTX-1701 0.53(mm)2003/15/2023 16:00

CCV 180-429231/18 RTX-50 0.53(mm)103/15/2023 16:19

CCV 180-429231/18 RTX-1701 0.53(mm)103/15/2023 16:19

CCVL 180-429231/19 RTX-50 0.53(mm)103/15/2023 16:39

CCVL 180-429231/19 RTX-1701 0.53(mm)103/15/2023 16:39

HERBICIDES BATCH WORKSHEET

180-152564-1

Batch Number: Batch Analyst:Batch Start Date:

Batch End Date:

Catanzariti, Mathew J

03/15/23 11:20

02/28/23 16:30427647

Batch Method:

Eurofins Pittsburgh

EPA 1312

Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount FiltCompDate FiltCompTime LeachatepH ExtractFluid

100.00 g 2000 mL 3/1/23 2 hrs 4.21 SPLPE FluidEPA 1312, 8151A, EPA

8151A

LB 180-427647/1

#20230098

AMENDED COMP 2

100.36 g 2000 mL 3/1/23 2 hrs 11.84EPA 1312, 8151A, EPA

8151A

E180-152564-C-2

The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent.

Page 1 of 2EPA 8151A

HERBICIDES BATCH WORKSHEET

180-152564-1

Batch Number: Batch Analyst:Batch Start Date:

Batch End Date:

Catanzariti, Mathew J

03/15/23 11:20

02/28/23 16:30427647

Batch Method:

Eurofins Pittsburgh

EPA 1312

Batch Notes

First Start time 2/28/23 1830

First End time 3/1/23 1230

Uncorrected Minimum Temperature 21 Celsius

Minimum Temperature 21 Celsius

Uncorrected Maximum Temperature 24 Celsius

Maximum Temperature 24 Celsius

Rotator ID # 6

Tumbler Rotations per Minute 30

Balance ID AND SN14577823 pH Meter ID AccumeXL 150 XL94108693

Probe ID 13-620-285

Room Temperature Thermometer ID Fisher-160719405

SPLP Solution 1 ID 5264446 pH Meter Calibration Slope 99.5 / 98.3

SPLP Fluid pH 4.21 SU

Bottle Lot ID 2-1758-08BB pH Buffer 1 ID 4817262 pH 2.00 , 4817478 pH 13.00 pH Buffer 2 ID 48692489 pH 4.00 , 4817508 pH 7.00 (Second Source

/ LCS)

pH Buffer 3 ID 4538548 pH 7.00 pH Buffer 4 ID 4817477 pH 10.00

Filter Paper ID 17511962

Room Temperature during Rotation 23 Degrees C

Uncorrected Room Temperature 23 Degrees C

Analyst ID - Filtration CRT

Basis Basis Description

E SPLP East

The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent.

Page 2 of 2EPA 8151A

HERBICIDES BATCH WORKSHEET

180-152564-1

Batch Number: Batch Analyst:Batch Start Date:

Batch End Date:

Fenk, Courtney 103/01/23 08:51427726

Batch Method:

Eurofins Pittsburgh

EPA 8151A

Lab Sample ID Client Sample ID Method Chain Basis FinalAmount GCHERBCALSL1 00034

GCHERBCALSL2

00030

GCHERBCALSL3

00044

GCHERBCALSL4

00035

GCHERBCALSL5

00030

1 mLEPA 8151AIC 180-427726/1

1 mL 1 mLEPA 8151AIC 180-427726/2

1 mL 1 mLEPA 8151AIC 180-427726/3

1 mL 1 mLEPA 8151AICRT 180-427726/4

1 mL 1 mLEPA 8151AIC 180-427726/5

1 mL 1 mLEPA 8151AIC 180-427726/6

1 mLEPA 8151AIC 180-427726/7

1 mLEPA 8151AICV 180-427726/8

Lab Sample ID Client Sample ID Method Chain Basis GCHERBCALSL6 00018

GCHERBCALSL7

00024

GCHERBICVSTD

00027

1 mLEPA 8151AIC 180-427726/1

EPA 8151AIC 180-427726/2

EPA 8151AIC 180-427726/3

EPA 8151AICRT

180-427726/4

EPA 8151AIC 180-427726/5

EPA 8151AIC 180-427726/6

1 mLEPA 8151AIC 180-427726/7

1 mLEPA 8151AICV 180-427726/8

Batch Notes

Diluting Solvent ID 4742400

Basis Basis Description

The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent.

Page 1 of 1EPA 8151A

HERBICIDES BATCH WORKSHEET

180-152564-1

Batch Number: Batch Analyst:Batch Start Date:

Batch End Date:

Yushinski, Charles

03/09/23 08:28

03/03/23 06:04427988

Batch Method:

Eurofins Pittsburgh

8151A

Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount ReceivedpH FirstAdjustpH SecondAdjustpH Herb(RTS)spk 00014

1000 mL 10.0 mL 6 SU 12 SU 2 SU8151A, EPA 8151A

MB 180-427988/1

1000 mL 10.0 mL 6 SU 12 SU 2 SU 1 mL8151A, EPA 8151A

LCS

180-427988/2

1000 mL 10.0 mL 6 SU 12 SU 2 SU 1 mL8151A, EPA 8151A

LCSD

180-427988/3

1060 mL 10.0 mL 6 SU 12 SU 2 SU8151A, EPA 8151A

LB

180-427647/1-A

#20230098

AMENDED COMP 2

1060 mL 10.0 mL 12 SU 12 SU 2 SU8151A, EPA 8151A

E180-152564-C-2- A

Lab Sample ID Client Sample ID Method Chain Basis OPHERBRTSSURR 00015

AnalysisComment

1 mL Funnel 18151A, EPA 8151A

MB 180-427988/1

1 mL Funnel 28151A, EPA 8151A

LCS

180-427988/2

1 mL Funnel 38151A, EPA 8151A

LCSD

180-427988/3

1 mL Funnel 48151A, EPA 8151A

LB

180-427647/1-A

#20230098

AMENDED COMP 2

1 mL Funnel 58151A, EPA 8151A

E180-152564-C-2- A

The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent.

Page 1 of 2EPA 8151A

HERBICIDES BATCH WORKSHEET

180-152564-1

Batch Number: Batch Analyst:Batch Start Date:

Batch End Date:

Yushinski, Charles

03/09/23 08:28

03/03/23 06:04427988

Batch Method:

Eurofins Pittsburgh

8151A

Batch Notes

Sulfuric Acid Lot Number 5225500 pH Indicator ID Ph paper HC168773

Analyst ID - Extraction CBY

Analyst ID - Spike Analyst CBY

Sufficient Volume for Batch QC no

MeCL2 ID 5284168

NaCl ID 5230117

Base Used to Adjust pH ID 5073599

Acid Used for pH Adjustment ID 5225500

Diethyl Ether ID 5141657

Acidified Na2SO4 ID 4823845

Analyst ID - Concentration DD

Concentration 1 Equipment ID water bath 1

Concentration 1 Thermometer ID water bath 1

Concentration 1 Uncorrected Temperature 65 CF 0.0 Degrees C

Concentration 1 Corrected Temperature 65 Degrees C

Concentration 2 Equipment ID 1

Concentration 2 Thermometer ID 1

Concentration 2 Uncorrected Temperature 21 CF 1.0 Degrees C

Concentration 2 Corrected Temperature 22 Degrees C

NaOH Start Time - 1 Hour 03/03/2023 06:04

NaOH End Time - 1 Hour 03/03/2023 08:04

TMSDM ID 4760266

Methylation Start Time - 1 Hour 03/09/2023 05:05

Methylation End Time - 1 Hour 03/09/2023 06:05

Silicic Acid ID 5034016

Hexane ID 5284165

Basis Basis Description

E SPLP East

The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent.

Page 2 of 2EPA 8151A

HERBICIDES BATCH WORKSHEET

180-152564-1

Batch Number: Batch Analyst:Batch Start Date:

Batch End Date:

Yushinski, Charles

03/13/23 09:15

03/06/23 00:45428159

Batch Method:

Eurofins Pittsburgh

8151A

Lab Sample ID Client Sample ID Method Chain Basis InitialAmount FinalAmount pHSoilLess2 FirstpHGreater1

SecondpHLess2 Herb(RTS)spk 00014

10.0 g 40.0 mL 2 12 28151A, EPA 8151A

MB 180-428159/1

10.0 g 40.0 mL 2 12 2 0.2 mL8151A, EPA 8151A

LCS

180-428159/2

#20230094

COMPOSITE 2

10.0 g 40.0 mL 2 12 28151A, EPA 8151A

T180-152564-D-1

#20230098

AMENDED COMP 2

10.0 g 40.0 mL 2 12 28151A, EPA 8151A

T180-152564-B-2

Lab Sample ID Client Sample ID Method Chain Basis OPHERBRTSSURR 00015

0.2 mL8151A, EPA 8151A

MB 180-428159/1

0.2 mL8151A, EPA 8151A

LCS

180-428159/2

#20230094

COMPOSITE 2

0.2 mL8151A, EPA 8151A

T180-152564-D-1

#20230098

AMENDED COMP 2

0.2 mL8151A, EPA 8151A

T180-152564-B-2

The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent.

Page 1 of 3EPA 8151A

HERBICIDES BATCH WORKSHEET

180-152564-1

Batch Number: Batch Analyst:Batch Start Date:

Batch End Date:

Yushinski, Charles

03/13/23 09:15

03/06/23 00:45428159

Batch Method:

Eurofins Pittsburgh

8151A

Batch Notes

Nominal Amount Used yes g

Sonicator ID# 1

Water Bath ID 2

Water Bath Temperature 65 CF 1.0 Degrees C

Uncorrected Temperature 66 Degrees C

Acidified NaSO4 Start Time - 2 Hour 03/06/2023 00:45

Acidified NaSO4 End Time - 2 Hour 03/06/2023 03:45

TMSDM ID 4760266

Methylation Start Time 03/13/2023 04:30

Methylation End Time 03/13/2023 05:30

1:1 Sulfuric + Water Lot ID 5225500

Acidic Sodium Sulfate ID 4823845

Diethyl Ether ID 5141660

Prep Solvent Volume Used 120

Vendor of Reagent used Fisher

Na2SO4 ID 5274896

Potassium Hydroxide ID 4570169

Sulfuric Acid Lot Number 5225500

Silicic Acid ID 5034016

Hexane ID 5284165

N-evap ID 1

N-evap Temperature 21 CF 1.0 Degrees C

N-evap Thermometer ID 1

Uncorrected N-evap Temperature 22 Degrees C

Sufficient volume for MS/MSD? yes

Balance ID T0358722 pH Paper ID Ph paper HC168773

MeCL2 ID 5284168

MeCl2 / Acetone ID 5228072

Filter Paper ID glass wool 16022999

The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent.

Page 2 of 3EPA 8151A

HERBICIDES BATCH WORKSHEET

180-152564-1

Batch Number: Batch Analyst:Batch Start Date:

Batch End Date:

Yushinski, Charles

03/13/23 09:15

03/06/23 00:45428159

Batch Method:

Eurofins Pittsburgh

8151A Vial Lot Number 0126501H

Hydrochloric Acid ID 5245183

Basis Basis Description

T Total/NA

The pound sign (#) in the amount added field denotes that the reagent was used undiluted. All calculations are performed using the stated concentration for this reagent.

Page 3 of 3EPA 8151A

Method 9056A Anions, Ion Chromatography by Method

9056A

HPLC/IC LAB CONTROL SAMPLE RECOVERY

FORM III

Job No.:Lab Name: 180-152564-1Eurofins Pittsburgh

SDG No.:

Level:Matrix: Low Lab File ID: 03-03-20237.dWater

Lab ID: LCS 180-428036/7 Client ID:

REC

REC

QC

LIMITSCONCENTRATION

(mg/L)

SPIKE

ADDED

(mg/L)

LCS LCS

COMPOUND

Chloride 50.0 48.4 80-12097

FORM III EPA 9056A

# Column to be used to flag recovery and RPD values

HPLC/IC LAB CONTROL SAMPLE RECOVERY

FORM III

Job No.:Lab Name: 180-152564-1Eurofins Pittsburgh

SDG No.:

Level:Matrix: Low Lab File ID: 03-03-202337.dWater

Lab ID: LCS 180-428036/37 Client ID:

REC

REC

QC

LIMITSCONCENTRATION

(mg/L)

SPIKE

ADDED

(mg/L)

LCS LCS

COMPOUND

Chloride 50.0 49.0 80-12098

FORM III EPA 9056A

# Column to be used to flag recovery and RPD values

FORM IV

HPLC/IC METHOD BLANK SUMMARY

Lab Name: Job No.: 180-152564-1Eurofins Pittsburgh

SDG No.:

Instrument ID:

Level:(Low/Med)

Date Extracted:

Date Analyzed: 03/03/2023 12:05

Low

INTEGRION

Lab File ID: 03-03-20236.d Lab Sample ID: MB 180-428036/6

Matrix: Water

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES:

LAB SAMPLE ID

LAB

FILE ID DATE ANALYZEDCLIENT SAMPLE ID

03/03/2023 12:2303-03-20237

.d

LCS 180-428036/7

03/04/2023 04:2403-03-20235 9.d

LB 180-427647/1-A

FORM IV EPA 9056A

FORM IV

HPLC/IC METHOD BLANK SUMMARY

Lab Name: Job No.: 180-152564-1Eurofins Pittsburgh

SDG No.:

Instrument ID:

Level:(Low/Med)

Date Extracted:

Date Analyzed: 03/03/2023 21:20

Low

INTEGRION

Lab File ID: 03-03-202336.d Lab Sample ID: MB 180-428036/36

Matrix: Water

THIS METHOD BLANK APPLIES TO THE FOLLOWING SAMPLES:

LAB SAMPLE ID

LAB

FILE ID DATE ANALYZEDCLIENT SAMPLE ID

03/03/2023 21:3803-03-20233

7.d

LCS 180-428036/37

03/04/2023 07:2903-03-20236 9.d

180-152564-2#20230098 AMENDED COMP 2

FORM IV EPA 9056A

FORM I

HPLC/IC ORGANICS ANALYSIS DATA SHEET

Lab Name: Job No.: 180-152564-1Eurofins Pittsburgh

SDG No.:

Client Sample ID: #20230098 AMENDED COMP 2 Lab Sample ID: 180-152564-2

Matrix: 03-03-202369.dLab File ID:

Date Collected:EPA 9056AAnalysis Method:

Sediment (SPLP East)

02/20/2023 09:46

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Extracted:

Date Analyzed:

Dilution Factor: 1

Extraction Method:

03/04/2023 07:29

1(mL)

1(uL)

Sample wt/vol: 1(mL)

% Moisture:

GC Column: ID:AS-18

N% Solids:

Cleanup Factor:

Analysis Batch No.: 428036 mg/LUnits:

CAS NO. COMPOUND NAME RESULT Q MDLRL

1.0 0.7116887-00-6 Chloride 340

FORM I EPA 9056A

Report Date: 04-Mar-2023 12:39:45 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230303-46900.b\03-03-202369.d

Lims ID: 180-152564-C-2-A

Client ID: #20230098 AMENDED COMP 2

Sample Type: Client

Inject. Date: 04-Mar-2023 07:29:00 ALS Bottle#: 0 Worklist Smp#: 69

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046900-069

Misc. Info.: 180-152564-C-2-A

Operator ID: Instrument ID: INTEGRION

Method: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230303-46900.b\300_9056_INTEGRION.m

Limit Group: GC Anions ICAL

Last Update: 04-Mar-2023 12:39:43 Calib Date: 28-Feb-2023 19:20:00

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL25.d

Column 1 : Det: 0008

Process Host: CTX1610

First Level Reviewer: KDC6 Date: 04-Mar-2023 12:35:53

Compound

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

OnCol Amt ug/ml Flags

2 Chloride 4.970 5.030 -0.060 10892893384 342.8

QC Flag Legend Processing Flags

Report Date: 04-Mar-2023 12:39:45 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230303-46900.b\03-03-202369.d

Injection Date: 04-Mar-2023 07:29:00 Instrument ID: INTEGRION Operator ID:

Lims ID: 180-152564-C-2-A Lab Sample ID: 180-152564-2 Worklist Smp#: 69

Client ID: #20230098 AMENDED COMP 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 0

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

-1

Y

X

03-03-202369, 03-03-202369.d h lo ri d e

.9

FORM VI

Calibration ID:

SDG No.:

Instrument ID: Heated Purge: (Y/N)

HPLC/IC BY EXTERNAL STANDARD - INITIAL CALIBRATION DATA

Eurofins Pittsburgh 180-152564-1

INTEGRION

Analy Batch No.: 427642

50399Calibration Start Date: Calibration End Date:02/28/2023 15:57

N

02/28/2023 19:20

GC Column: AS-18 ID:

RETENTION TIME SUMMARY

Calibration Files

LEVEL: LAB SAMPLE ID: LAB FILE ID:

Level 1 IC 180-427642/14 02-28-2023 ICAL14.d

Level 2 IC 180-427642/15 02-28-2023 ICAL15.d

Level 3 IC 180-427642/16 02-28-2023 ICAL16.d

Level 4 IC 180-427642/17 02-28-2023 ICAL17.d

Level 5 IC 180-427642/18 02-28-2023 ICAL18.d

Level 6 IC 180-427642/19 02-28-2023 ICAL19.d

Level 7 IC 180-427642/20 02-28-2023 ICAL20.d

Level 8 IC 180-427642/21 02-28-2023 ICAL21.d

Level 9 IC 180-427642/22 02-28-2023 ICAL22.d

Level 10 IC 180-427642/23 02-28-2023 ICAL23.d

Level 11 IC 180-427642/24 02-28-2023 ICAL24.d

Level 12 IC 180-427642/25 02-28-2023 ICAL25.d

ANALYTE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 LVL 8 LVL 9 LVL 10 AVG RTRT WINDOW

LVL 11 LVL 12

Fluoride 3.473 - 4.173 3.824+++++ 3.810 3.820 3.823 3.820 3.823 3.823 3.827 3.830 3.833

3.833 +++++

Chloride 4.680 - 5.380 5.008+++++ 5.037 5.033 5.030 5.027 5.017 5.010 5.003 4.993 4.990

4.973 4.973

Sulfate 6.643 - 7.343 6.773+++++ 7.060 7.020 6.993 6.950 6.883 6.837 6.797 6.720 6.660

6.417 6.170

Bromide 7.380 - 8.080 7.7037.733 7.737 7.737 7.730 7.720 7.697 7.680 7.663 7.633 +++++

FORM VI EPA 9056A Page 5346 of 6008

HPLC/IC BY EXTERNAL STANDARD - INITIAL CALIBRATION DATA

Eurofins Pittsburgh 180-152564-1 Analy Batch No.: 427642

CURVE EVALUATION

SDG No.:

Calibration ID:

Instrument ID: GC Column: Heated Purge: (Y/N)INTEGRION

50399Calibration Start Date: Calibration End Date:02/28/2023 15:57

N

02/28/2023 19:20

AS-18 ID:

Calibration Files

LEVEL: LAB SAMPLE ID: LAB FILE ID:

1Level IC 180-427642/14 02-28-2023 ICAL14.d 2Level IC 180-427642/15 02-28-2023 ICAL15.d 3Level IC 180-427642/16 02-28-2023 ICAL16.d 4Level IC 180-427642/17 02-28-2023 ICAL17.d 5Level IC 180-427642/18 02-28-2023 ICAL18.d 6Level IC 180-427642/19 02-28-2023 ICAL19.d 7Level IC 180-427642/20 02-28-2023 ICAL20.d 8Level IC 180-427642/21 02-28-2023 ICAL21.d 9Level IC 180-427642/22 02-28-2023 ICAL22.d 10Level IC 180-427642/23 02-28-2023 ICAL23.d 11Level IC 180-427642/24 02-28-2023 ICAL24.d 12Level IC 180-427642/25 02-28-2023 ICAL25.d

MIN R^2

OR COD

#R^2

OR COD

MAX

%RSD

#%RSD#COEFFICIENT

M2M1B

CURVE

TYPE

LVL 4LVL 3LVL 2LVL 1

CFANALYTE MIN CF

/RSE

/RSE

LVL 5 LVL 6 LVL 7 LVL 8

LVL 9 LVL 10 LVL 11 LVL 12

Fluoride Lin2 0.9950 0.9950+++++ 25342400 39328420 40296398 42561951 43904992 45864562 46723646 53504448 46982643 43387681 +++++

-1064208.

45784396.

Chloride Lin2 1.0000 0.9950+++++ 30247937 31387940 32054422 32349993 31693992 32042405 31873916 31850856 31719471 31210656 31055228

-1472554.

31778197.

Sulfate Lin2 0.9980 0.9950+++++ 16898026 19927014 19842536 21010389 21770404 22697144 22911325 23156587 23139188 22669511 22359632

-5765840.

22227278.

Bromide Lin2 0.9950 0.99501415950 1150805 1302042 1305318 1251771 1200321 1178462 1149810 1110485 +++++ +++++ +++++

16703.386

1197889.6

FORM VI EPA 9056A

Note: The M1 coefficient is the same as Ave CF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.

Calibration ID:

SDG No.:

Instrument ID: Heated Purge: (Y/N)

HPLC/IC BY EXTERNAL STANDARD - INITIAL CALIBRATION DATA

Eurofins Pittsburgh 180-152564-1

INTEGRION

Analy Batch No.: 427642

50399Calibration Start Date: Calibration End Date:02/28/2023 15:57

N

02/28/2023 19:20

GC Column: AS-18 ID:

RESPONSE AND CONCENTRATION

Calibration Files

LEVEL: LAB SAMPLE ID: LAB FILE ID:

Level 1 IC 180-427642/14 02-28-2023 ICAL14.d

Level 2 IC 180-427642/15 02-28-2023 ICAL15.d

Level 3 IC 180-427642/16 02-28-2023 ICAL16.d

Level 4 IC 180-427642/17 02-28-2023 ICAL17.d

Level 5 IC 180-427642/18 02-28-2023 ICAL18.d

Level 6 IC 180-427642/19 02-28-2023 ICAL19.d

Level 7 IC 180-427642/20 02-28-2023 ICAL20.d

Level 8 IC 180-427642/21 02-28-2023 ICAL21.d

Level 9 IC 180-427642/22 02-28-2023 ICAL22.d

Level 10 IC 180-427642/23 02-28-2023 ICAL23.d

Level 11 IC 180-427642/24 02-28-2023 ICAL24.d

Level 12 IC 180-427642/25 02-28-2023 ICAL25.d

CURVE

TYPE

RESPONSEANALYTE CONCENTRATION (UG/ML)

LVL 1 LVL 1LVL 2 LVL 2LVL 3 LVL 3LVL 4 LVL 4LVL 5 LVL 5

LVL 6 LVL 6LVL 7 LVL 7LVL 8 LVL 8LVL 9 LVL 9LVL 10 LVL 10

LVL 11 LVL 11LVL 12 LVL 12

Fluoride Lin2 +++++ 1267120 9832105 20148199 42561951 +++++ 0.0500 0.250 0.500 1.00

109762481 171992108 233618229 401283363 469826429 2.50 3.75 5.00 7.50 10.0

108469203

+++++ 25.0 +++++

Chloride Lin2 +++++ 30247937 156939700 320544216 646999859 +++++ 1.00 5.00 10.0 20.0

158469958

240318040

318739159

477762833

634389411

50.0 75.0 100 150 200

156053279

310552283

500 1000

Sulfate Lin2 +++++ 16898026 99635068 198425358 420207778 +++++ 1.00 5.00 10.0 20.0

108852019

170228576

229113254

347348805

462783768

50.0 75.0 100 150 200

113347554

223596319

500 1000

Bromide Lin2 141595 230161 1302042 2610636 5007083 0.100 0.200 1.00 2.00 4.00

12003208 17676930 22996208 33314556 +++++ 10.0 15.0 20.0 30.0 +++++

Curve Type Legend Lin2 = Linear 1/conc^2 by height

FORM VI EPA 9056A Page 5348 of 6008

Calibration ID:

SDG No.:

Instrument ID: GC Column: Heated Purge: (Y/N)

HPLC/IC BY EXTERNAL STANDARD - INITIAL CALIBRATION DATA

Eurofins Pittsburgh 180-152564-1

INTEGRION

Analy Batch No.: 427642

50399Calibration Start Date: Calibration End Date:02/28/2023 15:57

N

02/28/2023 19:20

AS-18 ID:

READBACK PERCENT ERROR

Calibration Files

LEVEL: LAB SAMPLE ID: LAB FILE ID:

1Level IC 180-427642/14 02-28-2023 ICAL14.d 2Level IC 180-427642/15 02-28-2023 ICAL15.d 3Level IC 180-427642/16 02-28-2023 ICAL16.d 4Level IC 180-427642/17 02-28-2023 ICAL17.d 5Level IC 180-427642/18 02-28-2023 ICAL18.d 6Level IC 180-427642/19 02-28-2023 ICAL19.d 7Level IC 180-427642/20 02-28-2023 ICAL20.d 8Level IC 180-427642/21 02-28-2023 ICAL21.d 9Level IC 180-427642/22 02-28-2023 ICAL22.d 10Level IC 180-427642/23 02-28-2023 ICAL23.d 11Level IC 180-427642/24 02-28-2023 ICAL24.d 12Level IC 180-427642/25 02-28-2023 ICAL25.d

ANALYTE PERCENT ERROR

LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 ##### LVL 6 # LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6

PERCENT ERROR LIMIT

LVL 11 LVL 12 ##LVL 7 LVL 8 LVL 9 LVL 10 #### LVL 7 LVL 8 LVL 9 LVL 10 LVL 11 LVL 12

Fluoride +++++ 1.8 -4.8 -7.3 -4.7 -3.2

0.8 2.5 17.2 2.8 -5.1 +++++

50 20 20 20 20 20 20 20 20 20

Chloride +++++ -0.2 -0.3 1.3 2.0 -0.2

0.9 0.3 0.3 -0.2 -1.8 -2.3

50 20 20 20 20 20 20 20 20 20 20

Sulfate +++++ 2.0 -5.2 -8.1 -4.2 -1.5

2.5 3.3 4.4 4.2 2.0 0.6

50 20 20 20 20 20 20 20 20 20 20

Bromide 4.3 -10.9 7.3 8.3 4.1 0.1 -1.7 -4.1 -7.3 +++++ +++++ +++++

50 20 20 20 20 20 20 20 20

FORM VI EPA 9056A Page 5349 of 6008

Report Date: 01-Mar-2023 08:39:42 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL14.d

Lims ID: ic

Client ID:

Sample Type: IC Calib Level: 1

Inject. Date: 28-Feb-2023 15:57:00 ALS Bottle#: 0 Worklist Smp#: 14

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046850-014

Misc. Info.: IC 1

Operator ID: Instrument ID: INTEGRION

Sublist: chrom-300_9056_INTEGRION*sub1

Method: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\300_9056_INTEGRION.m

Limit Group: GC Anions ICAL

Last Update: 01-Mar-2023 08:39:42 Calib Date: 28-Feb-2023 19:20:00

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL25.d

Column 1 : Det: 0008

Process Host: CTX1665

First Level Reviewer: EZ9C Date: 01-Mar-2023 08:13:55

Compound

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ug/ml

OnCol Amt ug/ml Flags

1 Fluoride 3.813 3.823 -0.010 1010172 0.0250 0.0453 M

2 Chloride 5.040 5.030 0.010 15169365 0.5000 0.5237

7 Nitrite as N 5.890 5.897 -0.007 900040 0.0250 0.0136 M

3 Sulfate 7.067 6.993 0.074 16276996 0.5000 0.99

4 Bromide 7.733 7.730 0.003 141595H 0.1000 0.1043

5 Nitrate as N 9.023 8.987 0.036 1530908 0.0250 0.0316

6 Orthophosphate as P 13.837 ND ND

QC Flag Legend Processing Flags

ND - Not Detected or Marked ND

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

ICSTDL1_00318 Amount Added: 1.00 Units: mL

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL14.d

Injection Date: 28-Feb-2023 15:57:00 Instrument ID: INTEGRION Operator ID:

Lims ID: ic Worklist Smp#: 14

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 0

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

-1

Y

X

02-28-2023 ICAL14, 02-28-2023 ICAL14.d

F lu o ri d e

.8 lo ri d e

.0

N it ri te a s N

.8 u lf a te

.0

B ro m id e

.7 ra te a s N

.0

Manual Integration/User Assign Peak Report

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL14.d

Injection Date: 28-Feb-2023 15:57:00 Instrument ID: INTEGRION

Lims ID: ic

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 14

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

1 Fluoride, CAS: 16984-48-8 Signal: 1

Processing Integration Results

RT: 3.81

Area: 1464450

Amount: 0.028838

Amount Units: ug/ml

3.3 3.5 3.7 3.9 4.1 4.3 4.5 Min

-16

-10

-4

Y

X

.8

Manual Integration Results

RT: 3.81

Area: 1010172

Amount: 0.045308

Amount Units: ug/ml

3.3 3.5 3.7 3.9 4.1 4.3 4.5 Min

RT

-16

-10

-4

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:12:31

Audit Action: Split an Integrated Peak Audit Reason: Incomplete Integration

Report Date: 01-Mar-2023 08:39:43 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL15.d

Lims ID: ic 2

Client ID:

Sample Type: IC Calib Level: 2

Inject. Date: 28-Feb-2023 16:16:00 ALS Bottle#: 0 Worklist Smp#: 15

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046850-015

Misc. Info.: IC 2

Operator ID: Instrument ID: INTEGRION

Sublist: chrom-300_9056_INTEGRION*sub1

Method: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\300_9056_INTEGRION.m

Limit Group: GC Anions ICAL

Last Update: 01-Mar-2023 08:39:43 Calib Date: 28-Feb-2023 19:20:00

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL25.d

Column 1 : Det: 0008

Process Host: CTX1665

First Level Reviewer: EZ9C Date: 01-Mar-2023 08:14:59

Compound

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ug/ml

OnCol Amt ug/ml Flags

1 Fluoride 3.810 3.823 -0.013 1267120 0.0500 0.0509 M

2 Chloride 5.037 5.030 0.007 30247937 1.00 1.00

7 Nitrite as N 5.893 5.897 -0.004 2277134 0.0500 0.0344 M

3 Sulfate 7.060 6.993 0.067 16898026 1.00 1.02

4 Bromide 7.737 7.730 0.007 230161H 0.2000 0.1782

5 Nitrate as N 9.020 8.987 0.033 3023244 0.0500 0.0497

6 Orthophosphate as P 13.837 ND ND

QC Flag Legend Processing Flags

ND - Not Detected or Marked ND

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

ICSTDL2_00746 Amount Added: 1.00 Units: mL

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL15.d

Injection Date: 28-Feb-2023 16:16:00 Instrument ID: INTEGRION Operator ID:

Lims ID: ic 2 Worklist Smp#: 15

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 0

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

-1

Y

X

02-28-2023 ICAL15, 02-28-2023 ICAL15.d o ri d e

.8 lo ri d e

.0 ri te a s N

.8 lf a te

.0 m id e

.7 ra te a s N

.0

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL15.d

Injection Date: 28-Feb-2023 16:16:00 Instrument ID: INTEGRION

Lims ID: ic 2

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 15

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

1 Fluoride, CAS: 16984-48-8 Signal: 1

Processing Integration Results

RT: 3.81

Area: 1750642

Amount: 0.043326

Amount Units: ug/ml

3.3 3.5 3.7 3.9 4.1 4.3 4.5 Min

-2

-1

Y

X

Manual Integration Results

RT: 3.81

Area: 1267120

Amount: 0.050920

Amount Units: ug/ml

3.3 3.5 3.7 3.9 4.1 4.3 4.5 Min

RT

-2

-1

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:14:12

Audit Action: Split an Integrated Peak Audit Reason: Incomplete Integration

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL16.d

Lims ID: ic 3

Client ID:

Sample Type: IC Calib Level: 3

Inject. Date: 28-Feb-2023 16:34:00 ALS Bottle#: 0 Worklist Smp#: 16

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046850-016

Misc. Info.: IC 3

Operator ID: Instrument ID: INTEGRION

Sublist: chrom-300_9056_INTEGRION*sub1

Method: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\300_9056_INTEGRION.m

Limit Group: GC Anions ICAL

Last Update: 01-Mar-2023 08:39:43 Calib Date: 28-Feb-2023 19:20:00

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL25.d

Column 1 : Det: 0008

Process Host: CTX1665

First Level Reviewer: EZ9C Date: 01-Mar-2023 08:15:57

Compound

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ug/ml

OnCol Amt ug/ml Flags

1 Fluoride 3.820 3.823 -0.003 9832105 0.2500 0.2380 M

2 Chloride 5.033 5.030 0.003 156939700 5.00 4.98 M

7 Nitrite as N 5.900 5.897 0.003 17329965 0.2500 0.2619 M

3 Sulfate 7.020 6.993 0.027 99635068 5.00 4.74 M

4 Bromide 7.737 7.730 0.007 1302042H 1.00 1.07 M

5 Nitrate as N 9.007 8.987 0.020 19909967 0.2500 0.2546 M

6 Orthophosphate as P 13.837 ND ND

QC Flag Legend Processing Flags

ND - Not Detected or Marked ND

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

ICSTDL3_00806 Amount Added: 1.00 Units: mL

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL16.d

Injection Date: 28-Feb-2023 16:34:00 Instrument ID: INTEGRION Operator ID:

Lims ID: ic 3 Worklist Smp#: 16

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 0

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

-1

Y

X

02-28-2023 ICAL16, 02-28-2023 ICAL16.d o ri d e

.8 lo ri d e

.0 ri te a s N

.9 lf a te

.0 m id e

.7 ra te a s N

.0

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL16.d

Injection Date: 28-Feb-2023 16:34:00 Instrument ID: INTEGRION

Lims ID: ic 3

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 16

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

1 Fluoride, CAS: 16984-48-8 Signal: 1

Processing Integration Results

RT: 3.82

Area: 10645222

Amount: 0.252038

Amount Units: ug/ml

3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 Min

-1

Y

X

Manual Integration Results

RT: 3.82

Area: 9832105

Amount: 0.237992

Amount Units: ug/ml

3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 Min

RT

-1

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:37:13

Audit Action: Assigned New Baseline Audit Reason: Incomplete Integration

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL16.d

Injection Date: 28-Feb-2023 16:34:00 Instrument ID: INTEGRION

Lims ID: ic 3

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 16

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

2 Chloride, CAS: 16887-00-6 Signal: 1

Processing Integration Results

RT: 5.03

Area: 158420196

Amount: 5.011548

Amount Units: ug/ml

4.5 4.7 4.9 5.1 5.3 5.5 5.7 5.9 Min

-1

Y

X

.0

Manual Integration Results

RT: 5.03

Area: 156939700

Amount: 4.984935

Amount Units: ug/ml

4.5 4.7 4.9 5.1 5.3 5.5 5.7 5.9 Min

RT

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:37:13

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL16.d

Injection Date: 28-Feb-2023 16:34:00 Instrument ID: INTEGRION

Lims ID: ic 3

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 16

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

3 Sulfate, CAS: 14808-79-8 Signal: 1

Processing Integration Results

RT: 7.02

Area: 102164109

Amount: 4.829933

Amount Units: ug/ml

6.4 6.6 6.8 7.0 7.2 7.4 7.6 7.8 Min

Y

X

Manual Integration Results

RT: 7.02

Area: 99635068

Amount: 4.741962

Amount Units: ug/ml

6.4 6.6 6.8 7.0 7.2 7.4 7.6 7.8 Min

RT

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:30:57

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL16.d

Injection Date: 28-Feb-2023 16:34:00 Instrument ID: INTEGRION

Lims ID: ic 3

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 16

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

4 Bromide, CAS: 24959-67-9 Signal: 1

Processing Integration Results

RT: 7.74

Height: 1350138

Amount: 1.113131

Amount Units: ug/ml

7.3 7.5 7.7 7.9 8.1 8.3 8.5 8.7 8.9 Min

Y

X

.7

Manual Integration Results

RT: 7.74

Height: 1302042

Amount: 1.073003

Amount Units: ug/ml

7.3 7.5 7.7 7.9 8.1 8.3 8.5 8.7 8.9 Min

RT

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:30:41

Report Date: 01-Mar-2023 08:39:44 Chrom Revision: 2.3 15-Feb-2023 20:44:50

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL17.d

Lims ID: ic 4

Client ID:

Sample Type: IC Calib Level: 4

Inject. Date: 28-Feb-2023 16:53:00 ALS Bottle#: 0 Worklist Smp#: 17

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046850-017

Misc. Info.: IC 4

Operator ID: Instrument ID: INTEGRION

Sublist: chrom-300_9056_INTEGRION*sub1

Method: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\300_9056_INTEGRION.m

Limit Group: GC Anions ICAL

Last Update: 01-Mar-2023 08:39:44 Calib Date: 28-Feb-2023 19:20:00

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL25.d

Column 1 : Det: 0008

Process Host: CTX1665

First Level Reviewer: EZ9C Date: 01-Mar-2023 08:16:20

Compound

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ug/ml

OnCol Amt ug/ml Flags

1 Fluoride 3.823 3.823 0.000 20148199 0.5000 0.4633 M

2 Chloride 5.030 5.030 0.000 320544216 10.0 10.1 M

7 Nitrite as N 5.897 5.897 0.000 35547139 0.5000 0.5372 M

3 Sulfate 6.993 6.993 0.000 198425358 10.0 9.19 M

4 Bromide 7.730 7.730 0.000 2610636H 2.00 2.17 M

5 Nitrate as N 8.987 8.987 0.000 41202517 0.5000 0.5131 M

6 Orthophosphate as P 13.837 13.837 0.000 29234H 0.5000 0.5691 Ma

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated a - User Assigned ID

Reagents:

ICSTDL4_00650 Amount Added: 1.00 Units: mL

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL17.d

Injection Date: 28-Feb-2023 16:53:00 Instrument ID: INTEGRION Operator ID:

Lims ID: ic 4 Worklist Smp#: 17

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 0

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

-1

Y

X

02-28-2023 ICAL17, 02-28-2023 ICAL17.d o ri d e

.8 lo ri d e

.0 ri te a s N

.8 lf a te

.9 m id e

.7 ra te a s N

.9

O rt h o p h o s p h a te a s P

.8

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL17.d

Injection Date: 28-Feb-2023 16:53:00 Instrument ID: INTEGRION

Lims ID: ic 4

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 17

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

1 Fluoride, CAS: 16984-48-8 Signal: 1

Processing Integration Results

RT: 3.82

Area: 21148315

Amount: 0.484835

Amount Units: ug/ml

3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 Min

-1

Y

X

Manual Integration Results

RT: 3.82

Area: 20148199

Amount: 0.463311

Amount Units: ug/ml

3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 Min

RT

-1

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:37:45

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL17.d

Injection Date: 28-Feb-2023 16:53:00 Instrument ID: INTEGRION

Lims ID: ic 4

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 17

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

2 Chloride, CAS: 16887-00-6 Signal: 1

Processing Integration Results

RT: 5.03

Area: 322434351

Amount: 10.181333

Amount Units: ug/ml

4.4 4.6 4.8 5.0 5.2 5.4 5.6 5.8 Min

-1

Y

X

Manual Integration Results

RT: 5.03

Area: 320544216

Amount: 10.133261

Amount Units: ug/ml

4.4 4.6 4.8 5.0 5.2 5.4 5.6 5.8 Min

RT

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:37:45

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL17.d

Injection Date: 28-Feb-2023 16:53:00 Instrument ID: INTEGRION

Lims ID: ic 4

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 17

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

3 Sulfate, CAS: 14808-79-8 Signal: 1

Processing Integration Results

RT: 6.99

Area: 202305029

Amount: 9.329795

Amount Units: ug/ml

6.4 6.6 6.8 7.0 7.2 7.4 7.6 7.8 Min

Y

X

Manual Integration Results

RT: 6.99

Area: 198425358

Amount: 9.186514

Amount Units: ug/ml

6.4 6.6 6.8 7.0 7.2 7.4 7.6 7.8 Min

RT

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:31:53

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL17.d

Injection Date: 28-Feb-2023 16:53:00 Instrument ID: INTEGRION

Lims ID: ic 4

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 17

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

4 Bromide, CAS: 24959-67-9 Signal: 1

Processing Integration Results

RT: 7.73

Height: 2686886

Amount: 2.239414

Amount Units: ug/ml

7.2 7.4 7.6 7.8 8.0 8.2 8.4 8.6 8.8 9.0 Min

Y

X

Manual Integration Results

RT: 7.73

Height: 2610636

Amount: 2.165419

Amount Units: ug/ml

7.2 7.4 7.6 7.8 8.0 8.2 8.4 8.6 8.8 9.0 Min

RT

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:31:49

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL18.d

Lims ID: ic 5

Client ID:

Sample Type: IC Calib Level: 5

Inject. Date: 28-Feb-2023 17:11:00 ALS Bottle#: 0 Worklist Smp#: 18

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0046850-018

Misc. Info.: IC 5

Operator ID: Instrument ID: INTEGRION

Sublist: chrom-300_9056_INTEGRION*sub1

Method: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\300_9056_INTEGRION.m

Limit Group: GC Anions ICAL

Last Update: 01-Mar-2023 08:39:42 Calib Date: 28-Feb-2023 19:20:00

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL25.d

Column 1 : Det: 0008

Process Host: CTX1665

First Level Reviewer: EZ9C Date: 01-Mar-2023 08:39:42

Compound

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ug/ml

OnCol Amt ug/ml Flags

1 Fluoride 3.820 3.823 -0.003 42561951 1.00 0.9529 M

2 Chloride 5.027 5.030 -0.003 646999859 20.0 20.4 M

7 Nitrite as N 5.897 5.897 0.000 71671370 1.00 1.08 M

3 Sulfate 6.950 6.993 -0.043 420207778 20.0 19.2 M

4 Bromide 7.720 7.730 -0.010 5007083H 4.00 4.17 M

5 Nitrate as N 8.960 8.987 -0.027 80519929 1.00 0.99 M

6 Orthophosphate as P 13.640 13.837 -0.197 103914H 1.00 0.8095 M

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

ICSTDL5_00627 Amount Added: 1.00 Units: mL

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL18.d

Injection Date: 28-Feb-2023 17:11:00 Instrument ID: INTEGRION Operator ID:

Lims ID: ic 5 Worklist Smp#: 18

Client ID:

Injection Vol: 1.0 ul Dil. Factor: 1.0000 ALS Bottle#: 0

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

-1

Y

X

02-28-2023 ICAL18, 02-28-2023 ICAL18.d o ri d e

.8 lo ri d e

.0 ri te a s N

.8 lf a te

.9 m id e

.7 ra te a s N

.9 h o p h o s p h a te a s P

.6

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL18.d

Injection Date: 28-Feb-2023 17:11:00 Instrument ID: INTEGRION

Lims ID: ic 5

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 18

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: 300_9056_INTEGRION Limit Group: GC Anions ICAL

Column: Detector 0008

1 Fluoride, CAS: 16984-48-8 Signal: 1

Processing Integration Results

RT: 3.82

Area: 44072890

Amount: 0.990496

Amount Units: ug/ml

3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 Min

-1

Y

X

Manual Integration Results

RT: 3.82

Area: 42561951

Amount: 0.952861

Amount Units: ug/ml

3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 Min

RT

-1

Y

X

Reviewer: EZ9C, 01-Mar-2023 08:38:21

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\INTEGRION\20230228-46850.b\02-28-2023 ICAL18.d

Injection Date: 28-Feb-2023 17:11:00 Instrument ID: INTEGRION

Lims ID: ic 5

Client ID:

Operator ID: ALS Bottle#: 0 Worklist Smp#: 18

Injection Vol: 1.0 ul Dil. Factor: 1.