ATTACHMENT 13 - First Quarterly Groundwater Monitoring Report.pdf
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This is a First Quarterly Groundwater Monitoring Report for the Bruce W. Carter Veterans Affairs Medical Center in Miami, Florida, prepared by Tierra Group on behalf of the Department of Veterans Affairs. The facility, located at 1201 NW 16th Street, Miami, is subject to groundwater monitoring and assessment directed by Miami-Dade County Division of Environmental Resources Management (DERM) under regulatory file DERM UT-2694/File-0751 and FDEP No. 13-8628963.
Groundwater samples were collected on September 9, 2024, from monitoring wells MW-3 and MW-8 and analyzed by Pace Analytical Services for volatile organic halocarbons (VOHs), total recoverable petroleum hydrocarbons (TRPH), and arsenic. Results indicated total arsenic concentrations of 2.4 micrograms per liter (ug/L) at MW-3 and 8.8 ug/L at MW-8, with dissolved arsenic at 8.9 ug/L at MW-8 and chloroform detected at 1.0 ug/L at MW-8. All detected parameters were reported below their respective maximum contaminant levels (MCLs) and groundwater cleanup target levels (GCTLs). The report includes supporting laboratory analytical documentation, groundwater sampling logs, chain of custody records, calibration logs, and regulatory correspondence from June 17, 2024, approving the Groundwater Sampling Plan. Based on the results, continued quarterly groundwater monitoring is recommended in support of No Further Action with Controls (NFAC) status under Chapter 62-780.680, F.A.C.
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FIRST QUARTERLY
GROUNDWATER MONITORING REPORT
Department of Veterans Affairs – Miami Veterans Affairs Healthcare System
Bruce W. Carter Veterans Affairs Medical Center
DERM UT-2694/File-0751
FDEP No. 13-8628963
Prepared for:
Miami-Dade County Department of Regulatory and Economic Resources
Environmental Monitoring and Evaluation Section
Division of Environmental Resources Management (DERM)
701 NW 1st Court, 4th Floor
Miami, Florida 33136
On behalf of:
1201 NW 16th Street
Miami, Florida 33125
Prepared by:
Tierra Group
1230 SW 6th Street
Pompano Beach, FL 33069
September 30, 2024
I, Scott Zednek, P.G. #2086, certify that I currently hold an active license in the state of Florida and am competent through education and experience to provide the geological service contained in this report. I further certify that, in my professional judgement, this report meets the requirements of Chapter 62-780, F.A.C., Contaminated Site Cleanup Criteria, and was prepared by me or under my responsible charge. Moreover, I certify that Tierra Group holds an active
Certificate of Authorization #GB374 to provide this geological service.
Scott C. Zednek, P.G.
Florida License No. 0002086
TABLE OF CONTENTS
SECTION PAGE
1.0 Introduction
2.0 Site Description
3.0 Groundwater Sampling and Analysis
4.0 Conclusions and Recommendations
TABLES
Table 1 Well Construction Details and Groundwater Elevation Data
Table 2 Summary of Groundwater Analytical Results
FIGURES
Figure 1 USGS Site Location Map
Figure 2 Site Plan
Figure 3 Groundwater Analytical Results
APPENDICES
Appendix A Regulatory Correspondence, Dated June 17, 2024
Appendix B Laboratory Analytical Report, Groundwater Sampling Logs, and Calibration Logs
First Quarterly Groundwater Monitoring Report Page 1
DERM UT-2694/File-0751; FDEP No. 13-8628963
FIRST QUARTERLY
GROUNDWATER MONITORING REPORT
DERM UT-2694/File-0751
FDEP No. 13-8628963
1.0 INTRODUCTION
Tierra Group (Tierra) has prepared this First Quarterly Groundwater Monitoring Report for the
Bruce W. Carter Veterans Affairs Medical Center facility (DERM UT-2694/File-0751; FDEP No.
13-8628963), addressed as 1201 NW 16th Street, Miami, Florida, on behalf of the Department of
Veterans Affairs, Miami Veterans Affairs Healthcare System. The USGS Topographic Quadrangle
Map [Miami, Florida-Dade Co.] depicting the location of the facility is included as Figure 1.
According to the Miami-Dade County Property Appraiser, United States of America VA Hospital, is the legal owner of the subject property. Miami-Dade County Division of Environmental
Resources Management (DERM) is directing the assessment and monitoring at the site. This report summarizes the first quarter of groundwater monitoring activities performed following approval of the Groundwater Sampling Plan by Miami-Dade County DERM on June 17, 2024 (Appendix
A). Tierra conducted all sampling in accordance with the Florida Department of Environmental
Protection (FDEP) Standard Operating Procedures for Field Activities (DEP-SOP-001/01).
2.0 SITE DESCRIPTION
The site is situated in Section 35, Township 53 South, Range 41 East in Miami-Dade County at the junction of NW 16th Street and NW 14th Avenue. The site is currently occupied by the Bruce
W. Carter Veterans Affairs Medical Center, which spans 26 acres measuring approximately 900 feet from north to south and 1,200 feet from east to west. A Site Plan depicting the location of groundwater monitoring wells is included as Figure 2.
According to historical records, the facility was the subject of previous environmental evaluations, cleanup activities, and monitoring related to petroleum releases from underground storage tank
(UST) and aboveground storage tank (AST) systems. Site assessment activities included installing monitoring wells, evaluating groundwater flow conditions, and assessing contaminants of concern
First Quarterly Groundwater Monitoring Report Page 2
DERM UT-2694/File-0751; FDEP No. 13-8628963 in soil and groundwater. Prior recommendations included quarterly groundwater monitoring and excavation of impacted soils to facilitate site closure. During tank closure activities performed between May and June 2018, a total of 98.92 tons of impacted soil were removed from the UST excavation and properly disposed of at a permitted waste disposal facility. Further assessment data indicated that soil impacts remain beyond the footprint of the UST area.
3.0 GROUNDWATER SAMPLING AND ANALYSIS
On September 9, 2024, groundwater samples were collected from monitoring wells MW-3 and
MW-8. Groundwater samples were submitted to Pace Analytical Services, a National
Environmental Laboratory Accreditation Program (NELAP) accredited environmental laboratory
[Florida DOH certification number E83079], for analysis of volatile organic halocarbons (VOHs), total recoverable petroleum hydrocarbons (TRPH), and arsenic. Due to elevated turbidity after purging five well volumes from MW-8, an additional unpreserved sample was collected and requested for laboratory filtration and analysis of dissolved arsenic. Groundwater samples were collected in accordance with DEP-SOP-001/01 FS 2200, as provided by Chapter 62-160, Florida
Administrative Code (F.A.C.).
Review of groundwater analytical results yielded the following observations:
• Total arsenic was detected at a concentration of 2.4 micrograms per liter (ug/L) at MW-3.
No other parameters were detected above laboratory method detection limits (MDLs);
• Total arsenic and dissolved arsenic were detected at MW-8 at concentrations of 8.8 ug/L and 8.9 ug/L, respectively, demonstrating that turbidity did not contribute to the total arsenic concentration. Chloroform was detected at a concentration of 1.0 ug/L at MW-8.
No other parameters were detected above laboratory MDLs; and
• All parameters detected during the first quarterly groundwater monitoring event were reported at concentrations below their respective maximum contaminant levels (MCLs) and groundwater cleanup target levels (GCTLs), as provided by Chapter 62-550 and
Chapter 62-777, F.A.C., and/or Chapter 24, Code of Miami-Dade County.
Depth-to-water measurements gauged at monitoring wells MW-3 and MW-8 are included in Table
1. Groundwater analytical results are summarized in Table 2 and are depicted on Figure 3.
Groundwater sampling logs, calibration logs, and the laboratory analytical report with supporting chain of custody documentation are provided as Appendix B.
First Quarterly Groundwater Monitoring Report Page 3
DERM UT-2694/File-0751; FDEP No. 13-8628963
4.0 CONCLUSIONS AND RECOMMENDATIONS
Tierra Group prepared the First Quarterly Groundwater Monitoring Report for the Bruce W. Carter
Veterans Affairs Medical Center in Miami, Florida, on behalf of the Department of Veterans
Affairs, Miami Veterans Affairs Healthcare System. The report summarizes groundwater monitoring activities conducted following the approval of the Groundwater Sampling Plan by
Miami-Dade County DERM in June 2024. Prior assessment at the site demonstrated elevated concentrations of VOHs, TRPH, and arsenic, leading to recommendations for quarterly groundwater monitoring and soil excavation activities.
In September 2024, groundwater samples were collected from monitoring wells MW-3 and MW-
8 for analysis of VOHs, TRPH, and arsenic. Analytical results indicated total arsenic concentrations of 2.4 ug/L at MW-3 and 8.8 ug/L at MW-8. Dissolved arsenic was detected at
MW-8 at a concentration 8.9 ug/L, demonstrating that turbidity did not contribute to the total arsenic concentration. Chloroform, a common residual product of chlorinated potable water, was detected at 1.0 ug/L at MW-8. All detected parameters were reported below their respective MCLs and GCTLs.
Based upon results of the first quarterly groundwater sampling event, Tierra recommends continued groundwater monitoring in accordance with the approved Groundwater Sampling Plan, dated May 24, 2024, in support of No Further Action with Controls (NFAC) status under Chapter
62-780.680, F.A.C.
TABLES
Well ID
Well Diameter (in)
Screened Interval (ft)
TOC (ft)
Date DTW GW ELEV. DTW GW ELEV.
9/9/2024 3.89 N/A 6.99 N/A
Notes:
TOC - Top of Casing Elevation
DTW - Depth to Water below TOC in feet
N/A - Not Available
TABLE 1: WELL CONSTRUCTION DETAILS AND GROUNDWATER ELEVATION DATA
FACILITY ID: DERM UT-2694/File-0751; FDEP No. 13-8628963
FACILITY NAME: Bruce W. Carter Veterans Affairs Medical Center
FACILITY ADDRESS: V/O 1201 NW 16th Street, Miami, Florida 33125
N/A
MW-8
2-inch
4.90 to 14.90
2-inch
3.08 to 13.08
N/A
MW-3
Parameter Units MW-3 MW-8 GCTL/MCL NADC
Arsenic (Total) ug/L 2.4 8.8 10 100
Arsenic (Dissolved) ug/L - 8.9 10 100
1,1,1-Trichloroethane ug/L 0.30 U 0.30 U 200 2,000
1,1,2,2-Tetrachloroethane ug/L 0.59 U 0.59 U 0.2 20
1,1,2-Trichloroethane ug/L 0.30 U 0.30 U 5 500
1,1-Dichloroethane ug/L 0.34 U 0.34 U 70 700
1,1-Dichloroethene ug/L 0.59 U 0.59 U 7 70
1,2-Dichloroethane ug/L 0.27 U 0.27 U 3 300
1,2-Dichloropropane ug/L 0.23 U 0.23 U 5 500
2-Chloroethylvinyl ether ug/L 6.1 U 6.1 U - -
Bromodichloromethane ug/L 0.19 U 0.19 U 0.6 60
Bromoform ug/L 0.48 U 0.48 U 4.4 440
Bromomethane ug/L 3.9 U 3.9 U 9.8 98
Carbon tetrachloride ug/L 0.44 U 0.44 U 3 300
Chloroethane ug/L 3.7 U 3.7 U 12 1,200
Chloroform ug/L 0.56 U 1.0 70 700
Chloromethane ug/L 0.43 U 0.43 U 2.7 270
Dibromochloromethane ug/L 0.45 U 0.45 U 0.4 40
Dichlorodifluoromethane ug/L 0.80 U 0.80 U 1,400 14,000
Methylene Chloride ug/L 1.7 U 1.7 U 5 500
Tetrachloroethene ug/L 0.38 U 0.38 U 3 300
Trichloroethene ug/L 0.36 U 0.36 U 3 300
Trichlorofluoromethane ug/L 0.72 U 0.72 U 2,100 21,000
Vinyl chloride ug/L 0.39 U 0.39 U 1 100 cis-1,2-Dichloroethene ug/L 0.27 U 0.27 U 70 700 cis-1,3-Dichloropropene ug/L 0.17 U 0.17 U 0.4 40 trans-1,2-Dichloroethene ug/L 0.23 U 0.23 U 100 1,000 trans-1,3-Dichloropropene ug/L 0.37 U 0.37 U 0.4 40
TRPH ug/L 750 U 740 U 5,000 50,000
Notes:
ug/L - Micrograms per liter
GCTL - Groundwater Cleanup Target Level, Florida Administrative Code 62-777, Table I
MCL - Maximum Contaminant Level, Florida Adminstrative Code 62-550, Table I
NADC - Natural Attenuation Default Concentration, Florida Administrative Code 62-777, Table V
U - Indicates parameter was analyzed but not detected
I - Parameter reported value between laboratory method detection limit and practical quantitation limit
TABLE 2: SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
FACILITY ID: DERM UT-2694/File-0751; FDEP No. 13-8628963
FACILITY NAME: Bruce W. Carter Veterans Affairs Medical Center FACILITY ADDRESS: V/O 1201 NW 16th Street, Miami, Florida 33125
FIGURES
FIGURE 1 - USGS SITE LOCATION MAP DRAWN BY: TKDATE: 09/27/2024500’
SCALE: APPROX. 1” = 1,000’
1,000’0’
CLIENT: DEPT. OF VETERANS AFFAIRS
O: (954) 202 9226 E: ADMIN@TIERRASOLUTIONS.COM WWW.TIERRASOLUTIONS.COM
Project Site 1201 NW 16th Street
Miami, FL
PROJECT: BRUCE W. CARTER VA MEDICAL CENTER
NOTE:
- USGS TOPOGRAPHIC MAP, MIAMI QUADRANGLE, FLORIDA-DADE CO., 7.5-MINUTE SERIES (TOPOGRAPHIC), 1994.
FIGURE 2 - SITE PLAN DRAWN BY: TKDATE: 09/27/202420’
SCALE: APPROX. 1” = 40’
40’0’
CLIENT: DEPT. OF VETERANS AFFAIRS
O: (954) 202 9226 E: ADMIN@TIERRASOLUTIONS.COM WWW.TIERRASOLUTIONS.COM
PROJECT: BRUCE W. CARTER VA MEDICAL CENTER
MW-3
MW-8
= GRASS / OPEN GROUND
LEGEND
= MONITORING WELL
= EXISTING BUILDING
FIGURE 3 - GW ANALYTICAL RESULTS DRAWN BY: TKDATE: 09/27/202420’
SCALE: APPROX. 1” = 40’
40’0’
CLIENT: DEPT. OF VETERANS AFFAIRS
O: (954) 202 9226 E: ADMIN@TIERRASOLUTIONS.COM WWW.TIERRASOLUTIONS.COM
PROJECT: BRUCE W. CARTER VA MEDICAL CENTER
MW-3
Arsenic (Total): 2.4 ug/L
Arsenic (Total): 8.8 ug/L Arsenic (Dissolved): 8.9 ug/L Chloroform: 1.0 ug/L
MW-8
NOTES:
- UG/L = MICROGRAMS PER LITER; ANALYTICAL RESULTS OF GROUNDWATER SAMPLES COLLECTED ON SEPTEMBER 9, 2024.
= GRASS / OPEN GROUND
LEGEND
= MONITORING WELL
= EXISTING BUILDING
APPENDIX A
Regulatory Correspondence, Dated June 17, 2024
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VHAMIACarloO Text Box Former UST and Incinerator Area
VHAMIACarloO Text Box Miami VA Healthcare System UT-2694/File-751
VHAMIACarloO Oval
VHAMIACarloO Text Box
MW-24
VHAMIACarloO Oval
VHAMIACarloO Text Box
MW-3
VHAMIACarloO Text Box
MW-8
VHAMIACarloO Oval
VHAMIACarloO Oval
VHAMIACarloO Text Box New MW
APPENDIX B
Laboratory Analytical Report, Groundwater Sampling Logs, and
Calibration Logs
#=CL#
September 18, 2024
LIMS USE: FR - ALEX CARLTON
LIMS OBJECT ID: 35904422
35904422 Project:
Pace Project No.:
RE:
Alex Carlton Tierra Consulting Group, LLC 1230 SW 6 Street Pompano Beach, FL 33069
Miami VA
Dear Alex Carlton:
Enclosed are the analytical results for sample(s) received by the laboratory on September 09, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely, Rossy Guima rossy.guima@pacelabs.com
Project Manager 954-582-4300
Enclosures cc: Admin, Tierra Consulting Group, LLC Jane Carlton, Tierra Consulting Group, LLC Tom Knox, Tierra Consulting Group, Inc.
Jean Mazza, Tierra Consulting Group, LLC Andrea Wolverton, Tierra Group Scott Zednek, Tierra Consulting Group, LLC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC 3610 Park Central Blvd N
Pompano Beach, FL 33064 (954)582-4300
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
35904422 Miami VA
Pace Analytical Services Ormond Beach 8 East Tower Circle, Ormond Beach, FL 32174 Alaska DEC- CS/UST/LUST Alabama Certification #: 41320 California Certification# 3096 Colorado Certification: FL NELAC Reciprocity Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity DoD-ANAB #:ADE-3199 Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maine Certification #: FL01264 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236
Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL022 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Ohio DEP 87780 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Utah FL NELAC Reciprocity Utah Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC 3610 Park Central Blvd N
Pompano Beach, FL 33064
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
35904422 Miami VA
Lab ID Sample ID Matrix Date Collected Date Received
35904422001 MW-3 Water 09/09/24 14:16 09/09/24 17:40
35904422002 MW-8 Water 09/09/24 12:56 09/09/24 17:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC 3610 Park Central Blvd N
Pompano Beach, FL 33064
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
35904422 Miami VA
Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts
35904422001 MW-3 FL-PRO 3 PASI-OMBI
EPA 6020 1 PASI-OBSL
EPA 8260 29 PASI-OCLT
35904422002 MW-8 FL-PRO 3 PASI-OMBI
EPA 6020 1 PASI-OBSL
EPA 6020 1 PASI-OBSL
EPA 8260 29 PASI-OCLT
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC 3610 Park Central Blvd N
Pompano Beach, FL 33064
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
35904422 Miami VA
Parameters AnalyzedResult Lab Sample ID
Report Limit QualifiersUnitsMethod Client Sample ID
35904422001 MW-3
Arsenic 2.4 ug/L 09/18/24 12:141.0EPA 6020
35904422002 MW-8
Arsenic 8.8 ug/L 09/17/24 18:521.0EPA 6020 Arsenic, Dissolved 8.9 ug/L 09/17/24 18:171.0EPA 6020 Chloroform 1.0 ug/L 09/13/24 18:561.0EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC 3610 Park Central Blvd N
Pompano Beach, FL 33064
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
35904422 Miami VA
Sample: MW-3 Lab ID: 35904422001 Collected: 09/09/24 14:16 Received: 09/09/24 17:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: FL-PRO Preparation Method: EPA 3510 Pace Analytical Services - Ormond Beach
FL-PRO Water, Low Volume
Petroleum Range Organics 0.75 U mg/L 09/10/24 17:0809/10/24 12:440.94 0.75 1 Surrogates o-Terphenyl (S) 98 % 09/10/24 17:08 84-15-109/10/24 12:4466-139 1 N-Pentatriacontane (S) 92 % 09/10/24 17:08 630-07-0909/10/24 12:4442-159 1
Analytical Method: EPA 6020 Preparation Method: EPA 3010 Pace Analytical Services - Ormond Beach
6020 MET ICPMS
Arsenic 2.4 ug/L 09/18/24 12:14 7440-38-209/10/24 08:031.0 0.50 1
Analytical Method: EPA 8260 Pace Analytical Services - Ormond Beach
8260 MSV
1,1,1-Trichloroethane 0.30 U ug/L 09/13/24 18:30 71-55-61.0 0.30 1 1,1,2,2-Tetrachloroethane 0.59 U ug/L 09/13/24 18:30 79-34-51.0 0.59 1 1,1,2-Trichloroethane 0.30 U ug/L 09/13/24 18:30 79-00-51.0 0.30 1 1,1-Dichloroethane 0.34 U ug/L 09/13/24 18:30 75-34-31.0 0.34 1 1,1-Dichloroethene 0.59 U ug/L 09/13/24 18:30 75-35-41.0 0.59 1 1,2-Dichloroethane 0.27 U ug/L 09/13/24 18:30 107-06-21.0 0.27 1 1,2-Dichloropropane 0.23 U ug/L 09/13/24 18:30 78-87-51.0 0.23 1 2-Chloroethylvinyl ether 6.1 U ug/L 09/13/24 18:30 110-75-8 c240.0 6.1 1 Bromodichloromethane 0.19 U ug/L 09/13/24 18:30 75-27-41.0 0.19 1 Bromoform 0.48 U ug/L 09/13/24 18:30 75-25-23.0 0.48 1 Bromomethane 3.9 U ug/L 09/13/24 18:30 74-83-910.0 3.9 1 Carbon tetrachloride 0.44 U ug/L 09/13/24 18:30 56-23-53.0 0.44 1 Chloroethane 3.7 U ug/L 09/13/24 18:30 75-00-310.0 3.7 1 Chloroform 0.56 U ug/L 09/13/24 18:30 67-66-31.0 0.56 1 Chloromethane 0.43 U ug/L 09/13/24 18:30 74-87-3 J(v1)1.0 0.43 1 Dibromochloromethane 0.45 U ug/L 09/13/24 18:30 124-48-12.0 0.45 1 Dichlorodifluoromethane 0.80 U ug/L 09/13/24 18:30 75-71-8 J(v1)1.0 0.80 1 Methylene Chloride 1.7 U ug/L 09/13/24 18:30 75-09-25.0 1.7 1 Tetrachloroethene 0.38 U ug/L 09/13/24 18:30 127-18-4 J(v2)1.0 0.38 1 Trichloroethene 0.36 U ug/L 09/13/24 18:30 79-01-61.0 0.36 1 Trichlorofluoromethane 0.72 U ug/L 09/13/24 18:30 75-69-41.0 0.72 1 Vinyl chloride 0.39 U ug/L 09/13/24 18:30 75-01-4 J(v1)1.0 0.39 1 cis-1,2-Dichloroethene 0.27 U ug/L 09/13/24 18:30 156-59-21.0 0.27 1 cis-1,3-Dichloropropene 0.17 U ug/L 09/13/24 18:30 10061-01-51.0 0.17 1 trans-1,2-Dichloroethene 0.23 U ug/L 09/13/24 18:30 156-60-51.0 0.23 1 trans-1,3-Dichloropropene 0.37 U ug/L 09/13/24 18:30 10061-02-61.0 0.37 1 Surrogates 4-Bromofluorobenzene (S) 99 % 09/13/24 18:30 460-00-470-130 1 Toluene-d8 (S) 101 % 09/13/24 18:30 2037-26-570-130 1 1,2-Dichlorobenzene-d4 (S) 98 % 09/13/24 18:30 2199-69-170-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/18/2024 02:51 PM
Pace Analytical Services, LLC 3610 Park Central Blvd N
Pompano Beach, FL 33064
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
35904422 Miami VA
Sample: MW-8 Lab ID: 35904422002 Collected: 09/09/24 12:56 Received: 09/09/24 17:40 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL
Analytical Method: FL-PRO Preparation Method: EPA 3510 Pace Analytical Services - Ormond Beach
FL-PRO Water, Low Volume
Petroleum Range Organics 0.74 U mg/L 09/10/24 19:0909/10/24 12:440.92 0.74 1 Surrogates o-Terphenyl (S) 92 % 09/10/24 19:09 84-15-109/10/24 12:4466-139 1 N-Pentatriacontane (S) 101 % 09/10/24 19:09 630-07-0909/10/24 12:4442-159 1
Analytical Method: EPA 6020 Preparation Method: EPA 3010 Pace Analytical Services - Ormond Beach
6020 MET ICPMS
Arsenic 8.8 ug/L 09/17/24 18:52 7440-38-209/10/24 08:031.0 0.50 1
Analytical Method: EPA 6020 Preparation Method: EPA 3010 Pace Analytical Services - Ormond Beach
6020 MET ICPMS, Lab Filtered
Arsenic, Dissolved 8.9 ug/L 09/17/24 18:17 7440-38-209/17/24 00:061.0 0.50 1
Analytical Method: EPA 8260 Pace Analytical Services - Ormond Beach
8260 MSV
1,1,1-Trichloroethane 0.30 U ug/L 09/13/24 18:56 71-55-61.0 0.30 1 1,1,2,2-Tetrachloroethane 0.59 U ug/L 09/13/24 18:56 79-34-51.0 0.59 1 1,1,2-Trichloroethane 0.30 U ug/L 09/13/24 18:56 79-00-51.0 0.30 1 1,1-Dichloroethane 0.34 U ug/L 09/13/24 18:56 75-34-31.0 0.34 1 1,1-Dichloroethene 0.59 U ug/L 09/13/24 18:56 75-35-41.0 0.59 1 1,2-Dichloroethane 0.27 U ug/L 09/13/24 18:56 107-06-21.0 0.27 1 1,2-Dichloropropane 0.23 U ug/L 09/13/24 18:56 78-87-51.0 0.23 1 2-Chloroethylvinyl ether 6.1 U ug/L 09/13/24 18:56 110-75-8 c240.0 6.1 1 Bromodichloromethane 0.19 U ug/L 09/13/24 18:56 75-27-41.0 0.19 1 Bromoform 0.48 U ug/L 09/13/24 18:56 75-25-23.0 0.48 1 Bromomethane 3.9 U ug/L 09/13/24 18:56 74-83-910.0 3.9 1 Carbon tetrachloride 0.44 U ug/L 09/13/24 18:56 56-23-53.0 0.44 1 Chloroethane 3.7 U ug/L 09/13/24 18:56 75-00-310.0 3.7 1 Chloroform 1.0 ug/L 09/13/24 18:56 67-66-31.0 0.56 1 Chloromethane 0.43 U ug/L 09/13/24 18:56 74-87-3 J(v1)1.0 0.43 1 Dibromochloromethane 0.45 U ug/L 09/13/24 18:56 124-48-12.0 0.45 1 Dichlorodifluoromethane 0.80 U ug/L 09/13/24 18:56 75-71-8 J(v1)1.0 0.80 1 Methylene Chloride 1.7 U ug/L 09/13/24 18:56 75-09-25.0 1.7 1 Tetrachloroethene 0.38 U ug/L 09/13/24 18:56 127-18-4 J(v2)1.0 0.38 1 Trichloroethene 0.36 U ug/L 09/13/24 18:56 79-01-61.0 0.36 1 Trichlorofluoromethane 0.72 U ug/L 09/13/24 18:56 75-69-41.0 0.72 1 Vinyl chloride 0.39 U ug/L 09/13/24 18:56 75-01-4 J(v1)1.0 0.39 1 cis-1,2-Dichloroethene 0.27 U ug/L 09/13/24 18:56 156-59-21.0 0.27 1 cis-1,3-Dichloropropene 0.17 U ug/L 09/13/24 18:56 10061-01-51.0 0.17 1 trans-1,2-Dichloroethene 0.23 U ug/L 09/13/24 18:56 156-60-51.0 0.23 1 trans-1,3-Dichloropropene 0.37 U ug/L 09/13/24 18:56 10061-02-61.0 0.37 1 Surrogates 4-Bromofluorobenzene (S) 97 % 09/13/24 18:56 460-00-470-130 1 Toluene-d8 (S) 100 % 09/13/24 18:56 2037-26-570-130 1 1,2-Dichlorobenzene-d4 (S) 100 % 09/13/24 18:56 2199-69-170-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/18/2024 02:51 PM
Pace Analytical Services, LLC 3610 Park Central Blvd N
Pompano Beach, FL 33064
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
35904422 Miami VA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1040134
EPA 3010
EPA 6020
6020 MET
Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35904422001, 35904422002
Parameter Units Blank Result
Reporting Limit Qualifiers
METHOD BLANK: 5715889
Associated Lab Samples: 35904422001, 35904422002
Matrix: Water
AnalyzedMDL
Arsenic ug/L 0.50 U 1.0 09/18/24 12:160.50
Parameter Units
LCS
Result % Rec Limits Qualifiers% RecConc.
5715890LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 48.350 97 80-120
Parameter Units
MS
Result % Rec Limits Qual% RecConc.
5715891MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike Result
35903582001
5715892
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike Conc.
Arsenic ug/L 50 100 75-125102 1 20502.4 52.6 53.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/18/2024 02:51 PM
Pace Analytical Services, LLC 3610 Park Central Blvd N
Pompano Beach, FL 33064
Pace Project No.:
Project:
35904422 Miami VA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1041732
EPA 3010
EPA 6020
6020 MET Dissolved
Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35904422002
Parameter Units Blank Result
Reporting Limit Qualifiers
METHOD BLANK: 5724824
Associated Lab Samples: 35904422002
Matrix: Water
AnalyzedMDL
Arsenic, Dissolved ug/L 0.50 U 1.0 09/17/24 18:140.50
Parameter Units
LCS
Result % Rec Limits Qualifiers% RecConc.
5724825LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic, Dissolved ug/L 95.5100 96 80-120
Parameter Units
MS
Result % Rec Limits Qual% RecConc.
5724826MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike Result
35904422002
5724827
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike Conc.
Arsenic, Dissolved ug/L 100 102 70-130103 1 201008.9 111 112
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/18/2024 02:51 PM
Pace Analytical Services, LLC 3610 Park Central Blvd N
Pompano Beach, FL 33064
Pace Project No.:
Project:
35904422 Miami VA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1041138
EPA 8260
EPA 8260
8260 MSV
Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 35904422001, 35904422002
Parameter Units Blank Result
Reporting Limit Qualifiers
METHOD BLANK: 5721730
Associated Lab Samples: 35904422001, 35904422002
Matrix: Water
AnalyzedMDL
1,1,1-Trichloroethane ug/L 0.30 U 1.0 09/13/24 10:390.30 1,1,2,2-Tetrachloroethane ug/L 0.59 U 1.0 09/13/24 10:390.59 1,1,2-Trichloroethane ug/L 0.30 U 1.0 09/13/24 10:390.30 1,1-Dichloroethane ug/L 0.34 U 1.0 09/13/24 10:390.34 1,1-Dichloroethene ug/L 0.59 U 1.0 09/13/24 10:390.59 1,2-Dichloroethane ug/L 0.27 U 1.0 09/13/24 10:390.27 1,2-Dichloropropane ug/L 0.23 U 1.0 09/13/24 10:390.23 2-Chloroethylvinyl ether ug/L 6.1 U 40.0 09/13/24 10:396.1 Bromodichloromethane ug/L 0.19 U 1.0 09/13/24 10:390.19 Bromoform ug/L 0.48 U 3.0 09/13/24 10:390.48 Bromomethane ug/L 3.9 U 10.0 09/13/24 10:393.9 Carbon tetrachloride ug/L 0.44 U 3.0 09/13/24 10:390.44 Chloroethane ug/L 3.7 U 10.0 09/13/24 10:393.7 Chloroform ug/L 0.56 U 1.0 09/13/24 10:390.56 Chloromethane ug/L 0.43 U 1.0 J(v1)09/13/24 10:390.43 cis-1,2-Dichloroethene ug/L 0.27 U 1.0 09/13/24 10:390.27 cis-1,3-Dichloropropene ug/L 0.17 U 1.0 09/13/24 10:390.17 Dibromochloromethane ug/L 0.45 U 2.0 09/13/24 10:390.45 Dichlorodifluoromethane ug/L 0.80 U 1.0 J(v1)09/13/24 10:390.80 Methylene Chloride ug/L 1.7 U 5.0 09/13/24 10:391.7 Tetrachloroethene ug/L 0.38 U 1.0 J(v2)09/13/24…
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