J185280_1 Std_Tal_L4 Final Report_Part11.pdf

FORM I

DIOXIN ORGANICS ANALYSIS DATA SHEET

Lab Name: Job No.: 180-185280-1Eurofins Lancaster Laboratories Environment Testing, LLC

SDG No.:

Client Sample ID: #20250046 COMPOSITE

P/DISCRETE #46

Lab Sample ID: 180-185280-7

Matrix: 25feb12zb-10.dLab File ID:

Date Collected:1613BAnalysis Method:

Sediment

01/10/2025 10:21

Level: (low/med)

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Analyzed:

Date Extracted:

Dilution Factor:

Extract. Method: 02/11/2025 04:14

HRMS-Sox

02/12/2025 17:44

Low

1(uL)

20(uL)

% Moisture: 65.2

Sample wt/vol: 10.18(g)

N% Solids: 34.8

GC Column: 0.25(mm)ID:ZB-Dioxin

Cleanup Factor:

Analysis Batch No.: 605182 ng/KgUnits:

Preparation Batch No.: Instrument ID: 604528 DF17611B

CAS NO. COMPOUND NAME RESULT Q MDLRL

14 5.635822-46-9 1,2,3,4,6,7,8-HpCDD 290

14 5.667562-39-4 1,2,3,4,6,7,8-HpCDF 260

14 5.6U39227-28-6 1,2,3,4,7,8-HxCDD 14

14 5.670648-26-9 1,2,3,4,7,8-HxCDF 44

14 5.6J I55673-89-7 1,2,3,4,7,8,9-HpCDF 12

14 5.657653-85-7 1,2,3,6,7,8-HxCDD 15

14 5.657117-44-9 1,2,3,6,7,8-HxCDF 14

14 5.6U40321-76-4 1,2,3,7,8-PeCDD 14

14 5.6J57117-41-6 1,2,3,7,8-PeCDF 9.4

14 5.6J19408-74-3 1,2,3,7,8,9-HxCDD 10

14 5.6U72918-21-9 1,2,3,7,8,9-HxCDF 14

14 5.6J60851-34-5 2,3,4,6,7,8-HxCDF 12

14 5.657117-31-4 2,3,4,7,8-PeCDF 17

2.8 0.561746-01-6 2,3,7,8-TCDD 37

2.8 0.56I51207-31-9 2,3,7,8-TCDF 12

28 5.63268-87-9 OCDD 3000

28 5.639001-02-0 OCDF 410

FORM I 1613B

Page 10957 of 21459

Lab Name: Job No.: 180-185280-1Eurofins Lancaster Laboratories Environment Testing, LLC

SDG No.:

Client Sample ID: #20250046 COMPOSITE

P/DISCRETE #46

Lab Sample ID: 180-185280-7

Matrix: 25feb12zb-10.dLab File ID:

Date Collected:1613BAnalysis Method:

Sediment

01/10/2025 10:21

Level: (low/med)

Con. Extract Vol.:

Injection Volume:

GPC Cleanup:(Y/N)

Date Analyzed:

Date Extracted:

Dilution Factor:

Extract. Method: 02/11/2025 04:14

HRMS-Sox

02/12/2025 17:44

Low

1(uL)

20(uL)

% Moisture: 65.2

Sample wt/vol: 10.18(g)

N% Solids: 34.8

GC Column: 0.25(mm)ID:ZB-Dioxin

Cleanup Factor:

Analysis Batch No.: 605182 ng/KgUnits:

Preparation Batch No.: Instrument ID: 604528 DF17611B

%RECCAS NO. LIMITSQISOTOPE DILUTION

59 23-140109719-83-7 13C-1,2,3,4,6,7,8-HpCDD

50 28-143109719-84-8 13C-1,2,3,4,6,7,8-HpCDF

59 32-141109719-80-4 13C-1,2,3,4,7,8-HxCDD

52 26-152114423-98-2 13C-1,2,3,4,7,8-HxCDF

56 26-138109719-94-0 13C-1,2,3,4,7,8,9-HpCDF

55 28-130109719-81-5 13C-1,2,3,6,7,8-HxCDD

54 26-123116843-03-9 13C-1,2,3,6,7,8-HxCDF

61 25-181109719-79-1 13C-1,2,3,7,8-PeCDD

46 24-185109719-77-9 13C-1,2,3,7,8-PeCDF

58 28-130109719-82-6 13C-1,2,3,7,8,9-HxCDD

53 29-147116843-04-0 13C-1,2,3,7,8,9-HxCDF

52 28-136116843-05-1 13C-2,3,4,6,7,8-HxCDF

59 21-178116843-02-8 13C-2,3,4,7,8-PeCDF

57 25-16476523-40-5 13C-2,3,7,8-TCDD

50 24-16989059-46-1 13C-2,3,7,8-TCDF

63 17-157114423-97-1 13C-OCDD

58 17-157109719-78-0 13C-OCDF

Page 10958 of 21459

Report Date: 13-Feb-2025 13:22:59 Chrom Revision: 2.3 12-Feb-2025 13:38:10

Eurofins Lancaster Laboratories Environment Testing, LLC

Target Compound Quantitation Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Sample Type: Client

Inject. Date: 12-Feb-2025 17:44:00 ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info:

Misc. Info.: 410-0137977-010

Operator ID: Xcalibur_System Instrument ID: DF17611B

Method: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\Dioxin_DF17611B.m

Limit Group: HR - 1613B

Last Update: 13-Feb-2025 13:22:59 Calib Date: 12-Feb-2025 00:28:00

Integrator: Picker

Quant Method: Isotopic Dilution Quant By: Initial Calibration

Last ICal File: \\chromfs\Lancaster\ChromData\DF17611B\20250211-137875.b\25feb12zb(ical)-08.d

Column 1 : ZB-Dioxin 60m 0.20um ( 0.25 mm) Det: F1(18.06 :21.01 )

Process Host: CTX1630

First Level Reviewer: U4LD Date: 13-Feb-2025 13:22:59

Compound

RT

(min.) Area Ratio Ical

RRF

Amount ng/ml

EMPC

ng/ml

Noise

EDL

Final EDL %Rec Flags

* 13C-1,2,3,4-TCDD 31.353 5985529 0.80 100.0 100.0

* 13C-1,2,3,4,6,8-HxCDD 39.242 5780471 1.24 100.0 100.0

D 13C-2,3,7,8-TCDF 31.472 5265893 0.76 1.7598 50.0 50.0 0.0160 0.0160 49.99

D 13C-2,3,7,8-TCDD 32.214 4752792 0.79 1.3818 57.5 57.5 0.007412 0.007412 57.47

D 13C-1,2,3,7,8-PeCDF 35.886 3702300 1.65 1.3348 46.3 46.3 0.0967 0.0967 46.34

D 13C-2,3,4,7,8-PeCDF 36.921 4416499 1.56 1.2586 58.6 58.6 0.1026 0.1026 58.62

D 13C-1,2,3,7,8-PeCDD 37.091 2507649 1.61 0.6881 60.9 60.9 0.0441 0.0441 60.89

D 13C-1,2,3,4,7,8-HxCDF 39.390 3428182 0.51 1.1324 52.4 52.4 0.0384 0.0384 52.37

D 13C-1,2,3,6,7,8-HxCDF 39.511 3616307 0.53 1.1669 53.6 53.6 0.0373 0.0373 53.61

D 13C-2,3,4,6,7,8-HxCDF 40.035 3319498 0.51 1.1070 51.9 51.9 0.0393 0.0393 51.88

D 13C-1,2,3,6,7,8-HxCDD 40.196 3061461 1.25 0.9618 55.1 55.1 0.0177 0.0177 55.06

D 13C-1,2,3,4,7,8-HxCDD 40.102 3192215 1.28 0.9300 59.4 59.4 0.0183 0.0183 59.38

D 13C-1,2,3,7,8,9-HxCDD 40.425 3237765 1.23 0.9637 58.1 58.1 0.0177 0.0177 58.12

D 13C-1,2,3,7,8,9-HxCDF 40.856 3134060 0.52 1.0178 53.3 53.3 0.0427 0.0427 53.27

D 13C-1,2,3,4,6,7,8-HpCDF 41.959 2439490 0.43 0.8475 49.8 49.8 0.0362 0.0362 49.79

D 13C-1,2,3,4,6,7,8-HpCDD 43.008 2548390 1.04 0.7480 58.9 58.9 0.0247 0.0247 58.94

D 13C-1,2,3,4,7,8,9-HpCDF 43.694 2129340 0.45 0.6581 56.0 56.0 0.0467 0.0467 55.98

D 13C-OCDD 46.125 3975604 0.90 0.5483 125.4 125.4 0.0237 0.0237 62.72

D 13C-OCDF 46.498 4820795 0.88 0.7186 116.1 116.1 0.0145 0.0145 58.03

$ 13C-1,2,7,8-TCDD 32.802 0.0 0.0

2,3,7,8-TCDF 31.489 98746 0.62 0.8998 2.084 2.084 0.0240 0.0240 RM

2,3,7,8-TCDD 32.248 328235 0.76 1.0591 6.521 6.521 0.0103 0.0103 M

1,2,3,7,8-PeCDF 35.901 68397 1.48 1.1059 1.670 1.670 0.0827 0.0827

2,3,4,7,8-PeCDF 36.936 165235 1.53 1.2127 3.085 3.085 0.0728 0.0728 M

1,2,3,7,8-PeCDD 37.103 0.3712 0.3712

1,2,3,4,7,8-HxCDF 39.403 258820 1.11 0.9716 7.770 7.770 0.0932 0.0932

1,2,3,6,7,8-HxCDF 39.524 90529 1.07 0.9886 2.532 2.532 0.0849 0.0849

2,3,4,6,7,8-HxCDF 40.062 74141 1.06 1.0153 2.200 2.200 0.0856 0.0856 M

1,2,3,4,7,8-HxCDD 40.116 24828 1.33 1.0564 0.7362 0.7362 0.2176 0.2176 Ma

1,2,3,6,7,8-HxCDD 40.210 90860 1.31 1.1240 2.640 2.640 0.2165 0.2165 Ma

1,2,3,7,8,9-HxCDD 40.439 59725 1.22 1.0374 1.778 1.778 0.2305 0.2305

1,2,3,7,8,9-HxCDF 40.909 0.1183 0.1183 U

1,2,3,4,6,7,8-HpCDF 41.972 1167993 0.91 1.0526 45.5 45.5 0.1089 0.1089

1,2,3,4,6,7,8-HpCDD 43.022 1370270 1.03 1.0531 51.1 51.1 0.0383 0.0383

1,2,3,4,7,8,9-HpCDF 43.721 50017 1.45 1.1202 2.097 2.097 0.1360 0.1360 R

Page 10959 of 21459

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Compound

RT

(min.) Area Ratio Ical

RRF

Amount ng/ml

EMPC

ng/ml

Noise

EDL

Final EDL %Rec Flags

OCDD 46.139 11056338 0.89 1.0453 532.1 532.1 0.0468 0.0468

OCDF 46.511 1574381 0.84 0.9066 72.0 72.0 0.0502 0.0502

A Non-2,3,7,8-sub-TCDF 29.577 2424992 0.64 0.8998 51.2 51.2 0.0240 11.1 R

A Non-2,3,7,8-sub-TCDD 30.437 1959010 0.05 1.0591 38.9 38.9 0.0103 34.0 R

A F2 PeCDFs 33.678 442893 1.57 1.1593 9.411 9.411 0.005779 9.279 R

A Non-2,3,7,8-sub-PeCDF 34.899 1081088 1.49 1.1593 23.0 23.0 0.0775 8.759 R

A Non-2,3,7,8-sub-PeCDD 35.934 143423 1.36 1.2742 4.489 4.489 0.3712 2.459 R

A Non-2,3,7,8-sub-HxCDD 39.501 842715 1.19 1.0726 24.8 24.8 0.2213 11.5

A Non-2,3,7,8-sub-HxCDF 39.521 866075 1.09 0.9764 26.3 26.3 0.0941 14.5

A Non-2,3,7,8-sub-HpCDD 42.690 1985540 1.03 1.0531 74.0 74.0 0.0383 74.0

A Non-2,3,7,8-sub-HpCDF 42.811 563618 0.94 1.0864 22.7 22.7 0.1204 21.3

S Total TCDF 53.3 53.3 0.0240 0.0240 R

S Total TCDD 45.4 45.4 0.0103 0.0103 R

S Total PeCDF 37.1 37.1 0.0778 0.0778 R

S Total PeCDD 4.489 4.489 0.3712 0.3712 R

S Total HxCDF 38.8 38.8 0.0955 0.0955

S Total HxCDD 30.0 30.0 0.2215 0.2215

S Total HpCDD 125.0 125.0 0.0383 0.0383

S Total HpCDF 70.3 70.3 0.1225 0.1225 R

S Total PCDD 737.1 737.1 0.1376 0.1376 R

S Total PCDF 271.5 271.5 0.0740 0.0740 R

S Total PCDD/PCDF 1008.6 1008.6 0.1058 0.1058 R

S Total 2378-Chlorinated Dioxins & 733.8 733.8 0.1169 0.1169 R

QC Flag Legend Processing Flags R - Failed Signal Ratio Test Review Flags M - Manually Integrated U - Marked Undetected a - User Assigned ID

Reagents:

HRM_DF_ISTD_00066 Amount Added: 10.00 Units: uL Run Reagent

Page 10960 of 21459

Target Compound Quantitation Worksheet Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Sample Type: Client

Inject. Date: 12-Feb-2025 17:44:00 ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info:

Misc. Info.: 410-0137977-010

Operator ID: Xcalibur_System Instrument ID: DF17611B

Method: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\Dioxin_DF17611B.m

Limit Group: HR - 1613B

Last Update: 13-Feb-2025 13:22:59 Calib Date: 12-Feb-2025 00:28:00

Integrator: Picker

Quant Method: Isotopic Dilution Quant By: Initial Calibration

Last ICal File: \\chromfs\Lancaster\ChromData\DF17611B\20250211-137875.b\25feb12zb(ical)-08.d

Column 1 : ZB-Dioxin 60m 0.20um ( 0.25 mm) Det: F1(18.06 :21.01 )

Process Host: CTX1630

First Level Reviewer: U4LD Date: 13-Feb-2025 13:22:59

Signal

RT

(min.)

Exp RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

13C-1,2,3,4-TCDD

331.9363 31.353 31.337 1 2658995 483079 25 62 19323

333.9333 31.353 31.337 1 3326534 610490 20 50 30525 0.80(0.65-0.89)

13C-1,2,3,4,6,8-HxCDD

401.8554 39.242 39.227 1 3203144 1133907 79 197 14353

403.8524 39.242 39.227 1 2577327 923822 61 152 15145 1.24(1.05-1.43)

13C-2,3,7,8-TCDF

315.9413 31.472 31.438 2 1.004 2273404 420547 65 162 6470

317.9384 31.472 31.438 2 1.004 2992489 560211 58 145 9659 0.76(0.65-0.89)

13C-2,3,7,8-TCDD

331.9363 32.214 32.197 1 1.027 2099606 425049 25 62 17002

333.9333 32.214 32.197 1 1.027 2653186 538941 20 50 26947 0.79(0.65-0.89)

13C-1,2,3,7,8-PeCDF

351.8994 35.886 35.867 1 1.145 2304665 791034 329 822 2404

353.8965 35.886 35.867 1 1.145 1397635 484960 236 590 2055 1.65(1.32-1.78)

13C-2,3,4,7,8-PeCDF

351.8994 36.921 36.918 0 1.178 2691379 805479 329 822 2448

353.8965 36.921 36.918 0 1.178 1725120 515719 236 590 2185 1.56(1.32-1.78)

13C-1,2,3,7,8-PeCDD

367.8943 37.091 37.088 0 1.183 1545569 467024 61 152 7656

369.8914 37.091 37.088 0 1.183 962080 294188 72 180 4086 1.61(1.32-1.78)

13C-1,2,3,4,7,8-HxCDF

383.8634 39.390 39.375 1 1.004 1151092 404648 201 502 2013

385.8604 39.390 39.375 1 1.004 2277090 801214 157 392 5103 0.51(0.43-0.59)

Page 10961 of 21459

Signal

RT

(min.)

Exp RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

13C-1,2,3,6,7,8-HxCDF

383.8634 39.511 39.496 1 1.007 1247797 451804 201 502 2248

385.8604 39.511 39.496 1 1.007 2368510 849031 157 392 5408 0.53(0.43-0.59)

13C-2,3,4,6,7,8-HxCDF

383.8634 40.035 40.021 1 1.020 1127327 428717 201 502 2133

385.8604 40.035 40.021 1 1.020 2192171 827608 157 392 5271 0.51(0.43-0.59)

13C-1,2,3,6,7,8-HxCDD

401.8554 40.196 40.088 6 1.024 1700009 626111 79 197 7925

403.8524 40.196 40.088 6 1.024 1361452 506594 61 152 8305 1.25(1.05-1.43)

13C-1,2,3,4,7,8-HxCDD

401.8554 40.102 40.182 -5 1.022 1792578 672922 79 197 8518

403.8524 40.102 40.182 -5 1.022 1399637 526444 61 152 8630 1.28(1.05-1.43)

13C-1,2,3,7,8,9-HxCDD

401.8554 40.425 40.398 2 1.030 1784891 637042 79 197 8064

403.8524 40.425 40.398 2 1.030 1452874 515848 61 152 8457 1.23(1.05-1.43)

13C-1,2,3,7,8,9-HxCDF

383.8634 40.856 40.828 2 1.041 1068098 339142 201 502 1687

385.8604 40.856 40.828 2 1.041 2065962 653575 157 392 4163 0.52(0.43-0.59)

13C-1,2,3,4,6,7,8-HpCDF

417.8244 41.959 41.933 2 1.069 728874 250971 125 312 2008

419.8215 41.959 41.933 2 1.069 1710616 594872 128 320 4647 0.43(0.37-0.51)

13C-1,2,3,4,6,7,8-HpCDD

435.8164 43.008 42.982 2 1.096 1299962 432955 82 205 5280

437.8134 43.008 42.982 2 1.096 1248428 414090 70 175 5916 1.04(0.88-1.20)

13C-1,2,3,4,7,8,9-HpCDF

417.8244 43.694 43.681 1 1.113 657205 194968 125 312 1560

419.8215 43.694 43.681 1 1.113 1472135 441951 128 320 3453 0.45(0.37-0.51)

13C-OCDD

469.7774 46.125 46.082 3 1.175 1881192 511178 41 102 12468

471.7745 46.125 46.082 3 1.175 2094412 571148 66 165 8654 0.90(0.76-1.02)

13C-OCDF

453.7825 46.498 46.454 3 1.185 2259251 597806 39 97 15328

455.7795 46.498 46.454 3 1.185 2561544 675568 47 117 14374 0.88(0.76-1.02)

13C-1,2,7,8-TCDD

331.9363 32.802 25 62

333.9333 32.802 20 50

2,3,7,8-TCDF RM

303.9011 31.489 31.472 1 1.001 37621 7385 37 92 200 M

305.8981 31.489 31.472 1 1.001 61125 11559 48 120 241 0.62(0.65-0.89) M

2,3,7,8-TCDD M

319.8960 32.248 32.231 1 1.001 141963 29415 6 15 4903

321.8930 32.248 32.231 1 1.001 186272 38494 36 90 1069 0.76(0.65-0.89) M

1,2,3,7,8-PeCDF

339.8592 35.901 35.883 1 1.000 40852 13462 303 757 44

341.8562 35.901 35.883 1 1.000 27545 8363 164 410 51 1.48(1.32-1.78)

Page 10962 of 21459

Signal

RT

(min.)

Exp RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

2,3,4,7,8-PeCDF M

339.8592 36.936 36.933 0 1.000 99871 24011 303 757 79 M

341.8562 36.936 36.933 0 1.000 65364 15674 164 410 96 1.53(1.32-1.78)

1,2,3,7,8-PeCDD

355.8541 37.103 797 1992

357.8511 37.103 643 1607

1,2,3,4,7,8-HxCDF

373.8201 39.403 39.388 1 1.000 136425 47504 210 525 226

375.8172 39.403 39.388 1 1.000 122395 43319 227 567 191 1.11(1.05-1.43)

1,2,3,6,7,8-HxCDF

373.8201 39.524 39.509 1 1.000 46868 16610 210 525 79

375.8172 39.524 39.509 1 1.000 43661 15390 227 567 68 1.07(1.05-1.43)

2,3,4,6,7,8-HxCDF M

373.8201 40.062 40.034 2 1.001 38148 9406 210 525 45 M

375.8172 40.049 40.034 1 1.000 35993 9103 227 567 40 1.06(1.05-1.43) M

1,2,3,4,7,8-HxCDD Ma

389.8151 40.116 40.101 1 1.000 14155 5654 270 675 21 a

391.8121 40.116 40.101 1 1.000 10673 4247 833 2082 5 1.33(1.05-1.43) M

1,2,3,6,7,8-HxCDD Ma

389.8151 40.210 40.196 1 1.000 51569 18778 270 675 70 M

391.8121 40.210 40.196 1 1.000 39291 14472 833 2082 17 1.31(1.05-1.43) a

1,2,3,7,8,9-HxCDD

389.8151 40.439 40.411 2 1.000 32859 12033 270 675 45

391.8121 40.439 40.411 2 1.000 26866 9473 833 2082 11 1.22(1.05-1.43)

1,2,3,7,8,9-HxCDF U

373.8201 40.842 210 525

375.8172 40.842 227 567

1,2,3,4,6,7,8-HpCDF

407.7812 41.972 41.946 2 1.000 555786 192279 235 587 818

409.7783 41.972 41.946 2 1.000 612207 212341 153 382 1388 0.91(0.88-1.20)

1,2,3,4,6,7,8-HpCDD

423.7761 43.022 42.996 2 1.000 694784 234700 71 177 3306

425.7732 43.022 42.996 2 1.000 675486 225969 66 165 3424 1.03(0.88-1.20)

1,2,3,4,7,8,9-HpCDF R

407.7812 43.721 43.695 2 1.001 29599 6282 235 587 27

409.7783 43.708 43.695 1 1.000 20418 6485 153 382 42 1.45(0.88-1.20)

OCDD

457.7372 46.139 46.096 3 1.000 5191678 1409988 36 90 39166

459.7342 46.139 46.096 3 1.000 5864660 1583204 70 175 22617 0.89(0.76-1.02)

OCDF

441.7422 46.511 46.468 3 1.000 720292 189096 64 160 2955

443.7393 46.511 46.468 3 1.000 854089 223609 52 130 4300 0.84(0.76-1.02)

A Non-2,3,7,8-sub-TCDF R

303.9011 25.584 29.577 -239 0.813 12377 2139 37 92 58

305.8981 25.584 29.577 -239 0.813 19271 3341 48 120 70 0.64(0.65-0.89)

Page 10963 of 21459

Signal

RT

(min.)

Exp RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

303.9011 26.123 29.577 -207 0.830 19834 3171 37 92 86

305.8981 26.123 29.577 -207 0.830 32744 5170 48 120 108 0.61(0.65-0.89)

303.9011 26.578 29.577 -180 0.845 16435 2659 37 92 72

305.8981 26.578 29.577 -180 0.845 24842 3826 48 120 80 0.66(0.65-0.89)

303.9011 26.848 29.577 -163 0.853 40414 6723 37 92 182

305.8981 26.848 29.577 -163 0.853 62734 10944 48 120 228 0.64(0.65-0.89)

303.9011 27.473 29.577 -126 0.873 67423 4250 37 92 115

305.8981 27.456 29.577 -127 0.872 104577 6261 48 120 130 0.64(0.65-0.89)

303.9011 27.793 29.577 -107 0.883 101065 11692 37 92 316

305.8981 27.793 29.577 -107 0.883 160763 18523 48 120 386 0.63(0.65-0.89)

303.9011 28.316 29.577 -76 0.900 25340 3853 37 92 104

305.8981 28.316 29.577 -76 0.900 39666 5557 48 120 116 0.64(0.65-0.89)

303.9011 28.468 29.577 -66 0.905 20295 3047 37 92 82

305.8981 28.468 29.577 -66 0.905 29805 4622 48 120 96 0.68(0.65-0.89)

303.9011 28.721 29.577 -51 0.913 41506 5984 37 92 162

305.8981 28.721 29.577 -51 0.913 66336 9417 48 120 196 0.63(0.65-0.89)

303.9011 29.345 29.577 -14 0.932 26322 2479 37 92 67

305.8981 29.362 29.577 -13 0.933 40508 3940 48 120 82 0.65(0.65-0.89)

303.9011 29.717 29.577 8 0.944 101184 10684 37 92 289

305.8981 29.717 29.577 8 0.944 160272 17038 48 120 355 0.63(0.65-0.89)

303.9011 30.307 29.577 44 0.963 26923 4317 37 92 117

305.8981 30.307 29.577 44 0.963 42388 6941 48 120 145 0.64(0.65-0.89)

303.9011 30.678 29.577 66 0.975 27416 2519 37 92 68

305.8981 30.695 29.577 67 0.975 40119 3430 48 120 71 0.68(0.65-0.89)

303.9011 31.151 29.577 94 0.990 12909 2233 37 92 60

305.8981 31.151 29.577 94 0.990 18951 3229 48 120 67 0.68(0.65-0.89)

303.9011 31.337 29.577 105 0.996 67363 12283 37 92 332

305.8981 31.337 29.577 105 0.996 105524 18686 48 120 389 0.64(0.65-0.89)

303.9011 31.826 29.577 135 1.011 42338 6200 37 92 168

305.8981 31.826 29.577 135 1.011 68163 10513 48 120 219 0.62(0.65-0.89)

303.9011 32.130 29.577 153 1.021 20046 3165 37 92 86

305.8981 32.130 29.577 153 1.021 33278 5835 48 120 122 0.60(0.65-0.89)

303.9011 32.349 29.577 166 1.028 3166 477 37 92 13

305.8981 32.332 29.577 165 1.027 4780 665 48 120 14 0.66(0.65-0.89)

303.9011 32.652 29.577 184 1.038 208575 48545 37 92 1312

305.8981 32.652 29.577 184 1.038 318825 76088 48 120 1585 0.65(0.65-0.89)

303.9011 32.855 29.577 196 1.044 34623 8094 37 92 219

305.8981 32.855 29.577 196 1.044 54949 12992 48 120 271 0.63(0.65-0.89)

303.9011 33.226 29.577 218 1.056 4450 672 37 92 18

305.8981 33.175 29.577 215 1.054 6538 776 48 120 16 0.68(0.65-0.89)

303.9011 33.479 29.577 234 1.064 2792 748 37 92 20

305.8981 33.462 29.577 233 1.063 7172 993 48 120 21 0.39(0.65-0.89)

303.9011 33.563 29.577 239 1.066 7891 1725 37 92 47

305.8981 33.563 29.577 239 1.066 12466 3132 48 120 65 0.63(0.65-0.89)

Page 10964 of 21459

Signal

RT

(min.)

Exp RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

303.9011 33.698 29.577 247 1.071 15245 3404 37 92 92

305.8981 33.698 29.577 247 1.071 24389 5281 48 120 110 0.63(0.65-0.89)

A Non-2,3,7,8-sub-TCDD R

319.8960 27.692 30.437 -164 0.860 48899 7424 6 15 1237

321.8930 27.675 30.437 -165 0.859 60263 8811 36 90 245 0.81(0.65-0.89)

319.8960 28.080 30.437 -141 0.872 15731 2364 6 15 394

321.8930 28.080 30.437 -141 0.872 32865 3807 36 90 106 0.48(0.65-0.89)

319.8960 28.704 30.437 -104 0.891 3536 472 6 15 79

321.8930 28.772 30.437 -100 0.893 10661 929 36 90 26 0.33(0.65-0.89)

319.8960 29.784 30.437 -39 0.925 4375 611 6 15 102

321.8930 29.852 30.437 -35 0.927 1707062 261383 36 90 7261 0.00(0.65-0.89)

319.8960 30.324 30.437 -7 0.941 13277 2050 6 15 342

321.8930 30.307 30.437 -8 0.941 18074 2710 36 90 75 0.73(0.65-0.89)

319.8960 30.560 30.437 7 0.949 2002 390 6 15 65

321.8930 30.594 30.437 9 0.950 6256 813 36 90 23 0.32(0.65-0.89)

319.8960 31.016 30.437 35 0.963 4574 480 6 15 80

321.8930 30.982 30.437 33 0.962 8696 1937 36 90 54 0.53(0.65-0.89)

319.8960 31.472 30.437 62 0.977 3736 528 6 15 88

321.8930 31.472 30.437 62 0.977 3402 498 36 90 14 1.10(0.65-0.89)

319.8960 32.585 30.437 129 1.012 3144 629 6 15 105

321.8930 32.602 30.437 130 1.012 3753 850 36 90 24 0.84(0.65-0.89)

319.8960 32.754 30.437 139 1.017 637 215 6 15 36

321.8930 32.787 30.437 141 1.018 3317 618 36 90 17 0.19(0.65-0.89)

319.8960 33.226 30.437 167 1.031 1813 414 6 15 69

321.8930 33.226 30.437 167 1.031 2937 418 36 90 12 0.62(0.65-0.89)

A F2 PeCDFs R

339.8592 33.125 33.678 -33 0.923 267041 53900 18 45 2994

341.8562 33.125 33.678 -33 0.923 169643 34830 17 42 2049 1.57(1.32-1.78)

339.8592 33.698 33.678 1 0.939 1634 399 18 45 22

341.8562 33.682 33.678 0 0.939 767 171 17 42 10 2.13(1.32-1.78)

339.8592 34.171 33.678 30 0.952 2191 269 18 45 15

341.8562 34.171 33.678 30 0.952 1617 285 17 42 17 1.35(1.32-1.78)

A Non-2,3,7,8-sub-PeCDF R

339.8592 34.695 34.899 -12 0.967 89361 15407 303 757 51

341.8562 34.695 34.899 -12 0.967 63439 10355 164 410 63 1.41(1.32-1.78)

339.8592 34.881 34.899 -1 0.972 248630 46304 303 757 153

341.8562 34.881 34.899 -1 0.972 163571 30258 164 410 185 1.52(1.32-1.78)

339.8592 35.159 34.899 16 0.980 10633 3330 303 757 11

341.8562 35.159 34.899 16 0.980 10093 2334 164 410 14 1.05(1.32-1.78)

339.8592 35.375 34.899 29 0.986 15293 2005 303 757 7

341.8562 35.360 34.899 28 0.985 7499 1413 164 410 9 2.04(1.32-1.78)

339.8592 35.545 34.899 39 0.991 156868 34904 303 757 115

341.8562 35.545 34.899 39 0.991 105536 22414 164 410 137 1.49(1.32-1.78)

Page 10965 of 21459

Signal

RT

(min.)

Exp RT (min.)

Q Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

339.8592 35.746 34.899 51 0.996 38195 11004 303 757 36

341.8562 35.746 34.899 51 0.996 26365 7054 164 410 43 1.45(1.32-1.78)

339.8592 35.978 34.899 65 1.003 18338 6668 303 757 22

341.8562 35.978 34.899 65 1.003 11109 3891 164 410 24 1.65(1.32-1.78)

339.8592 36.148 34.899 75 1.007 61137 16423 303 757 54

341.8562 36.148 34.899 75 1.007 41313 10677 164 410 65 1.48(1.32-1.78)

339.8592 36.643 34.899 104 1.021 7794 2203 303 757 7

341.8562 36.643 34.899 104 1.021 5914 1589 164 410 10 1.32(1.32-1.78)

A Non-2,3,7,8-sub-PeCDD R

355.8541 34.819 35.934 -67 0.939 47741 9064 797 1992 11

357.8511 34.803 35.934 -68 0.938 30823 5602 643 1607 9 1.55(1.32-1.78)

355.8541 36.797 35.934 52 0.992 34895 9301 797 1992 12

357.8511 36.797 35.934 52 0.992 29964 8877 643 1607 14 1.16(1.32-1.78)

A Non-2,3,7,8-sub-HxCDD

389.8151 38.744 39.501 -45 0.964 207542 69166 270 675 256

391.8121 38.744 39.501 -45 0.964 172468 55763 833 2082 67 1.20(1.05-1.43)

389.8151 39.255 39.501 -15 0.977 37956 13047 270 675 48

391.8121 39.255 39.501 -15 0.977 32958 10364 833 2082 12 1.15(1.05-1.43)

389.8151 39.511 39.501 1 0.983 212571 58225 270 675 216

391.8121 39.497 39.501 0 0.983 179220 47688 833 2082 57 1.19(1.05-1.43)

A Non-2,3,7,8-sub-HxCDF

373.8201 38.246 39.521 -76 0.936 63366 21366 210 525 102

375.8172 38.246 39.521 -76 0.936 59245 19837 227 567 87 1.07(1.05-1.43)

373.8201 38.408 39.521 -67 0.940 250716 83039 210 525 395

375.8172 38.408 39.521 -67 0.940 228431 76101 227 567 335 1.10(1.05-1.43)

373.8201 38.811 39.521 -43 0.950 14034 3766 210 525 18

375.8172 38.811 39.521 -43 0.950 12259 3137 227 567 14 1.14(1.05-1.43)

373.8201 38.986 39.521 -32 0.954 89022 31248 210 525 149

375.8172 38.986 39.521 -32 0.954 81751 28955 227 567 128 1.09(1.05-1.43)

373.8201 39.295 39.521 -14 0.962 23846 8061 210 525 38

375.8172 39.295 39.521 -14 0.962 21964 6951 227 567 31 1.09(1.05-1.43)

373.8201 39.780 39.521 15 0.974 11292 4366 210 525 21

375.8172 39.780 39.521 15 0.974 10149 3639 227 567 16 1.11(1.05-1.43)

A Non-2,3,7,8-sub-HpCDD

423.7761 42.201 42.690 -29 1.052 1005172 343629 71 177 4840

425.7732 42.201 42.690 -29 1.052 980368 332742 66 165 5042 1.03(0.88-1.20)

A Non-2,3,7,8-sub-HpCDF

407.7812 42.308 42.811 -30 1.008 16647 5596 235 587 24

409.7783 42.308 42.811 -30 1.008 18747 6246 153 382 41 0.89(0.88-1.20)

407.7812 42.483 42.811 -20 1.013 256538 86786 235 587 369

409.7783 42.483 42.811 -20 1.013 271686 92806 153 382 607 0.94(0.88-1.20)

QC Flag Legend Processing Flags

R - Failed Signal Ratio Test

Page 10966 of 21459

Review Flags

M - Manually Integrated

U - Marked Undetected a - User Assigned ID

Reagents:

Page 10967 of 21459

Report Date: 13-Feb-2025 13:23:00 Chrom Revision: 2.3 12-Feb-2025 13:38:10

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Inject. Date: 12-Feb-2025 17:44:00 Dil. Factor: 1.0000

Sample Type: Client Sample

Instrument ID: DF17611B Operator: Xcalibur_System

Lims Batch ID: 605182 Lims Sample ID: 10

Non-2,3,7,8-sub-TCDF, RT: 29.577

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

2,3,7,8-TCDF 0.900 D 13C-2,3,7,8-TCDF 100.000 5265893 980758

Averages:

RRFn Qis Ris Area Ris Height

0.900 100.000 5265893 980758

Sum the Uncalibrated Results

RT

303.9011

Area 303.9011

Height 305.8981

Area 305.8981

Height Amount

Ratio Flags

25.584 12377 2139 19271 3341 0.6679 0.64 R

26.123 19834 3171 32744 5170 1.11 0.61 R

26.578 16435 2659 24842 3826 0.8711 0.66

26.848 40414 6723 62734 10944 2.18 0.64 R

27.473 67423 4250 104577 6261 3.63 0.64 R

27.793 101065 11692 160763 18523 5.53 0.63 R

28.316 25340 3853 39666 5557 1.37 0.64 R

28.468 20295 3047 29805 4622 1.06 0.68

28.721 41506 5984 66336 9417 2.28 0.63 R

29.345 26322 2479 40508 3940 1.41 0.65

29.717 101184 10684 160272 17038 5.52 0.63 R

30.307 26923 4317 42388 6941 1.46 0.64 R

30.678 27416 2519 40119 3430 1.43 0.68

31.151 12909 2233 18951 3229 0.6724 0.68

31.337 67363 12283 105524 18686 3.65 0.64 R

31.826 42338 6200 68163 10513 2.33 0.62 R

32.130 20046 3165 33278 5835 1.13 0.60 R

32.349 3166 477 4780 665 0.1677 0.66

32.652 208575 48545 318825 76088 11.1 0.65

32.855 34623 8094 54949 12992 1.89 0.63 R

33.226 4450 672 6538 776 0.2319 0.68

33.479 2792 748 7172 993 0.2103 0.39 R

33.563 7891 1725 12466 3132 0.4296 0.63 R

33.698 15245 3404 24389 5281 0.8364 0.63 R

Signal Totals:

945932 151063 1479060 237200

Total Responses:

Rx Area Rx Height Amount Ratio Flags

2424992 388263 0.64 R

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 51.178 = (2424992 * 100.000) / (5265893 * 0.900)

Page 10968 of 21459

QC Flag Legend

Processing Flags

Page 10969 of 21459

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Inject. Date: 12-Feb-2025 17:44:00 Dil. Factor: 1.0000

Sample Type: Client Sample

Instrument ID: DF17611B Operator: Xcalibur_System

Lims Batch ID: 605182 Lims Sample ID: 10

Non-2,3,7,8-sub-TCDD, RT: 30.437

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

2,3,7,8-TCDD 1.059 D 13C-2,3,7,8-TCDD 100.000 4752792 963990

Averages:

RRFn Qis Ris Area Ris Height

1.059 100.000 4752792 963990

Sum the Uncalibrated Results

RT

319.8960

Area 319.8960

Height 321.8930

Area 321.8930

Height Amount

Ratio Flags

27.692 48899 7424 60263 8811 2.17 0.81

28.080 15731 2364 32865 3807 0.9654 0.48 R

28.704 3536 472 10661 929 0.2820 0.33 R

29.784 4375 611 1707062 261383 34.0 0.00 R

30.324 13277 2050 18074 2710 0.6228 0.73

30.560 2002 390 6256 813 0.1641 0.32 R

31.016 4574 480 8696 1937 0.2636 0.53 R

31.472 3736 528 3402 498 0.1418 1.10 R

32.585 3144 629 3753 850 0.1370 0.84

32.754 637 215 3317 618 0.0786 0.19 R

33.226 1813 414 2937 418 0.0944 0.62 R

Signal Totals:

101724 15577 1857286 282774

Total Responses:

Rx Area Rx Height Amount Ratio Flags

1959010 298351 0.05 R

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 38.918 = (1959010 * 100.000) / (4752792 * 1.059)

QC Flag Legend

Processing Flags

Page 10970 of 21459

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Inject. Date: 12-Feb-2025 17:44:00 Dil. Factor: 1.0000

Sample Type: Client Sample

Instrument ID: DF17611B Operator: Xcalibur_System

Lims Batch ID: 605182 Lims Sample ID: 10

F2 PeCDFs, RT: 33.678

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

Averages:

RRFn Qis Ris Area Ris Height

1.159 100.000 4059399 1298596

Sum the Uncalibrated Results

RT

339.8592

Area 339.8592

Height 341.8562

Area 341.8562

Height Amount

Ratio Flags

33.125 267041 53900 169643 34830 9.28 1.57

33.698 1634 399 767 171 0.0510 2.13 R

34.171 2191 269 1617 285 0.0809 1.35

Signal Totals:

270866 54568 172027 35286

Total Responses:

Rx Area Rx Height Amount Ratio Flags

442893 89854 1.57 R

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 9.411 = (442893 * 100.000) / (4059399 * 1.159)

QC Flag Legend

Processing Flags

Page 10971 of 21459

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Inject. Date: 12-Feb-2025 17:44:00 Dil. Factor: 1.0000

Sample Type: Client Sample

Instrument ID: DF17611B Operator: Xcalibur_System

Lims Batch ID: 605182 Lims Sample ID: 10

Non-2,3,7,8-sub-PeCDF, RT: 34.899

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

1,2,3,7,8-PeCDF 1.106 D 13C-1,2,3,7,8-PeCDF 100.000 3702300 1275994

2,3,4,7,8-PeCDF 1.213 D 13C-2,3,4,7,8-PeCDF 100.000 4416499 1321198

Averages:

RRFn Qis Ris Area Ris Height

1.159 100.000 4059399 1298596

Sum the Uncalibrated Results

RT

339.8592

Area 339.8592

Height 341.8562

Area 341.8562

Height Amount

Ratio Flags

34.695 89361 15407 63439 10355 3.25 1.41

34.881 248630 46304 163571 30258 8.76 1.52

35.159 10633 3330 10093 2334 0.4404 1.05 R

35.375 15293 2005 7499 1413 0.4843 2.04 R

35.545 156868 34904 105536 22414 5.58 1.49

35.746 38195 11004 26365 7054 1.37 1.45

35.978 18338 6668 11109 3891 0.6257 1.65

36.148 61137 16423 41313 10677 2.18 1.48

36.643 7794 2203 5914 1589 0.2913 1.32

Signal Totals:

646249 138248 434839 89985

Total Responses:

Rx Area Rx Height Amount Ratio Flags

1081088 228233 1.49 R

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 22.972 = (1081088 * 100.000) / (4059399 * 1.159)

QC Flag Legend

Processing Flags

Page 10972 of 21459

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Inject. Date: 12-Feb-2025 17:44:00 Dil. Factor: 1.0000

Sample Type: Client Sample

Instrument ID: DF17611B Operator: Xcalibur_System

Lims Batch ID: 605182 Lims Sample ID: 10

Non-2,3,7,8-sub-PeCDD, RT: 35.934

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

1,2,3,7,8-PeCDD 1.274 D 13C-1,2,3,7,8-PeCDD 100.000 2507649 761212

Averages:

RRFn Qis Ris Area Ris Height

1.274 100.000 2507649 761212

Sum the Uncalibrated Results

RT

355.8541

Area 355.8541

Height 357.8511

Area 357.8511

Height Amount

Ratio Flags

34.819 47741 9064 30823 5602 2.46 1.55

36.797 34895 9301 29964 8877 2.03 1.16 R

Signal Totals:

82636 18365 60787 14479

Total Responses:

Rx Area Rx Height Amount Ratio Flags

143423 32844 1.36 R

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 4.489 = (143423 * 100.000) / (2507649 * 1.274)

QC Flag Legend

Processing Flags

Page 10973 of 21459

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Inject. Date: 12-Feb-2025 17:44:00 Dil. Factor: 1.0000

Sample Type: Client Sample

Instrument ID: DF17611B Operator: Xcalibur_System

Lims Batch ID: 605182 Lims Sample ID: 10

Non-2,3,7,8-sub-HxCDD, RT: 39.501

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

1,2,3,4,7,8-HxCDD 1.056 D 13C-1,2,3,4,7,8-HxCDD 100.000 3192215 1199366

1,2,3,6,7,8-HxCDD 1.124 D 13C-1,2,3,6,7,8-HxCDD 100.000 3061461 1132705

1,2,3,7,8,9-HxCDD 1.037 D 13C-1,2,3,7,8,9-HxCDD 100.000 3237765 1152890

Averages:

RRFn Qis Ris Area Ris Height

1.073 100.000 3163813 1161653

Sum the Uncalibrated Results

RT

389.8151

Area 389.8151

Height 391.8121

Area 391.8121

Height Amount

Ratio Flags

38.744 207542 69166 172468 55763 11.2 1.20

39.255 37956 13047 32958 10364 2.09 1.15

39.511 212571 58225 179220 47688 11.5 1.19

Signal Totals:

458069 140438 384646 113815

Total Responses:

Rx Area Rx Height Amount Ratio Flags

842715 254253 1.19

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 24.833 = (842715 * 100.000) / (3163813 * 1.073)

Page 10974 of 21459

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Inject. Date: 12-Feb-2025 17:44:00 Dil. Factor: 1.0000

Sample Type: Client Sample

Instrument ID: DF17611B Operator: Xcalibur_System

Lims Batch ID: 605182 Lims Sample ID: 10

Non-2,3,7,8-sub-HxCDF, RT: 39.521

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

1,2,3,4,7,8-HxCDF 0.972 D 13C-1,2,3,4,7,8-HxCDF 100.000 3428182 1205862

1,2,3,6,7,8-HxCDF 0.989 D 13C-1,2,3,6,7,8-HxCDF 100.000 3616307 1300835

2,3,4,6,7,8-HxCDF 1.015 D 13C-2,3,4,6,7,8-HxCDF 100.000 3319498 1256325

1,2,3,7,8,9-HxCDF 0.930 D 13C-1,2,3,7,8,9-HxCDF 100.000 3134060 992717

Averages:

RRFn Qis Ris Area Ris Height

0.976 100.000 3374511 1188934

Sum the Uncalibrated Results

RT

373.8201

Area 373.8201

Height 375.8172

Area 375.8172

Height Amount

Ratio Flags

38.246 63366 21366 59245 19837 3.72 1.07

38.408 250716 83039 228431 76101 14.5 1.10

38.811 14034 3766 12259 3137 0.7980 1.14

38.986 89022 31248 81751 28955 5.18 1.09

39.295 23846 8061 21964 6951 1.39 1.09

39.780 11292 4366 10149 3639 0.6508 1.11

Signal Totals:

452276 151846 413799 138620

Total Responses:

Rx Area Rx Height Amount Ratio Flags

866075 290466 1.09

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 26.287 = (866075 * 100.000) / (3374511 * 0.976)

Page 10975 of 21459

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Inject. Date: 12-Feb-2025 17:44:00 Dil. Factor: 1.0000

Sample Type: Client Sample

Instrument ID: DF17611B Operator: Xcalibur_System

Lims Batch ID: 605182 Lims Sample ID: 10

Non-2,3,7,8-sub-HpCDD, RT: 42.690

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

1,2,3,4,6,7,8-HpCDD 1.053 D 13C-1,2,3,4,6,7,8-HpCDD 100.000 2548390 847045

Averages:

RRFn Qis Ris Area Ris Height

1.053 100.000 2548390 847045

Sum the Uncalibrated Results

RT

423.7761

Area 423.7761

Height 425.7732

Area 425.7732

Height Amount

Ratio Flags

42.201 1005172 343629 980368 332742 74.0 1.03

Signal Totals:

1005172 343629 980368 332742

Total Responses:

Rx Area Rx Height Amount Ratio Flags

1985540 676371 1.03

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 73.988 = (1985540 * 100.000) / (2548390 * 1.053)

Page 10976 of 21459

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Lims ID: 180-185280-D-7-B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Inject. Date: 12-Feb-2025 17:44:00 Dil. Factor: 1.0000

Sample Type: Client Sample

Instrument ID: DF17611B Operator: Xcalibur_System

Lims Batch ID: 605182 Lims Sample ID: 10

Non-2,3,7,8-sub-HpCDF, RT: 42.811

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

1,2,3,4,6,7,8-HpCDF 1.053 D 13C-1,2,3,4,6,7,8-HpCDF 100.000 2439490 845843

1,2,3,4,7,8,9-HpCDF 1.120 D 13C-1,2,3,4,7,8,9-HpCDF 100.000 2129340 636919

Averages:

RRFn Qis Ris Area Ris Height

1.086 100.000 2284415 741381

Sum the Uncalibrated Results

RT

407.7812

Area 407.7812

Height 409.7783

Area 409.7783

Height Amount

Ratio Flags

42.308 16647 5596 18747 6246 1.43 0.89

42.483 256538 86786 271686 92806 21.3 0.94

Signal Totals:

273185 92382 290433 99052

Total Responses:

Rx Area Rx Height Amount Ratio Flags

563618 191434 0.94

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 22.710 = (563618 * 100.000) / (2284415 * 1.086)

Page 10977 of 21459

Manual Integration/User Assign Peak Report

Eurofins Lancaster Laboratories Environment Testing, LLC

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Instrument ID: DF17611B

Lims ID: 180-185280-D-7-B Lab Sample ID: 410-185280-7

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Operator ID: Xcalibur_System ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Column: ZB-Dioxin 60m 0.20um ( 0.25 mm) Detector F2(21.11 :31.50 )

2,3,7,8-TCDF, CAS: 51207-31-9

Signal: 1

Processing Integration Results

RT: 31.49

Area: 42536

Amount: 2.327297

Amount Units: ng/ml

31.1 31.3 31.5 31.7 31.9 Min

Y

X

F2:m/z 303.9011

.4

Manual Integration Results

RT: 31.49

Area: 37621

Amount: 2.083964

Amount Units: ng/ml

31.1 31.3 31.5 31.7 31.9 Min

RT

Y

X

F2:m/z 303.9011

.4

Reviewer: ABB4, 12-Feb-2025 18:38:07 -05:00:00 (UTC)

Audit Action: Split an Integrated Peak Audit Reason: Split Peak

Page 10978 of 21459

Eurofins Lancaster Laboratories Environment Testing, LLC

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Instrument ID: DF17611B

Lims ID: 180-185280-D-7-B Lab Sample ID: 410-185280-7

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Operator ID: Xcalibur_System ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Column: ZB-Dioxin 60m 0.20um ( 0.25 mm) Detector F2(21.11 :31.50 )

2,3,7,8-TCDF, CAS: 51207-31-9

Signal: 2

Processing Integration Results

RT: 31.49

Area: 67740

Amount: 2.327297

Amount Units: ng/ml

31.1 31.3 31.5 31.7 31.9 Min

Y

X

F2:m/z 305.8981

.4

Manual Integration Results

RT: 31.49

Area: 61125

Amount: 2.083964

Amount Units: ng/ml

31.1 31.3 31.5 31.7 31.9 Min

RT

Y

X

F2:m/z 305.8981

.4

Reviewer: ABB4, 12-Feb-2025 18:38:09 -05:00:00 (UTC)

Page 10979 of 21459

Eurofins Lancaster Laboratories Environment Testing, LLC

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Instrument ID: DF17611B

Lims ID: 180-185280-D-7-B Lab Sample ID: 410-185280-7

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Operator ID: Xcalibur_System ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Column: ZB-Dioxin 60m 0.20um ( 0.25 mm) Detector F2(21.11 :31.50 )

2,3,7,8-TCDD, CAS: 1746-01-6

Signal: 2

Processing Integration Results

RT: 32.25

Area: 255891

Amount: 7.903893

Amount Units: ng/ml

31.5 31.7 31.9 32.1 32.3 32.5 32.7 Min

Y

X

F2:m/z 321.8930

.2

Manual Integration Results

RT: 32.25

Area: 186272

Amount: 6.520820

Amount Units: ng/ml

31.5 31.7 31.9 32.1 32.3 32.5 32.7 Min

RT

Y

X

F2:m/z 321.8930

.2

Reviewer: ABB4, 12-Feb-2025 18:38:13 -05:00:00 (UTC)

Page 10980 of 21459

Eurofins Lancaster Laboratories Environment Testing, LLC

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Instrument ID: DF17611B

Lims ID: 180-185280-D-7-B Lab Sample ID: 410-185280-7

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Operator ID: Xcalibur_System ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Column: ZB-Dioxin 60m 0.20um ( 0.25 mm) Detector F3(31.61 :36.10 )

2,3,4,7,8-PeCDF, CAS: 57117-31-4 Signal: 1

Processing Integration Results

RT: 36.94

Area: 127846

Amount: 3.607495

Amount Units: ng/ml

36.4 36.6 36.8 37.0 37.2 Min

Y

X

F3:m/z 339.8592

.9

Manual Integration Results

RT: 36.94

Area: 99871

Amount: 3.085163

Amount Units: ng/ml

36.4 36.6 36.8 37.0 37.2 Min

RT

Y

X

F3:m/z 339.8592

.9

Reviewer: ABB4, 12-Feb-2025 18:38:17 -05:00:00 (UTC)

Page 10981 of 21459

Eurofins Lancaster Laboratories Environment Testing, LLC

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Instrument ID: DF17611B

Lims ID: 180-185280-D-7-B Lab Sample ID: 410-185280-7

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Operator ID: Xcalibur_System ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Column: ZB-Dioxin 60m 0.20um ( 0.25 mm) Detector F4(36.20 :39.59 )

2,3,4,6,7,8-HxCDF, CAS: 60851-34-5 Signal: 1

Processing Integration Results

RT: 40.06

Area: 35516

Amount: 1.987619

Amount Units: ng/ml

39.7 39.9 40.1 40.3 40.5 Min

Y

X

F4:m/z 373.8201

.0

Manual Integration Results

RT: 40.06

Area: 38148

Amount: 2.199792

Amount Units: ng/ml

39.7 39.9 40.1 40.3 40.5 Min

RT

Y

X

F4:m/z 373.8201

.0

Reviewer: ABB4, 12-Feb-2025 18:38:28 -05:00:00 (UTC)

Audit Action: Manually Integrated Audit Reason: Split Peak

Page 10982 of 21459

Eurofins Lancaster Laboratories Environment Testing, LLC

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Instrument ID: DF17611B

Lims ID: 180-185280-D-7-B Lab Sample ID: 410-185280-7

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Operator ID: Xcalibur_System ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Column: ZB-Dioxin 60m 0.20um ( 0.25 mm) Detector F4(36.20 :39.59 )

2,3,4,6,7,8-HxCDF, CAS: 60851-34-5 Signal: 2

Processing Integration Results

RT: 40.05

Area: 31474

Amount: 1.987619

Amount Units: ng/ml

39.6 39.8 40.0 40.2 40.4 40.6 Min

Y

X

F4:m/z 375.8172

.0

Manual Integration Results

RT: 40.05

Area: 35993

Amount: 2.199792

Amount Units: ng/ml

39.6 39.8 40.0 40.2 40.4 40.6 Min

RT

-1

Y

X

F4:m/z 375.8172

.0

Reviewer: ABB4, 12-Feb-2025 18:38:31 -05:00:00 (UTC)

Page 10983 of 21459

Page 10984 of 21459

Eurofins Lancaster Laboratories Environment Testing, LLC

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Instrument ID: DF17611B

Lims ID: 180-185280-D-7-B Lab Sample ID: 410-185280-7

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Operator ID: Xcalibur_System ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Column: ZB-Dioxin 60m 0.20um ( 0.25 mm) Detector F4(36.20 :39.59 )

1,2,3,4,7,8-HxCDD, CAS: 39227-28-6 Signal: 2

Processing Integration Results

Not Detected

Expected RT: 40.10

39.8 40.0 40.2 40.4 Min

Y

X

F4:m/z 391.8121

Manual Integration Results

RT: 40.12

Area: 10673

Amount: 0.736212

Amount Units: ng/ml

39.8 40.0 40.2 40.4 Min

RT

Y

X

F4:m/z 391.8121

.1

Reviewer: ABB4, 12-Feb-2025 18:38:52 -05:00:00 (UTC)

Page 10985 of 21459

Page 10986 of 21459

Eurofins Lancaster Laboratories Environment Testing, LLC

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Instrument ID: DF17611B

Lims ID: 180-185280-D-7-B Lab Sample ID: 410-185280-7

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Operator ID: Xcalibur_System ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Column: ZB-Dioxin 60m 0.20um ( 0.25 mm) Detector F4(36.20 :39.59 )

1,2,3,6,7,8-HxCDD, CAS: 57653-85-7 Signal: 1

Processing Integration Results

RT: 40.21

Area: 51479

Amount: 2.637741

Amount Units: ng/ml

39.9 40.1 40.3 40.5 Min

Y

X

F4:m/z 389.8151

.2

Manual Integration Results

RT: 40.21

Area: 51569

Amount: 2.640357

Amount Units: ng/ml

39.9 40.1 40.3 40.5 Min

RT

Y

X

F4:m/z 389.8151

.2

Reviewer: ABB4, 12-Feb-2025 18:38:59 -05:00:00 (UTC)

Page 10987 of 21459

User Disabled Compound Report

Eurofins Lancaster Laboratories Environment Testing, LLC

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Instrument ID: DF17611B

Lims ID: 180-185280-D-7-B Lab Sample ID: 410-185280-7

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Operator ID: Xcalibur_System ALS Bottle#: 0 Worklist Smp#: 10

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Column: ZB-Dioxin 60m 0.20um ( 0.25 mm) Detector F4(36.20 :39.59 )

1,2,3,7,8,9-HxCDF, CAS: 72918-21-9

Processing Results

40.3 40.6 40.9 41.2 Min

RT

Y

X

F4:m/z 373.8201

.9

40.3 40.6 40.9 41.2 Min

RT

Y

X

F4:m/z 375.8172

.9

RT Mass Response Amount

40.91 373.82 18500

40.91 375.82 15009

40.91 373.82 33509 1.149789

Reviewer: U4LD, 13-Feb-2025 13:22:48 -05:00:00 (UTC)

Audit Action: Marked Compound Undetected Audit Reason: Invalid Compound ID

Page 10988 of 21459

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Injection Vol: 1.0 ul

Instrument ID: DF17611B Operator ID: Xcalibur_System

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Worklist#: 605182 Sample Line#: 10

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

TCDF

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 303.9011

Non-2,3,7,8-sub-TCDF 32.65

Non-2,3,7,8-sub-TCDF 28.32

Non-2,3,7,8-sub-TCDF 31.15

Non-2,3,7,8-sub-TCDF 25.58

34.1421.17 33.8533.3922.4121.86

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 305.8981

Non-2,3,7,8-sub-TCDF 32.65

Non-2,3,7,8-sub-TCDF 28.32

Non-2,3,7,8-sub-TCDF 25.58

Non-2,3,7,8-sub-TCDF 31.15

34.1421.52 33.87

TCDF Standards

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 315.9413

13C-2,3,7,8-TCDF

31.47

24.02

21.45 25.57 26.2622.70 23.04 34.0030.2629.67

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 317.9384

13C-2,3,7,8-TCDF

31.47

24.02

21.45 25.57 26.2422.70 23.05 30.26 33.95

Page 10989 of 21459

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Injection Vol: 1.0 ul

Instrument ID: DF17611B Operator ID: Xcalibur_System

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Worklist#: 605182 Sample Line#: 10

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

TCDF

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 303.9011

Non-2,3,7,8-sub-TCDF 32.65

Non-2,3,7,8-sub-TCDF

31.34 Non-2,3,7,8-sub-TCDF

32.85Non-2,3,7,8-sub-TCDF 28.32

Non-2,3,7,8-sub-TCDF 31.15

Non-2,3,7,8-sub-TCDF 25.5821.17

33.8533.3922.4121.86

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 305.8981

Non-2,3,7,8-sub-TCDF 32.65

Non-2,3,7,8-sub-TCDF 31.34

Non-2,3,7,8-sub-TCDF 27.79

Non-2,3,7,8-sub-TCDF 32.85Non-2,3,7,8-sub-TCDF

28.32 Non-2,3,7,8-sub-TCDF 25.58

Non-2,3,7,8-sub-TCDF

31.1521.52 33.87

TCDF Interference Mass

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 375.836421.50

32.64

22.38

21.15

32.84

31.9431.5726.04 33.55 34.1229.8927.6122.62 31.32 33.8533.2130.17

Page 10990 of 21459

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Injection Vol: 1.0 ul

Instrument ID: DF17611B Operator ID: Xcalibur_System

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Worklist#: 605182 Sample Line#: 10

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

TCDD

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 319.8960

2,3,7,8-TCDD

32.25

31.93Non-2,3,7,8-sub-TCDD 27.69

Non-2,3,7,8-sub-TCDD 33.23

Non-2,3,7,8-sub-TCDD 30.56

21.37 24.02

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 321.8930

Non-2,3,7,8-sub-TCDD 29.85

31.93 Non-2,3,7,8-sub-TCDD 27.67

Non-2,3,7,8-sub-TCDD 30.59

Non-2,3,7,8-sub-TCDD 33.23

TCDD Standards

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 331.9363

13C-1,2,3,4-TCDD

31.35 13C-2,3,7,8-TCDD

32.21

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 333.9333

13C-1,2,3,4-TCDD

31.35 13C-2,3,7,8-TCDD

32.21

Page 10991 of 21459

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Injection Vol: 1.0 ul

Instrument ID: DF17611B Operator ID: Xcalibur_System

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Worklist#: 605182 Sample Line#: 10

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

13C-TCDD

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 331.9363

13C-1,2,3,4-TCDD

31.35 13C-2,3,7,8-TCDD

32.21

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 333.9333

13C-1,2,3,4-TCDD

31.35 13C-2,3,7,8-TCDD

32.21

13C-TCDD Standards

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 331.9363

13C-1,2,3,4-TCDD

31.35 13C-2,3,7,8-TCDD

32.21

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 333.9333

13C-1,2,3,4-TCDD

31.35 13C-2,3,7,8-TCDD

32.21

Page 10992 of 21459

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Injection Vol: 1.0 ul

Instrument ID: DF17611B Operator ID: Xcalibur_System

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Worklist#: 605182 Sample Line#: 10

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

PeCDF

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 339.8592

F2 PeCDFs 33.12

21.50

22.38 32.65

21.17

24.8823.59 32.84

F2 PeCDFs

33.7022.14 26.58 29.7326.02 30.6621.7221.37 32.1122.95 24.4522.62 29.51

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 341.8562

F2 PeCDFs 33.12

21.50

22.38 32.65

21.15 24.89 26.5823.6122.13 24.45 26.04 29.7321.72 22.72 32.11

F2 PeCDFs

33.6821.35 29.53

Page 10993 of 21459

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Injection Vol: 1.0 ul

Instrument ID: DF17611B Operator ID: Xcalibur_System

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Worklist#: 605182 Sample Line#: 10

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

PeCDF

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 339.8592

F2 PeCDFs 33.12

21.50

22.38

32.6521.17 24.8823.59 F2 PeCDFs

33.7022.14 26.58 29.7326.02 30.6621.7221.37 32.1122.95 24.4522.62 29.51

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 341.8562

F2 PeCDFs 33.12

21.50

22.38 32.65

21.15 24.89 26.5823.6122.13 24.45 26.04 29.7321.72 32.11 F2 PeCDFs

33.6821.35 29.53

PeCDF Interference Mass

21.0 23.0 25.0 27.0 29.0 31.0 33.0 35.0 Min

Y

X

F2:m/z 341.8562 33.12

21.50

22.38 32.65

21.15 24.89 26.5823.6122.13 34.1724.45 26.04 29.7321.72 22.72 32.11 33.6821.35 29.53

Page 10994 of 21459

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Injection Vol: 1.0 ul

Instrument ID: DF17611B Operator ID: Xcalibur_System

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Worklist#: 605182 Sample Line#: 10

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

PeCDF

34.4 34.7 35.0 35.3 35.6 35.9 36.2 36.5 36.8 37.1 37.4 37.7 Min

Y

X

F3:m/z 339.8592 Non-2,3,7,8-sub-PeCDF 34.88

L 2,3,4,7,8-PeCDF 36.94

37.60

36.77Non-2,3,7,8-sub-PeCDF 35.98Non-2,3,7,8-sub-PeCDF

35.16 37.38

34.4 34.7 35.0 35.3 35.6 35.9 36.2 36.5 36.8 37.1 37.4 37.7 Min

Y

X

F3:m/z 341.8562 Non-2,3,7,8-sub-PeCDF 34.88

L 2,3,4,7,8-PeCDF 36.94

37.60

36.75Non-2,3,7,8-sub-PeCDF 35.98

Non-2,3,7,8-sub-PeCDF

35.16 37.38

PeCDF Standards

34.4 34.7 35.0 35.3 35.6 35.9 36.2 36.5 36.8 37.1 37.4 37.7 Min

Y

X

F3:m/z 351.8994

13C-2,3,4,7,8-PeCDF 36.92

13C-1,2,3,7,8-PeCDF 35.89

34.4 34.7 35.0 35.3 35.6 35.9 36.2 36.5 36.8 37.1 37.4 37.7 Min

Y

X

F3:m/z 353.8965

13C-2,3,4,7,8-PeCDF 36.9213C-1,2,3,7,8-PeCDF

35.89

Page 10995 of 21459

Data File: \\chromfs\Lancaster\ChromData\DF17611B\20250212-137977.b\25feb12zb-10.d

Injection Date: 12-Feb-2025 17:44:00 Injection Vol: 1.0 ul

Instrument ID: DF17611B Operator ID: Xcalibur_System

Method: Dioxin_DF17611B Limit Group: HR - 1613B

Client ID: #20250046 COMPOSITE P/DISCRETE #46

Worklist#: 605182 Sample Line#: 10

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

PeCDF

34.4 34.7 35.0 35.3 35.6 35.9 36.2 36.5 36.8 37.1 37.4 37.7 Min

Y

X

F3:m/z 339.8592

Non-2,3,7,8-sub-PeCDF 34.88

Non-2,3,7,8-sub-PeCDF 35.55

L 2,3,4,7,8-PeCDF 36.94

37.60 Non-2,3,7,8-sub-PeCDF

34.70 1,2,3,7,8-PeCDF

35.90

Non-2,3,7,8-sub-PeCDF

35.16 37.38Non-2,3,7,8-sub-PeCDF

36.64

34.4 34.7 35.0 35.3 35.6 35.9 36.2 36.5 36.8 37.1 37.4 37.7 Min

Y

X

F3:m/z 341.8562

Non-2,3,7,8-sub-PeCDF 34.88

N…