SDS_-_PHOS-CHEK®_3%_AFFF_Milspec.pdf

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Attached to
Aircraft Rescue and Fire Fighting (ARFF) F3 Foam Transition
Solicitation number
26-0082MC
Issued by
Lee County, Fort Lauderdale City, Florida

About this file

This is a Safety Data Sheet (SDS) for PHOS-CHEK 3% AFFF Milspec, a fire extinguishing foam product manufactured by Perimeter Solutions LP and applicable to the Lee County Port Authority's Aircraft Rescue and Fire Fighting (ARFF) foam transition project in Florida. The document provides comprehensive hazard and safety information for the aqueous film-forming foam (AFFF) concentrate that the port authority is transitioning away from in favor of synthetic fluorine-free foam (SFFF). PHOS-CHEK 3% AFFF Milspec is classified as a liquid mixture intended for professional use only as a fire extinguisher, with a primary hazard of serious eye irritation (GHS Classification Eye Irritant 2A). The product contains diethylene glycol monobutyl ether (10-30%), ethyl alcohol (1-5%), and D-Glucopyranose oligomeric decyl octyl glycosides (1-5%), with additional chemical components withheld as trade secrets.

The SDS specifies exposure control parameters, including ACGIH TWA limits of 10 ppm for diethylene glycol monobutyl ether and 1000 ppm STEL for ethyl alcohol, with OSHA PEL and NIOSH REL of 1900 mg/m³ or 1000 ppm for ethyl alcohol. The product has a pH of 7.6-8.6, density of 1002-1042 kg/m³, flash point greater than 199.4°F, and is non-flammable with low acute toxicity (LD50 oral rat 5660 mg/kg). First-aid measures include rinsing eyes cautiously with water for several minutes and obtaining medical attention if irritation persists. The product may cause long-term adverse effects in the aquatic environment and is listed on the EPA TSCA inventory with certain component exceptions. Emergency contact information is provided through CHEMTREC (800-424-9300) and Perimeter Solutions customer service (1-800-682-3626), with proper disposal required in accordance with local and national regulations.

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PHOS-CHEK® 3% AFFF Milspec J mF Quality Products. Exceptional Response D

Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

Date of issue 07/24/2019 Revision date 07/24/2019 Version 10

SECTION 1: Identification

1.1. Identification

Product form Mixture Product name PHOS-CHEK® 3% AFFF Milspec

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Fire extinguisher

For professional use only

1.3. Details of the supplier of the safety data sheet

Manufacturer Perimeter Solutions LP, Solberg 1520 Brookfield Ave.

Green Bay, Wl 54313 T 1-920-593-9445

Perimeter Solutions 10667 Jersey Blvd.

Rancho Cucamonga CA, 91730 T. 1-800-682-3626

Perimeter Solutions Canada Ltd., 3060 Airport Rd., Kamloops B.C., V2B 7X2 T. 1-250-554-3530

1.4. Emergency telephone number

Emergency number CHEMTREC 800-424-9300, CANUTEC 613-996-6666 (transport only)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS classification Eyelrnt. 2A H319

2.2. Label elements

GHS labelling

Hazard pictograms (GHS)

GHS07

Signal word (GHS) Hazard statements (GHS) Precautionary statements (GHS)

Warning H319 - Causes serious eye irritation.

P264 - Wash hands thoroughly after handling.

P280 - Wear eye protection, face protection, protective clothing, protective gloves P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing.

P337+P313 - If eye irritation persists. Get medical advice/attention.

2.3. Other hazards

No additional information available

2.4. Unknown acute toxicity

Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable

3.2. Mixtures

'Chemical name, CAS number and/or exact concentration have been withheld as a trade secret

Name Product identifier % Diethylene glycol monobutyl ether (CAS-No) 112-34-5 10-30 Ethyl alcohol (CAS-No) 64-17-5 1-5 D-Glucopyranose, oligomeric, decyl octyl glycosides (CAS-No) 68515-73-1 1-5

07/24/2019 EN (English) Page 1

Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910 1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

SECTION 4: First-aid measures

4.1. Description of first aid measures

First-aid measures after inhalation If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell.

First-aid measures after skin contact If skin irritation occurs Wash skin with plenty of water. Obtain medical attention if irritation persists.

First-aid measures after eye contact IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists Get medical advice/attention.

First-aid measures after ingestion Do not induce vomiting without medical advice Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell

4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation May cause irritation to the respiratory tract Symptoms/effects after skin contact May cause skin irritation Repeated exposure may cause skin dryness or cracking Symptoms/effects after eye contact Causes serious eye irritation Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva Symptoms/effects after ingestion May be harmful if swallowed May cause gastrointestinal irritation, nausea, vomiting and diarrhea

4.3. Indication of any immediate medical attention and special treatment needed Symptoms may be delayed In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media Use extinguishing media appropriate for surrounding fire. Polyvalent powder extinguishers (ABC powder).

Unsuitable extinguishing media Tap water

5.2. Special hazards arising from the substance or mixture

Fire hazard Products of combustion may include, and are not limited to oxides of carbon, organic compounds.

5.3. Advice for firefighters

Firefighting instructions Cool closed containers exposed to fire with water spray Protection during firefighting Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA).

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures Use personal protection recommended in Section 8 Isolate the hazard area and deny entry to unnecessary and unprotected personnel

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Prevent entry to sewers and public waters

6.3. Methods and material for containment and cleaning up

For containment Absorb and/or contain spill with inert material (sand, vermiculite or other appropriate material), then place in suitable container. Do not flush into surface water or sewer system. Wear recommended personal protective equipment

Methods for cleaning up Sweep or shovel spills into appropriate container for disposal

6.4. Reference to other sections

For further information refer to section 8 "Exposure controls/personal protection"

07/24/2019 EN (English) 2/6

According to the Hazard Communication Standard (CFR29 1910 1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes Avoid breathing dust/fume/gas/mist/vapours/spray Do not swallow Handle and open container with care When using do not eat drink or smoke Ensure adequate ventilation

Hygiene measures Wash contaminated clothing before reuse Always wash hands after handling the product

7.2. Conditions for safe storage, including any incompatibilities Storage conditions Keep out of the reach of children Keep container tightly closed

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Diethylene glycol monobutyl ether (112-34-5) ACGIH ACGIH TWA (ppm) 10 ppm (inhalable fraction and vapor)

D-Glucopyranose, oligomeric, decyl octyl glycosides (68515-73-1) Not applicable

Ethyl alcohol (64-17-5) ACGIH ACGIH STEL (ppm) 1000 ppm

OSHA OSHA PEL (TWA) (mg/m3) 1900 mg/m3

OSHA OSHA PEL (TWA) (ppm) 1000 ppm

IDLH US IDLH (ppm) 3300 ppm (10% LEL)

NIOSH NIOSH REL (TWA) (mg/m3) 1900 mg/m3

NIOSH NIOSH REL (TWA) (ppm) 1000 ppm

8.2. Exposure controls

Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection

Environmental exposure controls Other information

Ensure good ventilation of the work station Wear suitable gloves Wear eye/face protection Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator Avoid release to the environment Handle in accordance with good industrial hygiene and safety procedures Do not eat, drink or smoke when using this product

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state Appearance Colour Odour Odour threshold pH Melting point Freezing point Boiling point Flash point Relative evaporation rate (butylacetate=1) Relative evaporation rate (ether=1) Flammability (solid, gas) Vapour pressure Relative vapour density at 20 °C

Liquid Transparent yellowish Characteristic No data available 76-86 No data available No data available No data available > 199 4 °F Non flammable No data available No data available Not flammable No data available No data available

07/24/2019 EN (English) 3/6

According to the Hazard Communication Standard (CFR29 1910 1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

9.2. Other information

Relative density Density Solubility Partition coefficient n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity dynamic Explosive limits

No data available 1002 - 1042 kg/m3 (@ 68 F) Material highly soluble in water No data available No data available No data available No data available 3 cP @ 68 °F Lower explosive limit (LEL) No data available Upper explosive limit (UEL) No data available

Explosive properties Oxidising properties

No data available No data available

Refractive index 1 367

SECTION 10: Stability and reactivity

10.1. Reactivity

No dangerous reactions known under normal conditions of use

10.2. Chemical stability

Stable under normal conditions

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use

10.4. Conditions to avoid

Heat Sunlight Incompatible materials

10.5. Incompatible materials

Strong acids Alkalis Strong bases

10.6. Hazardous decomposition products

May include, and are not limited to oxides of carbon, organic compounds

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) Not classified Acute toxicity (dermal) Not classified Acute toxicity (inhalation) Not classified

Diethylene glycol monobutyl ether (112-34-5) LD50 oral rat 5660 mg/kg LD50 dermal rabbit 2700 mg/kg ATE CA (oral) 5660 mg/kg bodyweight ATE CA (Dermal) 2700 mg/kg bodyweight

Skin corrosion/irritation

Serious eye damage/irntation

Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity

Not classified pH 7 6-86 Causes serious eye irritation pH 7 6-86 Not classified Not classified Not classified

Ethyl alcohol (64-17-5) IARC group 1 - Carcinogenic to humans

Reproductive toxicity Not classified

STOT-single exposure Not classified

STOT-repeated exposure Not classified

07/24/2019 EN (English) 4/6

According to the Hazard Communication Standard (CFR29 1910 1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

Aspiration hazard Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact

Symptoms/effects after ingestion

Other information

Not classified May cause irritation to the respiratory tract May cause skin irritation Repeated exposure may cause skin dryness or cracking.

Causes serious eye irritation Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva May be harmful if swallowed May cause gastrointestinal irritation, nausea, vomiting and diarrhea Likely routes of exposure ingestion, inhalation, skin and eye.

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general May cause long-term adverse effects in the aquatic environment

12.2. Persistence and degradability

PHOS-CHEK® 3% AFFF Milspec Persistence and degradability | Not established

12.3. Bioaccumulative potential

PHOS-CHEK® 3% AFFF Milspec Partition coefficient n-octanol/water Not applicable Bioaccumulative potential Not established

12.4. Mobility in soil

No additional information available

12.5. Other adverse effects

Other information No other effects known

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product/Packaging disposal recommendations Dispose in a safe manner in accordance with local/national regulations.

SECTION 14: Transport information Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG) In accordance with DOT/TDG Not applicable

SECTION 15: Regulatory information

15.1. Federal regulations

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (T5CA) inventory except for

[ Alcohols, C9-11, branched and linear, ethoxylated, sulfates, sodium salts | CAS-No 160901-28-0

All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic Substances List) inventories except for

| Alcohols, C9-11, branched and linear, ethoxylated sulfates, sodium salts | CAS-No 160901-28-0

15.2. International regulations

No additional information available

15.3. US State regulations

A WARNING: This product can expose you to Ethylene glycol, which is known to the State of California to cause birth defects or other reproductive harm For more information go to www P65Warnings ca gov

SECTION 16: Other information Revision date Other information Prepared by

07/24/2019 None Nexreg Compliance Inc www Nexreq com

07/24/2019 EN (English) 5/6

According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

NFPA health hazard : 2 NFPA fire hazard : 0 NFPA reactivity : 0

Hazard Rating Health Flammability Physical

2 Moderate Hazard 0 Minimal Hazard 0 Minimal Hazard

SDS HazCom 2012 - WHMIS 2015 (NexReg)

Disclaimer We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind The information contained in this document applies to this specific matenal as supplied It may not be valid for this matenal if it is used in combination with any other matenals It is the user's responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use

07/24/2019 EN (English) 6/6

A BSSES- PHOS-CHEK® 3% AFFF Milspec △

According to the Hazard Communication Standard (CFR29 1910 1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 Date of issue 07/24/2019 Revision date 07/24/2019 Version 10

SECTION 1: Identification

1.1. Identification

Product form Mixture Product name PHOS-CHEK® 3% AFFF Milspec

1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Fire extinguisher

For professional use only

1.3. Details of the supplier of the safety data sheet

Manufacturer Perimeter Solutions LP, Solberg 1520 Brookfield Ave.

Green Bay, Wl 54313 T. 1-920-593-9445

Perimeter Solutions 10667 Jersey Blvd Rancho Cucamonga CA, 91730 T 1-800-682-3626

Perimeter Solutions Canada Ltd 3060 Airport Rd , Kamloops B C , V2B 7X2 T 1-250-554-3530

1.4. Emergency telephone number

Emergency number CHEMTREC 800-424-9300, CANUTEC 613-996-6666 (transport only)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS classification Eye I mt. 2A H319

2.2. Label elements

GHS labelling

Hazard pictograms (GHS)

GHS07

Signal word (GHS) Hazard statements (GHS) Precautionary statements (GHS)

Warning H319 - Causes serious eye irritation.

P264 - Wash hands thoroughly after handling P280 - Wear eye protection, face protection, protective clothing, protective gloves.

P305+P351+P338 - IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing.

P337+P313 - If eye irritation persists Get medical advice/attention.

2.3. Other hazards

No additional information available

2.4. Unknown acute toxicity

Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable

3.2. Mixtures

Name Product identifier % Diethylene glycol monobutyl ether (CAS-No) 112-34-5 10-30 Ethyl alcohol (CAS-No) 64-17-5 1-5 D-Glucopyranose oligomeric, decyl octyl glycosides (CAS-No) 68515-73-1 1-5

‘Chemical name, CAS number and/or exact concentration have been withheld as a trade secret

07/24/2019 EN (English) Page 1

According to the Hazard Communication Standard (CFR29 1910 1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

SECTION 4: First-aid measures

4.1. Description of first aid measures

First-aid measures after inhalation

First-aid measures after skin contact

First-aid measures after eye contact

First-aid measures after ingestion

If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing Get medical advice/attention if you feel unwell If skin irritation occurs Wash skin with plenty of water Obtain medical attention if irritation persists IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing If eye irritation persists Get medical advice/attention Do not induce vomiting without medical advice Never give anything by mouth to an unconscious person Get medical advice/attention if you feel unwell

4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation May cause irritation to the respiratory tract Symptoms/effects after skin contact May cause skin irritation Repeated exposure may cause skin dryness or cracking Symptoms/effects after eye contact Causes serious eye irritation Symptoms may include discomfort or pain excess blinking and tear production with marked redness and swelling of the conjunctiva Symptoms/effects after ingestion May be harmful if swallowed May cause gastrointestinal irritation, nausea, vomiting and diarrhea

4.3. Indication of any immediate medical attention and special treatment needed Symptoms may be delayed In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible)

(SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media Use extinguishing media appropriate for surrounding fire Polyvalent powder extinguishers (ABC powder)

Unsuitable extinguishing media Tap water

5.2. Special hazards arising from the substance or mixture

Fire hazard Products of combustion may include, and are not limited to oxides of carbon, organic compounds

5.3. Advice for firefighters

Firefighting instructions Cool closed containers exposed to fire with water spray Protection during firefighting Keep upwind of fire Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA)

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures Use personal protection recommended in Section 8 Isolate the hazard area and deny entry to unnecessary and unprotected personnel

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders

No additional information available

6.2. Environmental precautions

Prevent entry to sewers and public waters

6.3. Methods and material for containment and cleaning up

For containment Absorb and/or contain spill with inert material (sand, vermiculite or other appropriate material), then place in suitable container Do not flush into surface water or sewer system Wear recommended personal protective equipment

Methods for cleaning up Sweep or shovel spills into appropriate container for disposal

6.4. Reference to other sections

For further information refer to section 8 "Exposure controls/personal protection"

07/24/2019 EN (English) 2/6

According to the Hazard Communication Standard (CFR29 1910 1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling Avoid contact with skin and eyes Avoid breathing dust/fume/gas/mist/vapours/spray. Do not swallow Handle and open container with care. When using do not eat, drink or smoke Ensure adequate ventilation

Hygiene measures Wash contaminated clothing before reuse Always wash hands after handling the product

7.2. Conditions for safe storage, including any incompatibilities Storage conditions Keep out of the reach of children. Keep container tightly closed

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Diethylene glycol monobutyl ether (112-34-5) ACGIH ACGIH TWA (ppm) 10 ppm (inhalable fraction and vapor)

D-Glucopyranose, oligomeric, decyl octyl glycosides (68515-73-1) Not applicable

Ethyl alcohol (64-17-5) ACGIH ACGIH STEL (ppm) 1000 ppm

OSHA OSHA PEL (TWA) (mg/m3) 1900 mg/m3

OSHA OSHA PEL (TWA) (ppm) 1000 ppm

IDLH US IDLH (ppm) 3300 ppm (10% LEL)

NIOSH NIOSH REL (TWA) (mg/m3) 1900 mg/m3

NIOSH NIOSH REL (TWA) (ppm) 1000 ppm

8.2. Exposure controls

Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection

Environmental exposure controls Other information

Ensure good ventilation of the work station Wear suitable gloves Wear eye/face protection Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator Avoid release to the environment Handle in accordance with good industrial hygiene and safety procedures Do not eat, drink or smoke when using this product

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state Appearance Colour Odour Odour threshold pH Melting point Freezing point Boiling point Flash point Relative evaporation rate (butylacetate=1) Relative evaporation rate (ether=1) Flammability (solid, gas) Vapour pressure Relative vapour density at 20 °C

Liquid Transparent yellowish Characteristic No data available 76-8.6 No data available No data available No data available > 199 4 °F Non flammable No data available No data available Not flammable No data available No data available

07/24/2019 EN (English) 3/6

According to the Hazard Communication Standard (CFR29 1910 1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

9.2. Other information

Relative density Density Solubility Partition coefficient n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosive limits

No data available 1002- 1042 kg/m3 (@ 68 F) Material highly soluble in water No data available No data available No data available No data available 3 cP @ 68 °F Lower explosive limit (LEL) No data available Upper explosive limit (UEL) No data available

Explosive properties Oxidising properties

No data available No data available

Refractive index 1.367

SECTION 10: Stability and reactivity

10.1. Reactivity

No dangerous reactions known under normal conditions of use

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

No dangerous reactions known under normal conditions of use.

10.4. Conditions to avoid

Heat Sunlight Incompatible materials

10.5. Incompatible materials

Strong acids Alkalis. Strong bases

10.6. Hazardous decomposition products

May include, and are not limited to oxides of carbon, organic compounds

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation)

Not classified.

Not classified Not classified

Diethylene glycol monobutyl ether (112-34-5) LD50 oral rat 5660 mg/kg LD50 dermal rabbit 2700 mg/kg ATE CA (oral) 5660 mg/kg bodyweight ATE CA (Dermal) 2700 mg/kg bodyweight

Skin corrosion/irntation

Serious eye damage/irntation

Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity

Not classified.

pH 7.6-8.6 Causes serious eye irritation pH 7.6-8 6 Not classified.

Not classified.

Not classified.

Ethyl alcohol (64-17-5) IARC group 1 - Carcinogenic to humans

Reproductive toxicity Not classified

STOT-single exposure Not classified.

STOT-repeated exposure Not classified.

07/24/2019 EN (English) 4/6

According to the Hazard Communication Standard (CFR29 1910 1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

Aspiration hazard Not classified Symptoms/effects after inhalation May cause irritation to the respiratory tract Symptoms/effects after skin contact May cause skin irritation Repeated exposure may cause skin dryness or cracking Symptoms/effects after eye contact Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva Symptoms/effects after ingestion . May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Other information Likely routes of exposure ingestion, inhalation, skin and eye.

SECTION 12: Ecological information 12,1. Toxicity

Ecology - general May cause long-term adverse effects in the aquatic environment

12.2. Persistence and degradability

PHOS-CHEK® 3% AFFF Mijspec Persistence and degradability| Not established.

12.3. Bioaccumulative potential

PHOS-CHEK® 3% AFFF Milspec Partition coefficient n-octanol/water Not applicable Bioaccumulative potential Not established

12.4. Mobility in soil

No additional information available

12.5. Other adverse effects

Other information No other effects known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product/Packagmg disposal recommendations Dispose in a safe manner in accordance with local/national regulations.

SECTION 14: Transport information Department of Transportation (DOT) and Transportation of Dangerous Goods (TDG) In accordance with DOT/TDG Not applicable

SECTION 15: Regulatory information

15.1. Federal regulations

All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for___________________________________________________________________________

| Alcohols, C9-11, branched and linear, ethoxylated, sulfates, sodium salts | CAS-No. 160901-28-0

All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic Substances List) inventories except for

| Alcohols, C9-11, branched and linear, ethoxylated, sulfates, sodium salts | CAS-No. 160901-28-0

15.2. International regulations

No additional information available

15.3. US State regulations

A WARNING: This product can expose you to Ethylene glycol, which is known to the State of California to cause birth defects or other reproductive harm For more information go to www.P65Warnings.ca.gov.

SECTION 16: Other information Revision date 07/24/2019 Other information None.

Prepared by Nexreg Compliance Inc.

www Nexreq com exreg

07/24/2019 EN (English) 5/6 http://www.P65Warnings.ca.gov

According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015

NFPA health hazard NFPA fire hazard NFPA reactivity

Hazard Rating Health Flammability Physical

2 Moderate Hazard 0 Minimal Hazard 0 Minimal Hazard

SDS HazCom 2012 - WHMIS 2015 (NexReg)

Disclaimer We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind The information contained in this document applies to this specific matenal as supplied It may not be valid for this matenal If it is used in combination with any other matenals It is the user's responsibility to satisfy oneself as to the suitability and completeness of this information for the user's own particular use

07/24/2019 EN (English) 6/6

File details come from the government source that posted it. Updated .