J185041_1 Std_Tal_L4 Final Report_Part10.pdf

Segment 4

Lock mass 425.9770 [m/z] Resolution: 11611 [5%height]

Cali. mass 513.9706 [m/z] Resolution: 12804 [5%height]

Ref. mass 451.9738 [m/z] Resolution: 13715 [5%height]

Ref. mass 463.9738 [m/z] Resolution: 11241 [5%height]

Ref. mass 475.9738 [m/z] Resolution: 11914 [5%height]

Ref. mass 501.9706 [m/z] Resolution: 11093 [5%height]

25FEB19ZB(ICAL)-01Ra_0 Page 3 of 4Page 10660 of 15442

25FEB19ZB(ICAL)-01Ra_0 Page 4 of 4Page 10661 of 15442

Resolution Check Report ( DFS SN: 1209 )

Date: 20 Feb 2025 03:37

MID Experiment: ResCheck_FC43-21OCT06-PCDD+F

Target Resolution: 10000

Resolution Warning : 9500

Resolution Error : 8000

Reference: FC43

Status: RESOLUTION WARNING

Segment 1

Lock mass 313.9834 [m/z] Resolution: 10968 [5%height]

Cali. mass 375.9802 [m/z] Resolution: 11431 [5%height]

Ref. mass 325.9834 [m/z] Resolution: 10274 [5%height]

Ref. mass 344.9818 [m/z] Resolution: 10377 [5%height]

Ref. mass 351.9802 [m/z] Resolution: 11634 [5%height]

Ref. mass 363.9802 [m/z] Resolution: 11374 [5%height]

Segment 2

25FEB19ZB(ICAL)-11R_0 Page 1 of 4Page 10662 of 15442

Lock mass 375.9802 [m/z] Resolution: 11342 [5%height]

Cali. mass 463.9738 [m/z] Resolution: 10798 [5%height]

Ref. mass 401.9770 [m/z] Resolution: 8874 [5%height]

Ref. mass 413.9770 [m/z] Resolution: 11200 [5%height]

Ref. mass 425.9770 [m/z] Resolution: 10751 [5%height]

Ref. mass 451.9738 [m/z] Resolution: 12401 [5%height]

Segment 3

Lock mass 413.9770 [m/z] Resolution: 11071 [5%height]

Cali. mass 501.9706 [m/z] Resolution: 10847 [5%height]

Ref. mass 425.9770 [m/z] Resolution: 11378 [5%height]

Ref. mass 451.9738 [m/z] Resolution: 11305 [5%height]

Ref. mass 463.9738 [m/z] Resolution: 11065 [5%height]

Ref. mass 475.9738 [m/z] Resolution: 11070 [5%height]

25FEB19ZB(ICAL)-11R_0 Page 2 of 4Page 10663 of 15442

Lock mass 425.9770 [m/z] Resolution: 11203 [5%height]

Cali. mass 513.9706 [m/z] Resolution: 11018 [5%height]

Ref. mass 451.9738 [m/z] Resolution: 12798 [5%height]

Ref. mass 463.9738 [m/z] Resolution: 10849 [5%height]

Ref. mass 475.9738 [m/z] Resolution: 10694 [5%height]

Ref. mass 501.9706 [m/z] Resolution: 10778 [5%height]

25FEB19ZB(ICAL)-11R_0 Page 3 of 4Page 10664 of 15442

25FEB19ZB(ICAL)-11R_0 Page 4 of 4Page 10665 of 15442

Report Date: 24-Feb-2025 15:10:53 Chrom Revision: 2.3 18-Feb-2025 08:41:40

Eurofins Lancaster Laboratories Environment Testing, LLC

Target Compound Quantitation Report

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Lims ID: WDM

Client ID:

Sample Type: WDM

Inject. Date: 24-Feb-2025 13:09:00 ALS Bottle#: 0 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info:

Operator ID: Xcalibur_System Instrument ID: DF18471

Method: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\ZBDioxin_18471.m

Limit Group: HR - 1613B

Last Update: 24-Feb-2025 15:10:52 Calib Date: 20-Feb-2025 01:07:00

Integrator: Picker

Quant Method: Isotopic Dilution Quant By: Initial Calibration

Last ICal File: \\chromfs\Lancaster\ChromData\DF18471\20250219-138628.b\25feb19zb(ical)-08.d

Column 1 : ZB-Dioxin 60m 0.20um ( 0.25 mm) Det: F1(18.08 :21.30 )

Process Host: CTX1606

First Level Reviewer: TJK2 Date: 24-Feb-2025 15:09:53

Compound

RT

(min.) Area Ratio Ical

RRF

Amount ng/ml

EMPC

ng/ml

Noise

EDL

Final EDL %Rec Flags

* 13C-1,2,3,4-TCDD 28.960 1262496 0.79 25.0 25.0

D 13C-2,3,7,8-TCDF 29.129 1910446 0.78 1.5372 24.6 24.6 0.0144 0.0144 98.44

D 13C-2,3,7,8-TCDD 30.142 1198540 0.78 1.3559 17.5 17.5 0.0174 0.0174 70.01

1,3,6,8-TCDF 23.422 8921676 0.78

1,3,6,8-TCDD 25.296 2707843 0.79

2,3,4,8-TCDF 28.943 3673139 0.78

2,3,7,8-TCDF 29.163 7987523 0.79 1.0765 97.1 97.1 0.1013 0.1013

1,2,8,9-TCDD 29.838 4367350 0.76

2,3,7,8-TCDD 30.176 2774839 0.77 0.9650 60.0 60.0 0.0313 0.0313

1,3,4,6,8-PeCDF 31.240 3647103 1.53

1,2,3,9-TCDD 31.409 2601301 0.77

1,2,8,9-TCDF 31.848 7625453 0.78

1,2,4,7,9-PeCDD 33.282 3313563 1.55

1,2,3,7,8-PeCDF 34.531 3264570 1.57 1.0105

2,3,4,7,8-PeCDF 35.688 3447560 1.57 1.1263

1,2,3,7,8-PeCDD 35.873 2167443 1.57 1.1029

1,2,3,8,9-PeCDD 36.258 2609209 1.57

1,2,3,8,9-PeCDF 36.675 3334505 1.56

1,2,3,4,6,8-HxCDF 37.086 3159908 1.24

1,2,4,6,7,9-HxCDD 37.610 2354841 1.23

1,2,3,4,7,8-HxCDF 38.337 3055150 1.23 1.2283

1,2,3,6,7,8-HxCDF 38.445 3294109 1.25 1.2425

2,3,4,6,7,8-HxCDF 39.010 3187477 1.26 1.2801

1,2,3,4,7,8-HxCDD 39.077 2120030 1.24 1.0334

1,2,3,6,7,8-HxCDD 39.171 2335987 1.24 1.0910

1,2,3,4,6,7-HxCDD 39.306 2128892 1.25

1,2,3,7,8,9-HxCDD 39.400 2351469 1.26 0.9911

1,2,3,7,8,9-HxCDF 39.817 5517868 1.24 1.1885

1,2,3,4,8,9-HxCDF 39.817 5517868 1.24

1,2,3,4,6,7,8-HpCDF 40.876 2891001 1.03 1.3387

1,2,3,4,6,7,9-HpCDD 41.104 2228343 1.05

1,2,3,4,6,7,8-HpCDD 41.858 2063334 1.04 1.0483

1,2,3,4,7,8,9-HpCDF 42.490 2528408 1.05 1.4621

OCDD 44.706 1736401 0.88 1.0206

OCDF 45.037 1974856 0.91 0.9909

A Non-2,3,7,8-sub-TCDD 27.567 2815352 0.78 0.9650 60.9 60.9 0.0313 31.2

Page 10666 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Compound

RT

(min.) Area Ratio Ical

RRF

Amount ng/ml

EMPC

ng/ml

Noise

EDL

Final EDL %Rec Flags

A Non-2,3,7,8-sub-TCDF 27.635 11238233 0.78 1.0765 136.6 136.6 0.1013 44.4 R

A F2 PeCDFs 32.000 11233 1.57 0.0000

A Non-2,3,7,8-sub-PeCDF 33.957 3671436 1.56 0.0000

A Non-2,3,7,8-sub-PeCDD 34.577 0.0 0.0

A Non-2,3,7,8-sub-HxCDF 38.451 0.0 0.0

A Non-2,3,7,8-sub-HxCDD 38.458 0.0 0.0

A Non-2,3,7,8-sub-HpCDD 41.481 0.0 0.0

A Non-2,3,7,8-sub-HpCDF 41.683 0.0 0.0

S Total TCDF 233.7 233.7 0.1013 0.1013 R

S Total TCDD 120.8 120.8 0.0313 0.0313

S Total PeCDF 0.0 0.0

S Total PeCDD 0.0 0.0

S Total HxCDF 0.0 0.0

S Total HxCDD 0.0 0.0

S Total HpCDD 0.0 0.0

S Total HpCDF 0.0 0.0

S Total PCDD 120.8 120.8 0.006262 0.006262

S Total PCDF 233.7 233.7 0.0203 0.0203 R

S Total PCDD/PCDF 354.5 354.5 0.0133 0.0133 R

S Total 2378-Chlorinated Dioxins & 157.1 157.1 0.007801 0.007801

QC Flag Legend Processing Flags R - Failed Signal Ratio Test

Reagents:

HRM_TDTFWD_00036 Amount Added: 1.00 Units: uL

Page 10667 of 15442

Target Compound Quantitation Worksheet Report

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Lims ID: WDM

Client ID:

Sample Type: WDM

Inject. Date: 24-Feb-2025 13:09:00 ALS Bottle#: 0 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info:

Operator ID: Xcalibur_System Instrument ID: DF18471

Method: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\ZBDioxin_18471.m

Limit Group: HR - 1613B

Last Update: 24-Feb-2025 15:10:52 Calib Date: 20-Feb-2025 01:07:00

Integrator: Picker

Quant Method: Isotopic Dilution Quant By: Initial Calibration

Last ICal File: \\chromfs\Lancaster\ChromData\DF18471\20250219-138628.b\25feb19zb(ical)-08.d

Column 1 : ZB-Dioxin 60m 0.20um ( 0.25 mm) Det: F1(18.08 :21.30 )

Process Host: CTX1606

First Level Reviewer: TJK2 Date: 24-Feb-2025 15:09:53

Signal

RT

(min.)

Exp RT (min.)

R Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

13C-1,2,3,4-TCDD

331.9362 28.960 28.960 0 558792 75112 33 82 2276

333.9333 28.960 28.960 0 703704 94713 31 77 3055 0.79(0.65-0.89)

13C-2,3,7,8-TCDF

315.9413 29.129 29.129 0 1.006 839239 113644 35 87 3247

317.9384 29.112 29.129 -1 1.005 1071207 140139 25 62 5606 0.78(0.65-0.89)

13C-2,3,7,8-TCDD

331.9362 30.142 30.142 0 1.041 524966 75313 33 82 2282

333.9333 30.142 30.142 0 1.041 673574 98455 31 77 3176 0.78(0.65-0.89)

1,3,6,8-TCDF

303.9011 23.422 23.422 0 0.804 3907180 616926 200 500 3085

305.8981 23.405 23.422 -1 0.804 5014496 785223 243 607 3231 0.78(0.65-0.89)

1,3,6,8-TCDD

319.8960 25.296 25.296 0 0.839 1195161 185540 37 92 5015

321.8930 25.296 25.296 0 0.839 1512682 230558 47 117 4905 0.79(0.65-0.89)

2,3,4,8-TCDF

303.9011 28.943 28.943 0 0.994 1609868 218099 200 500 1090

305.8981 28.943 28.943 0 0.994 2063271 282546 243 607 1163 0.78(0.65-0.89)

2,3,7,8-TCDF

303.9011 29.163 29.163 0 1.001 3519976 429627 200 500 2148

305.8981 29.146 29.163 -1 1.001 4467547 555044 243 607 2284 0.79(0.65-0.89)

1,2,8,9-TCDD

319.8960 29.838 29.838 0 0.990 1879181 196392 37 92 5308

321.8930 29.838 29.838 0 0.990 2488169 252508 47 117 5373 0.76(0.65-0.89)

2,3,7,8-TCDD

319.8960 30.176 30.176 0 1.001 1209423 173257 37 92 4683

321.8930 30.176 30.176 0 1.001 1565416 224651 47 117 4780 0.77(0.65-0.89)

Page 10668 of 15442

Signal

RT

(min.)

Exp RT (min.)

R Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

1,3,4,6,8-PeCDF

339.8591 31.240 31.240 0 1.000 2206877 394205 14 35 28158

341.8562 31.240 31.240 0 1.000 1440226 258277 16 40 16142 1.53(1.32-1.78)

1,2,3,9-TCDD

319.8960 31.409 31.409 0 1.042 1135062 201427 37 92 5444

321.8930 31.409 31.409 0 1.042 1466239 256914 47 117 5466 0.77(0.65-0.89)

1,2,8,9-TCDF

303.9011 31.848 31.848 0 1.093 3330344 576614 200 500 2883

305.8981 31.848 31.848 0 1.093 4295109 752499 243 607 3097 0.78(0.65-0.89)

1,2,4,7,9-PeCDD

355.8541 33.282 33.282 0 1.000 2012873 313275 135 337 2321

357.8511 33.282 33.282 0 1.000 1300690 201104 92 230 2186 1.55(1.32-1.78)

1,2,3,7,8-PeCDF

339.8591 34.531 34.531 0 1.000 1994333 470881 148 370 3182

341.8562 34.516 34.531 -1 1.000 1270237 291013 103 257 2825 1.57(1.32-1.78)

2,3,4,7,8-PeCDF

339.8591 35.688 35.688 0 1.000 2103832 544769 148 370 3681

341.8562 35.672 35.688 -1 1.000 1343728 340435 103 257 3305 1.57(1.32-1.78)

1,2,3,7,8-PeCDD

355.8541 35.873 35.873 0 1.000 1324858 340856 135 337 2525

357.8511 35.873 35.873 0 1.000 842585 220786 92 230 2400 1.57(1.32-1.78)

1,2,3,8,9-PeCDD

355.8541 36.258 36.258 0 1.000 1595113 438352 135 337 3247

357.8511 36.258 36.258 0 1.000 1014096 284519 92 230 3093 1.57(1.32-1.78)

1,2,3,8,9-PeCDF

339.8591 36.675 36.675 0 1.000 2033689 553461 148 370 3740

341.8562 36.675 36.675 0 1.000 1300816 351550 103 257 3413 1.56(1.32-1.78)

1,2,3,4,6,8-HxCDF

373.8202 37.086 37.086 0 1.000 1750741 523971 111 277 4720

375.8172 37.086 37.086 0 1.000 1409167 416576 102 255 4084 1.24(1.05-1.43)

1,2,4,6,7,9-HxCDD

389.8151 37.610 37.610 0 1.000 1297650 403736 85 212 4750

391.8121 37.610 37.610 0 1.000 1057191 333143 67 167 4972 1.23(1.05-1.43)

1,2,3,4,7,8-HxCDF

373.8202 38.337 38.337 0 1.000 1687313 553421 111 277 4986

375.8172 38.337 38.337 0 1.000 1367837 436565 102 255 4280 1.23(1.05-1.43)

1,2,3,6,7,8-HxCDF

373.8202 38.445 38.445 0 1.000 1832481 552202 111 277 4975

375.8172 38.445 38.445 0 1.000 1461628 454140 102 255 4452 1.25(1.05-1.43)

2,3,4,6,7,8-HxCDF

373.8202 39.010 39.010 0 1.000 1777700 589453 111 277 5310

375.8172 39.010 39.010 0 1.000 1409777 476907 102 255 4676 1.26(1.05-1.43)

1,2,3,4,7,8-HxCDD

389.8151 39.077 39.077 0 1.000 1172842 394455 85 212 4641

391.8121 39.077 39.077 0 1.000 947188 327122 67 167 4882 1.24(1.05-1.43)

Page 10669 of 15442

Signal

RT

(min.)

Exp RT (min.)

R Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

1,2,3,6,7,8-HxCDD

389.8151 39.171 39.171 0 1.000 1292590 429686 85 212 5055

391.8121 39.171 39.171 0 1.000 1043397 356861 67 167 5326 1.24(1.05-1.43)

1,2,3,4,6,7-HxCDD

389.8151 39.306 39.306 0 1.000 1181866 420832 85 212 4951

391.8121 39.306 39.306 0 1.000 947026 345532 67 167 5157 1.25(1.05-1.43)

1,2,3,7,8,9-HxCDD

389.8151 39.400 39.400 0 1.000 1312128 425519 85 212 5006

391.8121 39.400 39.400 0 1.000 1039341 340104 67 167 5076 1.26(1.05-1.43)

1,2,3,7,8,9-HxCDF

373.8202 39.817 39.817 0 1.000 3059373 938485 111 277 8455

375.8172 39.817 39.817 0 1.000 2458495 731683 102 255 7173 1.24(1.05-1.43)

1,2,3,4,8,9-HxCDF

373.8202 39.817 39.817 0 1.000 3059373 938485 111 277 8455

375.8172 39.817 39.817 0 1.000 2458495 731683 102 255 7173 1.24(1.05-1.43)

1,2,3,4,6,7,8-HpCDF

407.7812 40.876 40.876 0 1.000 1463578 468854 69 172 6795

409.7783 40.862 40.876 -1 1.000 1427423 452169 53 132 8531 1.03(0.88-1.20)

1,2,3,4,6,7,9-HpCDD

423.7761 41.104 41.104 0 1.000 1142237 356940 44 110 8112

425.7732 41.091 41.104 -1 1.000 1086106 344716 54 135 6384 1.05(0.88-1.20)

1,2,3,4,6,7,8-HpCDD

423.7761 41.858 41.858 0 1.000 1053088 324326 44 110 7371

425.7732 41.858 41.858 0 1.000 1010246 311754 54 135 5773 1.04(0.88-1.20)

1,2,3,4,7,8,9-HpCDF

407.7812 42.490 42.490 0 1.000 1294585 359597 69 172 5212

409.7783 42.490 42.490 0 1.000 1233823 350959 53 132 6622 1.05(0.88-1.20)

OCDD

457.7371 44.706 44.706 0 1.000 815206 217506 15 37 14500

459.7342 44.706 44.706 0 1.000 921195 242833 21 52 11563 0.88(0.76-1.02)

OCDF

441.7422 45.037 45.037 0 1.000 942083 229243 17 42 13485

443.7393 45.037 45.037 0 1.000 1032773 246273 22 55 11194 0.91(0.76-1.02)

A Non-2,3,7,8-sub-TCDD

319.8960 28.403 27.567 50 0.942 627526 88469 37 92 2391

321.8930 28.403 27.567 50 0.942 814424 112123 47 117 2386 0.77(0.65-0.89)

319.8960 28.994 27.567 85 0.962 604455 80765 37 92 2183

321.8930 28.994 27.567 85 0.962 768947 101737 47 117 2165 0.79(0.65-0.89)

A Non-2,3,7,8-sub-TCDF R

303.9011 27.728 27.635 6 0.952 150179 20540 200 500 103

305.8981 27.728 27.635 6 0.952 196989 25469 243 607 105 0.76(0.65-0.89)

303.9011 28.724 27.635 65 0.986 1559876 208771 200 500 1044

305.8981 28.707 27.635 64 0.986 2000039 270401 243 607 1113 0.78(0.65-0.89)

303.9011 30.041 27.635 144 1.031 1590842 231023 200 500 1155

305.8981 30.041 27.635 144 1.031 2012114 296612 243 607 1221 0.79(0.65-0.89)

Page 10670 of 15442

Signal

RT

(min.)

Exp RT (min.)

R Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

303.9011 30.328 27.635 161 1.041 1598350 227039 200 500 1135

305.8981 30.328 27.635 161 1.041 2050977 295438 243 607 1216 0.78(0.65-0.89)

303.9011 31.257 27.635 217 1.073 38236 6714 200 500 34

305.8981 31.257 27.635 217 1.073 40631 7885 243 607 32 0.94(0.65-0.89)

A F2 PeCDFs

339.8591 31.628 32.000 -22 1.000 6862 635 14 35 45

341.8562 31.713 32.000 -17 1.000 4371 385 16 40 24 1.57(1.32-1.78)

A Non-2,3,7,8-sub-PeCDF

339.8591 33.313 33.957 -39 1.000 313941 65256 148 370 441

341.8562 33.297 33.957 -40 1.000 197780 41157 103 257 400 1.59(1.32-1.78)

339.8591 35.487 33.957 92 1.000 1920942 523638 148 370 3538

341.8562 35.487 33.957 92 1.000 1238773 334229 103 257 3245 1.55(1.32-1.78)

A Non-2,3,7,8-sub-PeCDD

355.8541 34.577 135 337

357.8511 34.577 92 230

A Non-2,3,7,8-sub-HxCDF

373.8202 38.451 111 277

375.8172 38.451 102 255

A Non-2,3,7,8-sub-HxCDD

389.8151 38.458 85 212

391.8121 38.458 67 167

A Non-2,3,7,8-sub-HpCDD

423.7761 41.481 44 110

425.7732 41.481 54 135

A Non-2,3,7,8-sub-HpCDF

407.7812 41.683 69 172

409.7783 41.683 53 132

QC Flag Legend Processing Flags

R - Failed Signal Ratio Test

Reagents:

Page 10671 of 15442

Report Date: 24-Feb-2025 15:10:54 Chrom Revision: 2.3 18-Feb-2025 08:41:40

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Lims ID: WDM

Client ID:

Inject. Date: 24-Feb-2025 13:09:00 Dil. Factor: 1.0000

Sample Type: WDM, Window Defining Mix

Instrument ID: DF18471 Operator: Xcalibur_System

Lims Batch ID: 609311 Lims Sample ID: 2

Non-2,3,7,8-sub-TCDD, RT: 27.567

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

2,3,7,8-TCDD 0.965 D 13C-2,3,7,8-TCDD 25.000 1198540 173768

Averages:

RRFn Qis Ris Area Ris Height

0.965 25.000 1198540 173768

Sum the Uncalibrated Results

RT

319.8960

Area 319.8960

Height 321.8930

Area 321.8930

Height Amount

Ratio Flags

28.403 627526 88469 814424 112123 31.2 0.77

28.994 604455 80765 768947 101737 29.7 0.79

Signal Totals:

1231981 169234 1583371 213860

Total Responses:

Rx Area Rx Height Amount Ratio Flags

2815352 383094 0.78

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 60.854 = (2815352 * 25.000) / (1198540 * 0.965)

Page 10672 of 15442

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Lims ID: WDM

Client ID:

Inject. Date: 24-Feb-2025 13:09:00 Dil. Factor: 1.0000

Sample Type: WDM, Window Defining Mix

Instrument ID: DF18471 Operator: Xcalibur_System

Lims Batch ID: 609311 Lims Sample ID: 2

Non-2,3,7,8-sub-TCDF, RT: 27.635

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

2,3,7,8-TCDF 1.076 D 13C-2,3,7,8-TCDF 25.000 1910446 253783

Averages:

RRFn Qis Ris Area Ris Height

1.076 25.000 1910446 253783

Sum the Uncalibrated Results

RT

303.9011

Area 303.9011

Height 305.8981

Area 305.8981

Height Amount

Ratio Flags

27.728 150179 20540 196989 25469 4.22 0.76

28.724 1559876 208771 2000039 270401 43.3 0.78

30.041 1590842 231023 2012114 296612 43.8 0.79

30.328 1598350 227039 2050977 295438 44.4 0.78

31.257 38236 6714 40631 7885 0.9587 0.94 R

Signal Totals:

4937483 694087 6300750 895805

Total Responses:

Rx Area Rx Height Amount Ratio Flags

11238233 1589892 0.78 R

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 136.617 = (11238233 * 25.000) / (1910446 * 1.076)

QC Flag Legend

Processing Flags

R - Failed Signal Ratio Test

Page 10673 of 15442

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Lims ID: WDM

Client ID:

Inject. Date: 24-Feb-2025 13:09:00 Dil. Factor: 1.0000

Sample Type: WDM, Window Defining Mix

Instrument ID: DF18471 Operator: Xcalibur_System

Lims Batch ID: 609311 Lims Sample ID: 2

F2 PeCDFs, RT: 32.000

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

Averages:

RRFn Qis Ris Area Ris Height

0.000 0.0 0 0

Sum the Uncalibrated Results

RT

339.8591

Area 339.8591

Height 341.8562

Area 341.8562

Height Amount

Ratio Flags

31.628 6862 635 4371 385 1.57

Signal Totals:

6862 635 4371 385

Total Responses:

Rx Area Rx Height Amount Ratio Flags

11233 1020 1.57

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 0.0 = (11233 * 0.0) / (0 * 0.000)

Page 10674 of 15442

AreaSum WorkSheet Report

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Lims ID: WDM

Client ID:

Inject. Date: 24-Feb-2025 13:09:00 Dil. Factor: 1.0000

Sample Type: WDM, Window Defining Mix

Instrument ID: DF18471 Operator: Xcalibur_System

Lims Batch ID: 609311 Lims Sample ID: 2

Non-2,3,7,8-sub-PeCDF, RT: 33.957

Initial Calibration RRF IsoDil Std Amount Added and Responses

Target Compound RRF

Iso Dil Std Compound

Amount ng/ml Area Height

1,2,3,7,8-PeCDF 1.010

2,3,4,7,8-PeCDF 1.126

Averages:

RRFn Qis Ris Area Ris Height

0.000 0.0 0 0

Sum the Uncalibrated Results

RT

339.8591

Area 339.8591

Height 341.8562

Area 341.8562

Height Amount

Ratio Flags

33.313 313941 65256 197780 41157 1.59

35.487 1920942 523638 1238773 334229 1.55

Signal Totals:

2234883 588894 1436553 375386

Total Responses:

Rx Area Rx Height Amount Ratio Flags

3671436 964280 1.56

On-Column Amount = (Rx * Qis) / (Ris * RRFn)

Quant By: Area

Amount: 0.0 = (3671436 * 0.0) / (0 * 0.000)

Page 10675 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

TCDF

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 303.9011

F 1,3,6,8-TCDF

23.42

2,3,7,8-TCDF

29.16

Non-2,3,7,8-sub-TCDF 30.04

Non-2,3,7,8-sub-TCDF 30.33

2,3,4,8-TCDF

28.94

Non-2,3,7,8-sub-TCDF 28.72

Non-2,3,7,8-sub-TCDF 27.73

Non-2,3,7,8-sub-TCDF 31.26

L 1,2,8,9-TCDF

31.85

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 305.8981

F 1,3,6,8-TCDF

23.41

2,3,7,8-TCDF

29.15

Non-2,3,7,8-sub-TCDF 30.04

Non-2,3,7,8-sub-TCDF 30.33

2,3,4,8-TCDF

28.94

Non-2,3,7,8-sub-TCDF 28.71

Non-2,3,7,8-sub-TCDF 27.73

Non-2,3,7,8-sub-TCDF 31.26

L 1,2,8,9-TCDF

31.85

TCDF Standards

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 315.9413

13C-2,3,7,8-TCDF

29.13

29.94 30.46

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 317.9384

13C-2,3,7,8-TCDF

29.11

29.4029.7727.68 30.3829.70 30.19 31.3829.94 30.82

Page 10676 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

TCDF

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 303.9011

F 1,3,6,8-TCDF

23.42

2,3,7,8-TCDF

29.16

Non-2,3,7,8-sub-TCDF 30.04

Non-2,3,7,8-sub-TCDF 30.33

2,3,4,8-TCDF

28.94

Non-2,3,7,8-sub-TCDF 28.72

Non-2,3,7,8-sub-TCDF 27.73

Non-2,3,7,8-sub-TCDF 31.26

L 1,2,8,9-TCDF

31.85

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 305.8981

F 1,3,6,8-TCDF

23.41

2,3,7,8-TCDF

29.15

Non-2,3,7,8-sub-TCDF 30.04

Non-2,3,7,8-sub-TCDF 30.33

2,3,4,8-TCDF

28.94

Non-2,3,7,8-sub-TCDF 28.71

Non-2,3,7,8-sub-TCDF 27.73

Non-2,3,7,8-sub-TCDF 31.26

L 1,2,8,9-TCDF

31.85

TCDF Interference Mass

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 375.8364 28.86

27.39 30.95

25.9025.45 32.44

32.2031.53 30.07

25.55 31.0524.5423.51 29.31

27.51 30.31

25.77 28.25

27.58 28.9425.06 30.4327.1926.58

25.65 31.59

23.29 23.7923.08 23.69

27.05 32.03

31.80

Page 10677 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

TCDD

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 319.8960

F 1,3,6,8-TCDD

25.30

1,2,8,9-TCDD

29.84

2,3,7,8-TCDD

30.18

Non-2,3,7,8-sub-TCDD 28.40

Non-2,3,7,8-sub-TCDD 28.99

25.65

L 1,2,3,9-TCDD

31.41

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 321.8930

F 1,3,6,8-TCDD

25.30

1,2,8,9-TCDD

29.84

2,3,7,8-TCDD

30.18

Non-2,3,7,8-sub-TCDD 28.40

Non-2,3,7,8-sub-TCDD 28.99

L 1,2,3,9-TCDD

31.41

TCDD Standards

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 331.9362

13C-1,2,3,4-TCDD

28.96

30.63

30.48 31.6631.05

13C-2,3,7,8-TCDD

30.14

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 333.9333

13C-1,2,3,4-TCDD

28.96

30.65 31.27

13C-2,3,7,8-TCDD

30.14

Page 10678 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

13C-TCDD

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 331.9362

13C-1,2,3,4-TCDD

28.96

30.63

30.48 31.6631.05

13C-2,3,7,8-TCDD

30.14

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 333.9333

13C-1,2,3,4-TCDD

28.96

30.65 31.27

13C-2,3,7,8-TCDD

30.14

13C-TCDD Standards

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 331.9362

13C-1,2,3,4-TCDD

28.96

30.63

30.48 31.6631.05

13C-2,3,7,8-TCDD

30.14

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 333.9333

13C-1,2,3,4-TCDD

28.96

30.65 31.27

13C-2,3,7,8-TCDD

30.14

Page 10679 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

PeCDF

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 339.8591

F 1,3,4,6,8-PeCDF 31.24

F2 PeCDFs 31.63

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 341.8562

F 1,3,4,6,8-PeCDF 31.24

F2 PeCDFs 31.71

Page 10680 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

PeCDF

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 339.8591

F 1,3,4,6,8-PeCDF 31.24

F2 PeCDFs 31.63

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 341.8562

F 1,3,4,6,8-PeCDF 31.24

F2 PeCDFs 31.71

PeCDF Interference Mass

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

X

F2:m/z 341.8562 F 31.24

31.71

Page 10681 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

PeCDF

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 339.8591

Non-2,3,7,8-sub-PeCDF 33.31

2,3,4,7,8-PeCDF 35.69Non-2,3,7,8-sub-PeCDF

35.49 1,2,3,7,8-PeCDF 34.53

L 1,2,3,8,9-PeCDF 36.67

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 341.8562

Non-2,3,7,8-sub-PeCDF 33.30

2,3,4,7,8-PeCDF 35.67Non-2,3,7,8-sub-PeCDF

35.491,2,3,7,8-PeCDF 34.52

L 1,2,3,8,9-PeCDF 36.67

PeCDF Standards

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 351.8994

35.66

34.52

36.00 36.5034.78 36.2035.8434.36

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 353.8965

34.53

35.67

33.33 35.90

Page 10682 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

PeCDF

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 339.8591

Non-2,3,7,8-sub-PeCDF 33.31

2,3,4,7,8-PeCDF 35.69Non-2,3,7,8-sub-PeCDF

35.491,2,3,7,8-PeCDF 34.53

L 1,2,3,8,9-PeCDF 36.67

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 341.8562

Non-2,3,7,8-sub-PeCDF 33.30

2,3,4,7,8-PeCDF 35.67Non-2,3,7,8-sub-PeCDF

35.491,2,3,7,8-PeCDF 34.52

L 1,2,3,8,9-PeCDF 36.67

PeCDF Interference Mass

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 409.7969 36.40

35.2433.85 35.76

36.0433.27

36.3233.79 34.72 36.6134.9034.18

33.05

Page 10683 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

PeCDD

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 355.8541

F 1,2,4,7,9-PeCDD 33.28

1,2,3,7,8-PeCDD 35.87

L 1,2,3,8,9-PeCDD 36.26

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 357.8511

F 1,2,4,7,9-PeCDD 33.28

1,2,3,7,8-PeCDD 35.87

L 1,2,3,8,9-PeCDD 36.26

PeCDD Standards

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 367.8943

35.87

36.00 36.7534.69 36.3234.04 34.50 36.6136.5235.3034.1533.34 33.79 36.4134.32

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

X

F3:m/z 369.8914

35.87

35.75 36.2036.0133.85 35.6935.19 36.7233.20 35.0234.22

Page 10684 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

HxCDF

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 373.8202

F 1,2,3,4,6,8-HxCDF 37.09

2,3,4,6,7,8-HxCDF 39.01

1,2,3,4,7,8-HxCDF 38.34

1,2,3,6,7,8-HxCDF 38.44

L 1,2,3,7,8,9-HxCDF 39.82

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 375.8172

F 1,2,3,4,6,8-HxCDF 37.09

2,3,4,6,7,8-HxCDF 39.01

1,2,3,6,7,8-HxCDF 38.441,2,3,4,7,8-HxCDF

38.34

L 1,2,3,7,8,9-HxCDF 39.82

HxCDF Standards

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 383.8634

39.79

39.01

38.44

38.32

39.06 39.92

39.8839.3138.7137.48 38.5738.1537.21

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 385.8604

39.80

39.01

38.44

38.32

39.40

39.08 40.13

37.42 38.74

Page 10685 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

HxCDF

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 373.8202

F 1,2,3,4,6,8-HxCDF 37.09

2,3,4,6,7,8-HxCDF 39.011,2,3,4,7,8-HxCDF

38.34 1,2,3,6,7,8-HxCDF 38.44

L 1,2,3,7,8,9-HxCDF 39.82

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 375.8172

F 1,2,3,4,6,8-HxCDF 37.09

2,3,4,6,7,8-HxCDF 39.01

1,2,3,6,7,8-HxCDF 38.441,2,3,4,7,8-HxCDF

38.34

L 1,2,3,7,8,9-HxCDF 39.82

HxCDF Interference Mass

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 445.7550 39.83 39.48

39.99

37.35 38.15

39.91 40.34

39.33

38.65

38.23 39.64

39.2139.01

38.5538.35 37.93

37.19 38.77

Page 10686 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

HxCDD

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 389.8151

F 1,2,4,6,7,9-HxCDD 37.61

1,2,3,6,7,8-HxCDD 39.171,2,3,4,6,7-HxCDD

39.31 1,2,3,4,7,8-HxCDD 39.08

L 1,2,3,7,8,9-HxCDD 39.40

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 391.8121

F 1,2,4,6,7,9-HxCDD 37.61

1,2,3,6,7,8-HxCDD 39.171,2,3,4,6,7-HxCDD

39.31 1,2,3,4,7,8-HxCDD 39.08

L 1,2,3,7,8,9-HxCDD 39.40

HxCDD Standards

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 401.8553

39.39

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

X

F4:m/z 403.8524

39.39

Page 10687 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

HpCDF

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 407.7812

F 1,2,3,4,6,7,8-HpCDF 40.88

L 1,2,3,4,7,8,9-HpCDF 42.49

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 409.7783

F 1,2,3,4,6,7,8-HpCDF 40.86

L 1,2,3,4,7,8,9-HpCDF 42.49

HpCDF Standards

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 417.8244

42.49

40.85

43.26

41.2441.36 41.7541.84

42.64

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 419.8215

40.86

42.48

42.72 43.0841.7141.33 42.65 43.4543.0141.55 41.84 43.2442.07 42.88

Page 10688 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

HpCDF

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 407.7812

F 1,2,3,4,6,7,8-HpCDF 40.88

L 1,2,3,4,7,8,9-HpCDF 42.49

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 409.7783

F 1,2,3,4,6,7,8-HpCDF 40.86

L 1,2,3,4,7,8,9-HpCDF 42.49

HpCDF Interference Mass

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 479.7160 42.11

42.19

41.98 43.28

43.19 42.6840.82

41.27

Page 10689 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

HpCDD

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 423.7761

F 1,2,3,4,6,7,9-HpCDD

41.10 L 1,2,3,4,6,7,8-HpCDD

41.86

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 425.7732

F 1,2,3,4,6,7,9-HpCDD

41.09 L 1,2,3,4,6,7,8-HpCDD

41.86

HpCDD Standards

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 435.8164

41.84

41.9841.09 43.3642.8841.37 43.2641.7540.65 41.04 41.64 42.56

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

X

F5:m/z 437.8134

41.84

40.96 42.0241.6741.08 42.4141.55 43.07

Page 10690 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

OCDF

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 441.7422

OCDF

45.04

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 443.7393

OCDF

45.04

45.33

OCDF Standards

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 453.7825

45.01

43.77 45.26 45.4844.75 46.1044.06 46.6043.88 45.6644.42 45.42 45.99 47.56

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 455.7795

45.02

47.1145.5145.15 45.6044.0044.08 44.7143.84 44.39 45.8044.18 44.84 46.2243.71 45.31 47.7647.8747.2646.72

Page 10691 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

OCDF

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 441.7422

OCDF

45.04

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 443.7393

OCDF

45.04

45.33

OCDF Interference Mass

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 513.6770 45.35

44.29

45.88 46.18

44.21 44.69

47.80 44.07

43.78 45.66

45.30

44.58 45.09

46.0045.73

46.0943.99 44.42

47.0844.90 46.24

46.64 47.42

Page 10692 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

OCDD

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 457.7371

OCDD

44.71

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 459.7342

OCDD

44.71

45.05

OCDD Standards

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 469.7774

44.69

45.12 47.9345.77 47.5543.71 44.97 46.5343.89 45.8645.5345.26 46.2445.44 46.1144.18

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

X

F6:m/z 471.7745

44.69

44.75 44.90

44.15 45.30 46.2843.73 44.02 44.39 45.37 45.5244.95 45.1744.54 47.8545.75 46.09

Page 10693 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

22.0 24.0 26.0 28.0 30.0 32.0 Min

Y

F2:m/z 313.9834

32.9 33.3 33.7 34.1 34.5 34.9 35.3 35.7 36.1 36.5 36.9 Min

Y

F3:m/z 313.9834

36.9 37.2 37.5 37.8 38.1 38.4 38.7 39.0 39.3 39.6 39.9 40.2 Min

Y

F4:m/z 375.9802

40.4 40.7 41.0 41.3 41.6 41.9 42.2 42.5 42.8 43.1 43.4 Min

Y

F5:m/z 413.9770

Page 10694 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250224-138971.b\25feb24zb-02.d

Injection Date: 24-Feb-2025 13:09:00 Injection Vol: 1.0 ul

Instrument ID: DF18471 Operator ID: Xcalibur_System

Method: ZBDioxin_18471 Limit Group: HR - 1613B

Client ID:

Worklist#: 609311 Sample Line#: 2

Column Type: ZB-Dioxin 60m 0.20um Column Dia: 0.25 mm

43.5 43.9 44.3 44.7 45.1 45.5 45.9 46.3 46.7 47.1 47.5 47.9 Min

Y

F6:m/z 425.9770

Page 10695 of 15442

Date: 24 Feb 2025 10:50

MID Experiment: ResCheck_FC43-21OCT06-PCDD+F

Target Resolution: 10000

Resolution Warning : 9500

Resolution Error : 8000

Reference: FC43

Status: RESOLUTION PASSED

Segment 1

Lock mass 313.9834 [m/z] Resolution: 11122 [5%height]

Cali. mass 375.9802 [m/z] Resolution: 11119 [5%height]

Ref. mass 325.9834 [m/z] Resolution: 11276 [5%height]

Ref. mass 344.9818 [m/z] Resolution: 10590 [5%height]

Ref. mass 351.9802 [m/z] Resolution: 12559 [5%height]

Ref. mass 363.9802 [m/z] Resolution: 11203 [5%height]

25FEB24ZB-01Rb_0 Page 1 of 4Page 10696 of 15442

Lock mass 375.9802 [m/z] Resolution: 10990 [5%height]

Cali. mass 463.9738 [m/z] Resolution: 10761 [5%height]

Ref. mass 401.9770 [m/z] Resolution: 10556 [5%height]

Ref. mass 413.9770 [m/z] Resolution: 10900 [5%height]

Ref. mass 425.9770 [m/z] Resolution: 11397 [5%height]

Ref. mass 451.9738 [m/z] Resolution: 12055 [5%height]

Segment 3

Lock mass 413.9770 [m/z] Resolution: 10820 [5%height]

Cali. mass 501.9706 [m/z] Resolution: 10771 [5%height]

Ref. mass 425.9770 [m/z] Resolution: 11030 [5%height]

Ref. mass 451.9738 [m/z] Resolution: 14160 [5%height]

Ref. mass 463.9738 [m/z] Resolution: 10988 [5%height]

Ref. mass 475.9738 [m/z] Resolution: 12711 [5%height]

25FEB24ZB-01Rb_0 Page 2 of 4Page 10697 of 15442

Lock mass 425.9770 [m/z] Resolution: 11610 [5%height]

Cali. mass 513.9706 [m/z] Resolution: 10659 [5%height]

Ref. mass 451.9738 [m/z] Resolution: 12063 [5%height]

Ref. mass 463.9738 [m/z] Resolution: 10983 [5%height]

Ref. mass 475.9738 [m/z] Resolution: 11366 [5%height]

Ref. mass 501.9706 [m/z] Resolution: 10929 [5%height]

25FEB24ZB-01Rb_0 Page 3 of 4Page 10698 of 15442

25FEB24ZB-01Rb_0 Page 4 of 4Page 10699 of 15442

Date: 25 Feb 2025 00:09

MID Experiment: ResCheck_FC43-21OCT06-PCDD+F

Target Resolution: 10000

Resolution Warning : 9500

Resolution Error : 8000

Reference: FC43

Status: RESOLUTION WARNING

Segment 1

Lock mass 313.9834 [m/z] Resolution: 11362 [5%height]

Cali. mass 375.9802 [m/z] Resolution: 11206 [5%height]

Ref. mass 325.9834 [m/z] Resolution: 10364 [5%height]

Ref. mass 344.9818 [m/z] Resolution: 11536 [5%height]

Ref. mass 351.9802 [m/z] Resolution: 11697 [5%height]

Ref. mass 363.9802 [m/z] Resolution: 10960 [5%height]

25FEB24ZB-15R_0 Page 1 of 4Page 10700 of 15442

Lock mass 375.9802 [m/z] Resolution: 11893 [5%height]

Cali. mass 463.9738 [m/z] Resolution: 11044 [5%height]

Ref. mass 401.9770 [m/z] Resolution: 10307 [5%height]

Ref. mass 413.9770 [m/z] Resolution: 11111 [5%height]

Ref. mass 425.9770 [m/z] Resolution: 11549 [5%height]

Ref. mass 451.9738 [m/z] Resolution: 13307 [5%height]

Segment 3

Lock mass 413.9770 [m/z] Resolution: 11146 [5%height]

Cali. mass 501.9706 [m/z] Resolution: 10982 [5%height]

Ref. mass 425.9770 [m/z] Resolution: 11625 [5%height]

Ref. mass 451.9738 [m/z] Resolution: 15053 [5%height]

Ref. mass 463.9738 [m/z] Resolution: 11073 [5%height]

Ref. mass 475.9738 [m/z] Resolution: 7672 [5%height]

25FEB24ZB-15R_0 Page 2 of 4Page 10701 of 15442

Lock mass 425.9770 [m/z] Resolution: 11160 [5%height]

Cali. mass 513.9706 [m/z] Resolution: 11811 [5%height]

Ref. mass 451.9738 [m/z] Resolution: 13909 [5%height]

Ref. mass 463.9738 [m/z] Resolution: 11318 [5%height]

Ref. mass 475.9738 [m/z] Resolution: 12029 [5%height]

Ref. mass 501.9706 [m/z] Resolution: 10959 [5%height]

25FEB24ZB-15R_0 Page 3 of 4Page 10702 of 15442

25FEB24ZB-15R_0 Page 4 of 4Page 10703 of 15442

Report Date: 03-Mar-2025 08:59:44 Chrom Revision: 2.3 18-Feb-2025 08:41:40

Target Compound Quantitation Report

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250228-139525.b\25feb28zb-02.d

Lims ID: WDM

Client ID:

Sample Type: WDM

Inject. Date: 28-Feb-2025 13:50:00 ALS Bottle#: 0 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info:

Operator ID: Xcalibur_System Instrument ID: DF18471

Method: \\chromfs\Lancaster\ChromData\DF18471\20250228-139525.b\ZBDioxin_18471.m

Limit Group: HR - 1613B

Last Update: 03-Mar-2025 08:59:43 Calib Date: 20-Feb-2025 01:07:00

Integrator: Picker

Quant Method: Isotopic Dilution Quant By: Initial Calibration

Last ICal File: \\chromfs\Lancaster\ChromData\DF18471\20250219-138628.b\25feb19zb(ical)-08.d

Column 1 : ZB-Dioxin 60m 0.20um ( 0.25 mm) Det: F1(18.08 :21.30 )

Process Host: CTX1602

First Level Reviewer: AQ46 Date: 28-Feb-2025 19:22:25

Compound

RT

(min.) Area Ratio Ical

RRF

Amount ng/ml

EMPC

ng/ml

Noise

EDL

Final EDL %Rec Flags

* 13C-1,2,3,4-TCDD 28.793 866964 0.79 25.0 25.0

D 13C-2,3,7,8-TCDF 28.962 1344072 0.76 1.5372 25.2 25.2 0.0167 0.0167 101

D 13C-2,3,7,8-TCDD 30.008 829248 0.79 1.3559 17.6 17.6 0.0174 0.0174 70.54

1,3,6,8-TCDF 23.306 6390124 0.78

1,3,6,8-TCDD 25.163 1939392 0.79

2,3,4,8-TCDF 28.776 2655479 0.78

2,3,7,8-TCDF 28.995 5829552 0.79 1.0765 100.7 100.7 0.1171 0.1171

1,2,8,9-TCDD 29.687 2615796 0.78 M

2,3,7,8-TCDD 30.042 2013980 0.78 0.9650 62.9 62.9 0.0387 0.0387

1,3,4,6,8-PeCDF 31.123 2575368 1.59

1,2,3,9-TCDD 31.292 1855652 0.78

1,2,8,9-TCDF 31.747 5431048 0.78

1,2,4,7,9-PeCDD 33.206 2383695 1.55

1,2,3,7,8-PeCDF 34.439 2361033 1.58 1.0105

2,3,4,7,8-PeCDF 35.611 2507358 1.56 1.1263

1,2,3,7,8-PeCDD 35.811 1561222 1.54 1.1029

1,2,3,8,9-PeCDD 36.197 1886853 1.56

1,2,3,8,9-PeCDF 36.598 2343150 1.59 M

1,2,3,4,6,8-HxCDF 37.026 2237956 1.27

1,2,4,6,7,9-HxCDD 37.551 1641712 1.24

1,2,3,4,7,8-HxCDF 38.277 2144316 1.24 1.2283

1,2,3,6,7,8-HxCDF 38.398 2335654 1.25 1.2425

2,3,4,6,7,8-HxCDF 38.963 2261108 1.24 1.2801

1,2,3,4,7,8-HxCDD 39.030 1479648 1.24 1.0334

1,2,3,6,7,8-HxCDD 39.125 1629074 1.26 1.0910

1,2,3,4,6,7-HxCDD 39.259 1544845 1.24

1,2,3,7,8,9-HxCDD 39.353 1636958 1.26 0.9911

1,2,3,7,8,9-HxCDF 39.757 3765003 1.26 1.1885

1,2,3,4,8,9-HxCDF 39.757 3765003 1.26

1,2,3,4,6,7,8-HpCDF 40.825 2046278 1.03 1.3387

1,2,3,4,6,7,9-HpCDD 41.040 1563051 1.03

1,2,3,4,6,7,8-HpCDD 41.807 1424460 1.04 1.0483

1,2,3,4,7,8,9-HpCDF 42.439 1675475 1.04 1.4621

OCDD 44.638 1189006 0.89 1.0206

OCDF 44.969 1192595 0.92 0.9909

A Non-2,3,7,8-sub-TCDD 27.425 2093292 0.77 0.9650 65.4 65.4 0.0387 32.8 R

Page 10704 of 15442

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250228-139525.b\25feb28zb-02.d

Compound

RT

(min.) Area Ratio Ical

RRF

Amount ng/ml

EMPC

ng/ml

Noise

EDL

Final EDL %Rec Flags

A Non-2,3,7,8-sub-TCDF 27.527 8056591 0.79 1.0765 139.2 139.2 0.1171 44.7 R

A F2 PeCDFs 31.943 8153 1.39 0.0000

A Non-2,3,7,8-sub-PeCDF 33.860 2649489 1.55 0.0000

A Non-2,3,7,8-sub-PeCDD 34.508 0.0 0.0

A Non-2,3,7,8-sub-HxCDF 38.392 0.0 0.0

A Non-2,3,7,8-sub-HxCDD 38.405 0.0 0.0

A Non-2,3,7,8-sub-HpCDD 41.423 0.0 0.0

A Non-2,3,7,8-sub-HpCDF 41.632 0.0 0.0

S Total TCDF 239.9 239.9 0.1171 0.1171 R

S Total TCDD 128.3 128.3 0.0387 0.0387 R

S Total PeCDF 0.0 0.0

S Total PeCDD 0.0 0.0

S Total HxCDF 0.0 0.0

S Total HxCDD 0.0 0.0

S Total HpCDD 0.0 0.0

S Total HpCDF 0.0 0.0

S Total PCDD 128.3 128.3 0.007734 0.007734 R

S Total PCDF 239.9 239.9 0.0234 0.0234 R

S Total PCDD/PCDF 368.3 368.3 0.0156 0.0156 R

S Total 2378-Chlorinated Dioxins & 163.6 163.6 0.009160 0.009160

QC Flag Legend Processing Flags R - Failed Signal Ratio Test Review Flags M - Manually Integrated

Reagents:

Page 10705 of 15442

Target Compound Quantitation Worksheet Report

Data File: \\chromfs\Lancaster\ChromData\DF18471\20250228-139525.b\25feb28zb-02.d

Lims ID: WDM

Client ID:

Sample Type: WDM

Inject. Date: 28-Feb-2025 13:50:00 ALS Bottle#: 0 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info:

Operator ID: Xcalibur_System Instrument ID: DF18471

Method: \\chromfs\Lancaster\ChromData\DF18471\20250228-139525.b\ZBDioxin_18471.m

Limit Group: HR - 1613B

Last Update: 03-Mar-2025 08:59:43 Calib Date: 20-Feb-2025 01:07:00

Integrator: Picker

Quant Method: Isotopic Dilution Quant By: Initial Calibration

Last ICal File: \\chromfs\Lancaster\ChromData\DF18471\20250219-138628.b\25feb19zb(ical)-08.d

Column 1 : ZB-Dioxin 60m 0.20um ( 0.25 mm) Det: F1(18.08 :21.30 )

Process Host: CTX1602

First Level Reviewer: AQ46 Date: 28-Feb-2025 19:22:25

Signal

RT

(min.)

Exp RT (min.)

P Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

13C-1,2,3,4-TCDD

331.9362 28.793 28.793 0 383607 51489 27 67 1907

333.9333 28.810 28.793 1 483357 65276 17 42 3840 0.79(0.65-0.89)

13C-2,3,7,8-TCDF

315.9413 28.962 28.962 0 1.006 579472 71369 29 72 2461

317.9384 28.962 28.962 0 1.006 764600 98661 19 47 5193 0.76(0.65-0.89)

13C-2,3,7,8-TCDD

331.9362 30.008 30.008 0 1.042 364721 53188 27 67 1970

333.9333 30.008 30.008 0 1.042 464527 67400 17 42 3965 0.79(0.65-0.89)

1,3,6,8-TCDF

303.9011 23.306 23.306 0 0.805 2790490 433540 154 385 2815

305.8981 23.306 23.306 0 0.805 3599634 560042 189 472 2963 0.78(0.65-0.89)

1,3,6,8-TCDD

319.8960 25.163 25.163 0 0.839 853742 127120 33 82 3852

321.8930 25.163 25.163 0 0.839 1085650 163830 39 97 4201 0.79(0.65-0.89)

2,3,4,8-TCDF

303.9011 28.776 28.776 0 0.994 1164342 157011 154 385 1020

305.8981 28.776 28.776 0 0.994 1491137 199503 189 472 1056 0.78(0.65-0.89)

2,3,7,8-TCDF

303.9011 28.995 28.995 0 1.001 2567928 306792 154 385 1992

305.8981 28.995 28.995 0 1.001 3261624 394795 189 472 2089 0.79(0.65-0.89)

1,2,8,9-TCDD M

319.8960 29.687 29.687 0 0.989 1145701 134095 33 82 4063

321.8930 29.687 29.687 0 0.989 1470095 177760 39 97 4558 0.78(0.65-0.89) M

2,3,7,8-TCDD

319.8960 30.042 30.042 0 1.001 884203 126631 33 82 3837

321.8930 30.042 30.042 0 1.001 1129777 154018 39 97 3949 0.78(0.65-0.89)

Page 10706 of 15442

Signal

RT

(min.)

Exp RT (min.)

P Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

1,3,4,6,8-PeCDF

339.8591 31.123 31.123 0 1.000 1580271 281574 14 35 20112

341.8562 31.123 31.123 0 1.000 995097 177700 14 35 12693 1.59(1.32-1.78)

1,2,3,9-TCDD

319.8960 31.292 31.292 0 1.043 813099 137831 33 82 4177

321.8930 31.292 31.292 0 1.043 1042553 175100 39 97 4490 0.78(0.65-0.89)

1,2,8,9-TCDF

303.9011 31.747 31.747 0 1.096 2378855 419357 154 385 2723

305.8981 31.747 31.747 0 1.096 3052193 528484 189 472 2796 0.78(0.65-0.89)

1,2,4,7,9-PeCDD

355.8541 33.206 33.206 0 1.000 1450425 223264 102 255 2189

357.8511 33.206 33.206 0 1.000 933270 148859 71 177 2097 1.55(1.32-1.78)

1,2,3,7,8-PeCDF

339.8591 34.439 34.439 0 1.000 1446269 344077 141 352 2440

341.8562 34.439 34.439 0 1.000 914764 218117 96 240 2272 1.58(1.32-1.78)

2,3,4,7,8-PeCDF

339.8591 35.611 35.611 0 1.000 1527686 403790 141 352 2864

341.8562 35.611 35.611 0 1.000 979672 257409 96 240 2681 1.56(1.32-1.78)

1,2,3,7,8-PeCDD

355.8541 35.811 35.811 0 1.000 945738 257381 102 255 2523

357.8511 35.796 35.811 -1 1.000 615484 161910 71 177 2280 1.54(1.32-1.78)

1,2,3,8,9-PeCDD

355.8541 36.197 36.197 0 1.000 1149030 313301 102 255 3072

357.8511 36.181 36.197 -1 1.000 737823 196649 71 177 2770 1.56(1.32-1.78)

1,2,3,8,9-PeCDF M

339.8591 36.598 36.598 0 1.000 1437544 388757 141 352 2757

341.8562 36.598 36.598 0 1.000 905606 252067 96 240 2626 1.59(1.32-1.78) M

1,2,3,4,6,8-HxCDF

373.8202 37.026 37.026 0 1.000 1249937 370846 105 262 3532

375.8172 37.012 37.026 -1 1.000 988019 299811 81 202 3701 1.27(1.05-1.43)

1,2,4,6,7,9-HxCDD

389.8151 37.551 37.551 0 1.000 909043 296442 74 185 4006

391.8121 37.551 37.551 0 1.000 732669 241179 62 155 3890 1.24(1.05-1.43)

1,2,3,4,7,8-HxCDF

373.8202 38.277 38.277 0 1.000 1185966 396821 105 262 3779

375.8172 38.277 38.277 0 1.000 958350 312813 81 202 3862 1.24(1.05-1.43)

1,2,3,6,7,8-HxCDF

373.8202 38.398 38.398 0 1.000 1295861 393937 105 262 3752

375.8172 38.385 38.398 -1 1.000 1039793 317454 81 202 3919 1.25(1.05-1.43)

2,3,4,6,7,8-HxCDF

373.8202 38.963 38.963 0 1.000 1252215 415606 105 262 3958

375.8172 38.963 38.963 0 1.000 1008893 327672 81 202 4045 1.24(1.05-1.43)

1,2,3,4,7,8-HxCDD

389.8151 39.030 39.030 0 1.000 818729 295483 74 185 3993

391.8121 39.030 39.030 0 1.000 660919 231128 62 155 3728 1.24(1.05-1.43)

Page 10707 of 15442

Signal

RT

(min.)

Exp RT (min.)

P Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

1,2,3,6,7,8-HxCDD

389.8151 39.125 39.125 0 1.000 909754 311832 74 185 4214

391.8121 39.125 39.125 0 1.000 719320 247517 62 155 3992 1.26(1.05-1.43)

1,2,3,4,6,7-HxCDD

389.8151 39.259 39.259 0 1.000 854941 296136 74 185 4002

391.8121 39.259 39.259 0 1.000 689904 232717 62 155 3754 1.24(1.05-1.43)

1,2,3,7,8,9-HxCDD

389.8151 39.353 39.353 0 1.000 912989 296558 74 185 4008

391.8121 39.353 39.353 0 1.000 723969 227988 62 155 3677 1.26(1.05-1.43)

1,2,3,7,8,9-HxCDF

373.8202 39.757 39.757 0 1.000 2097421 666635 105 262 6349

375.8172 39.757 39.757 0 1.000 1667582 533402 81 202 6585 1.26(1.05-1.43)

1,2,3,4,8,9-HxCDF

373.8202 39.757 39.757 0 1.000 2097421 666635 105 262 6349

375.8172 39.757 39.757 0 1.000 1667582 533402 81 202 6585 1.26(1.05-1.43)

1,2,3,4,6,7,8-HpCDF

407.7812 40.825 40.825 0 1.000 1039789 338462 73 182 4636

409.7783 40.811 40.825 -1 1.000 1006489 329642 73 182 4516 1.03(0.88-1.20)

1,2,3,4,6,7,9-HpCDD

423.7761 41.040 41.040 0 1.000 793373 256436 42 105 6106

425.7732 41.040 41.040 0 1.000 769678 250651 48 120 5222 1.03(0.88-1.20)

1,2,3,4,6,7,8-HpCDD

423.7761 41.807 41.807 0 1.000 725666 235948 42 105 5618

425.7732 41.807 41.807 0 1.000 698794 219939 48 120 4582 1.04(0.88-1.20)

1,2,3,4,7,8,9-HpCDF

407.7812 42.439 42.439 0 1.000 855021 251646 73 182 3447

409.7783 42.425 42.439 -1 1.000 820454 231658 73 182 3173 1.04(0.88-1.20)

OCDD

457.7371 44.638 44.638 0 1.000 560484 152865 18 45 8493

459.7342 44.638 44.638 0 1.000 628522 172935 21 52 8235 0.89(0.76-1.02)

OCDF

441.7422 44.969 44.969 0 1.000 572840 142793 18 45 7933

443.7393 44.955 44.969 -1 1.000 619755 158259 17 42 9309 0.92(0.76-1.02)

A Non-2,3,7,8-sub-TCDD R

319.8960 27.257 27.425 -10 0.908 7634 880 33 82 27

321.8930 27.257 27.425 -10 0.908 10139 1078 39 97 28 0.75(0.65-0.89)

319.8960 28.236 27.425 49 0.941 453297 62016 33 82 1879

321.8930 28.236 27.425 49 0.941 597625 81013 39 97 2077 0.76(0.65-0.89)

319.8960 28.827 27.425 84 0.961 430866 56874 33 82 1723

321.8930 28.827 27.425 84 0.961 560026 74719 39 97 1916 0.77(0.65-0.89)

319.8960 30.346 27.425 175 1.011 19160 1386 33 82 42

321.8930 30.481 27.425 183 1.016 14545 1236 39 97 32 1.32(0.65-0.89)

A Non-2,3,7,8-sub-TCDF R

303.9011 27.577 27.527 3 0.952 115946 15214 154 385 99

305.8981 27.577 27.527 3 0.952 146257 19548 189 472 103 0.79(0.65-0.89)

Page 10708 of 15442

Signal

RT

(min.)

Exp RT (min.)

P Sec.

REL

RT Area Height

Avg Noise

EDL

Height S/N Ratio(Limits) Flags

303.9011 28.556 27.527 62 0.986 1126423 156296 154 385 1015

305.8981 28.556 27.527 62 0.986 1447484 199460 189 472 1055 0.78(0.65-0.89)

303.9011 29.907 27.527 143 1.033 1126769 157098 154 385 1020

305.8981 29.890 27.527 142 1.032 1438461 208553 189 472 1103 0.78(0.65-0.89)

303.9011 30.194 27.527 160 1.043 1153421 161736 154 385 1050

305.8981 30.194 27.527 160 1.043 1435110 205137 189 472 1085 0.80(0.65-0.89)

303.9011 31.140 27.527 216 1.075 25296 4489 154 385 29

305.8981 31.140 27.527 216 1.075 41424 6258 189 472 33 0.61(0.65-0.89)

A F2 PeCDFs

339.8591 31.579 31.943 -22 1.000 4742 425 14 35 30

341.8562 31.612 31.943 -20 1.000 3411 259 14 35 19 1.39(1.32-1.78)

A Non-2,3,7,8-sub-PeCDF

339.8591 33.206 33.860 -39 1.000 221433 45403 141 352 322

341.8562 33.206 33.860 -39 1.000 144006 30130 96 240 314 1.54(1.32-1.78)

339.8591 35.410 33.860 93 1.000 1390969 371432 141 352 2634

341.8562 35.410 33.860 93 1.000 893081 239917 96 240 2499 1.56(1.32-1.78)

A Non-2,3,7,8-sub-PeCDD

355.8541 34.508 102 255

357.8511 34.508 71 177

A Non-2,3,7,8-sub-HxCDF

373.8202 38.392 105 262

375.8172 38.392 81 202

A Non-2,3,7,8-sub-HxCDD

389.8151 38.405 74 185

391.8121 38.405 62 155

A…