Attachment 10 - Castrol2986195.pdf

Hysol MB 50Product name

Section 1. Identification

Hysol MB 50

Product type

SDS no. 465450

Use of the substance/mixture Metalworking fluid - soluble.

For specific application advice see appropriate Technical Data Sheet or consult our company representative.

Supplier Castrol New Zealand Limited 73 Remuera Road Newmarket Auckland, New Zealand www.castrol.com/nz Technical Helpline 0800 10 40 60

Emergency telephone number 0800 243643 (0800 CHEMHELP) (NZ use only)

SAFETY DATA SHEET

Product code 465450-AU22

0800 764 766 National Poison CentreNew Zealand National Poisons Centre

Liquid.

Section 2. Hazards identification

SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 SKIN SENSITISATION - Category 1

HSNO Classification

Signal word Danger

Hazard statements Causes skin irritation.

May cause an allergic skin reaction.

Causes serious eye damage.

Symbol

Precautionary statements

Prevention Wear protective gloves. Wear eye or face protection. Avoid breathing vapour.

Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.

Response Take off contaminated clothing and wash it before reuse. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician.

Storage Not applicable.

Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.

GHS label elements

This material is classified as hazardous according to criteria in the Hazardous Substances (Hazard Classification) Notice 2020.

This material is not classified as DANGEROUS GOODS according to criteria in New Zealand Standard 5433:2012 Transport of Dangerous Goods on Land.

Dermal contact. Eye contact. Inhalation.Routes of entry

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 1/9

ENGLISH

( ENGLISH )

Version

Section 2. Hazards identification Other hazards which do not result in classification

Defatting to the skin.

Section 3. Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Highly refined mineral oil, emulsifiers and additives.

Ingredient name CAS number% (w/w)

Distillates (petroleum), hydrotreated heavy naphthenic ≥30 - ≤60 64742-52-5

Amine neutralised carboxylic acids ≥10 - ≤30 -

Amine neutralised phosphoric acid esters ≤5 -

2-Amino-2-methylpropanol ≤3.4 124-68-5

Amine neutralised carboxylic acids <3 -

2,2',2''-nitrilotriethanol ≤3 102-71-6 boric acid ≤1 10043-35-3

3-Iodo-2-propynyl butylcarbamate ≤0.21 55406-53-6

Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Wash out mouth with water if person is conscious. Get medical attention immediately. Chemical burns must be treated promptly by a physician.

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.

Check for and remove any contact lenses. Get medical attention immediately.

Chemical burns must be treated promptly by a physician.

Get medical attention immediately. In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser.

Wash clothing before reuse. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Clean shoes thoroughly before reuse. In the event of any complaints or symptoms, avoid further exposure. Chemical burns must be treated promptly by a physician.

If inhaled, remove to fresh air. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Get medical attention immediately.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.

In case of inhalation of decomposition products in a fire, symptoms may be delayed.

The exposed person may need to be kept under medical surveillance for 48 hours.

Description of necessary first aid measures

Indication of immediate medical attention and special treatment needed, if necessary

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 2/9

ENGLISH

Section 5. Firefighting measures

No action shall be taken involving any personal risk or without suitable training.

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.

Hazardous combustion products

Specific hazards arising from the chemical

Combustion products may include the following:

phosphorus oxides carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide) nitrogen oxides (NO, NO2 etc.)

In a fire or if heated, a pressure increase will occur and the container may burst.

Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full turnout gear.

Special protective equipment for fire-fighters

In case of fire, use water fog, alcohol resistant foam, dry chemical or carbon dioxide extinguisher or spray.

Extinguishing media

Do not use water jet.

Suitable

Not suitable

Special precautions for fire-fighters

Hazchem code Not available.

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g.

sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Contaminated absorbent material may pose the same hazard as the spilt product. Dispose of via a licensed waste disposal contractor.

Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".

Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill

Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

Methods and material for containment and cleaning up

For non-emergency personnel

For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".

Section 7. Handling and storage Precautions for safe handling

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator.

Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Avoid contact of spilt material and runoff with soil and surface waterways. Avoid prolonged or repeated contact with skin. During metal working, solid particles from workpieces or tools will contaminate the fluid and may cause abrasions of the skin. Where such abrasions result in a penetration of the skin, first aid treatment should be applied as soon as reasonably possible. The presence of certain metals in the workpiece or tool, such as chromium, cobalt and nickel, can contaminate the metalworking fluid and as a

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 3/9

ENGLISH

Section 7. Handling and storage

Conditions for safe storage, including any incompatibilities result may induce allergic skin reactions. Evaporation of water from soluble cutting fluids during use may lead to an increase in concentration which may result in the development of skin conditions due to irritation and defatting. It is important to monitor fluid strength on a regular basis with a refractometer and maintain it at the recommended concentration. Lubricants from other sources and other contaminants should be minimised. Swarf and other debris should be removed. To maintain optimum performance and minimise bacterial spoilage, machine tool coolant systems should be cleaned on a regular basis.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/ containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. DO NOT ADD NITRITES TO THIS FLUID.

Distillates (petroleum), hydrotreated heavy naphthenic NZ HSWA 2015 - GRWM 2016 (New Zealand).

WES-TWA: 5 mg/m³ 8 hours. Issued/ Revised: 6/2016 Form: Mist WES-STEL: 10 mg/m³ 15 minutes. Issued/ Revised: 9/2010 Form: Mist

2,2',2''-nitrilotriethanol NZ HSWA 2015 - GRWM 2016 (New Zealand).

WES-TWA: 5 mg/m³ 8 hours. Issued/ Revised: 1/1994

Boric acid ACGIH TLV (United States).

TWA: 2 mg/m³ 8 hours. Issued/Revised:

1/2005 Form: Inhalable fraction STEL: 6 mg/m³ 15 minutes. Issued/Revised:

1/2005 Form: Inhalable fraction

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards. Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Appropriate engineering controls

All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.

Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.

Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.

The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.

Control parameters

Occupational exposure limits

Biological exposure indices

No exposure indices known.

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 4/9

ENGLISH

Section 8. Exposure controls/personal protection

Hand protection

In case of insufficient ventilation, wear suitable respiratory equipment.

For protection against metal working fluids, respiratory protection that is classified as “resistant to oil” (class R) or oil proof (class P) should be selected where appropriate. Depending on the level of airborne contaminants, an air-purifying, half-mask respirator (with HEPA filter) including disposable (P- or R-series) (for oil mists less than 50mg/m3), or any powered, air-purifying respirator equipped with hood or helmet and HEPA filter (for oil mists less than 125 mg/m3).

Where organic vapours are a potential hazard during metalworking operations, a combination particulate and organic vapour filter may be necessary.

The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application.

Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.

Wear suitable gloves. Undiluted fluid: Wear chemical resistant gloves.

Recommended: nitrile gloves.

Diluted fluid: Wear protective gloves if prolonged or repeated contact is likely.

Recommended: nitrile gloves. The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.

Undiluted fluid: Chemical goggles.

Diluted fluid: Safety glasses with side shields.

Eye protection

Respiratory protection

Skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.

Appropriate techniques should be used to remove potentially contaminated clothing.

Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Section 9. Physical and chemical properties

Physical state Liquid.

Not available.

Not available.Odour pH

Yellow. [Light]Colour

Flash point

9.4 to 9.9 [Conc. (% w/w): 5%]

Appearance

Auto-ignition temperature

Drop Point Not available.

Boiling point, initial boiling point, and boiling range

Not available.

Melting point/freezing point

Closed cup: >100°C (>212°F) [Estimated. Water content interferes with flash point determination.]

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 5/9

ENGLISH

Section 9. Physical and chemical properties

Not available.

Density <1000 kg/m³ (<1 g/cm³) at 15°C

Particle characteristics

Median particle size Not applicable.

Ingredient name °C °F Method

2-Amino-2-methylpropanol 438 820.4 ASTM D 2161

2,2',2''-nitrilotriethanol 324 615.2

Vapour pressure

Ingredient name

Vapour Pressure at 20˚C Vapour pressure at 50˚C mm Hg kPa Method mm Hg kPa Method

Distillates (petroleum), hydrotreated heavy naphthenic

<0.08 <0.011 ASTM D 5191

Water 23.8 3.2

2-Amino- 2-methylpropanol

0.34 0.045 ASTM E 1194

2,2',2''-nitrilotriethanol <0.01 <0.0013

Relative vapour density

Solubility(ies) Not available.

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid Avoid excessive heat.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Under normal conditions of storage and use, hazardous polymerisation will not occur.

Reactive or incompatible with the following materials: oxidising materials.

Slightly reactive or incompatible with the following materials: acids.

Section 11. Toxicological information Information on likely routes of exposure

Inhalation May give off gas, vapour or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.

May cause burns to mouth, throat and stomach.Ingestion

Skin contact Causes skin irritation. Defatting to the skin. May cause an allergic skin reaction.

Causes serious eye damage.Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation No specific data.

Adverse symptoms may include the following:

stomach pains

Adverse symptoms may include the following:

irritation redness dryness cracking

Eye contact Adverse symptoms may include the following:

pain watering redness

Potential chronic health effects

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 6/9

ENGLISH

Section 11. Toxicological information No known significant effects or critical hazards.General

No known significant effects or critical hazards.Carcinogenicity

No known significant effects or critical hazards.Mutagenicity

No known significant effects or critical hazards.Teratogenicity

Developmental effects No known significant effects or critical hazards.

Fertility effects No known significant effects or critical hazards.

Inhalation Not applicable.

Not applicable.Ingestion

Skin contact Not applicable.

Not applicable.Eye contact

Section 12. Ecological information

Mobility Liquid. Soluble in water.

LogPow BCF Potential

Bioaccumulative potential

Product/ingredient name

2-Amino-2-methylpropanol -0.63 - low 2,2',2''-nitrilotriethanol -1 - low Boric acid -1.09 - low

Persistence and degradability

Ecotoxicity No known significant effects or critical hazards.

Mobility in soil

Soil/water partition coefficient (KOC)

Not available.

Not available.

Expected to be biodegradable.

Section 13. Disposal considerations The generation of waste should be avoided or minimised wherever possible.

Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled.

Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Diluted Fluid The spent diluted fluid comprises a relatively stable emulsion. Dispose of via an authorised person/ licensed waste disposal contractor or by other suitable waste treatment techniques (e.g. emulsion splitting, coagulation and filtration) approved by the local authority. Spent fluid should never be disposed of down the drain. The aqueous phase should not be discharged into sewage systems unless provided for by local regulations; the non-aqueous phase should be disposed of as undiluted fluid. Note that separated aqueous solutions or effluents may contain metal salts as well as traces of oil and must be checked for conformity in these respects against consents given by the authorities before disposal. Further treatment may be required.

Disposal methods

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 7/9

ENGLISH

Section 14. Transport information

UN number Proper shipping name

ClassesRegulatory information

PG* Label Additional information

IATA Class

IMDG Class

Not regulated.

Not regulated.

PG* : Packing group

ADG Class

New Zealand Class

Not regulated.

Not regulated.

Section 15. Regulatory information

HSNO Approval Number HSR002606

HSNO Group Standard Lubricants, Lubricant Additives, Coolants and Anti-freeze Agents (Subsidiary Hazard) Group Standard 2020

HSNO Classification SKIN IRRITATION - Category 2 SERIOUS EYE DAMAGE - Category 1 SKIN SENSITISATION - Category 1

For the REACH status of this product please consult your company contact, as identified in Section 1.

Not determined.

All components are listed or exempted.

Not determined.

Not determined.

At least one component is not listed.

Not determined.

At least one component is not listed.

REACH Status

United States inventory (TSCA 8b)

Philippines inventory

(PICCS)

China inventory (IECSC)

Canada inventory status

Australia inventory (AIIC)

Korea inventory (KECI)

Japan inventory (CSCL)

Regulation according to other foreign laws

New Zealand Regulatory Information

Taiwan Chemical Substances Inventory (TCSI)

Not determined.

Section 16. Other information History

Not available.

Date of issue/Date of revision

Version

Prepared by

Notice to reader

Date of previous issue

Indicates information that has changed from previously issued version.

Key to abbreviations Varies = may contain one or more of the following 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7, 64742-63-8, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0, 72623-87-1

16 August 2023

29 July 2022.

3.01

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 8/9

ENGLISH

Section 16. Other information All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited.

Product name

Date of issue3.01

Hysol MB 50

16 August 2023 Format New Zealand

Product code 465450-AU22

Language

Page: 9/9

ENGLISH