MSDS_for_Fuel.pdf

F-76 Military Diesel

No. 2 Grade Diesel Fuel Oil; Diesel No. 2; Off-Road Diesel Fuel; Diesel Motor Fuel No.

2; High Sulfur Diesel Fuel; HS Diesel Fuel; Gas Oil (Medium); C9-C16 Petroleum Hydrocarbons.

Technical Contact: (800) 248-4684 Medical Emergency: (832) 486-4700 CHEMTREC Emergency: (800) 424-9300 (United States Only)

SAFETY DATA SHEET

GHS product identifier

Synonyms

Emergency telephone number (with hours of operation)

Section 1. Identification

Chemical name : Fuels, diesel, No 2

Supplier's details : CITGO Petroleum Corporation P.O. Box 4689 Houston, TX 77210

F-76 Military Diesel

Fuel.Material uses :

13176:Code

MSDS # : 13176

sdsvend@citgo.com

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2B CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (central nervous system (CNS)) - Category 2 ASPIRATION HAZARD - Category 1 AQUATIC HAZARD (LONG-TERM) - Category 2

Classification of the substance or mixture

Signal word : Danger

Hazard statements : Flammable liquid and vapor.

Harmful if inhaled.

Causes skin and eye irritation.

Suspected of causing cancer.

May be fatal if swallowed and enters airways.

May cause damage to organs through prolonged or repeated exposure. (central nervous system (CNS)) Toxic to aquatic life with long lasting effects.

Hazard pictograms :

Precautionary statements

GHS label elements

General : Diesel engine exhaust can cause upper respiratory tract irritation and reversible pulmonary effects. Long-term exposure to diesel engine exhaust may cause cancer.

Do not syphon by mouth.

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 1/17

Section 2. Hazards identification Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection.

Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Do not breathe vapor.

Wash hands thoroughly after handling.

Response : Collect spillage. Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:

Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage : Store locked up. Store in a well-ventilated place. Keep cool.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Supplemental label elements

: Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and receiving equipment. These alone may be insufficient to remove static electricity. Do not taste or swallow. Wash thoroughly after handling.

Hazards not otherwise classified

: Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor may cause flash fire or explosion. Causes digestive tract burns. Prolonged or repeated contact may dry skin and cause irritation.

Section 3. Composition/information on ingredients

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Chemical name : Fuels, diesel, No 2

Other means of identification

: No. 2 Grade Diesel Fuel Oil; Diesel No. 2; Off-Road Diesel Fuel; Diesel Motor Fuel No.

2; High Sulfur Diesel Fuel; HS Diesel Fuel; Gas Oil (Medium); C9-C16 Petroleum Hydrocarbons.

CAS number : 68476-34-6

Substance/mixture

CAS number/other identifiers

Occupational exposure limits, if available, are listed in Section 8.

Substance

Any concentration shown as a range is to protect confidentiality or is due to process variation.

Fuels, diesel, No 2 >99 68476-34-6 Benzene, trimethyl- 1 - 5 25551-13-7 Naphthalene 0.5 - 1.5 91-20-3 biphenyl 0.5 - 1.5 92-52-4 Cumene 0.5 - 1.5 98-82-8 Xylene 0.5 - 1.5 1330-20-7 Ethylbenzene 0.5 - 1.5 100-41-4

* = Various ** = Mixture *** = Proprietary

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 2/17

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Notes to physician : If ingested, this material presents a significant aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal intubation or by placement of the body in a Trendelenburg and left lateral decubitus position.

Description of necessary first aid measures

Specific treatments : Treat symptomatically and supportively.

Most important symptoms/effects, acute and delayed

Inhalation : Harmful if inhaled.

Corrosive to the digestive tract. Causes burns. May be fatal if swallowed and enters airways.

:Ingestion

Skin contact : Causes skin irritation. Defatting to the skin.

Causes eye irritation.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Repeated or prolonged overexposure to solvents can cause brain or other nervous system damage. The symptoms can include the loss of memory, the loss of intellectual capacity and the loss of coordination.

Adverse symptoms may include the following:

stomach pains nausea or vomiting

Adverse symptoms may include the following:

irritation redness dryness cracking

Eye contact : Adverse symptoms may include the following:

pain or irritation watering redness

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 3/17

Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that gas or vapor is still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:

carbon dioxide carbon monoxide Diesel engine exhaust

Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static accumulation may be significantly increased by the presence of small quantities of water or other contaminants. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use caution when applying carbon dioxide in confined spaces.

SMALL FIRE: Steam, CO2, dry chemical or inert gas (e.g., nitrogen). LARGE FIRE:

Use foam, water fog or water spray. Water fog and spray are effective in cooling containers and adjacent structures. However, water can cause frothing and/or may not extinguish the fire. Water can be used to cool the external walls of vessels to prevent excessive pressure, ignition or explosion.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures

: No action shall be taken involving any personal risk or without suitable training.

Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.

No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 4/17

Section 6. Accidental release measures Environmental precautions

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

Large spill :

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

Section 7. Handling and storage

Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure -obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Restrict flow velocity according to API 2003 (2008), NFPA 77 (2007), and Laurence Britton, “Avoiding Static Ignition Hazards in Chemical Operations”. To reduce potential for static discharge, ensure that all equipment is properly grounded and bonded and meets appropriate electrical classification requirements. Non equilibrium conditions may increase the fire hazard associated with this product. Always bond receiving containers to the fill pipe before and during loading. Always confirm that receiving container is properly grounded. Bonding and grounding alone may be inadequate to eliminate fire and explosion hazards. Carefully review operations that may increase the risks such as tank and container filling, tank cleaning, sampling, gauging, loading, filtering, mixing, agitation, etc. In addition to bonding and grounding, efforts to mitigate the hazards may include, but are not limited to, ventilation, inerting and/or reduction of transfer velocities.

Always keep nozzle in contact with the container throughout the loading process. Do NOT fill any portable container in or on a vehicle.

Precautions for safe handling

Special precautions, such as reduced loading rates and increased monitoring, must be observed during "switch loading" operations (i.e., loading this material in tanks or shipping compartments that previously contained a dissimilar product).

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 5/17

Section 7. Handling and storage Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area.

Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use.

Bulk Storage Conditions: Maintain all storage tanks in accordance with applicable regulations. Use necessary controls to monitor tank inventories. Inspect all storage tanks on a periodic basis. Test tanks and associated piping for tightness. Maintain the automatic leak detection devices to assure proper working condition.

Head spaces in tanks and other containers may contain a mixture of air and vapor in the flammable range. Vapor may be ignited by static discharge. Storage area must meet OSHA requirements and applicable fire codes. Additional information regarding the design and control of hazards associated with the handling and storage of flammable and combustible liquids may be found in professional and industrial documents including, but not limited to, the National Fire Protection Association (NFPA) publications NFPA 30 ("Flammable and Combustible Liquid Code"), NFPA 77 ("Recommended Practice on Static Electricity") and the American Petroleum Institute (API) Recommended Practice 2003, (“Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents").

Section 8. Exposure controls/personal protection Control parameters

Occupational exposure limits

Benzene, trimethyl- ACGIH TLV (United States, 4/2014).

TWA: 25 ppm 8 hours.

TWA: 123 mg/m³ 8 hours.

Naphthalene ACGIH (United States). Absorbed through skin.

TWA: 10 ppm 8 hours.

STEL: 15 ppm 15 minutes.

OSHA (United States).

TWA: 10 ppm 8 hours.

ACGIH TLV (United States, 4/2014).

Absorbed through skin.

TWA: 10 ppm 8 hours.

TWA: 52 mg/m³ 8 hours.

OSHA PEL (United States, 2/2013).

TWA: 10 ppm 8 hours.

TWA: 50 mg/m³ 8 hours.

biphenyl OSHA PEL Z2 (United States).

TWA: 0.2 ppm 8 hours.

ACGIH TLV (United States, 4/2014).

TWA: 0.2 ppm 8 hours.

TWA: 1.3 mg/m³ 8 hours.

OSHA PEL (United States, 2/2013).

TWA: 0.2 ppm 8 hours.

TWA: 1 mg/m³ 8 hours.

Cumene ACGIH TLV (United States, 4/2014).

TWA: 50 ppm 8 hours.

OSHA PEL (United States, 2/2013).

Absorbed through skin.

TWA: 50 ppm 8 hours.

TWA: 245 mg/m³ 8 hours.

Xylene ACGIH TLV (United States, 4/2014).

TWA: 100 ppm 8 hours.

TWA: 434 mg/m³ 8 hours.

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 6/17

Section 8. Exposure controls/personal protection

Hand protection

Avoid inhalation of gases, vapors, mists or dusts. Use a properly fitted, air-purifying or supplied-air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. If an air purifying respirator is appropriate, use one equipped with cartridges rated for organic vapors.

Avoid skin contact with liquid. Chemical-resistant gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Recommended: Heavy duty, industrial grade chemically resistant gloves constructed of nitrile, neoprene, polyethylene, fluoroelastomer rubber or polyvinyl chloride as approved by glove manufacturer.

Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. Leather gloves are not protective for liquid contact.

Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If inhalation hazards exist, a full-face respirator may be required instead.

Eye/face protection

Respiratory protection :

Body protection Avoid skin contact with liquid. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, vapor controls, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection : Avoid skin contact with liquid. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Leather boots are not protective for liquid contact.

STEL: 150 ppm 15 minutes.

STEL: 651 mg/m³ 15 minutes.

OSHA PEL (United States, 2/2013).

TWA: 100 ppm 8 hours.

TWA: 435 mg/m³ 8 hours.

Ethylbenzene ACGIH TLV (United States, 4/2014).

TWA: 20 ppm 8 hours.

OSHA PEL (United States, 2/2013).

TWA: 100 ppm 8 hours.

TWA: 435 mg/m³ 8 hours.

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 7/17

Section 9. Physical and chemical properties

Physical state

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

0.84

5 [Air = 1]

0.27 kPa (2 mm Hg) [room temperature]

Very slightly soluble in the following materials: cold water.

Characteristic.Odor pH

Amber.Color

Evaporation rate <1 (butyl acetate = 1)

Flash point Closed cup: 54°C (129.2°F) [Pensky-Martens.]

>3.3

Not available.

Viscosity Kinematic (40°C (104°F)): 0.02 cm2/s (2 cSt)

Partition coefficient: n-octanol/water

Appearance

Boiling point : 282 to 338°C (539.6 to 640.4°F)

Lower and upper explosive (flammable) limits

: Lower: 0.6% Upper: 6.5%

Density lbs/gal

Gravity, °API

: Estimated 37 @ 60 F

Estimated 7 lbs/gal

Viscosity SUS : Estimated 9 SUS @104 F

Conductivity : <50 picosiemens/meter (unadditized)

Flow time (ISO 2431) : Not available.

Density gm/cm3 : 0.87 g/cm³

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Do not store with strong oxidizing agents.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Reactive or incompatible with the following materials:

oxidizing materials

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : Not expected to be Explosive, Self-Reactive, Self-Heating, or an Organic Peroxide under US GHS Definition(s).

Section 11. Toxicological information

Acute toxicity Information on toxicological effects

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 8/17

Section 11. Toxicological information

Benzene, trimethyl- LD50 Oral Rat 8970 mg/kg - Naphthalene LD50 Oral Rat 490 mg/kg -biphenyl LD50 Dermal Rabbit >5010 mg/kg -

LD50 Oral Rat 2140 mg/kg - Cumene LC50 Inhalation Vapor Mouse 10 g/m³ 7 hours

LD50 Dermal Rabbit 12300 uL/kg - LD50 Oral Rat 2.9 g/kg - LD50 Oral Rat 4000 mg/kg -

Xylene LC50 Inhalation Vapor Rat 5000 ppm 4 hours LC50 Inhalation Vapor Rat 6700 ppm 4 hours LD50 Oral Mouse 2119 mg/kg - LD50 Oral Rat 4300 mg/kg - LD50 Oral Rat 4300 mg/kg -

Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg -

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Not available.

Mutagenicity

Not available.

Irritation/Corrosion

Benzene, trimethyl- Eyes - Mild irritant Rabbit - 24 hours 500 milligrams

Skin - Moderate irritant Rabbit - 24 hours 500 milligrams

Naphthalene Skin - Mild irritant Rabbit - 495 milligrams biphenyl Eyes - Mild irritant Rabbit - 100 milligrams

Skin - Severe irritant Rabbit - 24 hours 500 microliters

Cumene Eyes - Mild irritant Rabbit - 86 milligrams - Skin - Mild irritant Rabbit - 24 hours 10 milligrams

Xylene Skin - Mild irritant Rat - 8 hours 60 microliters

Skin - Moderate irritant Rabbit - 24 hours 500 milligrams

Skin - Moderate irritant Rabbit - 100 Percent - Ethylbenzene Skin - Mild irritant Rabbit - 24 hours 15 milligrams

Product/ingredient name Result Score Exposure Observation

Sensitization

Not available.

Species

Classification

Conclusion/Summary : No additional information.

Conclusion/Summary : No additional information.

Skin

Respiratory

No additional information.

No additional information.

Skin

Eyes Respiratory

No additional information.

No additional information.

No additional information.

Conclusion/Summary : No additional information.

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 9/17

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Information on the likely routes of exposure

Inhalation : Harmful if inhaled.

Corrosive to the digestive tract. Causes burns. May be fatal if swallowed and enters airways.

:Ingestion

Skin contact : Causes skin irritation. Defatting to the skin.

Causes eye irritation.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:

pain or irritation watering redness

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Benzene, trimethyl- Category 3 Not applicable. Respiratory tract irritation and Narcotic effects biphenyl Category 3 Not applicable. Respiratory tract irritation

Cumene Category 3 Not applicable. Respiratory tract irritation

Ethylbenzene Category 3 Not applicable. Respiratory tract irritation

Name Category

Name Category

Benzene, trimethyl- Category 2 Not determined central nervous system (CNS)

Ethylbenzene Category 2 Inhalation ears

Aspiration hazard

Name Result

Benzene, trimethyl- ASPIRATION HAZARD - Category 1 Cumene ASPIRATION HAZARD - Category 1 Ethylbenzene ASPIRATION HAZARD - Category 1 Propylbenzene ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Route of exposure

Target organs

: Routes of entry anticipated: Dermal, Inhalation.

Potential acute health effects

Fuels, diesel, No 2 - 3 - Naphthalene - 2B Reasonably anticipated to be a human carcinogen.

Cumene - 2B Reasonably anticipated to be a human carcinogen.

Xylene - 3 - Ethylbenzene - 2B -

Product/ingredient name NTPIARCOSHA

Conclusion/Summary : No additional information.

No additional information.Conclusion/Summary :

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 10/17

Skin contact

Ingestion

Inhalation Repeated or prolonged overexposure to solvents can cause brain or other nervous system damage. The symptoms can include the loss of memory, the loss of intellectual capacity and the loss of coordination.

Adverse symptoms may include the following:

stomach pains nausea or vomiting

Adverse symptoms may include the following:

irritation redness dryness cracking

Delayed and immediate effects and also chronic effects from short and long term exposure

Potential immediate effects

: Not available.

Short term exposure

Potential delayed effects : Not available.

Potential immediate effects

: Not available.

Long term exposure

Potential delayed effects : Not available.

Not available.

May cause damage to organs through prolonged or repeated exposure.General :

Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Potential chronic health effects

Section 12. Ecological information Toxicity

Benzene, trimethyl- Acute LC50 5600 µg/l Marine water Crustaceans - Palaemonetes pugio

48 hours

Naphthalene Acute EC50 1.6 ppm Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 2350 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours

Acute LC50 213 µg/l Fresh water Fish - Melanotaenia fluviatilis - Larvae

96 hours

Chronic NOEC 0.5 mg/l Marine water Crustaceans - Uca pugnax - Adult 3 weeks Chronic NOEC 1.5 mg/l Fresh water Fish - Oreochromis mossambicus 60 days biphenyl Acute LC50 360 µg/l Fresh water Daphnia - Daphnia magna - Neonate

48 hours

Acute LC50 1450 µg/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 0.17 mg/l Fresh water Daphnia - Daphnia magna -

Neonate 21 days

Chronic NOEC 0.229 mg/l Fresh water Fish - Oncorhynchus mykiss 87 days Cumene Acute EC50 2600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours

Acute EC50 7400 µg/l Fresh water Crustaceans - Artemia sp. - 48 hours

Product/ingredient name SpeciesResult Exposure

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 11/17

Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

Fuels, diesel, No 2 >3.3 - low Benzene, trimethyl- 3.4 to 3.8 - low Naphthalene 3.4 36.5 to 168 low biphenyl 4.008 1900 high Cumene 3.55 35.48 low Xylene 3.12 8.1 to 25.9 low Ethylbenzene 3.6 - low

Nauplii Acute EC50 10600 µg/l Fresh water Daphnia - Daphnia magna -

Neonate 48 hours

Acute LC50 2700 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours Xylene Acute EC50 90 mg/l Fresh water Crustaceans - Cypris subglobosa 48 hours

Acute LC50 8.5 ppm Marine water Crustaceans - Palaemonetes pugio - Adult

48 hours

Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes pugio

48 hours

Acute LC50 15700 µg/l Fresh water Fish - Lepomis macrochirus - Juvenile (Fledgling, Hatchling, Weanling)

96 hours

Acute LC50 19000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours Acute LC50 16940 µg/l Fresh water Fish - Carassius auratus 96 hours

Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata

72 hours

Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata

96 hours

Acute EC50 6530 µg/l Fresh water Crustaceans - Artemia sp. - Nauplii

48 hours

Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna - Neonate

48 hours

Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

Not available.

Conclusion/Summary : Not available.

Conclusion/Summary : Not available.

Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.

Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.

Vapor from product residues may create a highly flammable or explosive atmosphere

:Disposal methods

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 12/17

Section 13. Disposal considerations inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

RCRA classification : D001, D018

Section 14. Transport information

Packaging instruction Passenger aircraft Quantity limitation: 60 L Packaging instructions: Y309

Cargo aircraft Quantity limitation: 220 L Packaging instructions: 310

Remarks 49 CFR 173.150 (f)(1) states that a flammable liquid with a flash point at or above 38ºC (100ºF) that does not meet the definition of any other hazard class may be reclassed as a combustible liquid. This provision does not apply to transportation by vessel or aircraft except where other means of transportaion is impracticable.

Quantity limitation Cargo Aircraft Only: 220 L. Packaging instructions: 310. Limited Quantities - Passenger Aircraft: 60 L. Packaging instructions: 309Y.

Additional information

Special precautions for user

Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3).

Tunnel code (D/E)

DOT Classification

TDG Classification

ADR/RID

IATA

Diesel Fuel

III

Diesel Fuel

UN 1202

NA1993

DOT Classification IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Environmental hazards

No. No.

IMDG

UN 1202

Diesel Fuel

No.

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 13/17

Section 15. Regulatory information U.S. Federal regulations :

SARA 302/304

SARA 304 RQ : Not applicable.

Composition/information on ingredients

SARA 311/312

Classification : FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2B CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (central nervous system (CNS)) - Category 2 ASPIRATION HAZARD - Category 1 HNOC - Corrosive to digestive tract HNOC - Static-accumulating flammable liquid

Clean Water Act (CWA) 307: ethylbenzene; naphthalene; toluene; benzene

Clean Water Act (CWA) 311: ethylbenzene; xylene; naphthalene; toluene; benzene

United States inventory (TSCA 8b): All components are listed or exempted.

This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802.

Fuels, diesel, No 2 >99 FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2B CARCINOGENICITY - Category 2

SPECIFIC TARGET ORGAN TOXICITY (REPEATED

EXPOSURE) (central nervous system (CNS)) - Category 2 ASPIRATION HAZARD - Category 1 HNOC - Corrosive to digestive tract HNOC - Static-accumulating flammable liquid

Benzene, trimethyl- 1 - 5 FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Respiratory tract irritation) - Category 3

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Narcotic effects) - Category 3

SPECIFIC TARGET ORGAN TOXICITY (REPEATED

EXPOSURE) (central nervous system (CNS)) - Category 2 ASPIRATION HAZARD - Category 1

Naphthalene 0.5 - 1.5 FLAMMABLE SOLIDS - Category 2 ACUTE TOXICITY (oral) - Category 4 CARCINOGENICITY - Category 2 biphenyl 0.5 - 1.5 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Respiratory tract irritation) - Category 3

Cumene 0.5 - 1.5 FLAMMABLE LIQUIDS - Category 3 EYE IRRITATION - Category 2A CARCINOGENICITY (inhalation) - Category 2

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Respiratory tract irritation) - Category 3 ASPIRATION HAZARD - Category 1

Name % Classification

Composition/information on ingredients

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 14/17

The following components are listed: trimethylbenzene; ethyltolueneMassachusetts :

New York : The following components are listed: Ethylbenzene; Cumene; Benzene, 1-methylethyl-;

Naphthalene

New Jersey : The following components are listed: ethylbenzene; cumene; NAPHTHALENE; MOTH FLAKES; TRIMETHYL BENZENE (mixed isomers); BENZENE, TRIMETHYL-;

ETHYLTOLUENES; BENZENE, ETHYLMETHYL-

Pennsylvania : The following components are listed: ethylbenzene; cumene; NAPHTHALENE;

trimethylbenzene; ethyltoluene

State regulations

International regulations

Inventory list

Australia : All components are listed or exempted.

Canada : All components are listed or exempted.

China : All components are listed or exempted.

United States : All components are listed or exempted.

SARA 313

Product name CAS number %

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

naphthalene 91-20-3 <1 ethylbenzene 100-41-4 <1 naphthalene 91-20-3 <1 ethylbenzene 100-41-4 <1

Form R - Reporting requirements

Supplier notification

Diesel exhaust particulate <0.2 Yes. No. - -naphthalene <1 Yes. No. Yes. -cumene <1 Yes. No. - -ethylbenzene <1 Yes. No. Yes. -toluene <0.1 No. Yes. - Yes.

benzene <0.1 Yes. Yes. Yes. Yes.

Ingredient name Cancer Reproductive No significant risk level

Maximum acceptable dosage level

WHMIS (Canada) : Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F).

Class D-2A: Material causing other toxic effects (Very toxic).

WARNING: This product can expose you to Benzene, which is known to the State of California to cause cancer and birth defects or other reproductive harm. This product can expose you to chemicals including Diesel exhaust particulate, Naphthalene, Cumene, Ethylbenzene, which are known to the State of California to cause cancer, and Toluene, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.

California Prop. 65 Clear and Reasonable Warnings (2018)

Xylene 0.5 - 1.5 FLAMMABLE LIQUIDS - Category 3 ACUTE TOXICITY (inhalation) - Category 4 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A

SPECIFIC TARGET ORGAN TOXICITY (REPEATED

EXPOSURE) (hearing organs) - Category 2

Ethylbenzene 0.5 - 1.5 FLAMMABLE LIQUIDS - Category 2 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A CARCINOGENICITY (inhalation) - Category 2

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(Respiratory tract irritation) - Category 3 ASPIRATION HAZARD - Category 1

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 15/17

Europe : All components are listed or exempted.

Japan : Japan inventory (ENCS): All components are listed or exempted.

Japan inventory (ISHL): Not determined.

Republic of Korea : All components are listed or exempted.

Malaysia : Not determined.

New Zealand : All components are listed or exempted.

Philippines : All components are listed or exempted.

Taiwan : Not determined.

Turkey : Not determined.

Thailand : Not determined.

Viet Nam : Not determined.

Section 16. Other information

3/22/2018

History

Date of printing

Date of issue/Date of revision

Version

Date of previous issue

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

3/22/2018

No previous validation

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.

Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.

Procedure used to derive the classification

Classification Justification

FLAMMABLE LIQUIDS - Category 3 Expert judgment ACUTE TOXICITY (inhalation) - Category 4 Expert judgment SKIN IRRITATION - Category 2 Expert judgment EYE IRRITATION - Category 2B Expert judgment CARCINOGENICITY - Category 2 Expert judgment SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (central nervous system (CNS)) - Category 2

Calculation method

ASPIRATION HAZARD - Category 1 Expert judgment AQUATIC HAZARD (LONG-TERM) - Category 2 Expert judgment

National Fire Protection Association (U.S.A.)

Health

Special

Instability/Reactivity

Flammability

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 16/17

Section 16. Other information

Notice to reader

Indicates information that has changed from previously issued version.

References : Not available.

THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR

IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY. SOME INFORMATION PRESENTED AND

CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR

PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION.

THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE

PRODUCT.

CITGO is a registered trademark of CITGO Petroleum Corporation

Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version : 1 17/17

Safety Data Sheet

Material Name: Jet Fuel JP-8

SDS No. 9946

US GHS

Synonyms: Military Aviation Jet Fuel JP –8

Page 1 of 10 Revision Date 8/30/12

* * * Section 1 - Product and Company Identification * * * Manufacturer Information Hess Corporation Phone: 732-750-6000 Corporate EHS 1 Hess Plaza Emergency # 800-424-9300 CHEMTREC Woodbridge, NJ 07095-0961 www.hess.com (Environment, Health, Safety Internet Website)

* * * Section 2 - Hazards Identification * * * GHS Classification:

Flammable Liquids - Category 3 Skin Corrosion/Irritation - Category 2 Eye Damage/Irritation - Category 2A Carcinogenicity - Category 2 Specific Target Organ Systemic Toxicity (STOT) - Single Exposure Category 3 Aspiration Hazard - Category 1 Hazardous to the Aquatic Environment Chronic - Category 2

GHS LABEL ELEMENTS

Symbol(s)

Signal Word

Danger Hazard Statements

Flammable liquid and vapor.

Causes skin irritation.

Causes serious eye irritation.

Suspected of causing cancer.

May cause respiratory irritation.

May cause drowsiness or dizziness.

May be fatal if swallowed and enters airways.

Toxic to aquatic life with long lasting effects.

Precautionary Statements Prevention Keep away from heat/sparks/open flames/hot surfaces. No smoking Keep container tightly closed.

Ground/bond container and receiving equipment.

http://www.hess.com/

Page 2 of 10 Revision Date 8/30/12

Use explosion-proof electrical/ventilating/lighting/equipment.

Use only non-sparking tools.

Take precautionary measures against static discharge.

Wear protective gloves/protective clothing/eye protection/face protection.

Wash thoroughly after handling.

Obtain special instructions before use.

Do not handle until all safety precautions have been read and understood.

Avoid breathing fume/gas/mist/vapors/spray.

Use only outdoors or in a well-ventilated area.

Response IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. If eye irritation persists: Get medical advice/attention.

IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell.

IF SWALLOWED: Immediately call a poison center or doctor/physician. Do NOT induce vomiting.

If exposed or concerned: Get medical advice/attention.

In case of fire: Use water spray, fog or fire fighting foam to extinguish.

Storage Store locked up.

Store in a well-ventilated place. Keep cool.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

* * * Section 3 - Composition / Information on Ingredients * * *

CAS # Component Percent 8008-20-6 Kerosene 100 91-20-3 Naphthalene 0.04

A complex combination of hydrocarbons including naphthenes, paraffins, and aromatics.

* * * Section 4 - First Aid Measures * * * First Aid: Eyes

In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold eyelids open to ensure adequate flushing. Seek medical attention.

First Aid: Skin Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or with waterless hand cleanser. Obtain medical attention if irritation or redness develops. Thermal burns require immediate medical attention depending on the severity and the area of the body burned.

Page 3 of 10 Revision Date 8/30/12

First Aid: Ingestion DO NOT INDUCE VOMITING. Do not give liquids. Obtain immediate medical attention. If spontaneous vomiting occurs, lean victim forward to reduce the risk of aspiration. Monitor for breathing difficulties. Small amounts of material which enter the mouth should be rinsed out until the taste is dissipated.

First Aid: Inhalation Remove person to fresh air. If person is not breathing, provide artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately.

* * * Section 5 - Fire Fighting Measures * * * General Fire Hazards

See Section 9 for Flammability Properties.

Vapors may be ignited rapidly when exposed to heat, spark, open flame or other source of ignition. When mixed with air and exposed to an ignition source, flammable vapors can burn in the open or explode in confined spaces.

Being heavier than air, vapors may travel long distances to an ignition source and flash back. Runoff to sewer may cause fire or explosion hazard.

Hazardous Combustion Products Carbon monoxide, carbon dioxide and…