Attachment 12 - qdna-HOCUT795H.pdf

HOCUT™ 795-H

Not available.

CHEMTREC US/Canada:1-800-424-9300 or 1-703-527-3887 (24 hours)

SAFETY DATA SHEET

Product name

Other means of identification

Emergency telephone number (with hours of operation)

Section 1. Identification

Supplier : Quaker Houghton PA, Inc.

901 E. Hector Street Conshohocken, PA 19428 USA T: 610-832-4000

Wallover Oil Company 21845 Drake Road Strongsville, OH 44149 USA www.wallover.com T: (440) 238-9250

ProductStewardship@quakerhoughton.com www.quakerhoughton.com

HOCUT™ 795-H

Relevant identified uses of the substance or mixture and uses advised against

Relevant uses

Uses advised against

Product code : 202374-01

SDS according to the U.S. OSHA Hazard Communication Standard (29 CFR 1910.1200), Revison 2012

Metalworking fluid

Any other purpose.

Section 2. Hazards identification

SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1

Classification of the substance or mixture

Signal word : Warning

Hazard statements : Causes skin irritation.

May cause an allergic skin reaction.

Causes serious eye irritation.

Hazard pictograms :

GHS label elements

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard

(29 CFR 1910.1200).

Date of issue/Date of revision : 24 January 2021 Version : 1 1/10

HOCUT™ 795-H 202374-01

Section 2. Hazards identification Precautionary statements

Prevention : Wear eye or face protection. Avoid breathing vapor. Wash thoroughly after handling.

Response : Take off contaminated clothing and wash it before reuse. Wash contaminated clothing before reuse. IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing. If eye irritation persists: Get medical advice or attention.

Storage : Not applicable.

Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

: None known.

Section 3. Composition/information on ingredients

Mineral oil ≥50 - ≤75 ** 1-aminopropan-2-ol ≤10 78-96-6 Amine neutralized carboxylic Acid ≤5 - Amine neutralized carboxylic Acid ≤5 - Amine neutralized dicarboxylic Acid ≤3 - Alcohols, C12-15, ethoxylated ≤3 68131-39-5 Amine neutralized carboxylic Acid ≤3 - Amine neutralized carboxylic Acid ≤2.3 - 1,2-benzisothiazol-3(2H)-one ≤0.1 2634-33-5

Ingredient name CAS number%

Substance/mixture : Mixture

The exact percentage (concentration) of composition has been withheld as a trade secret

64742-52-5,64742-53-6:** May contain

The mineral oils in the product contain < 3% DMSO extract (IP 346).

Ingestion may cause gastrointestinal irritation and diarrhea. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.

Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Remove contact lenses, if present and easy to do. Get medical attention if symptoms occur.

Wash with plenty of soap and water. Remove contaminated clothing and wash it before reuse. Get medical attention if symptoms occur.

Move affected person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.

Get medical attention.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion :

Description of necessary first aid measures

Most important symptoms and effects, both acute and delayed

Inhalation : Not expected under normal use.

Not expected under normal use.:Ingestion

Skin contact : pain or irritation,redness,skin rash or hives pain or irritation,redness,watering:Eye contact

General advice : Get medical attention. If medical advice is needed, have product container or label at hand. Use personal protective equipment as required. Remove contaminated clothing and wash it before reuse. Wash skin surfaces thoroughly after contact.

Date of issue/Date of revision : 24 January 2021 Version : 1 2/10

Section 4. First aid measures

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Use personal protective equipment as required.

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments : No specific treatment.

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

In a fire, hazardous decomposition products may be produced. carbon oxides (CO, CO₂) nitrogen oxides

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire. Use dry chemical, CO₂, water spray (fog) or foam.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. For large spills, dike spilled material or otherwise contain it to ensure runoff does not reach a waterway. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

: No action shall be taken involving any personal risk or without suitable training. Put on appropriate personal protective equipment (see Section 8). Keep unnecessary personnel away. Avoid breathing vapor or mist. Provide adequate ventilation.

Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Do not allow any potentially contaminated water, including rain water, runoff from fire fighting or spills, to enter any waterway, sewer or drain.

Large spill :

Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill :

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Evacuate area.

Date of issue/Date of revision : 24 January 2021 Version : 1 3/10

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.

Precautions for safe handling

Storage temperature : Store between the following temperatures: -5 to 50°C (23 to 122°F).

Mineral oil NIOSH REL (United States, 10/2016).

TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: Mist ACGIH TLV (United States).

TWA: 5 mg/m³ 8 hours.

STEL: 10 mg/m³ 15 minutes.

1-aminopropan-2-ol None.

Amine neutralized carboxylic Acid None.

Amine neutralized carboxylic Acid None.

Amine neutralized dicarboxylic Acid None.

Alcohols, C12-15, ethoxylated None.

Amine neutralized carboxylic Acid None.

Amine neutralized carboxylic Acid None.

1,2-benzisothiazol-3(2H)-one None.

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection :

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Keep equipment clean.

Hygiene measures :

Control parameters

Individual protection measures

Occupational exposure limits

Date of issue/Date of revision : 24 January 2021 Version : 1 4/10

Section 8. Exposure controls/personal protection Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers.

Respiratory protection :

Other skin protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Thermal hazards : Not expected under normal use. Not relevant/applicable due to nature of the product.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

Not available.

0.942

Not available.

Not available.

Characteristic.Odor pH

HazyColor

Evaporation rate Not available.

Auto-ignition temperature

Flash point

Not available.

Not available.

Not available.

10.2 [Conc. (% w/w): 5%]

Viscosity Kinematic (40°C (104°F)): >0.206 cm2/s (>20.6 cSt)

Not available.Odor threshold

Partition coefficient: n-octanol/water

Appearance

Boiling point : Not available.

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.

Decomposition temperature : Not available.

Solubility in water : Not available.

Emulsifies.

VOC content

142 g/l:Product ASTM E1868-10

Date of issue/Date of revision : 24 January 2021 Version : 1 5/10

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid No specific measures identified.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Strong oxidizing materials. strong acids. strong alkalis

Incompatible materials :

Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Numerical measures of toxicity

1-aminopropan-2-ol LD50 Dermal Rabbit 1851 mg/kg - LD50 Oral Rat 1715 mg/kg -

Alcohols, C12-15, ethoxylated LD50 Oral Rat 2 g/kg - 1,2-benzisothiazol-3(2H)-one LC50 Inhalation Dusts and mists Rat 0.0501 mg/l 4 hours

LD50 Dermal Rat 4115 mg/kg - LD50 Oral Rat 1020 mg/kg -

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Mutagenicity

Reproductive toxicity

Irritation/Corrosion

1-aminopropan-2-ol Eyes - Severe irritant Rabbit - 24 hours 250 ug

Eyes - Severe irritant Rabbit - 970 ug - Skin - Mild irritant Rabbit - 24 hours 500 mg

Skin - Moderate irritant Rabbit - 485 mg - 1,2-benzisothiazol-3(2H)-one Skin - Mild irritant Human - 48 hours 5 % -

Product/ingredient name Result Score Exposure Observation

: Causes severe eye irritation. Causes skin irritation.

Sensitization

Species

Information on the likely routes of exposure

Other information : None identified.

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Acute toxicity estimates

Aspiration hazard

Information on toxicological effects

Route

Oral 4816.6 mg/kg Dermal 10785.65 mg/kg

ATE value

Acute toxicity : Based on available data, the classification criteria are not met.

: May cause sensitization by skin contact.

Based on available data, the classification criteria are not met.

Based on available data, the classification criteria are not met.

: Based on available data, the classification criteria are not met.

Based on available data, the classification criteria are not met.

Based on available data, the classification criteria are not met.

: Based on available data, the classification criteria are not met.

Date of issue/Date of revision : 24 January 2021 Version : 1 6/10

Section 11. Toxicological information Inhalation : No known significant effects or critical hazards.

:Ingestion

Skin contact : Causes skin irritation. May cause sensitization by skin contact.

Causes serious eye irritation.:Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Not expected under normal use.

Not expected under normal use.

pain or irritation,redness,skin rash or hives

Eye contact : pain or irritation,redness,watering

No known significant effects or critical hazards.

Delayed and immediate effects and also chronic effects from short and long term exposure

None identified.

Section 12. Ecological information

LogPow BCF Potential

Bioaccumulative potential

Other adverse effects : No known significant effects or critical hazards.

Product/ingredient name

1-aminopropan-2-ol -0.96 0.11 low Alcohols, C12-15, ethoxylated 2.03 to 6.24 - high

Toxicity

1-aminopropan-2-ol Acute EC50 32.7 mg/l Algae - Scenedesmus subspicatus

72 hours

Acute EC50 108.82 mg/l Daphnia - Daphnia magna 48 hours Acute LC50 210 mg/l Fresh water Fish - Carassius auratus 96 hours

Alcohols, C12-15, ethoxylated Acute EC50 0.7 mg/l Fresh water Algae - Pseudokirchneriella subcapitata

96 hours

Acute EC50 0.39 mg/l Fresh water Crustaceans - Ceriodaphnia dubia - Neonate

48 hours

Acute EC50 302 µg/l Fresh water Daphnia - Daphnia magna - Neonate

48 hours

Acute LC50 1400 µg/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 1 mg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours

Chronic NOEC 83 µg/l Fresh water Daphnia - Daphnia magna - Neonate

21 days

1,2-benzisothiazol-3(2H)-one Acute EC50 0.11 mg/l Algae - Selenastrum capricornutum

72 hours

Acute EC50 97 ppb Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 10 to 20 mg/l Fresh water Crustaceans - Ceriodaphnia dubia 48 hours

Acute LC50 167 ppb Fresh water Fish - Oncorhynchus mykiss 96 hours

Product/ingredient name SpeciesResult Exposure

Persistence and degradability

Soil/water partition coefficient (KOC)

: Not available.

Mobility in soil

This material is toxic to aquatic life. This material is harmful to aquatic life with long lasting effects.

Date of issue/Date of revision : 24 January 2021 Version : 1 7/10

Section 12. Ecological information

Section 13. Disposal considerations Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Empty containers or liners may retain some product residues. Empty containers retain product residue and can be hazardous.

Care should be taken when handling emptied containers that have not been cleaned or rinsed out.

:Disposal methods

Section 14. Transport information

Not regulated.

Not regulated. Not regulated.

DOT Classification

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

Special precautions for user

No. No. No.

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

IMDG IATA

Transport in bulk according to IMO instruments

: Not available.

Section 15. Regulatory information U.S. Federal regulations

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)

SARA 302/304

None of the components are listed.

Clean Water Act (CWA) 311

None of the components are listed.

None of the components are listed.

Clean Water Act (CWA) 307

CERCLA: Hazardous substances.

Reportable quantity 1,4-dioxane: 100 lbs. (45.4 kg); ethylene oxide: 10 lbs. (4.54 kg); 2,2'-iminodiethanol:

100 lbs. (45.4 kg); sodium hydroxide: 1000 lbs. (454 kg); acetaldehyde: 1000 lbs. (454 kg);

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302).

Date of issue/Date of revision : 24 January 2021 Version : 1 8/10

Section 15. Regulatory information

The following components are listed: 1-AMINO-2-PROPANOLMassachusetts :

SARA 313

Diethanolamine Trace Cancer Ethylene oxide Trace Cancer, Developmental, Reproductive female, Reproductive male Acetaldehyde Trace Cancer 1,4-Dioxane Trace Cancer

Ingredient name Concentration

California Prop. 65

New York : None of the components are listed.

New Jersey : The following components are listed: 2-PROPANOL, 1-AMINO-

Pennsylvania : The following components are listed: 2-PROPANOL, 1-AMINO-

State regulations

None of the components are listed.

SARA 311/312

Classification : See GHS Classification in section 2 for hazard class information

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

California

SCAQMD Rule 1144

142 g/l ASTM E1868-10Product as-supplied :

International regulations

Montreal Protocol

Not listed.

Stockholm Convention on Persistent Organic Pollutants

Not listed.

Rotterdam Convention on Prior Informed Consent (PIC)

UNECE Aarhus Protocol on POPs and Heavy Metals

Not listed.

Inventory list

United States : All components are active or exempted.

Not listed.

Canada : All components are listed or exempted.

The sale or distribution in the SCAQM District of California for metal working fluids or direct-contact lubricants is allowed if EITHER the VOC of the product itself OR the VOC of the diluted product at the point of use is less than the following limits: (1) 75 g VOC/L for metal forming, metal removal, metal treating; (2) 50 g VOC/L for metal protection, direct-contact lubricant. The VOC of this product as sold is:

Date of issue/Date of revision : 24 January 2021 Version : 1 9/10

Section 16. Other information

Version

This product's safety information is provided to assist our customers in assessing compliance with safety/health/ environmental regulations. The information contained herein is based on data available to us and is correct to the best of our knowledge, information and belief at the date of its publication. However, no warranty of merchantability, fitness for any use, or any other warranty is expressed or implied regarding the accuracy of this data, the results to be obtained from the use thereof, or the hazards connected with the use of the product. Since the use of this product is within the exclusive control of the user, it is the user's obligation to determine the conditions for safe use of the product. Such conditions should comply with all regulations concerning the product. The company referenced in this Safety Data Sheet assumes no liability for any injury or damage, direct or consequential, resulting from the use of this product unless such injury or damage is attributable to the gross negligence of such company.

Notice to reader

Indicates information that has changed from previously issued version.

References :

Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations VOC = Volatile Organic Compound

Quaker Houghton Product Stewardship

Safety data sheets of raw materials, global regulatory body information, scientific literature, and testing data .

Date of issue/Date of revision

: 1/24/2021

Date of issue/Date of revision : 24 January 2021 Version : 1 10/10