J185041_1 Std_Tal_L4 Final Report_Part9.pdf

Report Date: 26-Sep-2024 05:43:17 Chrom Revision: 2.3 26-Aug-2024 17:14:48

Eurofins Pittsburgh Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Injection Date: 25-Sep-2024 09:03:28 Instrument ID: CGC1

Lims ID: IC

Client ID:

Operator ID: 402331 ALS Bottle#: 7 Worklist Smp#: 7

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0925240000007.D

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0925240000007.D

Page 8608 of 15442

Calibration / Dalapon

Curve Type: Average

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.068E+08

Error Coefficients

Relative Standard Deviation: 10.2

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.01 1222534.0 122253400.0 Y

2 IC 180-480078/2 0.02 2151643.0 107582150.0 Y

3 IC 180-480078/3 0.04 4289090.0 107227250.0 Y

4 ICRT 180-480078/4 0.08 7486236.0 93577950.0 Y

5 IC 180-480078/5 0.16 19093930.0 119337062.5 Y

6 IC 180-480078/6 0.32 32178401.0 100557503.125 Y

7 IC 180-480078/7 0.64 62011369.0 96892764.0625 Y

Response = [1.068E+08]x

Concentration

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.0

1.0

2.0

3.0

4.0

5.0

6.0

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

IC 180-480078/6

Page 8609 of 15442

Calibration / 2,4-Dichlorophenylacetic acid

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.816E+08

Error Coefficients

Relative Standard Deviation: 19.9

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.002 74822.0 37411000.0 N

2 IC 180-480078/2 0.004 960860.0 240215000.0 Y

3 IC 180-480078/3 0.008 1604401.0 200550125.0 Y

4 ICRT 180-480078/4 0.016 2926401.0 182900062.5 Y

5 IC 180-480078/5 0.032 5612284.0 175383875.0 Y

6 IC 180-480078/6 0.064 9681722.0 151276906.25 Y

7 IC 180-480078/7 0.128 17841838.0 139389359.375 Y

Response = [1.816E+08]x

Concentration

0 0.1 0.2 0.0

0.5

1.0

1.5

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

IC 180-480078/6

IC 180-480078/7

Page 8610 of 15442

Calibration / MCPP

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 6.161E+05

Error Coefficients

Relative Standard Deviation: 14.2

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 1.0 751007.0 751007.0 Y

2 IC 180-480078/2 2.0 1390528.0 695264.0 Y

3 IC 180-480078/3 4.0 2557858.0 639464.5 Y

4 ICRT 180-480078/4 8.0 4764424.0 595553.0 Y

5 IC 180-480078/5 16.0 9507130.0 594195.625 Y

6 IC 180-480078/6 32.0 17241090.0 538784.0625 Y

7 IC 180-480078/7 64.0 31910401.0 498600.015625 Y

Response = [6.161E+05]x

Concentration

0 10 20 30 40 50 60 70 0.0

0.5

1.0

1.5

2.0

2.5

3.0

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8611 of 15442

Calibration / Dicamba

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 5.332E+08

Error Coefficients

Relative Standard Deviation: 9.0

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.005 3096313.0 619262600.0 Y

2 IC 180-480078/2 0.01 5654256.0 565425600.0 Y

3 IC 180-480078/3 0.02 10580771.0 529038550.0 Y

4 ICRT 180-480078/4 0.04 20730219.0 518255475.0 Y

5 IC 180-480078/5 0.08 42687996.0 533599950.0 Y

6 IC 180-480078/6 0.16 79069632.0 494185200.0 Y

7 IC 180-480078/7 0.32 151178763.0 472433634.375 Y

Response = [5.332E+08]x

Concentration

0 0.1 0.2 0.3 0.4 0.0

0.5

1.0

1.5

R esponse ( X

100000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8612 of 15442

Calibration / MCPA

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 8.986E+05

Error Coefficients

Relative Standard Deviation: 15.2

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 1.0 154240.0 154240.0 N

2 IC 180-480078/2 2.0 2244490.0 1122245.0 Y

3 IC 180-480078/3 4.0 3880188.0 970047.0 Y

4 ICRT 180-480078/4 8.0 7201802.0 900225.25 Y

5 IC 180-480078/5 16.0 13961374.0 872585.875 Y

6 IC 180-480078/6 32.0 25154628.0 786082.125 Y

7 IC 180-480078/7 64.0 47368260.0 740129.0625 Y

Response = [8.986E+05]x

Concentration

0 10 20 30 40 50 60 70 0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8613 of 15442

Calibration / Dichlorprop

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.516E+08

Error Coefficients

Relative Standard Deviation: 13.0

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.01 1865456.0 186545600.0 Y

2 IC 180-480078/2 0.02 3340669.0 167033450.0 Y

3 IC 180-480078/3 0.04 6093877.0 152346925.0 Y

4 ICRT 180-480078/4 0.08 11610707.0 145133837.5 Y

5 IC 180-480078/5 0.16 23555061.0 147219131.25 Y

6 IC 180-480078/6 0.32 42761206.0 133628768.75 Y

7 IC 180-480078/7 0.64 82707932.0 129231143.75 Y

Response = [1.516E+08]x

Concentration

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8614 of 15442

Calibration / 2,4-D

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.688E+08

Error Coefficients

Relative Standard Deviation: 11.4

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.01 2040062.0 204006200.0 Y

2 IC 180-480078/2 0.02 3599969.0 179998450.0 Y

3 IC 180-480078/3 0.04 6735565.0 168389125.0 Y

4 ICRT 180-480078/4 0.08 13114687.0 163933587.5 Y

5 IC 180-480078/5 0.16 26804260.0 167526625.0 Y

6 IC 180-480078/6 0.32 48970089.0 153031528.125 Y

7 IC 180-480078/7 0.64 92781927.0 144971760.9375 Y

Response = [1.688E+08]x

Concentration

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8615 of 15442

Calibration / Pentachlorophenol

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.821E+09

Error Coefficients

Relative Standard Deviation: 7.0

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.0025 5129901.0 2051960400.0 Y

2 IC 180-480078/2 0.005 9423891.0 1884778200.0 Y

3 IC 180-480078/3 0.01 17791935.0 1779193500.0 Y

4 ICRT 180-480078/4 0.02 35623120.0 1781156000.0 Y

5 IC 180-480078/5 0.04 74546656.0 1863666400.0 Y

6 IC 180-480078/6 0.08 137918054.0 1723975675.0 Y

7 IC 180-480078/7 0.16 265871167.0 1661694793.75 Y

Response = [1.821E+09]x

Concentration

0 0.1 0.2 0.0

0.5

1.0

1.5

2.0

2.5

R esponse ( X

100000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8616 of 15442

Calibration / Silvex (2,4,5-TP)

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 7.739E+08

Error Coefficients

Relative Standard Deviation: 9.2

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.0025 2255120.0 902048000.0 Y

2 IC 180-480078/2 0.005 4029458.0 805891600.0 Y

3 IC 180-480078/3 0.01 7642264.0 764226400.0 Y

4 ICRT 180-480078/4 0.02 15253139.0 762656950.0 Y

5 IC 180-480078/5 0.04 31510223.0 787755575.0 Y

6 IC 180-480078/6 0.08 57282047.0 716025587.5 Y

7 IC 180-480078/7 0.16 108542766.0 678392287.5 Y

Response = [7.739E+08]x

Concentration

0 0.1 0.2 0.0

0.2

0.4

0.6

0.8

1.0

R esponse ( X

100000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8617 of 15442

Calibration / 2,4,5-T

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 6.639E+08

Error Coefficients

Relative Standard Deviation: 5.8

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.0025 1776639.0 710655600.0 Y

2 IC 180-480078/2 0.005 3450075.0 690015000.0 Y

3 IC 180-480078/3 0.01 6594384.0 659438400.0 Y

4 ICRT 180-480078/4 0.02 13053390.0 652669500.0 Y

5 IC 180-480078/5 0.04 27875316.0 696882900.0 Y

6 IC 180-480078/6 0.08 51014257.0 637678212.5 Y

7 IC 180-480078/7 0.16 95951831.0 599698943.75 Y

Response = [6.639E+08]x

Concentration

0 0.1 0.2 0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8618 of 15442

Calibration / Dinoseb

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 3.662E+08

Error Coefficients

Relative Standard Deviation: 9.5

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.01 4249799.0 424979900.0 Y

2 IC 180-480078/2 0.02 7733242.0 386662100.0 Y

3 IC 180-480078/3 0.04 14473667.0 361841675.0 Y

4 ICRT 180-480078/4 0.08 28569716.0 357121450.0 Y

5 IC 180-480078/5 0.16 60182206.0 376138787.5 Y

6 IC 180-480078/6 0.32 108683649.0 339636403.125 Y

7 IC 180-480078/7 0.64 202846382.0 316947471.875 Y

Response = [3.662E+08]x

Concentration

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.0

0.5

1.0

1.5

2.0

R esponse ( X

100000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8619 of 15442

Calibration / 2,4-DB

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 8.411E+07

Error Coefficients

Relative Standard Deviation: 4.1

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.01 983494.0 98349400.0 N

2 IC 180-480078/2 0.02 1720838.0 86041900.0 Y

3 IC 180-480078/3 0.04 3219888.0 80497200.0 Y

4 ICRT 180-480078/4 0.08 6703301.0 83791262.5 Y

5 IC 180-480078/5 0.16 14388815.0 89930093.75 Y

6 IC 180-480078/6 0.32 26624730.0 83202281.25 Y

7 IC 180-480078/7 0.64 51967886.0 81199821.875 Y

Response = [8.411E+07]x

Concentration

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8620 of 15442

FORM VI

Lab Name: Job No.:

HERBICIDES BY EXTERNAL STANDARD - INITIAL CALIBRATION DATA

Eurofins Pittsburgh 180-185041-1 Analy Batch No.: 480078

RETENTION TIME SUMMARY

SDG No.:

Calibration ID:

Instrument ID: Heated Purge: (Y/N)CGC1

52916Calibration Start Date: Calibration End Date:09/25/2024 07:03

N

09/25/2024 09:03

0.53(mm)GC Column: RTX-1701 ID:

Calibration Files:

LEVEL: LAB SAMPLE ID: LAB FILE ID:

Level 1 IC 180-480078/1 0925240000001.D Level 2 IC 180-480078/2 0925240000002.D Level 3 IC 180-480078/3 0925240000003.D Level 4 ICRT 180-480078/4 0925240000004.D Level 5 IC 180-480078/5 0925240000005.D Level 6 IC 180-480078/6 0925240000006.D Level 7 IC 180-480078/7 0925240000007.D

ANALYTE LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6 LVL 7 AVG RTRT WINDOW

Dalapon 2.5322.504 - 2.5642.533 2.532 2.534 2.534 2.529 2.531 2.530 Dicamba 8.4548.426 - 8.4868.454 8.453 8.457 8.456 8.455 8.453 8.452

MCPP 8.6058.578 - 8.6388.605 8.604 8.607 8.608 8.606 8.604 8.604

MCPA 8.9128.885 - 8.945+++++ 8.911 8.915 8.915 8.912 8.911 8.910

Dichlorprop 9.2759.247 - 9.3079.275 9.274 9.276 9.277 9.275 9.273 9.272 2,4-D 9.6699.642 - 9.7029.670 9.669 9.671 9.672 9.670 9.668 9.666 Pentachlorophenol 9.8949.866 - 9.9269.894 9.893 9.896 9.896 9.894 9.891 9.891 Silvex (2,4,5-TP) 10.43810.410 - 10.47010.439 10.437 10.441 10.440 10.438 10.436 10.435 2,4,5-T 10.89110.863 - 10.92310.893 10.891 10.893 10.893 10.891 10.888 10.887

2,4-DB 11.31911.291 - 11.351+++++ 11.321 11.322 11.321 11.318 11.316 11.315

Dinoseb 11.96611.938 - 11.99811.966 11.965 11.968 11.968 11.967 11.964 11.964 2,4-Dichlorophenylacetic acid 8.1878.160 - 8.220+++++ 8.187 8.190 8.190 8.187 8.185 8.184

FORM VI EPA 8151A Page 8621 of 15442

HERBICIDES BY EXTERNAL STANDARD - INITIAL CALIBRATION DATA

Eurofins Pittsburgh 180-185041-1 Analy Batch No.: 480078

CURVE EVALUATION

SDG No.:

Calibration ID:

Instrument ID: GC Column: Heated Purge: (Y/N)CGC1

52916Calibration Start Date: Calibration End Date:09/25/2024 07:03

N

09/25/2024 09:03

0.53(mm)RTX-1701 ID:

Calibration Files

LEVEL: LAB SAMPLE ID: LAB FILE ID:

1Level IC 180-480078/1 0925240000001.D 2Level IC 180-480078/2 0925240000002.D 3Level IC 180-480078/3 0925240000003.D 4Level ICRT 180-480078/4 0925240000004.D 5Level IC 180-480078/5 0925240000005.D 6Level IC 180-480078/6 0925240000006.D 7Level IC 180-480078/7 0925240000007.D

MIN R^2

OR COD

#R^2

OR COD

MAX

%RSD

#%RSD#COEFFICIENT

M2M1B

CURVE

TYPE

LVL 4LVL 3LVL 2LVL 1

CFANALYTE MIN CF

/RSE

/RSE

LVL 5 LVL 6 LVL 7

Dalapon Ave 10.3 20.0152359800 135627200 125251350 121842838 142147156 120519878 114878122

130375192

Dicamba Ave 9.3 20.0678934000 622125200 583189700 570856625 586896113 541444831 511840859

585041047

MCPP Ave 50.5 * 20.02992631 2467484 1983582 1545270 1186778 879258 694239

1678463.2

MCPA Ave 46.5 * 20.0+++++ 3171929 2480709 1901763

1484452 1118563 918844 1846043.2

Dichlorprop Ave 12.8 20.0202768300 180018350 169809075 162202350

161446063 146670350 138682431 165942417

2,4-D Ave 9.2 20.0206592000 194763250 183750575 178950513 183558644 166296088 156712125

181517599

Pentachlorophenol Ave 6.5 20.0218817000

203376100

196669210

196870250

0206446307

187947708

179016380

198448993

Silvex (2,4,5-TP) Ave 8.1 20.0945145600 877868800 848508800 839144400 875725750 783833400 733445831

843381797

2,4,5-T Ave 5.0 20.0694380400 707411400 696548200 698567650 737944775 669290688 626247756

690055838

2,4-DB Ave 6.0 20.0+++++ 82896100 84460000 89900875 97764663 91208953 87533539

88960688.

Dinoseb Ave 9.0 20.0453572900 407874850 398944625 393901663

408224444 363340372 342092258 395421587

2,4-Dichlorophenylacetic acid

Ave 11.0 20.0+++++ 218813250 205988625 202630813 199815750 176570406 160796563

194102568

FORM VI EPA 8151A

Note: The M1 coefficient is the same as Ave CF for an Ave curve type. RSD is calculated for Ave curve types. RSE is used for all other types.

Page 8622 of 15442

HERBICIDES BY EXTERNAL STANDARD - INITIAL CALIBRATION DATA

Eurofins Pittsburgh 180-185041-1 Analy Batch No.: 480078

RESPONSE AND CONCENTRATION

SDG No.:

Calibration ID:

Instrument ID: Heated Purge: (Y/N)CGC1

52916Calibration Start Date: Calibration End Date:09/25/2024 07:03

N

09/25/2024 09:03

GC Column: RTX-1701 ID: 0.53(mm)

Calibration Files:

LEVEL: LAB SAMPLE ID: LAB FILE ID:

Level 1 IC 180-480078/1 0925240000001.D Level 2 IC 180-480078/2 0925240000002.D Level 3 IC 180-480078/3 0925240000003.D Level 4 ICRT 180-480078/4 0925240000004.D Level 5 IC 180-480078/5 0925240000005.D Level 6 IC 180-480078/6 0925240000006.D Level 7 IC 180-480078/7 0925240000007.D

CURVE

TYPE

RESPONSEANALYTE CONCENTRATION (NG)

LVL 1 LVL 1LVL 2 LVL 2LVL 3 LVL 3LVL 4 LVL 4LVL 5 LVL 5

LVL 6 LVL 6LVL 7 LVL 7

Dalapon Ave 1523598 2712544 5010054 9747427 22743545 0.0100 0.0200 0.0400 0.0800 0.160 38566361 73521998 0.320 0.640

Dicamba Ave 3394670 6221252 11663794 22834265 46951689 0.00500 0.0100 0.0200 0.0400 0.0800 86631173 163789075 0.160 0.320

MCPP Ave 2992631 4934968 7934329 12362162 18988444 1.00 2.00 4.00 8.00 16.0 28136254 44431310 32.0 64.0

MCPA Ave +++++ 6343857 9922837 15214100 23751225 +++++ 2.00 4.00 8.00 16.0 35794017 58806041 32.0 64.0

Dichlorprop Ave 2027683 3600367 6792363 12976188 25831370 0.0100 0.0200 0.0400 0.0800 0.160 46934512 88756756 0.320 0.640

2,4-D Ave 2065920 3895265 7350023 14316041 29369383 0.0100 0.0200 0.0400 0.0800 0.160 53214748 100295760 0.320 0.640

Pentachlorophenol Ave 5470425 10168805 19666921 39374050 82578523 0.00250 0.00500 0.0100 0.0200 0.0400 150358167 286426209 0.0800 0.160

Silvex (2,4,5-TP) Ave 2362864 4389344 8485088 16782888 35029030 0.00250 0.00500 0.0100 0.0200 0.0400 62706672 117351333 0.0800 0.160

2,4,5-T Ave 1735951 3537057 6965482 13971353 29517791 0.00250 0.00500 0.0100 0.0200 0.0400 53543255 100199641 0.0800 0.160

2,4-DB Ave +++++ 1657922 3378400 7192070 15642346 +++++ 0.0200 0.0400 0.0800 0.160 29186865 56021465 0.320 0.640

Dinoseb Ave 4535729 8157497 15957785 31512133 65315911 0.0100 0.0200 0.0400 0.0800 0.160 116268919 218939045 0.320 0.640

2,4-Dichlorophenylacetic acid Ave +++++ 875253 1647909 3242093 6394104 +++++ 0.00400 0.00800 0.0160 0.0320 11300506 20581960 0.0640 0.128

Curve Type Legend:

Ave = Average by Height

FORM VI EPA 8151A Page 8623 of 15442

HERBICIDES BY EXTERNAL STANDARD - INITIAL CALIBRATION DATA

Eurofins Pittsburgh 180-185041-1 Analy Batch No.: 480078

READBACK PERCENT ERROR

SDG No.:

Calibration ID:

Instrument ID: GC Column: Heated Purge: (Y/N)CGC1

52916Calibration Start Date: Calibration End Date:09/25/2024 07:03

N

09/25/2024 09:03

0.53(mm)RTX-1701 ID:

Calibration Files:

LEVEL: LAB SAMPLE ID: LAB FILE ID:

1Level IC 180-480078/1 0925240000001.D 2Level IC 180-480078/2 0925240000002.D 3Level IC 180-480078/3 0925240000003.D 4Level ICRT 180-480078/4 0925240000004.D 5Level IC 180-480078/5 0925240000005.D 6Level IC 180-480078/6 0925240000006.D 7Level IC 180-480078/7 0925240000007.D

ANALYTE PERCENT ERROR

LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 ##### LVL 6 # LVL 1 LVL 2 LVL 3 LVL 4 LVL 5 LVL 6

PERCENT ERROR LIMIT

LVL 7 # LVL 7

Dalapon 16.9 4.0 -3.9 -6.5 9.0 -7.6 -11.9

50 30 30 30 30 30

Dicamba 16.0 6.3 -0.3 -2.4 0.3 -7.5 -12.5

50 30 30 30 30 30

MCPP 78.3 47.0 18.2 -7.9 -29.3 -47.6

-58.6

50 30 30 30 30 30

MCPA +++++ 71.8 34.4 3.0 -19.6 -39.4

-50.2

50 30 30 30 30

Dichlorprop 22.2 8.5 2.3 -2.3 -2.7 -11.6 -16.4

50 30 30 30 30 30

2,4-D 13.8 7.3 1.2 -1.4 1.1 -8.4 -13.7

50 30 30 30 30 30

Pentachlorophenol 10.3 2.5 -0.9 -0.8 4.0 -5.3 -9.8

50 30 30 30 30 30

Silvex (2,4,5-TP) 12.1 4.1 0.6 -0.5 3.8 -7.1 -13.0

50 30 30 30 30 30

2,4,5-T 0.6 2.5 0.9 1.2 6.9 -3.0 -9.2

50 30 30 30 30 30

2,4-DB +++++ -6.8 -5.1 1.1 9.9 2.5

-1.6

50 30 30 30 30

Dinoseb 14.7 3.1 0.9 -0.4 3.2 -8.1 -13.5

50 30 30 30 30 30

2,4-Dichlorophenylacetic acid +++++ 12.7 6.1 4.4 2.9 -9.0 -17.2

50 30 30 30 30

FORM VI EPA 8151A Page 8624 of 15442

Report Date: 26-Sep-2024 05:43:10 Chrom Revision: 2.3 26-Aug-2024 17:14:48

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000001.D

Lims ID: IC

Client ID:

Sample Type: IC Calib Level: 7

Inject. Date: 25-Sep-2024 07:03:39 ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0053936-001

Operator ID: 402331 Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 26-Sep-2024 05:43:09 Calib Date: 25-Sep-2024 09:03:28

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Column 1 : Det: GC ECD1A

Column 2 : Det: GC ECD2B

Process Host: CTX1638

First Level Reviewer: XXL1 Date: 25-Sep-2024 08:07:50

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon M

1 2.184 2.185 -0.001 1222534H 0.0100 0.0114 M

2 2.533 2.534 -0.001 1523598H 0.0100 0.0117 M

RPD = 2.05

$ 2 2,4-Dichlorophenylacetic acid

1 7.868 7.870 -0.002 74822H 0.002000 0.000412

2 8.188 8.190 -0.002 73495H 0.002000 0.000379

RPD = 8.43

3 MCPP

1 8.085 8.087 -0.002 751007H 1.00 1.22

2 8.605 8.608 -0.003 2992631H 1.00 1.78

RPD = 37.58

4 Dicamba

1 8.159 8.162 -0.003 3096313H 0.005000 0.005807

2 8.454 8.456 -0.002 3394670H 0.005000 0.005802

RPD = 0.08

5 MCPA

1 8.500 8.504 -0.004 154240H 1.00 0.1717

2 8.912 8.915 -0.003 3865496H 1.00 2.09

RPD = 169.69

6 Dichlorprop

1 8.779 8.782 -0.003 1865456H 0.0100 0.0123

2 9.275 9.277 -0.002 2027683H 0.0100 0.0122

RPD = 0.71

7 2,4-D

1 9.267 9.268 -0.001 2040062H 0.0100 0.0121

2 9.670 9.672 -0.002 2065920H 0.0100 0.0114

RPD = 5.98

Page 8625 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000001.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.784 9.787 -0.003 5129901H 0.002500 0.002817

2 9.894 9.896 -0.002 5470425H 0.002500 0.002757

RPD = 2.18

9 Silvex (2,4,5-TP)

1 9.947 9.948 -0.001 2255120H 0.002500 0.002914

2 10.439 10.440 -0.001 2362864H 0.002500 0.002802

RPD = 3.94

10 2,4,5-T

1 10.493 10.493 0.000 1776639H 0.002500 0.002676

2 10.893 10.893 0.000 1735951H 0.002500 0.002516

RPD = 6.18

11 Dinoseb

1 10.749 10.749 0.000 4249799H 0.0100 0.0116

2 11.966 11.968 -0.002 4535729H 0.0100 0.0115

RPD = 1.17

12 2,4-DB M

1 10.878 10.874 0.004 983494H 0.0100 0.0117 M

2 11.323 11.321 0.002 908706H 0.0100 0.0102 M

RPD = 13.49

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

GCHERBCALSL7_00029 Amount Added: 1.00 Units: mL

Page 8626 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000001.D

Injection Date: 25-Sep-2024 07:03:39 Instrument ID: CGC1

Lims ID: IC

Client ID:

Operator ID: 402331 ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0925240000001.D

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0925240000001.D

Page 8627 of 15442

Manual Integration/User Assign Peak Report

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000001.D

Injection Date: 25-Sep-2024 07:03:39 Instrument ID: CGC1

Lims ID: IC

Client ID:

Operator ID: 402331 ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: Detector GC ECD2B

1 Dalapon, CAS: 75-99-0 Signal: 2

Processing Integration Results

RT: 2.53

Height: 1406312

Amount: 0.011186

Amount Units: ng

2.2 2.4 2.6 2.8 Min

Y

X

.5

Manual Integration Results

RT: 2.53

Height: 1523598

Amount: 0.011686

Amount Units: ng

2.2 2.4 2.6 2.8 Min

RT

Y

X

Reviewer: XXL1, 25-Sep-2024 10:54:15 -04:00:00 (UTC)

Audit Action: Assigned New Baseline Audit Reason: Baseline Smoothing

Page 8628 of 15442

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000001.D

Injection Date: 25-Sep-2024 07:03:39 Instrument ID: CGC1

Lims ID: IC

Client ID:

Operator ID: 402331 ALS Bottle#: 1 Worklist Smp#: 1

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: Detector GC ECD2B

12 2,4-DB, CAS: 94-82-6

Signal: 2

Processing Integration Results

RT: 11.32

Height: 99185

Amount: 0.001115

Amount Units: ng

11.0 11.2 11.4 11.6 Min

Y

X

GC ECD2B, 0925240000001.D

.3

Manual Integration Results

RT: 11.32

Height: 908706

Amount: 0.010215

Amount Units: ng

11.0 11.2 11.4 11.6 Min

RT

Y

X

GC ECD2B, 0925240000001.D

.3

Reviewer: XXL1, 25-Sep-2024 10:51:05 -04:00:00 (UTC)

Audit Action: Manually Integrated Audit Reason: Baseline Smoothing

Page 8629 of 15442

Report Date: 26-Sep-2024 05:43:11 Chrom Revision: 2.3 26-Aug-2024 17:14:48

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000002.D

Lims ID: IC

Client ID:

Sample Type: IC Calib Level: 1

Inject. Date: 25-Sep-2024 07:23:34 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0053936-002

Operator ID: 402331 Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 26-Sep-2024 05:43:10 Calib Date: 25-Sep-2024 09:03:28

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Column 1 : Det: GC ECD1A

Column 2 : Det: GC ECD2B

Process Host: CTX1638

First Level Reviewer: XXL1 Date: 25-Sep-2024 08:08:12

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon M

1 2.182 2.185 -0.003 2151643H 0.0200 0.0202 M

2 2.532 2.534 -0.002 2712544H 0.0200 0.0208 M

RPD = 3.20

$ 2 2,4-Dichlorophenylacetic acid M

1 7.867 7.870 -0.003 960860H 0.004000 0.005291 M

2 8.187 8.190 -0.003 875253H 0.004000 0.004509

RPD = 15.95

3 MCPP

1 8.084 8.087 -0.003 1390528H 2.00 2.26

2 8.604 8.608 -0.004 4934968H 2.00 2.94

RPD = 26.29

4 Dicamba

1 8.159 8.162 -0.003 5654256H 0.0100 0.0106

2 8.453 8.456 -0.003 6221252H 0.0100 0.0106

RPD = 0.27

5 MCPA

1 8.500 8.504 -0.004 2244490H 2.00 2.50

2 8.911 8.915 -0.004 6343857H 2.00 3.44

RPD = 31.63

6 Dichlorprop

1 8.778 8.782 -0.004 3340669H 0.0200 0.0220

2 9.274 9.277 -0.003 3600367H 0.0200 0.0217

RPD = 1.56

7 2,4-D

1 9.265 9.268 -0.003 3599969H 0.0200 0.0213

2 9.669 9.672 -0.003 3895265H 0.0200 0.0215

RPD = 0.64

Page 8630 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000002.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.783 9.787 -0.004 9423891H 0.005000 0.005175

2 9.893 9.896 -0.003 10168805H 0.005000 0.005124

RPD = 0.99

9 Silvex (2,4,5-TP)

1 9.944 9.948 -0.004 4029458H 0.005000 0.005207

2 10.437 10.440 -0.003 4389344H 0.005000 0.005204

RPD = 0.05

10 2,4,5-T

1 10.491 10.493 -0.002 3450075H 0.005000 0.005197

2 10.891 10.893 -0.002 3537057H 0.005000 0.005126

RPD = 1.38

11 Dinoseb

1 10.746 10.749 -0.003 7733242H 0.0200 0.0211

2 11.965 11.968 -0.003 8157497H 0.0200 0.0206

RPD = 2.34

12 2,4-DB

1 10.874 10.874 0.000 1720838H 0.0200 0.0205

2 11.321 11.321 0.000 1657922H 0.0200 0.0186

RPD = 9.32

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

GCHERBCALSL1_00038 Amount Added: 1.00 Units: mL

Page 8631 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000002.D

Injection Date: 25-Sep-2024 07:23:34 Instrument ID: CGC1

Lims ID: IC

Client ID:

Operator ID: 402331 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0925240000002.D

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0925240000002.D

Page 8632 of 15442

Eurofins Pittsburgh

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000002.D

Injection Date: 25-Sep-2024 07:23:34 Instrument ID: CGC1

Lims ID: IC

Client ID:

Operator ID: 402331 ALS Bottle#: 2 Worklist Smp#: 2

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

Column: Detector GC ECD2B

1 Dalapon, CAS: 75-99-0 Signal: 2

Processing Integration Results

RT: 2.53

Height: 2594233

Amount: 0.019192

Amount Units: ng

2.2 2.4 2.6 2.8 Min

Y

X

Manual Integration Results

RT: 2.53

Height: 2712544

Amount: 0.020806

Amount Units: ng

2.2 2.4 2.6 2.8 Min

RT

Y

X

Reviewer: XXL1, 25-Sep-2024 10:54:30 -04:00:00 (UTC)

Audit Action: Assigned New Baseline Audit Reason: Baseline Smoothing

Page 8633 of 15442

Report Date: 26-Sep-2024 05:43:12 Chrom Revision: 2.3 26-Aug-2024 17:14:48

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000003.D

Lims ID: IC

Client ID:

Sample Type: IC Calib Level: 2

Inject. Date: 25-Sep-2024 07:43:31 ALS Bottle#: 3 Worklist Smp#: 3

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0053936-003

Operator ID: 402331 Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 26-Sep-2024 05:43:12 Calib Date: 25-Sep-2024 09:03:28

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Column 1 : Det: GC ECD1A

Column 2 : Det: GC ECD2B

Process Host: CTX1638

First Level Reviewer: XXL1 Date: 25-Sep-2024 08:09:20

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon M

1 2.186 2.185 0.001 4289090H 0.0400 0.0402 M

2 2.534 2.534 0.000 5010054H 0.0400 0.0384

RPD = 4.43

$ 2 2,4-Dichlorophenylacetic acid

1 7.871 7.870 0.001 1604401H 0.008000 0.008834

2 8.190 8.190 0.000 1647909H 0.008000 0.008490

RPD = 3.97

3 MCPP

1 8.087 8.087 0.000 2557858H 4.00 4.15

2 8.607 8.608 -0.001 7934329H 4.00 4.73

RPD = 12.97

4 Dicamba

1 8.162 8.162 0.000 10580771H 0.0200 0.0198

2 8.457 8.456 0.001 11663794H 0.0200 0.0199

RPD = 0.46

5 MCPA

1 8.504 8.504 0.000 3880188H 4.00 4.32

2 8.915 8.915 0.000 9922837H 4.00 5.38

RPD = 21.81

6 Dichlorprop

1 8.782 8.782 0.000 6093877H 0.0400 0.0402

2 9.276 9.277 -0.001 6792363H 0.0400 0.0409

RPD = 1.81

7 2,4-D

1 9.269 9.268 0.001 6735565H 0.0400 0.0399

2 9.671 9.672 -0.001 7350023H 0.0400 0.0405

RPD = 1.49

Page 8634 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000003.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.787 9.787 0.000 17791935H 0.0100 0.009771

2 9.896 9.896 0.000 19666921H 0.0100 0.0099

RPD = 1.42

9 Silvex (2,4,5-TP)

1 9.950 9.948 0.002 7642264H 0.0100 0.009876

2 10.441 10.440 0.001 8485088H 0.0100 0.0101

RPD = 1.86

10 2,4,5-T

1 10.493 10.493 0.000 6594384H 0.0100 0.0099

2 10.893 10.893 0.000 6965482H 0.0100 0.0101

RPD = 1.61

11 Dinoseb

1 10.750 10.749 0.001 14473667H 0.0400 0.0395

2 11.968 11.968 0.000 15957785H 0.0400 0.0404

RPD = 2.08

12 2,4-DB

1 10.876 10.874 0.002 3219888H 0.0400 0.0383

2 11.322 11.321 0.001 3378400H 0.0400 0.0380

RPD = 0.80

QC Flag Legend Processing Flags

H - Response Measured by Height

Review Flags

M - Manually Integrated

Reagents:

GCHERBCALSL2_00034 Amount Added: 1.00 Units: mL

Page 8635 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000003.D

Injection Date: 25-Sep-2024 07:43:31 Instrument ID: CGC1

Lims ID: IC

Client ID:

Operator ID: 402331 ALS Bottle#: 3 Worklist Smp#: 3

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0925240000003.D

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0925240000003.D

Page 8636 of 15442

Report Date: 26-Sep-2024 05:43:13 Chrom Revision: 2.3 26-Aug-2024 17:14:48

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000004.D

Lims ID: ICRT

Client ID:

Sample Type: ICRT Calib Level: 3

Inject. Date: 25-Sep-2024 08:03:28 ALS Bottle#: 4 Worklist Smp#: 4

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0053936-004

Operator ID: 402331 Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 26-Sep-2024 05:43:13 Calib Date: 25-Sep-2024 09:03:28

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Column 1 : Det: GC ECD1A

Column 2 : Det: GC ECD2B

Process Host: CTX1638

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.185 2.185 0.000 7486236H 0.0800 0.0701

2 2.534 2.534 0.000 9747427H 0.0800 0.0748

RPD = 6.42

$ 2 2,4-Dichlorophenylacetic acid

1 7.870 7.870 0.000 2926401H 0.0160 0.0161

2 8.190 8.190 0.000 3242093H 0.0160 0.0167

RPD = 3.60

3 MCPP

1 8.087 8.087 0.000 4764424H 8.00 7.73

2 8.608 8.608 0.000 12362162H 8.00 7.37

RPD = 4.87

4 Dicamba

1 8.162 8.162 0.000 20730219H 0.0400 0.0389

2 8.456 8.456 0.000 22834265H 0.0400 0.0390

RPD = 0.38

5 MCPA

1 8.504 8.504 0.000 7201802H 8.00 8.01

2 8.915 8.915 0.000 15214100H 8.00 8.24

RPD = 2.79

6 Dichlorprop

1 8.782 8.782 0.000 11610707H 0.0800 0.0766

2 9.277 9.277 0.000 12976188H 0.0800 0.0782

RPD = 2.07

7 2,4-D

1 9.268 9.268 0.000 13114687H 0.0800 0.0777

2 9.672 9.672 0.000 14316041H 0.0800 0.0789

RPD = 1.52

Page 8637 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000004.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.787 9.787 0.000 35623120H 0.0200 0.0196

2 9.896 9.896 0.000 39374050H 0.0200 0.0198

RPD = 1.41

9 Silvex (2,4,5-TP)

1 9.948 9.948 0.000 15253139H 0.0200 0.0197

2 10.440 10.440 0.000 16782888H 0.0200 0.0199

RPD = 0.95

10 2,4,5-T

1 10.493 10.493 0.000 13053390H 0.0200 0.0197

2 10.893 10.893 0.000 13971353H 0.0200 0.0202

RPD = 2.93

11 Dinoseb

1 10.749 10.749 0.000 28569716H 0.0800 0.0780

2 11.968 11.968 0.000 31512133H 0.0800 0.0797

RPD = 2.12

12 2,4-DB

1 10.874 10.874 0.000 6703301H 0.0800 0.0797

2 11.321 11.321 0.000 7192070H 0.0800 0.0808

RPD = 1.43

Reagents:

GCHERBCALSL3_00050 Amount Added: 1.00 Units: mL

Page 8638 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000004.D

Injection Date: 25-Sep-2024 08:03:28 Instrument ID: CGC1

Lims ID: ICRT

Client ID:

Operator ID: 402331 ALS Bottle#: 4 Worklist Smp#: 4

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0925240000004.D

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0925240000004.D

Page 8639 of 15442

Report Date: 26-Sep-2024 05:43:15 Chrom Revision: 2.3 26-Aug-2024 17:14:48

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000005.D

Lims ID: IC

Client ID:

Sample Type: IC Calib Level: 4

Inject. Date: 25-Sep-2024 08:23:28 ALS Bottle#: 5 Worklist Smp#: 5

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0053936-005

Operator ID: 402331 Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 26-Sep-2024 05:43:14 Calib Date: 25-Sep-2024 09:03:28

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Column 1 : Det: GC ECD1A

Column 2 : Det: GC ECD2B

Process Host: CTX1638

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.181 2.185 -0.004 19093930H 0.1600 0.1788

2 2.529 2.534 -0.005 22743545H 0.1600 0.1744

RPD = 2.48

$ 2 2,4-Dichlorophenylacetic acid

1 7.869 7.870 -0.001 5612284H 0.0320 0.0309

2 8.187 8.190 -0.003 6394104H 0.0320 0.0329

RPD = 6.39

3 MCPP

1 8.087 8.087 0.000 9507130H 16.0 15.4

2 8.606 8.608 -0.002 18988444H 16.0 11.3

RPD = 30.79

4 Dicamba

1 8.162 8.162 0.000 42687996H 0.0800 0.0801

2 8.455 8.456 -0.001 46951689H 0.0800 0.0803

RPD = 0.24

5 MCPA

1 8.502 8.504 -0.002 13961374H 16.0 15.5

2 8.912 8.915 -0.003 23751225H 16.0 12.9

RPD = 18.81

6 Dichlorprop

1 8.781 8.782 -0.001 23555061H 0.1600 0.1554

2 9.275 9.277 -0.002 25831370H 0.1600 0.1557

RPD = 0.18

7 2,4-D

1 9.267 9.268 -0.001 26804260H 0.1600 0.1588

2 9.670 9.672 -0.002 29369383H 0.1600 0.1618

RPD = 1.90

Page 8640 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000005.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.785 9.787 -0.002 74546656H 0.0400 0.0409

2 9.894 9.896 -0.002 82578523H 0.0400 0.0416

RPD = 1.63

9 Silvex (2,4,5-TP)

1 9.947 9.948 -0.001 31510223H 0.0400 0.0407

2 10.438 10.440 -0.002 35029030H 0.0400 0.0415

RPD = 1.98

10 2,4,5-T

1 10.491 10.493 -0.002 27875316H 0.0400 0.0420

2 10.891 10.893 -0.002 29517791H 0.0400 0.0428

RPD = 1.86

11 Dinoseb

1 10.748 10.749 -0.001 60182206H 0.1600 0.1643

2 11.967 11.968 -0.001 65315911H 0.1600 0.1652

RPD = 0.51

12 2,4-DB

1 10.872 10.874 -0.002 14388815H 0.1600 0.1711

2 11.318 11.321 -0.003 15642346H 0.1600 0.1758

RPD = 2.75

Reagents:

GCHERBCALSL4_00039 Amount Added: 1.00 Units: mL

Page 8641 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000005.D

Injection Date: 25-Sep-2024 08:23:28 Instrument ID: CGC1

Lims ID: IC

Client ID:

Operator ID: 402331 ALS Bottle#: 5 Worklist Smp#: 5

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD1A, 0925240000005.D

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0925240000005.D

Page 8642 of 15442

Report Date: 26-Sep-2024 05:43:16 Chrom Revision: 2.3 26-Aug-2024 17:14:48

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000006.D

Lims ID: IC

Client ID:

Sample Type: IC Calib Level: 5

Inject. Date: 25-Sep-2024 08:43:25 ALS Bottle#: 6 Worklist Smp#: 6

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0053936-006

Operator ID: 402331 Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 26-Sep-2024 05:43:15 Calib Date: 25-Sep-2024 09:03:28

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Column 1 : Det: GC ECD1A

Column 2 : Det: GC ECD2B

Process Host: CTX1638

First Level Reviewer: XXL1 Date: 25-Sep-2024 09:40:59

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.183 2.185 -0.002 32178401H 0.3200 0.3014

2 2.531 2.534 -0.003 38566361H 0.3200 0.2958

RPD = 1.86

$ 2 2,4-Dichlorophenylacetic acid

1 7.867 7.870 -0.003 9681722H 0.0640 0.0533

2 8.185 8.190 -0.005 11300506H 0.0640 0.0582

RPD = 8.81

3 MCPP

1 8.084 8.087 -0.003 17241090H 32.0 28.0

2 8.604 8.608 -0.004 28136254H 32.0 16.8

RPD = 50.15

4 Dicamba

1 8.159 8.162 -0.003 79069632H 0.1600 0.1483

2 8.453 8.456 -0.003 86631173H 0.1600 0.1481

RPD = 0.15

5 MCPA

1 8.500 8.504 -0.004 25154628H 32.0 28.0

2 8.911 8.915 -0.004 35794017H 32.0 19.4

RPD = 36.32

6 Dichlorprop

1 8.777 8.782 -0.005 42761206H 0.3200 0.2821

2 9.273 9.277 -0.004 46934512H 0.3200 0.2828

RPD = 0.27

7 2,4-D

1 9.264 9.268 -0.004 48970089H 0.3200 0.2900

2 9.668 9.672 -0.004 53214748H 0.3200 0.2932

RPD = 1.07

Page 8643 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000006.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.782 9.787 -0.005 137918054H 0.0800 0.0757

2 9.891 9.896 -0.005 150358167H 0.0800 0.0758

RPD = 0.03

9 Silvex (2,4,5-TP)

1 9.944 9.948 -0.004 57282047H 0.0800 0.0740

2 10.436 10.440 -0.004 62706672H 0.0800 0.0744

RPD = 0.44

10 2,4,5-T

1 10.488 10.493 -0.005 51014257H 0.0800 0.0768

2 10.888 10.893 -0.005 53543255H 0.0800 0.0776

RPD = 0.97

11 Dinoseb

1 10.744 10.749 -0.005 108683649H 0.3200 0.2968

2 11.964 11.968 -0.004 116268919H 0.3200 0.2940

RPD = 0.93

12 2,4-DB

1 10.869 10.874 -0.005 26624730H 0.3200 0.3165

2 11.316 11.321 -0.005 29186865H 0.3200 0.3281

RPD = 3.58

QC Flag Legend Processing Flags

H - Response Measured by Height

Reagents:

GCHERBCALSL5_00034 Amount Added: 1.00 Units: mL

Page 8644 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000006.D

Injection Date: 25-Sep-2024 08:43:25 Instrument ID: CGC1

Lims ID: IC

Client ID:

Operator ID: 402331 ALS Bottle#: 6 Worklist Smp#: 6

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0925240000006.D

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0925240000006.D

Page 8645 of 15442

Target Compound Quantitation Report

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Lims ID: IC

Client ID:

Sample Type: IC Calib Level: 6

Inject. Date: 25-Sep-2024 09:03:28 ALS Bottle#: 7 Worklist Smp#: 7

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Sample Info: 180-0053936-007

Operator ID: 402331 Instrument ID: CGC1

Sublist: chrom-Herbicides_CGC1*sub1

Method: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\Herbicides_CGC1.m

Limit Group: GCS 8151A ICAL

Last Update: 26-Sep-2024 05:43:17 Calib Date: 25-Sep-2024 09:03:28

Integrator: Falcon

Quant Method: External Standard Quant By: Initial Calibration

Last ICal File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Column 1 : Det: GC ECD1A

Column 2 : Det: GC ECD2B

Process Host: CTX1638

First Level Reviewer: XXL1 Date: 25-Sep-2024 09:30:53

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

1 Dalapon

1 2.183 2.185 -0.002 62011369H 0.6400 0.5808

2 2.530 2.534 -0.004 73521998H 0.6400 0.5639

RPD = 2.94

$ 2 2,4-Dichlorophenylacetic acid

1 7.866 7.870 -0.004 17841838H 0.1280 0.0982

2 8.184 8.190 -0.006 20581960H 0.1280 0.1060

RPD = 7.64

3 MCPP

1 8.084 8.087 -0.003 31910401H 64.0 51.8

2 8.604 8.608 -0.004 44431310H 64.0 26.5

RPD = 64.71

4 Dicamba

1 8.159 8.162 -0.003 151178763H 0.3200 0.2835

2 8.452 8.456 -0.004 163789075H 0.3200 0.2800

RPD = 1.27

5 MCPA

1 8.501 8.504 -0.003 47368260H 64.0 52.7

2 8.910 8.915 -0.005 58806041H 64.0 31.9

RPD = 49.33

6 Dichlorprop

1 8.778 8.782 -0.004 82707932H 0.6400 0.5456

2 9.272 9.277 -0.005 88756756H 0.6400 0.5349

RPD = 1.99

7 2,4-D

1 9.264 9.268 -0.004 92781927H 0.6400 0.5495

2 9.666 9.672 -0.006 100295760H 0.6400 0.5525

RPD = 0.55

Page 8646 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Col

RT

(min.)

Exp RT (min.)

Dlt RT (min.) Response

Cal Amt ng

OnCol Amt ng Flags

8 Pentachlorophenol

1 9.784 9.787 -0.003 265871167H 0.1600 0.1460

2 9.891 9.896 -0.005 286426209H 0.1600 0.1443

RPD = 1.16

9 Silvex (2,4,5-TP)

1 9.944 9.948 -0.004 108542766H 0.1600 0.1403

2 10.435 10.440 -0.005 117351333H 0.1600 0.1391

RPD = 0.80

10 2,4,5-T

1 10.488 10.493 -0.005 95951831H 0.1600 0.1445

2 10.887 10.893 -0.006 100199641H 0.1600 0.1452

RPD = 0.46

11 Dinoseb

1 10.745 10.749 -0.004 202846382H 0.6400 0.5539

2 11.964 11.968 -0.004 218939045H 0.6400 0.5537

RPD = 0.05

12 2,4-DB

1 10.869 10.874 -0.005 51967886H 0.6400 0.6179

2 11.315 11.321 -0.006 56021465H 0.6400 0.6297

RPD = 1.90

QC Flag Legend Processing Flags

H - Response Measured by Height

Reagents:

GCHERBCALSL6_00022 Amount Added: 1.00 Units: mL

Page 8647 of 15442

Data File: \\chromfs\Pittsburgh\ChromData\CGC1\20240925-53936.b\0925240000007.D

Injection Date: 25-Sep-2024 09:03:28 Instrument ID: CGC1

Lims ID: IC

Client ID:

Operator ID: 402331 ALS Bottle#: 7 Worklist Smp#: 7

Injection Vol: 1.0 ul Dil. Factor: 1.0000

Method: Herbicides_CGC1 Limit Group: GCS 8151A ICAL

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 17.0 Min

Y

X

GC ECD1A, 0925240000007.D

0.0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 11.0 12.0 13.0 14.0 15.0 16.0 Min

Y

X

GC ECD2B, 0925240000007.D

Page 8648 of 15442

Calibration / Dalapon

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.304E+08

Error Coefficients

Relative Standard Deviation: 10.3

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.01 1523598.0 152359800.0 Y

2 IC 180-480078/2 0.02 2712544.0 135627200.0 Y

3 IC 180-480078/3 0.04 5010054.0 125251350.0 Y

4 ICRT 180-480078/4 0.08 9747427.0 121842837.5 Y

5 IC 180-480078/5 0.16 22743545.0 142147156.25 Y

6 IC 180-480078/6 0.32 38566361.0 120519878.125 Y

7 IC 180-480078/7 0.64 73521998.0 114878121.875 Y

Response = [1.304E+08]x

Concentration

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8649 of 15442

Calibration / 2,4-Dichlorophenylacetic acid

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.941E+08

Error Coefficients

Relative Standard Deviation: 11.0

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.002 73495.0 36747500.0 N

2 IC 180-480078/2 0.004 875253.0 218813250.0 Y

3 IC 180-480078/3 0.008 1647909.0 205988625.0 Y

4 ICRT 180-480078/4 0.016 3242093.0 202630812.5 Y

5 IC 180-480078/5 0.032 6394104.0 199815750.0 Y

6 IC 180-480078/6 0.064 11300506.0 176570406.25 Y

7 IC 180-480078/7 0.128 20581960.0 160796562.5 Y

Response = [1.941E+08]x

Concentration

0 0.1 0.2 0.0

0.5

1.0

1.5

2.0

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

IC 180-480078/6

IC 180-480078/7

Page 8650 of 15442

Calibration / Dicamba

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 5.85E+08

Error Coefficients

Relative Standard Deviation: 9.3

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.005 3394670.0 678934000.0 Y

2 IC 180-480078/2 0.01 6221252.0 622125200.0 Y

3 IC 180-480078/3 0.02 11663794.0 583189700.0 Y

4 ICRT 180-480078/4 0.04 22834265.0 570856625.0 Y

5 IC 180-480078/5 0.08 46951689.0 586896112.5 Y

6 IC 180-480078/6 0.16 86631173.0 541444831.25 Y

7 IC 180-480078/7 0.32 163789075.0 511840859.375 Y

Response = [5.85E+08]x

Concentration

0 0.1 0.2 0.3 0.4 0.0

0.5

1.0

1.5

R esponse ( X

100000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8651 of 15442

Calibration / MCPP

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.678E+06

Error Coefficients

Relative Standard Deviation: 50.5

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 1.0 2992631.0 2992631.0 Y

2 IC 180-480078/2 2.0 4934968.0 2467484.0 Y

3 IC 180-480078/3 4.0 7934329.0 1983582.25 Y

4 ICRT 180-480078/4 8.0 12362162.0 1545270.25 Y

5 IC 180-480078/5 16.0 18988444.0 1186777.75 Y

6 IC 180-480078/6 32.0 28136254.0 879257.9375 Y

7 IC 180-480078/7 64.0 44431310.0 694239.21875 Y

Response = [1.678E+06]x

Concentration

0 10 20 30 40 50 60 70 0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8652 of 15442

Calibration / MCPA

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.846E+06

Error Coefficients

Relative Standard Deviation: 46.5

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 1.0 3865496.0 3865496.0 N

2 IC 180-480078/2 2.0 6343857.0 3171928.5 Y

3 IC 180-480078/3 4.0 9922837.0 2480709.25 Y

4 ICRT 180-480078/4 8.0 15214100.0 1901762.5 Y

5 IC 180-480078/5 16.0 23751225.0 1484451.5625 Y

6 IC 180-480078/6 32.0 35794017.0 1118563.03125 Y

7 IC 180-480078/7 64.0 58806041.0 918844.390625 Y

Response = [1.846E+06]x

Concentration

0 10 20 30 40 50 60 70 0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8653 of 15442

Calibration / Dichlorprop

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.659E+08

Error Coefficients

Relative Standard Deviation: 12.8

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.01 2027683.0 202768300.0 Y

2 IC 180-480078/2 0.02 3600367.0 180018350.0 Y

3 IC 180-480078/3 0.04 6792363.0 169809075.0 Y

4 ICRT 180-480078/4 0.08 12976188.0 162202350.0 Y

5 IC 180-480078/5 0.16 25831370.0 161446062.5 Y

6 IC 180-480078/6 0.32 46934512.0 146670350.0 Y

7 IC 180-480078/7 0.64 88756756.0 138682431.25 Y

Response = [1.659E+08]x

Concentration

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.0

1.0

2.0

3.0

4.0

5.0

6.0

7.0

8.0

R esponse ( X

10000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8654 of 15442

Calibration / 2,4-D

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.815E+08

Error Coefficients

Relative Standard Deviation: 9.2

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.01 2065920.0 206592000.0 Y

2 IC 180-480078/2 0.02 3895265.0 194763250.0 Y

3 IC 180-480078/3 0.04 7350023.0 183750575.0 Y

4 ICRT 180-480078/4 0.08 14316041.0 178950512.5 Y

5 IC 180-480078/5 0.16 29369383.0 183558643.75 Y

6 IC 180-480078/6 0.32 53214748.0 166296087.5 Y

7 IC 180-480078/7 0.64 100295760.0 156712125.0 Y

Response = [1.815E+08]x

Concentration

0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.0

0.2

0.4

0.6

0.8

1.0

R esponse ( X

100000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8655 of 15442

Calibration / Pentachlorophenol

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 1.984E+09

Error Coefficients

Relative Standard Deviation: 6.5

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.0025 5470425.0 2188170000.0 Y

2 IC 180-480078/2 0.005 10168805.0 2033761000.0 Y

3 IC 180-480078/3 0.01 19666921.0 1966692100.0 Y

4 ICRT 180-480078/4 0.02 39374050.0 1968702500.0 Y

5 IC 180-480078/5 0.04 82578523.0 2064463075.0 Y

6 IC 180-480078/6 0.08 150358167.0 1879477087.5 Y

7 IC 180-480078/7 0.16 286426209.0 1790163806.25 Y

Response = [1.984E+09]x

Concentration

0 0.1 0.2 0.0

0.5

1.0

1.5

2.0

2.5

R esponse ( X

100000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8656 of 15442

Calibration / Silvex (2,4,5-TP)

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 8.434E+08

Error Coefficients

Relative Standard Deviation: 8.1

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.0025 2362864.0 945145600.0 Y

2 IC 180-480078/2 0.005 4389344.0 877868800.0 Y

3 IC 180-480078/3 0.01 8485088.0 848508800.0 Y

4 ICRT 180-480078/4 0.02 16782888.0 839144400.0 Y

5 IC 180-480078/5 0.04 35029030.0 875725750.0 Y

6 IC 180-480078/6 0.08 62706672.0 783833400.0 Y

7 IC 180-480078/7 0.16 117351333.0 733445831.25 Y

Response = [8.434E+08]x

Concentration

0 0.1 0.2 0.0

0.2

0.4

0.6

0.8

1.0

1.2

R esponse ( X

100000000)

IC 180-480078/1

IC 180-480078/2

IC 180-480078/3

ICRT 180-480078/4

IC 180-480078/5

Page 8657 of 15442

Calibration / 2,4,5-T

Weighting: Conc_Sq

Origin: Force

Dependency: Response

Calib Mode: ESTD

Response Base: HEIGHT

RF Rounding: 0

Curve Coefficients

Intercept: 0

Slope: 6.901E+08

Error Coefficients

Relative Standard Deviation: 5.0

ID Level Concentration Response IS Amount IS Response RF Used

1 IC 180-480078/1 0.0025 1735951.0 694380400.0 Y

2 IC 180-480078/2 0.005 3537057.0 707411400.0 Y

3 IC 180-480078/3 0.01 6965482.0 696548200.0 Y

4 ICRT 180-480078/4 0.02 13971353.0 698567650.0 Y

5 IC 180-480078/5 0.04 29517791.0 737944775.0 Y

6 IC 180-480078/6 0.08 53543255.0 669290687.5 Y

7 IC 180-480078/7 0.16 100199641.0 626247756.25 Y

Response = [6.901E+08]x

Concentration

0 0.1 0.2 0.0

0.2

0.4

0.6