Att._7_-_ANSULITE_3__SDS.pdf

Safety Data Sheet

This safety data sheet complies with the requirements of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200)

Product name ANSULITE 3% (AFC-3A) AFFF Concentrate

1. Identification

Product name ANSULITE 3% (AFC-3A) AFFF Concentrate

Product code 431499 Synonyms None Chemical Family No information available

Recommended use Fire extinguishing agent Uses advised against Consumer use

Contact point Product Stewardship at 1-715-735-7411 E-mail address psra@tycofp.com

Emergency telephone CHEMTREC 800-424-9300 or 703-527-3887

2. Hazards Identification

OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Precautionary Statements

Not Applicable.

Unknown Acute Toxicity 4.824% of the mixture consists of ingredient(s) of unknown toxicity

3. Composition/information on Ingredients

1.1. Product Identifier

1.2. Other means of identification

1.3. Recommended use of the chemical and restrictions on use

1.4. Details of the Supplier of the Safety Data Sheet

Company Name Tyco Fire Protection Products

One Stanton Street Marinette, WI 54143-2542 Telephone: 715-735-7411

1.5. Emergency Telephone Number

Classification

2.2. Label Elements

2.3. Hazards Not Otherwise Classified (HNOC)

2.4. OTHER INFORMATION

Revision date 25-May-2015

The product contains no substances which at their given concentration, are considered to be hazardous to health

Version 25

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ANSULITE 3% SDS

Product code 431499 / Product name ANSULITE 3% (AFC-3A) AFFF Concentrate

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The following component(s) in this product are considered hazardous under applicable OSHA(USA)

Chemical name CAS No weight-% 2-(2-Butoxyethoxy)ethanol 112-34-5 5 - 10

Lauryl Imino Propionate, Sodium Salt 14960-06-6 1 - 5

4. First aid measures

Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.

Consult a physician.

Skin contact Wash skin with soap and water. Get medical attention if irritation develops and persists.

Inhalation Remove to fresh air. If breathing is difficult, give oxygen. (Get medical attention immediately if symptoms occur.).

Ingestion Rinse mouth. Do not induce vomiting without medical advice. If swallowed, call a poison control center or physician immediately.

Symptoms No information available.

Note to physicians Treat symptomatically.

5. Fire-fighting measures

Hazardous Combustion Products

Carbon oxides, Fluorinated oxides, Nitrogen oxides (NOx), Oxides of sulfur

Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

3.1. Mixture

4.1. Description of first aid measures

4.2. Most Important Symptoms and Effects, Both Acute and Delayed

4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed

5.1. Suitable Extinguishing Media

Product is extinguishing agent. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

5.2. Unsuitable Extinguishing Media

None.

Revision date 25-May-2015

5.3. Specific Hazards Arising from the Chemical

None known.

5.4. Explosion Data

Version 25

5.5. Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

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6. Accidental release measures

Personal Precautions Ensure adequate ventilation, especially in confined areas.

For emergency responders Use personal protection recommended in Section 8.

Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information.

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Pick up and transfer to properly labeled containers.

7. Handling and Storage

Advice on safe handling Avoid contact with skin and eyes. Handle in accordance with good industrial hygiene and safety practice.

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible Materials Strong oxidizing agents. Strong acids. Strong bases.

8. Exposure Controls/Personal Protection

Exposure guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH

2-(2-Butoxyethoxy)ethanol 112-34-5

TWA: 10 ppm inhalable fraction and vapor

ACGIH (American Conference of Governmental Industrial Hygienists) OSHA (Occupational Safety and Health Administration of the US Department of Labor) NIOSH IDLH Immediately Dangerous to Life or Health

Engineering controls Showers Eyewash stations Ventilation systems.

Eye/Face Protection Avoid contact with eyes. Tight sealing safety goggles.

Skin and Body Protection Wear protective gloves and protective clothing.

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental Precautions

6.3. Methods and material for containment and cleaning up

7.1. Precautions for Safe Handling

7.2. Conditions for safe storage, including any incompatibilities

8.1. Control Parameters

8.2. Appropriate Engineering Controls

Revision date 25-May-2015 Version 25

8.3. Individual protection measures, such as personal protective equipment

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Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

Ventilation Use local exhaust or general dilution ventilation to control exposure with applicable limits

9. Physical and Chemical Properties

Physical State Liquid density 1.03

10. Stability and Reactivity

Stable under recommended storage conditions.

None under normal processing.

8.4. General hygiene considerations

Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice.

9.1. Information on basic physical and chemical properties

Odor Characteristic Color Light yellow odor threshold No data available

Property VALUES Remarks • Method pH 7.5 Melting point/freezing point No data available Boiling point / boiling range > 100 °C / 212 °F Flash Point > 100 °C / > 212 °F Evaporation Rate No data available flammability (solid, gas) No data available Flammability limit in air

Upper flammability limit: No data available Lower flammability limit: No data available

Vapor Pressure No data available Vapor Density No data available Specific gravity No data available Water Solubility No data available Solubility in Other Solvents No data available Partition coefficient No data available Autoignition Temperature

No data available Decomposition Temperature No data available Kinematic viscosity 2.9 mm2/s

Revision date 25-May-2015

10.1. Chemical Stability

10.2. Reactivity

Version 25

No data available

10.3. Possibility of hazardous reactions

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hazardous polymerization Hazardous polymerization does not occur.

Extremes of temperature and direct sunlight.

Strong oxidizing agents. Strong acids. Strong bases.

Carbon oxides. Nitrogen oxides (NOx). Oxides of sulfur. Fluorinated oxides.

11. Toxicological Information

Product information no data available

INHALATION no data available.

Eye Contact no data available.

Skin contact no data available.

INGESTION no data available.

Acute Toxicity

Chemical name Oral LD50 dermal LD50 Inhalation LC50 2-(2-Butoxyethoxy)ethanol 112-34-5

= 3384 mg/kg ( Rat ) = 2700 mg/kg ( Rabbit ) -

Symptoms No information available.

sensitization No information available.

Germ Cell Mutagenicity No information available carcinogenicity No information available.

Reproductive Toxicity No information available.

STOT - Single Exposure No information available.

STOT - Repeated Exposure No information available.

Aspiration Hazard No information available.

The following values are calculated based on chapter 3.1 of the GHS document mg/kg

12. Ecological Information

Not classified

10.4. Conditions to Avoid

10.5. Incompatible Materials

10.6. Hazardous decomposition products

11.1. Information on Likely Routes of Exposure

Revision date 25-May-2015

11.2. Information on Toxicological Effects

11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure

Version 25

11.4. Numerical Measures of Toxicity - Product information

12.1. ecotoxicity

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0% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical name Algae/aquatic plants Fish Crustacea

2-(2-Butoxyethoxy)ethanol 112-34-5

EC50 96 h > 100 mg/L Desmodesmus subspicatus

LC50 96 h = 1300 mg/L Lepomis macrochirus static

EC50 24 h = 2850 mg/L Daphnia magna EC50 48 h > 100 mg/L

Daphnia magna 2-Methyl-2,4-pentanediol

107-41-5

- LC50 96 h 10500 - 11000 mg/L

Pimephales promelas flow-through LC50 96 h = 10000 mg/L Lepomis macrochirus static LC50 96 h = 8690 mg/L Pimephales promelas flow-through LC50 96 h = 10700 mg/L Pimephales promelas static

EC50 48 h 2700 - 3700 mg/L Daphnia magna t-Butanol 75-65-0

EC50 72 h > 1000 mg/L Desmodesmus subspicatus

LC50 96 h 6130 - 6700 mg/L Pimephales promelas flow-through

EC50 48 h = 933 mg/L Daphnia magna EC50 48 h 4607 - 6577 mg/L Daphnia magna Static Sodium chloride

7647-14-5

- LC50 96 h 5560 - 6080 mg/L

Lepomis macrochirus flow-through LC50 96 h = 12946 mg/L Lepomis macrochirus static LC50 96 h 6020

- 7070 mg/L Pimephales promelas static LC50 96 h = 7050 mg/L Pimephales promelas semi-static

LC50 96 h 6420 - 6700 mg/L Pimephales promelas static LC50

96 h 4747 - 7824 mg/L Oncorhynchus mykiss flow-through

EC50 48 h = 1000 mg/L Daphnia magna EC50 48 h 340.7 - 469.2 mg/L Daphnia magna Static

Polyethylene Glycol 25322-68-3

- LC50 24 h > 5000 mg/L Carassius auratus

Formaldehyde 50-00-0

- LC50 96 h 22.6 - 25.7 mg/L Pimephales promelas flow-through

LC50 96 h = 1510 µg/L Lepomis macrochirus static LC50 96 h = 41 mg/L Brachydanio rerio static LC50

96 h 0.032 - 0.226 mL/L Oncorhynchus mykiss flow-through

LC50 96 h 100 - 136 mg/L Oncorhynchus mykiss static LC50 96 h 23.2 - 29.7 mg/L Pimephales promelas static

LC50 48 h = 2 mg/L Daphnia magna EC50 48 h 11.3 - 18 mg/L

Daphnia magna Static

No information available.

No information available.

No information available

13. Disposal Considerations

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

12.2. Persistence and Degradability

12.3. Bioaccumulation

Revision date 25-May-2015

12.4. Other Adverse Effects

Version 25

13.1. Waste Treatment Methods

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Contaminated Packaging Do not reuse container.

14. Transport Information

DOT NOT REGULATED

TDG NOT REGULATED

MEX NOT REGULATED

ICAO (air) NOT REGULATED

IATA NOT REGULATED

IMDG NOT REGULATED

15. Regulatory Information

TSCA Complies DSL/NDSL Complies ENCS Does not comply IECSC Does not comply KECL Does not comply PICCS Does not comply AICS Complies

Legend:

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical name SARA 313 - Threshold Values % 2-(2-Butoxyethoxy)ethanol - 112-34-5 1.0 SARA 311/312 Hazard Categories

Acute Health Hazard No Chronic health hazard No

Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

Revision date 25-May-2015

15.1. International Inventories

Version 25

15.2. US Federal Regulations

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CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42)

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

California Proposition 65 This product contains the following Proposition 65 chemicals

Chemical name California Proposition 65 Formaldehyde - 50-00-0 Carcinogen

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania 2-(2-Butoxyethoxy)ethanol

112-34-5 X - X t-Butanol 75-65-0

X X X

Formaldehyde 50-00-0

X X X

16. Other information, including date of preparation of the last revision

Revision date 25-May-2015 Revision note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

15.3. US State Regulations

NFPA Health Hazards 0 flammability 1 Instability 0 Physical and chemical properties -

HMIS

Revision date 25-May-2015

Health Hazards 0 flammability 1

Version 25

Physical Hazards 0 Personal Protection X

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DATA SHEET

One Stanton Street | Marinette, WI 54143-2542, USA | +1-715-735-7411 | www.ansul.com

© 2017 Johnson Controls. All rights reserved. All specifications and other information shown were current as of document revision date and are subject to change without notice. | Form No. F-2015246-02

ANSULITE AFC-3MS

3% AFFF

Concentrate

Description ANSULITE AFC-3MS 3% AFFF (Aqueous Film-Forming Foam) Concentrate combines fluoro- and hydrocarbon-surfactant technologies to provide superior fire and vapor suppression for Class B hydrocarbon fuel fires. This synthetic foam concentrate is intended for firefighting applications at 3% solution in fresh, salt, or hard water.

ANSULITE AFC-3MS foam solution utilizes three suppression mechanisms for rapid fire knockdown and superior burnback resistance:

n The foam blanket blocks oxygen supply to the fuel.

n Liquid drains from the foam blanket and forms an aqueous film that suppresses fuel vapor and seals the fuel surface.

n The water content of the foam solution produces a cooling effect for additional fire suppression.

TYPICAL PHYSIOCHEMICAL PROPERTIES AT 77 °F (25 °C)

Appearance Pale yellow liquid Density 1.02 ± 0.02 g/ml pH 7.0 – 8.5 Refractive Index 1.3655 minimum Viscosity* 3.25 ± 1.0 cSt Spreading Coefficient 3 dynes/cm minimum at 3% dilution Pour Point 27 °F (-3 °C) Freeze Point 27 °F (-3 °C) *Cannon-Fenske viscometer at 77 °F (25 °C)

Application ANSULITE AFC-3MS 3% AFFF Concentrate is intended for use on Class B hydrocarbon fuel fires with low water solubility, such as crude oils, gasolines, diesel fuels, and aviation fuels. It is not suitable for use on polar fuels with appreciable water solubility, such as methyl and ethyl alcohol, acetone, and methyl ethyl ketone.

The concentrate has excellent wetting properties that can effectively combat Class A fires as well. It may also be used in conjunction with dry chemical agents to provide even greater fire suppression performance.

ANSULITE AFC-3MS Concentrate can be ideal for fixed and emergency response firefighting systems designed to protect naval and aviation assets. Typical applications include:

n Military and civilian aircraft facilities n Crash fire rescue (per US DOT FAA AC No. 150/5210-6D) n On-board marine/naval fire suppression systems n Storage tanks n Docks/marine tankers

009786

Approvals, Listings, and Standards ANSULITE AFC-3MS 3% AFFF Concentrate is approved, listed, qualified under, or meets the requirements of the following specifications and standards:

n US Department of Defense Military Specification

– MIL-F-24385F: Fire Extinguishing Agent, Aqueous Film-

Forming Foam (AFFF) Liquid Concentrate, for Fresh and Sea Water n Underwriters Laboratories Inc.

– UL Standard 162, Foam Liquid Concentrates

– Fresh and Sea Water n National Fire Protection Association (NFPA)

– NFPA 403, Standard for Aircraft Rescue and Fire-Fighting

Services at Airports

– NFPA 409, Standard on Aircraft Hangars

– NFPA 412, Standard for Evaluating Aircraft Rescue and Fire- Fighting Foam Fire Equipment

– NFPA 414, Standard for Aircraft Rescue and Fire -Fighting Vehicles

– NFPA 418, Standard for Heliports

Contact Johnson Controls Technical Services and/or refer to listing agency for current product and compatible hardware listings.

The environmentally-mindful ANSULITE AFC-3MS 3% AFFF Concentrate formulation contains short-chain, C-6 fluoro-chem-icals manufactured using a telomer-based process. The telomer process produces no PFOS, and these C-6 materials do not breakdown to yield PFOA. The fluorochemicals used in the concentrate meet the goals of the U.S.

Environmental Protection Agency 2010/15 PFOA Stewardship Program and the current ECHA Directive (EU) 2017/1000.

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Foaming Properties ANSULITE AFC-3MS 3% AFFF Concentrate may be effectively applied using most conventional foam discharge equipment at 3% dilution with fresh, salt, or hard water. For optimum perfor-mance, water hardness should not exceed 500 ppm expressed as calcium and magnesium.

ANSULITE AFC-3MS Concentrate requires low energy to foam and the foam solution may be applied with aspirating and non-aspirating discharge devices. Non-aspirating devices, such as handline water fog/stream nozzles or standard sprinkler heads, typically produce expansion ratios from 2:1 to 4:1. Aspirating low-expansion discharge devices typically produce expansion ratios from 3.5:1 to 10:1, depending on the type of device and the flow rate. Medium-expansion discharge devices typically produce expansion ratios from 20:1 to 60:1.

TYPICAL FOAM CHARACTERISTICS** (Fresh and Sea Water)

Proportioning Rate 3%

Expansion Ratio LE 9.5

25% Drain Time (min:sec) 3:30

50% Drain Time (min:sec) 5:45 **per EN 1568-3, 2008 protocol

Proportioning The recommended operational temperature range for ANSULITE AFC-3MS 3% AFFF Concentrate is 35 °F to 120 °F (2 °C to 49 °C) per UL-162. This foam concentrate can be correctly proportioned using most conventional, properly calibrated, in-line proportioning equipment such as:

n Balanced and in-line balanced pressure pump proportioners n Balanced pressure bladder tanks and ratio flow controllers n Around-the-pump type proportioners n Fixed or portable in-line venturi type proportioners n Handline nozzles with fixed eductor/pick-up tubes

For immediate use: The concentrate may also be diluted with fresh or sea water to a 3% pre-mix solution.

For delayed use: Consult Technical Services for guidance regarding suitability of a stored pre-mix solution (fresh water only).

Materials of Construction Compatibility ANSULITE AFC-3MS 3 % AFFF Concentrate compatibility with HDPE has been successfully evaluated using ASTM D1693- 70 protocol under UL-162 standard. Concentrate corrosion studies with cold-rolled carbon steel (UNS G10100), 90-10 copper-nickel (UNS C70600), 70-30 nickel-copper (UNC N04400), bronze (UNS C90500), and CRES steel (UNS S30400) have been successfully completed per ASTM E527 protocol under MIL-F-24385F specification.

To help avoid corrosion, galvanized pipe and fittings should never be used in contact with undiluted ANSULITE AFC-3MS Concentrate. Refer to Johnson Controls Technical Bulletin "Acceptable Materials of Construction" for recommendations and guidance regarding compatibility of foam concentrate with common materials of construction in the firefighting foam industry.

Storage and Handling ANSULITE AFC-3MS 3% AFFF Concentrate should be stored in the original supplied package (HDPE totes, drums, or pails) or in the recommended foam system equipment as outlined in Johnson Controls Technical Bulletin "Storage of Foam Concentrates". The product should be maintained within the recommended temperature range. If the concentrate freezes during transport or storage, full product serviceability can be restored upon thaw with gentle re-mixing.

Factors affecting the foam concentrate's long-term effectiveness include temperature exposure and cycling, storage container characteristics, air exposure, evaporation, dilution, and contami-nation. The effective life of ANSULITE AFC-3MS Concentrate can be maximized through optimal storage conditions and proper handling. ANSULITE concentrates have demonstrated effective firefighting performance with contents stored in the original package under proper conditions for more than 10 years.

ANSULITE AFC-3MS Concentrate has been successfully evalu-ated by the US Naval Sea Systems Command for prolonged compatibility with other 3% AFFF concentrates qualified under MIL-F-24385F specification.

n Mixing with foam concentrates not vetted by MIL-F-24385F is not recommended.

n For immediate incident response, it is appropriate to use the concentrate in conjunction with comparable 3% AFFF products.

Inspection ANSULITE AFC-3MS 3% AFFF Concentrate should be inspected periodically per NFPA 11, EN 13565-2, or other relevant standard.

A representative concentrate sample should be sent to Johnson Controls Foam Analytical Services or other qualified labora-tory for quality analysis per the applicable standard. An annual inspection and sample analysis is typically sufficient, unless the product has been exposed to unusual conditions.

Ordering Information ANSULITE AFC-3MS 3% AFFF Concentrate is available in pails, drums, totes, or bulk shipment. Commercially-packaged product is designated AFC-3MS-C. Product requiring DLA, US military contract packaging is designated AFC-3MS.

Approximate Part No. Description Shipping Weight

Pail 442708* 5 gal (19 L) 45 lb (20.4 kg)

Drum 442710* 55 gal (208 L) 495 lb (224.5 kg)

Tote 442711* 265 gal (1,003 L) 2,463 lb (1,117 kg)

Pail 442707‡ 5 gal (19 L) 45 lb (20.4 kg)

Drum 442709‡ 55 gal (208 L) 495 lb (224.5 kg)

* AFC-3MS-C Concentrate in commercial packaging (Pails and Drums, UL-162 compliant)

‡ AFC-3MS Concentrate in MIL-F-24385F specified packaging for direct government acquisition. Packaging requirements for specific contract identification is the responsibility of the contract holder.

Note: The converted metric values provided are for dimensional reference only and do not reflect an actual measurement.

ANSUL, ANSULITE, and the product names listed in this material are marks and/or registered marks. Unauthorized use is strictly prohibited.

Safety Data Sheets (SDS) are available at www.ansul.com

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