099000 Provon 1941-02 Foam Hand Soap SDS.pdf

SAFETY DATA SHEET

PROVON® Clear & Mild Foam Handwash

Version 1.1 SDS Number: 400000000385 Revision Date: 04/18/2017

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SECTION 1. IDENTIFICATION

Product name

: PROVON® Clear & Mild Foam Handwash

Manufacturer or supplier's details

Company name of supplier

: GOJO Industries, Inc.

Address

: One GOJO Plaza, Suite 500 Akron, Ohio 44311

Telephone

: 1 (330) 255-6000

Emergency telephone number

: 1-800-424-9300 CHEMTREC

Recommended use of the chemical and restrictions on use

Recommended use

: Skin-care

Restrictions on use

: This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer.

While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Eye irritation

: Category 2B

GHS label elements

Signal word

: Warning

Hazard statements

: H320 Causes eye irritation.

Precautionary statements

: Response:

P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P337 + P313 If eye irritation persists: Get medical advice/ attention.

Item# 099000

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Other hazards

None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous components

Chemical name CAS-No. Concentration (%)

Sodium Laureth Sulfate 68585-34-2 >= 1 - < 5

Glycerin 56-81-5 >= 1 - < 5

SECTION 4. FIRST AID MEASURES

General advice

: In the case of accident or if you feel unwell, seek medical advice immediately.

When symptoms persist or in all cases of doubt seek medical advice.

If inhaled

: If inhaled, remove to fresh air.

If symptoms persist, call a physician.

In case of skin contact

: Wash with water and soap as a precaution.

Get medical attention if irritation develops and persists.

In case of eye contact

: Immediately flush eye(s) with plenty of water.

If easy to do, remove contact lens, if worn.

Seek medical advice.

If swallowed

: If swallowed, DO NOT induce vomiting.

Rinse mouth with water.

Obtain medical attention.

Most important symptoms and effects, both acute and delayed

: Causes eye irritation.

Protection of first-aiders

: First Aid responders should pay attention to self-protection and use the recommended protective clothing

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media

: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media

: None known.

Hazardous combustion products

: Sulphur oxides Carbon oxides Nitrogen oxides (NOx) Metal oxides

Specific extinguishing : Use extinguishing measures that are appropriate to local

3 / 11 methods circumstances and the surrounding environment.

Use a water spray to cool fully closed containers.

Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Special protective equipment for firefighters

: In the event of fire, wear self-contained breathing apparatus.

Use personal protective equipment.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Use personal protective equipment.

Ensure adequate ventilation.

Evacuate personnel to safe areas.

Material can create slippery conditions.

Environmental precautions

: Discharge into the environment must be avoided.

Prevent further leakage or spillage if safe to do so.

Prevent spreading over a wide area (e.g. by containment or oil barriers).

Retain and dispose of contaminated wash water.

Local authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up

: Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).

Keep in suitable, closed containers for disposal.

Clean contaminated floors and objects thoroughly while observing environmental regulations.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling

: For personal protection see section 8.

Do not swallow.

Avoid contact with eyes.

Keep container closed when not in use.

Conditions for safe storage

: Keep in properly labelled containers.

Keep container tightly closed in a dry and well-ventilated place.

Store in accordance with the particular national regulations.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type (Form of exposure)

Control parameters / Permissible

Basis

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Glycerin 56-81-5 TWA (mist, respirable fraction)

5 mg/m3 OSHA Z-1

TWA (mist, total dust)

15 mg/m3 OSHA Z-1

Personal protective equipment

Respiratory protection

: No personal respiratory protective equipment normally required.

Eye protection

: No special measures necessary provided product is used correctly.

Wear face-shield and protective suit for abnormal processing problems.

Skin and body protection

: No special measures necessary provided product is used correctly.

Protective measures

: Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place.

Ensure that eye flushing systems and safety showers are located close to the working place.

Hygiene measures

: Handle in accordance with good industrial hygiene and safety practice.

Avoid contact with eyes.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance

: liquid

Colour

: clear, colourless, light yellow

Odour

: like soap

Odour Threshold

: No data available pH

: 5.3 - 6.7, (20 °C)

Solidification / Setting point

: 1.4 °C

Initial boiling point and boiling range

: 98 °C

Flash point

: > 100 °C

Evaporation rate

Flammability (solid, gas)

: Not applicable

Upper explosion limit

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Lower explosion limit

Vapour pressure

Relative vapour density

Density

: 1.012 g/cm3

Solubility(ies) Water solubility

: soluble

Partition coefficient: n-octanol/water

: Not applicable

Auto-ignition temperature

: not determined

Thermal decomposition

: The substance or mixture is not classified self-reactive.

Viscosity Viscosity, kinematic

: 10 - 20 mm2/s (20 °C)

Explosive properties

: Not explosive

Oxidizing properties

: The substance or mixture is not classified as oxidizing.

SECTION 10. STABILITY AND REACTIVITY

Reactivity

: Not classified as a reactivity hazard.

Chemical stability

: Stable under normal conditions.

Possibility of hazardous reactions

: No dangerous reaction known under conditions of normal use.

Incompatible materials

: Strong oxidizing agents

Hazardous decomposition products

: No hazardous decomposition products are known.

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure Skin contact Eye contact Inhalation

Acute toxicity

Not classified based on available information.

Product:

Acute oral toxicity

: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method

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Components:

Sodium Laureth Sulfate:

: LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity

Glycerin:

: LD50 (Rat): > 5,000 mg/kg

Skin corrosion/irritation

Not classified based on available information.

Product:

Assessment: Not irritating when applied to human skin.

Result: No skin irritation

Result: Skin irritation

Result: No skin irritation

Serious eye damage/eye irritation

Causes eye irritation.

Result: Mild eye irritation

Result: Eye irritation Remarks: Severe eye irritation

Result: No eye irritation

Respiratory or skin sensitisation

Skin sensitisation: Not classified based on available information.

Respiratory sensitisation: Not classified based on available information.

Germ cell mutagenicity

Not classified based on available information.

Components:

Genotoxicity in vitro

: Test Type: In vitro mammalian cell gene mutation test Method: OECD Test Guideline 476 Result: negative

Carcinogenicity

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Species: Rat Application Route: Ingestion Exposure time: 2 Years

IARC

No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH

equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

OSHA

equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

NTP

equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

Reproductive toxicity

Components:

Effects on fertility

: Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion

Effects on foetal development

: Test Type: Embryo-foetal development Species: Rabbit Application Route: Ingestion

STOT - single exposure

STOT - repeated exposure

Not classified based on available information.

Repeated dose toxicity

Components:

Sodium Laureth Sulfate:

Repeated dose toxicity - Assessment

: Causes serious eye irritation.

Species: Rat

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NOAEL: 167 mg/m3 LOAEL: 660 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 13 w Symptoms: Local irritation

Aspiration toxicity

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Components:

Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 54,000 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 1,955 mg/l Exposure time: 48 h

Toxicity to bacteria

: NOEC (Pseudomonas putida): > 10,000 mg/l Exposure time: 16 h

Persistence and degradability

Biodegradability

: Result: Readily biodegradable.

Biodegradability

: Result: Readily biodegradable.

Biodegradation: 94 % Exposure time: 1 d

Bioaccumulative potential

Glycerin:

Partition coefficient: n-octanol/water

: log Pow: -1.76

Mobility in soil

No data available

Other adverse effects

No data available

Regulation

40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances

Remarks This product neither contains, nor was manufactured with a

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Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues : Dispose of in accordance with local regulations.

Contaminated packaging : Dispose of as unused product.

Empty containers should be taken to an approved waste handling site for recycling or disposal.

SECTION 14. TRANSPORT INFORMATION

International Regulation

IATA-DGR

Not regulated as a dangerous good

IMDG-Code Not regulated as a dangerous good

National Regulations

49 CFR

Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards

: Acute Health Hazard

SARA 302

: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313

: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61).

This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F).

The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489):

Glycerin 56-81-5 1.75 %

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This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450.

Clean Water Act

This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A.

This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3.

This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section

Massachusetts Right To Know

Glycerin 56-81-5 1 - 5 %

Pennsylvania Right To Know

Water (Aqua) 7732-18-5 90 - 100 %

Glycerin 56-81-5 1 - 5 %

New Jersey Right To Know

Water (Aqua) 7732-18-5 90 - 100 %

Sodium Laureth Sulfate 68585-34-2 1 - 5 %

Glycerin 56-81-5 1 - 5 %

California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

The components of this product are reported in the following inventories:

CH INV

: On the inventory, or in compliance with the inventory

TSCA

DSL

: All components of this product are on the Canadian DSL.

AICS

NZIoC

ENCS

ISHL

KECI

PICCS

IECSC

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)

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SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS III:

Revision Date

: 04/18/2017

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Flammability

H e a lt h

In s ta b ility

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

Special hazard.

0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic