SDS_-_CHEMGUARD_3%_AFFF.pdf

SAFETY DATA SHEET

This safety data sheet was created pursuant to the requirements of:

US OSHA Hazard Communication Standard (29 CFR 1910.1200)

Revision date 22-Nov-2023 Revision Number 3

1. Identification

Product identifier

Product name CHEMGUARD 3% AFFF C306-MS-C - OBSOLETE

Other means of identification

Product code 770810

Synonyms None

Recommended use of the chemical and restrictions on use

Recommended use Fire extinguishing agent

Uses advised against Consumer use

Details of the supplier of the safety data sheet

Company Name Tyco Fire Protection Products One Stanton Street Marinette, WI 54143-2542 Telephone: 715-735-7411

E-mail psra@jci.com

Company Phone Number Product Stewardship at +1-715-735-7411

Emergency telephone CHEMTREC 001-800-424-9300 or 001-703-527-3887

2. Hazard(s) identification

Classification

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Serious eye damage/eye irritation Category 1 Skin sensitization Category 1B Reproductive toxicity Category 2

Label elements Signal word Danger

Hazard Statements Causes serious eye damage May cause an allergic skin reaction Suspected of damaging fertility or the unborn child

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770810 - CHEMGUARD 3% AFFF C306-MS-C -

OBSOLETE

Revision date 22-Nov-2023

Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Wear protective gloves/clothing and eye/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing must not be allowed out of the workplace

Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor IF ON SKIN: Wash with plenty of water and soap If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse

Precautionary Statements - Storage Store locked up

Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Not applicable

Other information No information available.

3. Composition/information on ingredients

Substance

Not applicable.

Mixture

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Chemical name CAS No. Weight-% Trade secret 2-(2-Butoxyethoxy)ethanol 112-34-5 10 - 20 * Laurylamidopropyl betaine 4292-10-8 1 - 5 *

Caprylcaprilyl glucoside 68515-73-1 1 - 5 * Polyfluorinated alkyl polyamide Trade secret 1 - 5 * Octylphenoxypolyethoxyethanol 9036-19-5 1 - 5 *

2-Methyl-2,4-pentanediol 107-41-5 0.1-1 *

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OBSOLETE

Revision date 22-Nov-2023

2-hydroxy-N,N,N-trimethyl-3-[(3,3,4,4,5,5,6,6,7,7,8, 8,8-tridecafluorooctyl)thio]-1-Propanaminium, chloride (1:1)

88992-45-4 0.1-1 *

*The exact percentage (concentration) of composition has been withheld as a trade secret.

4. First-aid measures

Description of first aid measures

General advice Immediate medical attention is required. Show this safety data sheet to the doctor in attendance.

Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur.

Eye contact Get immediate medical attention. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area.

Skin contact Wash off immediately with soap and plenty of water for at least 15 minutes. May cause an allergic skin reaction. In the case of skin irritation or allergic reactions see a physician.

Ingestion Rinse mouth. Never give anything by mouth to an unconscious person. Do NOT induce vomiting. Call a physician.

Self-protection of the first aider Avoid contact with skin, eyes or clothing. Wear personal protective clothing (see section 8).

Most important symptoms and effects, both acute and delayed

Symptoms Burning sensation. Itching. Rashes. Hives.

Effects of Exposure No information available.

Indication of any immediate medical attention and special treatment needed

Note to physicians May cause sensitization in susceptible persons. Treat symptomatically.

5. Fire-fighting measures

Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Large Fire CAUTION: Use of water spray when fighting fire may be inefficient.

Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams.

Specific hazards arising from the chemical

Product is or contains a sensitizer. May cause sensitization by skin contact.

Hazardous combustion products Carbon oxides. Nitrogen oxides (NOx). Oxides of sulfur. Fluorinated oxides.

Explosion data Sensitivity to mechanical impact None.

Sensitivity to static discharge None.

Special protective equipment and Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear.

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OBSOLETE

Revision date 22-Nov-2023 precautions for fire-fighters Use personal protection equipment.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.

Ensure adequate ventilation. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

Other information Refer to protective measures listed in Sections 7 and 8.

For emergency responders Use personal protection recommended in Section 8.

Environmental Precautions

Environmental Precautions See Section 12 for additional Ecological Information.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

7. Handling and storage

Precautions for safe handling

Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Take off contaminated clothing and wash before reuse.

Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up.

Keep out of the reach of children.

8. Exposure controls/personal protection

Control parameters

Chemical name ACGIH TLV OSHA PEL NIOSH 2-(2-Butoxyethoxy)ethanol

112-34-5 TWA: 10 ppm inhalable fraction and vapor

2-Methyl-2,4-pentanediol 107-41-5

STEL: 50 ppm vapor fraction STEL: 10 mg/m3 inhalable particulate matter, aerosol only TWA: 25 ppm vapor fraction

- Ceiling: 25 ppm Ceiling: 125 mg/m3

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OBSOLETE

Revision date 22-Nov-2023

Appropriate engineering controls

Engineering controls Showers Eyewash stations Ventilation systems.

Individual protection measures, such as personal protective equipment

Eye/face protection Tight sealing safety goggles.

Hand protection Wear suitable gloves.

Skin and Body Protection Wear chemical resistant clothing such as gloves, apron, boots or whole bodysuits made from neoprene, as appropriate Antistatic footwear

Respiratory Protection In case of insufficient ventilation, wear suitable respiratory equipment Wear a respirator conforming to EN 140 with Type A filter or better

Ventilation Use local exhaust or general dilution ventilation to control exposure with applicable limits

General hygiene considerations Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or smoke when using this product.

9. Physical and chemical properties

Information on basic physical and chemical properties Physical state Liquid Appearance No information available Color light yellow Odor Characteristic Odor threshold No information available

Other information

Property Values Remarks • Method pH 7 - 8.5 pH (as aqueous solution) None known Melting point / freezing point No data available None known Initial boiling point and boiling range No data available None known Flash point No data available None known Evaporation rate No data available None known Flammability No data available None known Flammability Limit in Air None known

Upper flammability or explosive limits

No data available

Lower flammability or explosive limits

No data available

Vapor pressure No data available Relative vapor density No data available None known Relative density No data available None known Water solubility No data available None known Solubility(ies) No data available None known Partition coefficient No data available None known Autoignition temperature No data available None known Decomposition temperature None known Kinematic viscosity No data available None known Dynamic viscosity No data available

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None known

OBSOLETE

Revision date 22-Nov-2023

Explosive properties No information available Oxidizing properties No information available Softening point No information available Molecular weight No information available VOC content 18.7575 Liquid Density 1.02 Refractive Index No information available Bulk density No information available

10. Stability and reactivity

Reactivity No information available.

Chemical stability Stable under normal conditions.

Possibility of hazardous reactions None under normal processing.

Conditions to avoid Extremes of temperature and direct sunlight.

Incompatible materials Strong acids. Strong bases. Strong oxidizing agents.

Hazardous decomposition products Carbon oxides. Nitrogen oxides (NOx). Oxides of sulfur. Fluorinated oxides.

11. Toxicological information

Information on likely routes of exposure

Product Information

Inhalation Specific test data for the substance or mixture is not available.

Eye contact Causes serious eye damage. May cause irreversible damage to eyes.

Skin contact (based on components). May cause sensitization by skin contact. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. May cause irritation.

Ingestion Specific test data for the substance or mixture is not available.

Symptoms related to the physical, chemical and toxicological characteristics

Symptoms Redness. Burning. May cause blindness. Itching. Rashes. Hives.

Acute toxicity .

Numerical measures of toxicity

The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 10,702.60 mg/kg ATEmix (dermal) 10,789.80 mg/kg ATEmix (inhalation-dust/mist) 292.10 mg/l

Chemical name Oral LD50 Dermal LD50 Inhalation LC50 2-(2-Butoxyethoxy)ethanol

112-34-5 = 5660 mg/kg ( Rat ) = 2700 mg/kg ( Rabbit ) -

Laurylamidopropyl betaine > 2000 mg/kg ( Rat ) - -

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OBSOLETE

Revision date 22-Nov-2023

4292-10-8 Caprylcaprilyl glucoside

68515-73-1

- > 2000 mg/kg ( Rabbit ) -

Polyfluorinated alkyl polyamide

>2000 mg/kg >2000 mg/kg >5.11 mg/l

Octylphenoxypolyethoxyethanol 9036-19-5

= 1700 mg/kg ( Rat ) - -

2-Methyl-2,4-pentanediol 107-41-5

= 3700 mg/kg ( Rat ) = 12300 mg/kg ( Rabbit ) > 310 mg/m3 ( Rat ) 1 h

2-hydroxy-N,N,N-trimethyl-3-[(3, 3,4,4,5,5,6,6,7,7,8,8,8-tridecaflu orooctyl)thio]-1-Propanaminium, chloride (1:1) 88992-45-4

>300 - <2000 mg/kg > 2000 mg/kg ( Rat ) -

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation No information available.

2-hydroxy-N,N,N-trimethyl-3-[(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)thio]-1-Propanaminium, chloride (1:1) (88992-45-4) Method species Exposure Route Effective dose Exposure time Results OECD Test No. 439: In Vitro Skin Irritation: Reconstructed Human Epidermis Test Method

EPISKIN™ in vitro non-irritant

Serious eye damage/eye irritation Classification based on data available for ingredients. Causes burns. Causes serious eye damage.

Polyfluorinated alkyl polyamide Method species Exposure Route Effective dose Exposure time Results OECD Test No. 405: Acute Eye Irritation/Corrosion

Rabbit eye Class 4 on a 1 to 8 scale according to a modified Kay and Calandra classification system. Mild eye irritation

Respiratory or skin sensitization May cause an allergic skin reaction.

2-hydroxy-N,N,N-trimethyl-3-[(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)thio]-1-Propanaminium, chloride (1:1) (88992-45-4) Method species Exposure Route Results OECD Test No. 429: Skin Sensitization:

Local Lymph Node Assay

Mouse Dermal Sensitizing

Germ cell mutagenicity No information available.

2-hydroxy-N,N,N-trimethyl-3-[(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)thio]-1-Propanaminium, chloride (1:1) (88992-45-4) Method species Results OECD Test No. 471: Bacterial Reverse Mutation Test in vitro Not mutagenic

Carcinogenicity No information available.

Reproductive toxicity Suspected of damaging fertility or the unborn child.

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OBSOLETE

Revision date 22-Nov-2023

STOT - single exposure No information available.

STOT - repeated exposure No information available.

Aspiration hazard No information available.

Other adverse effects No information available.

Interactive effects No information available.

12. Ecological information

Ecotoxicity

Chemical name Algae/aquatic plants Fish Toxicity to microorganisms

Crustacea

2-(2-Butoxyethoxy)ethan ol

112-34-5

EC50 (96h) > 100 mg/L Desmodesmus subspicatus

LC50: =1300mg/L (96h, Lepomis macrochirus)

- EC50: >100mg/L (48h, Daphnia magna)

Caprylcaprilyl glucoside 68515-73-1

- LC50: =170mg/L (96h, Danio rerio)

2-Methyl-2,4-pentanediol 107-41-5

- LC50: 10500 - 11000mg/L (96h, Pimephales promelas) LC50: =10000mg/L (96h, Lepomis macrochirus) LC50: =8690mg/L (96h, Pimephales promelas)

LC50: =10700mg/L (96h, Pimephales promelas)

- EC50: 2700 - 3700mg/L (48h, Daphnia magna)

Persistence and degradability No information available.

Bioaccumulation There is no data for this product.

Chemical name Partition coefficient 2-(2-Butoxyethoxy)ethanol

112-34-5

2-Methyl-2,4-pentanediol 107-41-5

0.14

2-hydroxy-N,N,N-trimethyl-3-[(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecaflu orooctyl)thio]-1-Propanaminium, chloride (1:1)

88992-45-4

0.4

Other adverse effects No information available.

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OBSOLETE

Revision date 22-Nov-2023

13. Disposal considerations

Disposal methods

Waste from residues/unused products

Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation.

Contaminated packaging Do not reuse empty containers.

14. Transport information

DOT Not regulated

TDG Not regulated

MEX Not regulated

ICAO (air) Not regulated

IATA Not regulated

IMDG Not regulated

15. Regulatory information

International Inventories

TSCA Complies DSL/NDSL Does not comply EINECS/ELINCS Does not comply ENCS Does not comply IECSC Does not comply KECL Does not comply PICCS Does not comply AIIC Does not comply NZIoC Complies

Legend:

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AIIC - Australian Inventory of Industrial Chemicals NZIoC - New Zealand Inventory of Chemicals

US Federal Regulations

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SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any

OBSOLETE

Revision date 22-Nov-2023 chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

Chemical name SARA 313 - Threshold Values % 2-(2-Butoxyethoxy)ethanol - 112-34-5 1.0

SARA 311/312 Hazard Categories Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate classifications.

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42).

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material.

US State Regulations

California Proposition 65 This product contains the following Proposition 65 chemicals:.

Chemical name California Proposition 65 Dichloroacetic acid - 79-43-6 Carcinogen

Developmental Male Reproductive

Perfluorooctanoic acid - 335-67-1 Developmental Toxicity

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania Water

7732-18-5

- - X

2-(2-Butoxyethoxy)ethanol 112-34-5

X - X

2-Methyl-2,4-pentanediol 107-41-5

X X X t-Butanol 75-65-0

X X X

Dichloroacetic acid 79-43-6

X - -

Chloroacetic acid 79-11-8

X X X

Dimethylaminopropylamine

(DMAPA)

109-55-7

X X X

U.S. EPA Label Information

EPA Pesticide Registration Number Not applicable

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OBSOLETE

Revision date 22-Nov-2023

16. Other information

Chronic Hazard Star Legend * = Chronic Health Hazard

Key or legend to abbreviations and acronyms used in the safety data sheet Legend Section 8: Exposure controls/personal protection

Key literature references and sources for data used to compile the SDS Agency for Toxic Substances and Disease Registry (ATSDR) U.S. Environmental Protection Agency ChemView Database European Food Safety Authority (EFSA) EPA (Environmental Protection Agency) Acute Exposure Guideline Level(s) (AEGL(s)) U.S. Environmental Protection Agency Federal Insecticide, Fungicide, and Rodenticide Act U.S. Environmental Protection Agency High Production Volume Chemicals Food Research Journal Hazardous Substance Database International Uniform Chemical Information Database (IUCLID) National Institute of Technology and Evaluation (NITE) Australia National Industrial Chemicals Notification and Assessment Scheme (NICNAS) NIOSH (National Institute for Occupational Safety and Health) National Library of Medicine's ChemID Plus (NLM CIP) National Library of Medicine’s PubMed database (NLM PUBMED) National Toxicology Program (NTP) New Zealand's Chemical Classification and Information Database (CCID) Organization for Economic Co-operation and Development Environment, Health, and Safety Publications Organization for Economic Co-operation and Development High Production Volume Chemicals Program Organization for Economic Co-operation and Development Screening Information Data Set World Health Organization

Revision date 22-Nov-2023 Revision Note 2. 3.

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

NFPA Health hazards 3 Flammability 0 Instability 0 Special hazards - HMIS Health hazards 3 Flammability 0 Physical hazards 0 Personal protection X

TWA TWA (time-weighted average) STEL STEL (Short Term Exposure Limit) Ceiling Maximum limit value *

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Skin designation