Att._6_-_JET-X_SDS.PDF

Safety Data Sheet

This safety data sheet complies with the requirements of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200)

Product name JET-X 2 3/4% High-Expansion Foam Concentrate

1. Identification

Product name JET-X 2 3/4% High-Expansion Foam Concentrate

Product code 420008 Synonyms None Chemical Family No information available

Recommended use Fire extinguishing agent.

Uses advised against Consumer use.

Contact point Product Stewardship at 1-715-735-7411 E-mail address psra@tycofp.com

Emergency telephone CHEMTREC 001-800-424-9300 or 001-703-527-3887

2. Hazards Identification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation - Category 2A

Precautionary Statements

1.1. Product Identifier

1.2. Other means of identification

1.3. Recommended use of the chemical and restrictions on use

1.4. Details of the Supplier of the Safety Data Sheet

Company Name Tyco Fire Protection Products

One Stanton Street Marinette, WI 54143-2542 Telephone: 715-735-7411

1.5. Emergency Telephone Number

Classification

2.2. Label Elements

Signal Word

WARNING

Hazard Statements Causes serious eye irritation

Revision date 12-Dec-2017 Version 31

Product code 420008 / Product name JET-X 2 3/4% High-Expansion Foam Concentrate

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Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wash face, hands and any exposed skin thoroughly after handling. Wear eye/face protection.

Response IF exposed or concerned: Get medical advice/attention.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Storage Store locked up.

Disposal Dispose of contents/container to an approved waste disposal plant.

Not Applicable.

Very toxic to aquatic life with long lasting effects. Very toxic to aquatic life.

Unknown Acute Toxicity 33.4232% of the mixture consists of ingredient(s) of unknown toxicity

3. Composition/information on Ingredients

The following component(s) in this product are considered hazardous under applicable OSHA(USA)

Chemical name CAS No. weight-% Ammonium Alcohol ether sufate (C8-C10) 68891-29-2 10 - 30

Ethanol 64-17-5 1 - 5 Sulfuric Acid, mono-C10-16 esters, Ammonium salts 68081-96-9 1 - 5

Lauryl Alcohol 112-53-8 1 - 5

4. First aid measures

Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.

Consult a physician.

Skin contact Wash skin with soap and water. Get medical attention if irritation develops and persists.

Inhalation Remove to fresh air. If breathing is difficult, give oxygen. (Get medical attention immediately if symptoms occur.).

Ingestion Rinse mouth. Do not induce vomiting without medical advice. If swallowed, call a poison control center or physician immediately.

Symptoms No information available.

Note to physicians Treat symptomatically.

2.3. Hazards Not Otherwise Classified (HNOC)

2.4. Other Information

3.1. Mixture

4.1. Description of first aid measures

4.2. Most Important Symptoms and Effects, Both Acute and Delayed

4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed

High-Expansion Foam Concentrate

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5. Fire-fighting measures

Hazardous Combustion Products

Carbon oxides, Nitrogen oxides (NOx), Oxides of sulfur

Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

6. Accidental release measures

Personal Precautions Ensure adequate ventilation, especially in confined areas.

For emergency responders Use personal protection recommended in Section 8.

Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information.

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Pick up and transfer to properly labeled containers.

7. Handling and Storage

Advice on safe handling Avoid contact with skin and eyes. Handle in accordance with good industrial hygiene and safety practice.

5.1. Suitable Extinguishing Media

Product is extinguishing agent. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

5.2. Unsuitable Extinguishing Media

None.

5.3. Specific Hazards Arising from the Chemical

None known.

5.4. Explosion Data

5.5. Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental Precautions

6.3. Methods and material for containment and cleaning up

7.1. Precautions for Safe Handling

High-Expansion Foam Concentrate

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Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible Materials Strong oxidizing agents. Strong acids. Strong bases.

8. Exposure Controls/Personal Protection

Exposure guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL

Ethanol 64-17-5

STEL: 1000 ppm - IDLH: 3300 ppm TWA: 1000 ppm

TWA: 1900 mg/m3

TWA 1000 ppm (VLE-PPT) TWA 1900 mg/m3

(VLE-PPT)

ACGIH (American Conference of Governmental Industrial Hygienists) OSHA (Occupational Safety and Health Administration of the US Department of Labor) NIOSH IDLH Immediately Dangerous to Life or Health

Engineering controls Ensure adequate ventilation, especially in confined areas.

Eye/Face Protection Avoid contact with eyes. Tight sealing safety goggles.

Skin and Body Protection Wear protective gloves and protective clothing.

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

Ventilation Use local exhaust or general dilution ventilation to control exposure with applicable limits

9. Physical and Chemical Properties

Physical State Liquid

7.2. Conditions for safe storage, including any incompatibilities

8.1. Control Parameters

8.2. Appropriate Engineering Controls

8.3. Individual protection measures, such as personal protective equipment

8.4. General hygiene considerations

Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice.

9.1. Information on basic physical and chemical properties

Odor Characteristic Color Green Odor Threshold No data available

Property Values Remarks • Method pH 7 Melting point/freezing point No data available Boiling point / boiling range 100 °C / 212 °F Flash Point > 100 °C / > 212 °F Evaporation Rate No data available Flammability (solid, gas) No data available Flammability limit in air

High-Expansion Foam Concentrate

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10. Stability and Reactivity

Stable under recommended storage conditions.

None under normal processing.

Hazardous Polymerization Hazardous polymerization does not occur.

Extremes of temperature and direct sunlight.

Strong oxidizing agents. Strong acids. Strong bases.

Carbon oxides. Nitrogen oxides (NOx). Oxides of sulfur.

11. Toxicological Information

Product information

Inhalation No data available.

Eye Contact Severely irritating to eyes.

Skin contact No data available.

Ingestion No data available.

Component Information Acute Toxicity

Upper flammability limit: No data available Lower flammability limit: No data available

Vapor Pressure No data available Vapor Density No data available Specific gravity No data available Water Solubility No data available Solubility in Other Solvents No data available Partition coefficient No data available Autoignition Temperature No data available Decomposition Temperature No data available Kinematic viscosity No data available

10.1. Chemical Stability

10.2. Reactivity

No data available

10.3. Possibility of hazardous reactions

10.4. Conditions to Avoid

10.5. Incompatible Materials

10.6. Hazardous decomposition products

11.1. Information on Likely Routes of Exposure

High-Expansion Foam Concentrate

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Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Ethanol 64-17-5

= 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h

Lauryl Alcohol 112-53-8

> 12800 mg/kg ( Rat ) - -

Symptoms No information available.

Skin Corrosion/Irritation No information available.

Serious eye damage/eye irritation Severely irritating to eyes.

Sensitization No information available.

Germ Cell Mutagenicity No information available.

Carcinogenicity Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage.

Chemical name ACGIH IARC NTP OSHA Ethanol 64-17-5

A3 Group 1 Known X

ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present

Reproductive Toxicity No information available.

STOT - Single Exposure No information available.

STOT - Repeated Exposure No information available.

Chronic Toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin.

Target organ effects Blood, Central Nervous System, Eyes, Liver, Reproductive system, Respiratory System, Skin.

Aspiration Hazard No information available.

The following values are calculated based on chapter 3.1 of the GHS document ATEmix (inhalation-dust/mist) 2163.5 mg/l

12. Ecological Information

Very toxic to aquatic life with long lasting effects.

28.703% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical name Algae/aquatic plants Fish Crustacea

Dipropylene glycol 25265-71-8

- LC50 (24h) static > 5000 mg/L Carassius auratus

Ethanol 64-17-5

- LC50 (96h) static 12.0 - 16.0 mL/L Oncorhynchus mykiss LC50 (96h) flow-through 13400 - 15100 mg/L Pimephales promelas LC50 (96h) static > 100 mg/L Pimephales

EC50 (24h) = 10800 mg/L Daphnia magna LC50 (48h) 9268 - 14221 mg/L Daphnia magna EC50 (48h) Static = 2 mg/L Daphnia magna

11.2. Information on Toxicological Effects

11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure

11.4. Numerical Measures of Toxicity - Product information

12.1. Ecotoxicity

High-Expansion Foam Concentrate

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promelas Sulfuric Acid, mono-C10-16 esters, Ammonium salts 68081-96-9

EC50 (96h) = 42 mg/L Desmodesmus subspicatus

LC50 (48h) static = 19 mg/L Leuciscus idus

EC50 (24h) = 56 mg/L Daphnia magna

Lauryl Alcohol 112-53-8

EC50 (96h) = 0.62 mg/L Desmodesmus subspicatus

LC50 (96h) = 0.1855 mg/L Pimephales promelas LC50 (96h) flow-through = 1.01 mg/L Pimephales promelas

EC50 (48h) = 320 mg/L Daphnia magna

No information available.

No information available.

Chemical name Partition coefficient Ethanol 64-17-5

-0.32

Lauryl Alcohol 112-53-8

5.36

No information available

13. Disposal Considerations

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated Packaging Do not reuse container.

14. Transport Information

DOT NOT REGULATED

TDG NOT REGULATED

MEX NOT REGULATED

ICAO (air) NOT REGULATED

IATA NOT REGULATED

IMDG NOT REGULATED

15. Regulatory Information

TSCA Complies DSL/NDSL Complies

12.2. Persistence and Degradability

12.3. Bioaccumulation

12.4. Other Adverse Effects

13.1. Waste Treatment Methods

15.1. International Inventories

High-Expansion Foam Concentrate

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ENCS Does not comply IECSC Complies KECL Does not comply PICCS Complies AICS Complies

Legend:

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic health hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

CERCLA

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

California Proposition 65 This product contains the following Proposition 65 chemicals

Chemical name California Proposition 65 Ethanol - 64-17-5 Carcinogen

Developmental

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania Ethanol 64-17-5

X X X di-Sodium hydrogen phosphate anhydrous 7558-79-4

X X X

15.2. US Federal Regulations

15.3. US State Regulations

High-Expansion Foam Concentrate

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16. Other information, including date of preparation of the last revision

Revision date 12-Dec-2017 Revision note No information available.

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

NFPA Health Hazards 2 Flammability 1 Instability 0 Physical and chemical properties -

HMIS Health Hazards 2 Flammability 1 Physical Hazards 0 Personal Protection X