SDS_-_ECOPOL_A3+.pdf

SAFETY DATA SHEET (REGULATION (EC) n° 1907/2006 - REACH) Version 5.1 (25/10/2023) - Page 1/8

BIO-EX

ECOPOL A3+

SAFETY DATA SHEET

(REACH regulation (EC) n° 1907/2006 - n° 2020/878)

SECTION 1 : IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name : ECOPOL A3+

1.2. Relevant identified uses of the substance or mixture and uses advised against

Fire fighting foam concentrate

1.3. Details of the supplier of the safety data sheet

Registered company name : BIO-EX.

Address : 5 chemin de Clape-Loup .69280.Sainte-Consorce.FRANCE.

Telephone : +33 (0)4.74.70.23.81. Fax : +33 (0)4.74.70.23.94.

contact@bio-ex.fr

1.4. Emergency telephone number : +33 (0)1 45 42 59 59.

Association/Organisation : France: INRS / ORFILA http://www.centres-antipoison.net.

SECTION 2 : HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

In compliance with EC regulation No. 1272/2008 and its amendments.

Eye irritation, Category 2 (Eye Irrit. 2, H319).

This mixture does not present a physical hazard. Refer to the recommendations regarding the other products present on the site.

This mixture does not present an environmental hazard. No known or foreseeable environmental damage under standard conditions of use.

2.2. Label elements

In compliance with EC regulation No. 1272/2008 and its amendments.

Hazard pictograms :

GHS07

Signal Word :

WARNING

Hazard statements :

H319 Causes serious eye irritation.

Precautionary statements - Prevention :

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ...

Precautionary statements - Response :

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337 + P313 If eye irritation persists: Get medical advice/attention.

2.3. Other hazards

The mixture does not contain substances classified as 'Substances of Very High Concern' (SVHC) >= 0.1% published by the European CHemicals Agency (ECHA) under article 57 of REACH: http://echa.europa.eu/fr/candidate-list-table

The mixture fulfils neither the PBT nor the vPvB criteria for mixtures in accordance with annexe XIII of the REACH regulations EC 1907/2006.

The mixture does not contain substances> = 0.1% with endocrine disrupting properties in accordance with the criteria of the Delegated Regulation (EU) 2017/2100 of the Commission or Regulation (EU) 2018/605 of the Commission.

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SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

Composition :

Identification Classification (EC) 1272/2008 Note %

INDEX: 603-096-00-8

CAS: 112-34-5

EC: 203-961-6

REACH: 01-2119475104-44

2-(2-BUTOXYETHOXY)ETHANOL

GHS07

Wng Eye Irrit. 2, H319

[1]

[XVII]

10 <= x % < 25

ALKYL SULFATE GHS07, GHS05

Dgr Acute Tox. 4, H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 3, H412

2.5 <= x % < 10

ANIONIC SURFACTANT GHS07

Wng Eye Irrit. 2, H319

0 <= x % < 2.5

ALKYLBETAINE GHS05

Dgr Eye Dam. 1, H318 Aquatic Chronic 3, H412

0 <= x % < 2.5

AMPHOTERIC SURFACTANT GHS07, GHS05, GHS09

Dgr Acute Tox. 4, H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 2, H411 Aquatic Acute 1, H400 M Acute = 1

0 <= x % < 2.5

Specific concentration limits:

Identification Specific concentration limits ATE ALKYL SULFATE Eye Dam. 1: H318 C>= 20%

Eye Irrit. 2: H319 10% <= C < 20% ALKYLBETAINE Eye Dam. 1: H318 C>= 10.1%

Eye Irrit. 2: H319 4% <= C < 10.1%

Information on ingredients :

(Full text of H-phrases: see section 16)

[XVII] Restricted substance under Regulation (EC) No. 1907/2006 (REACH), Annex XVII.

[1] Substance for which maximum workplace exposure limits are available.

SECTION 4 : FIRST AID MEASURES

As a general rule, in case of doubt or if symptoms persist, always call a doctor.

NEVER induce swallowing by an unconscious person.

4.1. description of first aid measures

In the event of splashes or contact with eyes :

Wash thoroughly with fresh, clean water for 15 minutes holding the eyelids open.

If there is any redness, pain or visual impairment, consult an ophthalmologist.

In the event of swallowing :

Seek medical attention, showing the label.

4.2. Most important symptoms and effects, both acute and delayed

No data available.

4.3. Indication of any immediate medical attention and special treatment needed

No data available.

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SECTION 5 : FIREFIGHTING MEASURES

Non-flammable.

5.1. Extinguishing media

Firefighting foam concentrate not flammable

5.2. Special hazards arising from the substance or mixture

A fire will often produce a thick black smoke. Exposure to decomposition products may be hazardous to health.

Do not breathe in smoke.

In the event of a fire, the following may be formed :

- carbon monoxide (CO)

- carbon dioxide (CO2)

5.3. Advice for firefighters

No data available.

SECTION 6 : ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Consult the safety measures listed under headings 7 and 8.

For non first aid worker

Avoid any contact with the skin and eyes.

For first aid worker

First aid workers will be equipped with suitable personal protective equipment (See section 8).

6.2. Environmental precautions

Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite, diatomaceous earth in drums for waste disposal.

Prevent any material from entering drains or waterways.

6.3. Methods and material for containment and cleaning up

Clean preferably with a detergent, do not use solvents.

6.4. Reference to other sections

No data available.

SECTION 7 : HANDLING AND STORAGE

Requirements relating to storage premises apply to all facilities where the mixture is handled.

7.1. Precautions for safe handling

Always wash hands after handling.

Remove and wash contaminated clothing before re-using.

Fire prevention :

Prevent access by unauthorised personnel.

Recommended equipment and procedures :

For personal protection, see section 8.

Observe precautions stated on label and also industrial safety regulations.

Avoid eye contact with this mixture.

Prohibited equipment and procedures :

No smoking, eating or drinking in areas where the mixture is used.

7.2. Conditions for safe storage, including any incompatibilities

No data available.

Packaging

Always keep in packaging made of an identical material to the original.

Recommended types of packaging :

Product in bulk : stainless steel, polyester or mild steel protected with epoxy or polyurethane coating. Tanks in PE, PP

Unsuitable packaging materials :

Mild steel

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7.3. Specific end use(s)

No data available.

SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Occupational exposure limits :

- European Union (2022/431, 2019/1831, 2017/2398, 2017/164, 2009/161, 2006/15/CE, 2000/39/CE, 98/24/CE) :

CAS VME-mg/m3 : VME-ppm : VLE-mg/m3 : VLE-ppm : Notes :

112-34-5 67.5 10 101.2 15 -

- Germany - AGW (BAuA - TRGS 900, 02/2022) :

CAS VME : VME : Excess Notes 112-34-5 10 ppm

67 mg/m3

1.5 (I)

- France (INRS - Outils 65 / 2021-1849, 2021-1763, decree of 09/12/2021) :

CAS VME-ppm : VME-mg/m3 : VLE-ppm : VLE-mg/m3 : Notes : TMP No :

112-34-5 10 67.5 15 101.2 - -

- UK / WEL (Workplace exposure limits, EH40/2005, Fourth Edition 2020) :

CAS TWA : STEL : Ceiling : Definition : Criteria :

112-34-5 10 ppm

67.5 mg/m3 15 ppm

101.2 mg/m3

8.2. Exposure controls

Personal protection measures, such as personal protective equipment

Pictogram(s) indicating the obligation of wearing personal protective equipment (PPE) :

Use personal protective equipment that is clean and has been properly maintained.

Store personal protective equipment in a clean place, away from the work area.

Never eat, drink or smoke during use. Remove and wash contaminated clothing before re-using. Ensure that there is adequate ventilation, especially in confined areas.

- Eye / face protection

Avoid contact with eyes.

Use eye protectors designed to protect against liquid splashes

Before handling, wear safety goggles with protective sides accordance with standard EN166.

In the event of high danger, protect the face with a face shield.

Prescription glasses are not considered as protection.

Individuals wearing contact lenses should wear prescription glasses during work where they may be exposed to irritant vapours.

Provide eyewash stations in facilities where the product is handled constantly.

- Hand protection

Wear suitable protective gloves in the event of prolonged or repeated skin contact.

Use suitable protective gloves that are resistant to chemical agents in accordance with standard EN ISO 374-1.

Gloves must be selected according to the application and duration of use at the workstation.

Protective gloves need to be selected according to their suitability for the workstation in question : other chemical products that may be handled, necessary physical protections (cutting, pricking, heat protection), level of dexterity required.

Type of gloves recommended :

- PVC (polyvinyl chloride)

- Body protection

Work clothing worn by personnel shall be laundered regularly.

After contact with the product, all parts of the body that have been soiled must be washed.

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SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Physical state Physical state : Fluid liquid.

Colour Unspecified

Odour Odour threshold : Not stated.

Melting point Melting point/melting range : Not specified.

Freezing point Freezing point / Freezing range : Not stated.

Boiling point or initial boiling point and boiling range Boiling point/boiling range : Not specified.

Flammability Flammability (solid, gas) : Not stated.

Lower and upper explosion limit Explosive properties, lower explosivity limit (%)

Not stated.

Explosive properties, upper explosivity limit (%)

Not stated.

Flash point Flash point interval : Not relevant.

Auto-ignition temperature Self-ignition temperature : Not specified.

Decomposition temperature Decomposition point/decomposition range : Not specified.

pH pH : Not stated.

Neutral.

pH (aqueous solution) : Not stated.

Kinematic viscosity Viscosity : Not stated.

Solubility Water solubility : Soluble.

Fat solubility : Not stated.

Partition coefficient n-octanol/water (log value) Partition coefficient: n-octanol/water : Not stated.

Vapour pressure Vapour pressure (50°C) : Not relevant.

Density and/or relative density Density : > 1

Relative vapour density Vapour density : Not stated.

Particle characteristics The mixture does not contain nanoforms.

9.2. Other information

No data available.

9.2.1. Information with regard to physical hazard classes

No data available.

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9.2.2. Other safety characteristics

No data available.

SECTION 10 : STABILITY AND REACTIVITY

10.1. Reactivity

No data available.

10.2. Chemical stability

This mixture is stable under the recommended handling and storage conditions in section 7.

10.3. Possibility of hazardous reactions

No data available.

10.4. Conditions to avoid

No data available.

10.5. Incompatible materials

No data available.

10.6. Hazardous decomposition products

The thermal decomposition may release/form :

- carbon monoxide (CO)

- carbon dioxide (CO2)

SECTION 11 : TOXICOLOGICAL INFORMATION

11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

May have reversible effects on the eyes, such as eye irritation which is totally reversible by the end of observation at 21 days.

11.1.1. Substances

No toxicological data available for the substances.

11.1.2. Mixture

No toxicological data available for the mixture.

11.2. Information on other hazards

SECTION 12 : ECOLOGICAL INFORMATION

12.1. Toxicity

12.1.2. Mixtures

No aquatic toxicity data available for the mixture.

12.2. Persistence and degradability

12.2.1. Substances

ALKYL SULFATE

Biodegradability : Rapidly degradable.

12.2.2. Mixtures

Rapidly degradable

12.3. Bioaccumulative potential

No data available.

12.4. Mobility in soil

No data available.

12.5. Results of PBT and vPvB assessment

No data available.

12.6. Endocrine disrupting properties

No data available.

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12.7. Other adverse effects

No data available.

SECTION 13 : DISPOSAL CONSIDERATIONS

Proper waste management of the mixture and/or its container must be determined in accordance with Directive 2008/98/EC.

13.1. Waste treatment methods

Do not pour into drains or waterways.

Waste :

Waste management is carried out without endangering human health, without harming the environment and, in particular without risk to water, air, soil, plants or animals.

Recycle or dispose of waste in compliance with current legislation, via a certified collector or company.

Do not contaminate the ground or water with waste, do not dispose of waste into the environment.

Soiled packaging :

Empty container completely. Keep label(s) on container.

Give to a certified disposal contractor.

SECTION 14 : TRANSPORT INFORMATION

Exempt from transport classification and labelling.

14.1. UN number or ID number

14.2. UN proper shipping name

14.3. Transport hazard class(es)

14.4. Packing group

14.5. Environmental hazards

14.6. Special precautions for user

14.7. Maritime transport in bulk according to IMO instruments

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Classification and labelling information included in section 2:

The following regulations have been used:

- EU Regulation No. 1272/2008 amended by EU Regulation No. 2022/692 (ATP 18)

Container information:

No data available.

Restrictions applied under Title VIII of Regulation (EC) No. 1907/2006 (REACH):

The mixture contains at least one restricted substance under Annex XVII of Regulation (EC) No. 1907/2006 (REACH):

https://echa.europa.eu/substances-restricted-under-reach. Please refer to Section 3 to identify the substance involved.

Explosives precursors :

The mixture does not contain any substance subject to Regulation (EU) 2019/1148 on the marketing and use of explosives precursors.

Particular provisions :

No data available.

15.2. Chemical safety assessment

No data available.

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SECTION 16 : OTHER INFORMATION

Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations.

The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions.

It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations.

The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof.

Wording of the phrases mentioned in section 3 :

H302 Harmful if swallowed.

H315 Causes skin irritation.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H400 Very toxic to aquatic life.

H411 Toxic to aquatic life with long lasting effects.

H412 Harmful to aquatic life with long lasting effects.

Abbreviations and acronyms :

REACH : Registration, Evaluation, Authorization and Restriction of Chemical Substances.

STEL : Short-term exposure limit

TWA : Time Weighted Averages

TMP : French Occupational Illness table

TLV : Threshold Limit Value (exposure)

AEV : Average Exposure Value.

ADR : European agreement concerning the international carriage of dangerous goods by Road.

IMDG : International Maritime Dangerous Goods.

IATA : International Air Transport Association.

ICAO : International Civil Aviation Organisation

RID : Regulations concerning the International carriage of Dangerous goods by rail.

WGK : Wassergefahrdungsklasse (Water Hazard Class).

GHS07 : Exclamation mark

PBT: Persistent, bioaccumulable and toxic.

vPvB : Very persistent, very bioaccumulable.

SVHC : Substances of very high concern.

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