SDS_-_ANSULITE_3%_AFFF.pdf

Safety Data Sheet

This safety data sheet complies with the requirements of: 2012 OSHA Hazard Communication Standard ( 29CFR 1910.1200)

Product name ANSULITE 3% AFFF (AFC3B)

1. Identification

Product name ANSULITE 3% AFFF (AFC3B)

Product code 443090 Synonyms None Chemical Family No information available

Recommended use Fire extinguishing agent.

Uses advised against Consumer use.

Contact point Product Stewardship at 1-715-735-7411 E-mail address psra@tycofp.com

Emergency telephone CHEMTREC 001-800-424-9300 or 001-703-527-3887

2. Hazards Identification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation - Category 2A

Precautionary Statements

1.1. Product Identifier

1.2. Other means of identification

1.3. Recommended use of the chemical and restrictions on use

1.4. Details of the Supplier of the Safety Data Sheet

Company Name Tyco Fire Protection Products

One Stanton Street Marinette, WI 54143-2542 Telephone: 715-735-7411

1.5. Emergency Telephone Number

Classification

2.2. Label Elements

Signal Word

WARNING

Hazard Statements Causes serious eye irritation

Revision date 11-Jan-2019 Version 4

Product code 443090 / Product name ANSULITE 3%

AFFF (AFC3B)

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Prevention Wash face, hands and any exposed skin thoroughly after handling. Wear eye/face protection.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Not Applicable.

3. Composition/information on Ingredients

The following component(s) in this product are considered hazardous under applicable OSHA(USA)

Chemical name CAS No. weight-% 2-(2-Butoxyethoxy)ethanol 112-34-5 5 - 10

Lauryl Imino Propionate, Sodium Salt 14960-06-6 1 - 5 Polyfluorinated alkyl betaine Proprietary 1 - 5

4. First aid measures

Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.

Consult a physician.

Skin contact Wash skin with soap and water. Get medical attention if irritation develops and persists.

Inhalation Remove to fresh air. If breathing is difficult, give oxygen. (Get medical attention immediately if symptoms occur.).

Ingestion Rinse mouth. Do not induce vomiting without medical advice. If swallowed, call a poison control center or physician immediately.

Symptoms No information available.

Note to physicians Treat symptomatically.

5. Fire-fighting measures

2.3. Hazards Not Otherwise Classified (HNOC)

2.4. Other Information

3.1. Mixture

4.1. Description of first aid measures

4.2. Most Important Symptoms and Effects, Both Acute and Delayed

4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed

5.1. Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

5.2. Unsuitable Extinguishing Media

None.

AFFF (AFC3B)

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Hazardous Combustion Products

Carbon oxides, Fluorinated oxides, Nitrogen oxides (NOx), Oxides of sulfur

Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

6. Accidental release measures

Personal Precautions Ensure adequate ventilation, especially in confined areas.

For emergency responders Use personal protection recommended in Section 8.

Environmental Precautions Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewers, basements or confined areas. See Section 12 for additional Ecological Information.

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Pick up and transfer to properly labeled containers.

7. Handling and Storage

Advice on safe handling Avoid contact with skin and eyes. Handle in accordance with good industrial hygiene and safety practice.

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible Materials Strong oxidizing agents. Strong acids. Strong bases.

8. Exposure Controls/Personal Protection

Exposure guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL

2-(2-Butoxyethoxy)ethanol TWA: 10 ppm inhalable - - -

5.3. Specific Hazards Arising from the Chemical

None known.

5.4. Explosion Data

5.5. Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental Precautions

6.3. Methods and material for containment and cleaning up

7.1. Precautions for Safe Handling

7.2. Conditions for safe storage, including any incompatibilities

8.1. Control Parameters

AFFF (AFC3B)

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112-34-5 fraction and vapor ACGIH (American Conference of Governmental Industrial Hygienists) OSHA (Occupational Safety and Health Administration of the US Department of Labor) NIOSH IDLH Immediately Dangerous to Life or Health

Engineering controls Ensure adequate ventilation, especially in confined areas.

Eye/Face Protection Avoid contact with eyes. Tight sealing safety goggles.

Skin and Body Protection Wear protective gloves and protective clothing.

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

Ventilation Use local exhaust or general dilution ventilation to control exposure with applicable limits

9. Physical and Chemical Properties

Physical State Liquid

VOC content (%) 10.0568 Density 1.01 g/cm3

8.2. Appropriate Engineering Controls

8.3. Individual protection measures, such as personal protective equipment

8.4. General hygiene considerations

Do not eat, drink or smoke when using this product. Handle in accordance with good industrial hygiene and safety practice.

9.1. Information on basic physical and chemical properties

Odor Characteristic Color Amber Odor Threshold No data available

Property Values Remarks • Method pH No data available Melting point/freezing point No data available Boiling point / boiling range 100 °C / 212 °F Flash Point No data available No flash up to boiling point.

Evaporation Rate No data available Flammability (solid, gas) No data available Flammability limit in air

Upper flammability limit: No data available Lower flammability limit: No data available

Vapor Pressure No data available Vapor Density No data available Specific gravity No data available Water Solubility No data available Solubility in Other Solvents No data available Partition coefficient No data available Autoignition Temperature No data available Decomposition Temperature No data available Kinematic viscosity No data available

AFFF (AFC3B)

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10. Stability and Reactivity

Stable under recommended storage conditions.

None under normal processing.

Hazardous Polymerization Hazardous polymerization does not occur.

Extremes of temperature and direct sunlight.

Strong oxidizing agents. Strong acids. Strong bases.

Carbon oxides. Nitrogen oxides (NOx). Oxides of sulfur. Fluorinated oxides.

11. Toxicological Information

Product information

Inhalation No data available.

Eye Contact Severely irritating to eyes.

Skin contact No data available.

Ingestion No data available.

Component Information Acute Toxicity

Chemical name Oral LD50 Dermal LD50 Inhalation LC50 2-(2-Butoxyethoxy)ethanol

112-34-5 = 5660 mg/kg ( Rat ) = 2700 mg/kg ( Rabbit ) -

Symptoms No information available.

Serious eye damage/eye irritation Severely irritating to eyes.

Carcinogenicity No information available.

10.1. Chemical Stability

10.2. Reactivity

No data available

10.3. Possibility of hazardous reactions

10.4. Conditions to Avoid

10.5. Incompatible Materials

10.6. Hazardous decomposition products

11.1. Information on Likely Routes of Exposure

11.2. Information on Toxicological Effects

11.3. Delayed and immediate effects as well as chronic effects from short and long-term exposure

AFFF (AFC3B)

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Reproductive Toxicity No information available.

STOT - Single Exposure No information available.

STOT - Repeated Exposure No information available.

Aspiration Hazard No information available.

The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 25600 mg/kg ATEmix (dermal) 27648 mg/kg

12. Ecological Information

Chemical name Algae/aquatic plants Fish Crustacea 2-(2-Butoxyethoxy)ethanol

112-34-5 EC50 (96h) > 100 mg/L

Desmodesmus subspicatus LC50 (96h) static = 1300 mg/L

Lepomis macrochirus EC50 (48h) > 100 mg/L Daphnia magna EC50 (24h) = 2850 mg/L

Daphnia magna 1,2-Propanediol

57-55-6 EC50 (96h) = 19000 mg/L

Pseudokirchneriella subcapitata LC50 (96h) static = 51600 mg/L

Oncorhynchus mykiss LC50 (96h) static = 51400 mg/L Pimephales promelas LC50 (96h) = 710 mg/L Pimephales promelas LC50 (96h) static 41 - 47 mL/L Oncorhynchus mykiss

EC50 (48h) Static > 1000 mg/L Daphnia magna EC50 (24h) > 10000 mg/L Daphnia magna

1-Octanol 111-87-5

EC50 (48h) static = 14 mg/L Desmodesmus subspicatus

LC50 (96h) static = 17.68 mg/L Oncorhynchus mykiss LC50 (96h) flow-through 11.4 - 12.9 mg/L Pimephales promelas

EC50 (24h) 15 - 26 mg/L Daphnia magna

Concentrate Method Biological Test Method: Acute Lethality

Test Using Daphnia ssp. (EPS

1/RM/11)

Species Daphnia magna Endpoint type LC50 Effective dose 928 mg/L Exposure time 48h

Method Biological Test Method: Acute Lethality Test Using Daphnia ssp. (EPS

1/RM/11)

Species Daphnia magna Endpoint type EC50 Effective dose 790 mg/L Exposure time 48h

Method Biological Test Method: Acute Lethality Test Using Rainbow Trout (EPS

1/RM/9)

Species Oncorhynchus mykiss (rainbow trout) Endpoint type LC50 Effective dose 5,320 mg/L Exposure time 96h

11.4. Numerical Measures of Toxicity - Product information

12.1. Ecotoxicity

AFFF (AFC3B)

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3% Solution Method Biological Test Method: Acute Lethality Test Using Daphnia ssp. (EPS 1/RM/11) Species Daphnia magna Endpoint type LC50 Effective dose 52,830 mg/L Exposure time 48h

Method Biological Test Method: Acute Lethality Test Using Daphnia ssp. (EPS 1/RM/11) Species Daphnia magna Endpoint type EC50 Effective dose 36,990 mg/L Exposure time 48h

Method Biological Test Method: Acute Lethality Test Using Rainbow Trout (EPS 1/RM/9) Species Oncorhynchus mykiss (rainbow trout) Endpoint type LC50 Effective dose 185,200 mg/L Exposure time 96h

Method Biological Test Method: Acute Lethality Using Threespine Stickleback (Gasterosteus aculeatus) (EPS 1/RM/10)

Species Gasterosteus aculeatus Endpoint type LC50 Effective dose 80,000 mg/L Exposure time 96h

Chemical Oxygen Demand (mg/L) Concentrate 230,000 3% Solution 7,000

Concentrate Biological Oxygen Demand (mg/L) Biological Oxygen Demand (5 Day) <20000

%BOD/COD 6.96

Biological Oxygen Demand (10 Day) 150000

%BOD/COD 65.22

Biological Oxygen Demand (15 Day) 170000

%BOD/COD 73.91

Biological Oxygen Demand (20 Day) 190000

%BOD/COD 82.61

3% Solution Biological Oxygen Demand (mg/L) Biological Oxygen Demand (5 Day) 390

%BOD/COD 5.57

Biological Oxygen Demand (10 Day) 4600

%BOD/COD 65.71

Biological Oxygen Demand (15 Day) 5000

%BOD/COD 71.43

Biological Oxygen Demand (20 Day) 5200

%BOD/COD 74.29

12.2. Persistence and Degradability

AFFF (AFC3B)

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No information available.

No information available

13. Disposal Considerations

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated Packaging Do not reuse container.

14. Transport Information

DOT NOT REGULATED

TDG NOT REGULATED

MEX NOT REGULATED

ICAO (air) NOT REGULATED

IATA NOT REGULATED

IMDG NOT REGULATED

15. Regulatory Information

TSCA Complies DSL/NDSL Does not comply ENCS Complies IECSC Complies KECL Complies PICCS Does not comply AICS Complies

Legend:

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

12.3. Bioaccumulation

12.4. Other Adverse Effects

13.1. Waste Treatment Methods

15.1. International Inventories

15.2. US Federal Regulations

AFFF (AFC3B)

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Chemical name SARA 313 - Threshold Values % 2-(2-Butoxyethoxy)ethanol - 112-34-5 1.0 SARA 311/312 Hazard Categories

Acute Health Hazard Yes Chronic health hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40

CFR 122.42)

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material

California Proposition 65 This product contains the following Proposition 65 chemicals

Chemical name California Proposition 65 Perfluorooctanoic acid - 335-67-1 Developmental Toxicity

U.S. State Right-to-Know Regulations

Chemical name New Jersey Massachusetts Pennsylvania 2-(2-Butoxyethoxy)ethanol

112-34-5 X - X

1,2-Propanediol 57-55-6

X - X

1-Octanol 111-87-5

- - X

16. Other information, including date of preparation of the last revision

Revision date 11-Jan-2019 Revision note SDS sections updated, 12.

Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

15.3. US State Regulations

NFPA Health Hazards 1 Flammability 0 Instability 0 Physical and chemical properties -

HMIS Health Hazards 1 Flammability 0 Physical Hazards 0

Personal Protection X