042854 Ecolab HD Muli purpose cleaner SDS.pdf

SAFETY DATA SHEET

MULTI-PURPOSE DISINFECTANT CLEANER

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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : MULTI-PURPOSE DISINFECTANT CLEANER

Other means of identification : Not applicable

Recommended use : Disinfectant

Restrictions on use : Reserved for industrial and professional use.

Product dilution information : 0.39 %

Company : Ecolab Inc.

1 Ecolab Place St. Paul, Minnesota USA 55102 1-800-352-5326

Emergency health information

: 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US)

Issuing date : 03/15/2021

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification

Product AS SOLD Acute toxicity (Oral) : Category 4 Acute toxicity (Dermal) : Category 4 Skin corrosion : Category 1C Serious eye damage : Category 1

Product AT USE DILUTION Acute toxicity (Dermal) : Category 4 Eye irritation : Category 2B

GHS label elements

Hazard pictograms :

Signal Word : Danger

Hazard Statements : Harmful if swallowed or in contact with skin.

Causes severe skin burns and eye damage.

Precautionary Statements : Prevention:

Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/ protective clothing/ eye protection/ face protection.

Response:

IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.

Rinse mouth. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove person

Item# 042854

914273 2 / 13 to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. Immediately call a POISON CENTER/ doctor. Wash contaminated clothing before reuse.

Storage:

Store locked up.

Disposal:

Dispose of contents/ container to an approved waste disposal plant.

Product AT USE DILUTION Hazard pictograms :

Signal Word : Warning

Hazard Statements : Harmful in contact with skin.

Causes eye irritation.

Precautionary Statements : Prevention:

Wash skin thoroughly after handling.

Response:

IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. If eye irritation persists: Get medical advice/ attention. Wash contaminated clothing before reuse.

Disposal:

Dispose of contents/container in accordance with local/regional/national/international regulations.

Other hazards : None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical name CAS-No. Concentration (%) Alkyl (C14 50%, C12 40%, C16 10%) dimethyl benzyl ammonium chloride

68424-85-1 8.68

Octyl decyl dimethyl ammonium chloride 32426-11-2 6.51 Alcohols, C9-11, ethoxylated 68439-46-3 5 - 10 ethanol 64-17-5 1 - 5 Didecyl Dimethyl Ammonium Chloride 7173-51-5 3.906 Tetrasodium EDTA 64-02-8 1 - 5 Dioctyl dimethyl ammonium chloride 5538-94-3 2.604 disodium metasilicate 6834-92-0 1 - 5

Product AT USE DILUTION Chemical name CAS-No. Concentration (%) Octyl decyl dimethyl ammonium chloride 32426-11-2 0.0254 Alkyl (C14 50%, C12 40%, C16 10%) dimethyl benzyl ammonium chloride

68424-85-1 0.0339

Didecyl Dimethyl Ammonium Chloride 7173-51-5 0.0152

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Dioctyl dimethyl ammonium chloride 5538-94-3 0.0102

SECTION 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. Get medical attention immediately.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes.

Wash clothing before reuse. Thoroughly clean shoes before reuse.

Get medical attention immediately.

If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur.

Protection of first-aiders : If potential for exposure exists refer to Section 8 for specific personal protective equipment.

Notes to physician : Treat symptomatically.

Most important symptoms and effects, both acute and delayed

: See Section 11 for more detailed information on health effects and symptoms.

In case of eye contact : Rinse with plenty of water.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops and persists.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Get medical attention if symptoms occur.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

: High volume water jet

Specific hazards during fire fighting

: Fire Hazard Keep away from heat and sources of ignition.

Flash back possible over considerable distance.

Beware of vapors accumulating to form explosive concentrations.

Vapors can accumulate in low areas.

Hazardous combustion products

: Decomposition products may include the following materials:

Carbon oxides

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Nitrogen oxides (NOx)

Special protective equipment for fire-fighters

: Use personal protective equipment.

Specific extinguishing methods

: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Ensure adequate ventilation. Remove all sources of ignition. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for containment and cleaning up

: Eliminate all ignition sources if safe to do so. Stop leak if safe to do so.

Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.

Personal precautions, protective equipment and emergency procedures

: Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for containment and cleaning up

: Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Do not ingest. Do not get in eyes, on skin, or on clothing. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Use only with adequate ventilation. Keep away from fire, sparks and heated surfaces. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Wash hands thoroughly after handling. In case of mechanical malfunction, or if in contact with unknown dilution of product, wear full Personal Protective Equipment

(PPE).

Conditions for safe storage : Keep away from heat and sources of ignition. Keep in a cool, well-ventilated place. Do not store near acids. Keep away from oxidizing

914273 5 / 13 agents. Keep out of reach of children. Keep container tightly closed.

Store in suitable labeled containers.

Storage temperature : 0 °C to 40 °C

Advice on safe handling : Wash hands thoroughly after handling. In case of mechanical malfunction, or if in contact with unknown dilution of product, wear full Personal Protective Equipment (PPE).

Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Components CAS-No. Form of exposure

Permissible concentration

Basis ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3

NIOSH REL

TWA 1,000 ppm 1,900 mg/m3

OSHA Z1

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.

Personal protective equipment

Eye protection : Wear eye protection and/or face protection.

Hand protection : Wear the following personal protective equipment:

Standard glove type.

Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Skin protection : Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing

Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use.

Wash face, hands and any exposed skin thoroughly after handling.

Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.

Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants.

Personal protective equipment

Eye protection : No special protective equipment required.

Hand protection : No special protective equipment required.

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Skin protection : No special protective equipment required.

Respiratory protection : No personal respiratory protective equipment normally required.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Product AS SOLD Product AT USE DILUTION

Appearance : liquid liquid

Color : clear, dark orange light orange

Odor : Disinfectants Disinfectants pH : 13.0, (100 %) 10.0

Flash point : 58 °C closed cup, Does not sustain combustion.

Odor Threshold : No data available

Melting point/freezing point : No data available

Initial boiling point and boiling range

: > 100 °C

Evaporation rate : No data available

Flammability (solid, gas) : Not applicable

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapor pressure : No data available

Relative vapor density : No data available

Relative density : 0.99 - 1.01

Water solubility : soluble

Solubility in other solvents : No data available

Partition coefficient: n-octanol/water

: No data available

Autoignition temperature : No data available

Thermal decomposition : No data available

Viscosity, kinematic : No data available

Explosive properties : No data available

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Molecular weight : No data available

VOC : No data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reactions

: No dangerous reaction known under conditions of normal use.

Conditions to avoid : Heat, flames and sparks.

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Incompatible materials : Acids

Hazardous decomposition products

: In case of fire hazardous decomposition products may be produced such as:

Carbon oxides Nitrogen oxides (NOx)

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

: Inhalation, Eye contact, Skin contact

Potential Health Effects

Eyes : Causes serious eye damage.

Skin : Causes severe skin burns. Harmful in contact with skin.

Ingestion : Harmful if swallowed. Causes digestive tract burns.

Inhalation : May cause nose, throat, and lung irritation.

Chronic Exposure : Health injuries are not known or expected under normal use.

Product AT USE DILUTION Eyes : Causes eye irritation.

Skin : Harmful in contact with skin.

Ingestion : Health injuries are not known or expected under normal use.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Health injuries are not known or expected under normal use.

Experience with human exposure

Product AS SOLD Eye contact : Redness, Pain, Corrosion

Skin contact : Redness, Pain, Corrosion

Ingestion : Corrosion, Abdominal pain

Inhalation : Respiratory irritation, Cough

Product AT USE DILUTION Eye contact : Redness, Irritation

Skin contact : No information available.

Ingestion : No symptoms known or expected.

Inhalation : No symptoms known or expected.

Toxicity

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Product Acute oral toxicity : No data available

Acute inhalation toxicity : No data available

Skin corrosion/irritation : No data available

Respiratory or skin sensitization

: No data available

Carcinogenicity : No data available

Reproductive effects : No data available

Germ cell mutagenicity : No data available

Teratogenicity : No data available

STOT-single exposure : No data available

STOT-repeated exposure : No data available

Aspiration toxicity : No data available

Components

Acute oral toxicity : Alkyl (C14 50%, C12 40%, C16 10%) dimethyl benzyl ammonium chloride LD50 Rat: 344 mg/kg

Octyl decyl dimethyl ammonium chloride LD50 Rat: 238 mg/kg

Alcohols, C9-11, ethoxylated LD50 Rat: 4,044 mg/kg ethanol LD50 Rat: 10,470 mg/kg

Didecyl Dimethyl Ammonium Chloride LD50 Rat: 329 mg/kg

Tetrasodium EDTA LD50 Rat: 1,700 mg/kg

Dioctyl dimethyl ammonium chloride LD50 Rat: 238 mg/kg disodium metasilicate LD50 Rat: 500 mg/kg

Components

Acute inhalation toxicity : Alkyl (C14 50%, C12 40%, C16 10%) dimethyl benzyl ammonium chloride 4 h LC50 Rat: 0.054 mg/l Test atmosphere: dust/mist

Octyl decyl dimethyl ammonium chloride 4 h LC50 Rat: 0.07 mg/l

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4 h LC50 Rat: 117 mg/l Test atmosphere: vapor

4 h LC50 Rat: 0.07 mg/l

4 h LD50 Rat: 0.07 mg/l

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Environmental Effects : This product has no known ecotoxicological effects.

Product

Toxicity to fish : No data available

Toxicity to daphnia and other aquatic invertebrates

: No data available

Toxicity to algae : No data available

Components

Toxicity to fish : Octyl decyl dimethyl ammonium chloride 96 h LC50 Fish: 1 mg/l

96 h LC50 Oncorhynchus mykiss (rainbow trout): 5 mg/l

96 h LC50 Pimephales promelas: > 100 mg/l

96 h LC50 Fish: 1 mg/l

96 h LC50 Fish: 121 mg/l

96 h LC50 Oncorhynchus mykiss (rainbow trout): 0.35 mg/l disodium metasilicate 96 h LC50 Fish: 210 mg/l

Toxicity to daphnia and other aquatic invertebrates

: Alkyl (C14 50%, C12 40%, C16 10%) dimethyl benzyl ammonium chloride 48 h EC50 Daphnia magna (Water flea): 0.016 mg/l

48 h EC50 Daphnia magna (Water flea): 2.5 mg/l

48 h EC50 Aquatic Invertebrate: 857 mg/l

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48 h EC50 Daphnia magna (Water flea): 140 mg/l

96 h LC50: 0.073 mg/l

Toxicity to algae : Alcohols, C9-11, ethoxylated 96 h EC50 Pseudokirchneriella subcapitata (algae): 1.4 mg/l

72 h EC50 Pseudokirchneriella subcapitata (algae): 0.122 mg/l

Persistence and degradability

Not applicable - Biocide

Product AT USE DILUTION Not applicable - Biocide

Bioaccumulative potential

No data available

Mobility in soil

No data available

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Dispose of in accordance with local, state, and federal regulations.

RCRA - Resource Conservation and Recovery Authorization Act Hazardous waste

: D002 (Corrosive)

Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of contents/ container to an approved landfill.

Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Dispose of in accordance with local, state, and federal regulations.

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SECTION 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.

Land transport (DOT)

UN number : 3267

Description of the goods : Corrosive liquid, basic, organic, n.o.s.

(quaternary ammonium compound)

Class : 8

Packing group : III

Environmentally hazardous : no

Sea transport (IMDG/IMO)

UN number : 3267 Description of the goods : CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.

(quaternary ammonium compound) Class : 8 Packing group : III Marine pollutant : yes

SECTION 15. REGULATORY INFORMATION

EPA Registration number : 1677-233

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards

: Acute toxicity (any route of exposure) Skin corrosion or irritation Serious eye damage or eye irritation

SARA 302 : This material does not contain any components with a section 302

EHS TPQ.

SARA 313

: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

California Prop. 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.

California Cleaning Product Right to Know Act of 2017 (SB 258)

This regulation applies to this product.

Chemical Name CAS-No. Function List(s)

914273 12 / 13 water 7732-18-5 Diluent Not Applicable

Quaternary ammonium compounds, di-C8-10-alkyldimethyl, chlorides

68424-95-3 Biocide Not Applicable

Alkyl (C14 50%, C12 40%, C16 10%) dimethyl benzyl ammonium chloride

68424-85-1 Biocide Not Applicable

Alcohols, C9-11, ethoxylated 68439-46-3 Cleaning Agent Not Applicable

Tetrasodium EDTA 64-02-8 Cleaning Agent Not Applicable

Dioctyl dimethyl ammonium chloride

5538-94-3 Biocide Not Applicable disodium metasilicate 6834-92-0 Film Former Not Applicable

Pine, Pinus palustris, ext 97435-14-8 Fragrance Not Applicable

Colorant Withheld Dye Not Applicable citrus, ext. 94266-47-4 Fragrance Not Applicable

Cinnamal 104-55-2 Fragrance FRA

Methyl Salicylate 119-36-8 Fragrance Not Applicable

3-cyclohexene-1-methanol, .alpha.,.alpha.,4-trimethyl-

98-55-5 Fragrance Not Applicable

Colorant Withheld Dye Not Applicable

*refer to ecolab.com/sds for electronic links to designated lists

The ingredients of this product are reported in the following inventories:

United States TSCA Inventory :

On the inventory, or in compliance with the inventory

Canadian Domestic Substances List (DSL) :

All components of this product are on the Canadian DSL

Australia. Australian Industrial Chemicals Introduction Scheme (AICIS) :

not determined

New Zealand. Inventory of Chemical Substances :

On the inventory, or in compliance with the inventory

Japan. ENCS - Existing and New Chemical Substances Inventory :

On the inventory, or in compliance with the inventory

Korea. Korean Existing Chemicals Inventory (KECI) :

On the inventory, or in compliance with the inventory

Philippines Inventory of Chemicals and Chemical Substances (PICCS) :

On the inventory, or in compliance with the inventory

China. Inventory of Existing Chemical Substances in China (IECSC) :

On the inventory, or in compliance with the inventory

Taiwan Chemical Substance Inventory (TCSI) :

not determined

SECTION 16. OTHER INFORMATION

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NFPA: HMIS III:

NFPA: HMIS III:

Issuing date : 03/15/2021 Version : 1.7 Prepared by : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Flammability

H e a lt h

In s ta b ility

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

Special hazard 0 = not significant, 1 = Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic

Flammability

H e a lt h

In s ta b ility

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

Special hazard 0 = not significant, 1 = Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic