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About this file
This is a Material Safety Data Sheet (MSDS) for Mineral Spirits Rule 66 DR 55 GA, a liquid chemical product manufactured by Ashland. The safety data sheet provides comprehensive information about the product's physical and chemical properties, potential health hazards, and safety precautions. Key details include:
The product is a combustible liquid that can cause central nervous system effects such as dizziness, headache, and nausea. It may cause skin and respiratory tract irritation, with potential for dermatitis and burns upon prolonged contact. Exposure routes include inhalation, skin absorption, skin contact, eye contact, and ingestion. The safety data sheet outlines first aid measures, fire-fighting techniques, accidental release procedures, handling and storage recommendations, and exposure controls. The product is not listed as a carcinogen by major regulatory bodies, but may have potential reproductive health implications. Disposal should be done in accordance with local, state, and federal regulations, avoiding discharge into water systems or sewers without proper notification.
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09 91 00
PAINTING AND FINISHES
Page: 1 SAFETY DATA SHEET Revision Date: 04/05/2010 Print Date: 7/5/2011 MSDS Number: R0000591
MINERAL SPIRITS RULE 66 DR 55 GA
VURULE66
Version: 1.11
Page 1 / 12
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
Ashland Regulatory Information Number 1-800-325-3751 P.O. Box 2219 Telephone 614-790-3333 Columbus, OH 43216 Emergency telephone 1-800-ASHLAND (1-800-274-
5263)
Product name MINERAL SPIRITS RULE 66 DR 55 GA
Product code VURULE66 Product Use Description No data
2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance: liquid, colourless
CAUTION! COMBUSTIBLE LIQUID AND VAPOR. MAY AFFECT THE CENTRAL NERVOUS
SYSTEM CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY CAUSE RESPIRATORY
TRACT IRRITATION. MAY BE HARMFUL IF INHALED OR SWALLOWED. MAY CAUSE
SKIN AND RESPIRATORY TRACT IRRITATION. PROLONGED OR REPEATED CONTACT
MAY DRY SKIN AND CAUSE DERMATITIS AND BURNS.
Potential Health Effects
Exposure routes Inhalation, Skin absorption, Skin contact, Eye Contact, Ingestion
Eye contact May cause mild eye irritation. Symptoms include stinging, tearing, and redness.
Skin contact Can cause skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, burning, and drying and cracking of skin, burns and other skin damage. Passage of this material into the body through the skin is possible, but it is unlikely that this would result in harmful effects during safe handling and use.
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MINERAL SPIRITS RULE 66 DR 55 GA
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Ingestion Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury.
Inhalation
Breathing of vapor or mist is possible. Breathing small amounts of this material during normal handling is not likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms are not expected at air concentrations below the recommended exposure limits, if applicable (see Section 8.).
Aggravated Medical Condition Preexisting disorders of the following organs (or organ systems) may be aggravated by exposure to this material:, Skin, lung (for example, asthma-like conditions), immune system
Symptoms
Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include:, stomach or intestinal upset (nausea, vomiting, diarrhea), irritation (nose, throat, airways), central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) and other central nervous system effects, respiratory failure
Target Organs This material (or a component) has been shown to lower activity of certain immune system cells in experimental animals. The significance of this effect with respect to human health is uncertain., Exposure to this material (or a component) has been found to cause kidney damage in male rats. The mechanism by which this toxicity occurs is specific to the male rat and the kidney effects are not expected to occur in humans., Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals:, mild, reversible liver effects
Carcinogenicity This material is not listed as a carcinogen by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), or the Occupational Safety and Health Administration
(OSHA).
Reproductive hazard Based on the available information, risk to the fetus from maternal exposure to this material cannot be assessed.
3. COMPOSITION/INFORMATION ON INGREDIENTS
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Print Date: 7/5/2011 MSDS Number: R0000591
MINERAL SPIRITS RULE 66 DR 55 GA
Page 3 / 12
Hazardous Components CAS-No. Concentration
MINERAL SPIRITS REGULAR 8052-41-3 <=100%
TRIMETHYLBENZENE 1,2,4- 95-63-6 >=1.5-<5%
4. FIRST AID MEASURES
Eyes If symptoms develop, move individual away from exposure and into fresh air. Flush eyes gently with water while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention.
Skin Remove contaminated clothing. Flush exposed area with large amounts of water. If skin is damaged, seek immediate medical attention. If skin is not damaged and symptoms persist, seek medical attention. Launder clothing before reuse.
Ingestion Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth;
place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. If symptoms develop, move individual away from exposure and into fresh air. If symptoms persist, seek medical attention. If breathing is difficult, administer oxygen. Keep person warm and quiet; seek immediate medical attention.
Notes to physician Hazards: This material is an aspiration hazard. Potential danger from aspiration must be weighed against possible oral toxicity (See Section 2 - Swallowing) when deciding whether to induce vomiting.
Treatment: No information available.
5. FIRE-FIGHTING MEASURES
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Suitable extinguishing media Dry chemical, Foam, Carbon dioxide (CO2)
Hazardous combustion products carbon dioxide and carbon monoxide, Hydrocarbons
Precautions for fire-fighting If product is heated above its flash point it will produce vapors sufficient to support combustion. Vapors are heavier than air and may travel along the ground and be ignited by heat, pilot lights, other flames and ignition sources at locations near the point of release. Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively.Wear full firefighting turn-out gear (full Bunker gear), and respiratory protection (SCBA).
NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class II
6. ACCIDENTAL RELEASE MEASURES
Personal precautions For personal protection see section 8. Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent from spreading. If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other materials to containers for disposal. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks).
Environmental precautions Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required, that a spill has occurred.
Methods for cleaning up Absorb liquid on vermiculite, floor absorbent or other absorbent material.
7. HANDLING AND STORAGE
Handling
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Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. Static ignition hazard can result from handling and use. Electrically bond and ground all containers, personnel and equipment before transfer or use of material. Special precautions may be necessary to dissipate static electricity for non-conductive containers. Use proper bonding and grounding during product transfer as described in National Fire Protection Association document NFPA
77. Hydrocarbon solvents are basically non-conductors of electricity and can become electrostatically charged during mixing, filtering or pumping at high flow rates. If this charge reaches a sufficiently high level, sparks can form that may ignite the vapors of flammable liquids. Warning. Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without the presence of obvious ignition sources. Published "autoignition" or "ignition" temperature values cannot be treated as safe operating temperatures in chemical processes without analysis of the actual process conditions.
Any use of this product in elevated temperature processes should be thoroughly evaluated to establish and maintain safe operating conditions.
Storage Do not store near extreme heat, open flame, or sources of ignition.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
MINERAL SPIRITS REGULAR 8052-41-3
ACGIH time weighted average 100 ppm NIOSH Recommended exposure limit (REL):
350 mg/m3
NIOSH Ceiling Limit Value and Time Period (if specified):
1,800 mg/m3
OSHA Z1 Permissible exposure limit
500 ppm
OSHA Z1 Permissible exposure limit
2,900 mg/m3
OSHA Z1A time weighted average 100 ppm OSHA Z1A time weighted average 525 mg/m3 US CA OEL Time Weighted Average
(TWA) Permissible Exposure Limit (PEL):
100 ppm
US CA OEL Time Weighted Average (TWA) Permissible Exposure Limit (PEL):
525 mg/m3
TRIMETHYLBENZENE 1,2,4- 95-63-6
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MINERAL SPIRITS RULE 66 DR 55 GA
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NIOSH Recommended exposure limit (REL):
25 ppm
NIOSH Recommended exposure limit (REL):
125 mg/m3
ACGIH time weighted average 25 ppm OSHA Z1A time weighted average 25 ppm OSHA Z1A time weighted average 125 mg/m3 US CA OEL Time Weighted Average
(TWA) Permissible Exposure Limit (PEL):
25 ppm
US CA OEL Time Weighted Average (TWA) Permissible Exposure Limit (PEL):
125 mg/m3
General advice These recommendations provide general guidance for handling this product. Personal protective equipment should be selected for individual applications and should consider factors which affect exposure potential, such as handling practices, chemical concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local authorities.
Exposure controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below TLV(s).
Eye protection Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Consult your safety representative.
Skin and body protection Wear resistant gloves (consult your safety equipment supplier).
To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
Respiratory protection If workplace exposure limit(s) of product or any component is exceeded (see exposure guidelines), a NIOSH-approved air supplied respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH respirators (negative pressure type) under specified conditions (see your industrial hygienist). Engineering or administrative controls should be implemented to reduce exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state liquid
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MINERAL SPIRITS RULE 66 DR 55 GA
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Form liquid Colour colourless Odour hydrocarbon-like Boiling point/boiling range 315.00 °F / 157.22 °C Melting point/range -94 °F / -70 °C
Sublimation point no data available pH no data available Flash point 40.55 °C Tag closed cup Ignition temperature no data available Evaporation rate 0.11 n-Butyl Acetate Lower explosion limit/Upper explosion limit 1.0 %(V) / 6.0 %(V) Particle size no data available Vapour pressure 2.000 mmHg @ 68.00 °F / 20.00 °C Relative vapour density 4.9 AIR=1 Density 0.7720 g/cm3 @ 60.00 °F / 15.56 °C Bulk density 6.44 lb/gal @ 60.00 °F / 15.56 °C Water solubility negligible Solubility no data available Partition coefficient: n-octanol/water no data available log Pow no data available Autoignition temperature 450 °F / 232 °C Viscosity, dynamic no data available Viscosity, kinematic no data available Solids in Solution no data available Decomposition temperature no data available Burning number no data available Dust explosion constant no data available Minimum ignition energy no data available
10. STABILITY AND REACTIVITY
Stability Stable.
Conditions to avoid None known.
Incompatible products Strong oxidizing agents
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Hazardous decomposition products carbon dioxide and carbon monoxide, Hydrocarbons
Hazardous reactions Product will not undergo hazardous polymerization.
Thermal decomposition No data
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD 50 Rat : > 5 g/kg
Acute inhalation toxicity MINERAL SPIRITS REGULAR : no data available
TRIMETHYLBENZENE 1,2,4- : LC 50 Rat: 18 g/m3; 4 h
LC 50 Rat: > 2,000 mg/L; 48 h
Acute dermal toxicity : LD 50 Rabbit: (>) 3 g/kg
12. ECOLOGICAL INFORMATION
Biodegradability
TRIMETHYLBENZENE 1,2,4- : no data available
Bioaccumulation
Ecotoxicity effects
Toxicity to fish
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MINERAL SPIRITS RULE 66 DR 55 GA
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TRIMETHYLBENZENE 1,2,4- : 96 h flow-through test LC 50 Fathead minnow
(Pimephales promelas): 7.19 - 8.28 mg/L Method:
Flow through; Mortality
Toxicity to daphnia and other aquatic invertebrates.
Toxicity to algae
Toxicity to bacteria
Biochemical Oxygen Demand (BOD)
Chemical Oxygen Demand (COD)
Additional ecological information
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MINERAL SPIRITS RULE 66 DR 55 GA
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13. DISPOSAL CONSIDERATIONS
Waste disposal methods Dispose of in accordance with all applicable local, state and federal regulations. Do not discharge effluent containing this product into lakes, streams, ponds or estuaries, oceans, or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit, and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of the EPA.
For assistance with your waste management needs - including disposal, recycling and waste stream reduction, contact Ashland Distribution's Environmental Services Group at 800-637-7922.
14. TRANSPORT INFORMATION
REGULATION
ID
NUMBER
PROPER SHIPPING NAME *HAZARD
CLASS
SUBSIDIARY
HAZARDS
PACKING
GROUP
MARINE
POLLUTANT
/ LTD. QTY.
U.S. DOT - ROAD
Not dangerous goods
U.S. DOT - RAIL
U.S. DOT - INLAND WATERWAYS
TRANSPORT CANADA - ROAD
TRANSPORT CANADA - RAIL
TRANSPORT CANADA - INLAND WATERWAYS
INTERNATIONAL MARITIME DANGEROUS GOODS
UN 1268 PETROLEUM DISTILLATES,
N.O.S.
3 III
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MINERAL SPIRITS RULE 66 DR 55 GA
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INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO
UN 1268 Petroleum distillates, n.o.s. 3 III
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
UN 1268 Petroleum distillates, n.o.s. 3 III
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND
WASTES
UN 1268 DESTILADOS DE PETROLEO,
N.E.P.
3 III
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment.
15. REGULATORY INFORMATION
California Prop. 65 WARNING! This product contains a chemical known to the State of California to cause cancer.
ETHYL BENZENE
NAPHTHALENE
BENZENE
WARNING! This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.
TOLUENE
BENZENE
SARA 313 Component(s)
TRIMETHYLBENZENE 1,2,4- 1.90 %
New Jersey RTK Label Information
MINERAL SPIRITS REGULAR 8052-41-3
TRIMETHYLBENZENE 1,2,4- 95-63-6
Pennsylvania RTK Label Information
MINERAL SPIRITS REGULAR 8052-41-3
TRIMETHYLBENZENE 1,2,4- 95-63-6
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MINERAL SPIRITS RULE 66 DR 55 GA
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Notification status Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing)
Switzerland. Consolidated Inventory y (positive listing) Canada. Canadian Environmental Protection Act (CEPA).
Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133) y (positive listing)
China. Inventory of Existing Chemical Substances y (positive listing) US. Toxic Substances Control Act y (positive listing) EU. EINECS y (positive listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act y (positive listing)
Japan. Kashin-Hou Law List y (positive listing) Japan. Kashin-Hou Law List y (positive listing) Japan. Industrial Safety & Health Law (ISHL) List y (positive listing) New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand y (positive listing)
HMIS NFPA
Health 1* 1 Flammability 2 2 Physical hazards 0 Instability 0 Specific Hazard -- --
16. OTHER INFORMATION
The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by Ashland's Environmental Health and Safety Department (1-800-325-3751).
Paint Thinner
Safety Data Sheet
Product Identifier Paint Thinner
Other Means of Identification
13-221, 13-224, 13-228, 13-321, 13-324, 13-324HD,, 13-324TAR, 13-325, 13-328, 13-341, 13-344, 13-371, 13-374, 13-374HD, 13-375, 14-534, 14-534IMDG, 14-535, 14-538, 14-538UN, 14-573, 23-229, 23-329, 23-329UN, 23-379, 23-379-M, 24-539, 24-539-1000, 33-319UFA, 33-321ACE, 33-321D, 33-321FSEXP, 33-321H, 33-321PAEXP, 33-321PLYEXP, 33-321PP, 33-321RONA, 33-324ACE, 33-324CL, 33-324D, 33-324FSEXP-PRO, 33-324H, 33-324PAEXP-PRO, 33-324PLYX-PRO, 33-324PP, 33-324RONA, 33-324TH, 33-325FSEXP-PRO, 33-325PAEXP-PRO, 33-325PP, 33-326PLYX-PRO, 33-328FSEXP-PRO, 33-328PAEXP-PRO, 33-328PLYX-PRO, 33-328UNI, 33-371H, 33-374H, 33-375H, 34-531C, 34-531FSEXP, 34-531H, 34-531PAEXP, 34-531WDS, 34-534C, 34-534FSEXP-PRO, 34-534H, 34-534PAEXP-PRO, 34-534PLYX-PRO, 34-534RONA, 34-534WDS, 34-535C, 34-535FSEXP-PRO, 34-535H, 34-535PAEXP-PRO, 34-535PLYX-PRO, 34-535RONA, 34-535STE, 34-535WDS, 34-538FSEXP-PRO, 34-538H, 34-538PAEXP, 34-538PAEXP-PRO, 34-538PLYX-PRO, 34-539UFA, 34-573C-CL, 34-573H, 34-574HH, 83-228, 83-229, 83-321, 83-324, 83-326, 83-328, 83-341, 83-344, 84-534, 84-535, 84-538, 84-539, 14-802, 14-804, 34-802SI, 84-802, 84-802ISR, 84-804ISR, 34-803WDS, 34-802WDS, 34-804WDS, 34-802SIEXP, 13-348LAU, 14-402, 14-535UFA, 14-802EXP, 34-802SIB40, 24-539LAU, 24-539U/N, 33-228FN, 33-324ZIPEXP, 34-573WDS-CL, 83-229-40, 83-329SHER, 83-329DU, 84-538-40, 84-539-40, 84-531, 53-325, 53-344, 53-371, 53-374HD, 53-375, 53-324HD, 53-341, 53-328, 53-321, 53-471
Other Identification Solvent, Varsol, Citronella, Charcoal Lighter Fluid, Kerosene, Lamp Oil, Mineral Spirits
Recochem Inc., 850 Montee de Liesse, Montreal, QC, H4T 1P4, Compliance and Regulatory Department, 905-878-5544, www.recochem.com
Recommended Use
SDS No.
Emergency Phone No.
SECTION 1. IDENTIFICATION
Manufacturer/Supplier Identifier
Please refer to Product label.
CANUTEC, 613-996-6666, 24 Hours
Restrictions on Use None known.
Label Elements
SECTION 2. HAZARD IDENTIFICATION
Signal Word:
Danger
Hazard Statement(s):
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 + H320 Causes skin and eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects.
H350 May cause cancer.
H373 May cause damage to organs (nervous system) through prolonged or repeated exposure if inhaled.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statement(s):
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical, ventilating, and lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe fume, mist, vapours, spray.
P264 Wash hands and skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves, eye protection, face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE or doctor.
P331 Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P312 Call a POISON CENTRE or doctor if you feel unwell.
P332 + P313 If skin irritation occurs: Get medical advice or attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTRE or doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTRE or doctor if you feel unwell.
P337 + P313 If eye irritation persists: Get medical advice or attention.
P370 + P378 In case of fire: Use appropriate foam, carbon dioxide, dry chemical powder, water spray or fog to extinguish.
P391 Collect spillage.
Storage:
Store in a well ventilated place. Keep cool. Keep container tightly closed. Store locked up.
Disposal:
Dispose of contents/container in accordance with applicable regional, national and local laws and regulations.
Note:
1-5 . % of the mixture consists of ingredient(s) of unknown acute toxicity.
Classification
Flammable liquid - Category 3; Skin irritation - Category 2; Eye irritation - Category 2A; Germ cell mutagenicity - Category 1B; Carcinogenicity - Category 1B; Specific target organ toxicity (single exposure) - Category 3; Specific target organ toxicity (repeated exposure) - Category 2; Aspiration hazard - Category 1; Aquatic hazard (Chronic) - Category 2
SDS No.:
Date of Preparation:
Page of 1101
August 21, 2017
Product Identifier: Paint Thinner - Ver. 1
June 06, 2019Date of Last Revision:
Hazard Statement(s):
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 + H320 Causes skin and eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects.
H350 May cause cancer.
H373 May cause damage to organs (nervous system) through prolonged or repeated exposure if inhaled.
H411 Toxic to aquatic life with long lasting effects.
Precautionary Statement(s):
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical, ventilating, and lighting equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe fume, mist, vapours, spray.
P264 Wash hands and skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves, eye protection, face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE or doctor.
P331 Do NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P312 Call a POISON CENTRE or doctor if you feel unwell.
P332 + P313 If skin irritation occurs: Get medical advice or attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTRE or doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTRE or doctor if you feel unwell.
P337 + P313 If eye irritation persists: Get medical advice or attention.
P370 + P378 In case of fire: Use appropriate foam, carbon dioxide, dry chemical powder, water spray or fog to extinguish.
P391 Collect spillage.
Storage:
Store in a well ventilated place. Keep cool. Keep container tightly closed. Store locked up.
Disposal:
Dispose of contents/container in accordance with applicable regional, national and local laws and regulations.
Note:
1-5 . % of the mixture consists of ingredient(s) of unknown acute toxicity. SDS No.:
Date of Preparation:
Page of 1102
August 21, 2017
1-5 . % of the mixture consists of ingredient(s) of unknown acute toxicity.
Other Hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Other Identifiers%
Mixture:
Other Names
Stoddard solvent 8052-41-3 80-100 n-Nonane 111-84-2 Constiuent Contained in Complex Mixture
1-5
1,2,4-Trimethylbenzene 95-63-6 Constiuent Contained in Complex Mixture
1-5
Naphthalene 91-20-3 Constiuent Contained in Complex Mixture
0.1-1
Xylene (mixed isomers) 1330-20-7 Constiuent Contained in Complex Mixture
0.1-1
Ethylbenzene 100-41-4 Constiuent Contained in Complex Mixture
0.1-1
Notes
Use of Generic SDS:
If the concentration or actual concentration range of an ingredient of a particular hazardous product in the series is different from the concentration or actual concentration range disclosed for the rest of the series, either the concentration or the actual concentration range must be indicated beside that ingredient under item 3 (Composition/Information on ingredients) of the SDS. Furthermore, if any other specific information element(s) (such as flash point, numerical measure of toxicity, etc.) for a particular hazardous product in the series differs from that of the other products in the series (without affecting the classification), the information element relevant to that hazardous product must be disclosed on the SDS with an indication to which hazardous product each relates.
Source: Health Canada - Technical Guidance on the Requirements of the Hazardous Products Act and the Hazardous Products Regulations WHMIS 2015 Supplier Requirements - pg 117
Inhalation
Take precautions to ensure your own safety before attempting rescue (e.g. wear appropriate protective equipment).
Remove source of exposure or move to fresh air. Keep at rest in a position comfortable for breathing. Call a Poison Centre or doctor if you feel unwell.
Skin Contact
Avoid direct contact. Wear chemical protective clothing if necessary. Take off contaminated clothing, shoes and leather goods (e.g. watchbands, belts). Wash gently and thoroughly with lukewarm, gently flowing water and mild soap for 5 minutes. Call a Poison Centre or doctor if you feel unwell. If skin irritation occurs, get medical advice or attention. Thoroughly clean clothing, shoes and leather goods before reuse or dispose of safely.
Eye Contact
Avoid direct contact. Wear chemical protective gloves if necessary. Quickly and gently blot or brush chemical off the face. Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding the eyelid(s) open. Remove contact lenses, if present and easy to do. Take care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists, get medical advice or attention.
SECTION 4. FIRST-AID MEASURES
First-aid Measures
SDS No.:
Date of Preparation:
Page of 1103
August 21, 2017 holding the eyelid(s) open. Remove contact lenses, if present and easy to do. Take care not to rinse contaminated water into the unaffected eye or onto the face. If eye irritation persists, get medical advice or attention.
Ingestion
Do not induce vomiting. Rinse mouth with water. Never give anything by mouth if person is rapidly losing consciousness, or is unconscious or convulsing. Do not induce vomiting. If vomiting occurs naturally, lie on your side in the recovery position. Rinse mouth with water again. If breathing has stopped, trained personnel should immediately begin rescue breathing. Immediately call a Poison Centre or doctor.
Special Instructions
No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Immediate Medical Attention and Special Treatment
Medical Conditions Aggravated by Exposure
Dermatitis.
Target Organs
Eyes, skin, respiratory system.
Most Important Symptoms and Effects, Acute and Delayed
No specific treatment. Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Extinguishing Media
Suitable Extinguishing Media
Carbon dioxide, dry chemical powder, appropriate foam, water spray or fog.
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Product
Flammable liquid and vapour. Can ignite at room temperature. Releases vapour that can form explosive mixture with air. Can be ignited by static discharge. Can accumulate static charge by flow, splashing or agitation. Liquid can float on water and may travel to distant locations and/or spread fire. See Section 9 (Physical and Chemical Properties) for flash point and explosive limits. Closed containers may rupture violently when heated releasing contents.
In a fire, the following hazardous materials may be generated: irritating chemicals; toxic chemicals; very toxic carbon monoxide, carbon dioxide.
Special Protective Equipment and Precautions for Fire-fighters
Review Section 6 (Accidental Release Measures) for important information on responding to leaks/spills.
See Skin Protection in Section 8 (Exposure Controls/Personal Protection) for advice on suitable chemical protective materials.
SECTION 5. FIRE-FIGHTING MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
No special precautions are necessary. Evacuate downwind locations. Use the personal protective equipment recommended in Section 8 of this safety data sheet. Increase ventilation to area or move leaking container to a well-ventilated and secure area. Eliminate all ignition sources. Use grounded, explosion-proof equipment.
Environmental Precautions
Do not allow into any sewer, on the ground or into any waterway.
Methods and Materials for Containment and Cleaning Up
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal.
SECTION 6. ACCIDENTAL RELEASE MEASURES
SDS No.:
Date of Preparation:
Page of 1104
August 21, 2017 explosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section 13 for waste disposal.
Precautions for Safe Handling
Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.
Conditions for Safe Storage
Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
SECTION 7. HANDLING AND STORAGE
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ACGIH TLV® OSHA PEL
Chemical Name TWA STEL TWA Ceiling
Control Parameters
AIHA WEEL
8-hr TWA TWA
Stoddard solvent 100 ppm Not established
100 ppm Not established
Naphthalene 10 ppm A3 Not established
10 ppm 15 ppm n-Nonane 200 ppm Not established
200 ppm Not established
1,2,4-Trimethylbenzene 25 ppm Not established
25 ppm Not established
Xylene (mixed isomers) 100 ppm 150 ppm 100 ppm 150 ppm
Ethylbenzene 100 ppm 125 ppm 100 ppm 125 ppm
Appropriate Engineering Controls
Individual Protection Measures
Skin Protection
Respiratory Protection
Eye/Face Protection
Not normally required if product is used as directed. For non-routine or emergency situations: wear a NIOSH approved air-purifying respirator with an appropriate cartridge.
Wear chemical protective clothing e.g. gloves, aprons, boots.
Wear chemical safety goggles.
General ventilation is usually adequate. For large scale use of this product: use local exhaust ventilation, if general ventilation is not adequate to control amount in the air. Use non-sparking ventilation systems, approved explosion-proof equipment and intrinsically safe electrical systems in areas where this product is used and stored. Control static electricity discharges which includes bonding of equipment to ground. Use only non-combustible, compatible materials for walls, floors, ventilation system, air cleaning devices, pallets, shelving. Provide eyewash and safety shower if contact or splash hazard exists.
SDS No.:
Date of Preparation:
Page of 1105
August 21, 2017
Respiratory Protection
Not normally required if product is used as directed. For non-routine or emergency situations: wear a NIOSH approved air-purifying respirator with an appropriate cartridge.
pH Not available
Appearance Available in these colours: Clear, Yellow, Gold, Red, Blue, Green, Amber, Pink, Orange, Purple, White, Brown, Grey, Teal.
Partition Coefficient, n-Octanol/Water (Log Kow)
Not available
Odour Hydrocarbon
Vapour Pressure 3.98 - 4.50 mm Hg (0.53 - 0.60 kPa) at 25 ºC
Odour Threshold Not available
Vapour Density (air = 1) 5
Initial Boiling Point/Range 159 - 195 ºC (318 - 383 ºF)
Evaporation Rate 0.1 (n-butyl acetate = 1)
Flash Point 43 ºC (109 ºF) (closed cup)
Melting Point/Freezing Point -76 ºC (-105 ºF) (melting); -76 ºC (-105 ºF) (freezing)
Relative Density (water = 1) 0.788 at 15 ºC
Upper/Lower Flammability or Explosive Limit
5.6% (upper); 0.8% (lower)
Solubility Insoluble in water; Not available (in other liquids)
Auto-ignition Temperature 260 ºC (500 ºF)
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Molecular Weight Not applicable
Not availableDecomposition Temperature
Viscosity 1.21 centistokes at 25 ºC (kinematic); Not available (dynamic)
Other Physical Property 1 Additional Appearance: Clear Yellow Liquid
Basic Physical and Chemical Properties
LiquidPhysical State Other Information
Flammability (solid, gas) Not applicable
Chemical Stability
Normally stable.
Conditions to Avoid
Open flames, sparks, static discharge, heat and other ignition sources. Temperatures above 43.0 ºC (109.4 ºF)
Incompatible Materials
Reacts explosively with: strong oxidizing agents (e.g. perchloric acid).
Not corrosive to metals.
Hazardous Decomposition Products
None known.
Possibility of Hazardous Reactions
None known.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
None known.
SDS No.:
Date of Preparation:
Page of 1106
August 21, 2017
LC50: Not applicable.
LD50 (oral): Not applicable.
Skin Corrosion/Irritation
Animal tests show moderate or severe irritation.
Serious Eye Damage/Irritation
Human experience shows mild irritation. The vapour also irritates the eyes.
SECTION 11. TOXICOLOGICAL INFORMATION
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
May cause depression of the central nervous system. Symptoms may include headache, nausea, dizziness, drowsiness and confusion. Nose and throat irritation. At high concentrations.
Skin Absorption
No information was located.
Ingestion
Not harmful based on animal tests.
Causes damage to organs based on studies in people. If inhaled: effects similar to STOT (Specific Target Organ Toxicity) - Single Exposure, as described above, effects on the central nervous system, "organic solvent syndrome".
Causes Following skin contact: dermatitis. Symptoms may include dry, red, cracked skin (dermatitis). effects similar to STOT (Specific Target Organ Toxicity) - Single Exposure, as described above.
May cause damage to organs based on limited evidence. If inhaled and/or following skin contact: at high concentrations harmful effects on the kidneys, harmful effects on the liver.
May cause damage to organs based on limited evidence. If inhaled and/or following skin contact: blood tests may show abnormal results.
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
No information was located. No information was located.
Carcinogenicity
LD50 (dermal): Not applicable.
Acute Toxicity
Can cause lung damage if aspirated based on human experience. Death can result.
Aspiration Hazard
Skin contact; eye contact; inhalation.
Likely Routes of Exposure
Chemical Name LC50 LD50 (oral) LD50 (dermal)
Stoddard solvent > 5500 mg/m3 (rat) (4-hour exposure)
5000 mg/kg (rat) > 3000 mg/kg (rabbit)
Naphthalene 739.2 mg/m3 (rat) (4-hour exposure)
316 mg/kg (mouse) > 20000 mg/kg (rabbit) n-Nonane 3200 ppm (rat) (4-hour exposure)
15 g/kg (rat) Not available
1,2,4-Trimethylbenzene 18000 mg/m3 (rat) 5000 mg/kg (rat) Not available
Xylene (mixed isomers) 6350 mg/m3 (male rat) (4-hour exposure)
3523 mg/kg (rat) > 1700 mg/kg (rabbit)
Ethylbenzene 4400 ppm (rat) (4-hour exposure)
3500 mg/kg (rat) 15380 mg/kg (rabbit)
Chemical Name IARC ACGIH® NTP OSHA
SDS No.:
Date of Preparation:
Page of 1107
August 21, 2017
Development of Offspring
Conclusions cannot be drawn from the limited studies available.
Reproductive Toxicity
No information was located.
Germ Cell Mutagenicity
May be mutagenic based on limited evidence. (Stoddard solvent)
Interactive Effects
No information was located.
Sexual Function and Fertility
Effects on or via Lactation
No information was located.
Stoddard solvent Group 3 Not designated Not Listed Not Listed
Naphthalene Group 2B A3 Reasonably anticipated
Not Listed n-Nonane Not Listed Not designated Not Listed Not Listed
1,2,4-Trimethylbenzene Not Listed Not designated Not Listed Not Listed
Xylene (mixed isomers) Group 3 A4 Not Listed Not Listed
Ethylbenzene Group 2B A3 Not Listed Not Listed
SECTION 12. ECOLOGICAL INFORMATION
This section is not required by WHMIS.
This section is not required by OSHA HCS 2012.
Ecotoxicity
Persistence and Degradability
Chronic Aquatic Toxicity
Acute Aquatic Toxicity
Chemical Name LC50 Fish EC50 Crustacea ErC50 Aquatic Plants
ErC50 Algae
Stoddard solvent Not available Not available
Naphthalene 0.9-9.8 mg/L (Oncorhynchus mykiss (rainbow trout); 96-hour; fresh water)
Not available n-Nonane Not available Not available
1,2,4-Trimethylbenzene 7.72 mg/L (Pimephales promelas (fathead minnow); 96-hour)
Not available
Xylene (mixed isomers) 13.4 mg/L (Oncorhynchus mykiss (rainbow trout); 96-hour; fresh water)
150 mg/L (Daphnia magna (water flea))
Ethylbenzene 88.00 mg/L (Pimephales promelas (fathead minnow); 96-hour)
2.90 mg/L (Daphnia magna (water flea);
48-hour)
Chemical Name NOEC Fish EC50 Fish NOEC Crustacea EC50 Crustacea
SDS No.:
Date of Preparation:
Page of 1108
August 21, 2017
No information was located.
No information was located.
There is no information available.
No information was located.
Persistence and Degradability
Mobility in Soil
Other Adverse Effects
Bioaccumulative Potential
Stoddard solvent Not available Not available
Naphthalene 1.8 mg/L (Oncorhynchus mykiss (rainbow trout); 3 days; fresh water)
Not available n-Nonane Not available Not available
1,2,4-Trimethylbenzene Not available Not available
Xylene (mixed isomers) Not available Not available
Ethylbenzene Not available Not available
SECTION 13. DISPOSAL CONSIDERATIONS
The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Disposal Methods
SECTION 14. TRANSPORT INFORMATION
UN No. Proper Shipping Name Packing Group
Transport Hazard Class(es)
Regulation
1268 PETROLEUM DISTILLATES, N.O.S. 3 IIICanadian TDG
1268 PETROLEUM DISTILLATES, N.O.S. 3 IIIUS DOT
1268 PETROLEUM DISTILLATES, N.O.S. 3 IIIIMO (Marine)
Special Precautions Please note: In containers of 450 L or less this product is not classified as a Dangerous Good according to TDG Exemption 1.33 In containers of 450L of less, this product meets the requirements of DOT exemption as per 49 CFR, section 173.150 (f).
Environmental Hazards
Potential Marine Pollutant (1,2,4-Trimethylbenzene)
Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
Proof of Dangerous Goods Classification
PETROLEUM DISTILLATES, N.O.S.
Date of Classification
Technical Name
January 13, 2017
Flashpoint as per Section 9
Classification 3 PG III
Classification Method
SDS No.:
Date of Preparation:
Page of 1109
August 21, 2017
SECTION 15. REGULATORY INFORMATION
Canada
Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL)
All ingredients are listed on the DSL/NDSL.
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are listed on the TSCA Inventory.
Additional USA Regulatory Lists
California Proposition 65:
WARNING: Cancer - www.P65Warnings.ca.gov/product.
Custom Regulatory 1
Consumer Product Safety Improvement Act of 2008 General Conformity Certification The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product container.
Safety, Health and Environmental Regulations
References CHEMINFO database. Canadian Centre for Occupational Health and Safety (CCOHS).
Additional Information We are committed to uphold the Industry Consumer Ingredient Communication Voluntary Initiative.
Please send us your request by visiting our website at www.recochem.com.
Ingredients present (intentionally added ingredients) at a concentration of greater than one percent (1%) shall be listed in descending order of predominance. Ingredients present at a concentration of not more than one percent shall be listed but may be disclosed without respect to order of predominance.
Disclaimer Notice to reader: To the best of our knowledge, the information contained herein is accurate.
However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
SECTION 16. OTHER INFORMATION
SDS Prepared By Compliance and Regulatory Department
Phone No. 905-878-5544
Date of Preparation August 21, 2017
Revision Indicators The following SDS content was changed on January 10, 2019:
SECTION 1. IDENTIFICATION; Other Means of Identification.
The following SDS content was changed on January 14, 2019:
SECTION 1. IDENTIFICATION; Other Means of Identification.
The following SDS content was changed on February 05, 2019:
SECTION 1. IDENTIFICATION; Other Means of Identification.
The following SDS content was changed on February 06, 2019:
SECTION 14. TRANSPORT INFORMATION; Shipping Information.
The following SDS content was changed on February 12, 2019:
SECTION 1. IDENTIFICATION; Other Means of Identification.
The following SDS content was changed on June 06, 2019:
SECTION 1. IDENTIFICATION; Other Means of Identification.
June 06, 2019Date of Last Revision
SDS No.:
Date of Preparation:
Page of 1110
August 21, 2017
Disclaimer may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
SDS No.:
Date of Preparation:
Page of 1111
August 21, 2017
Safety Data Sheet: Simple Green® All-Purpose Cleaner Version No. 13000-23A Issue Date: January 1, 2023 Supersedes Date: February 1, 2021 OSHA HCS-2012 / GHS
Section 1: IDENTIFICATION
Product Name: Simple Green® All-Purpose Cleaner Additional Names:
Manufacturer’s Part Number: *Please refer to Section 16
Recommended Use: Cleaner & Degreaser for water tolerant surfaces.
Restrictions on Use: Do not use on non-rinseable surfaces.
Company: Sunshine Makers, Inc.
15922 Pacific Coast Highway Huntington Beach, CA 92649 USA
Telephone: 800-228-0709 ● 562-795-6000 Mon – Fri, 8am – 5pm PST Fax: 562-592-3830 Email: info@simplegreen.com
Emergency Phone: Chem-Tel 24-Hour Emergency Service: 800-255-3924
Section 2: HAZARDS IDENTIFICATION
This product is not considered hazardous under 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
OSHA HCS 2012
Label Elements Signal Word: None Hazard Symbol(s)/Pictogram(s): None required Hazard Statements: None Precautionary Statements: None Hazards Not Otherwise Classified (HNOC): None Other Information: None Known
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS Number Percent Range
Water 7732-18-5 > 85.000%* Surfactant Proprietary < 5.000%* C9-11 Alcohols Ethoxylated 68439-46-3 < 5.000%* Tetrasodium Glutamate Diacetate 51981-21-6 < 2.000%* Sodium Bicarbonate 144-55-8 < 1.000%* Hydrochloric Acid 7647-01-0 < 1.000%* Blend of Polyoxyalkylene Substituted Chromophores (Cyan and Yellow) Proprietary Mixture < 0.100%* Fragrances Proprietary Mixture < 1.000%* Anethole 104-46-1 < 0.100%* Eucalyptol 470-82-6 < 0.100%* Methylchloroisothiazolinone 26172-55-4 < 0.001%* Methylisothiazolinone 2682-20-4 < 0.0001%*
*specific percentages of composition are being withheld as a trade secret
Section 4: FIRST-AID MEASURES
Inhalation: Not expected to cause respiratory irritation. If adverse effect occurs, move to fresh air.
Skin Contact: Not expected to cause skin irritation. If adverse effect occurs, rinse skin with water.
Eye Contact: Not expected to cause eye irritation. If adverse effect occurs, flush eyes with water.
Ingestion: May cause upset stomach. Drink plenty of water to dilute. See section 11.
Most Important Symptoms/Effects, Acute and Delayed: None known.
Section 4: FIRST-AID MEASURES - continued mailto:info@simplegreen.com
Version No. 13000-23A Issue Date: January 1, 2023 Supersedes Date: February 1, 2021 OSHA HCS-2012 / GHS
Indication of Immediate Medical Attention and Special Treatment Needed, if necessary: Treat symptomatically
Section 5: FIRE-FIGHTING MEASURES
Suitable & Unsuitable Extinguishing Media: Use Dry chemical, CO2, water spray or “alcohol” foam. Avoid high volume jet water.
Specific Hazards Arising from Chemical: In event of fire, fire created carbon oxides may be formed.
Special Protective Actions for Fire-Fighters: Wear positive pressure self-contained breathing apparatus; Wear full protective clothing.
This product is non-flammable. See Section 9 for Physical Properties.
Section 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures: For non-emergency and emergency personnel: See section 8 – personal protection. Avoid eye contact. Safety goggles suggested.
Environmental Precautions: Do not…
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