082040 Ecolab 903709 GEL HAND SANITIZER SDS.pdf

SAFETY DATA SHEET

GEL HAND SANITIZER

903709-10 1 / 8

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : GEL HAND SANITIZER

Other means of identification : Not applicable.

Recommended use : Hand Sanitizer

Restrictions on use : Reserved for industrial and professional use.

Product dilution information : Product is sold ready to use.

Company : Ecolab Co.

5105 Tomken Road Mississauga, Ontario Canada L4W 2X5 1-800-352-5326

Emergency health information

: 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US)

Issuing date : 12/14/2020

Section: 2. HAZARDS IDENTIFICATION

GHS Classification Flammable liquids : Category 3 Eye irritation : Category 2A

GHS Label element Hazard pictograms :

Signal Word : Warning

Hazard Statements : Flammable liquid and vapour.

Causes serious eye irritation.

Precautionary Statements : Prevention:

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed.

Response:

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.

Storage:

Store in a well-ventilated place. Keep cool.

Disposal:

Dispose of contents/ container to an approved waste disposal plant.

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical Name CAS-No. Concentration: (%)

ITEM# 082040

903709-10 2 / 8 ethanol 64-17-5 60 - 100 Isopropyl Alcohol 67-63-0 5 - 10

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse with water.

In case of skin contact : Rinse with water.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Get medical attention if symptoms occur.

Protection of first-aiders : No special precautions are necessary for first aid responders.

Notes to physician : Treat symptomatically.

Most important symptoms and effects, both acute and delayed

: See Section 11 for more detailed information on health effects and symptoms.

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

: High volume water jet

Specific hazards during firefighting

: Fire Hazard Keep away from heat and sources of ignition.

Flash back possible over considerable distance.

Beware of vapours accumulating to form explosive concentrations.

Vapours can accumulate in low areas.

Hazardous combustion products

: Decomposition products may include the following materials:

Carbon oxides

Special protective equipment and precautions for firefighters

: Use personal protective equipment.

Specific extinguishing methods

: Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.

Risk of explosion. : Not available.

Section: 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

: Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so.

903709-10 3 / 8 containment and cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Keep away from fire, sparks and heated surfaces. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Open drum carefully as content may be under pressure. In case of mechanical malfunction, or if in contact with unknown dilution of product, wear full Personal Protective Equipment

(PPE).

Conditions for safe storage : Keep away from heat and sources of ignition. Keep in a cool, well-ventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers.

Storage temperature : 0 °C to 35 °C

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Form of exposure

Permissible concentration

Basis ethanol 64-17-5 TWA 1,000 ppm 1,880 mg/m3

CAD AB OEL

STEL 1,000 ppm CAD BC OEL VME 1,000 ppm

1,880 mg/m3

OEL (QUE)

ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3

NIOSH REL

TWA 1,000 ppm 1,900 mg/m3

OSHA Z1

Isopropyl Alcohol 67-63-0 TWA 200 ppm 492 mg/m3

STEL 400 ppm 984 mg/m3

TWA 200 ppm CAD BC OEL STEL 400 ppm CAD BC OEL VME 400 ppm

983 mg/m3

OEL (QUE)

STEV 500 ppm

1,230 mg/m3

OEL (QUE)

Isopropyl Alcohol 67-63-0 TWA 200 ppm ACGIH STEL 400 ppm ACGIH TWA 400 ppm

980 mg/m3

STEL 500 ppm

1,225 mg/m3

TWA 400 ppm

980 mg/m3

OSHA Z1

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Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.

Personal protective equipment

Eye protection : No special protective equipment required.

Hand protection : No special protective equipment required.

Skin protection : No special protective equipment required.

Respiratory protection : No personal respiratory protective equipment normally required.

Hygiene measures : No specific measures identified.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : gel

Colour : clear, colourless

Odour : alcohol-like pH : 6.6 - 7.5, (100 %)

Flash point : 24 °C closed cup

Odour Threshold : no data available

Melting point/freezing point : no data available

Initial boiling point and boiling range

: no data available

Evaporation rate : no data available

Flammability (solid, gas) : Not applicable.

Upper explosion limit : no data available

Lower explosion limit : no data available

Vapour pressure : no data available

Relative vapour density : no data available

Relative density : 0.84 - 0.844

Water solubility : no data available

Solubility in other solvents : no data available

Partition coefficient: n-octanol/water

: no data available

Auto-ignition temperature : no data available

Thermal decomposition : no data available

Viscosity, kinematic : no data available

Explosive properties : no data available

Oxidizing properties : no data available

Molecular weight : no data available

VOC : no data available

Section: 10. STABILITY AND REACTIVITY

903709-10 5 / 8

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : Stable under normal conditions.

Possibility of hazardous reactions

: No dangerous reaction known under conditions of normal use.

Conditions to avoid : Heat, flames and sparks.

Incompatible materials : None known.

Hazardous decomposition products

: In case of fire hazardous decomposition products may be produced such as:

Carbon oxides

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

: Inhalation, Eye contact, Skin contact

Potential Health Effects

Eyes : Causes serious eye irritation.

Skin : Health injuries are not known or expected under normal use.

Ingestion : Health injuries are not known or expected under normal use.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact : Redness, Pain, Irritation

Skin contact : No symptoms known or expected.

Ingestion : No symptoms known or expected.

Inhalation : No symptoms known or expected.

Toxicity

Product Acute oral toxicity : no data available

Acute inhalation toxicity : 4 h Acute toxicity estimate : > 40 mg/l Test atmosphere: vapour

Acute dermal toxicity : no data available

Skin corrosion/irritation : no data available

Serious eye damage/eye irritation

: no data available

Respiratory or skin sensitization

: no data available

Carcinogenicity : no data available

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Reproductive effects : no data available

Germ cell mutagenicity : no data available

Teratogenicity : no data available

STOT - single exposure : no data available

STOT - repeated exposure : no data available

Aspiration toxicity : no data available

Components Acute oral toxicity : ethanol

LD50 rat: 10,470 mg/kg

Isopropyl Alcohol LD50 rat: 5,840 mg/kg

Components Acute dermal toxicity : ethanol

LD50 rabbit: 15,800 mg/kg

LD50 rabbit: 12,870 mg/kg

Section: 12. ECOLOGICAL INFORMATION

Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects.

Product Toxicity to fish : no data available

Toxicity to daphnia and other aquatic invertebrates

: no data available

Toxicity to algae : no data available

Components Toxicity to fish : ethanol

96 h LC50 Pimephales promelas (fathead minnow): > 100 mg/l

96 h LC50 Pimephales promelas (fathead minnow): 9,640 mg/l

Components Toxicity to daphnia and other aquatic invertebrates

: ethanol 48 h EC50 Aquatic Invertebrate: 857 mg/l

LC50 Daphnia magna (Water flea): > 10,000 mg/l

Persistence and degradability Readily biodegradable.

Bioaccumulative potential no data available

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Mobility in soil no data available

Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS

Disposal methods : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Dispose of in accordance with local, state, and federal regulations.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.

Land transport (TDG)

UN number : 1170 Description of the goods : ETHANOL SOLUTION Class : 3 Packing group : III Environmentally hazardous : No

Sea transport (IMDG/IMO)

UN number : 1170 Description of the goods : ETHANOL SOLUTION Class : 3 Packing group : III Marine pollutant : No

Section: 15. REGULATORY INFORMATION

This product has been classified according to the hazard criteria of the HPR and the SDS contains all of the information required by the HPR.

NPRI Components : Isopropyl Alcohol

The components of this product are reported in the following inventories:

Switzerland. New notified substances and declared preparations :

not determined

United States TSCA Inventory :

All substances listed as active on the TSCA inventory

Canadian Domestic Substances List (DSL) :

All components of this product are on the Canadian DSL.

Australia. Australian Industrial Chemicals Introduction Scheme (AICIS) :

not determined

903709-10 8 / 8

New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand :

not determined

Japan. ENCS - Existing and New Chemical Substances Inventory :

not determined

Korea. Korean Existing Chemicals Inventory (KECI) :

not determined

Philippines Inventory of Chemicals and Chemical Substances (PICCS) :

not determined

China Inventory of Existing Chemical Substances :

On the inventory, or in compliance with the inventory

Taiwan Chemical Substance Inventory :

not determined

Section: 16. OTHER INFORMATION

NFPA: HMIS III:

Issuing date : 12/14/2020 Version : 1.3 Prepared by : Regulatory Affairs 1-800-352-5326

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Flammability

H ea lth

Instability

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

Special hazard. 0 = not significant, 1 = Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic