034126 Kavo Spray SDS.pdf

KaVo Spray 2112

Safety Data Sheet according to Regulation (EC) No 1907/2006

SECTION 1: Identification of the substance/mixture and of the company/undertaking

KaVo Spray 2112

1.1. Product identifier

Product code:

0.411.9630 0.411.9640

KaVo Spray, KaVo Spray 2112 A Further trade names

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture The product is intended for professional use.

1.3. Details of the supplier of the safety data sheet

Kaltenbach & Voigt GmbH Company name:

Bismarckring 39 Street:

D-88400 Biberach Place:

Telephone: +49 (0) 7351 56 0 Telefax:+ 49 (0) 7351 56 1488 e-mail: sdb@kavo.com e-mail (Contact person): support@gefahrstoff.com http://www.kavo.com/ Internet:

Questions concerning SDB: PES-Ingenieurgesellschaft mbH Responsible Department:

+49 (0) 7351 56 4000 (24 h) 1.4. Emergency telephone number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008 Hazard categories:

Aerosol: Aerosol 1 Hazard Statements:

Extremely flammable aerosol.

Pressurised container: May burst if heated.

2.2. Label elements

Regulation (EC) No. 1272/2008 Signal word: Danger

Pictograms:

H222 Extremely flammable aerosol.

H229 Pressurised container: May burst if heated.

Hazard statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P211 Do not spray on an open flame or other ignition source.

P251 Do not pierce or burn, even after use.

P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

Precautionary statements

Revision No: 2,0 - Replaces version: 1,9 Revision date: 11.11.2015 GB - EN

Item# 034126 according to Regulation (EC) No 1907/2006

In case of insufficient ventilation and/or through use, explosive/highly flammable mixtures may develop.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components

Quantity Chemical name CAS No EC No Index No REACH No

Classification according to Regulation (EC) No. 1272/2008 [CLP]

8042-47-5 White mineral oil (petroleum) 25 - < 50 %

232-455-8 01-2119487078-27 Asp. Tox. 1; H304

Full text of H and EUH statements: see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Provide fresh air.

After inhalation

Wash with plenty of water. Change contaminated clothing.

After contact with skin

Rinse immediately carefully and thoroughly with eye-bath or water.

After contact with eyes

Rinse mouth immediately and drink plenty of water.

After ingestion

4.2. Most important symptoms and effects, both acute and delayed No information available.

4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Carbon dioxide (CO2), Foam, Extinguishing powder.

Suitable extinguishing media

Full water jet Unsuitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Extremely flammable. Combustible. Vapours can form explosive mixtures with air.

Danger of bursting container.

In case of fire: Wear self-contained breathing apparatus.

5.3. Advice for firefighters

Use water spray jet to protect personnel and to cool endangered containers. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.

Additional information

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures according to Regulation (EC) No 1907/2006

Remove all sources of ignition. Provide adequate ventilation.

Do not allow uncontrolled discharge of product into the environment. Danger of explosion.

6.2. Environmental precautions

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).

Treat the recovered material as prescribed in the section on waste disposal.

6.3. Methods and material for containment and cleaning up

Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Do not pierce or burn, even after use.

Advice on safe handling

Do not spray on naked flames or any incandescent material. Protect from sunlight. Do no expose to temperatures exceeding 50°C/122°F. Keep away from sources of ignition. - No smoking. Take precautionary measures against static discharges. Vapours can form explosive mixtures with air.

Advice on protection against fire and explosion

7.2. Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a cool, well-ventilated place. Keep away from sources of ignition. - No smoking.

Requirements for storage rooms and vessels

Do not store together with: Material, oxygen-rich, oxidizing. Oxidising agent. Pyrophoric or self-heating substances.

Advice on storage compatibility

Protect from frost. Protect against direct sunlight.

Further information on storage conditions

7.3. Specific end use(s)

The product is intended for professional use.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

Category fibres/mlmg/m³ppmSubstance CAS No Origin

TWA (8 h) 600Butane 106-97-8 1450 WEL

STEL (15 min) 750 1810 WEL none Additional advice on limit values

8.2. Exposure controls

If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe Appropriate engineering controls according to Regulation (EC) No 1907/2006 gas/fumes/vapour/spray. If handled uncovered, arrangements with local exhaust ventilation should be used if possible.

Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands and face before breaks and after work and take a shower if necessary. When using do not eat or drink.

Protective and hygiene measures

Wear eye/face protection.

Eye/face protection

When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.

Hand protection

Flame-retardant protective clothing. Wear anti-static footwear and clothing Skin protection

In case of inadequate ventilation wear respiratory protection.

Suitable respiratory protection apparatus: Combination filtering device (EN 14387) Filtering device with filter or ventilator filtering device of type: AX

Respiratory protection light yellow liquid (Aerosol) Physical state:

Colour:

9.1. Information on basic physical and chemical properties

SECTION 9: Physical and chemical properties odourless Odour:

Test method pH-Value: not determined

Changes in the physical state not determinedMelting point:

-40 °CInitial boiling point and boiling range:

- 80 °CFlash point:

Flammability not applicableSolid:

not applicableGas:

Vapours can form explosive mixtures with air.

Explosive properties

1 vol. %Lower explosion limits:

11 vol. %Upper explosion limits:

> 350 °CIgnition temperature:

Auto-ignition temperature not applicableSolid:

not applicableGas:

Decomposition temperature: not determined

Not oxidizing.

Oxidizing properties not determinedVapour pressure:

according to Regulation (EC) No 1907/2006

Density (at 20 °C): 0,853 g/cm³ DIN 51757

Water solubility: insoluble

Solubility in other solvents not determined not determinedPartition coefficient:

not determinedViscosity / dynamic:

Viscosity / kinematic: 15,5 mm²/s not determinedVapour density:

Evaporation rate: not determined

9.2. Other information

Odour threshold: not determined

SECTION 10: Stability and reactivity

10.1. Reactivity

Extremely flammable. Ignition hazard.

10.2. Chemical stability

The product is stable under storage at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Vapours can form explosive mixtures with air.

Heating causes rise in pressure with risk of bursting.

Keep away from sources of heat (e.g. hot surfaces), sparks and open flames.

10.4. Conditions to avoid

No information available.

10.5. Incompatible materials

No known hazardous decomposition products.

10.6. Hazardous decomposition products

Do not mix with other chemicals.

Further information

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity Based on available data, the classification criteria are not met.

Chemical name CAS No

Species Dose Method Exposure routes Source

8042-47-5 White mineral oil (petroleum)

Rat LD50 > 5000 mg/kg Manufacturer oral

Rabbit LD50 > 2000 mg/kg Manufacturer dermal inhalative (4 h) aerosol LC50 > 5000 mg/l Rat Manufacturer

Irritation and corrosivity Based on available data, the classification criteria are not met.

Irritating to eyes. Repeated exposure may cause skin dryness or cracking.

Sensitising effects Based on available data, the classification criteria are not met.

according to Regulation (EC) No 1907/2006

STOT-single exposure Based on available data, the classification criteria are not met.

Severe effects after repeated or prolonged exposure Based on available data, the classification criteria are not met.

Carcinogenic/mutagenic/toxic effects for reproduction Based on available data, the classification criteria are not met.

Aspiration hazard Based on available data, the classification criteria are not met.

This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [CLP].

Additional information on tests

SECTION 12: Ecological information

12.1. Toxicity

The product is not: Ecotoxic.

CAS No Chemical name [h] | [d] Aquatic toxicity Method Dose Source Species

White mineral oil (petroleum) 8042-47-5

Acute fish toxicity 96 h Manufacturer LC50 > 100 mg/l Brachydanio rerio (zebra-fish)

Acute algae toxicity 72 h Manufacturer ErC50 > 100 mg/l Desmodesmus subspicatus.

Acute crustacea toxicity 48 h Manufacturer EC50 > 100 mg/l Daphnia magna (Big water flea)

12.2. Persistence and degradability

The product has not been tested.

12.3. Bioaccumulative potential

The product has not been tested.

Partition coefficient n-octanol/water

Log Pow Chemical name CAS No 8042-47-5 > 3,5 White mineral oil (petroleum)

The product has not been tested.

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

The product has not been tested.

No information available.

12.6. Other adverse effects

Avoid release to the environment.

Further information

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation.

Waste disposal number of waste from residues/unused products according to Regulation (EC) No 1907/2006

160504 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded chemicals; gases in pressure containers (including halons) containing hazardous substances Classified as hazardous waste.

Waste disposal number of used product WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded chemicals; gases in pressure containers (including halons) containing hazardous substances Classified as hazardous waste.

160504

Waste disposal number of contaminated packaging

WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE

CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste); metallic packaging

150104

Completely emptied packages can be recycled.

For cleaning up: Water

Contaminated packaging

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: UN 1950

AEROSOLS 14.2. UN proper shipping name:

2 14.3. Transport hazard class(es):

14.4. Packing group: -

Hazard label: 2.1

Classification code: 5F Special Provisions: 190 327 344 625 Limited quantity: 1 L Excepted quantity: E0 Transport category: 2 Tunnel restriction code: D

Inland waterways transport (ADN)

14.1. UN number: UN 1950

14.2. UN proper shipping name: AEROSOLS

14.3. Transport hazard class(es): 2

14.4. Packing group: -

Hazard label: 2.1

5F Classification code:

190 327 344 625 Special Provisions:

Limited quantity: 1 L Excepted quantity: E0

Marine transport (IMDG)

14.1. UN number: UN 1950

according to Regulation (EC) No 1907/2006

AEROSOLS 14.2. UN proper shipping name:

14.3. Transport hazard class(es): 2.1

14.4. Packing group: -

Hazard label: 2.1

63, 190, 277, 327, 344, 959 Special Provisions:

Limited quantity: 1000 mL Excepted quantity: E0 EmS: F-D, S-U

Air transport (ICAO)

14.1. UN number: UN 1950

AEROSOLS, flammable 14.2. UN proper shipping name:

2.1 14.3. Transport hazard class(es):

- 14.4. Packing group:

Hazard label: 2.1

Special Provisions: A145 A167 A802 Limited quantity Passenger: 30 kg G

Y203 Passenger LQ:

Excepted quantity: E0

203 IATA-packing instructions - Passenger:

75 kg IATA-max. quantity - Passenger:

203 IATA-packing instructions - Cargo:

150 kg IATA-max. quantity - Cargo:

14.5. Environmental hazards

no ENVIRONMENTALLY HAZARDOUS:

14.6. Special precautions for user

Warning: Flammable gases.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulatory information

59,82 % 2010/75/EU (VOC):

Information according to 2012/18/EU

(SEVESO III):

P3a FLAMMABLE AEROSOLS

Additional information:

National regulatory information

Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC).

Employment restrictions:

1 - slightly water contaminating Water contaminating class (D):

according to Regulation (EC) No 1907/2006

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Changes This data sheet contains changes from the previous version in section(s): 7.

Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50%

H222 Extremely flammable aerosol.

H229 Pressurised container: May burst if heated.

H304 May be fatal if swallowed and enters airways.

Relevant H and EUH statements (number and full text)

The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

Further Information