Building 102 Demolition Executive Summary.pdf

NASA Glenn Research Center 2016 Building Demolition Soil Sampling Project

Building 102 Demolition Sampling Soil Characterization Executive Summary

Leidos Inc. was requested to conduct an environmental site assessment in support of the 2016 Building Demolition Soil Sampling Project. The assessment, titled Building 102 Demolition Sampling Project, was conducted at the National Aeronautics and Space Administration Glenn Research Center (NASA GRC) and pursuant to NASA form C-709 Work Request #EW-674925.

The site assessment was designed to identify if soil contamination occurred during previous activities on the site. The following is a brief summary of the field activities conducted to acquire the soil samples.

The sampling took place on 7/13/16 and consisted of a total of four boreholes. The boreholes were drilled using a GeoProbe drill rig provided by Leidos Environmental Equipment and Supply of Harrisburg, PA. The boreholes are located around the perimeter of Building 102. See appendix I for a map indicating the location of the boreholes. The NASA GRC Surveyors plotted the borehole locations, assigned a number to the boreholes and cleared the locations for utilities.

A total of four boreholes were drilled in support of this project. The boreholes were each drilled to the depth of eight feet. One composite sample was collected from the entire length of each borehole resulting in a total of four distinct samples. The samples were analyzed for disposal parameters. See appendix II for a list of disposal parameters. The samples were acquired using a four foot stainless steel auger with an acetate liner. The samples were screened in the field with a Photo Ionization Detector (PID) meter to check for Volatile Organic Compound (VOC) contamination. A TerraCore sampling system was used to acquire the VOC sample. This system incorporates a small plunger which is pushed into the soil to take approximately a 5 gram sample. The sample is immediately placed in a 40 ml VOA containing a preservative. This process produces a more accurate representation of the VOC content in the soil by limiting VOC loss through evaporation. The samples were containerized and labeled by Leidos and were picked up by a currier from TestAmerica Laboratories Inc., which is located in North Canton, Oh.

Borehole G-06-59-E was sampled on 7/13/16 and is located at the northeast corner of Building 102 in an asphalt paved area next to an abandoned oil/water separator. It was drilled to the depth of eight feet. See appendix I for a map indicating exact borehole location. The top eight inches of the sample consisted of asphalt and gravel fill with the remainder consisting of wet, sandy, brown clay. Field screening with the PID indicated that there were no elevated levels of VOC’s in the sample. A composite sample was taken from the entire length of the borehole and containerized in the field.

Borehole G-06-60-E was sampled on 7/13/16 and is located north of Building 102 in the asphalt paved area outside of the Building 102 test bay doors. It was drilled to the depth of eight feet.

See appendix I for a map indicating the exact borehole location. The top eight inches of sample consisted of asphalt and gravel fill with the remainder consisting of hard packed, brown clay.

Field screening with the PID indicated that there were no elevated levels of VOC’s in the sample. A composite sample was taken from the entire length of the borehole and containerized in the field.

Borehole G-06-61-E was sampled on 7/13/16 and is located at the southwest corner of Building 102 in the grassy area next to a cement driveway leading to the building shop area. It was drilled to the depth of eight feet. See appendix I for a map indicating the exact borehole location. The top four inches of the sample consisted of grass and organic matter with the remainder consisting of brown native soil. Field screening with the PID indicated that there were no elevated levels of VOC’s in the sample. A composite sample was taken from the entire length of the borehole and containerized in the field.

Borehole G-06-62-E was sampled on 7/13/16 and is located at the northwest corner of Building 102 in an asphalt paved area outside of a bay door. It was drilled to the depth of eight feet.

See appendix I for a map indicating the exact borehole location. The sample consisted of one foot of brown soil transitioning to hard packed brown clay. Field screening with the PID resulted in elevated readings ranging from 201ppb to 1043ppb at the depth of about five feet.

Due to the elevated readings, an extra TerraCore sample was taken from this area. This sample was labeled G-06-62-E-1 on the chain of custody. A composite sample was taken from the entire length of the remaining sample and containerized in the field.

The samples were transported to Building 215 and stored in a refrigerator pending laboratory pickup. The samples were labeled with project name, borehole number, date, time and initials of the sampler. A chain of custody was filled out with contact information, borehole identification numbers and the type of analysis requested. See appendix III for a copy of the chain of custody. The sample was picked up on 7/13/16 at 11:45am and transported directly to TestAmerica Laboratories Inc. in North Canton, Ohio.

The final analytical report was received from TestAmerica Laboratories Inc. on 7/27/16. See appendix IV for the complete analytical report.

A review of the analytical report raised concerns that 1,4-Dichlorobenzene showed up at low levels in many of the samples. This produced questions about possible contamination of the samples at some point in the sampling/analysis process. The lab was contacted and asked about this issue. The response by TestAmerica Laboratories Inc. is contained in appendix V.

Appendix I Map of Borehole Locations

Complete TCLP – (includes volatile organic compounds, semi-volatile organic compounds, metals, pesticides and herbicides)

Total Volatile Organic Compounds (VOC’s)

Total Semi-Volatile Organic Compounds (SVOC’s)

Total RCRA metals plus nickel

Polychlorinated Biphenyls (PCB’s)

Flashpoint pH

Total cyanide

Total sulfide

F scan (F001-F005)

Paint Filter Liquid Test

Appendix II List of Disposal Parameters

Appendix III Chain of Custody

ANALYTICAL REPORT

TestAmerica Laboratories, Inc.

TestAmerica Canton 4101 Shuffel Street NW North Canton, OH 44720 Tel: (330)497-9396

TestAmerica Job ID: 240-67116-1 Client Project/Site: B102 Demo WO#110

For:

Leidos, Inc.

21000 Brookpark Road Cleveland, Ohio 44135

Attn: Michael Hovanic

Authorized for release by:

7/27/2016 3:42:02 PM

Opal Johnson, Project Manager II (330)497-9396 opal.johnson@testamericainc.com

This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature.

Results relate only to the items tested and the sample(s) as received by the laboratory.

Table of Contents

Client: Leidos, Inc.

Project/Site: B102 Demo WO#110

TestAmerica Job ID: 240-67116-1

TestAmerica Canton

7/27/2016

Cover Page

Table of Contents

Definitions/Glossary

Case Narrative

Method Summary

Sample Summary

Detection Summary

Client Sample Results

Surrogate Summary

QC Sample Results

QC Association Summary

Lab Chronicle

Certification Summary

Chain of Custody

Receipt Checklists

Definitions/Glossary TestAmerica Job ID: 240-67116-1Client: Leidos, Inc.

Project/Site: B102 Demo WO#110

Qualifiers

GC/MS VOA

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

* LCS or LCSD is outside acceptance limits.

GC/MS Semi VOA

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

GC VOA

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

X Surrogate is outside control limits

GC Semi VOA

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

Metals

Qualifier Description

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

Qualifier

U Indicates the analyte was analyzed for but not detected.

B Compound was found in the blank and sample.

General Chemistry

Qualifier Description

U Indicates the analyte was analyzed for but not detected.

Qualifier

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.

Glossary

These commonly used abbreviations may or may not be present in this report.

¤ Listed under the "D" column to designate that the result is reported on a dry weight basis

Abbreviation

%R Percent Recovery

CFL Contains Free Liquid

CNF Contains no Free Liquid

DER Duplicate error ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample

DLC Decision level concentration

MDA Minimum detectable activity

EDL Estimated Detection Limit

MDC Minimum detectable concentration

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative error ratio

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference, a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TestAmerica Canton

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Definitions/Glossary

Project/Site: B102 Demo WO#110

Glossary (Continued)

These commonly used abbreviations may or may not be present in this report.

TEQ Toxicity Equivalent Quotient (Dioxin)

Abbreviation

TestAmerica Canton

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Case Narrative Client: Leidos, Inc. TestAmerica Job ID: 240-67116-1 Project/Site: B102 Demo WO#110

Job ID: 240-67116-1

Laboratory: TestAmerica Canton

Narrative

CASE NARRATIVE

Client: Leidos, Inc.

Project: B102 Demo WO#110

Report Number: 240-67116-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

The 8015C - DAI DI Leach - Nonhalogenated Organic by Direct Aqueous Injection analysis was performed at the TestAmerica Nashville Laboratory.

TestAmerica Canton attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the application methods. TestAmerica’s operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

All solid sample results are reported on an "as received" basis unless otherwise indicated by the presence of a % solids value in the method header.

This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.

RECEIPT

The samples were received on 7/13/2016 1:35 PM; the samples arrived in good condition, properly preserved and, where required, on ice.

The temperatures of the 4 coolers at receipt time were 9.0º C, 9.7º C, 11.1º C and 15.9º C.

Exception:

The following samples were received at the laboratory outside the required temperature criteria: G-06-59-E (240-67116-1), G-06-60-E

(240-67116-2), G-06-61-E (240-67116-3), G-06-62-E (240-67116-4), and G-06-62-E-1 (240-67116-5). The samples are considered acceptable since they were collected and submitted to the laboratory on the same day and there is evidence that the chilling process has begun.

TCLP VOLATILE ORGANIC COMPOUNDS (GCMS)

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for

TCLP volatile organic compounds (GCMS) in accordance with EPA SW-846 Methods 1311/8260B. The samples were leached on 07/21/2016 and 07/24/2016 and analyzed on 07/24/2016 and 07/25/2016.

The method blank for preparation batch 240-239544 contained Tetrachloroethene above the reporting limit (RL). None of the samples associated with this method blank contained the target compound; therefore, re-extraction and/or re-analysis of samples were not

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Project/Site: B102 Demo WO#110

Job ID: 240-67116-1 (Continued)

Laboratory: TestAmerica Canton (Continued) performed. The following samples were impacted: G-06-62-E (240-67116-4) and (LB 240-239544/1-A).

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

VOLATILE ORGANIC COMPOUNDS (GCMS)

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3), G-06-62-E (240-67116-4) and G-06-62-E-1

(240-67116-5) were analyzed for volatile organic compounds (GCMS) in accordance with EPA SW-846 Method 8260B. The samples were prepared on 07/14/2016 and analyzed on 07/18/2016.

Bromoform and trans-1,3-Dichloropropene were detected in method blank MB 240-238625/6 at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

The laboratory control sample (LCS) for preparation batch 240-238306 and analytical batch 240-238625 recovered outside control limits for the following analytes: Carbon Tetrachloride and 2,2-Dichloropropane. These analytes were biased high in the LCS and were not detected in the associated samples: G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3), G-06-62-E (240-67116-4), G-06-62-E-1 (240-67116-5), (LCS 240-238625/5), and (MB 240-238625/6); therefore, the data have been reported.

Insufficient sample volume was available to perform a matrix spike/matrix spike duplicate/sample duplicate (MS/MSD/DUP) associated with preparation batch 240-238306 and analytical batch 240-238625 on these samples: G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3), G-06-62-E (240-67116-4), and G-06-62-E-1 (240-67116-5).

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TCLP SEMIVOLATILE ORGANIC COMPOUNDS (GCMS)

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for TCLP semivolatile organic compounds (GCMS) in accordance with EPA SW-846 Methods 1311/8270D. The samples were leached on

07/21/2016, prepared on 07/22/2016 and analyzed on 07/24/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

SEMIVOLATILE ORGANIC COMPOUNDS (GCMS)

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for semivolatile organic compounds (GCMS) in accordance with EPA SW-846 Method 8270D. The samples were prepared on 07/15/2016 and 07/21/2016 and analyzed on 07/19/2016 and 07/25/2016.

Benzoic acid, Hexachlorocyclopentadiene, Pentachlorophenol and Pyridine failed the recovery criteria low for the MS of sample 240-67115-3 in batch 240-238721.

Hexachlorocyclopentadiene failed the recovery criteria low for the MSD of sample 240-67115-3 in batch 240-238721. Benzoic acid, Bis(2-chloroethyl)ether, Pentachlorophenol and Pyridine exceeded the RPD limit.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

DI LEACH - NONHALOGENATED ORGANIC BY DIRECT AQUEOUS INJECTION

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for

DI Leach - Nonhalogenated Organic by Direct Aqueous Injection in accordance with DI Leach/EPA SW-846 Method 8015C - DAI. The samples were leached on 07/16/2016 and analyzed on 07/18/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

DI LEACH - NONHALOGENATED ORGANIC BY DIRECT AQUEOUS INJECTION

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for

DI Leach - Nonhalogenated Organic by Direct Aqueous Injection in accordance with DI Leach/EPA SW-846 Method 8015C - DAI. The samples were leached on 07/16/2016 and analyzed on 07/18/2016.

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Project/Site: B102 Demo WO#110

Job ID: 240-67116-1 (Continued)

Laboratory: TestAmerica Canton (Continued)

The surrogate recovery for the blank and LCS associated with preparation batch 490-355765 and analytical batch 490-355792 were outside the upper control limits. Samples associated with this blank and LCS were in range; therefore, samples are being reported.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

POLYCHLORINATED BIPHENYLS (PCBS)

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for polychlorinated biphenyls (PCBs) in accordance with EPA SW-846 Method 8082A. The samples were prepared on 07/15/2016 and analyzed on 07/19/2016.

Surrogates are added during the extraction process prior to dilution. When the sample dilution is 5X or greater, surrogate recoveries are diluted out and no corrective action is required. All of the samples in this data set analyzed for PCBs were subjected to the sulfuric acid cleanup procedure before instrumental analysis, per EPA Method 3665A.

The following samples required a tetrabutylammonium sulfite (TBA) clean-up to reduce matrix interferences caused by sulfur: G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3), G-06-62-E (240-67116-4), (240-67119-E-1-A), (240-67119-E-1-B

MS), and (240-67119-E-1-C MSD). Reagents: 2595797, 2103098, and 2586316.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TCLP METALS (ICP)

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for TCLP metals (ICP) in accordance with EPA SW-846 Methods 1311/6010C. The samples were leached on 07/21/2016, prepared on 07/22/2016 and analyzed on 07/25/2016.

Aluminum was detected in method blank MB 240-239381/2-A and Aluminum, Arsenic, Chromium and Nickel were detected in method blank LB 240-239340/1-B at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TOTAL METALS (ICP)

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for total metals (ICP) in accordance with EPA SW-846 Method 6010C. The samples were prepared on 07/15/2016 and analyzed on

07/18/2016 and 07/19/2016.

Several analytes failed the recovery criteria low for the MS and MSD of sample 240-67161-1 in batch 240-238690. Lead exceeded the

RPD limit.

No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TCLP MERCURY

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for TCLP mercury in accordance with EPA SW-846 Methods 1311/7470A. The samples were leached on 07/21/2016, prepared on 07/22/2016 and analyzed on 07/23/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

MERCURY

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for mercury in accordance with EPA SW-846 Method 7471B. The samples were prepared on 07/15/2016 and analyzed on 07/18/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

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Project/Site: B102 Demo WO#110

Job ID: 240-67116-1 (Continued)

Laboratory: TestAmerica Canton (Continued)

FLASHPOINT

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for flashpoint in accordance with EPA SW-846 Method 1010. The samples were analyzed on 07/20/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

TOTAL CYANIDE

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for total cyanide in accordance with EPA SW-846 Method 9012A. The samples were prepared and analyzed on 07/15/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

SULFIDE

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for sulfide in accordance with EPA SW-846 Method 9034. The samples were prepared and analyzed on 07/19/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

PH

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for pH in accordance with EPA SW-846 Method 9045C. The samples were analyzed on 07/14/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

PAINT FILTER

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3) and G-06-62-E (240-67116-4) were analyzed for paint filter in accordance with EPA SW-846 Method 9095A. The samples were analyzed on 07/15/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

PERCENT SOLIDS

Samples G-06-59-E (240-67116-1), G-06-60-E (240-67116-2), G-06-61-E (240-67116-3), G-06-62-E (240-67116-4) and G-06-62-E-1 (240-67116-5) were analyzed for percent solids in accordance with EPA Method 160.3 MOD. The samples were analyzed on 07/14/2016.

No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.

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Method Summary

Project/Site: B102 Demo WO#110

Method Method Description LaboratoryProtocol

SW8468260B Volatile Organic Compounds (GC/MS) TAL CAN

SW8468270D TCLP Semivolatiles TAL CAN

SW8468270D Semivolatile Organic Compounds (GC/MS) TAL CAN

SW8468015C Glycols- Direct Injection (GC/FID) TAL NSH

SW8468015C Nonhalogenated Organic using GC/FID (Direct Aqueous Injection) TAL NSH

SW8468082A Polychlorinated Biphenyls (PCBs) by Gas Chromatography TAL CAN

SW8466010C Metals (ICP) TAL CAN

SW8467470A Mercury (CVAA) TAL CAN

SW8467471B Mercury (CVAA) TAL CAN

SW8461010 Ignitability, Pensky-Martens Closed-Cup Method TAL CAN

SW8469012A Cyanide, Total and/or Amenable TAL CAN

SW8469034 Sulfide, Acid soluble and Insoluble (Titrimetric) TAL CAN

SW8469045C pH TAL CAN

SW8469095A Paint Filter TAL CAN

EPAMoisture Percent Moisture TAL CAN

Protocol References:

EPA = US Environmental Protection Agency

SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.

Laboratory References:

TAL CAN = TestAmerica Canton, 4101 Shuffel Street NW, North Canton, OH 44720, TEL (330)497-9396

TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177

TestAmerica Canton

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Sample Summary

Project/Site: B102 Demo WO#110

Lab Sample ID Client Sample ID ReceivedCollectedMatrix

240-67116-1 G-06-59-E Solid 07/13/16 08:35 07/13/16 13:35

240-67116-2 G-06-60-E Solid 07/13/16 08:20 07/13/16 13:35

240-67116-3 G-06-61-E Solid 07/13/16 07:55 07/13/16 13:35

240-67116-4 G-06-62-E Solid 07/13/16 09:35 07/13/16 13:35

240-67116-5 G-06-62-E-1 Solid 07/13/16 09:35 07/13/16 13:35

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Detection Summary

Project/Site: B102 Demo WO#110

Client Sample ID: G-06-59-E Lab Sample ID: 240-67116-1

☼1,1,1-Trichloroethane

RL

3.5 ug/Kg

MDL

0.46

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA1J1.2 8260B

☼1,1,2-Trichloro-1,2,2-trichfluoroethane 3.5 ug/Kg0.30 Total/NA12.8 J 8260B

☼Acetone 14 ug/Kg4.0 Total/NA15.7 J 8260B

☼Benzo[a]pyrene 7.3 ug/Kg0.70 Total/NA15.2 J 8270D

☼Benzo[b]fluoranthene 7.3 ug/Kg0.65 Total/NA111 8270D

☼Benzo[g,h,i]perylene 7.3 ug/Kg0.38 Total/NA15.3 J 8270D

☼Chrysene 7.3 ug/Kg1.2 Total/NA18.7 8270D

☼Fluoranthene 7.3 ug/Kg0.60 Total/NA112 8270D

☼Phenanthrene 7.3 ug/Kg0.80 Total/NA18.5 8270D

☼Pyrene 7.3 ug/Kg0.48 Total/NA19.5 8270D

1,4-Dichlorobenzene 0.0040 mg/L0.00034 TCLP10.0080 8270D

☼Aluminum 20 mg/Kg5.7 Total/NA16000 6010C

☼Arsenic 1.5 mg/Kg0.40 Total/NA111 6010C

☼Barium 20 mg/Kg0.40 Total/NA130 6010C

☼Cadmium 0.49 mg/Kg0.021 Total/NA10.38 J 6010C

☼Chromium 0.99 mg/Kg0.074 Total/NA112 6010C

☼Lead 0.99 mg/Kg0.20 Total/NA19.4 6010C

☼Nickel 3.9 mg/Kg0.079 Total/NA123 6010C

Aluminum 0.20 mg/L0.0040 TCLP10.010 J B 6010C

Arsenic 0.050 mg/L0.0033 TCLP10.0078 J B 6010C

Barium 0.50 mg/L0.0024 TCLP10.40 J 6010C

Cadmium 0.050 mg/L0.00029 TCLP10.0040 J 6010C

Chromium 0.050 mg/L0.00055 TCLP10.0031 J B 6010C

Lead 0.050 mg/L0.0019 TCLP10.0063 J 6010C

Nickel 0.040 mg/L0.0016 TCLP10.071 B 6010C

Silver 0.050 mg/L0.00092 TCLP10.0017 J 6010C

☼Mercury 0.11 mg/Kg0.015 Total/NA10.025 J 7471B

Flashpoint 1.00 Degrees F1.00 Total/NA1>200 1010

☼Cyanide, Total 0.51 mg/Kg0.30 Total/NA12.9 9012A

☼Sulfide 33 mg/Kg24 Total/NA135 9034 pH 0.100 SU0.100 Total/NA18.33 9045C

Free Liquid 0.10 NONE0.10 Total/NA1CNF 9095A

Client Sample ID: G-06-60-E Lab Sample ID: 240-67116-2

☼1,1,1-Trichloroethane

RL

3.9 ug/Kg

MDL

0.50

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA1J2.5 8260B

☼1,1-Dichloroethane 3.9 ug/Kg0.26 Total/NA17.5 8260B

☼Acetone 15 ug/Kg4.4 Total/NA17.2 J 8260B

☼Chloroform 3.9 ug/Kg0.28 Total/NA10.33 J 8260B

☼m-Xylene & p-Xylene 7.7 ug/Kg0.32 Total/NA10.33 J 8260B

☼Toluene 3.9 ug/Kg0.21 Total/NA10.25 J 8260B

☼Bis(2-ethylhexyl) phthalate 80 ug/Kg22 Total/NA126 J 8270D

☼Dibenzofuran 57 ug/Kg0.75 Total/NA115 J 8270D

☼2-Methylnaphthalene 7.6 ug/Kg0.57 Total/NA1390 8270D

☼Naphthalene 7.6 ug/Kg0.93 Total/NA1180 8270D

☼Phenanthrene 7.6 ug/Kg0.83 Total/NA157 8270D

1,4-Dichlorobenzene 0.0040 mg/L0.00034 TCLP10.0036 J 8270D

☼Aluminum 21 mg/Kg6.1 Total/NA18900 6010C

☼Arsenic 1.6 mg/Kg0.43 Total/NA113 6010C

TestAmerica Canton

This Detection Summary does not include radiochemical test results.

Page 11 of 83 7/27/2016

Project/Site: B102 Demo WO#110

Client Sample ID: G-06-60-E (Continued) Lab Sample ID: 240-67116-2

☼Barium

RL

21 mg/Kg

MDL

0.43

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA161 6010C

☼Cadmium 0.53 mg/Kg0.022 Total/NA10.14 J 6010C

☼Chromium 1.1 mg/Kg0.079 Total/NA114 6010C

☼Lead 1.1 mg/Kg0.21 Total/NA111 6010C

☼Nickel 4.2 mg/Kg0.085 Total/NA135 6010C

☼Selenium 2.1 mg/Kg0.36 Total/NA10.42 J 6010C

Aluminum 0.20 mg/L0.0040 TCLP10.0055 J B 6010C

Arsenic 0.050 mg/L0.0033 TCLP10.0066 J B 6010C

Barium 0.50 mg/L0.0024 TCLP10.67 6010C

Cadmium 0.050 mg/L0.00029 TCLP10.0015 J 6010C

Chromium 0.050 mg/L0.00055 TCLP10.0022 J B 6010C

Lead 0.050 mg/L0.0019 TCLP10.0035 J 6010C

Nickel 0.040 mg/L0.0016 TCLP10.042 B 6010C

☼Mercury 0.11 mg/Kg0.016 Total/NA10.018 J 7471B

Flashpoint 1.00 Degrees F1.00 Total/NA1>200 1010 pH 0.100 SU0.100 Total/NA18.13 9045C

Free Liquid 0.10 NONE0.10 Total/NA1CNF 9095A

Client Sample ID: G-06-61-E Lab Sample ID: 240-67116-3

☼1,1,1-Trichloroethane

RL

4.8 ug/Kg

MDL

0.62

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA16.7 8260B

☼1,1-Dichloroethane 4.8 ug/Kg0.32 Total/NA10.37 J 8260B

☼Acetone 19 ug/Kg5.4 Total/NA17.1 J 8260B

☼Toluene 4.8 ug/Kg0.26 Total/NA10.67 J 8260B

2-Butanone (MEK) 0.25 mg/L0.029 TCLP10.11 J 8260B

☼Acenaphthene 7.8 ug/Kg0.89 Total/NA114 8270D

☼Anthracene 7.8 ug/Kg0.92 Total/NA123 8270D

☼Benzo[a]anthracene 7.8 ug/Kg0.74 Total/NA189 8270D

☼Benzo[a]pyrene 7.8 ug/Kg0.75 Total/NA199 8270D

☼Benzo[b]fluoranthene 7.8 ug/Kg0.69 Total/NA1160 8270D

☼Benzo[g,h,i]perylene 7.8 ug/Kg0.41 Total/NA151 8270D

☼Benzo[k]fluoranthene 7.8 ug/Kg0.80 Total/NA163 8270D

☼Bis(2-ethylhexyl) phthalate 82 ug/Kg22 Total/NA124 J 8270D

☼Chrysene 7.8 ug/Kg1.3 Total/NA1110 8270D

☼Dibenzofuran 59 ug/Kg0.78 Total/NA17.3 J 8270D

☼Fluoranthene 7.8 ug/Kg0.65 Total/NA1230 8270D

☼Fluorene 7.8 ug/Kg0.62 Total/NA113 8270D

☼Indeno[1,2,3-cd]pyrene 7.8 ug/Kg0.41 Total/NA147 8270D

☼2-Methylnaphthalene 7.8 ug/Kg0.59 Total/NA15.6 J 8270D

☼Naphthalene 7.8 ug/Kg0.96 Total/NA15.5 J 8270D

☼Phenanthrene 7.8 ug/Kg0.86 Total/NA1130 8270D

☼Pyrene 7.8 ug/Kg0.52 Total/NA1180 8270D

1,4-Dichlorobenzene 0.0040 mg/L0.00034 TCLP10.0011 J 8270D

☼Aluminum 22 mg/Kg6.3 Total/NA110000 6010C

☼Arsenic 1.6 mg/Kg0.44 Total/NA110 6010C

☼Barium 22 mg/Kg0.44 Total/NA180 6010C

☼Cadmium 0.54 mg/Kg0.023 Total/NA10.22 J 6010C

☼Chromium 1.1 mg/Kg0.081 Total/NA115 6010C

☼Lead 1.1 mg/Kg0.22 Total/NA122 6010C

TestAmerica Canton

This Detection Summary does not include radiochemical test results.

Page 12 of 83 7/27/2016

Project/Site: B102 Demo WO#110

Client Sample ID: G-06-61-E (Continued) Lab Sample ID: 240-67116-3

☼Nickel

RL

4.3 mg/Kg

MDL

0.086

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA122 6010C

☼Selenium 2.2 mg/Kg0.37 Total/NA10.56 J 6010C

Arsenic 0.050 mg/L0.0033 TCLP10.0067 J B 6010C

Barium 0.50 mg/L0.0024 TCLP10.47 J 6010C

Cadmium 0.050 mg/L0.00029 TCLP10.00046 J 6010C

Chromium 0.050 mg/L0.00055 TCLP10.0022 J B 6010C

Lead 0.050 mg/L0.0019 TCLP10.0025 J 6010C

Nickel 0.040 mg/L0.0016 TCLP10.010 J B 6010C

☼Mercury 0.12 mg/Kg0.017 Total/NA10.12 7471B

Flashpoint 1.00 Degrees F1.00 Total/NA1>200 1010

☼Cyanide, Total 0.55 mg/Kg0.33 Total/NA10.87 9012A

☼Sulfide 35 mg/Kg26 Total/NA133 J 9034 pH 0.100 SU0.100 Total/NA110.1 9045C

Free Liquid 0.10 NONE0.10 Total/NA1CNF 9095A

Client Sample ID: G-06-62-E Lab Sample ID: 240-67116-4

☼1,1,1-Trichloroethane

RL

4.2 ug/Kg

MDL

0.55

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA1J0.63 8260B

☼1,1-Dichloroethane 4.2 ug/Kg0.29 Total/NA10.36 J 8260B

☼1,2,4-Trimethylbenzene 4.2 ug/Kg0.49 Total/NA10.77 J 8260B

☼Acetone 17 ug/Kg4.8 Total/NA148 8260B

☼m-Xylene & p-Xylene 8.5 ug/Kg0.36 Total/NA10.55 J 8260B

☼Xylenes, Total 8.5 ug/Kg0.46 Total/NA10.55 J 8260B

☼Acenaphthene 7.7 ug/Kg0.88 Total/NA144 8270D

☼Acenaphthylene 7.7 ug/Kg0.40 Total/NA19.2 8270D

☼Anthracene 7.7 ug/Kg0.90 Total/NA192 8270D

☼Benzo[a]anthracene 7.7 ug/Kg0.73 Total/NA1380 8270D

☼Benzo[a]pyrene 7.7 ug/Kg0.74 Total/NA1440 8270D

☼Benzo[b]fluoranthene 7.7 ug/Kg0.68 Total/NA1680 8270D

☼Benzo[g,h,i]perylene 7.7 ug/Kg0.40 Total/NA1210 8270D

☼Benzo[k]fluoranthene 7.7 ug/Kg0.78 Total/NA1290 8270D

☼Bis(2-ethylhexyl) phthalate 81 ug/Kg22 Total/NA157 J 8270D

☼Butyl benzyl phthalate 81 ug/Kg12 Total/NA135 J 8270D

☼Carbazole 58 ug/Kg31 Total/NA182 8270D

☼Chrysene 7.7 ug/Kg1.3 Total/NA1460 8270D

☼Dibenzofuran 58 ug/Kg0.76 Total/NA121 J 8270D

☼Di-n-butyl phthalate 81 ug/Kg17 Total/NA126 J 8270D

☼Fluoranthene 7.7 ug/Kg0.63 Total/NA11000 8270D

☼Fluorene 7.7 ug/Kg0.61 Total/NA136 8270D

☼Indeno[1,2,3-cd]pyrene 7.7 ug/Kg0.40 Total/NA1190 8270D

☼2-Methylnaphthalene 7.7 ug/Kg0.58 Total/NA18.8 8270D

☼Naphthalene 7.7 ug/Kg0.95 Total/NA19.0 8270D

☼Phenanthrene 7.7 ug/Kg0.84 Total/NA1490 8270D

☼Pyrene 7.7 ug/Kg0.51 Total/NA1790 8270D

1,4-Dichlorobenzene 0.0040 mg/L0.00034 TCLP10.0018 J 8270D

Pyridine 0.0040 mg/L0.00035 TCLP10.0014 J 8270D

☼Aroclor-1260 38 ug/Kg10 Total/NA115 J 8082A

☼Aluminum 20 mg/Kg5.9 Total/NA18000 6010C

☼Arsenic 1.5 mg/Kg0.42 Total/NA112 6010C

TestAmerica Canton

This Detection Summary does not include radiochemical test results.

Page 13 of 83 7/27/2016

Project/Site: B102 Demo WO#110

Client Sample ID: G-06-62-E (Continued) Lab Sample ID: 240-67116-4

☼Barium

RL

20 mg/Kg

MDL

0.42

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA146 6010C

☼Cadmium 0.51 mg/Kg0.021 Total/NA10.53 6010C

☼Chromium 1.0 mg/Kg0.076 Total/NA118 6010C

☼Lead 1.0 mg/Kg0.20 Total/NA132 6010C

☼Nickel 4.1 mg/Kg0.081 Total/NA131 6010C

☼Selenium 2.0 mg/Kg0.35 Total/NA10.52 J 6010C

Arsenic 0.050 mg/L0.0033 TCLP10.0077 J B 6010C

Barium 0.50 mg/L0.0024 TCLP10.53 6010C

Cadmium 0.050 mg/L0.00029 TCLP10.0025 J 6010C

Chromium 0.050 mg/L0.00055 TCLP10.0027 J B 6010C

Lead 0.050 mg/L0.0019 TCLP10.0051 J 6010C

Nickel 0.040 mg/L0.0016 TCLP10.013 J B 6010C

☼Mercury 0.11 mg/Kg0.015 Total/NA10.44 7471B

Flashpoint 1.00 Degrees F1.00 Total/NA1>200 1010 pH 0.100 SU0.100 Total/NA18.50 9045C

Free Liquid 0.10 NONE0.10 Total/NA1CNF 9095A

Client Sample ID: G-06-62-E-1 Lab Sample ID: 240-67116-5

☼1,1,1-Trichloroethane

RL

4.0 ug/Kg

MDL

0.52

Analyte Result Qualifier Unit Dil Fac D Method Prep Type

Total/NA1J0.78 8260B

☼1,1-Dichloroethane 4.0 ug/Kg0.27 Total/NA10.70 J 8260B

☼Acetone 16 ug/Kg4.6 Total/NA153 8260B

TestAmerica Canton

This Detection Summary does not include radiochemical test results.

Page 14 of 83 7/27/2016

Client Sample Results

Project/Site: B102 Demo WO#110

Lab Sample ID: 240-67116-1Client Sample ID: G-06-59-E Matrix: SolidDate Collected: 07/13/16 08:35

Percent Solids: 91.3Date Received: 07/13/16 13:35

Method: 8260B - Volatile Organic Compounds (GC/MS)

RL MDL

1,1,1,2-Tetrachloroethane 3.5 U 3.5 0.35 ug/Kg ☼ 07/14/16 11:05 07/18/16 19:35 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

3.5 0.46 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,1,1-Trichloroethane 1.2 J

3.5 0.22 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,1,2,2-Tetrachloroethane 3.5 U

3.5 0.30 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,1,2-Trichloro-1,2,2-trichfluoroet hane

2.8 J

3.5 0.26 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,1,2-Trichloroethane 3.5 U

3.5 0.24 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,1-Dichloroethane 3.5 U

3.5 0.57 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,1-Dichloroethene 3.5 U

3.5 0.26 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,1-Dichloropropene 3.5 U

3.5 0.35 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,2,3-Trichlorobenzene 3.5 U

3.5 0.55 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,2,3-Trichloropropane 3.5 U

3.5 0.41 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,2,4-Trimethylbenzene 3.5 U

7.1 1.9 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,2-D bromo-3-Chloropropane 7.1 U

3.5 0.24 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,2-Dichlorobenzene 3.5 U

3.5 0.33 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,2-Dichloroethane 3.5 U

3.5 0.099 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼1,2-Dichloropropane 3.5 U

7.1 2.8 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼2-Nitropropane 7.1 U

3.5 0.31 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼2,2-Dichloropropane 3.5 U *

3.5 0.21 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼2-Chlorotoluene 3.5 U

14 0.48 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼2-Hexanone 14 U

3.5 0.23 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Bromobenzene 3.5 U

3.5 0.23 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Chlorobromomethane 3.5 U

3.5 0.18 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼4-Chlorotoluene 3.5 U

3.5 0.29 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼4-Isopropyltoluene 3.5 U

14 4.0 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Acetone 5.7 J

3.5 0.64 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Benzene 3.5 U

3.5 0.17 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Bromoform 3.5 U

3.5 0.30 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Bromomethane 3.5 U

3.5 0.42 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Carbon disulfide 3.5 U

3.5 0.46 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Carbon tetrachloride 3.5 U *

3.5 0.38 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Chlorobenzene 3.5 U

3.5 0.31 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Chloroethane 3.5 U

3.5 0.26 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Chloroform 3.5 U

3.5 0.56 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Chloromethane 3.5 U

3.5 0.20 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼cis-1,2-Dichloroethene 3.5 U

14 2.2 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Ethyl acetate 14 U

3.5 0.50 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼cis-1,3-Dichloropropene 3.5 U

71 12 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Cyclohexanone 71 U

3.5 0.30 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Dibromomethane 3.5 U

3.5 0.21 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Dichlorobromomethane 3.5 U

3.5 0.20 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Dichlorodifluoromethane 3.5 U

3.5 0.41 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Ethyl ether 3.5 U

3.5 0.23 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Ethylbenzene 3.5 U

3.5 0.38 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Ethylene Dibromide 3.5 U

140 6.5 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Isobutyl alcohol 140 U

7.1 0.30 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼m-Xylene & p-Xylene 7.1 U

3.5 0.42 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼n-Butylbenzene 3.5 U

3.5 0.14 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Isopropy benzene 3.5 U

3.5 0.43 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼N-Propylbenzene 3.5 U

TestAmerica Canton

Page 15 of 83 7/27/2016

Project/Site: B102 Demo WO#110

Lab Sample ID: 240-67116-1Client Sample ID: G-06-59-E Matrix: SolidDate Collected: 07/13/16 08:35

Percent Solids: 91.3Date Received: 07/13/16 13:35

Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)

RL MDL

2-Butanone (MEK) 14 U 14 0.79 ug/Kg ☼ 07/14/16 11:05 07/18/16 19:35 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

14 0.87 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼4-Methyl-2-pentanone (MIBK) 14 U

3.5 0.65 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼sec-Butylbenzene 3.5 U

3.5 0.31 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Methyl tert-butyl ether 3.5 U

3.5 0.53 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Methylene Chloride 3.5 U

710 16 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼n-Butanol 710 U

3.5 0.40 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼o-Xylene 3.5 U

3.5 0.28 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Styrene 3.5 U

3.5 0.48 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼tert-Butylbenzene 3.5 U

3.5 0.57 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Tetrachloroethene 3.5 U

3.5 0.19 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Toluene 3.5 U

3.5 0.23 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼trans-1,2-Dichloroethene 3.5 U

3.5 0.21 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼trans-1,3-Dichloropropene 3.5 U

3.5 0.27 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Trichloroethene 3.5 U

3.5 0.21 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Trichlorofluoromethane 3.5 U

3.5 0.21 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Vinyl chloride 3.5 U

7.1 0.38 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Xylenes, Total 7.1 U

3.5 0.26 ug/Kg 07/14/16 11:05 07/18/16 19:35 1☼Chlorodibromomethane 3.5 U

1,2-Dichloroethane-d4 (Surr) 104 58 - 123 07/14/16 11:05 07/18/16 19:35 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

4-Bromofluorobenzene (Surr) 88 07/14/16 11:05 07/18/16 19:35 152 - 136

Toluene-d8 (Surr) 97 07/14/16 11:05 07/18/16 19:35 167 - 125

Dibromofluoromethane (Surr) 94 07/14/16 11:05 07/18/16 19:35 137 - 132

Method: 8260B - Volatile Organic Compounds (GC/MS) - TCLP

RL MDL

1,1-Dichloroethene 0.025 U 0.025 0.0095 mg/L 07/24/16 20:25 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.025 0.011 mg/L 07/24/16 20:25 11,2-Dichloroethane 0.025 U

0.25 0.029 mg/L 07/24/16 20:25 12-Butanone (MEK) 0.25 U

0.025 0.0065 mg/L 07/24/16 20:25 1Benzene 0.025 U

0.025 0.0065 mg/L 07/24/16 20:25 1Carbon tetrachloride 0.025 U

0.025 0.0075 mg/L 07/24/16 20:25 1Chlorobenzene 0.025 U

0.025 0.0080 mg/L 07/24/16 20:25 1Chloroform 0.025 U

0.025 0.015 mg/L 07/24/16 20:25 1Tetrachloroethene 0.025 U

0.025 0.0085 mg/L 07/24/16 20:25 1Trichloroethene 0.025 U

0.025 0.011 mg/L 07/24/16 20:25 1Vinyl chloride 0.025 U

1,2-Dichloroethane-d4 (Surr) 92 80 - 121 07/24/16 20:25 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

4-Bromofluorobenzene (Surr) 84 07/24/16 20:25 170 - 124

Toluene-d8 (Surr) 93 07/24/16 20:25 180 - 120

Dibromofluoromethane (Surr) 97 07/24/16 20:25 180 - 128

Method: 8270D - Semivolatile Organic Compounds (GC/MS)

RL MDL

Acenaphthene 7.3 U 7.3 0.83 ug/Kg ☼ 07/21/16 07:45 07/25/16 11:44 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

7.3 0.38 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Acenaphthylene 7.3 U

7.3 0.85 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Anthracene 7.3 U

7.3 0.69 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Benzo[a]anthracene 7.3 U

TestAmerica Canton

Page 16 of 83 7/27/2016

Project/Site: B102 Demo WO#110

Lab Sample ID: 240-67116-1Client Sample ID: G-06-59-E Matrix: SolidDate Collected: 07/13/16 08:35

Percent Solids: 91.3Date Received: 07/13/16 13:35

Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued)

RL MDL

Benzo[a]pyrene 5.2 J 7.3 0.70 ug/Kg ☼ 07/21/16 07:45 07/25/16 11:44 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

7.3 0.65 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Benzo[b]fluoranthene 11

7.3 0.38 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Benzo[g,h,i]perylene 5.3 J

720 39 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Benzoic acid 720 U

7.3 0.74 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Benzo[k]fluoranthene 7.3 U

360 23 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Benzyl alcohol 360 U

110 24 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Bis(2-chloroethoxy)methane 110 U

110 2.2 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Bis(2-chloroethyl)ether 110 U

110 10 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼bis (2-chloroisopropyl) ether 110 U

77 21 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Bis(2-ethylhexyl) phthalate 77 U

55 14 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼4-Bromophenyl phenyl ether 55 U

77 11 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Butyl benzyl phthalate 77 U

55 30 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Carbazole 55 U

160 19 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼4-Chloroaniline 160 U

160 23 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼4-Chloro-3-methylphenol 160 U

55 0.49 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2-Chloronaphthalene 55 U

55 9.0 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2-Chlorophenol 55 U

55 14 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼4-Chlorophenyl phenyl ether 55 U

7.3 1.2 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Chrysene 8.7

7.3 0.72 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Dibenz(a,h)anthracene 7.3 U

55 0.72 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Dibenzofuran 55 U

55 12 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼1,3-Dichlorobenzene 55 U

55 22 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼1,4-Dichlorobenzene 55 U

110 20 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼3,3'-Dichlorobenzidine 110 U

160 22 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2,4-Dichlorophenol 160 U

77 18 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Diethyl phthalate 77 U

160 22 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2,4-Dimethylphenol 160 U

77 19 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Dimethyl phthalate 77 U

77 16 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Di-n-butyl phthalate 77 U

160 10 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼4,6-Dinitro-2-methylphenol 160 U

360 23 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2,4-Dinitrophenol 360 U

220 19 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2,4-Dinitrotoluene 220 U

220 23 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2,6-Dinitrotoluene 220 U

77 8.6 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Di-n-octyl phthalate 77 U

7.3 0.60 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Fluoranthene 12

7.3 0.58 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Fluorene 7.3 U

7.3 2.3 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Hexachlorobenzene 7.3 U

55 6.1 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Hexachlorobutadiene 55 U

360 8.9 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Hexachlorocyclopentadiene 360 U

55 9.9 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Hexachloroethane 55 U

7.3 0.38 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Indeno[1,2,3-cd]pyrene 7.3 U

55 14 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Isophorone 55 U

7.3 0.55 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2-Methylnaphthalene 7.3 U

220 12 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2-Methylphenol 220 U

440 22 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼3 & 4 Methylphenol 440 U

7.3 0.90 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Naphthalene 7.3 U

220 10 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2-Nitroaniline 220 U

220 18 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼3-Nitroaniline 220 U

220 28 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼4-Nitroaniline 220 U

TestAmerica Canton

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Project/Site: B102 Demo WO#110

Lab Sample ID: 240-67116-1Client Sample ID: G-06-59-E Matrix: SolidDate Collected: 07/13/16 08:35

Percent Solids: 91.3Date Received: 07/13/16 13:35

Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued)

RL MDL

Nitrobenzene 110 U 110 2.4 ug/Kg ☼ 07/21/16 07:45 07/25/16 11:44 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

55 9.1 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2-Nitrophenol 55 U

360 19 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼4-Nitrophenol 360 U

55 6.9 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼N-Nitrosodi-n-propylamine 55 U

55 23 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼N-Nitrosodiphenylamine 55 U

160 10 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Pentachlorophenol 160 U

7.3 0.80 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Phenanthrene 8.5

55 8.0 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Phenol 55 U

7.3 0.48 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Pyrene 9.5

110 3.8 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼Pyridine 110 U

55 3.8 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼1,2,4-Trichlorobenzene 55 U

160 27 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2,4,5-Trichlorophenol 160 U

160 9.7 ug/Kg 07/21/16 07:45 07/25/16 11:44 1☼2,4,6-Trichlorophenol 160 U

2-Fluorobiphenyl (Surr) 53 39 - 120 07/21/16 07:45 07/25/16 11:44 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

2-Fluorophenol (Surr) 46 07/21/16 07:45 07/25/16 11:44 133 - 120

Nitrobenzene-d5 (Surr) 41 07/21/16 07:45 07/25/16 11:44 132 - 120

Phenol-d5 (Surr) 49 07/21/16 07:45 07/25/16 11:44 132 - 120

Terphenyl-d14 (Surr) 61 07/21/16 07:45 07/25/16 11:44 147 - 120

2,4,6-Tribromophenol (Surr) 30 07/21/16 07:45 07/25/16 11:44 110 - 120

Method: 8270D - TCLP Semivolatiles - TCLP

RL MDL

1,4-Dichlorobenzene 0.0080 0.0040 0.00034 mg/L 07/22/16 12:01 07/24/16 16:49 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

0.0040 0.00030 mg/L 07/22/16 12:01 07/24/16 16:49 12,4,5-Trichlorophenol 0.0040 U

0.0040 0.00024 mg/L 07/22/16 12:01 07/24/16 16:49 12,4,6-Trichlorophenol 0.0040 U

0.0040 0.00025 mg/L 07/22/16 12:01 07/24/16 16:49 12,4-Dinitrotoluene 0.0040 U

0.00080 0.000085 mg/L 07/22/16 12:01 07/24/16 16:49 1Hexachlorobenzene 0.00080 U

0.0040 0.00027 mg/L 07/22/16 12:01 07/24/16 16:49 1Hexachlorobutadiene 0.0040 U

0.0040 0.00019 mg/L 07/22/16 12:01 07/24/16 16:49 1Hexachloroethane 0.0040 U

0.0040 0.00017 mg/L 07/22/16 12:01 07/24/16 16:49 12-Methylphenol 0.0040 U

0.0040 0.00080 mg/L 07/22/16 12:01 07/24/16 16:49 13 & 4 Methylphenol 0.0040 U

0.0040 0.000040 mg/L 07/22/16 12:01 07/24/16 16:49 1Nitrobenzene 0.0040 U

0.016 0.00027 mg/L 07/22/16 12:01 07/24/16 16:49 1Pentachlorophenol 0.016 U

0.0040 0.00035 mg/L 07/22/16 12:01 07/24/16 16:49 1Pyridine 0.0040 U

Terphenyl-d14 (Surr) 79 17 - 120 07/22/16 12:01 07/24/16 16:49 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Phenol-d5 (Surr) 45 07/22/16 12:01 07/24/16 16:49 110 - 120

Nitrobenzene-d5 (Surr) 64 07/22/16 12:01 07/24/16 16:49 136 - 120

2-Fluorophenol (Surr) 54 07/22/16 12:01 07/24/16 16:49 110 - 120

2-Fluorobiphenyl (Surr) 66 07/22/16 12:01 07/24/16 16:49 142 - 120

2,4,6-Tribromophenol (Surr) 68 07/22/16 12:01 07/24/16 16:49 135 - 125

Method: 8015C - Glycols- Direct Injection (GC/FID) - Soluble

RL MDL

2-Ethoxyethanol 11 U 11 1.1 mg/Kg ☼ 07/18/16 01:10 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier n-butyl alcohol (Surr) 122 60 - 140 07/18/16 01:10 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

TestAmerica Canton

Page 18 of 83 7/27/2016

Project/Site: B102 Demo WO#110

Method: 8015C - Nonhalogenated Organic using GC/FID (Direct Aqueous Injection) - Soluble

RL MDL

Methanol 11 U 11 4.4 mg/Kg ☼ 07/18/16 21:41 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

Isopropyl acetate (Surr) 67 40 - 120 07/18/16 21:41 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

Method: 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography

RL MDL

Aroclor-1016 37 U 37 13 ug/Kg ☼ 07/15/16 09:17 07/19/16 21:29 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

37 18 ug/Kg 07/15/16 09:17 07/19/16 21:29 1☼Aroclor-1221 37 U

37 22 ug/Kg 07/15/16 09:17 07/19/16 21:29 1☼Aroclor-1232 37 U

37 12 ug/Kg 07/15/16 09:17 07/19/16 21:29 1☼Aroclor-1242 37 U

37 8.8 ug/Kg 07/15/16 09:17 07/19/16 21:29 1☼Aroclor-1248 37 U

37 15 ug/Kg 07/15/16 09:17 07/19/16 21:29 1☼Aroclor-1254 37 U

37 10 ug/Kg 07/15/16 09:17 07/19/16 21:29 1☼Aroclor-1260 37 U

Tetrachloro-m-xylene 72 14 - 128 07/15/16 09:17 07/19/16 21:29 1

Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery

DCB Decachlorobiphenyl 72 07/15/16 09:17 07/19/16 21:29 110 - 132

Method: 6010C - Metals (ICP)

RL MDL

Aluminum 6000 20 5.7 mg/Kg ☼ 07/15/16 10:55 07/18/16 15:41 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

1.5 0.40 mg/Kg 07/15/16 10:55 07/18/16 15:41 1☼Arsenic 11

20 0.40 mg/Kg 07/15/16 10:55 07/18/16 15:41 1☼Barium 30

0.49 0.021 mg/Kg 07/15/16 10:55 07/18/16 15:41 1☼Cadmium 0.38 J

0.99 0.074 mg/Kg 07/15/16 10:55 07/18/16 15:41 1☼Chromium 12

0.99 0.20 mg/Kg 07/15/16 10:55 07/18/16 15:41 1☼Lead 9.4

3.9 0.079 mg/Kg 07/15/16 10:55 07/19/16 17:18 1☼Nickel 23

2.0 0.34 mg/Kg 07/15/16 10:55 07/18/16 15:41 1☼Selenium 2.0 U

0.99 0.062 mg/Kg 07/15/16 10:55 07/18/16 15:41 1☼Silver 0.99 U

Method: 6010C - Metals (ICP) - TCLP

RL MDL

Aluminum 0.010 J B 0.20 0.0040 mg/L 07/22/16…