052515 Kodak X-OMAT Developer and Replenisher SDS.pdf

MATERIAL SAFETY DATA SHEET

Page 1 / 8

Issuing date 2013-03-29 Revision Date 2013-03-29 Version 1.04

Supplier Carestream Health Canada, 8800 Dufferin Street, Suite 201, Vaughan, Ontario, L4K 0C5

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product Use: Photographic chemical.

Product code: 1249259B

Product name: KODAK RP X-OMAT Developer and Replenisher, Part B RP X-OMAT Developer and Replenisher, Part B

For Emergency Health Information call: 800-424-9300

2. HAZARDS IDENTIFICATION

For other information contact: 1-866-792-5011

Inhalation May be harmful if inhaled. Irritating to mucous membranes. May cause irritation of respiratory tract.

Potential Health Effects

Ingestion

Aggravated Medical Conditions Preexisting eye disorders. Skin disorders. Respiratory disorders.

May be harmful if swallowed. Ingestion causes burns of the upper digestive and respiratory tracts. Can burn mouth, throat, and stomach.

DANGER!

Eyes Causes burns. Corrosive to the eyes and may cause severe damage including blindness.

Risk of serious damage to eyes.

Environmental hazard Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 12 for additional Ecological Information.

Emergency Overview Corrosive

The product causes burns of eyes, skin and mucous membranes May be harmful if swallowed, inhaled, or absorbed through skin

Contains a known or suspected reproductive toxin

Chronic Effects

Skin Causes burns.

Chronic toxicity Avoid repeated exposure. Possible risks of irreversible effects. Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common.

Gastrointestinal disturbances may also be seen. Contains a known or suspected reproductive toxin.

Physical state liquid

Flammability - 1HMIS Health Hazard - 3*

Color orange

Physical Hazard

- 0

Odor Pungent

Item# 052515

Version 1.04

Page 2 / 8

Product code: 1249259B

Revision Date 2013-03-29

Use personal protective equipment. Avoid contact with skin, eyes and clothing.

10-15

5. FIRE-FIGHTING MEASURES

General advice Immediate medical attention is required. Show this material safety data sheet to the doctor in attendance.

Non-Hazardous

Flash point: > 93.4 °C

Chemical Name CAS-No

Eye contact

Suitable Extinguishing Media The product is not flammable. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Immediate medical attention is required. Rinse thoroughly with plenty of water, also under the eyelids. Keep eye wide open while rinsing. If easy to do, remove contact lens, if worn.

Chemical Name CAS-No

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.

Weight %

Weight %

Skin contact Immediate medical attention is required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes.

Hazardous Combustion Products Hazardous decomposition products due to incomplete combustion: Carbon oxides, Hydrocarbons, Aldehydes.

Water 7732-18-5

Specific hazards arising from the chemical The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating gases and vapors. In the event of fire and/or explosion do not breathe fumes.

20 - 25

Inhalation Immediate medical attention is required. Move to fresh air. Artificial respiration and/or oxygen may be necessary.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

Acetic acid

Ingestion Immediate medical attention is required. Do NOT induce vomiting. Drink plenty of water.

Never give anything by mouth to an unconscious person.

64-19-7 60-70

3. COMPOSITION/INFORMATION ON INGREDIENTS

Notes to physician Probable mucosal damage may contraindicate the use of gastric lavage. Treat symptomatically.

Hazardous

4. FIRST AID MEASURES

3-Pyrazolidinone, 1-phenyl- 92-43-3

Protection of First-aiders

NFPA Flammability - 1

Stability - 0Health Hazard - 3

Product code: 1249259B

Revision Date 2013-03-29 Version 1.04

Page 3 / 8

TWA: 10 ppm TWA: 25 mg/m3

Occupational Exposure Controls

Advice on safe handling Use only in area provided with appropriate exhaust ventilation. Wear personal protective equipment. Do not breathe vapors or spray mist. Do not get in eyes, on skin, or on clothing.

When using, do not eat, drink or smoke. Wash thoroughly after handling. Keep container tightly closed.

Engineering Measures Apply technical measures to comply with the occupational exposure limits. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Handle product only in closed system or provide appropriate exhaust ventilation at machinery. Ensure that eyewash stations and safety showers are close to the workstation location.

Methods for cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Take up mechanically and collect in suitable container for disposal. Clean contaminated surface thoroughly.

Personal Protective Equipment

Technical measures/Storage conditions

General Information These recommendations apply to the product as supplied.

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep at temperatures between 5°C and 30°C.

Respiratory protection Use only with adequate ventilation. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn.

6. ACCIDENTAL RELEASE MEASURES

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Other information

Eye/Face Protection Tightly fitting safety goggles. Face-shield.

Refer to protective measures listed in Sections 7 and 8.

Methods for Containment

Skin and body protection Impervious clothing.

Prevent further leakage or spillage if safe to do so.

Exposure Guidelines

Hand Protection Impervious gloves.

Personal precautions

Chemical Name ACGIH TLV AIHA - Workplace Environmental Exposure Levels (WEELs) - TWAs

OSHA PEL Advisory OEL

Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Use personal protective equipment. Do not touch or walk through spilled material. Ensure adequate ventilation. Avoid breathing vapors or mists. Avoid contact with skin, eyes and clothing.

7. HANDLING AND STORAGE

Acetic acid 64-19-7

STEL 15 ppm TWA: 10 ppm

Page 4 / 8

Product code: 1249259B

Revision Date 2013-03-29

Acute toxicity - Product Information

Stability Stable under normal conditions.

Density 1.083 g/cm3

Skin Causes burns.

Water Solubility completely soluble

Incompatible products Amines. Metals. Bases. Strong oxidizing agents.

Eyes Causes burns. Corrosive to the eyes and may cause severe damage including blindness. Risk of serious damage to eyes.

Melting point/range: No information available

Inhalation May be harmful if inhaled. Irritating to mucous membranes. May cause irritation of respiratory tract.

Conditions to Avoid Exposure to air or moisture over prolonged periods. Heat, flames and sparks.

Ingestion May be harmful if swallowed. Ingestion causes burns of the upper digestive and respiratory tracts. Can burn mouth, throat, and stomach.

Specific Gravity No information available

Acute toxicity - Component Information

Hazardous Decomposition Products Thermal decomposition can lead to release of irritating gases and vapors. Carbon oxides.

Nitrogen oxides (NOx).

Bulk Density: No information available

9. PHYSICAL AND CHEMICAL PROPERTIES

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Acetic acid 3310 mg/kg ( Rat ) 1060 mg/kg ( Rabbit ) 11.4 mg/L ( Rat ) 4 h

Hazardous Polymerization

Water 90,000 mg/kg ( Rat )

Hazardous polymerization does not occur.

Vapor Pressure No information available

3-Pyrazolidinone, 1-phenyl- 200 mg/kg ( Rat )

Chemical Name Other applicable information

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION

Vapor density No information available

Autoignition temperature: No information availableFlash point: > 93.4 °C

Odor Pungent ph 0.6 Physical state liquid

Boiling point/boiling range No information available

Color orange

Product code: 1249259B

Revision Date 2013-03-29 Version 1.04

Page 5 / 8

Contains no ingredient listed as a carcinogen.

Ecotoxicity

Sensitization

Ecotoxicity effects Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

May cause sensitization of susceptible persons.

Component Information

3-Pyrazolidinone, 1-phenyl- Mild skin irritation

Mild skin irritation Repeated exposure

Mild eye irritation

Did not cause sensitization on laboratory animals guinea pig

Based on repeated-dose ingestion studies in animals, this chemical may cause blood, testicular, and adverse reproductive effects.

Chemical Name Toxicity to algae Toxicity to fish Toxicity to daphnia and other aquatic invertebrates

Reproductive toxicity Contains ingredients that are suspected reproductive hazards.

Acetic acid LC50= 79 mg/L Pimephales promelas 96 h LC50= 75 mg/L

Lepomis macrochirus 96 h

EC50 = 47 mg/L 24 h (Daphnia magna) EC50 = 65 mg/L 48 h

(Daphnia magna)

Chronic toxicity Avoid repeated exposure. Possible risks of irreversible effects. Chronic exposure to corrosive fumes/gases may cause erosion of the teeth followed by jaw necrosis. Bronchial irritation with chronic cough and frequent attacks of pneumonia are common.

Gastrointestinal disturbances may also be seen. Contains a known or suspected reproductive toxin.

Persistence and degradability

Subchronic toxicity No information available

Target Organ Effects

Bioaccumulation: - No information available

Respiratory system, Eyes, Skin, Teeth, Blood, Testes.

Acetic acid Severe eye irritation Severe skin irritation Acute overexposure to extremely high airborne concentrations of respiratory irritants has been associated with development of an asthma-like reactive airways syndrome (RADS) in susceptible individuals. Extremely high airborne concentrations are not generated during normal conditions of use but may occur following a spill. The potential to generate extremely high airborne concentrations in a spill situation depends upon physical factors such as the concentration of the solution, the volume of the spill, the surface area of the spill, the size of the room where the spill occured, and the ventilation rate in the room.

Carcinogenicity

12. ECOLOGICAL INFORMATION

Page 6 / 8

Product code: 1249259B

Revision Date 2013-03-29 Version 1.04

UN/ID No UN2790 Proper Shipping Name Acetic acid solution

The information given below is provided to assist in documentation. It may supplement the information on the package. The package in your possession may carry a different version of the label depending on the date of manufacture. Depending on inner packaging quantities and packaging instructions, it may be subject to specific regulatory exceptions. Please consult the product packaging for further details.

log Pow

Hazard class 8 Packing Group II

DOT

ICAO/IATA

13. DISPOSAL CONSIDERATIONS

UN/ID No UN2790 Proper Shipping Name Acetic acid solution

UN/ID No UN2790

Hazard class 8

Contaminated packaging Dispose of in accordance with local regulations.

Packing Group II

Proper Shipping Name

ERG Code 8L

Acetic acid solution

Acetic acid

IMDG/IMO

Hazard class 8

UN/ID No UN2790 Proper Shipping Name Acetic acid, solution

Packing Group

Hazard class 8

II

Packing Group II

-0.31

EmS No. F-A, S-B

Special Provisions A3, A6, A7, A10, B2, IB2, T7, TP2

Mobility - No information available

For transportation information, go to: http://ship.carestreamhealth.com.

Emergency Response Guide Number

Waste Disposal Methods

15. REGULATORY INFORMATION

14. TRANSPORT INFORMATION

Dispose of in accordance with local regulations.

Chemical Name

TDG

Revision Date 2013-03-29 Version 1.04

Page 7 / 8

Product code: 1249259B

Complies

NZIoC - New Zealand Inventory of Chemicals

PICCS Complies

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

AICS

16. OTHER INFORMATION

Complies

TSCA

NZIoC

Disclaimer for Label The data below reflects current legislative requirements whereas the product in your possession may carry a different version of the label depending on the date of manufacture.

Complies

Complies

DSL/NDSL

Legend

DANGER!

Complies

EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances

- Contains:

EINECS/ELINCS

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory

Complies

Hazardous Components

DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

Chemical Name CAS-No Weight %

ENCS

Acetic acid 64-19-7 60-70

ENCS - Japan Existing and New Chemical Substances

Complies

3-Pyrazolidinone, 1-phenyl- 92-43-3 10-15

WHMIS Hazard Class D2A Very toxic materials D2B Toxic materials E Corrosive material

IECSC - China Inventory of Existing Chemical Substances

International Inventories

IECSC

Corrosive. The product causes burns of eyes, skin and mucous membranes. May be harmful if swallowed, inhaled, or absorbed through skin.

Contains a known or suspected reproductive toxin.

KECL - Korean Existing and Evaluated Chemical Substances

Complies

PICCS - Philippines Inventory of Chemicals and Chemical Substances

KECL

AICS - Australian Inventory of Chemical Substances

Page 8 / 8

Product code: 1249259B

Revision Date 2013-03-29

Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Ensure adequate ventilation. Wash thoroughly after handling.

Additional information is given in the Material Safety Data Sheet.

Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text