Building 98 Demolition Executive Summary.pdf

NASA Glenn Research Center 2016 Building Demolition Soil Sampling Project

Building 98 Demolition Sampling Soil Characterization Executive Summary

Leidos Inc. was requested to conduct an environmental site assessment in support of the 2016 Building Demolition Sampling Project. The assessment, titled Building 98 Demolition Sampling Project, was conducted at the National Aeronautics and Space Administration Glenn Research Center (NASA GRC) and pursuant to NASA form C-709 Work Request #EW-674925. The site assessment was designed to identify if soil contamination occurred during previous activities on the site. The following is a brief summary of the field activities conducted to acquire the soil samples.

The sampling took place on 7/13/16 and consisted of a total of one borehole. The borehole was drilled using a GeoProbe drill rig provided by Leidos Environmental Equipment and Supply of Harrisburg, PA. The borehole was located at the north end of Building 98. See appendix I for a map indicating the location of the boreholes. The NASA GRC Surveyors plotted the borehole location, assigned a number to the borehole and cleared the location for utilities.

A total of one borehole was drilled in support of this project. The borehole was drilled to a depth of eight feet. One composite sample was collected from the entire length of the borehole resulting in one distinct sample. The sample was analyzed for disposal parameters.

See appendix II for a list of disposal parameters. The sample was acquired using a four foot stainless steel auger with an acetate liner. The sample was screened in the field with a Photo Ionization Detector (PID) meter to check for Volatile Organic Compound (VOC) contamination.

A TerraCore sampling system was used to acquire the VOC sample. This system incorporates a small plunger which is pushed into the soil to take approximately a 5 gram sample. The sample is immediately placed in a 40 ml VOA containing a preservative. This process produces a more accurate representation of the VOC content in the soil by limiting VOC loss through evaporation. The sample was containerized and labeled by Leidos and was picked up by a currier from TestAmerica Laboratories Inc., which is located in North Canton, Oh.

Borehole G-06-63-E was sampled on 7/13/16 at 9:05am and is located north of Building 98 in a concrete pad next to the building. It was drilled to the depth of eight feet. See appendix I for a map indicating exact borehole location. The first push resulted in 6 inches of concrete and gravel fill and the remainder consisted of brown sandy clay. The remainder of the sample consisted of wet gray to brown clay. Field screening with the PID indicated that there were no elevated levels of VOC’s in the sample. A composite sample was taken from the entire length of the borehole and containerized in the field.

The sample was transported to Building 215 and stored in a refrigerator pending laboratory pick-up. The sample was labeled with project name, borehole number, date, time and initials of the sampler. A chain of custody was filled out with contact information, borehole identification number and the type of analysis requested. See appendix III for a copy of the chain of custody.

The sample was picked up on 7/13/16 at 11:45am and transported directly to TestAmerica Laboratory Inc. in North Canton, Ohio.

The final analytical report was received from TestAmerica Laboratories Inc. on 7/27/16. See appendix IV for the complete analytical report.

A review of the analytical report raised concerns that 1,4-Dichlorobenzene showed up at low levels in many of the samples. This produced questions about possible contamination of the samples at some point in the sampling/analysis process. The lab was contacted and asked about this issue. The response by TestAmerica Laboratories Inc. is contained in appendix V.

Appendix I Map of Borehole Locations

Complete TCLP – (includes volatile organic compounds, semi-volatile organic compounds, metals, pesticides and herbicides)

Total Volatile Organic Compounds (VOC’s)

Total Semi-Volatile Organic Compounds (SVOC’s)

Total RCRA metals plus nickel

Polychlorinated Biphenyls (PCB’s)

Flashpoint pH

Total cyanide

Total sulfide

F scan (F001-F005)

Paint Filter Liquid Test

Appendix II List of Disposal Parameters

ANALYTICAL REPORT

TestAmerica Laboratories, Inc.

TestAmerica Canton 4101 Shuffel Street NW North Canton, OH 44720 Tel: (330)497-9396

TestAmerica Job ID: 240-67113-1 Client Project/Site: B. 98 Demo

For:

Leidos, Inc.

21000 Brookpark Road Cleveland, Ohio 44135

Attn: Michael Hovanic

Authorized for release by:

7/27/2016 2:35:00 PM

Opal Johnson, Project Manager II (330)497-9396 opal.johnson@testamericainc.com

This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

Table of Contents

Client: Leidos, Inc.

Project/Site: B. 98 Demo

TestAmerica Job ID: 240-67113-1

TestAmerica Canton

7/27/2016

Cover Page

Table of Contents

Definitions/Glossary

Case Narrative

Method Summary

Sample Summary

Detection Summary

Client Sample Results

Surrogate Summary

QC Sample Results

QC Association Summary

Lab Chronicle

Certification Summary

Chain of Custody

Receipt Checklists

Definitions/Glossary TestAmerica Job ID: 240-67113-1Client: Leidos, Inc.

Project/Site: B. 98 Demo

Qualifiers

GC/MS VOA

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

* LCS or LCSD is outside acceptance limits.

GC/MS Semi VOA

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

GC VOA

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

X Surrogate is outside control limits

GC Semi VOA

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

Metals

Qualifier Description

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

Qualifier

U Indicates the analyte was analyzed for but not detected.

B Compound was found in the blank and sample.

General Chemistry

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

TestAmerica Canton

Page 3 of 50 7/27/2016

Case Narrative Client: Leidos, Inc. TestAmerica Job ID: 240-67113-1 Project/Site: B. 98 Demo

Job ID: 240-67113-1

Laboratory: TestAmerica Canton

Narrative

CASE NARRATIVE

Client: Leidos, Inc.

Project: B. 98 Demo

Report Number: 240-67113-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

The 8015C DAI analysis were performed at the TestAmerica Nashville Laboratory.

TestAmerica Canton attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmerica’s operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

All solid sample results are reported on an "as received" basis unless otherwise indicated by the presence of a % solids value in the method header.

This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.

RECEIPT

The samples were received on 7/13/2016 1:35 PM; the samples arrived in good condition, properly preserved and, where required, on ice.

The temperatures of the 4 coolers at receipt time were 9.7º C, 10.0º C, 11.1º C and 15.9º C.

Receipt Exceptions

The following sample was received at the laboratory outside the required temperature criteria: G-06-63-E (240-67113-1). The sample(s) is considered acceptable since it was collected and submitted to the laboratory on the same day and there is evidence that the chilling process has begun.

TCLP VOLATILE ORGANIC COMPOUNDS (GCMS)

Sample G-06-63-E (240-67113-1) was analyzed for TCLP volatile organic compounds (GCMS) in accordance with EPA SW-846 Methods

1311/8260B. The samples were leached on 07/21/2016 and analyzed on 07/24/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TestAmerica Canton Page 4 of 50 7/27/2016

Project/Site: B. 98 Demo

Job ID: 240-67113-1 (Continued)

Laboratory: TestAmerica Canton (Continued)

VOLATILE ORGANIC COMPOUNDS (GCMS)

Sample G-06-63-E (240-67113-1) was analyzed for volatile organic compounds (GCMS) in accordance with EPA SW-846 Method 8260B.

The samples were prepared on 07/14/2016 and analyzed on 07/18/2016.

Bromoform and trans-1,3-Dichloropropene were detected in method blank MB 240-238625/6 at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

The laboratory control sample (LCS) for preparation batch 240-238306 and analytical batch 240-238625 recovered outside control limits for the following analytes: Carbon Tetrachloride and 2,2-Dichloropropane. These analytes were biased high in the LCS and were not detected in the associated samplesG-06-63-E (240-67113-1), (LCS 240-238625/5) and (MB 240-238625/6) ; therefore, the data have been reported.

Insufficient sample volume was available to perform a matrix spike/matrix spike duplicate/sample duplicate (MS/MSD/DUP) associated with preparation batch 240-238306 and analytical batch 240-238625 on these samples G-06-63-E (240-67113-1) .

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TCLP SEMIVOLATILE ORGANIC COMPOUNDS (GCMS)

Sample G-06-63-E (240-67113-1) was analyzed for TCLP semivolatile organic compounds (GCMS) in accordance with EPA SW-846 Methods 1311/8270D. The samples were leached on 07/21/2016, prepared on 07/22/2016 and analyzed on 07/24/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

SEMIVOLATILE ORGANIC COMPOUNDS (GCMS)

Sample G-06-63-E (240-67113-1) was analyzed for semivolatile organic compounds (GCMS) in accordance with EPA SW-846 Method 8270D. The samples were prepared on 07/15/2016 and analyzed on 07/19/2016.

Benzoic acid, Hexachlorocyclopentadiene, Pentachlorophenol and Pyridine failed the recovery criteria low for the MS of sample 240-67115-3 in batch 240-238721. Bis(2-chloroethyl)ether failed the recovery criteria high.

Hexachlorocyclopentadiene failed the recovery criteria low for the MSD of sample 240-67115-3 in batch 240-238721. Benzoic acid, Bis(2-chloroethyl)ether, Pentachlorophenol and Pyridine exceeded the RPD limit.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

DI LEACH - NONHALOGENATED ORGANIC BY DIRECT AQUEOUS INJECTION

Sample G-06-63-E (240-67113-1) was analyzed for DI Leach - Nonhalogenated Organic by Direct Aqueous Injection in accordance with DI

Leach/EPA SW-846 Method 8015C - DAI. The samples were leached on 07/16/2016 and analyzed on 07/18/2016.

The surrogate recovery for the blank and LCS associated with preparation batch 490-355765 and analytical batch 490-355792 were outside the upper control limits. Samples associated with this blank and LCS were in range; therefore, samples are being reported.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

DI LEACH - NONHALOGENATED ORGANIC BY DIRECT AQUEOUS INJECTION

Sample G-06-63-E (240-67113-1) was analyzed for DI Leach - Nonhalogenated Organic by Direct Aqueous Injection in accordance with DI Leach/EPA SW-846 Method 8015C - DAI. The samples were leached on 07/16/2016 and analyzed on 07/17/2016.

n-butyl alcohol (Surr) and n-butyl alcohol (Surr) failed the surrogate recovery criteria high for MB 490-355765/1-A. n-butyl alcohol (Surr) and n-butyl alcohol (Surr) failed the surrogate recovery criteria high for LCS 490-355765/2-A.

The surrogate recovery for the blank and LCS associated with preparation batch 490-355765 and analytical batch 490-355793 were outside the upper control limits. The samples associated with this surrogate are in range; therefore, samples are being reported.

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Project/Site: B. 98 Demo

Job ID: 240-67113-1 (Continued)

Laboratory: TestAmerica Canton (Continued)

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

POLYCHLORINATED BIPHENYLS (PCBS)

Sample G-06-63-E (240-67113-1) was analyzed for polychlorinated biphenyls (PCBs) in accordance with EPA SW-846 Method 8082A. The samples were prepared on 07/15/2016 and analyzed on 07/19/2016.

Surrogates are added during the extraction process prior to dilution. When the sample dilution is 5X or greater, surrogate recoveries are diluted out and no corrective action is required. All of the samples in this data set analyzed for PCBs were subjected to the sulfuric acid cleanup procedure before instrumental analysis, per EPA Method 3665A.

The following sample appears to contain polychlorinated biphenyls (PCBs); however, due to weathering or other environmental processes, the PCBs in the sample do not closely match any of the laboratory's Aroclor standards used for instrument calibration:

G-06-63-E (240-67113-1). The sample has been quantified and reported as a mixture of Aroclors 1254 and 1260. Due to the poor match with the Aroclor standard(s), there is increased qualitative and quantitative uncertainty associated with this result.

The following samples required a tetrabutylammonium sulfite (TBA) clean-up to reduce matrix interferences caused by sulfur: G-06-63-E (240-67113-1), (240-67119-E-1-A), (240-67119-E-1-B MS) and (240-67119-E-1-C MSD).2595797: 2103098, 2586316

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TCLP METALS (ICP)

Sample G-06-63-E (240-67113-1) was analyzed for TCLP metals (ICP) in accordance with EPA SW-846 Methods 1311/6010C. The samples were leached on 07/21/2016, prepared on 07/22/2016 and analyzed on 07/25/2016.

Aluminum was detected in method blank MB 240-239381/2-A and Aluminum, Arsenic, Chromium and Nickel were detected in method blank LB 240-239340/1-B at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TOTAL METALS (ICP)

Sample G-06-63-E (240-67113-1) was analyzed for total metals (ICP) in accordance with EPA SW-846 Method 6010C. The samples were prepared on 07/15/2016 and analyzed on 07/18/2016 and 07/20/2016.

Several analytes failed the recovery criteria low for the MS of sample 240-67161-1 in batch 240-238690.

Several analytes failed the recovery criteria low for the MSD of sample 240-67161-1 in batch 240-238690. Lead exceeded the RPD limit.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TCLP MERCURY

Sample G-06-63-E (240-67113-1) was analyzed for TCLP mercury in accordance with EPA SW-846 Methods 1311/7470A. The samples were leached on 07/21/2016, prepared on 07/22/2016 and analyzed on 07/23/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

MERCURY

Sample G-06-63-E (240-67113-1) was analyzed for mercury in accordance with EPA SW-846 Method 7471B. The samples were prepared on 07/15/2016 and analyzed on 07/18/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

FLASHPOINT

Sample G-06-63-E (240-67113-1) was analyzed for flashpoint in accordance with EPA SW-846 Method 1010. The samples were analyzed

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Project/Site: B. 98 Demo

Job ID: 240-67113-1 (Continued)

Laboratory: TestAmerica Canton (Continued) on 07/19/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TOTAL CYANIDE

Sample G-06-63-E (240-67113-1) was analyzed for total cyanide in accordance with EPA SW-846 Method 9012A. The samples were prepared and analyzed on 07/15/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

SULFIDE

Sample G-06-63-E (240-67113-1) was analyzed for sulfide in accordance with EPA SW-846 Method 9034. The samples were prepared and analyzed on 07/19/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

PH

Sample G-06-63-E (240-67113-1) was analyzed for pH in accordance with EPA SW-846 Method 9045C. The samples were analyzed on 07/14/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

PAINT FILTER

Sample G-06-63-E (240-67113-1) was analyzed for paint filter in accordance with EPA SW-846 Method 9095A. The samples were analyzed on 07/15/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

PERCENT SOLIDS

Sample G-06-63-E (240-67113-1) was analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 07/14/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

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Method Summary

Project/Site: B. 98 Demo

Method Method Description LaboratoryProtocol

SW8468260B Volatile Organic Compounds (GC/MS) TAL CAN

SW8468270D TCLP Semivolatiles TAL CAN

SW8468270D Semivolatile Organic Compounds (GC/MS) TAL CAN

SW8468015C Nonhalogenated Organic using GC/FID (Direct Aqueous Injection) TAL NSH

SW8468015C Glycols- Direct Injection (GC/FID) TAL NSH

SW8468082A Polychlorinated Biphenyls (PCBs) by Gas Chromatography TAL CAN

SW8466010C Metals (ICP) TAL CAN

SW8467470A Mercury (CVAA) TAL CAN

SW8467471B Mercury (CVAA) TAL CAN

SW8461010 Ignitability, Pensky-Martens Closed-Cup Method TAL CAN

SW8469012A Cyanide, Total and/or Amenable TAL CAN

SW8469034 Sulfide, Acid soluble and Insoluble (Titrimetric) TAL CAN

SW8469045C pH TAL CAN

SW8469095A Paint Filter TAL CAN

EPAMoisture Percent Moisture TAL CAN

Protocol References:

EPA = US Environmental Protection Agency

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL CAN = TestAmerica Canton, 4101 Shuffel Street NW, North Canton, OH 44720, TEL (330)497-9396

TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177

TestAmerica Canton

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Sample Summary

Project/Site: B. 98 Demo

Lab Sample ID Client Sample ID ReceivedCollectedMatrix

240-67113-1 G-06-63-E Solid 07/13/16 09:05 07/13/16 13:35

TestAmerica Canton

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Detection Summary

Project/Site: B. 98 Demo

Client Sample ID: G-06-63-E Lab Sample ID: 240-67113-1

☼1,1-Dichloroethane

RL

3.7 ug/Kg

MDL

0.25

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA1J0.28 8260B

☼4-Isopropyltoluene 3.7 ug/Kg0.31 Total/NA10.34 J 8260B

☼Acetone 15 ug/Kg4.3 Total/NA112 J 8260B

☼Carbon disulfide 3.7 ug/Kg0.44 Total/NA10.88 J 8260B

☼Acenaphthene 7.8 ug/Kg0.88 Total/NA152 8270D

☼Acenaphthylene 7.8 ug/Kg0.41 Total/NA122 8270D

☼Anthracene 7.8 ug/Kg0.91 Total/NA190 8270D

☼Benzo[a]anthracene 7.8 ug/Kg0.73 Total/NA1250 8270D

☼Benzo[a]pyrene 7.8 ug/Kg0.74 Total/NA1270 8270D

☼Benzo[b]fluoranthene 7.8 ug/Kg0.69 Total/NA1480 8270D

☼Benzo[g,h,i]perylene 7.8 ug/Kg0.41 Total/NA1100 8270D

☼Benzo[k]fluoranthene 7.8 ug/Kg0.79 Total/NA1200 8270D

☼Bis(2-ethylhexyl) phthalate 81 ug/Kg22 Total/NA1230 8270D

☼Carbazole 58 ug/Kg31 Total/NA166 8270D

☼Chrysene 7.8 ug/Kg1.3 Total/NA1330 8270D

☼Dibenzofuran 58 ug/Kg0.77 Total/NA151 J 8270D

☼Di-n-butyl phthalate 81 ug/Kg17 Total/NA141 J 8270D

☼Fluoranthene 7.8 ug/Kg0.64 Total/NA1670 8270D

☼Fluorene 7.8 ug/Kg0.62 Total/NA164 8270D

☼Indeno[1,2,3-cd]pyrene 7.8 ug/Kg0.41 Total/NA1100 8270D

☼2-Methylnaphthalene 7.8 ug/Kg0.58 Total/NA173 8270D

☼Naphthalene 7.8 ug/Kg0.95 Total/NA131 8270D

☼Phenanthrene 7.8 ug/Kg0.85 Total/NA1490 8270D

☼Pyrene 7.8 ug/Kg0.51 Total/NA1540 8270D

1,4-Dichlorobenzene 0.0040 mg/L0.00034 TCLP10.0010 J 8270D

☼Aroclor-1254 39 ug/Kg16 Total/NA156 8082A

☼Aluminum 18 mg/Kg5.3 Total/NA19300 6010C

☼Arsenic 1.4 mg/Kg0.38 Total/NA111 6010C

☼Barium 18 mg/Kg0.38 Total/NA181 6010C

☼Cadmium 0.46 mg/Kg0.019 Total/NA10.30 J 6010C

☼Chromium 0.92 mg/Kg0.069 Total/NA120 6010C

☼Lead 0.92 mg/Kg0.18 Total/NA114 6010C

☼Nickel 3.7 mg/Kg0.073 Total/NA130 6010C

☼Selenium 1.8 mg/Kg0.31 Total/NA10.54 J 6010C

Aluminum 0.20 mg/L0.0040 TCLP10.0054 J B 6010C

Arsenic 0.050 mg/L0.0033 TCLP10.011 J B 6010C

Barium 0.50 mg/L0.0024 TCLP10.62 6010C

Cadmium 0.050 mg/L0.00029 TCLP10.0015 J 6010C

Chromium 0.050 mg/L0.00055 TCLP10.0021 J B 6010C

Lead 0.050 mg/L0.0019 TCLP10.0039 J 6010C

Nickel 0.040 mg/L0.0016 TCLP10.029 J B 6010C

Selenium 0.050 mg/L0.0051 TCLP10.0057 J 6010C

☼Mercury 0.11 mg/Kg0.015 Total/NA10.075 J 7471B

Flashpoint 1.00 Degrees F1.00 Total/NA1>200 1010

☼Sulfide 18 mg/Kg13 Total/NA149 9034 pH 0.100 SU0.100 Total/NA110.6 9045C

Free Liquid 0.10 NONE0.10 Total/NA1CNF 9095A

TestAmerica Canton

This Detection Summary does not include radiochemical test results.

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Client Sample Results

Project/Site: B. 98 Demo

Lab Sample ID: 240-67113-1Client Sample ID: G-06-63-E Matrix: SolidDate Collected: 07/13/16 09:05

Percent Solids: 85.3Date Received: 07/13/16 13:35

Method: 8260B - Volatile Organic Compounds (GC/MS)

RL MDL

1,1,1,2-Tetrachloroethane 3.7 U 3.7 0.37 ug/Kg ☼ 07/14/16 11:05 07/18/16 19:13 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

3.7 0.49 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,1,1-Trichloroethane 3.7 U

3.7 0.23 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,1,2,2-Tetrachloroethane 3.7 U

3.7 0.31 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,1,2-Trichloro-1,2,2-trichfluoroethane 3.7 U

3.7 0.28 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,1,2-Trichloroethane 3.7 U

3.7 0.25 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,1-Dichloroethane 0.28 J

3.7 0.60 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,1-Dichloroethene 3.7 U

3.7 0.28 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,1-Dichloropropene 3.7 U

3.7 0.37 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,2,3-Trichlorobenzene 3.7 U

3.7 0.58 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,2,3-Trichloropropane 3.7 U

3.7 0.43 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,2,4-Trimethylbenzene 3.7 U

7.5 2.0 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,2-D bromo-3-Chloropropane 7.5 U

3.7 0.25 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,2-Dichlorobenzene 3.7 U

3.7 0.34 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,2-Dichloroethane 3.7 U

3.7 0.10 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼1,2-Dichloropropane 3.7 U

7.5 2.9 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼2-Nitropropane 7.5 U

3.7 0.33 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼2,2-Dichloropropane 3.7 U *

3.7 0.22 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼2-Chlorotoluene 3.7 U

15 0.51 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼2-Hexanone 15 U

3.7 0.25 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Bromobenzene 3.7 U

3.7 0.25 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Chlorobromomethane 3.7 U

3.7 0.19 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼4-Chlorotoluene 3.7 U

3.7 0.31 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼4-Isopropyltoluene 0.34 J

15 4.3 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Acetone 12 J

3.7 0.67 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Benzene 3.7 U

3.7 0.18 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Bromoform 3.7 U

3.7 0.31 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Bromomethane 3.7 U

3.7 0.44 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Carbon disulfide 0.88 J

3.7 0.49 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Carbon tetrachloride 3.7 U *

3.7 0.40 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Chlorobenzene 3.7 U

3.7 0.33 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Chloroethane 3.7 U

3.7 0.27 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Chloroform 3.7 U

3.7 0.59 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Chloromethane 3.7 U

3.7 0.21 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼cis-1,2-Dichloroethene 3.7 U

15 2.3 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Ethyl acetate 15 U

3.7 0.53 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼cis-1,3-Dichloropropene 3.7 U

75 12 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Cyclohexanone 75 U

3.7 0.31 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Dibromomethane 3.7 U

3.7 0.22 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Dichlorobromomethane 3.7 U

3.7 0.21 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Dichlorodifluoromethane 3.7 U

3.7 0.43 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Ethyl ether 3.7 U

3.7 0.24 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Ethylbenzene 3.7 U

3.7 0.40 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Ethylene Dibromide 3.7 U

150 6.9 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Isobutyl alcohol 150 U

7.5 0.31 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼m-Xylene & p-Xylene 7.5 U

3.7 0.44 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼n-Butylbenzene 3.7 U

3.7 0.15 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Isopropy benzene 3.7 U

3.7 0.45 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼N-Propylbenzene 3.7 U

15 0.84 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼2-Butanone (MEK) 15 U

TestAmerica Canton

Page 11 of 50 7/27/2016

Project/Site: B. 98 Demo

Lab Sample ID: 240-67113-1Client Sample ID: G-06-63-E Matrix: SolidDate Collected: 07/13/16 09:05

Percent Solids: 85.3Date Received: 07/13/16 13:35

Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)

RL MDL

4-Methyl-2-pentanone (MIBK) 15 U 15 0.91 ug/Kg ☼ 07/14/16 11:05 07/18/16 19:13 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

3.7 0.68 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼sec-Butylbenzene 3.7 U

3.7 0.32 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Methyl tert-butyl ether 3.7 U

3.7 0.55 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Methylene Chloride 3.7 U

750 16 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼n-Butanol 750 U

3.7 0.43 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼o-Xylene 3.7 U

3.7 0.30 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Styrene 3.7 U

3.7 0.50 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼tert-Butylbenzene 3.7 U

3.7 0.60 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Tetrachloroethene 3.7 U

3.7 0.20 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Toluene 3.7 U

3.7 0.24 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼trans-1,2-Dichloroethene 3.7 U

3.7 0.22 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼trans-1,3-Dichloropropene 3.7 U

3.7 0.28 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Trichloroethene 3.7 U

3.7 0.22 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Trichlorofluoromethane 3.7 U

3.7 0.22 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Vinyl chloride 3.7 U

7.5 0.40 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Xylenes, Total 7.5 U

3.7 0.28 ug/Kg 07/14/16 11:05 07/18/16 19:13 1☼Chlorodibromomethane 3.7 U

1,2-Dichloroethane-d4 (Surr) 100 58 - 123 07/14/16 11:05 07/18/16 19:13 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

4-Bromofluorobenzene (Surr) 100 07/14/16 11:05 07/18/16 19:13 152 - 136

Toluene-d8 (Surr) 103 07/14/16 11:05 07/18/16 19:13 167 - 125

Dibromofluoromethane (Surr) 89 07/14/16 11:05 07/18/16 19:13 137 - 132

Method: 8260B - Volatile Organic Compounds (GC/MS) - TCLP

RL MDL

1,1-Dichloroethene 0.025 U 0.025 0.0095 mg/L 07/24/16 16:57 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.025 0.011 mg/L 07/24/16 16:57 11,2-Dichloroethane 0.025 U

0.25 0.029 mg/L 07/24/16 16:57 12-Butanone (MEK) 0.25 U

0.025 0.0065 mg/L 07/24/16 16:57 1Benzene 0.025 U

0.025 0.0065 mg/L 07/24/16 16:57 1Carbon tetrachloride 0.025 U

0.025 0.0075 mg/L 07/24/16 16:57 1Chlorobenzene 0.025 U

0.025 0.0080 mg/L 07/24/16 16:57 1Chloroform 0.025 U

0.025 0.015 mg/L 07/24/16 16:57 1Tetrachloroethene 0.025 U

0.025 0.0085 mg/L 07/24/16 16:57 1Trichloroethene 0.025 U

0.025 0.011 mg/L 07/24/16 16:57 1Vinyl chloride 0.025 U

1,2-Dichloroethane-d4 (Surr) 94 80 - 121 07/24/16 16:57 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

4-Bromofluorobenzene (Surr) 85 07/24/16 16:57 170 - 124

Toluene-d8 (Surr) 94 07/24/16 16:57 180 - 120

Dibromofluoromethane (Surr) 94 07/24/16 16:57 180 - 128

Method: 8270D - Semivolatile Organic Compounds (GC/MS)

RL MDL

Acenaphthene 52 7.8 0.88 ug/Kg ☼ 07/15/16 09:42 07/19/16 17:32 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

7.8 0.41 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Acenaphthylene 22

7.8 0.91 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Anthracene 90

7.8 0.73 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Benzo[a]anthracene 250

7.8 0.74 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Benzo[a]pyrene 270

TestAmerica Canton

Page 12 of 50 7/27/2016

Project/Site: B. 98 Demo

Lab Sample ID: 240-67113-1Client Sample ID: G-06-63-E Matrix: SolidDate Collected: 07/13/16 09:05

Percent Solids: 85.3Date Received: 07/13/16 13:35

Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued)

RL MDL

Benzo[b]fluoranthene 480 7.8 0.69 ug/Kg ☼ 07/15/16 09:42 07/19/16 17:32 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

7.8 0.41 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Benzo[g,h,i]perylene 100

770 42 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Benzoic acid 770 U

7.8 0.79 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Benzo[k]fluoranthene 200

380 24 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Benzyl alcohol 380 U

120 26 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Bis(2-chloroethoxy)methane 120 U

120 2.3 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Bis(2-chloroethyl)ether 120 U

120 11 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼bis (2-chloroisopropyl) ether 120 U

81 22 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Bis(2-ethylhexyl) phthalate 230

58 15 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼4-Bromophenyl phenyl ether 58 U

81 12 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Butyl benzyl phthalate 81 U

58 31 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Carbazole 66

170 20 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼4-Chloroaniline 170 U

170 24 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼4-Chloro-3-methylphenol 170 U

58 0.52 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2-Chloronaphthalene 58 U

58 9.5 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2-Chlorophenol 58 U

58 15 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼4-Chlorophenyl phenyl ether 58 U

7.8 1.3 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Chrysene 330

7.8 0.77 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Dibenz(a,h)anthracene 7.8 U

58 0.77 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Dibenzofuran 51 J

58 13 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼1,3-Dichlorobenzene 58 U

58 23 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼1,4-Dichlorobenzene 58 U

120 21 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼3,3'-Dichlorobenzidine 120 U

170 23 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2,4-Dichlorophenol 170 U

81 19 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Diethyl phthalate 81 U

170 23 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2,4-Dimethylphenol 170 U

81 20 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Dimethyl phthalate 81 U

81 17 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Di-n-butyl phthalate 41 J

170 11 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼4,6-Dinitro-2-methylphenol 170 U

380 24 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2,4-Dinitrophenol 380 U

230 20 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2,4-Dinitrotoluene 230 U

230 24 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2,6-Dinitrotoluene 230 U

81 9.2 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Di-n-octyl phthalate 81 U

7.8 0.64 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Fluoranthene 670

7.8 0.62 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Fluorene 64

7.8 2.4 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Hexachlorobenzene 7.8 U

58 6.5 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Hexachlorobutadiene 58 U

380 9.4 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Hexachlorocyclopentadiene 380 U

58 10 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Hexachloroethane 58 U

7.8 0.41 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Indeno[1,2,3-cd]pyrene 100

58 15 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Isophorone 58 U

7.8 0.58 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2-Methylnaphthalene 73

230 13 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2-Methylphenol 230 U

470 23 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼3 & 4 Methylphenol 470 U

7.8 0.95 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Naphthalene 31

230 11 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2-Nitroaniline 230 U

230 19 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼3-Nitroaniline 230 U

230 30 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼4-Nitroaniline 230 U

120 2.6 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Nitrobenzene 120 U

TestAmerica Canton

Page 13 of 50 7/27/2016

Project/Site: B. 98 Demo

Lab Sample ID: 240-67113-1Client Sample ID: G-06-63-E Matrix: SolidDate Collected: 07/13/16 09:05

Percent Solids: 85.3Date Received: 07/13/16 13:35

Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued)

RL MDL

2-Nitrophenol 58 U 58 9.7 ug/Kg ☼ 07/15/16 09:42 07/19/16 17:32 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

380 20 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼4-Nitrophenol 380 U

58 7.3 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼N-Nitrosodi-n-propylamine 58 U

58 24 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼N-Nitrosodiphenylamine 58 U

170 11 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Pentachlorophenol 170 U

7.8 0.85 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Phenanthrene 490

58 8.5 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Phenol 58 U

7.8 0.51 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Pyrene 540

120 4.1 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼Pyridine 120 U

58 4.1 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼1,2,4-Trichlorobenzene 58 U

170 29 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2,4,5-Trichlorophenol 170 U

170 10 ug/Kg 07/15/16 09:42 07/19/16 17:32 1☼2,4,6-Trichlorophenol 170 U

2-Fluorobiphenyl (Surr) 70 39 - 120 07/15/16 09:42 07/19/16 17:32 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

2-Fluorophenol (Surr) 68 07/15/16 09:42 07/19/16 17:32 133 - 120

Nitrobenzene-d5 (Surr) 64 07/15/16 09:42 07/19/16 17:32 132 - 120

Phenol-d5 (Surr) 70 07/15/16 09:42 07/19/16 17:32 132 - 120

Terphenyl-d14 (Surr) 78 07/15/16 09:42 07/19/16 17:32 147 - 120

2,4,6-Tribromophenol (Surr) 32 07/15/16 09:42 07/19/16 17:32 110 - 120

Method: 8270D - TCLP Semivolatiles - TCLP

RL MDL

1,4-Dichlorobenzene 0.0010 J 0.0040 0.00034 mg/L 07/22/16 12:01 07/24/16 13:12 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.0040 0.00030 mg/L 07/22/16 12:01 07/24/16 13:12 12,4,5-Trichlorophenol 0.0040 U

0.0040 0.00024 mg/L 07/22/16 12:01 07/24/16 13:12 12,4,6-Trichlorophenol 0.0040 U

0.0040 0.00025 mg/L 07/22/16 12:01 07/24/16 13:12 12,4-Dinitrotoluene 0.0040 U

0.00080 0.000085 mg/L 07/22/16 12:01 07/24/16 13:12 1Hexachlorobenzene 0.00080 U

0.0040 0.00027 mg/L 07/22/16 12:01 07/24/16 13:12 1Hexachlorobutadiene 0.0040 U

0.0040 0.00019 mg/L 07/22/16 12:01 07/24/16 13:12 1Hexachloroethane 0.0040 U

0.0040 0.00017 mg/L 07/22/16 12:01 07/24/16 13:12 12-Methylphenol 0.0040 U

0.0040 0.00080 mg/L 07/22/16 12:01 07/24/16 13:12 13 & 4 Methylphenol 0.0040 U

0.0040 0.000040 mg/L 07/22/16 12:01 07/24/16 13:12 1Nitrobenzene 0.0040 U

0.016 0.00027 mg/L 07/22/16 12:01 07/24/16 13:12 1Pentachlorophenol 0.016 U

0.0040 0.00035 mg/L 07/22/16 12:01 07/24/16 13:12 1Pyridine 0.0040 U

Terphenyl-d14 (Surr) 80 17 - 120 07/22/16 12:01 07/24/16 13:12 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Phenol-d5 (Surr) 54 07/22/16 12:01 07/24/16 13:12 110 - 120

Nitrobenzene-d5 (Surr) 60 07/22/16 12:01 07/24/16 13:12 136 - 120

2-Fluorophenol (Surr) 55 07/22/16 12:01 07/24/16 13:12 110 - 120

2-Fluorobiphenyl (Surr) 59 07/22/16 12:01 07/24/16 13:12 142 - 120

2,4,6-Tribromophenol (Surr) 72 07/22/16 12:01 07/24/16 13:12 135 - 125

Method: 8015C - Glycols- Direct Injection (GC/FID) - Soluble

RL MDL

2-Ethoxyethanol 12 U 12 1.2 mg/Kg ☼ 07/17/16 22:08 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier n-butyl alcohol (Surr) 123 60 - 140 07/17/16 22:08 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

TestAmerica Canton

Page 14 of 50 7/27/2016

Project/Site: B. 98 Demo

Lab Sample ID: 240-67113-1Client Sample ID: G-06-63-E Matrix: SolidDate Collected: 07/13/16 09:05

Percent Solids: 85.3Date Received: 07/13/16 13:35

Method: 8015C - Nonhalogenated Organic using GC/FID (Direct Aqueous Injection) - Soluble

RL MDL

Methanol 12 U 12 4.7 mg/Kg ☼ 07/18/16 20:34 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Isopropyl acetate (Surr) 50 40 - 120 07/18/16 20:34 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Method: 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography

RL MDL

Aroclor-1016 39 U 39 14 ug/Kg ☼ 07/15/16 09:17 07/19/16 18:38 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

39 19 ug/Kg 07/15/16 09:17 07/19/16 18:38 1☼Aroclor-1221 39 U

39 23 ug/Kg 07/15/16 09:17 07/19/16 18:38 1☼Aroclor-1232 39 U

39 13 ug/Kg 07/15/16 09:17 07/19/16 18:38 1☼Aroclor-1242 39 U

39 9.4 ug/Kg 07/15/16 09:17 07/19/16 18:38 1☼Aroclor-1248 39 U

39 16 ug/Kg 07/15/16 09:17 07/19/16 18:38 1☼Aroclor-1254 56

39 11 ug/Kg 07/15/16 09:17 07/19/16 18:38 1☼Aroclor-1260 39 U

Tetrachloro-m-xylene 50 14 - 128 07/15/16 09:17 07/19/16 18:38 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

DCB Decachlorobiphenyl 64 07/15/16 09:17 07/19/16 18:38 110 - 132

Method: 6010C - Metals (ICP)

RL MDL

Aluminum 9300 18 5.3 mg/Kg ☼ 07/15/16 10:55 07/18/16 16:19 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

1.4 0.38 mg/Kg 07/15/16 10:55 07/18/16 16:19 1☼Arsenic 11

18 0.38 mg/Kg 07/15/16 10:55 07/18/16 16:19 1☼Barium 81

0.46 0.019 mg/Kg 07/15/16 10:55 07/18/16 16:19 1☼Cadmium 0.30 J

0.92 0.069 mg/Kg 07/15/16 10:55 07/18/16 16:19 1☼Chromium 20

0.92 0.18 mg/Kg 07/15/16 10:55 07/18/16 16:19 1☼Lead 14

3.7 0.073 mg/Kg 07/15/16 10:55 07/20/16 13:32 1☼Nickel 30

1.8 0.31 mg/Kg 07/15/16 10:55 07/18/16 16:19 1☼Selenium 0.54 J

0.92 0.058 mg/Kg 07/15/16 10:55 07/18/16 16:19 1☼Silver 0.92 U

Method: 6010C - Metals (ICP) - TCLP

RL MDL

Aluminum 0.0054 J B 0.20 0.0040 mg/L 07/22/16 11:27 07/25/16 11:23 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.050 0.0033 mg/L 07/22/16 11:27 07/25/16 11:23 1Arsenic 0.011 J B

0.50 0.0024 mg/L 07/22/16 11:27 07/25/16 11:23 1Barium 0.62

0.050 0.00029 mg/L 07/22/16 11:27 07/25/16 11:23 1Cadmium 0.0015 J

0.050 0.00055 mg/L 07/22/16 11:27 07/25/16 11:23 1Chromium 0.0021 J B

0.050 0.0019 mg/L 07/22/16 11:27 07/25/16 11:23 1Lead 0.0039 J

0.040 0.0016 mg/L 07/22/16 11:27 07/25/16 11:23 1Nickel 0.029 J B

0.050 0.0051 mg/L 07/22/16 11:27 07/25/16 11:23 1Selenium 0.0057 J

0.050 0.00092 mg/L 07/22/16 11:27 07/25/16 11:23 1Silver 0.050 U

Method: 7470A - Mercury (CVAA) - TCLP

RL MDL

Mercury 0.0020 U 0.0020 0.000090 mg/L 07/22/16 14:00 07/23/16 13:02 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Method: 7471B - Mercury (CVAA)

RL MDL

Mercury 0.075 J 0.11 0.015 mg/Kg ☼ 07/15/16 13:00 07/18/16 10:52 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

TestAmerica Canton

Page 15 of 50 7/27/2016

Project/Site: B. 98 Demo

Lab Sample ID: 240-67113-1Client Sample ID: G-06-63-E Matrix: SolidDate Collected: 07/13/16 09:05

Percent Solids: 85.3Date Received: 07/13/16 13:35

General Chemistry

RL MDL

Flashpoint >200 1.00 1.00 Degrees F 07/19/16 13:59 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.53 0.32 mg/Kg 07/15/16 12:21 07/15/16 15:49 1☼Cyanide, Total 0.53 U

18 13 mg/Kg 07/19/16 09:30 07/19/16 15:10 1☼Sulfide 49

0.100 0.100 SU 07/14/16 15:19 1pH 10.6

0.10 0.10 NONE 07/15/16 05:42 1Free Liquid CNF

0.1 0.1 % 07/14/16 11:32 1Percent Solids 85.3

0.1 0.1 % 07/14/16 11:32 1Percent Moisture 14.7

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Surrogate Summary

Project/Site: B. 98 Demo

Method: 8260B - Volatile Organic Compounds (GC/MS) Prep Type: Total/NAMatrix: Solid

Lab Sample ID Client Sample ID (58-123) (52-136) (67-125) (37-132)

12DCE BFB TOL DBFM

100 100 103 89240-67113-1

Percent Surrogate Recovery (Acceptance Limits)

G-06-63-E

115 97 108 109LCS 240-238625/5 Lab Control Sample

108 90 103 97MB 240-238625/6 Method Blank

Surrogate Legend

12DCE = 1,2-Dichloroethane-d4 (Surr)

BFB = 4-Bromofluorobenzene (Surr)

TOL = Toluene-d8 (Surr)

DBFM = Dibromofluoromethane (Surr)

Method: 8260B - Volatile Organic Compounds (GC/MS) Prep Type: Total/NAMatrix: Solid

Lab Sample ID Client Sample ID (80-121) (70-124) (80-120) (80-128)

12DCE BFB TOL DBFM

88 88 95 95LCS 240-239538/9

Percent Surrogate Recovery (Acceptance Limits)

Lab Control Sample

Surrogate Legend

12DCE = 1,2-Dichloroethane-d4 (Surr)

BFB = 4-Bromofluorobenzene (Surr)

TOL = Toluene-d8 (Surr)

DBFM = Dibromofluoromethane (Surr)

Method: 8260B - Volatile Organic Compounds (GC/MS) Prep Type: TCLPMatrix: Solid

Lab Sample ID Client Sample ID (80-121) (70-124) (80-120) (80-128)

12DCE BFB TOL DBFM

94 85 94 94240-67113-1

Percent Surrogate Recovery (Acceptance Limits)

G-06-63-E

92 89 93 98LB 240-239434/1-A MB Method Blank

Surrogate Legend

12DCE = 1,2-Dichloroethane-d4 (Surr)

BFB = 4-Bromofluorobenzene (Surr)

TOL = Toluene-d8 (Surr)

DBFM = Dibromofluoromethane (Surr)

Method: 8270D - Semivolatile Organic Compounds (GC/MS) Prep Type: Total/NAMatrix: Solid

Lab Sample ID Client Sample ID (39-120) (33-120) (32-120) (32-120) (47-120) (10-120)

FBP 2FP NBZ PHL TPH TBP

70 68 64 70 78 32240-67113-1

Percent Surrogate Recovery (Acceptance Limits)

G-06-63-E

73 73 71 8675 64LCS 240-238377/20-A Lab Control Sample

64 60 58 7964 16MB 240-238377/19-A Method Blank

Surrogate Legend

FBP = 2-Fluorobiphenyl (Surr)

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Project/Site: B. 98 Demo

2FP = 2-Fluorophenol (Surr)

NBZ = Nitrobenzene-d5 (Surr)

PHL = Phenol-d5 (Surr)

TPH = Terphenyl-d14 (Surr)

TBP = 2,4,6-Tribromophenol (Surr)

Method: 8270D - TCLP Semivolatiles Prep Type: Total/NAMatrix: Solid

Lab Sample ID Client Sample ID (42-120) (10-120) (36-120) (10-120) (17-120) (35-125)

FBP 2FP NBZ PHL TPH TBP

71 72 77 67 82 84LCS 240-239397/18-A

Percent Surrogate Recovery (Acceptance Limits)

Lab Control Sample

72 57 68 8251 70MB 240-239397/17-A Method Blank

Surrogate Legend

FBP = 2-Fluorobiphenyl (Surr)

2FP = 2-Fluorophenol (Surr)

NBZ = Nitrobenzene-d5 (Surr)

PHL = Phenol-d5 (Surr)

TPH = Terphenyl-d14 (Surr)

TBP = 2,4,6-Tribromophenol (Surr)

Method: 8270D - TCLP Semivolatiles Prep Type: TCLPMatrix: Solid

Lab Sample ID Client Sample ID (17-120) (10-120) (36-120) (10-120) (42-120) (35-125)

TPH PHL NBZ 2FP FBP TBP

80 54 60 55 59 72240-67113-1

Percent Surrogate Recovery (Acceptance Limits)

G-06-63-E

84 52 71 7163 86240-67113-1 MS G-06-63-E

Surrogate Legend

TPH = Terphenyl-d14 (Surr)

PHL = Phenol-d5 (Surr)

NBZ = Nitrobenzene-d5 (Surr)

2FP = 2-Fluorophenol (Surr)

FBP = 2-Fluorobiphenyl (Surr)

TBP = 2,4,6-Tribromophenol (Surr)

Method: 8015C - Glycols- Direct Injection (GC/FID) Prep Type: SolubleMatrix: Solid

Lab Sample ID Client Sample ID (60-140) (60-140) nBA1 nBA1

123 123240-67113-1

Percent Surrogate Recovery (Acceptance Limits)

G-06-63-E

118 118240-67113-1 MS G-06-63-E

115 115240-67113-1 MSD G-06-63-E

158 X 158 XLCS 490-355765/2-A Lab Control Sample

155 X 155 XMB 490-355765/1-A Method Blank

Surrogate Legend nBA = n-butyl alcohol (Surr)

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Project/Site: B. 98 Demo

Method: 8015C - Nonhalogenated Organic using GC/FID (Direct Aqueous Injection) Prep Type: SolubleMatrix: Solid

Lab Sample ID Client Sample ID (40-120) yl acetate

50240-67113-1

Percent Surrogate Recovery (Acceptance Limits)

G-06-63-E

63240-67113-G-1-E MS 240-67113-G-1-E MS

58240-67113-G-1-F MSD 240-67113-G-1-F MSD

107LCS 490-355767/2-A Lab Control Sample

115MB 490-355767/1-A Method Blank

Surrogate Legend

Isopropyl acetate (Surr) = Isopropyl acetate (Surr)

Method: 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography Prep Type: Total/NAMatrix: Solid

Lab Sample ID Client Sample ID (14-128) (10-132)

TCX1 DCB1

50 64240-67113-1

Percent Surrogate Recovery (Acceptance Limits)

G-06-63-E

58 63LCS 240-238374/20-A Lab Control Sample

67 68MB 240-238374/19-A Method Blank

Surrogate Legend

TCX = Tetrachloro-m-xylene

DCB = DCB Decachlorobiphenyl

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QC Sample Results

Project/Site: B. 98 Demo

Method: 8260B - Volatile Organic Compounds (GC/MS)

Client Sample ID: Method BlankLab Sample ID: MB 240-238625/6 Matrix: Solid Prep Type: Total/NA Analysis Batch: 238625

RL MDL

1,1,1,2-Tetrachloroethane 5.0 U 5.0 0.50 ug/Kg 07/18/16 12:47 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

5.0 U 0.655.0 ug/Kg 07/18/16 12:47 11,1,1-Trichloroethane

5.0 U 0.315.0 ug/Kg 07/18/16 12:47 11,1,2,2-Tetrachloroethane

5.0 U 0.425.0 ug/Kg 07/18/16 12:47 11,1,2-Trichloro-1,2,2-trichfluoroethane

5.0 U 0.375.0 ug/Kg 07/18/16 12:47 11,1,2-Trichloroethane

5.0 U 0.345.0 ug/Kg 07/18/16 12:47 11,1-Dichloroethane

5.0 U 0.805.0 ug/Kg 07/18/16 12:47 11,1-Dichloroethene

5.0 U 0.375.0 ug/Kg 07/18/16 12:47 11,1-Dichloropropene

5.0 U 0.505.0 ug/Kg 07/18/16 12:47 11,2,3-Trichlorobenzene

5.0 U 0.785.0 ug/Kg 07/18/16 12:47 11,2,3-Trichloropropane

5.0 U 0.585.0 ug/Kg 07/18/16 12:47 11,2,4-Trimethylbenzene

10 U 2.710 ug/Kg 07/18/16 12:47 11,2-D bromo-3-Chloropropane

5.0 U 0.345.0 ug/Kg 07/18/16 12:47 11,2-Dichlorobenzene

5.0 U 0.465.0 ug/Kg 07/18/16 12:47 11,2-Dichloroethane

5.0 U 0.145.0 ug/Kg 07/18/16 12:47 11,2-Dichloropropane

10 U 3.910 ug/Kg 07/18/16 12:47 12-Nitropropane

5.0 U 0.445.0 ug/Kg 07/18/16 12:47 12,2-Dichloropropane

5.0 U 0.305.0 ug/Kg 07/18/16 12:47 12-Chlorotoluene

20 U 0.6820 ug/Kg 07/18/16 12:47 12-Hexanone

5.0 U 0.335.0 ug/Kg 07/18/16 12:47 1Bromobenzene

5.0 U 0.335.0 ug/Kg 07/18/16 12:47 1Chlorobromomethane

5.0 U 0.265.0 ug/Kg 07/18/16 12:47 14-Chlorotoluene

5.0 U 0.415.0 ug/Kg 07/18/16 12:47 14-Isopropyltoluene

20 U 5.720 ug/Kg 07/18/16 12:47 1Acetone

5.0 U 0.905.0 ug/Kg 07/18/16 12:47 1Benzene

1.37 J 0.245.0 ug/Kg 07/18/16 12:47 1Bromoform

5.0 U 0.425.0 ug/Kg 07/18/16 12:47 1Bromomethane

5.0 U 0.595.0 ug/Kg 07/18/16 12:47 1Carbon disulfide

5.0 U 0.655.0 ug/Kg 07/18/16 12:47 1Carbon tetrachloride

5.0 U 0.535.0 ug/Kg 07/18/16 12:47 1Chlorobenzene

5.0 U 0.445.0 ug/Kg 07/18/16 12:47 1Chloroethane

5.0 U 0.365.0 ug/Kg 07/18/16 12:47 1Chloroform

5.0 U 0.795.0 ug/Kg 07/18/16 12:47 1Chloromethane

5.0 U 0.285.0 ug/Kg 07/18/16 12:47 1cis-1,2-Dichloroethene

20 U 3.120 ug/Kg 07/18/16 12:47 1Ethyl acetate

5.0 U 0.715.0 ug/Kg 07/18/16 12:47 1cis-1,3-Dichloropropene

100 U 16100 ug/Kg 07/18/16 12:47 1Cyclohexanone

5.0 U 0.425.0 ug/Kg 07/18/16 12:47 1Dibromomethane

5.0 U 0.295.0 ug/Kg 07/18/16 12:47 1Dichlorobromomethane

5.0 U 0.285.0 ug/Kg 07/18/16 12:47 1Dichlorodifluoromethane

5.0 U 0.585.0 ug/Kg 07/18/16 12:47 1Ethyl ether

5.0 U 0.325.0 ug/Kg 07/18/16 12:47 1Ethylbenzene

5.0 U 0.535.0 ug/Kg 07/18/16 12:47 1Ethylene Dibromide

200 U 9.2200 ug/Kg 07/18/16 12:47 1Isobutyl alcohol

10 U 0.4210 ug/Kg 07/18/16 12:47 1m-Xylene & p-Xylene

5.0 U 0.595.0 ug/Kg 07/18/16 12:47 1n-Butylbenzene

5.0 U 0.205.0 ug/Kg 07/18/16 12:47 1Isopropy benzene

5.0 U 0.605.0 ug/Kg 07/18/16 12:47 1N-Propylbenzene

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Project/Site: B. 98 Demo

Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)

Client Sample ID: Method BlankLab Sample ID: MB 240-238625/6 Matrix: Solid Prep Type: Total/NA Analysis Batch: 238625

RL MDL

2-Butanone (MEK) 20 U 20 1.1 ug/Kg 07/18/16 12:47 1

MB MB

Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier

20 U 1.220 ug/Kg 07/18/16 12:47 14-Methyl-2-pentanone (MIBK)

5.0 U 0.915.0 ug/Kg 07/18/16 12:47 1sec-Butylbenzene

5.0 U 0.435.0 ug/Kg 07/18/16 12:47 1Methyl tert-butyl ether

5.0 U 0.745.0 ug/Kg 07/18/16 12:47 1Methylene Chloride

1000 U 221000 ug/Kg 07/18/16 12:47 1n-Butanol

5.0 U 0.575.0 ug/Kg 07/18/16 12:47 1o-Xylene

5.0 U 0.405.0 ug/Kg 07/18/16 12:47 1Styrene

5.0 U 0.675.0 ug/Kg 07/18/16 12:47 1tert-Butylbenzene

5.0 U 0.805.0 ug/Kg 07/18/16 12:47 1Tetrachloroethene

5.0 U 0.275.0 ug/Kg 07/18/16 12:47 1Toluene

5.0 U 0.325.0 ug/Kg 07/18/16 12:47 1trans-1,2-Dichloroethene

0.645 J 0.295.0 ug/Kg 07/18/16 12:47 1trans-1,3-Dichloropropene

5.0 U 0.385.0 ug/Kg 07/18/16 12:47 1Trichloroethene

5.0 U 0.295.0 ug/Kg 07/18/16 12:47 1Trichlorofluoromethane

5.0 U 0.305.0 ug/Kg 07/18/16 12:47 1Vinyl chloride

10 U 0.5410 ug/Kg 07/18/16 12:47 1Xylenes, Total

5.0 U 0.375.0 ug/Kg 07/18/16 12:47 1Chlorodibromomethane

1,2-Dichloroethane-d4 (Surr) 108 58 - 123 07/18/16 12:47 1

MB MB

Surrogate Dil FacPrepared AnalyzedQualifier Limits%Recovery

90 07/18/16 12:47…