038180 Carestream Dental 8606873 ReadyMatic SDS.pdf

SAFETY DATA SHEET

Revision Date 11/09/2018 Revision Number 1.01

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name: READYMATIC Fixer and Replenisher

Product Code(s) 8606873FIX

Supplier Carestream Health, Inc., 150 Verona Street, Rochester, NY, USA 14608

Emergency telephone number

CHEMTREC: +1-703-527-3887 (INTERNATIONAL)

1-800-424-9300 (NORTH AMERICA)

For other information contact: 800-328-2910

Recommended Use Restricted to professional users, Photographic chemical.

2. HAZARDS IDENTIFICATION

Classification

Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)

Label elements

Emergency Overview

Hazards not otherwise classified (HNOC)

• Not applicable

Other hazards which do not result in classification

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name CAS No. Weight-% Trade Secret Water

7732-18-5 7732-18-5 80-90 *

Ammonium thiosulfate 7783-18-8 10-15 *

Signal word No signal word

Hazard statements None

Appearance aqueous solution Physical state Liquid

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Odor Ammonia

ITEM# 038180

8606873FIX - READYMATIC Fixer and Replenisher Revision Date 11/09/2018

7783-18-8 Sodium bisulfite

7631-90-5 7631-90-5 1-3 *

Sodium borate 1330-43-4

1330-43-4 <1 *

*The exact percentages (concentrations) have been withheld as trade secrets.

4. FIRST AID MEASURES

First Aid Measures

General advice Show this safety data sheet to the doctor in attendance.

Eye contact IF IN EYES: Flush eyes for at least 15 minutes. If easy to do, remove contact lens, if worn.

Skin contact Wash off immediately with plenty of water for at least 15 minutes. Remove and wash contaminated clothing before re-use. Get medical attention immediately if symptoms occur.

Inhalation IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.

Ingestion IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Get medical attention.

Most important symptoms and effects, both acute and delayed

Main Symptoms None known.

Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media Carbon dioxide (CO2). Dry chemical. Foam.

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.

Specific hazards arising from the chemical Dried product residue can act as a reducing agent. Reacts violently with oxidizing materials. May cause spontaneous heating and ignition when absorbed on combustible, porous material (e.g. rags, paper, sawdust, cotton, clothing).

Hazardous combustion products Carbon oxides, Nitrogen oxides (NOx), Sulfur oxides.

Explosion data Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Personal precautions For personal protection see section 8. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Use personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

Other information Refer to protective measures listed in Sections 7 and 8.

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Environmental precautions

Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent entry into waterways, sewers, basements or confined areas.

Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so. Dike to collect large liquid spills.

Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Clean contaminated surface thoroughly.

7. HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Ensure adequate ventilation. Wash thoroughly after handling. Handle in accordance with good industrial hygiene and safety practice. In case of insufficient ventilation, wear suitable respiratory equipment. Wear personal protective equipment.

Conditions for safe storage, including any incompatibilities

Technical measures/Storage conditions

Keep containers tightly closed in a dry, cool and well-ventilated place. Keep in properly labeled containers.

Incompatible products Acids. Strong bases. Oxidizing agents. Halogenated compounds. Sodium hypochlorite.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines .

Chemical name ACGIH TLV AIHA - Workplace

Environmental Exposure Levels (WEELs) - TWAs

OSHA PEL Advisory OEL

Sodium bisulfite 7631-90-5

TWA: 5 mg/m3 -

Sodium borate 1330-43-4

STEL 6 mg/m3

TWA: 2 mg/m3

Appropriate engineering controls

Engineering Measures Ensure adequate ventilation. Apply technical measures to comply with the occupational exposure limits. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Ensure that eyewash stations and safety showers are close to the workstation location.

Individual protection measures, such as personal protective equipment

Eye/Face Protection Safety glasses with top and side-shields.

Skin and body protection Long sleeved clothing. Protective gloves. Skin contact should be prevented through use of suitable protective clothing, gloves, and footwear, selected with regard of use conditions and exposure potential.

Respiratory protection None required under normal conditions. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Respiratory protection must be provided in accordance with current local regulations. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. None required under normal usage.

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Hygiene measures Remove and wash contaminated clothing before re-use. When using, do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. Provide regular cleaning of equipment, work area and clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL AND CHEMICAL PROPERTIES

Physical state Liquid

10. STABILITY AND REACTIVITY

Reactivity

Chemical stability Stable under recommended storage conditions.

Possibility of hazardous reactions None under normal processing. Contact with strong acids liberates sulfur dioxide. Contact with sodium hypochlorite (bleach) may form chloramine (toxic gas). Contact with strong bases liberates ammonia.

Conditions to Avoid Do not freeze. Extreme pH's.

Appearance aqueous solution Odor Ammonia Color light yellow Odor threshold No information available

Property Values Remarks • Method pH 4.4 Melting point / freezing point No information available Boiling point / boiling range > 100 °C / 212 °F Flash point > 93 °C / 200 °F .

Evaporation rate No information available Flammability (solid, gas) no data available Upper flammability limit: Unknown Lower flammability limit: Not flammable

Vapor pressure 24 mbar @ 20 °C Vapor density 0.6 Specific Gravity 1.09 No information available Water solubility completely soluble Solubility(ies) No information available.

Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Oxidizing Properties No information available Explosive properties No information available

Other information

Softening point No information available Molecular weight No information available Liquid Density No information available Bulk density No information available

No dangerous reaction known under conditions of normal use.

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Incompatible Materials Acids. Strong bases. Oxidizing agents. Halogenated compounds. Sodium hypochlorite.

Hazardous decomposition products Ammonia. Chloramine. Sulfur oxides. Nitrogen oxides (NOx).

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information

Inhalation Expected to be a low hazard for recommended handling. May cause irritation of respiratory tract.

Eye contact May cause slight irritation.

Skin contact Substance may cause slight skin irritation.

Ingestion Expected to be a low hazard for recommended handling. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Toxicology data for the components Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Water 7732-18-5

90,000 mg/kg ( Rat ) - -

Ammonium thiosulfate 7783-18-8

> 2000 mg/kg ( Rat ) - -

Sodium bisulfite 7631-90-5

1420 mg/kg ( Rat ) - -

Sodium borate 1330-43-4

2660 mg/kg ( Rat ) Oral LD50 Rat 2660 mg/kg (Source:

JAPAN_GHS)

2000 mg/kg ( Rabbit ) Dermal LD50 Rabbit >2000 mg/kg

(Source: IUCLID)

2 mg/m3 ( Rat ) 4 h Inhalation LC50 Rat >2 mg/m3 4 h

(Source: HSDB)

Component Information

Information on toxicological effects

Symptoms Symptoms of allergic reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness, lightheadedness, chest pain, muscle pain, or flushing.

Severe eye irritation or burning.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation Substance may cause slight skin irritation.

Serious eye damage/eye irritation May cause slight irritation.

Sensitization May cause sensitization of susceptible persons.

Mutagenic effects No information available.

Carcinogenicity Contains no ingredients above reportable quantities listed as a carcinogen.

Reproductive toxicity Contains a known or suspected reproductive toxin. However, based on available data the product should not be classified for reproductive effects.

STOT - single exposure The substance or mixture is not classified as specific target organ toxicant, single exposure STOT - repeated exposure The substance or mixture is not classified as specific target organ toxicant, repeat exposure

Target Organ Effects Eyes, Skin, Respiratory system.

Aspiration Hazard No information available.

Numerical measures of toxicity - Product Information

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The following values are calculated based on chapter 3.1 of the GHS document .

ATEmix (oral) 16142 mg/kg ATEmix (dermal) 63095 mg/kg ATEmix (inhalation-dust/mist) 678.6

12. ECOLOGICAL INFORMATION

Ecotoxicity

The environmental impact of this product has not been fully investigated.

Chemical name Toxicity to algae Toxicity to fish Toxicity to microorganisms

Toxicity to daphnia and other aquatic invertebrates

Sodium bisulfite 7631-90-5

240: 96 h Gambusia affinis mg/L LC50 static

119: 48 h Daphnia magna mg/L EC50

Sodium borate 1330-43-4

158: 96 h Desmodesmus subspicatus mg/L EC50 2.6 -

21.8: 96 h Pseudokirchneriella subcapitata mg/L EC50 static

340: 96 h Limanda limanda mg/L LC50

1085 - 1402: 48 h Daphnia magna mg/L LC50

Persistence and degradability Expected to be readily biodegradable

Bioaccumulation: No information available

Mobility in soil No information available

Other adverse effects No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Waste Disposal Methods Dispose of in accordance with local regulations.

Contaminated packaging Do not re-use empty containers. Dispose of in accordance with local regulations.

This product contains one or more substances that are listed with the State of California as a hazardous waste.

14. TRANSPORT INFORMATION

The information given below is provided to assist in documentation. It may supplement the information on the package. The package in your possession may carry a different version of the label depending on the date of manufacture. Depending on inner packaging quantities and packaging instructions, it may be subject to specific regulatory exceptions. Please consult the product packaging for further details.

DOT Not regulated

TDG Not regulated

IATA Not regulated

IMDG Not regulated

For transportation information, go to: http://ship.carestream.com

15. REGULATORY INFORMATION

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International Inventories

TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies NZIoC Complies

Legend EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals

U.S. Federal Regulations

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

Chemical name SARA 313 - Threshold Values % Ammonium thiosulfate - 7783-18-8 1.0

SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No

Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42):

Chemical name CWA - Reportable Quantities

CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances

Ammonium acetate 5000 lb X Sodium bisulfite 5000 lb X

Aluminum sulfate 5000 lb X Acetic acid 5000 lb X

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product contains the following substances which are listed hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act:

CERCLA

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):

Chemical name Hazardous Substances RQs Extremely Hazardous Substances RQs

SARA Product RQ

Sodium bisulfite 5000 lb

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TSCA

Chemical name U.S. - TSCA (Toxic Substances Control Act) - Section 8(a) - Chemical-Specific Reporting and Recordkeeping

Sodium bisulfite PAIR: 01/26/1994 Component U.S. - TSCA (Toxic Substances Control Act) - Section 8(d) -

716.120(a) - Health and Safety Reporting - List of Substances Sodium bisulfite

7631-90-5 ( 1-3 ) 01/26/1994

U.S. State Regulations

California Proposition 65 This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

Chemical name Massachusetts New Jersey Pennsylvania Illinois Rhode Island Ammonium thiosulfate X X

Sodium bisulfite X X X X Sodium borate X X

International Regulations

Mexico - Grade Moderate risk, Grade 2 Chemical name Carcinogen Status Exposure Limits Sodium borate Mexico: TWA 1 mg/m3

16. OTHER INFORMATION

Issuing Date 02/05/2014 Revision Date 11/09/2018 Revision Note Update to OSHA GHS SDS format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

NFPA Health Hazard 1 Flammability 1 Instability 0 HMIS Health Hazard 1 Flammability 1 Physical Hazard 0

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