J189742-1 Std_Tal_L4 Final Report_Part4.pdf

Quantitation Report

5/28/2025 2:56 PM

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Sc 45 1 No Gas 1519667.16

Ge 72 1 No Gas 620177.30

Ge 72 1 No Gas 629029.01

Ge 72 1 No Gas 631260.93

Sc 45 2 H2 155823.81

Sc 45 2 H2 157784.26

Sc 45 2 H2 156127.62

Ge 72 2 H2 109995.71

Ge 72 2 H2 110992.24

Ge 72 2 H2 110207.05

In 115 2 H2 228235.68

In 115 2 H2 231756.97

In 115 2 H2 231908.08

Sc 45 3 He 41934.16

Sc 45 3 He 42425.67

Sc 45 3 He 41323.05

Ge 72 3 He 66418.04

Ge 72 3 He 66810.26

Ge 72 3 He 64370.04

In 115 3 He 49900.49

In 115 3 He 48746.78

In 115 3 He 48335.71

Tb 159 3 He 143356.78

Tb 159 3 He 143811.01

Tb 159 3 He 142893.59

Bi 209 3 He 81547.81

Bi 209 3 He 82756.31

Bi 209 3 He 82785.27

Page 15001 of 16273

Data File Name 087SMPL.d

Acq/Data Batch C:\Agilent\ICPMH\1\DATA\25E28A00.b

Acq Time 5/28/2025 11:41:01 AM

Sample Name 410-222272-L-1-A

Sample Type Sample

MS T16 RRComment

Prep Dilution 1.0000

Auto Dilution 1.0000

Total Dilution 1.0000

Operator Name us19_usr_ins23851

SpectrumAcq Mode

---Cal Title

External CalibrationCal Type

5/28/2025 10:14:18 AMLast Calib

---Bkg File

Bkg Mode Count Subtraction except for ISTD

FQ BlankFile ---

Point to PointVIS Fit

FullQuant Table

Element Mass ISTD Tune Mode Conc. Units RSD(%) CPS Ratio Det. Time(sec) Rep

Be 9 72 No Gas 0.044 ppb 42.4 57.33 0.0001 Pulse 0.5000 3

Se 78 72 H2 0.076 ppb 31.9 5.11 0.0000 Pulse 1.5000 3

Na 23 45 He 164206.942 ppb 1.7 19212224.30 429.7376 Analog 0.1000 3

Mg 24 45 He 7942.838 ppb 0.7 472074.16 10.5593 Pulse 0.1000 3

Al 27 45 He 42.996 ppb 10.4 970.06 0.0217 Pulse 0.1000 3

K 39 45 He 5389.060 ppb 1.6 323884.43 7.2451 Pulse 0.5000 3

Ca 44 72 He 58482.892 ppb 1.1 166121.22 2.3717 Pulse 0.5000 3

Ti 47 45 He 0.519 ppb 37.9 14.67 0.0003 Pulse 0.5000 3

V 51 45 He 3.519 ppb 2.4 3687.77 0.0825 Pulse 0.5000 3

Cr 52 45 He -0.989 ppb N/A 3500.48 0.0783 Pulse 0.1000 3

Mn 55 45 He 45.242 ppb 1.5 23295.97 0.5210 Pulse 0.5000 3

Fe 57 45 He 61.656 ppb 2.7 1846.83 0.0413 Pulse 0.1000 3

Co 59 45 He 1.300 ppb 3.2 2839.60 0.0635 Pulse 0.5000 3

Ni 60 45 He 5.350 ppb 3.8 3587.75 0.0803 Pulse 0.5000 3

Cu 63 72 He 0.063 ppb 13.4 1072.04 0.0153 Pulse 0.5000 3

Zn 66 72 He 0.678 ppb 10.7 376.01 0.0054 Pulse 0.5000 3

As 75 72 He 0.776 ppb 10.4 170.00 0.0024 Pulse 0.5000 3

Sr 88 115 He 458.608 ppb 3.0 260513.78 5.1250 Pulse 0.1000 3

Mo 98 115 He 0.053 ppb 58.0 133.34 0.0026 Pulse 0.1000 3

Ag 107 115 He -0.009 ppb N/A 20.00 0.0004 Pulse 0.1000 3

Cd 111 72 He -0.002 ppb N/A 4.67 0.0001 Pulse 0.5000 3

Sn 120 115 He -0.229 ppb N/A 3210.43 0.0631 Pulse 0.1000 3

Sb 121 115 He 0.087 ppb 9.3 74.44 0.0015 Pulse 0.3000 3

Ba 137 115 He 15.647 ppb 6.8 3450.50 0.0679 Pulse 0.1000 3

Tl 205 159 He 0.009 ppb 60.9 73.33 0.0005 Pulse 0.1000 3

Pb 208 159 He -0.102 ppb N/A 530.02 0.0036 Pulse 0.1000 3

U 238 159 He 0.145 ppb 4.6 443.35 0.0030 Pulse 0.1000 3

ISTD Table:

Page 15002 of 16273

Tune Mode Element Mass CPS RSD(%) ISTD Recovery % Det. Time(seq) Rep

No Gas Sc 45 1562802.84 0.2 99.8 Analog 0.1000 3

No Gas Ge 72 659793.60 1.1 104.0 Pulse 0.1000 3

H2 Sc 45 165448.08 1.9 110.6 Pulse 0.1000 3

H2 Ge 72 118998.84 1.6 112.6 Pulse 0.1000 3

H2 In 115 243684.73 0.4 111.6 Pulse 0.1000 3

He Sc 45 44708.53 1.3 111.1 Pulse 0.1000 3

He Ge 72 70042.95 0.2 108.4 Pulse 0.1000 3

He In 115 50854.59 2.2 104.8 Pulse 0.1000 3

He Tb 159 149364.28 1.1 103.9 Pulse 0.1000 3

He Bi 209 85883.80 1.6 105.9 Pulse 0.1000 3

No Gas

Mass

10 20 30 40 50 60 70 80 90 100

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190 200

Co un t

5x10

Mass

210 220 230 240 250 260 270 280 290 300

Co un t

5x10

H2

Mass

10 20 30 40 50 60 70 80 90

Co un t

4x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

4x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

4x10

Page 15003 of 16273

He

Mass

10 20 30 40 50 60 70 80 90

Co un t

6x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

6x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

6x10

Replicate:

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Be 9 1 No Gas 0.036 0.0001 52.00 0.0009 4.831E-05

Be 9 1 No Gas 0.031 0.0001 50.00 0.0009 4.831E-05

Be 9 1 No Gas 0.066 0.0001 70.00 0.0009 4.831E-05

Se 78 2 H2 0.069 0 4.67 0.0005 8.428E-06

Se 78 2 H2 0.056 0 4.00 0.0005 8.428E-06

Se 78 2 H2 0.103 0.0001 6.67 0.0005 8.428E-06

Na 23 3 He 161092.082 421.6065 18821123.47 0.0026 1.085

Na 23 3 He 166753.524 436.3853 19275318.46 0.0026 1.085

Na 23 3 He 164775.22 431.2211 19540230.96 0.0026 1.085

Mg 24 3 He 7893.835 10.4942 468475.74 0.0013 0.007869

Mg 24 3 He 8002.968 10.6392 469936.09 0.0013 0.007869

Mg 24 3 He 7931.712 10.5445 477810.66 0.0013 0.007869

Al 27 3 He 43.541 0.022 980.06 0.0004 0.002817

Al 27 3 He 47.164 0.0235 1040.06 0.0004 0.002817

Al 27 3 He 38.281 0.0196 890.06 0.0004 0.002817

K 39 3 He 5460.091 7.3332 327364.06 0.0012 0.5615

K 39 3 He 5417.053 7.2798 321552.16 0.0012 0.5615

K 39 3 He 5290.036 7.1223 322737.06 0.0012 0.5615

Ca 44 3 He 58367.985 2.367 165626.42 0 0.00417

Ca 44 3 He 57908.893 2.3484 164326.36 0 0.00417

Ca 44 3 He 59171.799 2.3996 168410.88 0 0.00417

Ti 47 3 He 0.403 0.0003 12.00 0.0005 6.671E-05

Ti 47 3 He 0.408 0.0003 12.00 0.0005 6.671E-05

Ti 47 3 He 0.746 0.0004 20.00 0.0005 6.671E-05

V 51 3 He 3.424 0.0806 3596.42 0.0202 0.01151

V 51 3 He 3.547 0.0831 3668.43 0.0202 0.01151

V 51 3 He 3.586 0.0838 3798.47 0.0202 0.01151

Cr 52 3 He -0.992 0.0782 3490.47 0.0256 0.1036

Cr 52 3 He -1.048 0.0768 3390.46 0.0256 0.1036

Cr 52 3 He -0.926 0.0799 3620.50 0.0256 0.1036

Mn 55 3 He 44.495 0.5126 22882.05 0.0113 0.007802

Page 15004 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Mn 55 3 He 45.484 0.5238 23136.39 0.0113 0.007802

Mn 55 3 He 45.746 0.5268 23869.48 0.0113 0.007802

Fe 57 3 He 60.119 0.0405 1810.16 0.0005 0.01103

Fe 57 3 He 61.46 0.0412 1820.15 0.0005 0.01103

Fe 57 3 He 63.389 0.0422 1910.17 0.0005 0.01103

Co 59 3 He 1.345 0.0656 2930.28 0.0463 0.003347

Co 59 3 He 1.288 0.063 2782.26 0.0463 0.003347

Co 59 3 He 1.265 0.0619 2806.26 0.0463 0.003347

Ni 60 3 He 5.443 0.0815 3638.43 0.0132 0.009623

Ni 60 3 He 5.492 0.0821 3628.42 0.0132 0.009623

Ni 60 3 He 5.115 0.0772 3496.40 0.0132 0.009623

Cu 63 3 He 0.064 0.0153 1072.04 0.0229 0.01386

Cu 63 3 He 0.071 0.0155 1084.04 0.0229 0.01386

Cu 63 3 He 0.054 0.0151 1060.04 0.0229 0.01386

Zn 66 3 He 0.65 0.0053 370.01 0.0028 0.00344

Zn 66 3 He 0.76 0.0056 392.01 0.0028 0.00344

Zn 66 3 He 0.624 0.0052 366.01 0.0028 0.00344

As 75 3 He 0.751 0.0024 166.00 0.0022 0.0006908

As 75 3 He 0.866 0.0026 184.00 0.0022 0.0006908

As 75 3 He 0.71 0.0023 160.00 0.0022 0.0006908

Sr 88 3 He 442.881 4.9493 258179.25 0.0112 0.001442

Sr 88 3 He 466.534 5.2135 261453.59 0.0112 0.001442

Sr 88 3 He 466.41 5.2121 261908.49 0.0112 0.001442

Mo 98 3 He 0.019 0.0019 100.00 0.021 0.001512

Mo 98 3 He 0.061 0.0028 140.01 0.021 0.001512

Mo 98 3 He 0.079 0.0032 160.01 0.021 0.001512

Ag 107 3 He -0.004 0.0006 30.00 0.0425 0.0007547

Ag 107 3 He -0.004 0.0006 30.00 0.0425 0.0007547

Ag 107 3 He -0.018 0 0.00 0.0425 0.0007547

Cd 111 3 He 0.012 0.0001 8.00 0.0036 7.231E-05

Cd 111 3 He -0.004 0.0001 4.00 0.0036 7.231E-05

Cd 111 3 He -0.012 0 2.00 0.0036 7.231E-05

Sn 120 3 He -0.205 0.0635 3310.42 0.014 0.06634

Sn 120 3 He -0.223 0.0632 3170.44 0.014 0.06634

Sn 120 3 He -0.26 0.0627 3150.42 0.014 0.06634

Sb 121 3 He 0.083 0.0014 73.33 0.0136 0.0002754

Sb 121 3 He 0.082 0.0014 70.00 0.0136 0.0002754

Sb 121 3 He 0.097 0.0016 80.00 0.0136 0.0002754

Ba 137 3 He 14.441 0.0627 3270.47 0.0043 0.0001378

Ba 137 3 He 16.036 0.0696 3490.48 0.0043 0.0001378

Ba 137 3 He 16.464 0.0715 3590.56 0.0043 0.0001378

Tl 205 3 He 0.005 0.0004 60.00 0.0176 0.0003242

Tl 205 3 He 0.016 0.0006 90.00 0.0176 0.0003242

Tl 205 3 He 0.008 0.0005 70.00 0.0176 0.0003242

Pb 208 3 He -0.071 0.0043 380.02 0.0229 0.005891

Pb 208 3 He -0.123 0.0031 280.01 0.0229 0.005891

Pb 208 3 He -0.113 0.0033 230.01 0.0229 0.005891

U 238 3 He 0.139 0.0028 420.02 0.0202 4.619E-05

U 238 3 He 0.144 0.0029 440.02 0.0202 4.619E-05

U 238 3 He 0.152 0.0031 470.02 0.0202 4.619E-05

Sc 45 1 No Gas 1566115.45

Sc 45 1 No Gas 1560516.38

Page 15005 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Sc 45 1 No Gas 1561776.70

Ge 72 1 No Gas 651702.53

Ge 72 1 No Gas 664536.16

Ge 72 1 No Gas 663142.10

Sc 45 2 H2 162387.67

Sc 45 2 H2 165378.73

Sc 45 2 H2 168577.83

Ge 72 2 H2 117417.69

Ge 72 2 H2 118515.12

Ge 72 2 H2 121063.71

In 115 2 H2 243228.24

In 115 2 H2 243032.91

In 115 2 H2 244793.04

Sc 45 3 He 44641.45

Sc 45 3 He 44170.41

Sc 45 3 He 45313.72

Ge 72 3 He 69972.39

Ge 72 3 He 69972.55

Ge 72 3 He 70183.91

In 115 3 He 52188.22

In 115 3 He 50171.22

In 115 3 He 50271.73

Tb 159 3 He 147788.69

Tb 159 3 He 149223.17

Tb 159 3 He 151080.97

Bi 209 3 He 84314.03

Bi 209 3 He 86659.23

Bi 209 3 He 86678.15

Page 15006 of 16273

Data File Name 088SMPL.d

Acq/Data Batch C:\Agilent\ICPMH\1\DATA\25E28A00.b

Acq Time 5/28/2025 11:43:12 AM

Sample Name RINSE

Sample Type Sample

---Comment

Prep Dilution 1.0000

Auto Dilution 1.0000

Total Dilution 1.0000

Operator Name us19_usr_ins23851

SpectrumAcq Mode

---Cal Title

External CalibrationCal Type

5/28/2025 10:14:18 AMLast Calib

---Bkg File

Bkg Mode Count Subtraction except for ISTD

FQ BlankFile ---

Point to PointVIS Fit

FullQuant Table

Element Mass ISTD Tune Mode Conc. Units RSD(%) CPS Ratio Det. Time(sec) Rep

Be 9 72 No Gas -0.015 ppb N/A 22.00 0.0000 Pulse 0.5000 3

Se 78 72 H2 0.029 ppb 91.3 2.44 0.0000 Pulse 1.5000 3

Na 23 45 He 63.122 ppb 13.5 52951.24 1.2497 Pulse 0.1000 3

Mg 24 45 He 5.914 ppb 31.9 666.70 0.0157 Pulse 0.1000 3

Al 27 45 He -1.750 ppb N/A 86.67 0.0020 Pulse 0.1000 3

K 39 45 He 19.271 ppb 332.9 24810.20 0.5854 Pulse 0.5000 3

Ca 44 72 He 31.644 ppb 24.8 358.68 0.0055 Pulse 0.5000 3

Ti 47 45 He 0.086 ppb 125.0 4.67 0.0001 Pulse 0.5000 3

V 51 45 He 0.024 ppb 79.1 508.01 0.0120 Pulse 0.5000 3

Cr 52 45 He -0.443 ppb N/A 3910.58 0.0923 Pulse 0.1000 3

Mn 55 45 He 0.067 ppb 40.0 362.68 0.0086 Pulse 0.5000 3

Fe 57 45 He -6.747 ppb N/A 326.68 0.0077 Pulse 0.1000 3

Co 59 45 He 0.026 ppb 50.6 193.33 0.0046 Pulse 0.5000 3

Ni 60 45 He 0.012 ppb 170.4 414.68 0.0098 Pulse 0.5000 3

Cu 63 72 He -0.055 ppb N/A 829.36 0.0126 Pulse 0.5000 3

Zn 66 72 He 0.144 ppb 77.2 253.33 0.0038 Pulse 0.5000 3

As 75 72 He 0.026 ppb 167.6 49.33 0.0007 Pulse 0.5000 3

Sr 88 115 He 0.473 ppb 6.0 326.68 0.0067 Pulse 0.1000 3

Mo 98 115 He 0.003 ppb 1024.8 76.67 0.0016 Pulse 0.1000 3

Ag 107 115 He -0.011 ppb N/A 13.33 0.0003 Pulse 0.1000 3

Cd 111 72 He -0.014 ppb N/A 1.33 0.0000 Pulse 0.5000 3

Sn 120 115 He -0.259 ppb N/A 3047.06 0.0627 Pulse 0.1000 3

Sb 121 115 He 0.003 ppb 318.6 15.55 0.0003 Pulse 0.3000 3

Ba 137 115 He 0.158 ppb 109.1 40.00 0.0008 Pulse 0.1000 3

Tl 205 159 He 0.016 ppb 63.0 86.67 0.0006 Pulse 0.1000 3

Pb 208 159 He -0.110 ppb N/A 483.36 0.0034 Pulse 0.1000 3

U 238 159 He -0.001 ppb N/A 3.33 0.0000 Pulse 0.1000 3

ISTD Table:

Page 15007 of 16273

Tune Mode Element Mass CPS RSD(%) ISTD Recovery % Det. Time(seq) Rep

No Gas Sc 45 1471445.19 1.4 94.0 Analog 0.1000 3

No Gas Ge 72 626096.21 0.6 98.7 Pulse 0.1000 3

H2 Sc 45 157226.30 1.0 105.1 Pulse 0.1000 3

H2 Ge 72 112056.00 1.6 106.0 Pulse 0.1000 3

H2 In 115 232231.04 0.4 106.3 Pulse 0.1000 3

He Sc 45 42369.04 0.7 105.2 Pulse 0.1000 3

He Ge 72 65808.94 0.5 101.9 Pulse 0.1000 3

He In 115 48575.27 1.9 100.1 Pulse 0.1000 3

He Tb 159 143733.42 0.2 100.0 Pulse 0.1000 3

He Bi 209 83167.44 0.5 102.6 Pulse 0.1000 3

No Gas

Mass

10 20 30 40 50 60 70 80 90 100

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190 200

Co un t

5x10

Mass

210 220 230 240 250 260 270 280 290 300

Co un t

5x10

H2

Mass

10 20 30 40 50 60 70 80 90

Co un t

4x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

4x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

4x10

Page 15008 of 16273

He

Mass

10 20 30 40 50 60 70 80 90

Co un t

4x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

4x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

4x10

Replicate:

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Be 9 1 No Gas 0.007 0.0001 34.00 0.0009 4.831E-05

Be 9 1 No Gas -0.033 0 12.00 0.0009 4.831E-05

Be 9 1 No Gas -0.019 0 20.00 0.0009 4.831E-05

Se 78 2 H2 0.021 0 2.00 0.0005 8.428E-06

Se 78 2 H2 0.007 0 1.33 0.0005 8.428E-06

Se 78 2 H2 0.059 0 4.00 0.0005 8.428E-06

Na 23 3 He 71.862 1.2725 54038.41 0.0026 1.085

Na 23 3 He 62.718 1.2486 53175.07 0.0026 1.085

Na 23 3 He 54.785 1.2279 51640.25 0.0026 1.085

Mg 24 3 He 5.776 0.0155 660.04 0.0013 0.007869

Mg 24 3 He 7.864 0.0183 780.04 0.0013 0.007869

Mg 24 3 He 4.101 0.0133 560.03 0.0013 0.007869

Al 27 3 He 0.021 0.0028 120.01 0.0004 0.002817

Al 27 3 He -4.272 0.0009 40.00 0.0004 0.002817

Al 27 3 He -0.999 0.0024 100.00 0.0004 0.002817

K 39 3 He 91.186 0.6746 28646.83 0.0012 0.5615

K 39 3 He -1.339 0.5598 23841.22 0.0012 0.5615

K 39 3 He -32.035 0.5218 21942.55 0.0012 0.5615

Ca 44 3 He 37.744 0.0057 376.01 0 0.00417

Ca 44 3 He 22.809 0.0051 336.01 0 0.00417

Ca 44 3 He 34.38 0.0056 364.01 0 0.00417

Ti 47 3 He 0.149 0.0001 6.00 0.0005 6.671E-05

Ti 47 3 He 0.148 0.0001 6.00 0.0005 6.671E-05

Ti 47 3 He -0.038 0 2.00 0.0005 6.671E-05

V 51 3 He 0.025 0.012 510.01 0.0202 0.01151

V 51 3 He 0.005 0.0116 494.01 0.0202 0.01151

V 51 3 He 0.042 0.0124 520.01 0.0202 0.01151

Cr 52 3 He -0.248 0.0973 4130.62 0.0256 0.1036

Cr 52 3 He -0.451 0.0921 3920.58 0.0256 0.1036

Cr 52 3 He -0.629 0.0875 3680.54 0.0256 0.1036

Mn 55 3 He 0.039 0.0082 350.01 0.0113 0.007802

Page 15009 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Mn 55 3 He 0.07 0.0086 366.01 0.0113 0.007802

Mn 55 3 He 0.092 0.0088 372.01 0.0113 0.007802

Fe 57 3 He -5.668 0.0082 350.01 0.0005 0.01103

Fe 57 3 He -8.585 0.0068 290.01 0.0005 0.01103

Fe 57 3 He -5.988 0.0081 340.01 0.0005 0.01103

Co 59 3 He 0.033 0.0049 208.00 0.0463 0.003347

Co 59 3 He 0.034 0.0049 210.00 0.0463 0.003347

Co 59 3 He 0.011 0.0039 162.00 0.0463 0.003347

Ni 60 3 He -0.012 0.0095 402.01 0.0132 0.009623

Ni 60 3 He 0.022 0.0099 422.01 0.0132 0.009623

Ni 60 3 He 0.028 0.01 420.01 0.0132 0.009623

Cu 63 3 He -0.06 0.0125 824.03 0.0229 0.01386

Cu 63 3 He -0.035 0.0131 862.03 0.0229 0.01386

Cu 63 3 He -0.07 0.0123 802.02 0.0229 0.01386

Zn 66 3 He 0.272 0.0042 278.00 0.0028 0.00344

Zn 66 3 He 0.07 0.0036 240.00 0.0028 0.00344

Zn 66 3 He 0.09 0.0037 242.00 0.0028 0.00344

As 75 3 He 0.057 0.0008 54.00 0.0022 0.0006908

As 75 3 He -0.024 0.0006 42.00 0.0022 0.0006908

As 75 3 He 0.046 0.0008 52.00 0.0022 0.0006908

Sr 88 3 He 0.504 0.0071 340.01 0.0112 0.001442

Sr 88 3 He 0.448 0.0064 320.01 0.0112 0.001442

Sr 88 3 He 0.467 0.0067 320.01 0.0112 0.001442

Mo 98 3 He -0.032 0.0008 40.00 0.021 0.001512

Mo 98 3 He 0.014 0.0018 90.00 0.021 0.001512

Mo 98 3 He 0.027 0.0021 100.00 0.021 0.001512

Ag 107 3 He -0.013 0.0002 10.00 0.0425 0.0007547

Ag 107 3 He -0.004 0.0006 30.00 0.0425 0.0007547

Ag 107 3 He -0.018 0 0.00 0.0425 0.0007547

Cd 111 3 He -0.02 0 0.00 0.0036 7.231E-05

Cd 111 3 He -0.02 0 0.00 0.0036 7.231E-05

Cd 111 3 He -0.003 0.0001 4.00 0.0036 7.231E-05

Sn 120 3 He -0.325 0.0618 2970.39 0.014 0.06634

Sn 120 3 He -0.147 0.0643 3190.42 0.014 0.06634

Sn 120 3 He -0.305 0.0621 2980.38 0.014 0.06634

Sb 121 3 He 0.015 0.0005 23.33 0.0136 0.0002754

Sb 121 3 He -0.005 0.0002 10.00 0.0136 0.0002754

Sb 121 3 He 0 0.0003 13.33 0.0136 0.0002754

Ba 137 3 He 0.304 0.0015 70.00 0.0043 0.0001378

Ba 137 3 He 0.201 0.001 50.00 0.0043 0.0001378

Ba 137 3 He -0.032 0 0.00 0.0043 0.0001378

Tl 205 3 He 0.005 0.0004 60.00 0.0176 0.0003242

Tl 205 3 He 0.025 0.0008 110.01 0.0176 0.0003242

Tl 205 3 He 0.017 0.0006 90.00 0.0176 0.0003242

Pb 208 3 He -0.121 0.0031 210.01 0.0229 0.005891

Pb 208 3 He -0.09 0.0038 290.01 0.0229 0.005891

Pb 208 3 He -0.121 0.0031 220.01 0.0229 0.005891

U 238 3 He 0.001 0.0001 10.00 0.0202 4.619E-05

U 238 3 He -0.002 0 0.00 0.0202 4.619E-05

U 238 3 He -0.002 0 0.00 0.0202 4.619E-05

Sc 45 1 No Gas 1476049.51

Sc 45 1 No Gas 1489817.95

Page 15010 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Sc 45 1 No Gas 1448468.10

Ge 72 1 No Gas 625194.29

Ge 72 1 No Gas 630197.84

Ge 72 1 No Gas 622896.51

Sc 45 2 H2 155743.77

Sc 45 2 H2 157190.32

Sc 45 2 H2 158744.80

Ge 72 2 H2 109974.38

Ge 72 2 H2 112926.89

Ge 72 2 H2 113266.74

In 115 2 H2 231572.01

In 115 2 H2 233408.90

In 115 2 H2 231712.22

Sc 45 3 He 42466.00

Sc 45 3 He 42586.45

Sc 45 3 He 42054.68

Ge 72 3 He 65995.97

Ge 72 3 He 65976.54

Ge 72 3 He 65454.31

In 115 3 He 48095.06

In 115 3 He 49649.87

In 115 3 He 48044.86

Tb 159 3 He 143802.12

Tb 159 3 He 143486.04

Tb 159 3 He 143912.09

Bi 209 3 He 82654.61

Bi 209 3 He 83348.72

Bi 209 3 He 83498.99

Page 15011 of 16273

Data File Name 089_CCV.d

Acq/Data Batch C:\Agilent\ICPMH\1\DATA\25E28A00.b

Acq Time 5/28/2025 11:45:25 AM

Sample Name CCV 7707786

Sample Type CCV

---Comment

Prep Dilution 1.0000

Auto Dilution 1.0000

Total Dilution 1.0000

Operator Name us19_usr_ins23851

SpectrumAcq Mode

---Cal Title

External CalibrationCal Type

5/28/2025 10:14:18 AMLast Calib

---Bkg File

Bkg Mode Count Subtraction except for ISTD

FQ BlankFile ---

Point to PointVIS Fit

FullQuant Table

Element Mass ISTD Tune Mode Conc. Units RSD(%) CPS Ratio Det. Time(sec) Rep

Be 9 72 No Gas 26.986 ppb 5.0 14771.85 0.0236 Pulse 0.5000 3

Se 78 72 H2 25.541 ppb 1.5 1309.39 0.0116 Pulse 1.5000 3

Na 23 45 He 2515.804 ppb 3.5 333458.43 7.6523 Pulse 0.1000 3

Mg 24 45 He 2545.272 ppb 2.3 147691.30 3.3891 Pulse 0.1000 3

Al 27 45 He 2516.732 ppb 3.2 48324.31 1.1090 Pulse 0.1000 3

K 39 45 He 2554.926 ppb 3.2 162561.95 3.7302 Pulse 0.5000 3

Ca 44 72 He 2699.283 ppb 2.5 7579.11 0.1134 Pulse 0.5000 3

Ti 47 45 He 2508.107 ppb 2.7 54878.60 1.2593 Pulse 0.5000 3

V 51 45 He 247.489 ppb 2.8 218004.41 5.0028 Pulse 0.5000 3

Cr 52 45 He 244.852 ppb 2.0 278134.11 6.3819 Pulse 0.1000 3

Mn 55 45 He 248.881 ppb 2.2 123382.56 2.8312 Pulse 0.5000 3

Fe 57 45 He 2422.145 ppb 1.6 52321.95 1.2005 Pulse 0.1000 3

Co 59 45 He 245.295 ppb 2.0 495104.73 11.3607 Pulse 0.5000 3

Ni 60 45 He 244.010 ppb 2.2 140839.79 3.2318 Pulse 0.5000 3

Cu 63 72 He 256.896 ppb 1.8 394072.82 5.8980 Pulse 0.5000 3

Zn 66 72 He 255.380 ppb 1.6 48769.67 0.7299 Pulse 0.5000 3

As 75 72 He 255.467 ppb 1.5 38260.69 0.5726 Pulse 0.5000 3

Sr 88 115 He 26.510 ppb 2.4 14850.76 0.2976 Pulse 0.1000 3

Mo 98 115 He 25.372 ppb 3.5 26720.04 0.5356 Pulse 0.1000 3

Ag 107 115 He 25.149 ppb 1.7 53425.14 1.0705 Pulse 0.1000 3

Cd 111 72 He 24.965 ppb 2.4 6079.89 0.0910 Pulse 0.5000 3

Sn 120 115 He 25.641 ppb 5.8 21255.19 0.4261 Pulse 0.1000 3

Sb 121 115 He 24.736 ppb 2.5 16830.33 0.3373 Pulse 0.3000 3

Ba 137 115 He 255.094 ppb 0.3 55157.05 1.1052 Pulse 0.1000 3

Tl 205 159 He 25.669 ppb 0.3 66200.49 0.4508 Pulse 0.1000 3

Pb 208 159 He 25.664 ppb 0.9 87197.88 0.5938 Pulse 0.1000 3

U 238 159 He 26.021 ppb 1.9 77062.25 0.5248 Pulse 0.1000 3

ISTD Table:

Page 15012 of 16273

Tune Mode Element Mass CPS RSD(%) ISTD Recovery % Det. Time(seq) Rep

No Gas Sc 45 1505851.75 0.1 96.2 Analog 0.1000 3

No Gas Ge 72 625333.14 0.8 98.6 Pulse 0.1000 3

H2 Sc 45 159719.27 0.6 106.7 Pulse 0.1000 3

H2 Ge 72 112730.70 0.3 106.7 Pulse 0.1000 3

H2 In 115 236488.54 0.7 108.3 Pulse 0.1000 3

He Sc 45 43592.03 2.0 108.3 Pulse 0.1000 3

He Ge 72 66826.68 1.6 103.5 Pulse 0.1000 3

He In 115 49908.81 1.7 102.8 Pulse 0.1000 3

He Tb 159 146842.50 0.5 102.2 Pulse 0.1000 3

He Bi 209 84799.53 1.5 104.6 Pulse 0.1000 3

No Gas

Mass

10 20 30 40 50 60 70 80 90 100

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190 200

Co un t

5x10

Mass

210 220 230 240 250 260 270 280 290 300

Co un t

5x10

H2

Mass

10 20 30 40 50 60 70 80 90

Co un t

4x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

4x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

4x10

Page 15013 of 16273

He

Mass

10 20 30 40 50 60 70 80 90

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

5x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

5x10

Replicate:

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Be 9 1 No Gas 25.65 0.0225 13985.86 0.0009 4.831E-05

Be 9 1 No Gas 26.981 0.0236 14900.60 0.0009 4.831E-05

Be 9 1 No Gas 28.327 0.0248 15429.08 0.0009 4.831E-05

Se 78 2 H2 25.947 0.0118 1335.39 0.0005 8.428E-06

Se 78 2 H2 25.467 0.0116 1302.06 0.0005 8.428E-06

Se 78 2 H2 25.211 0.0115 1290.72 0.0005 8.428E-06

Na 23 3 He 2564.297 7.7789 338600.85 0.0026 1.085

Na 23 3 He 2413.935 7.3864 328553.90 0.0026 1.085

Na 23 3 He 2569.179 7.7916 333220.54 0.0026 1.085

Mg 24 3 He 2555.9 3.4032 148134.41 0.0013 0.007869

Mg 24 3 He 2481.916 3.3049 147005.62 0.0013 0.007869

Mg 24 3 He 2597.999 3.4591 147933.87 0.0013 0.007869

Al 27 3 He 2564.902 1.1301 49193.08 0.0004 0.002817

Al 27 3 He 2424.19 1.0683 47519.02 0.0004 0.002817

Al 27 3 He 2561.103 1.1285 48260.82 0.0004 0.002817

K 39 3 He 2622.718 3.8142 166026.91 0.0012 0.5615

K 39 3 He 2464.146 3.6176 160913.66 0.0012 0.5615

K 39 3 He 2577.916 3.7587 160745.27 0.0012 0.5615

Ca 44 3 He 2778.171 0.1166 7657.80 0 0.00417

Ca 44 3 He 2656.624 0.1117 7501.74 0 0.00417

Ca 44 3 He 2663.054 0.112 7577.78 0 0.00417

Ti 47 3 He 2497.542 1.254 54586.22 0.0005 6.671E-05

Ti 47 3 He 2447.457 1.2289 54662.63 0.0005 6.671E-05

Ti 47 3 He 2579.321 1.2951 55386.97 0.0005 6.671E-05

V 51 3 He 247.904 5.0112 218129.48 0.0202 0.01151

V 51 3 He 240.421 4.8603 216191.42 0.0202 0.01151

V 51 3 He 254.142 5.137 219692.34 0.0202 0.01151

Cr 52 3 He 247.085 6.4391 280284.64 0.0256 0.1036

Cr 52 3 He 239.37 6.2413 277621.93 0.0256 0.1036

Cr 52 3 He 248.102 6.4652 276495.76 0.0256 0.1036

Mn 55 3 He 249.588 2.8392 123587.30 0.0113 0.007802

Page 15014 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Mn 55 3 He 242.992 2.7644 122964.67 0.0113 0.007802

Mn 55 3 He 254.063 2.89 123595.70 0.0113 0.007802

Fe 57 3 He 2445.605 1.212 52756.64 0.0005 0.01103

Fe 57 3 He 2377.109 1.1784 52415.37 0.0005 0.01103

Fe 57 3 He 2443.72 1.2111 51793.85 0.0005 0.01103

Co 59 3 He 245.541 11.3721 495006.75 0.0463 0.003347

Co 59 3 He 240.275 11.1282 494997.28 0.0463 0.003347

Co 59 3 He 250.069 11.5817 495310.16 0.0463 0.003347

Ni 60 3 He 243.044 3.219 140117.75 0.0132 0.009623

Ni 60 3 He 239.284 3.1693 140976.47 0.0132 0.009623

Ni 60 3 He 249.701 3.3069 141425.14 0.0132 0.009623

Cu 63 3 He 262.203 6.0196 395220.50 0.0229 0.01386

Cu 63 3 He 254.75 5.8489 392755.97 0.0229 0.01386

Cu 63 3 He 253.735 5.8256 394242.00 0.0229 0.01386

Zn 66 3 He 259.941 0.7429 48775.02 0.0028 0.00344

Zn 66 3 He 254.128 0.7264 48775.03 0.0028 0.00344

Zn 66 3 He 252.071 0.7205 48758.96 0.0028 0.00344

As 75 3 He 259.638 0.582 38209.20 0.0022 0.0006908

As 75 3 He 254.678 0.5709 38333.57 0.0022 0.0006908

As 75 3 He 252.085 0.5651 38239.30 0.0022 0.0006908

Sr 88 3 He 25.852 0.2903 14747.47 0.0112 0.001442

Sr 88 3 He 27.13 0.3045 15157.71 0.0112 0.001442

Sr 88 3 He 26.549 0.298 14647.11 0.0112 0.001442

Mo 98 3 He 24.354 0.5141 26122.24 0.021 0.001512

Mo 98 3 He 26.038 0.5496 27354.50 0.021 0.001512

Mo 98 3 He 25.724 0.543 26683.39 0.021 0.001512

Ag 107 3 He 25.103 1.0686 54294.37 0.0425 0.0007547

Ag 107 3 He 24.745 1.0534 52428.78 0.0425 0.0007547

Ag 107 3 He 25.599 1.0897 53552.26 0.0425 0.0007547

Cd 111 3 He 25.397 0.0926 6077.22 0.0036 7.231E-05

Cd 111 3 He 24.283 0.0885 5943.17 0.0036 7.231E-05

Cd 111 3 He 25.215 0.0919 6219.28 0.0036 7.231E-05

Sn 120 3 He 24.245 0.4065 20654.40 0.014 0.06634

Sn 120 3 He 25.478 0.4238 21094.85 0.014 0.06634

Sn 120 3 He 27.201 0.448 22016.31 0.014 0.06634

Sb 121 3 He 24.067 0.3282 16675.70 0.0136 0.0002754

Sb 121 3 He 24.849 0.3389 16865.92 0.0136 0.0002754

Sb 121 3 He 25.291 0.3449 16949.36 0.0136 0.0002754

Ba 137 3 He 254.919 1.1044 56113.19 0.0043 0.0001378

Ba 137 3 He 255.806 1.1082 55160.33 0.0043 0.0001378

Ba 137 3 He 254.557 1.1028 54197.62 0.0043 0.0001378

Tl 205 3 He 25.709 0.4515 66340.79 0.0176 0.0003242

Tl 205 3 He 25.566 0.449 65597.55 0.0176 0.0003242

Tl 205 3 He 25.733 0.4519 66663.12 0.0176 0.0003242

Pb 208 3 He 25.389 0.5875 46094.10 0.0229 0.005891

Pb 208 3 He 25.817 0.5973 46023.93 0.0229 0.005891

Pb 208 3 He 25.787 0.5966 46374.71 0.0229 0.005891

U 238 3 He 25.472 0.5137 75481.02 0.0202 4.619E-05

U 238 3 He 26.154 0.5275 77059.29 0.0202 4.619E-05

U 238 3 He 26.436 0.5332 78646.44 0.0202 4.619E-05

Sc 45 1 No Gas 1506820.92

Sc 45 1 No Gas 1504461.23

Page 15015 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Sc 45 1 No Gas 1506273.10

Ge 72 1 No Gas 622816.51

Ge 72 1 No Gas 630894.99

Ge 72 1 No Gas 622287.92

Sc 45 2 H2 160832.91

Sc 45 2 H2 158944.60

Sc 45 2 H2 159380.29

Ge 72 2 H2 113177.22

Ge 72 2 H2 112431.69

Ge 72 2 H2 112583.19

In 115 2 H2 235884.39

In 115 2 H2 238386.23

In 115 2 H2 235195.00

Sc 45 3 He 43528.30

Sc 45 3 He 44481.20

Sc 45 3 He 42766.58

Ge 72 3 He 65655.78

Ge 72 3 He 67150.64

Ge 72 3 He 67673.62

In 115 3 He 50953.60

In 115 3 He 49920.74

In 115 3 He 49298.43

Tb 159 3 He 146929.95

Tb 159 3 He 146091.28

Tb 159 3 He 147506.27

Bi 209 3 He 83347.39

Bi 209 3 He 85671.84

Bi 209 3 He 85379.36

Page 15016 of 16273

Data File Name 090_CCB.d

Acq/Data Batch C:\Agilent\ICPMH\1\DATA\25E28A00.b

Acq Time 5/28/2025 11:47:38 AM

Sample Name CCB 7726600

Sample Type CCB

---Comment

Prep Dilution 1.0000

Auto Dilution 1.0000

Total Dilution 1.0000

Operator Name us19_usr_ins23851

SpectrumAcq Mode

---Cal Title

External CalibrationCal Type

5/28/2025 10:14:18 AMLast Calib

---Bkg File

Bkg Mode Count Subtraction except for ISTD

FQ BlankFile ---

Point to PointVIS Fit

FullQuant Table

Element Mass ISTD Tune Mode Conc. Units RSD(%) CPS Ratio Det. Time(sec) Rep

Be 9 72 No Gas 0.041 ppb 48.1 52.67 0.0001 Pulse 0.5000 3

Se 78 72 H2 0.058 ppb 97.6 3.78 0.0000 Pulse 1.5000 3

Na 23 45 He -48.028 ppb N/A 41041.10 0.9595 Pulse 0.1000 3

Mg 24 45 He 3.999 ppb 21.5 563.36 0.0132 Pulse 0.1000 3

Al 27 45 He 2.782 ppb 72.3 173.35 0.0040 Pulse 0.1000 3

K 39 45 He 5.408 ppb 1248.3 24298.15 0.5682 Pulse 0.5000 3

Ca 44 72 He 13.480 ppb 40.8 315.34 0.0047 Pulse 0.5000 3

Ti 47 45 He 2.414 ppb 26.9 54.67 0.0013 Pulse 0.5000 3

V 51 45 He 0.242 ppb 3.2 701.35 0.0164 Pulse 0.5000 3

Cr 52 45 He -0.308 ppb N/A 4097.32 0.0957 Pulse 0.1000 3

Mn 55 45 He 0.217 ppb 26.0 438.68 0.0103 Pulse 0.5000 3

Fe 57 45 He -0.861 ppb N/A 453.35 0.0106 Pulse 0.1000 3

Co 59 45 He 0.187 ppb 14.3 514.01 0.0120 Pulse 0.5000 3

Ni 60 45 He 0.240 ppb 49.5 548.02 0.0128 Pulse 0.5000 3

Cu 63 72 He 0.119 ppb 28.2 1110.05 0.0166 Pulse 0.5000 3

Zn 66 72 He 0.417 ppb 21.7 309.34 0.0046 Pulse 0.5000 3

As 75 72 He 0.244 ppb 15.5 82.67 0.0012 Pulse 0.5000 3

Sr 88 115 He 0.127 ppb 57.8 140.00 0.0029 Pulse 0.1000 3

Mo 98 115 He 0.060 ppb 88.8 136.67 0.0028 Pulse 0.1000 3

Ag 107 115 He -0.003 ppb N/A 30.00 0.0006 Pulse 0.1000 3

Cd 111 72 He 0.013 ppb 128.5 8.00 0.0001 Pulse 0.5000 3

Sn 120 115 He -0.190 ppb N/A 3117.09 0.0637 Pulse 0.1000 3

Sb 121 115 He 0.085 ppb 5.0 70.00 0.0014 Pulse 0.3000 3

Ba 137 115 He 0.282 ppb 53.5 66.67 0.0014 Pulse 0.1000 3

Tl 205 159 He 0.067 ppb 25.1 216.68 0.0015 Pulse 0.1000 3

Pb 208 159 He -0.112 ppb N/A 483.35 0.0033 Pulse 0.1000 3

U 238 159 He 0.027 ppb 39.5 86.67 0.0006 Pulse 0.1000 3

ISTD Table:

Page 15017 of 16273

Tune Mode Element Mass CPS RSD(%) ISTD Recovery % Det. Time(seq) Rep

No Gas Sc 45 1477009.93 0.6 94.3 Analog 0.1000 3

No Gas Ge 72 625093.71 1.1 98.5 Pulse 0.1000 3

H2 Sc 45 153880.75 0.8 102.8 Pulse 0.1000 3

H2 Ge 72 109857.71 1.1 104.0 Pulse 0.1000 3

H2 In 115 227941.27 0.6 104.4 Pulse 0.1000 3

He Sc 45 42789.98 2.1 106.3 Pulse 0.1000 3

He Ge 72 66903.30 1.2 103.6 Pulse 0.1000 3

He In 115 48949.47 1.0 100.9 Pulse 0.1000 3

He Tb 159 145224.78 2.3 101.0 Pulse 0.1000 3

He Bi 209 83492.76 1.3 103.0 Pulse 0.1000 3

No Gas

Mass

10 20 30 40 50 60 70 80 90 100

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190 200

Co un t

5x10

Mass

210 220 230 240 250 260 270 280 290 300

Co un t

5x10

H2

Mass

10 20 30 40 50 60 70 80 90

Co un t

4x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

4x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

4x10

Page 15018 of 16273

He

Mass

10 20 30 40 50 60 70 80 90

Co un t

4x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

4x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

4x10

Replicate:

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Be 9 1 No Gas 0.024 0.0001 44.00 0.0009 4.831E-05

Be 9 1 No Gas 0.063 0.0001 64.00 0.0009 4.831E-05

Be 9 1 No Gas 0.036 0.0001 50.00 0.0009 4.831E-05

Se 78 2 H2 0.075 0 4.67 0.0005 8.428E-06

Se 78 2 H2 0.103 0.0001 6.00 0.0005 8.428E-06

Se 78 2 H2 -0.005 0 0.67 0.0005 8.428E-06

Na 23 3 He -43.408 0.9716 41191.63 0.0026 1.085

Na 23 3 He -60.843 0.9261 40589.93 0.0026 1.085

Na 23 3 He -39.832 0.9809 41341.73 0.0026 1.085

Mg 24 3 He 4.553 0.0139 590.03 0.0013 0.007869

Mg 24 3 He 3.008 0.0119 520.03 0.0013 0.007869

Mg 24 3 He 4.436 0.0138 580.03 0.0013 0.007869

Al 27 3 He 1.105 0.0033 140.01 0.0004 0.002817

Al 27 3 He 5.012 0.005 220.02 0.0004 0.002817

Al 27 3 He 2.229 0.0038 160.01 0.0004 0.002817

K 39 3 He 83.1 0.6646 28174.14 0.0012 0.5615

K 39 3 He -27.847 0.527 23096.15 0.0012 0.5615

K 39 3 He -39.028 0.5131 21624.15 0.0012 0.5615

Ca 44 3 He 10.105 0.0046 308.01 0 0.00417

Ca 44 3 He 10.502 0.0046 310.01 0 0.00417

Ca 44 3 He 19.834 0.005 328.01 0 0.00417

Ti 47 3 He 3.156 0.0017 70.00 0.0005 6.671E-05

Ti 47 3 He 2.139 0.0011 50.00 0.0005 6.671E-05

Ti 47 3 He 1.946 0.001 44.00 0.0005 6.671E-05

V 51 3 He 0.25 0.0166 702.02 0.0202 0.01151

V 51 3 He 0.235 0.0162 712.02 0.0202 0.01151

V 51 3 He 0.241 0.0164 690.02 0.0202 0.01151

Cr 52 3 He -0.435 0.0925 3920.60 0.0256 0.1036

Cr 52 3 He -0.251 0.0972 4260.71 0.0256 0.1036

Cr 52 3 He -0.238 0.0975 4110.64 0.0256 0.1036

Mn 55 3 He 0.269 0.0109 460.01 0.0113 0.007802

Page 15019 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Mn 55 3 He 0.157 0.0096 420.01 0.0113 0.007802

Mn 55 3 He 0.224 0.0103 436.01 0.0113 0.007802

Fe 57 3 He -1.317 0.0104 440.02 0.0005 0.01103

Fe 57 3 He -2.008 0.01 440.02 0.0005 0.01103

Fe 57 3 He 0.741 0.0114 480.02 0.0005 0.01103

Co 59 3 He 0.217 0.0134 568.01 0.0463 0.003347

Co 59 3 He 0.179 0.0116 510.01 0.0463 0.003347

Co 59 3 He 0.165 0.011 464.01 0.0463 0.003347

Ni 60 3 He 0.329 0.014 592.02 0.0132 0.009623

Ni 60 3 He 0.287 0.0134 588.02 0.0132 0.009623

Ni 60 3 He 0.105 0.011 464.01 0.0132 0.009623

Cu 63 3 He 0.134 0.0169 1138.05 0.0229 0.01386

Cu 63 3 He 0.143 0.0171 1156.05 0.0229 0.01386

Cu 63 3 He 0.081 0.0157 1036.04 0.0229 0.01386

Zn 66 3 He 0.473 0.0048 322.00 0.0028 0.00344

Zn 66 3 He 0.312 0.0043 292.00 0.0028 0.00344

Zn 66 3 He 0.464 0.0048 314.01 0.0028 0.00344

As 75 3 He 0.223 0.0012 80.00 0.0022 0.0006908

As 75 3 He 0.221 0.0012 80.00 0.0022 0.0006908

As 75 3 He 0.287 0.0013 88.00 0.0022 0.0006908

Sr 88 3 He 0.124 0.0028 140.00 0.0112 0.001442

Sr 88 3 He 0.202 0.0037 180.01 0.0112 0.001442

Sr 88 3 He 0.055 0.0021 100.00 0.0112 0.001442

Mo 98 3 He 0.12 0.004 200.01 0.021 0.001512

Mo 98 3 He 0.045 0.0025 120.00 0.021 0.001512

Mo 98 3 He 0.016 0.0019 90.00 0.021 0.001512

Ag 107 3 He 0.001 0.0008 40.00 0.0425 0.0007547

Ag 107 3 He -0.008 0.0004 20.00 0.0425 0.0007547

Ag 107 3 He -0.003 0.0006 30.00 0.0425 0.0007547

Cd 111 3 He 0.013 0.0001 8.00 0.0036 7.231E-05

Cd 111 3 He -0.004 0.0001 4.00 0.0036 7.231E-05

Cd 111 3 He 0.03 0.0002 12.00 0.0036 7.231E-05

Sn 120 3 He -0.22 0.0633 3130.43 0.014 0.06634

Sn 120 3 He -0.223 0.0632 3080.41 0.014 0.06634

Sn 120 3 He -0.126 0.0646 3140.43 0.014 0.06634

Sb 121 3 He 0.089 0.0015 73.33 0.0136 0.0002754

Sb 121 3 He 0.08 0.0014 66.67 0.0136 0.0002754

Sb 121 3 He 0.085 0.0014 70.00 0.0136 0.0002754

Ba 137 3 He 0.341 0.0016 80.01 0.0043 0.0001378

Ba 137 3 He 0.395 0.0018 90.00 0.0043 0.0001378

Ba 137 3 He 0.111 0.0006 30.00 0.0043 0.0001378

Tl 205 3 He 0.085 0.0018 260.01 0.0176 0.0003242

Tl 205 3 He 0.062 0.0014 210.01 0.0176 0.0003242

Tl 205 3 He 0.053 0.0013 180.01 0.0176 0.0003242

Pb 208 3 He -0.086 0.0039 290.01 0.0229 0.005891

Pb 208 3 He -0.131 0.0029 240.01 0.0229 0.005891

Pb 208 3 He -0.118 0.0032 250.01 0.0229 0.005891

U 238 3 He 0.039 0.0008 120.00 0.0202 4.619E-05

U 238 3 He 0.024 0.0005 80.00 0.0202 4.619E-05

U 238 3 He 0.018 0.0004 60.00 0.0202 4.619E-05

Sc 45 1 No Gas 1479178.73

Sc 45 1 No Gas 1484586.85

Page 15020 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Sc 45 1 No Gas 1467264.20

Ge 72 1 No Gas 632087.61

Ge 72 1 No Gas 618552.88

Ge 72 1 No Gas 624640.65

Sc 45 2 H2 152847.37

Sc 45 2 H2 155259.80

Sc 45 2 H2 153535.07

Ge 72 2 H2 109753.55

Ge 72 2 H2 108707.22

Ge 72 2 H2 111112.37

In 115 2 H2 226318.18

In 115 2 H2 228668.12

In 115 2 H2 228837.52

Sc 45 3 He 42395.53

Sc 45 3 He 43829.37

Sc 45 3 He 42145.05

Ge 72 3 He 67271.81

Ge 72 3 He 67472.12

Ge 72 3 He 65965.98

In 115 3 He 49509.71

In 115 3 He 48747.25

In 115 3 He 48656.91

Tb 159 3 He 142893.13

Tb 159 3 He 148980.62

Tb 159 3 He 143800.58

Bi 209 3 He 83086.46

Bi 209 3 He 82695.77

Bi 209 3 He 84696.05

Page 15021 of 16273

5/28/2025 2:57 PM

Data File Name 091SMPL.d

Acq/Data Batch C:\Agilent\ICPMH\1\DATA\25E28A00.b

Acq Time 5/28/2025 11:58:24 AM

Sample Name 180-189742-B-26-A@10

Sample Type Sample

MS E9Comment

Prep Dilution 1.0000

Auto Dilution 1.0000

Total Dilution 1.0000

Operator Name us19_usr_ins23851

SpectrumAcq Mode

---Cal Title

External CalibrationCal Type

5/28/2025 10:14:18 AMLast Calib

---Bkg File

Bkg Mode Count Subtraction except for ISTD

FQ BlankFile ---

Point to PointVIS Fit

FullQuant Table

Element Mass ISTD Tune Mode Conc. Units RSD(%) CPS Ratio Det. Time(sec) Rep

Be 9 72 No Gas -0.014 ppb N/A 21.33 0.0000 Pulse 0.5000 3

Se 78 72 H2 0.404 ppb 11.6 20.67 0.0002 Pulse 1.5000 3

Na 23 45 He 18311.442 ppb 1.8 2183964.44 48.8859 Analog 0.1000 3

Mg 24 45 He 3.610 ppb 28.3 566.70 0.0127 Pulse 0.1000 3

Al 27 45 He 45.027 ppb 5.1 1010.07 0.0226 Pulse 0.1000 3

K 39 45 He 3428.309 ppb 2.9 215021.58 4.8133 Pulse 0.5000 3

Ca 44 72 He 46612.118 ppb 0.8 118737.15 1.8911 Pulse 0.5000 3

Ti 47 45 He 0.193 ppb 95.5 7.33 0.0002 Pulse 0.5000 3

V 51 45 He 0.291 ppb 5.5 776.69 0.0174 Pulse 0.5000 3

Cr 52 45 He 0.216 ppb 85.4 4880.90 0.1092 Pulse 0.1000 3

Mn 55 45 He -0.037 ppb N/A 329.34 0.0074 Pulse 0.5000 3

Fe 57 45 He -1.191 ppb N/A 466.69 0.0104 Pulse 0.1000 3

Co 59 45 He 0.122 ppb 0.9 401.34 0.0090 Pulse 0.5000 3

Ni 60 45 He 2.122 ppb 6.1 1682.10 0.0376 Pulse 0.5000 3

Cu 63 72 He 4.080 ppb 1.6 6738.76 0.1073 Pulse 0.5000 3

Zn 66 72 He 0.644 ppb 31.4 331.34 0.0053 Pulse 0.5000 3

As 75 72 He 0.270 ppb 47.3 81.33 0.0013 Pulse 0.5000 3

Sr 88 115 He 342.318 ppb 0.5 193346.77 3.8258 Pulse 0.1000 3

Mo 98 115 He 4.068 ppb 2.0 4404.10 0.0871 Pulse 0.1000 3

Ag 107 115 He -0.010 ppb N/A 16.67 0.0003 Pulse 0.1000 3

Cd 111 72 He -0.014 ppb N/A 1.33 0.0000 Pulse 0.5000 3

Sn 120 115 He -0.233 ppb N/A 3187.11 0.0631 Pulse 0.1000 3

Sb 121 115 He 0.096 ppb 23.1 80.00 0.0016 Pulse 0.3000 3

Ba 137 115 He 22.124 ppb 4.9 4850.96 0.0960 Pulse 0.1000 3

Tl 205 159 He -0.002 ppb N/A 43.33 0.0003 Pulse 0.1000 3

Pb 208 159 He 0.213 ppb 21.4 1570.09 0.0108 Pulse 0.1000 3

U 238 159 He 0.001 ppb 0.6 10.00 0.0001 Pulse 0.1000 3

ISTD Table:

Page 15022 of 16273

Tune Mode Element Mass CPS RSD(%) ISTD Recovery % Det. Time(seq) Rep

No Gas Sc 45 1527765.08 2.3 97.6 Analog 0.1000 3

No Gas Ge 72 588578.66 1.7 92.8 Pulse 0.1000 3

H2 Sc 45 161233.47 0.9 107.8 Pulse 0.1000 3

H2 Ge 72 107478.29 1.1 101.7 Pulse 0.1000 3

H2 In 115 238500.41 0.1 109.2 Pulse 0.1000 3

He Sc 45 44685.13 2.3 111.0 Pulse 0.1000 3

He Ge 72 62790.43 1.3 97.2 Pulse 0.1000 3

He In 115 50537.38 0.4 104.1 Pulse 0.1000 3

He Tb 159 145783.21 0.2 101.4 Pulse 0.1000 3

He Bi 209 84773.57 1.1 104.6 Pulse 0.1000 3

No Gas

Mass

10 20 30 40 50 60 70 80 90 100

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190 200

Co un t

5x10

Mass

210 220 230 240 250 260 270 280 290 300

Co un t

5x10

H2

Mass

10 20 30 40 50 60 70 80 90

Co un t

4x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

4x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

4x10

Page 15023 of 16273

He

Mass

10 20 30 40 50 60 70 80 90

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

5x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

5x10

Replicate:

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Be 9 1 No Gas -0.02 0 18.00 0.0009 4.831E-05

Be 9 1 No Gas -0.013 0 22.00 0.0009 4.831E-05

Be 9 1 No Gas -0.009 0 24.00 0.0009 4.831E-05

Se 78 2 H2 0.354 0.0002 18.00 0.0005 8.428E-06

Se 78 2 H2 0.413 0.0002 21.33 0.0005 8.428E-06

Se 78 2 H2 0.446 0.0002 22.67 0.0005 8.428E-06

Na 23 3 He 18115.048 48.3732 2162854.34 0.0026 1.085

Na 23 3 He 18693.457 49.8831 2177851.37 0.0026 1.085

Na 23 3 He 18125.82 48.4013 2211187.62 0.0026 1.085

Mg 24 3 He 3 0.0119 530.03 0.0013 0.007869

Mg 24 3 He 3.043 0.0119 520.03 0.0013 0.007869

Mg 24 3 He 4.787 0.0142 650.03 0.0013 0.007869

Al 27 3 He 42.445 0.0215 960.06 0.0004 0.002817

Al 27 3 He 46.75 0.0234 1020.07 0.0004 0.002817

Al 27 3 He 45.887 0.023 1050.07 0.0004 0.002817

K 39 3 He 3504.319 4.9076 219428.00 0.0012 0.5615

K 39 3 He 3467.021 4.8613 212242.06 0.0012 0.5615

K 39 3 He 3313.587 4.6711 213394.67 0.0012 0.5615

Ca 44 3 He 46496.369 1.8864 119649.12 0 0.00417

Ca 44 3 He 47047.75 1.9088 118152.20 0 0.00417

Ca 44 3 He 46292.235 1.8782 118410.13 0 0.00417

Ti 47 3 He 0.402 0.0003 12.00 0.0005 6.671E-05

Ti 47 3 He 0.05 0.0001 4.00 0.0005 6.671E-05

Ti 47 3 He 0.129 0.0001 6.00 0.0005 6.671E-05

V 51 3 He 0.292 0.0174 778.02 0.0202 0.01151

V 51 3 He 0.274 0.017 744.02 0.0202 0.01151

V 51 3 He 0.306 0.0177 808.03 0.0202 0.01151

Cr 52 3 He 0.05 0.1049 4690.83 0.0256 0.1036

Cr 52 3 He 0.184 0.1084 4730.86 0.0256 0.1036

Cr 52 3 He 0.415 0.1143 5221.01 0.0256 0.1036

Mn 55 3 He -0.029 0.0075 334.01 0.0113 0.007802

Page 15024 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Mn 55 3 He 0.035 0.0082 358.01 0.0113 0.007802

Mn 55 3 He -0.117 0.0065 296.00 0.0113 0.007802

Fe 57 3 He -0.59 0.0107 480.02 0.0005 0.01103

Fe 57 3 He -1.929 0.0101 440.02 0.0005 0.01103

Fe 57 3 He -1.055 0.0105 480.02 0.0005 0.01103

Co 59 3 He 0.123 0.009 404.01 0.0463 0.003347

Co 59 3 He 0.121 0.0089 390.01 0.0463 0.003347

Co 59 3 He 0.122 0.009 410.01 0.0463 0.003347

Ni 60 3 He 2.269 0.0396 1770.11 0.0132 0.009623

Ni 60 3 He 2.068 0.0369 1612.09 0.0132 0.009623

Ni 60 3 He 2.03 0.0364 1664.09 0.0132 0.009623

Cu 63 3 He 4.147 0.1088 6903.49 0.0229 0.01386

Cu 63 3 He 4.076 0.1072 6637.40 0.0229 0.01386

Cu 63 3 He 4.018 0.1059 6675.40 0.0229 0.01386

Zn 66 3 He 0.72 0.0055 348.01 0.0028 0.00344

Zn 66 3 He 0.415 0.0046 286.00 0.0028 0.00344

Zn 66 3 He 0.798 0.0057 360.01 0.0028 0.00344

As 75 3 He 0.382 0.0015 98.00 0.0022 0.0006908

As 75 3 He 0.298 0.0014 84.00 0.0022 0.0006908

As 75 3 He 0.131 0.001 62.00 0.0022 0.0006908

Sr 88 3 He 343.305 3.8368 194844.47 0.0112 0.001442

Sr 88 3 He 343.179 3.8354 193385.35 0.0112 0.001442

Sr 88 3 He 340.468 3.8051 191810.49 0.0112 0.001442

Mo 98 3 He 4.045 0.0867 4400.77 0.021 0.001512

Mo 98 3 He 4.16 0.0891 4490.78 0.021 0.001512

Mo 98 3 He 4 0.0857 4320.74 0.021 0.001512

Ag 107 3 He -0.008 0.0004 20.00 0.0425 0.0007547

Ag 107 3 He -0.018 0 0.00 0.0425 0.0007547

Ag 107 3 He -0.004 0.0006 30.00 0.0425 0.0007547

Cd 111 3 He -0.02 0 0.00 0.0036 7.231E-05

Cd 111 3 He -0.011 0 2.00 0.0036 7.231E-05

Cd 111 3 He -0.011 0 2.00 0.0036 7.231E-05

Sn 120 3 He -0.503 0.0593 3010.40 0.014 0.06634

Sn 120 3 He -0.417 0.0605 3050.39 0.014 0.06634

Sn 120 3 He 0.221 0.0694 3500.53 0.014 0.06634

Sb 121 3 He 0.1 0.0016 83.33 0.0136 0.0002754

Sb 121 3 He 0.072 0.0013 63.33 0.0136 0.0002754

Sb 121 3 He 0.116 0.0019 93.34 0.0136 0.0002754

Ba 137 3 He 23.293 0.101 5131.08 0.0043 0.0001378

Ba 137 3 He 21.903 0.095 4790.95 0.0043 0.0001378

Ba 137 3 He 21.176 0.0919 4630.84 0.0043 0.0001378

Tl 205 3 He -0.003 0.0003 40.00 0.0176 0.0003242

Tl 205 3 He -0.007 0.0002 30.00 0.0176 0.0003242

Tl 205 3 He 0.005 0.0004 60.00 0.0176 0.0003242

Pb 208 3 He 0.218 0.0109 830.05 0.0229 0.005891

Pb 208 3 He 0.165 0.0097 760.05 0.0229 0.005891

Pb 208 3 He 0.256 0.0118 880.05 0.0229 0.005891

U 238 3 He 0.001 0.0001 10.00 0.0202 4.619E-05

U 238 3 He 0.001 0.0001 10.00 0.0202 4.619E-05

U 238 3 He 0.001 0.0001 10.00 0.0202 4.619E-05

Sc 45 1 No Gas 1489158.57

Sc 45 1 No Gas 1555066.07

Page 15025 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Sc 45 1 No Gas 1539070.60

Ge 72 1 No Gas 577009.21

Ge 72 1 No Gas 595433.62

Ge 72 1 No Gas 593293.16

Sc 45 2 H2 159844.49

Sc 45 2 H2 161125.21

Sc 45 2 H2 162730.72

Ge 72 2 H2 106421.36

Ge 72 2 H2 108705.55

Ge 72 2 H2 107307.95

In 115 2 H2 238754.88

In 115 2 H2 238559.23

In 115 2 H2 238187.13

Sc 45 3 He 44711.83

Sc 45 3 He 43659.10

Sc 45 3 He 45684.45

Ge 72 3 He 63425.95

Ge 72 3 He 61900.01

Ge 72 3 He 63045.34

In 115 3 He 50803.85

In 115 3 He 50442.29

In 115 3 He 50432.92

Tb 159 3 He 146041.67

Tb 159 3 He 145811.48

Tb 159 3 He 145496.48

Bi 209 3 He 85580.67

Bi 209 3 He 83782.36

Bi 209 3 He 84957.68

Page 15026 of 16273

Data File Name 092SMPL.d

Acq/Data Batch C:\Agilent\ICPMH\1\DATA\25E28A00.b

Acq Time 5/28/2025 12:00:34 PM

Sample Name 180-189742-B-26-B DU@10

Sample Type Sample

MS E9Comment

Prep Dilution 1.0000

Auto Dilution 1.0000

Total Dilution 1.0000

Operator Name us19_usr_ins23851

SpectrumAcq Mode

---Cal Title

External CalibrationCal Type

5/28/2025 10:14:18 AMLast Calib

---Bkg File

Bkg Mode Count Subtraction except for ISTD

FQ BlankFile ---

Point to PointVIS Fit

FullQuant Table

Element Mass ISTD Tune Mode Conc. Units RSD(%) CPS Ratio Det. Time(sec) Rep

Be 9 72 No Gas -0.007 ppb N/A 24.67 0.0000 Pulse 0.5000 3

Se 78 72 H2 0.456 ppb 21.7 22.89 0.0002 Pulse 1.5000 3

Na 23 45 He 18739.573 ppb 1.5 2192354.97 50.0035 Analog 0.1000 3

Mg 24 45 He 1.748 ppb 81.4 446.69 0.0102 Pulse 0.1000 3

Al 27 45 He 41.674 ppb 12.6 926.72 0.0211 Pulse 0.1000 3

K 39 45 He 3511.246 ppb 0.5 215558.05 4.9162 Pulse 0.5000 3

Ca 44 72 He 47404.170 ppb 1.2 119018.56 1.9232 Pulse 0.5000 3

Ti 47 45 He -0.012 ppb N/A 2.67 0.0001 Pulse 0.5000 3

V 51 45 He 0.342 ppb 3.4 806.69 0.0184 Pulse 0.5000 3

Cr 52 45 He 0.346 ppb 77.9 4934.23 0.1125 Pulse 0.1000 3

Mn 55 45 He -0.004 ppb N/A 340.01 0.0078 Pulse 0.5000 3

Fe 57 45 He 0.612 ppb 429.9 496.69 0.0113 Pulse 0.1000 3

Co 59 45 He 0.111 ppb 8.6 372.68 0.0085 Pulse 0.5000 3

Ni 60 45 He 2.108 ppb 4.9 1642.09 0.0375 Pulse 0.5000 3

Cu 63 72 He 4.156 ppb 1.5 6748.77 0.1090 Pulse 0.5000 3

Zn 66 72 He 0.586 ppb 10.2 316.01 0.0051 Pulse 0.5000 3

As 75 72 He 0.263 ppb 25.5 79.33 0.0013 Pulse 0.5000 3

Sr 88 115 He 344.597 ppb 1.0 193847.70 3.8513 Pulse 0.1000 3

Mo 98 115 He 4.455 ppb 6.2 4794.21 0.0953 Pulse 0.1000 3

Ag 107 115 He -0.004 ppb N/A 30.00 0.0006 Pulse 0.1000 3

Cd 111 72 He -0.014 ppb N/A 1.33 0.0000 Pulse 0.5000 3

Sn 120 115 He -0.203 ppb N/A 3197.09 0.0635 Pulse 0.1000 3

Sb 121 115 He 0.092 ppb 29.6 76.67 0.0015 Pulse 0.3000 3

Ba 137 115 He 21.484 ppb 8.3 4694.21 0.0932 Pulse 0.1000 3

Tl 205 159 He -0.003 ppb N/A 40.00 0.0003 Pulse 0.1000 3

Pb 208 159 He 0.212 ppb 36.5 1576.75 0.0107 Pulse 0.1000 3

U 238 159 He 0.001 ppb 310.4 10.00 0.0001 Pulse 0.1000 3

ISTD Table:

Page 15027 of 16273

Tune Mode Element Mass CPS RSD(%) ISTD Recovery % Det. Time(seq) Rep

No Gas Sc 45 1518672.94 1.6 97.0 Analog 0.1000 3

No Gas Ge 72 589744.52 0.8 92.9 Pulse 0.1000 3

H2 Sc 45 157723.13 1.1 105.4 Pulse 0.1000 3

H2 Ge 72 106203.04 1.0 100.5 Pulse 0.1000 3

H2 In 115 236394.42 2.3 108.2 Pulse 0.1000 3

He Sc 45 43846.13 0.5 108.9 Pulse 0.1000 3

He Ge 72 61893.20 1.7 95.8 Pulse 0.1000 3

He In 115 50336.64 1.1 103.7 Pulse 0.1000 3

He Tb 159 146801.95 0.2 102.1 Pulse 0.1000 3

He Bi 209 84129.29 0.5 103.8 Pulse 0.1000 3

No Gas

Mass

10 20 30 40 50 60 70 80 90 100

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190 200

Co un t

5x10

Mass

210 220 230 240 250 260 270 280 290 300

Co un t

5x10

H2

Mass

10 20 30 40 50 60 70 80 90

Co un t

4x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

4x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

4x10

Page 15028 of 16273

He

Mass

10 20 30 40 50 60 70 80 90

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

5x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

5x10

Replicate:

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Be 9 1 No Gas -0.009 0 24.00 0.0009 4.831E-05

Be 9 1 No Gas -0.004 0 26.00 0.0009 4.831E-05

Be 9 1 No Gas -0.009 0 24.00 0.0009 4.831E-05

Se 78 2 H2 0.365 0.0002 18.67 0.0005 8.428E-06

Se 78 2 H2 0.442 0.0002 22.00 0.0005 8.428E-06

Se 78 2 H2 0.561 0.0003 28.00 0.0005 8.428E-06

Na 23 3 He 18438.772 49.2183 2171029.81 0.0026 1.085

Na 23 3 He 18808.296 50.1829 2193959.03 0.0026 1.085

Na 23 3 He 18971.653 50.6093 2212076.06 0.0026 1.085

Mg 24 3 He 0.732 0.0088 390.02 0.0013 0.007869

Mg 24 3 He 3.375 0.0124 540.03 0.0013 0.007869

Mg 24 3 He 1.138 0.0094 410.02 0.0013 0.007869

Al 27 3 He 43.626 0.022 970.05 0.0004 0.002817

Al 27 3 He 35.747 0.0185 810.05 0.0004 0.002817

Al 27 3 He 45.648 0.0229 1000.07 0.0004 0.002817

K 39 3 He 3523.096 4.9309 217502.91 0.0012 0.5615

K 39 3 He 3492.949 4.8935 213940.44 0.0012 0.5615

K 39 3 He 3517.692 4.9242 215230.81 0.0012 0.5615

Ca 44 3 He 46752.419 1.8968 119105.35 0 0.00417

Ca 44 3 He 47830.075 1.9404 117931.23 0 0.00417

Ca 44 3 He 47630.015 1.9323 120019.10 0 0.00417

Ti 47 3 He -0.043 0 2.00 0.0005 6.671E-05

Ti 47 3 He 0.049 0.0001 4.00 0.0005 6.671E-05

Ti 47 3 He -0.042 0 2.00 0.0005 6.671E-05

V 51 3 He 0.329 0.0181 800.02 0.0202 0.01151

V 51 3 He 0.35 0.0186 812.03 0.0202 0.01151

V 51 3 He 0.346 0.0185 808.03 0.0202 0.01151

Cr 52 3 He 0.654 0.1204 5311.03 0.0256 0.1036

Cr 52 3 He 0.152 0.1075 4700.81 0.0256 0.1036

Cr 52 3 He 0.233 0.1096 4790.85 0.0256 0.1036

Mn 55 3 He -0.068 0.007 310.01 0.0113 0.007802

Page 15029 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Mn 55 3 He 0.078 0.0087 380.01 0.0113 0.007802

Mn 55 3 He -0.022 0.0076 330.01 0.0113 0.007802

Fe 57 3 He 2.017 0.012 530.03 0.0005 0.01103

Fe 57 3 He -2.423 0.0098 430.02 0.0005 0.01103

Fe 57 3 He 2.242 0.0121 530.03 0.0005 0.01103

Co 59 3 He 0.106 0.0083 364.01 0.0463 0.003347

Co 59 3 He 0.122 0.009 394.01 0.0463 0.003347

Co 59 3 He 0.106 0.0082 360.01 0.0463 0.003347

Ni 60 3 He 2.053 0.0367 1620.09 0.0132 0.009623

Ni 60 3 He 2.043 0.0366 1600.09 0.0132 0.009623

Ni 60 3 He 2.227 0.039 1706.10 0.0132 0.009623

Cu 63 3 He 4.091 0.1076 6753.43 0.0229 0.01386

Cu 63 3 He 4.16 0.1091 6633.39 0.0229 0.01386

Cu 63 3 He 4.217 0.1104 6859.48 0.0229 0.01386

Zn 66 3 He 0.538 0.005 312.01 0.0028 0.00344

Zn 66 3 He 0.653 0.0053 322.01 0.0028 0.00344

Zn 66 3 He 0.568 0.0051 314.00 0.0028 0.00344

As 75 3 He 0.275 0.0013 82.00 0.0022 0.0006908

As 75 3 He 0.191 0.0011 68.00 0.0022 0.0006908

As 75 3 He 0.324 0.0014 88.00 0.0022 0.0006908

Sr 88 3 He 341.68 3.8187 192771.58 0.0112 0.001442

Sr 88 3 He 348.364 3.8933 193611.21 0.0112 0.001442

Sr 88 3 He 343.748 3.8418 195160.31 0.0112 0.001442

Mo 98 3 He 4.503 0.0963 4860.92 0.021 0.001512

Mo 98 3 He 4.706 0.1006 5000.94 0.021 0.001512

Mo 98 3 He 4.156 0.089 4520.77 0.021 0.001512

Ag 107 3 He -0.013 0.0002 10.00 0.0425 0.0007547

Ag 107 3 He -0.004 0.0006 30.00 0.0425 0.0007547

Ag 107 3 He 0.005 0.001 50.00 0.0425 0.0007547

Cd 111 3 He -0.002 0.0001 4.00 0.0036 7.231E-05

Cd 111 3 He -0.02 0 0.00 0.0036 7.231E-05

Cd 111 3 He -0.02 0 0.00 0.0036 7.231E-05

Sn 120 3 He -0.408 0.0606 3060.40 0.014 0.06634

Sn 120 3 He -0.285 0.0623 3100.41 0.014 0.06634

Sn 120 3 He 0.085 0.0675 3430.47 0.014 0.06634

Sb 121 3 He 0.12 0.0019 96.67 0.0136 0.0002754

Sb 121 3 He 0.088 0.0015 73.33 0.0136 0.0002754

Sb 121 3 He 0.066 0.0012 60.00 0.0136 0.0002754

Ba 137 3 He 22.151 0.0961 4850.88 0.0043 0.0001378

Ba 137 3 He 19.469 0.0845 4200.75 0.0043 0.0001378

Ba 137 3 He 22.831 0.099 5031.00 0.0043 0.0001378

Tl 205 3 He -0.011 0.0001 20.00 0.0176 0.0003242

Tl 205 3 He 0.005 0.0004 60.00 0.0176 0.0003242

Tl 205 3 He -0.003 0.0003 40.00 0.0176 0.0003242

Pb 208 3 He 0.253 0.0117 890.06 0.0229 0.005891

Pb 208 3 He 0.26 0.0118 870.05 0.0229 0.005891

Pb 208 3 He 0.123 0.0087 560.03 0.0229 0.005891

U 238 3 He 0.001 0.0001 10.00 0.0202 4.619E-05

U 238 3 He -0.002 0 0.00 0.0202 4.619E-05

U 238 3 He 0.004 0.0001 20.00 0.0202 4.619E-05

Sc 45 1 No Gas 1496795.13

Sc 45 1 No Gas 1515119.04

Page 15030 of 16273

Name Mass Tune Step Tune Mode Calc Conc. Ratio CPS a b (blank)

Sc 45 1 No Gas 1544104.66

Ge 72 1 No Gas 589949.48

Ge 72 1 No Gas 585162.41

Ge 72 1 No Gas 594121.67

Sc 45 2 H2 157248.09

Sc 45 2 H2 156249.52

Sc 45 2 H2 159671.79

Ge 72 2 H2 107256.57

Ge 72 2 H2 105092.40

Ge 72 2 H2 106260.15

In 115 2 H2 231674.45

In 115 2 H2 235097.46

In 115 2 H2 242411.36

Sc 45 3 He 44110.25

Sc 45 3 He 43719.27

Sc 45 3 He 43708.87

Ge 72 3 He 62792.67

Ge 72 3 He 60775.85

Ge 72 3 He 62111.07

In 115 3 He 50502.86

In 115 3 He 49750.57

In 115 3 He 50823.63

Tb 159 3 He 146395.47

Tb 159 3 He 146908.97

Tb 159 3 He 147101.40

Bi 209 3 He 83739.76

Bi 209 3 He 84595.70

Bi 209 3 He 84052.42

Page 15031 of 16273

Data File Name 093SMPL.d

Acq/Data Batch C:\Agilent\ICPMH\1\DATA\25E28A00.b

Acq Time 5/28/2025 12:02:45 PM

Sample Name 180-189742-B-24-A@10

Sample Type Sample

MS E9Comment

Prep Dilution 1.0000

Auto Dilution 1.0000

Total Dilution 1.0000

Operator Name us19_usr_ins23851

SpectrumAcq Mode

---Cal Title

External CalibrationCal Type

5/28/2025 10:14:18 AMLast Calib

---Bkg File

Bkg Mode Count Subtraction except for ISTD

FQ BlankFile ---

Point to PointVIS Fit

FullQuant Table

Element Mass ISTD Tune Mode Conc. Units RSD(%) CPS Ratio Det. Time(sec) Rep

Be 9 72 No Gas -0.002 ppb N/A 28.00 0.0000 Pulse 0.5000 3

Se 78 72 H2 0.314 ppb 12.5 15.78 0.0002 Pulse 1.5000 3

Na 23 45 He 23715.816 ppb 0.4 2737981.21 62.9937 Analog 0.1000 3

Mg 24 45 He 3.601 ppb 11.2 550.03 0.0127 Pulse 0.1000 3

Al 27 45 He 49.627 ppb 11.7 1070.07 0.0246 Pulse 0.1000 3

K 39 45 He 3797.402 ppb 1.6 229122.93 5.2711 Pulse 0.5000 3

Ca 44 72 He 45666.500 ppb 0.8 117822.08 1.8528 Pulse 0.5000 3

Ti 47 45 He 0.050 ppb 182.8 4.00 0.0001 Pulse 0.5000 3

V 51 45 He 0.282 ppb 15.4 747.35 0.0172 Pulse 0.5000 3

Cr 52 45 He -0.164 ppb N/A 4320.72 0.0994 Pulse 0.1000 3

Mn 55 45 He 0.002 ppb 2302.1 340.01 0.0078 Pulse 0.5000 3

Fe 57 45 He 3.162 ppb 75.4 546.70 0.0126 Pulse 0.1000 3

Co 59 45 He 0.136 ppb 0.9 418.68 0.0096 Pulse 0.5000 3

Ni 60 45 He 1.937 ppb 7.8 1529.42 0.0352 Pulse 0.5000 3

Cu 63 72 He 4.768 ppb 3.1 7827.26 0.1231 Pulse 0.5000 3

Zn 66 72 He 0.453 ppb 33.1 300.67 0.0047 Pulse 0.5000 3

As 75 72 He 0.099 ppb 52.2 58.00 0.0009 Pulse 0.5000 3

Sr 88 115 He 336.842 ppb 0.7 190060.89 3.7646 Pulse 0.1000 3

Mo 98 115 He 3.291 ppb 5.0 3573.85 0.0708 Pulse 0.1000 3

Ag 107 115 He -0.002 ppb N/A 33.33 0.0007 Pulse 0.1000 3

Cd 111 72 He -0.008 ppb N/A 2.67 0.0000 Pulse 0.5000 3

Sn 120 115 He -0.064 ppb N/A 3303.80 0.0654 Pulse 0.1000 3

Sb 121 115 He 0.046 ppb 48.8 45.56 0.0009 Pulse 0.3000 3

Ba 137 115 He 13.628 ppb 5.7 2987.05 0.0592 Pulse 0.1000 3

Tl 205 159 He 0.006 ppb 133.0 63.33 0.0004 Pulse 0.1000 3

Pb 208 159 He 0.226 ppb 22.5 1610.09 0.0111 Pulse 0.1000 3

U 238 159 He 0.001 ppb 301.6 10.00 0.0001 Pulse 0.1000 3

ISTD Table:

Page 15032 of 16273

Tune Mode Element Mass CPS RSD(%) ISTD Recovery % Det. Time(seq) Rep

No Gas Sc 45 1560005.81 0.2 99.6 Analog 0.1000 3

No Gas Ge 72 598051.48 1.0 94.3 Pulse 0.1000 3

H2 Sc 45 157493.70 2.5 105.3 Pulse 0.1000 3

H2 Ge 72 104619.47 2.3 99.0 Pulse 0.1000 3

H2 In 115 232308.67 1.7 106.4 Pulse 0.1000 3

He Sc 45 43465.15 0.8 108.0 Pulse 0.1000 3

He Ge 72 63592.89 1.1 98.5 Pulse 0.1000 3

He In 115 50486.48 0.2 104.0 Pulse 0.1000 3

He Tb 159 145705.26 1.7 101.4 Pulse 0.1000 3

He Bi 209 84182.99 0.5 103.8 Pulse 0.1000 3

No Gas

Mass

10 20 30 40 50 60 70 80 90 100

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190 200

Co un t

5x10

Mass

210 220 230 240 250 260 270 280 290 300

Co un t

5x10

H2

Mass

10 20 30 40 50 60 70 80 90

Co un t

4x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

4x10

Mass

210 220 230 240 250 260 270 280 290

Co un t

4x10

Page 15033 of 16273

He

Mass

10 20 30 40 50 60 70 80 90

Co un t

5x10

Mass

110 120 130 140 150 160 170 180 190

Co un t

5x10

Mass

210 220 230…