Specifications Part 6 07073.pdf

PDF 5 MB Posted Oct 9, 2017

Attached to: Belgravia - Remediation System Construction Support
Solicitation number: RFQ 171 180000000015 6
Issued by: Van Buren County, South Haven City, Michigan

About this file

Written by GovTribe AI · Mar 11, 2026

This file contains specifications, analytical reports, and environmental assessment documents for the Belgravia Thermal Remediation Project located at 125 Elkenburg Street in South Haven, Michigan, involving the Michigan Department of Environmental Quality (MDEQ) and the City of South Haven. The project encompasses in-situ thermal site remediation of contaminated groundwater and soil using Electro-Thermal Dynamic Stripping Process (ET-DSP) technology. The work includes installation of subsurface electrodes, extraction wells, and related infrastructure to address volatile organic compounds (VOCs) and other contaminants identified in groundwater monitoring samples collected in November 2014 and April 2015. The documentation includes detailed analytical results from 18 groundwater sample locations and 20 soil boring locations, with contamination parameters including trichloroethylene (TCE), cis-1,2-dichloroethylene, vinyl chloride, arsenic, cadmium, and polycyclic aromatic hydrocarbons (PAHs) exceeding Michigan Part 201 residential cleanup criteria. Electrode installation procedures specify the use of sonic drilling technology with core-and-case methodology, graphite and sand backfill materials, and dual electrode configurations (shallow and deep) per borehole, with electrodes weighing approximately 100-130 pounds each and measuring 3.7 meters in length.

The contract documents indicate that the Professional (design entity) will provide electrode materials, graphite, hoses, and ancillary equipment, while the Contractor is responsible for offloading, staging, drilling, electrode installation, utility coordination through Miss Dig notification, and obtaining all required permits. The project site includes the former Overton Building and surrounding properties with groundwater depths ranging from 4 to 9 feet below ground surface. The remediation design addresses historical contamination sources including a 20,000-gallon oil tank leak, foundry operations, railroad spur use, and coal bunker operations. Truck access routes have been designated for heavy equipment delivery, and the project requires coordination with existing utilities, monitoring wells, and the adjacent bike path. The City of South Haven, as a non-liable party under MDEQ law, must complete a Baseline Environmental Assessment within six months of ownership and implement a Due Care Plan to prevent exacerbation and mitigate exposure risks during demolition and construction activities associated with the site's intended redevelopment.

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Specifications Part 4 07073.pdf	PDF	Oct 9, 2017
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Table 1

Summary of Analytical Results - Groundwater Samples

Belgravia - November, 2014

Sample ID MW-49I MW-47I MW-34 MW-36D MW-54 MW-40 MW-37I MW-37D MW-33I

Sample Date 11/12/2014 11/12/2014 11/12/2014 11/12/2014 11/12/2014 11/12/2014 11/12/2014 11/12/2014 11/12/2014

Total VOCs 14 35,500 40 0 0 2,500 4 1 0

2-Butanone (MEK) < < < < < < < < < 13,000 2,200 240,000,000

2-Propanone (acetone) < < < < < < < < < 730 1,700 1,000,000,000 cis-1,2-Dichloroethylene < 7,500 < < < 1,100 < < < 70 620 93,000

Tetrachloroethylene 14 < 40 < < < < < < 5 60 25,000

Trichloroethylene < 28,000 < < < < 2.3 1.3 < 5 200 2,200

Vinyl chloride < < < < < 1,400 1.2 < < 2 13 1,100

NOTES:

1. Presented in ug/L (ppb) against Part 201 residential criteria

2. < = Less than method detection limit

3. N/A = Not Available

4. NA = Not Applicable

5. ID = Inadequate data to develop criterion

6. NLV=Not Likely to Volatilize

7. Only compounds with detections are presented

8. Criterion are based on the

December 30, 2013 MDEQ BOLD=Exceeds one or more Part 201 Cleanup Criteria

Exceeds two or more Part 201 Cleanup Criteria

Exceeds three or more Part 201 Cleanup Criteria

DWC=Drinking Water Criteria

GSIC=Groundwater-Surface Water Interface Criteria

GVIAIC=Groundwater Volatilization to Indoor Air Inhalation Criteria

Part 201 DWC Part 201 GSIC Part 201 GVIAIC

Summary of Analytical Results - Groundwater Samples

Belgravia - November, 2014

Sample ID MW-33D MW-50I MW-43I MW-42I MW-30 MW-18R Dupicate Equipment Blank Field Blank

Sample Date 11/12/2014 11/12/2014 11/12/2014 11/12/2014 11/12/2014 11/12/2014 11/12/2014 11/12/2014 11/12/2014

Total VOCs 0 2 32 0 0 84,600 102,600 0 0

2-Butanone (MEK) < < 4.9 < < < < < < 13,000 2,200 240,000,000

2-Propanone (acetone) < < 27 < < < < < < 730 1,700 1,000,000,000 cis-1,2-Dichloroethylene < < < < < 33,000 33,000 < < 70 620 93,000

Tetrachloroethylene < < < < < < < < < 5 60 25,000

Trichloroethylene < 2.2 < < < 50,000 68,000 < < 5 200 2,200

Vinyl chloride < < < < < 1,600 1,600 < < 2 13 1,100

NOTES:

1. Presented in ug/L (ppb) against Part 201 residential criteria

2. < = Less than method detection limit

3. N/A = Not Available

4. NA = Not Applicable

5. ID = Inadequate data to develop criterion

6. NLV=Not Likely to Volatilize

7. Only compounds with detections are presented

8. Criterion are based on the

December 30, 2013 MDEQ BOLD=Exceeds one or more Part 201 Cleanup Criteria

Exceeds two or more Part 201 Cleanup Criteria

Exceeds three or more Part 201 Cleanup Criteria

DWC=Drinking Water Criteria

GSIC=Groundwater-Surface Water Interface Criteria

GVIAIC=Groundwater Volatilization to Indoor Air Inhalation Criteria

Part 201 DWC Part 201 GSIC Part 201 GVIAIC

P.O. Box 30270

Lansing, MI 48909

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

MDEQ-RRD-KALAMAZOO

RE: BELGRAVIA

Kalamazoo, MI 49009

7953 Adobe Road

Evans Ray Spaulding

I certify that the analyses performed by the MDEQ Environmental Laboratory were conducted by methods approved by the U.S. Environmental Protection Agency and other appropriate regulatory agencies .

Sincerely, 05 May 2015 Work Order: 1504159

Price: $880.00

George Krisztian

Laboratory Director

Lab Work Order # 1504159

Page 1 of 16Page 1 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

Project:

Project Manager:

Reported:

MDEQ-RRD-KALAMAZOO

7953 Adobe Road

Evans Ray Spaulding

BELGRAVIA

Kalamazoo MI, 49009

Site Code: LB041479 05/05/2015

Sample ID Laboratory ID Date SampledMatrix Date Received

Analytical Report for Samples

Qualifier

1504159-01 Water 04/22/2015RW-3-0415 04/21/2015

1504159-02 Water 04/22/2015MW-46i 0415 04/21/2015

1504159-03 Water 04/22/2015PSW-2-0415 04/21/2015

1504159-04 Water 04/22/2015107SUMP-0415 04/21/2015

1504159-05 Water 04/22/2015108SUMP-0415 04/21/2015

Notes and Definitions

X Methods 8260 & 624 are used to analyze volatile organics that have boiling points below 200 ºC. 2-Methylnaphthalene & naphthalene have boiling points above 200 ºC and are better suited to analysis by methods 8270 & 625 as semivolatile organics.

H Recommended laboratory holding time was exceeded.

A06 Result is estimated due to high continuing calibration standard criteria failure.

Reporting LimitRL

Indicates compound analyzed for but not detectedND

Not ApplicableNA

Page 2 of 16Page 2 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-01

RLCAS #

Client ID: RW-3-0415

QC Batch

Organics-Volatiles

5000 ug/L 5000 82601,1,1,2-Tetrachloroethane630-20-6 04/28/15ND B5D2807

5000 ug/L 5000 82601,1,1-Trichloroethane71-55-6 04/28/15ND B5D2807

5000 ug/L 5000 82601,1,2,2-Tetrachloroethane79-34-5 04/28/15ND B5D2807

5000 ug/L 5000 82601,1,2-Trichloroethane79-00-5 04/28/15ND B5D2807

5000 ug/L 5000 82601,1-Dichloroethane75-34-3 04/28/15ND B5D2807

5000 ug/L 5000 82601,1-Dichloroethylene75-35-4 04/28/15ND B5D2807

25000 ug/L 5000 82601,2,3-Trichlorobenzene87-61-6 04/28/15ND B5D2807

5000 ug/L 5000 82601,2,3-Trichloropropane96-18-4 04/28/15ND B5D2807

5000 ug/L 5000 82601,2,3-Trimethylbenzene526-73-8 04/28/15ND B5D2807

25000 ug/L 5000 82601,2,4-Trichlorobenzene120-82-1 04/28/15ND B5D2807

5000 ug/L 5000 82601,2,4-Trimethylbenzene95-63-6 04/28/15ND B5D2807

25000 ug/L 5000 82601,2-Dibromo-3-chloropropane96-12-8 04/28/15ND B5D2807

5000 ug/L 5000 82601,2-Dibromoethane106-93-4 04/28/15ND B5D2807

5000 ug/L 5000 82601,2-Dichlorobenzene95-50-1 04/28/15ND B5D2807

5000 ug/L 5000 82601,2-Dichloroethane107-06-2 04/28/15ND B5D2807

5000 ug/L 5000 82601,2-Dichloropropane78-87-5 04/28/15ND B5D2807

5000 ug/L 5000 82601,3,5-Trimethylbenzene108-67-8 04/28/15ND B5D2807

5000 ug/L 5000 82601,3-Dichlorobenzene541-73-1 04/28/15ND B5D2807

5000 ug/L 5000 82601,4-Dichlorobenzene106-46-7 04/28/15ND B5D2807

25000 ug/L 5000 82602-Butanone (MEK)78-93-3 04/28/15ND B5D2807

25000 ug/L 5000 82602-Hexanone591-78-6 04/28/15ND B5D2807

25000 Xug/L 5000 82602-Methylnaphthalene91-57-6 04/28/15ND B5D2807

100000 ug/L 5000 82602-Propanone (acetone)67-64-1 04/28/15ND B5D2807

25000 ug/L 5000 82604-Methyl-2-pentanone (MIBK)108-10-1 04/28/15ND B5D2807

25000 ug/L 5000 8260Acrylonitrile107-13-1 04/28/15ND B5D2807

5000 ug/L 5000 8260Benzene71-43-2 04/28/15ND B5D2807

5000 ug/L 5000 8260Bromobenzene108-86-1 04/28/15ND B5D2807

5000 ug/L 5000 8260Bromochloromethane74-97-5 04/28/15ND B5D2807

5000 ug/L 5000 8260Bromodichloromethane75-27-4 04/28/15ND B5D2807

5000 ug/L 5000 8260Bromoform75-25-2 04/28/15ND B5D2807

25000 ug/L 5000 8260Bromomethane74-83-9 04/28/15ND B5D2807

5000 ug/L 5000 8260Carbon disulfide75-15-0 04/28/15ND B5D2807

5000 ug/L 5000 8260Carbon tetrachloride56-23-5 04/28/15ND B5D2807

5000 ug/L 5000 8260Chlorobenzene108-90-7 04/28/15ND B5D2807

25000 ug/L 5000 8260Chloroethane75-00-3 04/28/15ND B5D2807

5000 ug/L 5000 8260Chloroform67-66-3 04/28/15ND B5D2807

25000 ug/L 5000 8260Chloromethane74-87-3 04/28/15ND B5D2807

5000 ug/L 5000 8260cis-1,2-Dichloroethylene156-59-2 04/28/1520000 B5D2807

5000 ug/L 5000 8260cis-1,3-Dichloropropylene10061-01-5 04/28/15ND B5D2807

25000 ug/L 5000 8260Cyclohexane110-82-7 04/28/15ND B5D2807

5000 ug/L 5000 8260Dibromochloromethane124-48-1 04/28/15ND B5D2807

Page 3 of 16Page 3 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-01

RLCAS #

Client ID: RW-3-0415

QC Batch

Organics-Volatiles

5000 ug/L 5000 8260Dibromomethane74-95-3 04/28/15ND B5D2807

25000 ug/L 5000 8260Dichlorodifluoromethane75-71-8 04/28/15ND B5D2807

25000 ug/L 5000 8260Diethyl ether60-29-7 04/28/15ND B5D2807

25000 ug/L 5000 8260Diisopropyl Ether108-20-3 04/28/15ND B5D2807

5000 ug/L 5000 8260Ethylbenzene100-41-4 04/28/15ND B5D2807

25000 ug/L 5000 8260Ethyltertiarybutylether637-92-3 04/28/15ND B5D2807

25000 ug/L 5000 8260Hexachloroethane67-72-1 04/28/15ND B5D2807

5000 ug/L 5000 8260Isopropylbenzene98-82-8 04/28/15ND B5D2807

10000 ug/L 5000 8260m & p - Xylene1330-20-7 04/28/15ND B5D2807

5000 ug/L 5000 8260Methyl iodide74-88-4 04/28/15ND B5D2807

25000 ug/L 5000 8260Methylene chloride75-09-2 04/28/15ND B5D2807

5000 ug/L 5000 8260Methyltertiarybutylether1634-04-4 04/28/15ND B5D2807

25000 Xug/L 5000 8260Naphthalene91-20-3 04/28/15ND B5D2807

5000 ug/L 5000 8260n-Butylbenzene104-51-8 04/28/15ND B5D2807

5000 ug/L 5000 8260n-Propylbenzene103-65-1 04/28/15ND B5D2807

5000 ug/L 5000 8260o-Xylene95-47-6 04/28/15ND B5D2807

5000 ug/L 5000 8260p-Isopropyl toluene99-87-6 04/28/15ND B5D2807

5000 ug/L 5000 8260sec-Butylbenzene135-98-8 04/28/15ND B5D2807

5000 ug/L 5000 8260Styrene100-42-5 04/28/15ND B5D2807

5000 ug/L 5000 8260tert-Butylbenzene98-06-6 04/28/15ND B5D2807

250000 ug/L 5000 8260tertiary Butyl Alcohol75-65-0 04/28/15ND B5D2807

25000 ug/L 5000 8260tertiaryAmylmethylether994-05-8 04/28/15ND B5D2807

5000 ug/L 5000 8260Tetrachloroethylene127-18-4 04/28/15ND B5D2807

25000 ug/L 5000 8260Tetrahydrofuran109-99-9 04/28/15ND B5D2807

5000 ug/L 5000 8260Toluene108-88-3 04/28/15ND B5D2807

5000 ug/L 5000 8260trans-1,2-Dichloroethylene156-60-5 04/28/15ND B5D2807

5000 ug/L 5000 8260trans-1,3-Dichloropropylene10061-02-6 04/28/15ND B5D2807

25000 ug/L 5000 8260trans-1,4-Dichloro-2-butene110-57-6 04/28/15ND B5D2807

5000 ug/L 5000 8260Trichloroethylene79-01-6 04/28/15140000 B5D2807

5000 ug/L 5000 8260Trichlorofluoromethane75-69-4 04/28/15ND B5D2807

5000 ug/L 5000 8260Vinyl chloride75-01-4 04/28/15ND B5D2807

85-115101 %Surrogate: Bromofluorobenzene 826004/28/15 B5D2807

82.7-115103 %Surrogate: Dibromofluoromethane 826004/28/15 B5D2807

85-115101 %Surrogate: Toluene-d8 826004/28/15 B5D2807

Page 4 of 16Page 4 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-01

RLCAS #

Client ID: RW-3-0415

QC Batch

Inorganics-General Chemistry

20 mg/L 1 310.2Alkalinity-Total 04/23/15150 B5D2306 umhos/cm 1 120.1Conductivity 04/22/15510 B5D2214

HpH Units 1 4500 H+ BpH 04/22/158.0 B5D2214

20 mg/L 1 2540 CTotal Dissolved SolidsTDS 04/24/15340 B5D2405

Inorganics-Metals

1.0 mg/L 1 6010/200.7Calcium, Dissolved7440-70-2 05/01/1545 B5D2401

4.6 mg/L 1 2340 BHardness - Calculated 05/01/15160 [CALC]

20 ug/L 1 6010/200.7Iron, Dissolved7439-89-6 05/01/15210 B5D2401

0.5 mg/L 1 6010/200.7Magnesium, Dissolved7439-95-4 05/01/1511 B5D2401

Page 5 of 16Page 5 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-02

RLCAS #

Client ID: MW-46i 0415

QC Batch

Organics-Volatiles

2000 ug/L 2000 82601,1,1,2-Tetrachloroethane630-20-6 04/28/15ND B5D2807

2000 ug/L 2000 82601,1,1-Trichloroethane71-55-6 04/28/15ND B5D2807

2000 ug/L 2000 82601,1,2,2-Tetrachloroethane79-34-5 04/28/15ND B5D2807

2000 ug/L 2000 82601,1,2-Trichloroethane79-00-5 04/28/15ND B5D2807

2000 ug/L 2000 82601,1-Dichloroethane75-34-3 04/28/15ND B5D2807

2000 ug/L 2000 82601,1-Dichloroethylene75-35-4 04/28/15ND B5D2807

10000 ug/L 2000 82601,2,3-Trichlorobenzene87-61-6 04/28/15ND B5D2807

2000 ug/L 2000 82601,2,3-Trichloropropane96-18-4 04/28/15ND B5D2807

2000 ug/L 2000 82601,2,3-Trimethylbenzene526-73-8 04/28/15ND B5D2807

10000 ug/L 2000 82601,2,4-Trichlorobenzene120-82-1 04/28/15ND B5D2807

2000 ug/L 2000 82601,2,4-Trimethylbenzene95-63-6 04/28/15ND B5D2807

10000 ug/L 2000 82601,2-Dibromo-3-chloropropane96-12-8 04/28/15ND B5D2807

2000 ug/L 2000 82601,2-Dibromoethane106-93-4 04/28/15ND B5D2807

2000 ug/L 2000 82601,2-Dichlorobenzene95-50-1 04/28/15ND B5D2807

2000 ug/L 2000 82601,2-Dichloroethane107-06-2 04/28/15ND B5D2807

2000 ug/L 2000 82601,2-Dichloropropane78-87-5 04/28/15ND B5D2807

2000 ug/L 2000 82601,3,5-Trimethylbenzene108-67-8 04/28/15ND B5D2807

2000 ug/L 2000 82601,3-Dichlorobenzene541-73-1 04/28/15ND B5D2807

2000 ug/L 2000 82601,4-Dichlorobenzene106-46-7 04/28/15ND B5D2807

10000 ug/L 2000 82602-Butanone (MEK)78-93-3 04/28/15ND B5D2807

10000 ug/L 2000 82602-Hexanone591-78-6 04/28/15ND B5D2807

10000 Xug/L 2000 82602-Methylnaphthalene91-57-6 04/28/15ND B5D2807

40000 ug/L 2000 82602-Propanone (acetone)67-64-1 04/28/15ND B5D2807

10000 ug/L 2000 82604-Methyl-2-pentanone (MIBK)108-10-1 04/28/15ND B5D2807

10000 ug/L 2000 8260Acrylonitrile107-13-1 04/28/15ND B5D2807

2000 ug/L 2000 8260Benzene71-43-2 04/28/15ND B5D2807

2000 ug/L 2000 8260Bromobenzene108-86-1 04/28/15ND B5D2807

2000 ug/L 2000 8260Bromochloromethane74-97-5 04/28/15ND B5D2807

2000 ug/L 2000 8260Bromodichloromethane75-27-4 04/28/15ND B5D2807

2000 ug/L 2000 8260Bromoform75-25-2 04/28/15ND B5D2807

10000 ug/L 2000 8260Bromomethane74-83-9 04/28/15ND B5D2807

2000 ug/L 2000 8260Carbon disulfide75-15-0 04/28/15ND B5D2807

2000 ug/L 2000 8260Carbon tetrachloride56-23-5 04/28/15ND B5D2807

2000 ug/L 2000 8260Chlorobenzene108-90-7 04/28/15ND B5D2807

10000 ug/L 2000 8260Chloroethane75-00-3 04/28/15ND B5D2807

2000 ug/L 2000 8260Chloroform67-66-3 04/28/15ND B5D2807

10000 ug/L 2000 8260Chloromethane74-87-3 04/28/15ND B5D2807

2000 ug/L 2000 8260cis-1,2-Dichloroethylene156-59-2 04/28/1547000 B5D2807

2000 ug/L 2000 8260cis-1,3-Dichloropropylene10061-01-5 04/28/15ND B5D2807

10000 ug/L 2000 8260Cyclohexane110-82-7 04/28/15ND B5D2807

2000 ug/L 2000 8260Dibromochloromethane124-48-1 04/28/15ND B5D2807

Page 6 of 16Page 6 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-02

RLCAS #

Client ID: MW-46i 0415

QC Batch

Organics-Volatiles

2000 ug/L 2000 8260Dibromomethane74-95-3 04/28/15ND B5D2807

10000 ug/L 2000 8260Dichlorodifluoromethane75-71-8 04/28/15ND B5D2807

10000 ug/L 2000 8260Diethyl ether60-29-7 04/28/15ND B5D2807

10000 ug/L 2000 8260Diisopropyl Ether108-20-3 04/28/15ND B5D2807

2000 ug/L 2000 8260Ethylbenzene100-41-4 04/28/15ND B5D2807

10000 ug/L 2000 8260Ethyltertiarybutylether637-92-3 04/28/15ND B5D2807

10000 ug/L 2000 8260Hexachloroethane67-72-1 04/28/15ND B5D2807

2000 ug/L 2000 8260Isopropylbenzene98-82-8 04/28/15ND B5D2807

4000 ug/L 2000 8260m & p - Xylene1330-20-7 04/28/15ND B5D2807

2000 ug/L 2000 8260Methyl iodide74-88-4 04/28/15ND B5D2807

10000 ug/L 2000 8260Methylene chloride75-09-2 04/28/15ND B5D2807

2000 ug/L 2000 8260Methyltertiarybutylether1634-04-4 04/28/15ND B5D2807

10000 Xug/L 2000 8260Naphthalene91-20-3 04/28/15ND B5D2807

2000 ug/L 2000 8260n-Butylbenzene104-51-8 04/28/15ND B5D2807

2000 ug/L 2000 8260n-Propylbenzene103-65-1 04/28/15ND B5D2807

2000 ug/L 2000 8260o-Xylene95-47-6 04/28/15ND B5D2807

2000 ug/L 2000 8260p-Isopropyl toluene99-87-6 04/28/15ND B5D2807

2000 ug/L 2000 8260sec-Butylbenzene135-98-8 04/28/15ND B5D2807

2000 ug/L 2000 8260Styrene100-42-5 04/28/15ND B5D2807

2000 ug/L 2000 8260tert-Butylbenzene98-06-6 04/28/15ND B5D2807

100000 ug/L 2000 8260tertiary Butyl Alcohol75-65-0 04/28/15ND B5D2807

10000 ug/L 2000 8260tertiaryAmylmethylether994-05-8 04/28/15ND B5D2807

2000 ug/L 2000 8260Tetrachloroethylene127-18-4 04/28/15ND B5D2807

10000 ug/L 2000 8260Tetrahydrofuran109-99-9 04/28/15ND B5D2807

2000 ug/L 2000 8260Toluene108-88-3 04/28/15ND B5D2807

2000 ug/L 2000 8260trans-1,2-Dichloroethylene156-60-5 04/28/15ND B5D2807

2000 ug/L 2000 8260trans-1,3-Dichloropropylene10061-02-6 04/28/15ND B5D2807

10000 ug/L 2000 8260trans-1,4-Dichloro-2-butene110-57-6 04/28/15ND B5D2807

2000 ug/L 2000 8260Trichloroethylene79-01-6 04/28/1577000 B5D2807

2000 ug/L 2000 8260Trichlorofluoromethane75-69-4 04/28/15ND B5D2807

2000 ug/L 2000 8260Vinyl chloride75-01-4 04/28/15ND B5D2807

85-115103 %Surrogate: Bromofluorobenzene 826004/28/15 B5D2807

82.7-115102 %Surrogate: Dibromofluoromethane 826004/28/15 B5D2807

85-115101 %Surrogate: Toluene-d8 826004/28/15 B5D2807

Page 7 of 16Page 7 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-02

RLCAS #

Client ID: MW-46i 0415

QC Batch

Inorganics-General Chemistry

20 mg/L 1 310.2Alkalinity-Total 04/23/15210 B5D2306 umhos/cm 1 120.1Conductivity 04/22/15875 B5D2214

HpH Units 1 4500 H+ BpH 04/22/158.1 B5D2214

20 mg/L 1 2540 CTotal Dissolved SolidsTDS 04/24/15580 B5D2405

Inorganics-Metals

1.0 mg/L 1 6010/200.7Calcium7440-70-2 04/28/1582 B5D2303

1.0 mg/L 1 6010/200.7Calcium, Dissolved7440-70-2 05/01/1574 B5D2401

4.6 mg/L 1 2340 BHardness - Calculated 04/28/15410 [CALC]

4.6 mg/L 1 2340 BHardness - Calculated 05/01/15390 [CALC]

20 ug/L 1 6010/200.7Iron7439-89-6 04/28/152200 B5D2303

20 ug/L 1 6010/200.7Iron, Dissolved7439-89-6 05/01/1534 B5D2401

0.5 mg/L 1 6010/200.7Magnesium7439-95-4 04/28/1550 B5D2303

0.5 mg/L 1 6010/200.7Magnesium, Dissolved7439-95-4 05/01/1549 B5D2401

Page 8 of 16Page 8 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-03

RLCAS #

Client ID: PSW-2-0415

QC Batch

Organics-Volatiles

20000 ug/L 20000 82601,1,1,2-Tetrachloroethane630-20-6 04/28/15ND B5D2807

20000 ug/L 20000 82601,1,1-Trichloroethane71-55-6 04/28/15ND B5D2807

20000 ug/L 20000 82601,1,2,2-Tetrachloroethane79-34-5 04/28/15ND B5D2807

20000 ug/L 20000 82601,1,2-Trichloroethane79-00-5 04/28/15ND B5D2807

20000 ug/L 20000 82601,1-Dichloroethane75-34-3 04/28/15ND B5D2807

20000 ug/L 20000 82601,1-Dichloroethylene75-35-4 04/28/15ND B5D2807

100000 ug/L 20000 82601,2,3-Trichlorobenzene87-61-6 04/28/15ND B5D2807

20000 ug/L 20000 82601,2,3-Trichloropropane96-18-4 04/28/15ND B5D2807

20000 ug/L 20000 82601,2,3-Trimethylbenzene526-73-8 04/28/15ND B5D2807

100000 ug/L 20000 82601,2,4-Trichlorobenzene120-82-1 04/28/15ND B5D2807

20000 ug/L 20000 82601,2,4-Trimethylbenzene95-63-6 04/28/15ND B5D2807

100000 ug/L 20000 82601,2-Dibromo-3-chloropropane96-12-8 04/28/15ND B5D2807

20000 ug/L 20000 82601,2-Dibromoethane106-93-4 04/28/15ND B5D2807

20000 ug/L 20000 82601,2-Dichlorobenzene95-50-1 04/28/15ND B5D2807

20000 ug/L 20000 82601,2-Dichloroethane107-06-2 04/28/15ND B5D2807

20000 ug/L 20000 82601,2-Dichloropropane78-87-5 04/28/15ND B5D2807

20000 ug/L 20000 82601,3,5-Trimethylbenzene108-67-8 04/28/15ND B5D2807

20000 ug/L 20000 82601,3-Dichlorobenzene541-73-1 04/28/15ND B5D2807

20000 ug/L 20000 82601,4-Dichlorobenzene106-46-7 04/28/15ND B5D2807

100000 ug/L 20000 82602-Butanone (MEK)78-93-3 04/28/15ND B5D2807

100000 ug/L 20000 82602-Hexanone591-78-6 04/28/15ND B5D2807

100000 Xug/L 20000 82602-Methylnaphthalene91-57-6 04/28/15ND B5D2807

400000 ug/L 20000 82602-Propanone (acetone)67-64-1 04/28/15ND B5D2807

100000 ug/L 20000 82604-Methyl-2-pentanone (MIBK)108-10-1 04/28/15ND B5D2807

100000 ug/L 20000 8260Acrylonitrile107-13-1 04/28/15ND B5D2807

20000 ug/L 20000 8260Benzene71-43-2 04/28/15ND B5D2807

20000 ug/L 20000 8260Bromobenzene108-86-1 04/28/15ND B5D2807

20000 ug/L 20000 8260Bromochloromethane74-97-5 04/28/15ND B5D2807

20000 ug/L 20000 8260Bromodichloromethane75-27-4 04/28/15ND B5D2807

20000 ug/L 20000 8260Bromoform75-25-2 04/28/15ND B5D2807

100000 ug/L 20000 8260Bromomethane74-83-9 04/28/15ND B5D2807

20000 ug/L 20000 8260Carbon disulfide75-15-0 04/28/15ND B5D2807

20000 ug/L 20000 8260Carbon tetrachloride56-23-5 04/28/15ND B5D2807

20000 ug/L 20000 8260Chlorobenzene108-90-7 04/28/15ND B5D2807

100000 ug/L 20000 8260Chloroethane75-00-3 04/28/15ND B5D2807

20000 ug/L 20000 8260Chloroform67-66-3 04/28/15ND B5D2807

100000 ug/L 20000 8260Chloromethane74-87-3 04/28/15ND B5D2807

20000 ug/L 20000 8260cis-1,2-Dichloroethylene156-59-2 04/28/1531000 B5D2807

20000 ug/L 20000 8260cis-1,3-Dichloropropylene10061-01-5 04/28/15ND B5D2807

100000 ug/L 20000 8260Cyclohexane110-82-7 04/28/15ND B5D2807

20000 ug/L 20000 8260Dibromochloromethane124-48-1 04/28/15ND B5D2807

Page 9 of 16Page 9 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-03

RLCAS #

Client ID: PSW-2-0415

QC Batch

Organics-Volatiles

20000 ug/L 20000 8260Dibromomethane74-95-3 04/28/15ND B5D2807

100000 ug/L 20000 8260Dichlorodifluoromethane75-71-8 04/28/15ND B5D2807

100000 ug/L 20000 8260Diethyl ether60-29-7 04/28/15ND B5D2807

100000 ug/L 20000 8260Diisopropyl Ether108-20-3 04/28/15ND B5D2807

20000 ug/L 20000 8260Ethylbenzene100-41-4 04/28/15ND B5D2807

100000 ug/L 20000 8260Ethyltertiarybutylether637-92-3 04/28/15ND B5D2807

100000 ug/L 20000 8260Hexachloroethane67-72-1 04/28/15ND B5D2807

20000 ug/L 20000 8260Isopropylbenzene98-82-8 04/28/15ND B5D2807

40000 ug/L 20000 8260m & p - Xylene1330-20-7 04/28/15ND B5D2807

20000 ug/L 20000 8260Methyl iodide74-88-4 04/28/15ND B5D2807

100000 ug/L 20000 8260Methylene chloride75-09-2 04/28/15ND B5D2807

20000 ug/L 20000 8260Methyltertiarybutylether1634-04-4 04/28/15ND B5D2807

100000 Xug/L 20000 8260Naphthalene91-20-3 04/28/15ND B5D2807

20000 ug/L 20000 8260n-Butylbenzene104-51-8 04/28/15ND B5D2807

20000 ug/L 20000 8260n-Propylbenzene103-65-1 04/28/15ND B5D2807

20000 ug/L 20000 8260o-Xylene95-47-6 04/28/15ND B5D2807

20000 ug/L 20000 8260p-Isopropyl toluene99-87-6 04/28/15ND B5D2807

20000 ug/L 20000 8260sec-Butylbenzene135-98-8 04/28/15ND B5D2807

20000 ug/L 20000 8260Styrene100-42-5 04/28/15ND B5D2807

20000 ug/L 20000 8260tert-Butylbenzene98-06-6 04/28/15ND B5D2807

1000000 ug/L 20000 8260tertiary Butyl Alcohol75-65-0 04/28/15ND B5D2807

100000 ug/L 20000 8260tertiaryAmylmethylether994-05-8 04/28/15ND B5D2807

20000 ug/L 20000 8260Tetrachloroethylene127-18-4 04/28/15ND B5D2807

100000 ug/L 20000 8260Tetrahydrofuran109-99-9 04/28/15ND B5D2807

20000 ug/L 20000 8260Toluene108-88-3 04/28/15ND B5D2807

20000 ug/L 20000 8260trans-1,2-Dichloroethylene156-60-5 04/28/15ND B5D2807

20000 ug/L 20000 8260trans-1,3-Dichloropropylene10061-02-6 04/28/15ND B5D2807

100000 ug/L 20000 8260trans-1,4-Dichloro-2-butene110-57-6 04/28/15ND B5D2807

20000 ug/L 20000 8260Trichloroethylene79-01-6 04/28/151300000 B5D2807

20000 ug/L 20000 8260Trichlorofluoromethane75-69-4 04/28/15ND B5D2807

20000 ug/L 20000 8260Vinyl chloride75-01-4 04/28/15ND B5D2807

85-115100 %Surrogate: Bromofluorobenzene 826004/28/15 B5D2807

82.7-115104 %Surrogate: Dibromofluoromethane 826004/28/15 B5D2807

85-115102 %Surrogate: Toluene-d8 826004/28/15 B5D2807

Page 10 of 16Page 10 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-03

RLCAS #

Client ID: PSW-2-0415

QC Batch

Inorganics-General Chemistry

20 mg/L 1 310.2Alkalinity-Total 04/23/15320 B5D2306 umhos/cm 1 120.1Conductivity 04/22/151400 B5D2214

HpH Units 1 4500 H+ BpH 04/22/158.0 B5D2214

20 mg/L 1 2540 CTotal Dissolved SolidsTDS 04/24/15900 B5D2405

Inorganics-Metals

10 mg/L 10 6010/200.7Calcium, Dissolved7440-70-2 05/01/15130 B5D2401

46 mg/L 10 2340 BHardness - Calculated 05/01/15690 [CALC]

20 ug/L 1 6010/200.7Iron, Dissolved7439-89-6 05/01/1536 B5D2401

5.0 mg/L 10 6010/200.7Magnesium, Dissolved7439-95-4 05/01/1588 B5D2401

Page 11 of 16Page 11 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-04

RLCAS #

Client ID: 107SUMP-0415

QC Batch

Organics-Volatiles

1.0 ug/L 1 82601,1,1,2-Tetrachloroethane630-20-6 04/28/15ND B5D2807

1.0 ug/L 1 82601,1,1-Trichloroethane71-55-6 04/28/15ND B5D2807

1.0 ug/L 1 82601,1,2,2-Tetrachloroethane79-34-5 04/28/15ND B5D2807

1.0 ug/L 1 82601,1,2-Trichloroethane79-00-5 04/28/15ND B5D2807

1.0 ug/L 1 82601,1-Dichloroethane75-34-3 04/28/15ND B5D2807

1.0 ug/L 1 82601,1-Dichloroethylene75-35-4 04/28/15ND B5D2807

5.0 ug/L 1 82601,2,3-Trichlorobenzene87-61-6 04/28/15ND B5D2807

1.0 ug/L 1 82601,2,3-Trichloropropane96-18-4 04/28/15ND B5D2807

1.0 ug/L 1 82601,2,3-Trimethylbenzene526-73-8 04/28/15ND B5D2807

5.0 ug/L 1 82601,2,4-Trichlorobenzene120-82-1 04/28/15ND B5D2807

1.0 ug/L 1 82601,2,4-Trimethylbenzene95-63-6 04/28/15ND B5D2807

5.0 ug/L 1 82601,2-Dibromo-3-chloropropane96-12-8 04/28/15ND B5D2807

1.0 ug/L 1 82601,2-Dibromoethane106-93-4 04/28/15ND B5D2807

1.0 ug/L 1 82601,2-Dichlorobenzene95-50-1 04/28/15ND B5D2807

1.0 ug/L 1 82601,2-Dichloroethane107-06-2 04/28/15ND B5D2807

1.0 ug/L 1 82601,2-Dichloropropane78-87-5 04/28/15ND B5D2807

1.0 ug/L 1 82601,3,5-Trimethylbenzene108-67-8 04/28/15ND B5D2807

1.0 ug/L 1 82601,3-Dichlorobenzene541-73-1 04/28/15ND B5D2807

1.0 ug/L 1 82601,4-Dichlorobenzene106-46-7 04/28/15ND B5D2807

5.0 ug/L 1 82602-Butanone (MEK)78-93-3 04/28/15ND B5D2807

5.0 ug/L 1 82602-Hexanone591-78-6 04/28/15ND B5D2807

5.0 Xug/L 1 82602-Methylnaphthalene91-57-6 04/28/15ND B5D2807

20 ug/L 1 82602-Propanone (acetone)67-64-1 04/28/15ND B5D2807

5.0 ug/L 1 82604-Methyl-2-pentanone (MIBK)108-10-1 04/28/15ND B5D2807

5.0 ug/L 1 8260Acrylonitrile107-13-1 04/28/15ND B5D2807

1.0 ug/L 1 8260Benzene71-43-2 04/28/15ND B5D2807

1.0 ug/L 1 8260Bromobenzene108-86-1 04/28/15ND B5D2807

1.0 ug/L 1 8260Bromochloromethane74-97-5 04/28/15ND B5D2807

1.0 ug/L 1 8260Bromodichloromethane75-27-4 04/28/15ND B5D2807

1.0 ug/L 1 8260Bromoform75-25-2 04/28/15ND B5D2807

5.0 ug/L 1 8260Bromomethane74-83-9 04/28/15ND B5D2807

1.0 ug/L 1 8260Carbon disulfide75-15-0 04/28/15ND B5D2807

1.0 ug/L 1 8260Carbon tetrachloride56-23-5 04/28/15ND B5D2807

1.0 ug/L 1 8260Chlorobenzene108-90-7 04/28/15ND B5D2807

5.0 ug/L 1 8260Chloroethane75-00-3 04/28/15ND B5D2807

1.0 ug/L 1 8260Chloroform67-66-3 04/28/15ND B5D2807

5.0 ug/L 1 8260Chloromethane74-87-3 04/28/15ND B5D2807

1.0 ug/L 1 8260cis-1,2-Dichloroethylene156-59-2 04/28/155.9 B5D2807

1.0 ug/L 1 8260cis-1,3-Dichloropropylene10061-01-5 04/28/15ND B5D2807

5.0 ug/L 1 8260Cyclohexane110-82-7 04/28/15ND B5D2807

1.0 ug/L 1 8260Dibromochloromethane124-48-1 04/28/15ND B5D2807

Page 12 of 16Page 12 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-04

RLCAS #

Client ID: 107SUMP-0415

QC Batch

Organics-Volatiles

1.0 ug/L 1 8260Dibromomethane74-95-3 04/28/15ND B5D2807

5.0 ug/L 1 8260Dichlorodifluoromethane75-71-8 04/28/15ND B5D2807

5.0 ug/L 1 8260Diethyl ether60-29-7 04/28/15ND B5D2807

5.0 ug/L 1 8260Diisopropyl Ether108-20-3 04/28/15ND B5D2807

1.0 ug/L 1 8260Ethylbenzene100-41-4 04/28/15ND B5D2807

5.0 ug/L 1 8260Ethyltertiarybutylether637-92-3 04/28/15ND B5D2807

5.0 ug/L 1 8260Hexachloroethane67-72-1 04/28/15ND B5D2807

1.0 ug/L 1 8260Isopropylbenzene98-82-8 04/28/15ND B5D2807

2.0 ug/L 1 8260m & p - Xylene1330-20-7 04/28/15ND B5D2807

1.0 ug/L 1 8260Methyl iodide74-88-4 04/28/15ND B5D2807

5.0 ug/L 1 8260Methylene chloride75-09-2 04/28/15ND B5D2807

1.0 ug/L 1 8260Methyltertiarybutylether1634-04-4 04/28/15ND B5D2807

5.0 Xug/L 1 8260Naphthalene91-20-3 04/28/15ND B5D2807

1.0 ug/L 1 8260n-Butylbenzene104-51-8 04/28/15ND B5D2807

1.0 ug/L 1 8260n-Propylbenzene103-65-1 04/28/15ND B5D2807

1.0 ug/L 1 8260o-Xylene95-47-6 04/28/15ND B5D2807

1.0 ug/L 1 8260p-Isopropyl toluene99-87-6 04/28/15ND B5D2807

1.0 ug/L 1 8260sec-Butylbenzene135-98-8 04/28/15ND B5D2807

1.0 ug/L 1 8260Styrene100-42-5 04/28/15ND B5D2807

1.0 ug/L 1 8260tert-Butylbenzene98-06-6 04/28/15ND B5D2807

50 ug/L 1 8260tertiary Butyl Alcohol75-65-0 04/28/15ND B5D2807

5.0 ug/L 1 8260tertiaryAmylmethylether994-05-8 04/28/15ND B5D2807

1.0 ug/L 1 8260Tetrachloroethylene127-18-4 04/28/15ND B5D2807

5.0 ug/L 1 8260Tetrahydrofuran109-99-9 04/28/15ND B5D2807

1.0 ug/L 1 8260Toluene108-88-3 04/28/15ND B5D2807

1.0 ug/L 1 8260trans-1,2-Dichloroethylene156-60-5 04/28/15ND B5D2807

1.0 ug/L 1 8260trans-1,3-Dichloropropylene10061-02-6 04/28/15ND B5D2807

5.0 ug/L 1 8260trans-1,4-Dichloro-2-butene110-57-6 04/28/15ND B5D2807

1.0 ug/L 1 8260Trichloroethylene79-01-6 04/28/1547 B5D2807

1.0 ug/L 1 8260Trichlorofluoromethane75-69-4 04/28/15ND B5D2807

1.0 ug/L 1 8260Vinyl chloride75-01-4 04/28/15ND B5D2807

85-11599.0 %Surrogate: Bromofluorobenzene 826004/28/15 B5D2807

82.7-115104 %Surrogate: Dibromofluoromethane 826004/28/15 B5D2807

85-115101 %Surrogate: Toluene-d8 826004/28/15 B5D2807

Page 13 of 16Page 13 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-05

RLCAS #

Client ID: 108SUMP-0415

QC Batch

Organics-Volatiles

1.0 ug/L 1 82601,1,1,2-Tetrachloroethane630-20-6 04/28/15ND B5D2807

1.0 ug/L 1 82601,1,1-Trichloroethane71-55-6 04/28/15ND B5D2807

1.0 ug/L 1 82601,1,2,2-Tetrachloroethane79-34-5 04/28/15ND B5D2807

1.0 ug/L 1 82601,1,2-Trichloroethane79-00-5 04/28/15ND B5D2807

1.0 ug/L 1 82601,1-Dichloroethane75-34-3 04/28/15ND B5D2807

1.0 ug/L 1 82601,1-Dichloroethylene75-35-4 04/28/15ND B5D2807

5.0 ug/L 1 82601,2,3-Trichlorobenzene87-61-6 04/28/15ND B5D2807

1.0 ug/L 1 82601,2,3-Trichloropropane96-18-4 04/28/15ND B5D2807

1.0 ug/L 1 82601,2,3-Trimethylbenzene526-73-8 04/28/15ND B5D2807

5.0 ug/L 1 82601,2,4-Trichlorobenzene120-82-1 04/28/15ND B5D2807

1.0 ug/L 1 82601,2,4-Trimethylbenzene95-63-6 04/28/15ND B5D2807

5.0 ug/L 1 82601,2-Dibromo-3-chloropropane96-12-8 04/28/15ND B5D2807

1.0 ug/L 1 82601,2-Dibromoethane106-93-4 04/28/15ND B5D2807

1.0 ug/L 1 82601,2-Dichlorobenzene95-50-1 04/28/15ND B5D2807

1.0 ug/L 1 82601,2-Dichloroethane107-06-2 04/28/15ND B5D2807

1.0 ug/L 1 82601,2-Dichloropropane78-87-5 04/28/15ND B5D2807

1.0 ug/L 1 82601,3,5-Trimethylbenzene108-67-8 04/28/15ND B5D2807

1.0 ug/L 1 82601,3-Dichlorobenzene541-73-1 04/28/15ND B5D2807

1.0 ug/L 1 82601,4-Dichlorobenzene106-46-7 04/28/15ND B5D2807

5.0 ug/L 1 82602-Butanone (MEK)78-93-3 04/28/15ND B5D2807

5.0 ug/L 1 82602-Hexanone591-78-6 04/28/15ND B5D2807

5.0 Xug/L 1 82602-Methylnaphthalene91-57-6 04/28/15ND B5D2807

20 ug/L 1 82602-Propanone (acetone)67-64-1 04/28/15ND B5D2807

5.0 ug/L 1 82604-Methyl-2-pentanone (MIBK)108-10-1 04/28/15ND B5D2807

5.0 ug/L 1 8260Acrylonitrile107-13-1 04/28/15ND B5D2807

1.0 ug/L 1 8260Benzene71-43-2 04/28/15ND B5D2807

1.0 ug/L 1 8260Bromobenzene108-86-1 04/28/15ND B5D2807

1.0 ug/L 1 8260Bromochloromethane74-97-5 04/28/15ND B5D2807

1.0 ug/L 1 8260Bromodichloromethane75-27-4 04/28/15ND B5D2807

1.0 ug/L 1 8260Bromoform75-25-2 04/28/15ND B5D2807

5.0 ug/L 1 8260Bromomethane74-83-9 04/28/15ND B5D2807

1.0 ug/L 1 8260Carbon disulfide75-15-0 04/28/15ND B5D2807

1.0 ug/L 1 8260Carbon tetrachloride56-23-5 04/28/15ND B5D2807

1.0 ug/L 1 8260Chlorobenzene108-90-7 04/28/15ND B5D2807

5.0 ug/L 1 8260Chloroethane75-00-3 04/28/15ND B5D2807

1.0 ug/L 1 8260Chloroform67-66-3 04/28/15ND B5D2807

5.0 ug/L 1 8260Chloromethane74-87-3 04/28/15ND B5D2807

1.0 ug/L 1 8260cis-1,2-Dichloroethylene156-59-2 04/28/152.6 B5D2807

1.0 ug/L 1 8260cis-1,3-Dichloropropylene10061-01-5 04/28/15ND B5D2807

5.0 ug/L 1 8260Cyclohexane110-82-7 04/28/15ND B5D2807

1.0 ug/L 1 8260Dibromochloromethane124-48-1 04/28/15ND B5D2807

Page 14 of 16Page 14 of 16

TEL: (517) 335-9800

FAX: (517) 335-9600

MICHIGAN DEPARTMENT OF ENVIRONMENTAL QUALITY

ENVIRONMENTAL LABORATORY

ResultAnalyte

Analyzed

Date Method QualifierDilutionUnits

Lab ID: 1504159-05

RLCAS #

Client ID: 108SUMP-0415

QC Batch

Organics-Volatiles

1.0 ug/L 1 8260Dibromomethane74-95-3 04/28/15ND B5D2807

5.0 ug/L 1 8260Dichlorodifluoromethane75-71-8 04/28/15ND B5D2807

5.0 ug/L 1 8260Diethyl ether60-29-7 04/28/15ND B5D2807

5.0 ug/L 1 8260Diisopropyl Ether108-20-3 04/28/15ND B5D2807

1.0 ug/L 1 8260Ethylbenzene100-41-4 04/28/15ND B5D2807

5.0 ug/L 1 8260Ethyltertiarybutylether637-92-3 04/28/15ND B5D2807

5.0 ug/L 1 8260Hexachloroethane67-72-1 04/28/15ND B5D2807

1.0 ug/L 1 8260Isopropylbenzene98-82-8 04/28/15ND B5D2807

2.0 ug/L 1 8260m & p - Xylene1330-20-7 04/28/15ND B5D2807

1.0 ug/L 1 8260Methyl iodide74-88-4 04/28/15ND B5D2807

5.0 ug/L 1 8260Methylene chloride75-09-2 04/28/15ND B5D2807

1.0 ug/L 1 8260Methyltertiarybutylether1634-04-4 04/28/15ND B5D2807

5.0 Xug/L 1 8260Naphthalene91-20-3 04/28/15ND B5D2807

1.0 ug/L 1 8260n-Butylbenzene104-51-8 04/28/15ND B5D2807

1.0 ug/L 1 8260n-Propylbenzene103-65-1 04/28/15ND B5D2807

1.0 ug/L 1 8260o-Xylene95-47-6 04/28/15ND B5D2807

1.0 ug/L 1 8260p-Isopropyl toluene99-87-6 04/28/15ND B5D2807

1.0 ug/L 1 8260sec-Butylbenzene135-98-8 04/28/15ND B5D2807

1.0 ug/L 1 8260Styrene100-42-5 04/28/15ND B5D2807

1.0 ug/L 1 8260tert-Butylbenzene98-06-6 04/28/15ND B5D2807

50 ug/L 1 8260tertiary Butyl Alcohol75-65-0 04/28/15ND B5D2807

5.0 ug/L 1 8260tertiaryAmylmethylether994-05-8 04/28/15ND B5D2807

1.0 ug/L 1 8260Tetrachloroethylene127-18-4 04/28/15ND B5D2807

5.0 ug/L 1 8260Tetrahydrofuran109-99-9 04/28/15ND B5D2807

1.0 ug/L 1 8260Toluene108-88-3 04/28/15ND B5D2807

1.0 ug/L 1 8260trans-1,2-Dichloroethylene156-60-5 04/28/15ND B5D2807

1.0 ug/L 1 8260trans-1,3-Dichloropropylene10061-02-6 04/28/15ND B5D2807

5.0 ug/L 1 8260trans-1,4-Dichloro-2-butene110-57-6 04/28/15ND B5D2807

1.0 ug/L 1 8260Trichloroethylene79-01-6 04/28/15ND B5D2807

1.0 ug/L 1 8260Trichlorofluoromethane75-69-4 04/28/15ND B5D2807

1.0 ug/L 1 8260Vinyl chloride75-01-4 04/28/15ND B5D2807

85-115101 %Surrogate: Bromofluorobenzene 826004/28/15 B5D2807

82.7-115107 %Surrogate: Dibromofluoromethane 826004/28/15 B5D2807

85-115101 %Surrogate: Toluene-d8 826004/28/15 B5D2807

Page 15 of 16Page 15 of 16

Project information Coordinate System Name: F:\Projects\2015\H2015_101\TBC\s_haven.vceName: US State Plane 1983 Size: 1 MB Datum: NAD 1983 (Conus) Modified: 10/25/2015 9:39:19 AM (UTC:‐4) Zone: Michigan South 2113 Time zone: Eastern Standard Time Geoid: GEOID12A (Conus) Reference number: Vertical datum:

Description: 125 Elkenburg St Topo Survey of Treatment Area Conducted October 24, 2015 Point List point id Northing Easting Elevation Feature Code Combined Scode description

1b 331311.8 12606732 626.09 cp sir 0.9999189 control point 10 331314.3 12606715 626.21 GS EM BPATH 0.9999189 west edge of bike path 11 331312.4 12606677 625.81 GS 0.9999189 ground shot 12 331319.5 12606678 625.75 MW 0.9999189 monitoring well

13 331309.5 12606652 627.44 GS 0.9999188

14 331309.5 12606652 627.44 GS 0.9999188

15 331305.1 12606599 627.53 GS 0.9999188

16 331301 12606515 627.58 GS 0.9999188

17 331301.9 12606503 623.55 gs em 0.999919 east edge of parking lot 18 331329 12606498 623.08 MST OG CTR 0.999919 storm‐open grate center of lid

19 331329.3 12606500 623.37 GS 0.999919

20 331360.1 12606498 624.93 BM J EJIW 1.0 AG 0.9999189 bench mark‐bolt on flange‐under j in ejiw‐1 foot above grade

21 331590.2 12606551 623.09 MST OG CTR 0.9999189

22 331536.4 12606572 625.25 GS 0.9999188

23 331488.4 12606591 623.68 MST BHIVE CTR 0.9999189 storm domed lid open grate center or high point 24 331488.4 12606591 623.65 MST BHIVE CTR 0.9999189 storm domed lid open grate center or high point 25 331488.4 12606591 623.69 MST BHIVE CTR 0.9999189 storm domed lid open grate center or high point

26 331489.3 12606591 623.42 GS RIM 0.9999189

27 331594.5 12606501 623.48 MST OG CTR 0.9999189

28 331594.4 12606501 623.49 MST OG CTR 0.9999189

29 331628.8 12606257 623.53 CP BW BW 0.9999189

30 331282.6 12606443 622.27 MST OG SQ CTR 0.9999191 storm open grate square center

31 331281.7 12606444 622.29 CP RIM SE X 0.9999191

32 331327.7 12606506 624.08 GS 0.999919

33 331329.2 12606519 627.79 GS 0.9999188

34 331329.2 12606525 627.23 GS 0.9999188

35 331332.9 12606614 627.22 GS 0.9999188

36 331331.7 12606657 626.78 GS 0.9999188

37 331331.7 12606677 625.6 GS 0.9999189

38 331336.5 12606711 626.14 GS EM 0.9999189 west edge of bike path 39 331394.9 12606702 625.69 GS EM 0.9999189 west edge of bike path

40 331386 12606679 625.47 MW 0.9999189

41 331387.5 12606655 626.55 GS 0.9999188

42 331393 12606597 625.46 GS 0.9999189

43 331396.8 12606579 625.24 MW 0.9999189

44 331394.2 12606524 624.83 GS 0.9999189

45 331393.1 12606499 623.64 GS EG 0.999919

46 331438.3 12606536 623.38 GS 0.999919

47 331446.5 12606575 623.56 GS 0.999919

48 331450.5 12606619 624.6 GS 0.9999189

49 331454.1 12606655 625.07 GS 0.9999189

50 331449.8 12606677 625.34 GS 0.9999189

51 331484.7 12606632 624.85 GS 0.9999189

52 331300.8 12606645 627.77 GS 0.9999188

53 331300.5 12606619 627.69 GS 0.9999188

54 331283 12606603 627.64 GS 0.9999188

55 331283 12606544 627.64 GS 0.9999188

56 331275 12606524 627.69 GS SC CJ 0.9999188 n edge of concrete at control joint

57 331282.6 12606511 627.4 GS 0.9999188

58 331282.5 12606502 623.46 GS EM 0.999919 east edge of parking lot

59 331360.1 12606498 625.02 CHK BM 0.9999189

60 331281.7 12606444 622.22 CHK CP SE MST 0.9999191

61 331421.7 12606699 625.31 GS EM 0.9999189

62 331492.3 12606699 624.85 GS EM 0.9999189 west edge of bike path 63 331490.4 12606719 622.23 IE E 18IN CONC 0.999919 invert elevation‐pipe runs west 64 331457.4 12606698 625.14 GS EM 0.9999189 west edge of bike path 100 331281.7 12606444 622.29 cp mst sex 0.9999191 102 331466.2 12606522 623.08 mst og ctr 0.999919 103 331466.3 12606521 623.16 gs 0.999919 104 331470.3 12606502 623.87 gs 0.9999189 105 331485.4 12606505 624.14 gs 0.9999189 106 331485.1 12606539 623.6 gs 0.9999189 107 331484.6 12606599 624.24 gs 0.9999189 108 331484.8 12606636 624.94 gs 0.9999189 109 331319.4 12606678 625.84 mw 0.9999189 monitoring well 110 331341.3 12606694 625.76 gs 0.9999189 111 331342.6 12606694 625.76 pp 0.9999189 112 331301 12606669 626.12 gs 0.9999189 113 331302 12606659 627.35 gs 0.9999188 114 331288 12606656 627.92 gs 0.9999188 115 331288.7 12606619 627.8 gs 0.9999188 116 331273.7 12606617 627.83 gs sc 0.9999188 117 331274.4 12606572 627.83 gs sc 0.9999188 118 331275.1 12606524 627.77 gs sc 0.9999188 119 331275.4 12606508 627.54 gs sc 0.9999188 120 331281.7 12606444 622.21 mst og ctr 0.9999191 122 331359.7 12606498 623.63 gs 0.999919 123 331360.2 12606498 624.91 chk bm 0.9999189 124 331360.4 12606498 625.92 top bolt +/‐ 0.9999189 125 331366 12606468 623.92 msa ctr 0.999919 sanitary sewer lid center

A ut h o r:

r ku sh m a n

P :\C u rr en t\

D E

\E n gi ne er in g

\L e m ke _S ur ve yi n g_ D at a.

m xd

Prepared for:

CLIENT NAME

Street Address, City, State Zip Prepared by:

GLOBAL REMEDIATION TECHNOLOGIES, INC.

1102 Cass Street - Traverse City, Michigan 49684

FIGURE TITLE

SITE NAME

STREET ADDRESS

CITY, STATE

Created: Month 20## / Scale: 1" = ##'

I Source of Aerial Imagery: Google Earth 2013

Elkenburg St

Aylworth Ct

St Jo se ph

58 57

55 54

53 52

494847

45 44 43

41 40

373635343332

17 16 15

11 10 1b

117 116

115 114

111110

108107

106105

Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and the GIS User Community

Prepared for:

CLIENT NAME

Street Address, City, State ZipSource of Aerial Imagery: Google Earth 2013 FI

Source of Aerial Imagery: ESRI Projection: NAD83 State Plane Zone 2113 (Intl Feet)

Prepared by:

GLOBAL REMEDIATION TECHNOLOGIES, INC.

1102 Cass Street - Traverse City, Michigan 49684

I 0 60 12030

Feet

RECENT SURVEYED DATA POINTS -

LEMKE SURVEYING

BELGRAVIA THERMAL REMEDIATION PROJECT

SOUTH HAVEN, MICHIGAN

Created: October 2015 / Scale: as noted

Prepared for:

MICHIGAN DEPT. OF ENVIRONMENTAL QUALITY

LEGEND

Lemke Surveyed Data Points

VanBuren County

Phase II ESA

PHASE II ENVIRONMENTAL SITE ASSESSMENT

229 ELKENBURG STREET, SOUTH HAVEN, MICHIGAN March 19, 2015

1.0 Summary

Villa Environmental Consultants, Inc. contracted by the City of South Haven to conduct a Phase II

Environmental Site Assessment (ESA) at 229 Elkenburg Street, South Haven, Michigan which is known as the Overton Building. This investigation was completed in response to the recognized environmental conditions outlined in the June 10, 2014 Phase I ESA report completed by Villa

Environmental Consultants, Inc.

The Phase I ESA found eight (8) Recognized Environmental Conditions (RECs) that might impact the subject property.

1. There was historical use of stains, paints, thinners, etc. at this site. These chemicals contain

Volatile and Semi-volatile organic compounds and may have contributed to a release.

2. A 20,000 gallon oil tank which leaked and was removed between 1965 and 1985. The removal of this underground storage tank was completed to the standards of that time period, but contamination may still exist and the levels may not meet the current cleanup criteria.

3. Historical use of a railroad spur on the property may have contaminated the site with heavy metals, creosote, or polynuclear aromatic hydrocarbons (PNA)s.

4. There was a coal bunker located within the building which may have contaminated the site with PNAs.

5. A foundry was located on the northern section of the subject property which may have lead to site contamination from heavy metals through distribution of foundry sand.

6. Based on interviews there was a historical filling station adjacent to the southeast of the subject property. Due to the proximity to the subject property this is a REC.

7. Belgravia is a state equivalent to CERCLIS site and is adjacent to the west portion of the subject property. Due to the proximity to the subject property this is a REC.

8. There are currently approximately 25 to 30 drums located within the building that are unlabeled and contain potentially hazardous or petroleum chemicals. These containers of unknown chemicals and their condition have the potential to cause a release.

To address the RECs identified in the Phase I ESA, a Phase II ESA was initiated which involved a subsurface investigation to determine if historic use of the subject property caused contamination that would need to be addressed during site development. This report summarizes the findings of this investigation.

A Site Location Map and Sampling Location Map are included in Appendix A.

2.0 Background Information

The City of South Haven (the City) is in the process of obtaining ownership of the subject property through tax foreclosure. The original Phase I ESA, a National Emissions Standard for Hazardous Air

Pollutants (asbestos NESHAP) inspection, and this Phase II ESA have been initiated to develop a plan for removing the existing building and redeveloping the site.

VILLA ENVIRONMENTAL CONSULTANTS, INC.

PROJECT #13-373-02 PAGE 1

Prior to tax foreclosure, control of the Overton Building was taken by the City to protect its residents.

The City secured the doors and installed perimeter fencing around the Overton Building to restrict access. The building is currently condemned and is dangerous to human health and the environment because of the failing roof and walls, deteriorating asbestos-containing material (ACM), and hazardous materials contained in 55-gallon steel drums throughout the building. The building is in very poor condition and is expected to be demolished.

3.0 Subsurface Investigation

Villa Environmental Consultants, Inc. contracted with Geoserve, Inc. of Woodstock, Illinois to advance soil borings at the site. On February 9 and 10, 2015, soil borings were advanced utilizing a track-mounted, Geoprobe 6620 DT throughout the interior and exterior of the Overton Building. A total of twenty-four (24) soil borings were advanced during this investigation, generally ranging from eight (8) to sixteen (16) feet below ground surface (bgs), with the depth of each boring based on field observations.

3.1 Geology

Fill material was encountered directly below the building slab and near the ground surface surrounding the Overton Building. A black slag material was noted underneath the north portion of the building and the current location of the rail spur along the west side of the building, which was encountered approximately ten inches bgs. The slag material is poorly graded and is a mix of silt to course sand.

A fine, well graded tan silty sand was noted underneath the southern half of the Overton Building where the original building was constructed. The tan sand is likely native soil and was encountered throughout the property.

Fill material and the building slab is underlain by native sand and clay. The clay that was encountered, was generally tan, moist and medium to hard in stiffness. Depth to clay ranged from directly below the building slab to 7.3' bgs. The depth to the bottom of the clay layer was not determined during this investigation. During the drilling operation, it was noted that the depth to groundwater ranged from

4 feet to 6 feet bgs. When no water bearing sand was present, depth to groundwater was 7 feet to 9 feet bgs. Based on the close proximity of this site to Lake Michigan (approximately 1,600 feet west of the site), groundwater likely flows west toward the lake.

3.2 Laboratory Analysis

Twenty (20) soil samples were collected for laboratory analysis during the subsurface investigation.

Samples were collected at different depths based on field observations and the groundwater level.

Field observations utilized were visual examination, olfactory observations, and the use of field instruments (a photo ionization detector) to determine the necessary sample analysis. The samples were analyzed for PNAs, unleaded gasoline parameters, and/or total metals based on observations.

In total, six (6) samples were analyzed for PNAs, three (3) samples were analyzed for unleaded gasoline parameters, and 20 samples were analyzed for total metals. Detailed sample results are outlined in Section 3.3. A complete laboratory report is included in the appendix of this report.

PROJECT #13-373-02 PAGE 2

3.3 Sample Methodology

Samples were preserved in appropriate jars, placed into a cooler with ice, and chain of custody procedures were initiated. The samples were then shipped via a laboratory courier to ALS

Environmental Laboratory (ALS), located in Holland, Michigan. As previously explained, sample analysis was based on observations, historic use of the property, and historic use of nearby properties.

Samples were analyzed for:

C PNAs by Environmental Protection Agency (EPA) Method 8270, C Unleaded gasoline parameters, which are part of Volatile Organic Compounds

(VOCs), by EPA Method 8260B, and/or

C Michigan 10 Metals, which is a list of heavy metals, analyzed using EPA Method

6020A.

3.4 Sample Results

Of the six (6) samples analyzed for PNAs, one sample was reported to exceed Michigan Department of Environmental Quality (MDEQ) residential cleanup criteria:

• Sample SB-8, located the shipping and receiving area at the northeast corner of the building, was reported to have levels of: benzo(a)pyrene, benzo(b)fluoranthene, and dibenzo(a,h)anthracene above MDEQ residential cleanup criteria.

No unleaded gasoline constituents were identified above applicable residential criteria. Seven of the

20 samples analyzed for Michigan 10 Metals were reported to have results exceeding applicable criteria:

• Sample locations: SB-8, SB-14, SB-15, SB-16, SB-17, SB-19, and SB-22 were reported to have arsenic concentrations above residential drinking water protection criteria. Samples: SB-14, SB-15, SB-16 and SB-22 were also reported to exceed direct contact criteria.

• SB-22 was also reported to have levels of cadmium that exceed drinking water protection criteria.

Based on the levels of soils identified above and according to MDEQ Part 201 Section 324.20101, the site is considered a facility. Contamination at the site is likely a consequence of using foundry sand and/or slag material as fill during the construction of the building additions. The original building, which is the production area near the south property line, did not exhibit contamination in analytical results or field observations.

4.0 Environmental Due Diligence

Since the City is a non-liable party, no further investigation is required at this time. However, environmental due diligence is required when owning and/or operating a facility. The following sections identify the owner/operator responsibilities. These recommendations are based on the subject property being redeveloped (for example) into a condominium and/or apartment complex following demolition of the existing structure.

PROJECT #13-373-02 PAGE 3

4.1 Due Care Plan

Based on the contaminates that exceed MDEQ Residential Cleanup Criteria outlined in Section 3.4, the site is considered a facility. The MDEQ does not require that their offices be notified of the presence of contamination in the soils because no formal release occurred at this site. The main focus of the MDEQ law regarding a facility is to:

1. Undertake measures as necessary to prevent exacerbation.

2. Undertake steps to mitigate exposure of unnecessary risks to human health.

Exacerbation is not a concern because no waste is being generated at the building. However, exacerbation could occur if materials are mishandled during site redevelopment. A due care plan is required for the site and will outline steps being taken to mitigate the risk of exposure and exacerbation during demolition and construction activities, and to protect future residents of a potential apartment and/or condominium development.

Villa Environmental Consultants, Inc. understands that the site is expected to be added to the City’s brownfield program. Including the site in the current brownfield authority means that the due care plan will likely be submitted to the MDEQ for comments and approval.

4.2 Baseline Environmental Assessment (BEA)

There is no transfer of liability to a government entity that seizes property through tax foreclosure, based on MDEQ law. However, the subject property is being included in the City’s brownfield program so a BEA must be completed and submitted to the MDEQ within 6 months of ownership to document the facility status of the site. It is likely that the City will want to submit the BEA sooner, based on the development activities expected to begin this year. A BEA establishes environmental conditions when a new owner or operator gains control of a site. The BEA documents site conditions to determine liability of each owner and/or operator.

4.3 Waste Characterization

During site investigation activities, several drums were opened by our subcontractor, Liquid Industrial of Grand Rapids, Michigan to characterize contents for disposal. The material inside the drums was frozen and unable to be sampled during this investigation. When warmer weather persists (likely in April 2015) and the drums are given time to thaw, the materials should be sampled to determine and plan proper disposal of the drum contents.

5.0 Conclusions

The following is a summary of the key conclusions identified from this investigation:

• The site is a facility based on concentrations of arsenic, cadmium, benzo(a)pyrene, benzo(b)fluoranthene, and dibenzo(a,h)anthracene.

• Within 6 months of becoming the owner or operator of the site, the City must submit a BEA to the MDEQ to document the facility status. This will also make the site eligible for brownfield redevelopment financing. More information is included in

PROJECT…

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