10-LEACHATE SAMPLING.pdf

#=CL#

September 13, 2024

LIMS USE: FR - LISA SAUPP

LIMS OBJECT ID: 35901688

35901688 Project:

Pace Project No.:

RE:

Lisa Saupp Aqua Pure W&SS, LLC 3855 East Silver Springs Blvd Unit #107 Ocala, FL 34470

Baseline LF Leachate

Dear Lisa Saupp:

Enclosed are the analytical results for sample(s) received by the laboratory on August 27, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.

The test results provided in this final report were generated by each of the following laboratories within the Pace Network:

• Pace National - Mt. Juliet

• Pace Analytical Services - Charlotte

• Pace Analytical Services - Ormond Beach

If you have any questions concerning this report, please feel free to contact me.

Sincerely, Jeff Baylor jeff.baylor@pacelabs.com

Project Manager (386)672-5668

Enclosures

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174 (386)672-5668

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CERTIFICATIONS

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Pace Analytical Services Ormond Beach 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 California Certification# 3096 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity DoD-ANAB #:ADE-3199 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maine Certification #: FL01264 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236

Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Ohio DEP 87780 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Utah FL NELAC Reciprocity Utah Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity

Pace Analytical Services National 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01

EPA# TN00003

Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: AI30792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324

Massachusetts Certification #: M-TN003 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification #: CERT0086 Nebraska Certification #: NE-OS-15-05 Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TN002 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LAO00356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

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CERTIFICATIONS

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Pace Analytical Services National Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Virginia Certification #: VT2006 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: 460132 Washington Certification #: C847

West Virginia Certification #: 233 Wisconsin Certification #: 998093910 Wyoming UST Certification #: via A2LA 2926.01 A2LA-ISO 17025 Certification #: 1461.01 A2LA-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789

Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006

South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

#=SS#

SAMPLE SUMMARY

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Lab ID Sample ID Matrix Date Collected Date Received

35901688001 L-1 Water 08/26/24 16:18 08/27/24 12:55

35901688002 Trip Blank Water 08/26/24 00:01 08/27/24 12:55

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

#=SA#

SAMPLE ANALYTE COUNT

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts

35901688001 L-1 EPA 8141B 6 PANNWH

EPA 8151A 6 PANHMH

EPA 8011 2 PASI-OSCL

EPA 8081 21 PASI-OBLM

EPA 8082 9 PASI-OCB1

EPA 6010 15 PASI-OAF

EPA 6020 3 PASI-OBSL

EPA 7470 1 PASI-OJNK

EPA 8270E 113 PASI-CPKS

EPA 8260 61 PASI-OAST

SM 2320B 1 PASI-OMCD

SM 2540C 1 PASI-OVAG

SM 4500-S2F 1 PASI-OJJB

EPA 300.0 1 PASI-OCMB

EPA 300.0 1 PASI-OEAD

EPA 350.1 1 PASI-OKW1

EPA 9012 1 PASI-OJH2

35901688002 Trip Blank EPA 8260 63 PASI-OAST

PAN = Pace National - Mt. Juliet PASI-C = Pace Analytical Services - Charlotte PASI-O = Pace Analytical Services - Ormond Beach

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

#=AR#

ANALYTICAL RESULTS

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Sample: L-1 Lab ID: 35901688001 Collected: 08/26/24 16:18 Received: 08/27/24 12:55 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Comments: • Chlorinated Acid Herbicides (GC) by Method 8151A - Dilution due to matrix impact during extraction procedure.

Analytical Method:

Pace Analytical Services - Ormond Beach

Field Data

Field pH 7.62 Std. Units 08/26/24 16:181 Field Temperature 29.2 deg C 08/26/24 16:181 Field Specific Conductance 14100 umhos/cm 08/26/24 16:181 Oxygen, Dissolved 0.05 mg/L 08/26/24 16:18 7782-44-71 Turbidity 12.2 NTU 08/26/24 16:181

Analytical Method: EPA 8141B Preparation Method: 3510C Pace National - Mt. Juliet

OP Pesticides 8141B

Dimethoate 0.000327 U mg/L 09/03/24 19:49 60-51-509/01/24 18:300.00100 0.000327 1

Disulfoton 0.000227 U mg/L 09/03/24 19:49 298-04-409/01/24 18:300.00100 0.000227 1

Methyl parathion 0.000383 U mg/L 09/03/24 19:49 298-00-009/01/24 18:300.00100 0.000383 1

Parathion (Ethyl parathion) 0.000454 U mg/L 09/03/24 19:49 56-38-209/01/24 18:300.00100 0.000454 1

Phorate 0.000276 U mg/L 09/03/24 19:49 298-02-209/01/24 18:300.00100 0.000276 1

Surrogates Triphenylphosphate (S) 42.9 % 09/03/24 19:49 115-86-609/01/24 18:3042.0-129 1

Analytical Method: EPA 8151A Preparation Method: 8151A Pace National - Mt. Juliet

Chlorinated Herb. (GC) 8151A

2,4,5-T 0.00246 U mg/L 09/03/24 06:36 93-76-5 J(L0), J(T3)

08/31/24 09:080.0190 0.00246 9.52

2,4,5-TP (Silvex) 0.00319 U mg/L 09/03/24 06:36 93-72-1 J(T3)08/31/24 09:080.0190 0.00319 9.52 2,4-D 0.00521 U mg/L 09/03/24 06:36 94-75-7 J(L0), J(T3) 08/31/24 09:080.0190 0.00521 9.52

Dinoseb 0.00238 U mg/L 09/03/24 06:36 88-85-7 J(T3)08/31/24 09:080.0190 0.00238 9.52 Pentachlorophenol 0.00106 U mg/L 09/03/24 06:36 87-86-5 J(T3)08/31/24 09:080.00952 0.00106 9.52 Surrogates

2,4-DCAA (S) 60.3 % 09/03/24 06:36 19719-28-908/31/24 09:0814.0-158 9.52

Analytical Method: EPA 8011 Preparation Method: EPA 8011 Pace Analytical Services - Ormond Beach

8011 GCS EDB and DBCP

1,2-Dibromo-3-chloropropane 0.0065 U ug/L 08/30/24 05:55 96-12-808/29/24 15:430.020 0.0065 1 1,2-Dibromoethane (EDB) 0.0076 U ug/L 08/30/24 05:55 106-93-408/29/24 15:430.010 0.0076 1

Analytical Method: EPA 8081 Preparation Method: EPA 3510 Pace Analytical Services - Ormond Beach

8081 GCS Pesticides

Aldrin 0.0090 U ug/L 09/06/24 10:02 309-00-2 1p08/28/24 04:200.0098 0.0090 1 alpha-BHC 0.0020 U ug/L 09/06/24 10:02 319-84-6 1p08/28/24 04:200.0098 0.0020 1 beta-BHC 0.020 U ug/L 09/06/24 10:02 319-85-7 1p08/28/24 04:200.029 0.020 1 delta-BHC 0.0097 U ug/L 09/06/24 10:02 319-86-8 1p08/28/24 04:200.0098 0.0097 1 gamma-BHC (Lindane) 0.0052 U ug/L 09/06/24 10:02 58-89-9 1p08/28/24 04:200.0098 0.0052 1 Chlordane (Technical) 0.24 U ug/L 09/06/24 10:02 57-74-9 1p08/28/24 04:200.49 0.24 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Sample: L-1 Lab ID: 35901688001 Collected: 08/26/24 16:18 Received: 08/27/24 12:55 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Comments: • Chlorinated Acid Herbicides (GC) by Method 8151A - Dilution due to matrix impact during extraction procedure.

Analytical Method: EPA 8081 Preparation Method: EPA 3510 Pace Analytical Services - Ormond Beach

8081 GCS Pesticides

4,4'-DDD 0.0026 U ug/L 09/06/24 10:02 72-54-8 1p08/28/24 04:200.0098 0.0026 1 4,4'-DDE 0.0049 U ug/L 09/06/24 10:02 72-55-9 1p08/28/24 04:200.0098 0.0049 1 4,4'-DDT 0.0050 U ug/L 09/06/24 10:02 50-29-3 1p08/28/24 04:200.0098 0.0050 1 Dieldrin 0.0020 U ug/L 09/06/24 10:02 60-57-1 1p08/28/24 04:200.0098 0.0020 1 Endosulfan I 0.0050 U ug/L 09/06/24 10:02 959-98-8 1p08/28/24 04:200.0098 0.0050 1 Endosulfan II 0.0039 U ug/L 09/06/24 10:02 33213-65-9 1p08/28/24 04:200.0098 0.0039 1 Endosulfan sulfate 0.0026 U ug/L 09/06/24 10:02 1031-07-8 1p08/28/24 04:200.098 0.0026 1 Endrin 0.0042 U ug/L 09/06/24 10:02 72-20-8 1p08/28/24 04:200.0098 0.0042 1 Endrin aldehyde 0.0035 U ug/L 09/06/24 10:02 7421-93-4 1p08/28/24 04:200.098 0.0035 1 Heptachlor 0.0060 U ug/L 09/06/24 10:02 76-44-8 1p08/28/24 04:200.0098 0.0060 1 Heptachlor epoxide 0.0028 U ug/L 09/06/24 10:02 1024-57-3 1p08/28/24 04:200.020 0.0028 1 Methoxychlor 0.0041 U ug/L 09/06/24 10:02 72-43-5 1p08/28/24 04:200.0098 0.0041 1 Toxaphene 0.24 U ug/L 09/06/24 10:02 8001-35-2 1p08/28/24 04:200.49 0.24 1 Surrogates Tetrachloro-m-xylene (S) 49 % 09/06/24 10:02 877-09-808/28/24 04:2027-124 1 Decachlorobiphenyl (S) 10 % 09/06/24 10:02 2051-24-308/28/24 04:2010-132 1

Analytical Method: EPA 8082 Preparation Method: EPA 3510 Pace Analytical Services - Ormond Beach

8082 GCS PCB

PCB-1016 (Aroclor 1016) 0.19 U ug/L 09/11/24 09:35 12674-11-2 1p08/28/24 04:220.49 0.19 1 PCB-1221 (Aroclor 1221) 0.23 U ug/L 09/11/24 09:35 11104-28-2 1p08/28/24 04:220.49 0.23 1 PCB-1232 (Aroclor 1232) 0.30 U ug/L 09/11/24 09:35 11141-16-5 1p08/28/24 04:220.49 0.30 1 PCB-1242 (Aroclor 1242) 0.12 U ug/L 09/11/24 09:35 53469-21-9 1p08/28/24 04:220.49 0.12 1 PCB-1248 (Aroclor 1248) 0.27 U ug/L 09/11/24 09:35 12672-29-6 1p08/28/24 04:220.49 0.27 1 PCB-1254 (Aroclor 1254) 0.14 U ug/L 09/11/24 09:35 11097-69-1 1p08/28/24 04:220.49 0.14 1 PCB-1260 (Aroclor 1260) 0.11 U ug/L 09/11/24 09:35 11096-82-5 1p08/28/24 04:220.49 0.11 1 Surrogates Tetrachloro-m-xylene (S) 39 % 09/11/24 09:35 877-09-808/28/24 04:2221-126 1 Decachlorobiphenyl (S) 11 % 09/11/24 09:35 2051-24-308/28/24 04:2210-140 1

Analytical Method: EPA 6010 Preparation Method: EPA 3010 Pace Analytical Services - Ormond Beach

6010 MET ICP

Barium 76.0 ug/L 09/03/24 16:11 7440-39-308/29/24 12:1010.0 0.84 1 Beryllium 0.17 U ug/L 09/03/24 16:11 7440-41-708/29/24 12:104.0 0.17 1 Cadmium 0.33 U ug/L 09/03/24 16:15 7440-43-908/29/24 12:101.0 0.33 1 Chromium 49.4 ug/L 09/03/24 16:15 7440-47-308/29/24 12:105.0 1.7 1 Cobalt 19.6 ug/L 09/03/24 16:15 7440-48-408/29/24 12:1010.0 0.96 1 Copper 3.6 I ug/L 09/03/24 16:15 7440-50-808/29/24 12:105.0 2.6 1 Iron 14500 ug/L 09/03/24 16:15 7439-89-608/29/24 12:1040.0 25.0 1 Lead 2.1 U ug/L 09/03/24 16:15 7439-92-108/29/24 12:1010.0 2.1 1 Nickel 57.7 ug/L 09/03/24 16:15 7440-02-008/29/24 12:105.0 1.0 1 Selenium 3.9 U ug/L 09/03/24 16:11 7782-49-208/29/24 12:1015.0 3.9 1 Silver 1.0 U ug/L 09/03/24 16:15 7440-22-408/29/24 12:105.0 1.0 1 Sodium 591 mg/L 09/03/24 16:14 7440-23-508/29/24 12:1020.0 5.4 10

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Sample: L-1 Lab ID: 35901688001 Collected: 08/26/24 16:18 Received: 08/27/24 12:55 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Comments: • Chlorinated Acid Herbicides (GC) by Method 8151A - Dilution due to matrix impact during extraction procedure.

Analytical Method: EPA 6010 Preparation Method: EPA 3010 Pace Analytical Services - Ormond Beach

6010 MET ICP

Tin 17.1 I ug/L 09/03/24 16:15 7440-31-508/29/24 12:1050.0 16.0 1 Vanadium 10.5 ug/L 09/03/24 16:15 7440-62-208/29/24 12:1010.0 1.0 1 Zinc 26.9 ug/L 09/03/24 16:15 7440-66-608/29/24 12:1020.0 11.0 1

Analytical Method: EPA 6020 Preparation Method: EPA 3010 Pace Analytical Services - Ormond Beach

6020 MET ICPMS

Antimony 27.7 ug/L 09/13/24 10:36 7440-36-008/29/24 12:102.0 1.0 2 Arsenic 126 ug/L 09/13/24 10:36 7440-38-208/29/24 12:102.0 1.0 2 Thallium 0.21 U ug/L 09/13/24 10:36 7440-28-0 D308/29/24 12:102.0 0.21 2

Analytical Method: EPA 7470 Preparation Method: EPA 7470 Pace Analytical Services - Ormond Beach

7470 Mercury

Mercury 0.28 U ug/L 09/11/24 09:40 7439-97-6 D309/10/24 11:020.40 0.28 1

Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte

8270E APP9 RV

Acenaphthene 10.0 U ug/L 09/05/24 13:31 83-32-9 Q09/04/24 23:2350.0 10.0 5 Acenaphthylene 9.8 U ug/L 09/05/24 13:31 208-96-8 Q09/04/24 23:2350.0 9.8 5 Acetophenone 10.5 I ug/L 09/05/24 13:31 98-86-2 Q09/04/24 23:2350.0 7.5 5 2-Acetylaminofluorene 20.4 U ug/L 09/05/24 13:31 53-96-3 Q09/04/24 23:2350.0 20.4 5 4-Aminobiphenyl 23.7 U ug/L 09/05/24 13:31 92-67-1 Q09/04/24 23:2350.0 23.7 5 Anthracene 11.6 U ug/L 09/05/24 13:31 120-12-7 Q09/04/24 23:2350.0 11.6 5 Benzo(a)anthracene 13.4 U ug/L 09/05/24 13:31 56-55-3 Q09/04/24 23:2350.0 13.4 5 Benzo(a)pyrene 13.9 U ug/L 09/05/24 13:31 50-32-8 Q09/04/24 23:2350.0 13.9 5 Benzo(b)fluoranthene 13.0 U ug/L 09/05/24 13:31 205-99-2 Q09/04/24 23:2350.0 13.0 5 Benzo(g,h,i)perylene 14.2 U ug/L 09/05/24 13:31 191-24-2 Q09/04/24 23:2350.0 14.2 5 Benzo(k)fluoranthene 13.6 U ug/L 09/05/24 13:31 207-08-9 Q09/04/24 23:2350.0 13.6 5 Benzyl alcohol 14.5 U ug/L 09/05/24 13:31 100-51-6 Q09/04/24 23:23100 14.5 5 4-Bromophenylphenyl ether 8.8 U ug/L 09/05/24 13:31 101-55-3 Q09/04/24 23:2350.0 8.8 5 Butylbenzylphthalate 15.7 U ug/L 09/05/24 13:31 85-68-7 Q09/04/24 23:2350.0 15.7 5 4-Chloro-3-methylphenol 16.7 U ug/L 09/05/24 13:31 59-50-7 J(M1),Q09/04/24 23:2350.0 16.7 5 4-Chloroaniline 18.2 U ug/L 09/05/24 13:31 106-47-8 Q09/04/24 23:23100 18.2 5 Chlorobenzilate 18.9 U ug/L 09/05/24 13:31 510-15-6 Q09/04/24 23:2350.0 18.9 5 bis(2-Chloroethoxy)methane 9.1 U ug/L 09/05/24 13:31 111-91-1 Q09/04/24 23:2350.0 9.1 5 bis(2-Chloroethyl) ether 9.6 U ug/L 09/05/24 13:31 111-44-4 Q09/04/24 23:2350.0 9.6 5 2-Chloronaphthalene 8.6 U ug/L 09/05/24 13:31 91-58-7 Q09/04/24 23:2350.0 8.6 5 2-Chlorophenol 6.0 U ug/L 09/05/24 13:31 95-57-8 Q09/04/24 23:2350.0 6.0 5 4-Chlorophenylphenyl ether 10.0 U ug/L 09/05/24 13:31 7005-72-3 Q09/04/24 23:2350.0 10.0 5 Chrysene 13.8 U ug/L 09/05/24 13:31 218-01-9 Q09/04/24 23:2350.0 13.8 5 Diallate 17.1 U ug/L 09/05/24 13:31 2303-16-4 Q09/04/24 23:2350.0 17.1 5 Dibenz(a,h)anthracene 14.8 U ug/L 09/05/24 13:31 53-70-3 Q09/04/24 23:2350.0 14.8 5 Dibenzofuran 10.5 U ug/L 09/05/24 13:31 132-64-9 Q09/04/24 23:2350.0 10.5 5 1,2-Dichlorobenzene 9.0 U ug/L 09/05/24 13:31 95-50-1 Q09/04/24 23:2350.0 9.0 5 1,3-Dichlorobenzene 8.0 U ug/L 09/05/24 13:31 541-73-1 Q09/04/24 23:2350.0 8.0 5

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Sample: L-1 Lab ID: 35901688001 Collected: 08/26/24 16:18 Received: 08/27/24 12:55 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Comments: • Chlorinated Acid Herbicides (GC) by Method 8151A - Dilution due to matrix impact during extraction procedure.

Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte

8270E APP9 RV

1,4-Dichlorobenzene 8.4 U ug/L 09/05/24 13:31 106-46-7 Q09/04/24 23:2350.0 8.4 5 3,3'-Dichlorobenzidine 40.6 U ug/L 09/05/24 13:31 91-94-1 Q09/04/24 23:23100 40.6 5 2,4-Dichlorophenol 7.0 U ug/L 09/05/24 13:31 120-83-2 Q09/04/24 23:2350.0 7.0 5 2,6-Dichlorophenol 21.1 U ug/L 09/05/24 13:31 87-65-0 Q09/04/24 23:2350.0 21.1 5 Diethylphthalate 10.2 U ug/L 09/05/24 13:31 84-66-2 Q09/04/24 23:2350.0 10.2 5 P-Dimethylaminoazobenzene 12.0 U ug/L 09/05/24 13:31 60-11-7 Q09/04/24 23:2325.0 12.0 5 7,12-Dimethylbenz(a)anthracene 14.8 U ug/L 09/05/24 13:31 57-97-6 Q09/04/24 23:2350.0 14.8 5 3,3'-Dimethylbenzidine 156 U ug/L 09/05/24 13:31 119-93-7 J(M1),Q09/04/24 23:23250 156 5 2,4-Dimethylphenol 8.5 U ug/L 09/05/24 13:31 105-67-9 Q09/04/24 23:2350.0 8.5 5 a,a-Dimethylphenylethylamine 310 U ug/L 09/05/24 13:31 122-09-8 Q09/04/24 23:23500 310 5 Dimethylphthalate 10.6 U ug/L 09/05/24 13:31 131-11-3 Q09/04/24 23:2350.0 10.6 5 Di-n-butylphthalate 11.0 U ug/L 09/05/24 13:31 84-74-2 Q09/04/24 23:2350.0 11.0 5 4,6-Dinitro-2-methylphenol 38.9 U ug/L 09/05/24 13:31 534-52-1 Q09/04/24 23:23100 38.9 5 1,3-Dinitrobenzene 18.8 U ug/L 09/05/24 13:31 99-65-0 Q09/04/24 23:2350.0 18.8 5 2,4-Dinitrophenol 130 U ug/L 09/05/24 13:31 51-28-5 Q09/04/24 23:23250 130 5 2,4-Dinitrotoluene 8.1 U ug/L 09/05/24 13:31 121-14-2 Q09/04/24 23:2350.0 8.1 5 2,6-Dinitrotoluene 8.6 U ug/L 09/05/24 13:31 606-20-2 Q09/04/24 23:2350.0 8.6 5 Di-n-octylphthalate 19.6 U ug/L 09/05/24 13:31 117-84-0 Q09/04/24 23:2350.0 19.6 5 bis(2-Ethylhexyl)phthalate 18.6 U ug/L 09/05/24 13:31 117-81-7 Q09/04/24 23:2330.0 18.6 5 Ethyl methanesulfonate 14.8 U ug/L 09/05/24 13:31 62-50-0 Q09/04/24 23:23100 14.8 5 Famphur 30.6 U ug/L 09/05/24 13:31 52-85-7 Q09/04/24 23:2350.0 30.6 5 Fluoranthene 11.0 U ug/L 09/05/24 13:31 206-44-0 Q09/04/24 23:2350.0 11.0 5 Fluorene 10.4 U ug/L 09/05/24 13:31 86-73-7 Q09/04/24 23:2350.0 10.4 5 Hexachloro-1,3-butadiene 8.8 U ug/L 09/05/24 13:31 87-68-3 Q09/04/24 23:2350.0 8.8 5 Hexachlorobenzene 10.8 U ug/L 09/05/24 13:31 118-74-1 Q09/04/24 23:2350.0 10.8 5 Hexachlorocyclopentadiene 8.0 U ug/L 09/05/24 13:31 77-47-4 Q09/04/24 23:2350.0 8.0 5 Hexachloroethane 6.9 U ug/L 09/05/24 13:31 67-72-1 Q09/04/24 23:2350.0 6.9 5 Hexachlorophene 246 U ug/L 09/05/24 13:31 70-30-4 J(v2), J(v3),Q 09/04/24 23:23500 246 5

Hexachloropropene 13.5 U ug/L 09/05/24 13:31 1888-71-7 Q09/04/24 23:2350.0 13.5 5 Indeno(1,2,3-cd)pyrene 14.4 U ug/L 09/05/24 13:31 193-39-5 Q09/04/24 23:2350.0 14.4 5 Isodrin 13.8 U ug/L 09/05/24 13:31 465-73-6 Q09/04/24 23:2350.0 13.8 5 Isophorone 8.3 U ug/L 09/05/24 13:31 78-59-1 Q09/04/24 23:2350.0 8.3 5 Isosafrole 12.4 U ug/L 09/05/24 13:31 120-58-1 Q09/04/24 23:2350.0 12.4 5 Kepone 70.5 U ug/L 09/05/24 13:31 143-50-0 Q09/04/24 23:23100 70.5 5 Methapyrilene 85.0 U ug/L 09/05/24 13:31 91-80-5 Q09/04/24 23:23250 85.0 5 3-Methylcholanthrene 18.7 U ug/L 09/05/24 13:31 56-49-5 J(L2), J(M0),Q 09/04/24 23:2350.0 18.7 5

Methyl methanesulfonate 15.5 U ug/L 09/05/24 13:31 66-27-3 Q09/04/24 23:2325.0 15.5 5 2-Methylnaphthalene 9.4 U ug/L 09/05/24 13:31 91-57-6 Q09/04/24 23:2350.0 9.4 5 2-Methylphenol(o-Cresol) 9.4 U ug/L 09/05/24 13:31 95-48-7 Q09/04/24 23:2350.0 9.4 5 3&4-Methylphenol(m&p Cresol) 53.3 ug/L 09/05/24 13:31 15831-10-4 Q09/04/24 23:2350.0 6.1 5 1-Naphthalenamine 30.1 U ug/L 09/05/24 13:31 134-32-7 Q09/04/24 23:2350.0 30.1 5 2-Naphthalenamine 27.2 U ug/L 09/05/24 13:31 91-59-8 Q09/04/24 23:2350.0 27.2 5 Naphthalene 10.4 U ug/L 09/05/24 13:31 91-20-3 Q09/04/24 23:2350.0 10.4 5

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Sample: L-1 Lab ID: 35901688001 Collected: 08/26/24 16:18 Received: 08/27/24 12:55 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Comments: • Chlorinated Acid Herbicides (GC) by Method 8151A - Dilution due to matrix impact during extraction procedure.

Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte

8270E APP9 RV

1,4-Naphthoquinone 22.0 U ug/L 09/05/24 13:31 130-15-4 Q09/04/24 23:2325.0 22.0 5 2-Nitroaniline 14.9 U ug/L 09/05/24 13:31 88-74-4 Q09/04/24 23:23100 14.9 5 3-Nitroaniline 18.8 U ug/L 09/05/24 13:31 99-09-2 Q09/04/24 23:23100 18.8 5 4-Nitroaniline 25.5 U ug/L 09/05/24 13:31 100-01-6 Q09/04/24 23:23100 25.5 5 Nitrobenzene 9.4 U ug/L 09/05/24 13:31 98-95-3 Q09/04/24 23:2350.0 9.4 5 2-Nitrophenol 7.0 U ug/L 09/05/24 13:31 88-75-5 Q09/04/24 23:2350.0 7.0 5 4-Nitrophenol 33.0 U ug/L 09/05/24 13:31 100-02-7 Q09/04/24 23:23250 33.0 5 5-Nitro-o-toluidine 19.2 U ug/L 09/05/24 13:31 99-55-8 Q09/04/24 23:2350.0 19.2 5 N-Nitrosodiethylamine 11.6 U ug/L 09/05/24 13:31 55-18-5 Q09/04/24 23:2350.0 11.6 5 N-Nitrosodimethylamine 9.4 U ug/L 09/05/24 13:31 62-75-9 Q09/04/24 23:2350.0 9.4 5 N-Nitroso-di-n-butylamine 9.8 U ug/L 09/05/24 13:31 924-16-3 Q09/04/24 23:2350.0 9.8 5 N-Nitroso-di-n-propylamine 6.6 U ug/L 09/05/24 13:31 621-64-7 Q09/04/24 23:2350.0 6.6 5 N-Nitrosodiphenylamine 15.0 U ug/L 09/05/24 13:31 86-30-6 Q09/04/24 23:2350.0 15.0 5 N-Nitrosomethylethylamine 37.3 U ug/L 09/05/24 13:31 10595-95-6 Q09/04/24 23:2350.0 37.3 5 N-Nitrosomorpholine 21.2 U ug/L 09/05/24 13:31 59-89-2 Q09/04/24 23:2350.0 21.2 5 N-Nitrosopiperidine 12.5 U ug/L 09/05/24 13:31 100-75-4 Q09/04/24 23:2350.0 12.5 5 N-Nitrosopyrrolidine 15.3 U ug/L 09/05/24 13:31 930-55-2 Q09/04/24 23:2350.0 15.3 5 O,O,O-Triethylphosphorothioate 12.8 U ug/L 09/05/24 13:31 126-68-1 Q09/04/24 23:2350.0 12.8 5 2,2'-Oxybis(1-chloropropane) 5.8 U ug/L 09/05/24 13:31 108-60-1 Q09/04/24 23:2350.0 5.8 5 Pentachlorobenzene 17.0 U ug/L 09/05/24 13:31 608-93-5 Q09/04/24 23:2350.0 17.0 5 Pentachloronitrobenzene 16.3 U ug/L 09/05/24 13:31 82-68-8 Q09/04/24 23:2350.0 16.3 5 Pentachlorophenol 18.8 U ug/L 09/05/24 13:31 87-86-5 Q09/04/24 23:23100 18.8 5 Phenacetin 18.0 U ug/L 09/05/24 13:31 62-44-2 Q09/04/24 23:2350.0 18.0 5 Phenanthrene 10.0 U ug/L 09/05/24 13:31 85-01-8 Q09/04/24 23:2350.0 10.0 5 Phenol 91.3 ug/L 09/05/24 13:31 108-95-2 Q09/04/24 23:2350.0 6.8 5 p-Phenylenediamine 50.0 U ug/L 09/05/24 13:31 106-50-3 Q09/04/24 23:2350.0 50.0 5 Pronamide 15.4 U ug/L 09/05/24 13:31 23950-58-5 Q09/04/24 23:2350.0 15.4 5 Pyrene 11.0 U ug/L 09/05/24 13:31 129-00-0 Q09/04/24 23:2350.0 11.0 5 Safrole 11.6 U ug/L 09/05/24 13:31 94-59-7 Q09/04/24 23:2350.0 11.6 5 1,2,4,5-Tetrachlorobenzene 22.3 U ug/L 09/05/24 13:31 95-94-3 Q09/04/24 23:2350.0 22.3 5 2,3,4,6-Tetrachlorophenol 7.6 U ug/L 09/05/24 13:31 58-90-2 Q09/04/24 23:2350.0 7.6 5 Thionazin 14.4 U ug/L 09/05/24 13:31 297-97-2 Q09/04/24 23:2350.0 14.4 5 O-Toluidine 13.2 U ug/L 09/05/24 13:31 95-53-4 J(M1),Q09/04/24 23:2350.0 13.2 5 2,4,5-Trichlorophenol 7.1 U ug/L 09/05/24 13:31 95-95-4 Q09/04/24 23:2350.0 7.1 5 2,4,6-Trichlorophenol 7.8 U ug/L 09/05/24 13:31 88-06-2 Q09/04/24 23:2350.0 7.8 5 1,3,5-Trinitrobenzene 27.4 U ug/L 09/05/24 13:31 99-35-4 J(v1),Q09/04/24 23:2350.0 27.4 5 Surrogates Nitrobenzene-d5 (S) 73 % 09/05/24 13:31 4165-60-0 D309/04/24 23:2310-133 5 2-Fluorobiphenyl (S) 56 % 09/05/24 13:31 321-60-809/04/24 23:2310-130 5 Terphenyl-d14 (S) 75 % 09/05/24 13:31 1718-51-009/04/24 23:2310-193 5 Phenol-d6 (S) 49 % 09/05/24 13:31 13127-88-309/04/24 23:2310-130 5 2-Fluorophenol (S) 56 % 09/05/24 13:31 367-12-409/04/24 23:2310-130 5 2,4,6-Tribromophenol (S) 89 % 09/05/24 13:31 118-79-609/04/24 23:2310-166 5

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Sample: L-1 Lab ID: 35901688001 Collected: 08/26/24 16:18 Received: 08/27/24 12:55 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Comments: • Chlorinated Acid Herbicides (GC) by Method 8151A - Dilution due to matrix impact during extraction procedure.

Analytical Method: EPA 8260 Pace Analytical Services - Ormond Beach

8260 MSV

Acetone 98.7 ug/L 09/08/24 07:42 67-64-125.0 8.7 1 Acetonitrile 14.9 I ug/L 09/08/24 07:42 75-05-850.0 12.2 1 Acrolein 6.2 U ug/L 09/08/24 07:42 107-02-820.0 6.2 1 Acrylonitrile 3.7 U ug/L 09/08/24 07:42 107-13-120.0 3.7 1 Allyl chloride 1.2 U ug/L 09/08/24 07:42 107-05-15.0 1.2 1 Benzene 3.5 ug/L 09/08/24 07:42 71-43-21.0 0.30 1 Bromochloromethane 0.37 U ug/L 09/08/24 07:42 74-97-51.0 0.37 1 Bromodichloromethane 0.19 U ug/L 09/08/24 07:42 75-27-41.0 0.19 1 Bromoform 0.48 U ug/L 09/08/24 07:42 75-25-2 J(v1)3.0 0.48 1 Bromomethane 3.9 U ug/L 09/08/24 07:42 74-83-9 J(v1)10.0 3.9 1 2-Butanone (MEK) 60.3 ug/L 09/08/24 07:42 78-93-350.0 6.7 1 Carbon disulfide 1.8 U ug/L 09/08/24 07:42 75-15-010.0 1.8 1 Carbon tetrachloride 0.44 U ug/L 09/08/24 07:42 56-23-53.0 0.44 1 Chlorobenzene 3.8 ug/L 09/08/24 07:42 108-90-71.0 0.35 1 Chloroethane 3.7 U ug/L 09/08/24 07:42 75-00-310.0 3.7 1 Chloroform 0.56 U ug/L 09/08/24 07:42 67-66-31.0 0.56 1 Chloromethane 0.43 U ug/L 09/08/24 07:42 74-87-31.0 0.43 1 Chloroprene 0.57 U ug/L 09/08/24 07:42 126-99-81.0 0.57 1 Dibromochloromethane 0.45 U ug/L 09/08/24 07:42 124-48-12.0 0.45 1 Dibromomethane 0.68 U ug/L 09/08/24 07:42 74-95-32.0 0.68 1 trans-1,4-Dichloro-2-butene 2.5 U ug/L 09/08/24 07:42 110-57-610.0 2.5 1 Dichlorodifluoromethane 0.80 U ug/L 09/08/24 07:42 75-71-81.0 0.80 1 1,1-Dichloroethane 0.34 U ug/L 09/08/24 07:42 75-34-31.0 0.34 1 1,2-Dichloroethane 0.27 U ug/L 09/08/24 07:42 107-06-21.0 0.27 1 1,1-Dichloroethene 0.59 U ug/L 09/08/24 07:42 75-35-41.0 0.59 1 cis-1,2-Dichloroethene 0.55 I ug/L 09/08/24 07:42 156-59-21.0 0.27 1 trans-1,2-Dichloroethene 0.23 U ug/L 09/08/24 07:42 156-60-51.0 0.23 1 1,2-Dichloropropane 0.23 U ug/L 09/08/24 07:42 78-87-51.0 0.23 1 1,3-Dichloropropane 0.26 U ug/L 09/08/24 07:42 142-28-91.0 0.26 1 2,2-Dichloropropane 0.59 U ug/L 09/08/24 07:42 594-20-71.0 0.59 1 1,1-Dichloropropene 0.66 U ug/L 09/08/24 07:42 563-58-61.0 0.66 1 cis-1,3-Dichloropropene 0.17 U ug/L 09/08/24 07:42 10061-01-51.0 0.17 1 trans-1,3-Dichloropropene 0.37 U ug/L 09/08/24 07:42 10061-02-61.0 0.37 1 Ethylbenzene 4.8 ug/L 09/08/24 07:42 100-41-41.0 0.30 1 Ethyl methacrylate 0.40 U ug/L 09/08/24 07:42 97-63-22.0 0.40 1 Hexachloro-1,3-butadiene 0.94 U ug/L 09/08/24 07:42 87-68-33.0 0.94 1 2-Hexanone 6.6 U ug/L 09/08/24 07:42 591-78-6 J(v1)25.0 6.6 1 Iodomethane 3.6 U ug/L 09/08/24 07:42 74-88-4 J(v1)10.0 3.6 1 Isobutyl Alcohol 13.0 U ug/L 09/08/24 07:42 78-83-1100 13.0 1 Methacrylonitrile 4.9 U ug/L 09/08/24 07:42 126-98-710.0 4.9 1 Methylene Chloride 1.7 U ug/L 09/08/24 07:42 75-09-25.0 1.7 1 Methyl methacrylate 1.5 U ug/L 09/08/24 07:42 80-62-610.0 1.5 1 4-Methyl-2-pentanone (MIBK) 7.5 U ug/L 09/08/24 07:42 108-10-1 J(v1)25.0 7.5 1 Propionitrile 6.5 U ug/L 09/08/24 07:42 107-12-025.0 6.5 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Sample: L-1 Lab ID: 35901688001 Collected: 08/26/24 16:18 Received: 08/27/24 12:55 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Comments: • Chlorinated Acid Herbicides (GC) by Method 8151A - Dilution due to matrix impact during extraction procedure.

Analytical Method: EPA 8260 Pace Analytical Services - Ormond Beach

8260 MSV

Styrene 0.26 U ug/L 09/08/24 07:42 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane 0.32 U ug/L 09/08/24 07:42 630-20-61.0 0.32 1 1,1,2,2-Tetrachloroethane 0.59 U ug/L 09/08/24 07:42 79-34-51.0 0.59 1 Tetrachloroethene 0.38 U ug/L 09/08/24 07:42 127-18-41.0 0.38 1 Toluene 3.9 ug/L 09/08/24 07:42 108-88-31.0 0.33 1 1,2,4-Trichlorobenzene 0.76 U ug/L 09/08/24 07:42 120-82-11.0 0.76 1 1,1,1-Trichloroethane 0.30 U ug/L 09/08/24 07:42 71-55-61.0 0.30 1 1,1,2-Trichloroethane 0.30 U ug/L 09/08/24 07:42 79-00-51.0 0.30 1 Trichloroethene 0.36 U ug/L 09/08/24 07:42 79-01-61.0 0.36 1 Trichlorofluoromethane 0.72 U ug/L 09/08/24 07:42 75-69-41.0 0.72 1 1,2,3-Trichloropropane 0.53 U ug/L 09/08/24 07:42 96-18-42.0 0.53 1 Vinyl acetate 1.8 U ug/L 09/08/24 07:42 108-05-4 J(L1), J(v1),L3

10.0 1.8 1

Vinyl chloride 0.39 U ug/L 09/08/24 07:42 75-01-41.0 0.39 1 Xylene (Total) 10.2 ug/L 09/08/24 07:42 1330-20-75.0 2.1 1 Surrogates 4-Bromofluorobenzene (S) 99 % 09/08/24 07:42 460-00-470-130 1 Toluene-d8 (S) 102 % 09/08/24 07:42 2037-26-570-130 1 1,2-Dichlorobenzene-d4 (S) 102 % 09/08/24 07:42 2199-69-170-130 1

Analytical Method: SM 2320B Pace Analytical Services - Ormond Beach

2320B Alkalinity

Alkalinity, Total as CaCO3 2050 mg/L 08/28/24 21:045.0 5.0 1

Analytical Method: SM 2540C Pace Analytical Services - Ormond Beach

2540C Total Dissolved Solids

Total Dissolved Solids 2780 mg/L 08/28/24 11:4350.0 50.0 1

Analytical Method: SM 4500-S2F Pace Analytical Services - Ormond Beach

4500S2F Sulfide

Sulfide 224 mg/L 08/29/24 09:37 18496-25-80.10 0.10 1

Analytical Method: EPA 300.0 Pace Analytical Services - Ormond Beach

300.0 IC Anions

Nitrate as N 0.50 U mg/L 08/28/24 14:56 14797-55-8 D31.0 0.50 20

Analytical Method: EPA 300.0 Pace Analytical Services - Ormond Beach

300.0 IC Anions 28 Days

Chloride 677 mg/L 09/08/24 03:24 16887-00-6250 125 50

Analytical Method: EPA 350.1 Pace Analytical Services - Ormond Beach

350.1 Ammonia

Nitrogen, Ammonia 343 mg/L 09/06/24 14:48 7664-41-75.0 3.5 100

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Sample: L-1 Lab ID: 35901688001 Collected: 08/26/24 16:18 Received: 08/27/24 12:55 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Comments: • Chlorinated Acid Herbicides (GC) by Method 8151A - Dilution due to matrix impact during extraction procedure.

Analytical Method: EPA 9012 Preparation Method: EPA 9012 Pace Analytical Services - Ormond Beach

9012 Cyanide, Total

Cyanide 0.0053 I mg/L 08/29/24 14:08 57-12-5 J(M1)08/29/24 09:320.010 0.0050 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Sample: Trip Blank Lab ID: 35901688002 Collected: 08/26/24 00:01 Received: 08/27/24 12:55 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 8260 Pace Analytical Services - Ormond Beach

8260 MSV

Acetone 8.7 U ug/L 09/08/24 02:02 67-64-125.0 8.7 1 Acetonitrile 12.2 U ug/L 09/08/24 02:02 75-05-850.0 12.2 1 Acrolein 6.2 U ug/L 09/08/24 02:02 107-02-820.0 6.2 1 Acrylonitrile 3.7 U ug/L 09/08/24 02:02 107-13-120.0 3.7 1 Allyl chloride 1.2 U ug/L 09/08/24 02:02 107-05-15.0 1.2 1 Benzene 0.30 U ug/L 09/08/24 02:02 71-43-21.0 0.30 1 Bromochloromethane 0.37 U ug/L 09/08/24 02:02 74-97-51.0 0.37 1 Bromodichloromethane 0.19 U ug/L 09/08/24 02:02 75-27-41.0 0.19 1 Bromoform 0.48 U ug/L 09/08/24 02:02 75-25-2 J(v1)3.0 0.48 1 Bromomethane 3.9 U ug/L 09/08/24 02:02 74-83-9 J(v1)10.0 3.9 1 2-Butanone (MEK) 6.7 U ug/L 09/08/24 02:02 78-93-350.0 6.7 1 Carbon disulfide 1.8 U ug/L 09/08/24 02:02 75-15-010.0 1.8 1 Carbon tetrachloride 0.44 U ug/L 09/08/24 02:02 56-23-53.0 0.44 1 Chlorobenzene 0.35 U ug/L 09/08/24 02:02 108-90-71.0 0.35 1 Chloroethane 3.7 U ug/L 09/08/24 02:02 75-00-310.0 3.7 1 Chloroform 0.56 U ug/L 09/08/24 02:02 67-66-31.0 0.56 1 Chloromethane 0.43 U ug/L 09/08/24 02:02 74-87-31.0 0.43 1 Chloroprene 0.57 U ug/L 09/08/24 02:02 126-99-81.0 0.57 1 1,2-Dibromo-3-chloropropane 1.9 U ug/L 09/08/24 02:02 96-12-85.0 1.9 1 Dibromochloromethane 0.45 U ug/L 09/08/24 02:02 124-48-12.0 0.45 1 1,2-Dibromoethane (EDB) 0.31 U ug/L 09/08/24 02:02 106-93-41.0 0.31 1 Dibromomethane 0.68 U ug/L 09/08/24 02:02 74-95-32.0 0.68 1 trans-1,4-Dichloro-2-butene 2.5 U ug/L 09/08/24 02:02 110-57-610.0 2.5 1 Dichlorodifluoromethane 0.80 U ug/L 09/08/24 02:02 75-71-81.0 0.80 1 1,1-Dichloroethane 0.34 U ug/L 09/08/24 02:02 75-34-31.0 0.34 1 1,2-Dichloroethane 0.27 U ug/L 09/08/24 02:02 107-06-21.0 0.27 1 1,1-Dichloroethene 0.59 U ug/L 09/08/24 02:02 75-35-41.0 0.59 1 cis-1,2-Dichloroethene 0.27 U ug/L 09/08/24 02:02 156-59-21.0 0.27 1 trans-1,2-Dichloroethene 0.23 U ug/L 09/08/24 02:02 156-60-51.0 0.23 1 1,2-Dichloropropane 0.23 U ug/L 09/08/24 02:02 78-87-51.0 0.23 1 1,3-Dichloropropane 0.26 U ug/L 09/08/24 02:02 142-28-91.0 0.26 1 2,2-Dichloropropane 0.59 U ug/L 09/08/24 02:02 594-20-71.0 0.59 1 1,1-Dichloropropene 0.66 U ug/L 09/08/24 02:02 563-58-61.0 0.66 1 cis-1,3-Dichloropropene 0.17 U ug/L 09/08/24 02:02 10061-01-51.0 0.17 1 trans-1,3-Dichloropropene 0.37 U ug/L 09/08/24 02:02 10061-02-61.0 0.37 1 Ethylbenzene 0.30 U ug/L 09/08/24 02:02 100-41-41.0 0.30 1 Ethyl methacrylate 0.40 U ug/L 09/08/24 02:02 97-63-22.0 0.40 1 Hexachloro-1,3-butadiene 0.94 U ug/L 09/08/24 02:02 87-68-33.0 0.94 1 2-Hexanone 6.6 U ug/L 09/08/24 02:02 591-78-6 J(v1)25.0 6.6 1 Iodomethane 3.6 U ug/L 09/08/24 02:02 74-88-4 J(v1)10.0 3.6 1 Isobutyl Alcohol 13.0 U ug/L 09/08/24 02:02 78-83-1100 13.0 1 Methacrylonitrile 4.9 U ug/L 09/08/24 02:02 126-98-710.0 4.9 1 Methylene Chloride 1.7 U ug/L 09/08/24 02:02 75-09-25.0 1.7 1 Methyl methacrylate 1.5 U ug/L 09/08/24 02:02 80-62-610.0 1.5 1 4-Methyl-2-pentanone (MIBK) 7.5 U ug/L 09/08/24 02:02 108-10-1 J(v1)25.0 7.5 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Sample: Trip Blank Lab ID: 35901688002 Collected: 08/26/24 00:01 Received: 08/27/24 12:55 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 8260 Pace Analytical Services - Ormond Beach

8260 MSV

Propionitrile 6.5 U ug/L 09/08/24 02:02 107-12-025.0 6.5 1 Styrene 0.26 U ug/L 09/08/24 02:02 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane 0.32 U ug/L 09/08/24 02:02 630-20-61.0 0.32 1 1,1,2,2-Tetrachloroethane 0.59 U ug/L 09/08/24 02:02 79-34-51.0 0.59 1 Tetrachloroethene 0.38 U ug/L 09/08/24 02:02 127-18-41.0 0.38 1 Toluene 0.33 U ug/L 09/08/24 02:02 108-88-31.0 0.33 1 1,2,4-Trichlorobenzene 0.76 U ug/L 09/08/24 02:02 120-82-11.0 0.76 1 1,1,1-Trichloroethane 0.30 U ug/L 09/08/24 02:02 71-55-61.0 0.30 1 1,1,2-Trichloroethane 0.30 U ug/L 09/08/24 02:02 79-00-51.0 0.30 1 Trichloroethene 0.36 U ug/L 09/08/24 02:02 79-01-61.0 0.36 1 Trichlorofluoromethane 0.72 U ug/L 09/08/24 02:02 75-69-41.0 0.72 1 1,2,3-Trichloropropane 0.53 U ug/L 09/08/24 02:02 96-18-42.0 0.53 1 Vinyl acetate 1.8 U ug/L 09/08/24 02:02 108-05-4 J(L1), J(v1),L3

10.0 1.8 1

Vinyl chloride 0.39 U ug/L 09/08/24 02:02 75-01-41.0 0.39 1 Xylene (Total) 2.1 U ug/L 09/08/24 02:02 1330-20-75.0 2.1 1 Surrogates 4-Bromofluorobenzene (S) 97 % 09/08/24 02:02 460-00-470-130 1 Toluene-d8 (S) 102 % 09/08/24 02:02 2037-26-570-130 1 1,2-Dichlorobenzene-d4 (S) 101 % 09/08/24 02:02 2199-69-170-130 1

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

#=QC#

QUALITY CONTROL DATA

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

2354465 3510C

EPA 8141B

OP Pesticides 8141B

Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 35901688001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: R4115641-1

Associated Lab Samples: 35901688001

Matrix: Water

AnalyzedMDL

Dimethoate mg/L 0.000327 U 0.00100 09/03/24 14:190.000327 Disulfoton mg/L 0.000227 U 0.00100 09/03/24 14:190.000227 Methyl parathion mg/L 0.000383 U 0.00100 09/03/24 14:190.000383 Parathion (Ethyl parathion) mg/L 0.000454 U 0.00100 09/03/24 14:190.000454 Phorate mg/L 0.000276 U 0.00100 09/03/24 14:190.000276 Triphenylphosphate (S) % 89.2 42.0-129 09/03/24 14:19

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

R4115641-2LABORATORY CONTROL SAMPLE:

LCSSpike

Dimethoate mg/L 0.003160.00500 63.2 27.0-120 Disulfoton mg/L 0.004070.00500 81.4 44.0-136 Methyl parathion mg/L 0.003830.00500 76.6 43.0-135 Parathion (Ethyl parathion) mg/L 0.004180.00500 83.6 42.0-134 Phorate mg/L 0.003790.00500 75.8 44.0-129 Triphenylphosphate (S) % 94.2 42.0-129

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R4115641-3MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1773424-01

R4115641-4

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Dimethoate mg/L 0.00500 53.4 17.0-12944.4 18.4 200.00500ND 0.00267 0.00222 Disulfoton mg/L J(R1)0.00500 80.8 42.0-13153.2 41.2 210.00500ND 0.00404 0.00266 Methyl parathion mg/L J(R1)0.00500 76.2 28.0-14252.8 36.3 200.00500ND 0.00381 0.00264 Parathion (Ethyl parathion) mg/L J(R1)0.00500 81.2 30.0-13855.0 38.5 200.00500ND 0.00406 0.00275 Phorate mg/L J(R1)0.00500 79.8 38.0-13452.2 41.8 200.00500ND 0.00399 0.00261 Triphenylphosphate (S) % 89.0 42.0-12959.8

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

2351501 8151A

EPA 8151A

Chlorinated Herb. (GC) 8151A

Laboratory: Pace National - Mt. Juliet Associated Lab Samples: 35901688001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: R4114884-1

Associated Lab Samples: 35901688001

Matrix: Water

AnalyzedMDL

2,4,5-T mg/L 0.000258 U 0.00200 09/02/24 16:530.000258 2,4,5-TP (Silvex) mg/L 0.000335 U 0.00200 09/02/24 16:530.000335 2,4-D mg/L 0.000547 U 0.00200 09/02/24 16:530.000547 Dinoseb mg/L 0.000250 U 0.00200 09/02/24 16:530.000250 Pentachlorophenol mg/L 0.000111 U 0.00100 09/02/24 16:530.000111

2,4-DCAA (S) % 97.6 14.0-158 09/02/24 16:53

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

R4114884-2LABORATORY CONTROL SAMPLE:

LCSSpike

2,4,5-T mg/L 0.00318 J(L0)0.00250 127 54.0-120 2,4,5-TP (Silvex) mg/L 0.002930.00250 117 50.0-125 2,4-D mg/L 0.00322 J(L0)0.00250 129 50.0-120 Dinoseb mg/L 0.003020.00250 121 36.0-134 Pentachlorophenol mg/L 0.0004440.000500 88.8 41.0-120

2,4-DCAA (S) % 109 14.0-158

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

R4114884-3MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

L1771847-03

R4114884-4

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

2,4,5-T mg/L J(MH)0.00258 122 54.0-120116 5.86 200.00258ND 0.00316 0.00298 2,4,5-TP (Silvex) mg/L 0.00258 111 50.0-125105 5.39 200.00258ND 0.00286 0.00271 2,4-D mg/L J(MH)0.00258 128 50.0-120121 5.93 200.00258ND 0.00330 0.00311 Dinoseb mg/L 0.00258 79.5 36.0-13475.6 5.00 200.00258ND 0.00205 0.00195 Pentachlorophenol mg/L 0.000515 85.2 41.0-12080.6 5.62 200.000515ND 0.000439 0.000415

2,4-DCAA (S) % 109 14.0-158102

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1040142

EPA 7470

EPA 7470

7470 Mercury

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35901688001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5715921

Associated Lab Samples: 35901688001

Matrix: Water

AnalyzedMDL

Mercury ug/L 0.14 U 0.20 09/11/24 09:350.14

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5715922LABORATORY CONTROL SAMPLE:

LCSSpike

Mercury ug/L 2.12 105 80-120

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5715923MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35902003001

5715924

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Mercury ug/L 2 110 75-125108 1 2020.14 U 2.2 2.2

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1037645

EPA 3010

EPA 6010

6010 MET

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35901688001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5702635

Associated Lab Samples: 35901688001

Matrix: Water

AnalyzedMDL

Barium ug/L 0.84 U 10.0 09/03/24 16:260.84 Beryllium ug/L 0.17 U 4.0 09/03/24 16:260.17 Cadmium ug/L 0.33 U 1.0 09/03/24 16:270.33 Chromium ug/L 1.7 U 5.0 09/03/24 16:271.7 Cobalt ug/L 0.96 U 10.0 09/03/24 16:270.96 Copper ug/L 2.6 U 5.0 09/03/24 16:272.6 Iron ug/L 25.0 U 40.0 09/03/24 16:2725.0 Lead ug/L 2.1 U 10.0 09/01/24 02:112.1 Nickel ug/L 1.0 U 5.0 09/03/24 16:271.0 Selenium ug/L 3.9 U 15.0 09/03/24 16:263.9 Silver ug/L 1.0 U 5.0 09/03/24 16:271.0 Sodium mg/L 0.54 U 2.0 09/03/24 16:270.54 Tin ug/L 16.0 U 50.0 09/03/24 16:2716.0 Vanadium ug/L 1.0 U 10.0 09/03/24 16:271.0 Zinc ug/L 11.0 U 20.0 09/03/24 16:2711.0

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5702636LABORATORY CONTROL SAMPLE:

LCSSpike

Barium ug/L 246250 99 80-120 Beryllium ug/L 23.825 95 80-120 Cadmium ug/L 26.125 104 80-120 Chromium ug/L 250250 100 80-120 Cobalt ug/L 256250 102 80-120 Copper ug/L 242250 97 80-120 Iron ug/L 25302500 101 80-120 Lead ug/L 249250 100 80-120 Nickel ug/L 256250 102 80-120 Selenium ug/L 247250 99 80-120 Silver ug/L 24.325 97 80-120 Sodium mg/L 12.012.5 96 80-120 Tin ug/L 12501250 100 80-120 Vanadium ug/L 251250 100 80-120 Zinc ug/L 12901250 103 80-120

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5702637MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35902107006

5702638

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Barium ug/L 250 97 75-125100 3 202507.8 I 251 258 Beryllium ug/L 25 95 75-12598 3 20250.17 U 23.8 24.4 Cadmium ug/L 25 103 75-125105 2 20250.33 U 25.7 26.1 Chromium ug/L 250 100 75-125101 1 202501.7 U 250 254 Cobalt ug/L 250 102 75-125104 2 202500.96 U 256 260 Copper ug/L 250 100 75-125102 2 202502.6 U 251 255 Iron ug/L 2500 101 75-125102 1 20250095.4 2620 2650 Lead ug/L 250 98 75-12599 1 202502.1 U 245 247 Nickel ug/L 250 102 75-125103 2 202501.0 U 254 258 Selenium ug/L 250 78 75-12579 1 202503.9 U 196 198 Silver ug/L 25 98 75-125100 2 20251.0 U 24.6 25.1 Sodium mg/L 12.5 103 75-125106 2 2012.57790 ug/L 20.7 21.0 Tin ug/L 1250 100 75-125102 2 20125016.0 U 1250 1270 Vanadium ug/L 250 102 75-125103 2 202501.0 U 255 259 Zinc ug/L 1250 101 75-125103 2 20125011.0 U 1270 1290

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1037646

EPA 3010

EPA 6020

6020 MET

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35901688001

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5702641

Associated Lab Samples: 35901688001

Matrix: Water

AnalyzedMDL

Antimony ug/L 0.50 U 1.0 09/13/24 10:210.50 Arsenic ug/L 0.50 U 1.0 09/13/24 10:210.50 Thallium ug/L 0.11 U 1.0 09/13/24 10:210.11

Parameter Units

LCS

Result % Rec Limits Qualifiers% RecConc.

5702642LABORATORY CONTROL SAMPLE:

LCSSpike

Antimony ug/L 52.250 104 80-120 Arsenic ug/L 51.550 103 80-120 Thallium ug/L 49.950 100 80-120

Parameter Units

MS

Result % Rec Limits Qual% RecConc.

5702643MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpike Result

35901697001

5702644

MSD

Result

MSD

% Rec RPD RPD

Max

MSDMS

Spike Conc.

Antimony ug/L 50 106 75-125108 3 20500.50 U 52.9 54.3 Arsenic ug/L 50 104 75-125105 1 20502.1 54.3 54.7 Thallium ug/L 50 101 75-125101 0 20500.11 I 50.8 50.5

REPORT OF LABORATORY ANALYSIS

This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/13/2024 03:50 PM

Pace Analytical Services, LLC 8 East Tower Circle

Ormond Beach, FL 32174

Pace Project No.:

Project:

35901688 Baseline LF Leachate

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:

QC Batch Method:

Analysis Method:

Analysis Description:

1039674

EPA 8260

EPA 8260

8260 MSV

Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35901688001, 35901688002

Parameter Units Blank Result

Reporting Limit Qualifiers

METHOD BLANK: 5713798

Associated Lab Samples: 35901688001, 35901688002

Matrix: Water

AnalyzedMDL

1,1,1,2-Tetrachloroethane ug/L 0.32 U 1.0 09/08/24 00:550.32 1,1,1-Trichloroethane ug/L 0.30 U 1.0 09/08/24 00:550.30 1,1,2,2-Tetrachloroethane ug/L 0.59 U 1.0 09/08/24 00:550.59 1,1,2-Trichloroethane ug/L 0.30 U 1.0 09/08/24 00:550.30 1,1-Dichloroethane ug/L 0.34 U 1.0 09/08/24 00:550.34 1,1-Dichloroethene ug/L 0.59 U 1.0 09/08/24 00:550.59 1,1-Dichloropropene ug/L 0.66 U 1.0 09/08/24 00:550.66 1,2,3-Trichloropropane ug/L 0.53 U 2.0 09/08/24 00:550.53 1,2,4-Trichlorobenzene ug/L 0.76 U 1.0 09/08/24 00:550.76 1,2-Dibromo-3-chloropropane ug/L 1.9 U 5.0 09/08/24 00:551.9 1,2-Dibromoethane (EDB) ug/L 0.31 U 1.0 09/08/24 00:550.31 1,2-Dichloroethane ug/L 0.27 U 1.0 09/08/24 00:550.27 1,2-Dichloropropane ug/L 0.23 U 1.0 09/08/24 00:550.23 1,3-Dichloropropane ug/L 0.26 U 1.0 09/08/24 00:550.26 2,2-Dichloropropane ug/L 0.59 U 1.0 09/08/24 00:550.59 2-Butanone (MEK) ug/L 6.7 U 50.0 09/08/24 00:556.7 2-Hexanone ug/L 6.6 U 25.0 J(v1)09/08/24 00:556.6 4-Methyl-2-pentanone (MIBK) ug/L 7.5 U 25.0 J(v1)09/08/24 00:557.5 Acetone ug/L 8.7 U 25.0 09/08/24 00:558.7…