J22919-1_Mini_Final_Report.pdf

ANALYTICAL REPORT

Job Number: 180-22919-1

Job Description: Newark Bay - Upland 33-061

For:

Battelle

397 Washington Street Duxbury, MA 02332

Attention: Elisabeth Barrows

Approved for release.

Debra Bowen Project Manager I

7/30/2013 3:24 PM

Designee for Carrie L Gamber, Senior Project Manager 301 Alpha Drive, Pittsburgh, PA, 15238

(412)963-2428 carrie.gamber@testamericainc.com

07/30/2013

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to the NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory. This report is confidential and is intended for the sole use of TestAmerica and its client. All questions regarding this report should be directed to the TestAmerica Project Manager or designee who has signed this report.

TestAmerica Laboratories, Inc.

TestAmerica Pittsburgh 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238

Tel (412) 963-7058 Fax (412) 963-2468 www.testamericainc.com

07/30/2013Page 1 of 4260 mailto:carrie.gamber@testamericainc.com http://www.testamericainc.com http://

Table of Contents Cover Title Page

Data Summaries

Report Narrative

Manual Integration Summary

Sample Summary

Executive Summary

Method Summary

Method / Analyst Summary

Sample Datasheets

Surrogate Summary

QC Data Summary

Data Qualifiers

QC Association Summary

Lab Chronicle

Reagent Traceability

COAs

Certification Summary

Organic Sample Data

GC/MS VOA

Method 8260B Method 8260B QC Summary Method 8260B Sample Data Standards Data

Method 8260B ICAL Data Method 8260B CCAL Data

Raw QC Data

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Method 8260B Tune Data Method 8260B Blank Data Method 8260B LCS/LCSD Data Method 8260B MS/MSD Data

Method 8260B Run Logs Method 8260B Prep Data

GC/MS Semi VOA

Method 8270C Method 8270C QC Summary Method 8270C Sample Data Standards Data

Method 8270C ICAL Data Method 8270C CCAL Data

Raw QC Data Method 8270C Tune Data Method 8270C Blank Data Method 8270C LCS/LCSD Data Method 8270C MS/MSD Data

Method 8270C Run Logs Method 8270C Prep Data

GC Semi VOA

Method 8081A Method 8081A QC Summary Method 8081A Sample Data Standards Data

Method 8081A ICAL Data

07/30/2013Page 3 of 4260

Method 8081A PEM Data Method 8081A CCAL Data

Raw QC Data Method 8081A Blank Data Method 8081A LCS/LCSD Data Method 8081A MS/MSD Data

Method 8081A Run Logs Method 8081A Prep Data

Method 8082 Method 8082 QC Summary Method 8082 Sample Data Standards Data

Method 8082 ICAL Data Method 8082 CCAL Data

Raw QC Data Method 8082 Blank Data Method 8082 LCS/LCSD Data Method 8082 MS/MSD Data

Method 8082 Run Logs Method 8082 Prep Data

Method 8151A Method 8151A QC Summary Method 8151A Sample Data Standards Data

Method 8151A ICAL Data Method 8151A CCAL Data

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Raw QC Data

Method 8151A Blank Data Method 8151A LCS/LCSD Data Method 8151A MS/MSD Data

Method 8151A Run Logs Method 8151A Prep Data

Inorganic Sample Data

Metals Data

Met Cover Page

Met Sample Data

Met QC Data Met ICV/CCV Met CRQL Met Blanks Met ICSA/ICSAB Met MS/MSD/PDS Met LCS/LCSD Met Serial Dilution

Met MDL

Met IECF

Met Linear Ranges

Met Preparation Log

Met Analysis Run Log

Met Raw Data

Met Prep Data

General Chemistry Data

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Gen Chem Cover Page

Gen Chem Sample Data

Gen Chem QC Data Gen Chem ICV/CCV Gen Chem Blanks Gen Chem MS/MSD/PDS Gen Chem Duplicates Gen Chem LCS/LCSD

Gen Chem MDL

Gen Chem Preparation Log

Gen Chem Analysis Run Log

Gen Chem Raw Data

Gen Chem Prep Data

Subcontracted Data

Shipping and Receiving Documents

Client Chain of Custody

Sample Receipt Checklist

07/30/2013Page 6 of 4260

CASE NARRATIVE

Client: Battelle

Project: Newark Bay - Upland 33-061

Report Number: 180-22919-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

RECEIPT

The samples were received on 07/09/2013. The samples arrived in good condition, properly preserved and on ice. The temperatures of the coolers at receipt time were 3.7º C and 4.3º C.

VOLATILE ORGANIC COMPOUNDS (GC-MS)

Dibromofluoromethane (Surr) failed the surrogate recovery criteria low for #20130941 AMENDED COMPOSITE B (180-22919-4). The surrogate issue is confirmed by analysis of the MS/MSD.

Dibromofluoromethane (Surr) failed the surrogate recovery criteria low for samples #20130942 AMENDED COMPOSITE C (180-22919-5) and #20130947 AMENDED COMPOSITE H (180-22919-6). Re-extraction and/or re-analysis was performed with concurring results. Both sets of data are reported.

Acrolein failed the recovery criteria for the MS/MSD of sample #20130919 COMPOSITE B (180-22919-1) in batch 180-77100.

Several analytes failed the recovery criteria for the MS and/or MSD of sample AMENDED COMPOSITE B (180-22919-4). Also, several analytes exceeded the relative percent difference (RPD) limits.

Acrolein failed the recovery low for LCS 180-77100. This compound is not a control compound. The data are reported.

Dichlorodofluoromethane failed the recovery high in LCS 180-77779. This compound was not detected in the associated samples. The data are reported.

SEMIVOLATILE ORGANIC COMPOUNDS (GC-MS)

Several samples were analyzed at a dilution due to the abundance of target analytes and/or matrix interference. As such, the surrogate concentration (s) will be considered as estimated. The reporting limits have been adjusted accordingly.

Benzidine failed the recovery low in LCS 180-77168. This compound has been identified as a poor performing analyte when analyzed using this method; therefore, re-extraction/re-analysis was not performed.

Hexachlorocyclopentadiene failed the recovery low for LCS 180-77590. This compound has been identified as a poor performing analyte when analyzed using this method; therefore, re-extraction/re-analysis was not performed.

Benzidine and Hexachlorocyclopentadiene failed the recovery criteria low for the MS/MSD of sample #20130941 AMENDED

COMPOSITE BMS (180-22919-4).

ORGANOCHLORINE PESTICIDES

Endrin aldehyde failed the recovery criteria low for the MS of sample #20130941 AMENDED COMPOSITE BMS (180-22919-4) in batch

180-77728.

Several analytes failed the recovery criteria for the MS/MSD of samples #20130919 COMPOSITE B (180-22919-1) and #20130941

AMENDED COMPOSITE (180-22919-4). Several analytes exceeded the relative percent difference (RPD) limit.

POLYCHLORINATED BIPHENYLS (PCBS)

PCB-1260 failed the recovery criteria low for the MS of sample #20130941 AMENDED COMPOSITE B (180-22919-4).

HERBICIDES

No difficulties were encountered during the Herbicides analysis.

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METALS

Several samples were analyzed at a dilution due to the abundance of mercury and/or matrix interference. The reporting limits have been adjusted accordingly.

Calcium, Cobalt and Selenium were detected in laboratory blank LB 180-77408/13 at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged.

Several analytes were detected in the method blanks at levels that were above the method detection limit but below the reporting limit.

The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or

RL, the result has been flagged.

Antimony failed the recovery criteria for the MS/MSD of sample #20130919 COMPOSITE B (180-22919-1). The presence of the '4' qualifier in the data indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.

Several analytes failed the recovery criteria for the MS and/or MSD of sample #20130941 AMENDED COMPOSITE (180-22919-4). The presence of the '4' qualifier in the data indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount. Also, Calcium exceeded the relative percent difference (RPD) limit.

Several analytes exceeded the serial dilution criteria for samples #20130919 COMPOSITE B (180-22919-1) and #20130941 AMENDED

COMPOSITE (180-22919-4).

GENERAL CHEMISTRY

Cr (VI) and Cr (VI) failed the recovery criteria low for the MS of sample #20130919 COMPOSITE B (180-22919-1) and sample #20130941

AMENDED COMPOSITE BMS (180-22919-4).

The matrix soluble spike, insoluble spike and post digestion spike (MSS/MSI/PDS) recoveries for batch 78283 were outside of control limits. The associated laboratory control sample (LCSS/LCSI) recoveries met acceptance criteria, which demonstrates that the analytical system was operating in control. This condition is most likely due to matrix interference. An ORP was performed for samples

180-180-22919-C-1 and 180-22919-B-4 and the chart is included in the report. This is the first analysis of the batch; a reanalysis will be performed in accordance with the SOP.

The matrix soluble spike, insoluble spike and post digestion spike (MSS/MSI/PDS) recoveries for batch 78288 were outside of control limits. The associated laboratory control sample (LCSS/LCSI) recoveries met acceptance criteria, which demonstrate that the analytical system was operating in control. This condition is most likely due to matrix interference. An ORP was performed for samples

180-22919-C-1 and 180-22919-B-4 and the chart is included in the report. This is the second analysis of the batch in accordance with the

SOP.

Cyanide, Total failed the recovery criteria for the MS/MSD of sample #20130941 AMENDED COMPOSITE B (180-22919-4).

SUBCONTRACT WORK

Method 1613B Dioxin-SPLP LEACH: This method was subcontracted to TestAmerica Knoxville. The subcontract certification is different from those listed on the TestAmerica cover page of this final report.

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Lab Name: Job No.:

SDG No.:

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP3 76109

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/2

3062803.D06/28/13 06:41 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:391.76

Trichlorofluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:402.96

Acrolein Peak Integrated Incorrectly gordonk 06/28/13 07:423.59

1,1-Dichloroethene Peak Integrated Incorrectly gordonk 06/28/13 07:403.74

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly gordonk 06/28/13 07:393.82

Carbon disulfide Peak Integrated Incorrectly gordonk 06/28/13 07:404.06 tert-Butyl alcohol Peak Integrated Incorrectly gordonk 06/28/13 07:414.80

Hexane Peak Integrated Incorrectly gordonk 06/28/13 07:425.39

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 07:416.33

Bromochloromethane Peak Integrated Incorrectly gordonk 06/28/13 07:406.57

Isobutyl alcohol Peak Integrated Incorrectly gordonk 06/28/13 07:427.24

Ethyl methacrylate Peak Integrated Incorrectly gordonk 06/28/13 07:429.62

1,2-Dibromo-3-Chloropropane Peak Integrated Incorrectly gordonk 06/28/13 07:4114.19

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/3

3062804.D06/28/13 07:06 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:441.76

Chloroethane Peak Integrated Incorrectly gordonk 06/28/13 07:442.60

Carbon disulfide Peak Integrated Incorrectly gordonk 06/28/13 07:444.05

Methylene Chloride Peak Integrated Incorrectly gordonk 06/28/13 07:454.54

2,2-Dichloropropane Peak Integrated Incorrectly gordonk 06/28/13 07:456.30

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 07:456.33

1,1,1-Trichloroethane Peak Integrated Incorrectly gordonk 06/28/13 07:456.89

8260B

07/30/2013Page 9 of 4260

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP3 76109

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/4

3062805.D06/28/13 07:32 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:471.76

1,1-Dichloroethene Peak Integrated Incorrectly gordonk 06/28/13 07:483.73

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly gordonk 06/28/13 07:473.81

Acetone Peak Integrated Incorrectly gordonk 06/28/13 07:483.85

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 07:486.33

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-76109/5

3062806.D06/28/13 07:58 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 06/28/13 07:593.87

Iodomethane Peak Integrated Incorrectly gordonk 06/28/13 08:003.95

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/6

3062807.D06/28/13 08:20 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 06/28/13 08:363.86

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 08:376.33

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/7

3062808.D06/28/13 08:46 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly gordonk 06/28/13 08:533.59

Acetone Peak Integrated Incorrectly gordonk 06/28/13 08:533.86

07/30/2013Page 10 of 4260

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP3 76109

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/8

3062809.D06/28/13 09:11 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 06/28/13 09:173.86

07/30/2013Page 11 of 4260

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP3 77063

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 #20130941 AMENDED COMPOSITE B

3071106.D07/11/13 06:56 GC Column: DB-624 ID: 0.18(mm)

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 07/11/13 07:006.33

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 MS #20130941 AMENDED COMPOSITE B MS

3071108.D07/11/13 07:42 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly gordonk 07/11/13 07:453.59

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 MSD #20130941 AMENDED COMPOSITE B MSD

3071110.D07/11/13 08:30 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly gordonk 07/11/13 08:343.58

Acetone Peak Integrated Incorrectly gordonk 07/11/13 08:333.85

07/30/2013Page 12 of 4260

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP3 77100

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-6 RA #20130947 AMENDED COMPOSITE H RA

3071017.D07/10/13 11:59 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly gordonk 07/11/13 04:144.07

07/30/2013Page 13 of 4260

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP7 76932

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/2

7070904.D07/09/13 01:35 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:011.96

Chloromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:011.99

1,3-Butadiene Peak Integrated Incorrectly zukowskim 07/09/13 02:072.19

Bromomethane Peak Integrated Incorrectly zukowskim 07/09/13 02:022.47

Chloroethane Peak Integrated Incorrectly zukowskim 07/09/13 02:022.59

Dichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:032.85

Trichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:032.90

Ethyl ether Peak Integrated Incorrectly zukowskim 07/09/13 02:083.38

1,1-Dichloroethene Peak Integrated Incorrectly zukowskim 07/09/13 02:043.54

Acrolein Peak Integrated Incorrectly zukowskim 07/09/13 02:083.54

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly zukowskim 07/09/13 02:033.66

Iodomethane Peak Integrated Incorrectly zukowskim 07/09/13 02:083.77

Acetone Peak Integrated Incorrectly zukowskim 07/09/13 02:053.84

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 04:573.85

Allyl chloride Unspecified zukowskim 07/09/13 04:564.00

Methylene Chloride Peak Integrated Incorrectly zukowskim 07/09/13 02:054.36 trans-1,2-Dichloroethene Peak Integrated Incorrectly zukowskim 07/09/13 02:054.75

Acrylonitrile Peak Integrated Incorrectly zukowskim 07/09/13 02:084.81 tert-Butyl alcohol Peak Integrated Incorrectly zukowskim 07/09/13 02:084.88

Vinyl acetate Peak Integrated Incorrectly zukowskim 07/09/13 02:095.50

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 02:066.18

Dioxane-d8 (IS) Peak Integrated Incorrectly zukowskim 07/09/13 02:018.14

07/30/2013Page 14 of 4260

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP7 76932

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/3

7070905.D07/09/13 02:02 GC Column: DB-624 ID: 0.18(mm)

Bromomethane Peak Integrated Incorrectly zukowskim 07/09/13 02:282.51

Chloroethane Peak Integrated Incorrectly zukowskim 07/09/13 02:292.61

Dichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:292.89

Trichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:292.91

Ethyl ether Peak Integrated Incorrectly zukowskim 07/09/13 02:333.35

Acrolein Peak Integrated Incorrectly zukowskim 07/09/13 02:333.53

1,1-Dichloroethene Peak Integrated Incorrectly zukowskim 07/09/13 02:293.55

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly zukowskim 07/09/13 02:293.65

Acetone Peak Integrated Incorrectly zukowskim 07/09/13 02:303.77

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 04:583.84

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 04:574.16

Methylene Chloride Peak Integrated Incorrectly zukowskim 07/09/13 02:304.38 trans-1,2-Dichloroethene Peak Integrated Incorrectly zukowskim 07/09/13 02:304.75

Acrylonitrile Peak Integrated Incorrectly zukowskim 07/09/13 02:334.79

MTBE Peak Integrated Incorrectly zukowskim 07/09/13 02:314.87

Hexane Peak Integrated Incorrectly zukowskim 07/09/13 02:345.17

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 02:316.17

07/30/2013Page 15 of 4260

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP7 76932

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/4

7070906.D07/09/13 02:27 GC Column: DB-624 ID: 0.18(mm)

Bromomethane Peak Integrated Incorrectly zukowskim 07/09/13 03:322.48

Chloroethane Peak Integrated Incorrectly zukowskim 07/09/13 03:322.60

Trichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 03:332.90

Ethyl ether Peak Integrated Incorrectly zukowskim 07/09/13 03:343.37

Acrolein Peak Integrated Incorrectly zukowskim 07/09/13 03:353.52

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly zukowskim 07/09/13 03:333.62

Acetone Peak Integrated Incorrectly zukowskim 07/09/13 03:343.80

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 04:583.83

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 04:584.12

Acrylonitrile Peak Integrated Incorrectly zukowskim 07/09/13 03:344.80 tert-Butyl alcohol Peak Integrated Incorrectly zukowskim 07/09/13 03:354.85

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 03:346.20

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-76932/5

7070907.D07/09/13 02:56 GC Column: DB-624 ID: 0.18(mm)

Chloromethane Peak Integrated Incorrectly zukowskim 07/09/13 03:352.01

Bromomethane Peak Integrated Incorrectly zukowskim 07/09/13 03:362.50

Chloroethane Peak Integrated Incorrectly zukowskim 07/09/13 03:362.60

Dichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 03:372.89

Acrolein Peak Integrated Incorrectly zukowskim 07/09/13 03:373.51

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 04:593.83

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 04:594.15

Acrylonitrile Peak Integrated Incorrectly zukowskim 07/09/13 03:374.80 tert-Butyl alcohol Peak Integrated Incorrectly zukowskim 07/09/13 03:384.88

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 03:376.20

07/30/2013Page 16 of 4260

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP7 76932

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/6

7070908.D07/09/13 03:23 GC Column: DB-624 ID: 0.18(mm)

Bromomethane Peak Integrated Incorrectly zukowskim 07/09/13 04:332.49

Ethyl ether Peak Integrated Incorrectly zukowskim 07/09/13 04:373.39

Acrolein Peak Integrated Incorrectly zukowskim 07/09/13 04:373.51

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 04:593.84

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 05:004.14

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 04:356.19

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/7

7070909.D07/09/13 03:52 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 04:391.96

Vinyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 04:392.19

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 05:003.85

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 05:004.15

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 04:406.18

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/8

7070910.D07/09/13 04:36 GC Column: DB-624 ID: 0.18(mm)

Dichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 05:042.87

Acetone Peak Integrated Incorrectly zukowskim 07/09/13 05:053.81

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 05:053.81

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 05:074.13

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 05:066.18

07/30/2013Page 17 of 4260

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP7 77779

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCVIS 180-77779/2

7071802.D07/18/13 07:51 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly journetp 07/18/13 08:363.92

Allyl chloride Peak Integrated Incorrectly journetp 07/18/13 08:374.11

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LB 180-77265/6-A

7071804.D07/18/13 09:24 GC Column: DB-624 ID: 0.18(mm)

Methylene Chloride Peak Integrated Incorrectly journetp 07/18/13 09:584.45

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 #20130941 AMENDED COMPOSITE B

7071808.D07/18/13 11:11 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly journetp 07/18/13 14:213.76

Carbon disulfide Peak Integrated Incorrectly journetp 07/18/13 13:543.96

Methylene Chloride Peak Integrated Incorrectly journetp 07/18/13 13:554.44

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LCS 180-77779/5

7071810.D07/18/13 12:18 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly journetp 07/18/13 13:563.49

Carbon disulfide Peak Integrated Incorrectly journetp 07/18/13 13:453.87

07/30/2013Page 18 of 4260

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:HP7 77779

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 MS #20130941 AMENDED COMPOSITE B MS

7071811.D07/18/13 12:45 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly journetp 07/18/13 13:453.86

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 MSD #20130941 AMENDED COMPOSITE B MSD

7071812.D07/18/13 13:13 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly journetp 07/18/13 13:463.86

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-5 #20130942 AMENDED COMPOSITE C

7071819.D07/18/13 16:14 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly journetp 07/18/13 17:123.73

Methylene Chloride Peak Integrated Incorrectly journetp 07/18/13 17:134.39 tert-Butyl alcohol Peak Integrated Incorrectly journetp 07/18/13 17:174.67

Dioxane-d8 (IS) Peak Integrated Incorrectly journetp 07/18/13 17:198.12

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-6 #20130947 AMENDED COMPOSITE H

7071820.D07/18/13 16:40 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly journetp 07/18/13 17:153.93

Methylene Chloride Peak Integrated Incorrectly journetp 07/18/13 17:154.43 tert-Butyl alcohol Peak Integrated Incorrectly journetp 07/18/13 17:164.67

Dioxane-d8 (IS) Peak Identified Incorrectly journetp 07/18/13 17:188.13

07/30/2013Page 19 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:71 77297

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/3

S07110C1.D07/11/13 21:05 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Peak Integrated Incorrectly bungardf 07/11/13 21:471.80

N-Nitrosodimethylamine Peak Integrated Incorrectly bungardf 07/11/13 21:472.46

Isophorone Peak Integrated Incorrectly bungardf 07/11/13 21:477.08

2-Nitrophenol Peak Integrated Incorrectly bungardf 07/11/13 21:477.17

4-Nitrophenol Peak Integrated Incorrectly bungardf 07/11/13 21:489.23

2-Naphthylamine Peak Integrated Incorrectly bungardf 07/11/13 21:489.49

4-Nitroaniline Peak Integrated Incorrectly bungardf 07/11/13 21:489.66

4,6-Dinitro-2-methylphenol Peak Integrated Incorrectly bungardf 07/11/13 21:489.69

2,4,6-Tribromophenol Peak Integrated Incorrectly bungardf 07/11/13 21:499.89

Atrazine Peak Integrated Incorrectly bungardf 07/11/13 21:4810.22

Di-n-butyl phthalate Peak Integrated Incorrectly bungardf 07/11/13 21:4811.06

Benzidine Peak Integrated Incorrectly bungardf 07/11/13 21:4912.01

3,3'-Dichlorobenzidine Peak Integrated Incorrectly bungardf 07/11/13 21:4914.03

Bis(2-ethylhexyl) phthalate Peak Integrated Incorrectly bungardf 07/11/13 21:4914.07

Di-n-octyl phthalate Peak Integrated Incorrectly bungardf 07/11/13 21:4915.38

Benzo[a]pyrene Peak Integrated Incorrectly bungardf 07/11/13 21:4916.98

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/11/13 21:4919.35

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/11/13 21:4919.38

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/11/13 21:4919.96

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/4

S07110C2.D07/11/13 21:31 GC Column: Rxi-5SilMS ID: 0.32(mm)

Di-n-octyl phthalate Peak Not Found bungardf 07/11/13 22:0615.38

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/11/13 22:0616.33

8270C

07/30/2013Page 20 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:71 77297

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/5

S07110C3.D07/11/13 21:58 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/11/13 22:222.53

Benzoic acid Peak Integrated Incorrectly bungardf 07/11/13 22:227.23

Di-n-octyl phthalate Peak Integrated Incorrectly bungardf 07/11/13 22:2315.39

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-77297/6

S07110C4.D07/11/13 22:24 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/11/13 22:522.51

Benzoic acid Peak Integrated Incorrectly bungardf 07/11/13 22:537.25

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/11/13 22:5310.36

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/7

S07110C5.D07/11/13 22:51 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzoic acid Peak Integrated Incorrectly bungardf 07/14/13 21:187.27

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/14/13 21:1810.36

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/8

S07110C6.D07/11/13 23:17 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/14/13 21:192.50

Benzoic acid Peak Integrated Incorrectly bungardf 07/14/13 21:207.29

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/14/13 21:2010.36

07/30/2013Page 21 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:71 77297

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/9

S07110C7.D07/11/13 23:44 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/14/13 21:212.50

Benzoic acid Peak Integrated Incorrectly bungardf 07/14/13 21:227.31

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/14/13 21:2210.36

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/10

S07110C8.D07/12/13 00:10 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/14/13 21:232.49

Benzoic acid Peak Integrated Incorrectly bungardf 07/14/13 21:247.32

07/30/2013Page 22 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:71 77550

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCVIS 180-77550/19

S07150C1.D07/16/13 01:19 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzoic acid Peak Integrated Incorrectly bungardf 07/16/13 01:447.26

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/16/13 01:4210.36

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LCS 180-77168/2-A

S0715002.D07/16/13 02:37 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/16/13 03:042.52 bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/16/13 03:046.57

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-1 #20130919 COMPOSITE B

S0715009.D07/16/13 05:44 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/17/13 01:0016.34

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/17/13 01:0019.96

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-1 MS #20130919 COMPOSITE B MS

S0715010.D07/16/13 06:11 GC Column: Rxi-5SilMS ID: 0.32(mm) bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/17/13 01:026.57

Benzidine Peak Integrated Incorrectly bungardf 07/17/13 01:0312.01

07/30/2013Page 23 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:71 77550

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-1 MSD #20130919 COMPOSITE B MSD

S0715011.D07/16/13 06:38 GC Column: Rxi-5SilMS ID: 0.32(mm) bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/17/13 01:046.57

Benzidine Peak Integrated Incorrectly bungardf 07/17/13 01:0412.01

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-2 #20130920 COMPOSITE C

S0715012.D07/16/13 07:04 GC Column: Rxi-5SilMS ID: 0.32(mm)

Methylphenol, 3 & 4 Peak Integrated Incorrectly bungardf 07/17/13 01:056.69

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/17/13 01:0616.32

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/17/13 01:0619.34

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/17/13 01:0619.37

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-3 #20130925 COMPOSITE H

S0715013.D07/16/13 07:31 GC Column: Rxi-5SilMS ID: 0.32(mm)

Fluorene Peak Integrated Incorrectly bungardf 07/17/13 01:079.67

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/17/13 01:0819.38

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/17/13 01:0819.97

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 #20130941 AMENDED COMPOSITE B

S0715014.D07/16/13 07:58 GC Column: Rxi-5SilMS ID: 0.32(mm)

2,4,6-Tribromophenol Unspecified bungardf 07/17/13 01:109.90

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/17/13 01:0919.34

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/17/13 01:1019.97

07/30/2013Page 24 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:71 77550

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 MS #20130941 AMENDED COMPOSITE B MS

S0715015.D07/16/13 08:25 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/17/13 01:102.54 bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/17/13 01:106.57

Benzidine Peak Integrated Incorrectly bungardf 07/17/13 01:1112.01

3,3'-Dichlorobenzidine Peak Integrated Incorrectly bungardf 07/17/13 01:1114.03

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 MSD #20130941 AMENDED COMPOSITE B MSD

S0715016.D07/16/13 08:51 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/17/13 01:122.53 bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/17/13 01:126.57

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-5 #20130942 AMENDED COMPOSITE C

S0715017.D07/16/13 09:18 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/17/13 01:1416.34

Benzo[a]pyrene Peak Integrated Incorrectly bungardf 07/17/13 01:1416.98

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/17/13 01:1419.35

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/17/13 01:1419.97

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-6 #20130947 AMENDED COMPOSITE H

S0715018.D07/16/13 09:45 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[a]pyrene Peak Integrated Incorrectly bungardf 07/17/13 01:1516.97

07/30/2013Page 25 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:732 74298

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/4

D0607IC1.D06/07/13 09:17 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Peak Not Found addisonc 06/07/13 12:141.53

N-Nitrosodimethylamine Poor Chromatography addisonc 06/07/13 12:142.10

Pyridine Poor Chromatography addisonc 06/07/13 12:142.21

Isophorone Peak Not Found addisonc 06/07/13 12:157.00

Butyl benzyl phthalate Peak Not Found addisonc 06/07/13 12:1513.39

3,3'-Dichlorobenzidine Peak Not Found addisonc 06/07/13 12:1514.39

Bis(2-ethylhexyl) phthalate Peak Not Found addisonc 06/07/13 12:1514.44

Di-n-octyl phthalate Peak Not Found addisonc 06/07/13 12:1515.76

7,12-Dimethylbenz(a)anthracene Peak Not Found addisonc 06/07/13 12:1616.60

Indeno[1,2,3-cd]pyrene Peak Not Found addisonc 06/07/13 12:1619.82

Dibenz(a,h)anthracene Peak Not Found addisonc 06/07/13 12:1619.84

Benzo[g,h,i]perylene Poor Chromatography addisonc 06/07/13 12:1620.51

07/30/2013Page 26 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:732 74298

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/5

D0607IC2.D06/07/13 10:39 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Poor Chromatography piccolino v

06/10/13 08:221.52

Pyridine Peak Not Found addisonc 06/07/13 12:162.17

Benzoic acid Poor Chromatography addisonc 06/07/13 12:167.17

3,3'-Dichlorobenzidine Poor Chromatography piccolino v

06/10/13 08:2314.39

Chrysene Poor Chromatography piccolino v

06/10/13 08:2414.52

Benzo[k]fluoranthene Poor Chromatography piccolino v

06/10/13 08:2416.67

Benzo[a]pyrene Poor Chromatography addisonc 06/07/13 12:1717.28

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 06/07/13 12:1719.81

Dibenz(a,h)anthracene Poor Chromatography addisonc 06/07/13 12:1719.85

Benzo[g,h,i]perylene Poor Chromatography addisonc 06/07/13 12:1720.51

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/6

D0607IC3.D06/07/13 11:06 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 12:182.15

Benzoic acid Poor Chromatography addisonc 06/07/13 12:187.18

2,3,4,6-Tetrachlorophenol Poor Chromatography piccolino v

06/10/13 08:259.51

Pentachlorophenol Poor Chromatography addisonc 06/07/13 12:1910.46

Chrysene-d12 Poor Chromatography addisonc 06/07/13 12:1814.48

7,12-Dimethylbenz(a)anthracene Poor Chromatography addisonc 06/07/13 12:1916.59

Benzo[k]fluoranthene Poor Chromatography piccolino v

06/10/13 08:2516.67

Dibenz(a,h)anthracene Poor Chromatography piccolino v

06/10/13 08:2519.85

Benzo[g,h,i]perylene Poor Chromatography addisonc 06/07/13 12:1920.50

07/30/2013Page 27 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:732 74298

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-74298/7

D0607IC4.D06/07/13 11:33 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 12:092.17

Benzoic acid Poor Chromatography addisonc 06/07/13 12:107.20

2,3,4,6-Tetrachlorophenol Poor Chromatography piccolino v

06/10/13 08:269.51

2-Naphthylamine Poor Chromatography piccolino v

06/10/13 08:269.54

Pentachlorophenol Poor Chromatography addisonc 06/07/13 12:1110.46

Benzo[k]fluoranthene Poor Chromatography piccolino v

06/10/13 08:2716.66

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 06/07/13 12:1119.81

Dibenz(a,h)anthracene Poor Chromatography piccolino v

06/10/13 08:2719.84

Benzo[g,h,i]perylene Poor Chromatography piccolino v

06/10/13 08:2720.50

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/8

D0607IC5.D06/07/13 12:01 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 12:422.17

Benzoic acid Poor Chromatography addisonc 06/07/13 12:437.22

Pentachlorophenol Poor Chromatography addisonc 06/07/13 12:4310.46

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 06/07/13 12:4419.80

Dibenz(a,h)anthracene Poor Chromatography addisonc 06/07/13 12:4419.86

07/30/2013Page 28 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:732 74298

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/9

D0607IC6.D06/07/13 12:28 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 13:062.16

Benzoic acid Poor Chromatography addisonc 06/07/13 13:067.25

Pentachlorophenol Poor Chromatography addisonc 06/07/13 13:0710.46

Chrysene-d12 Poor Chromatography addisonc 06/07/13 13:0514.48

Benzo[a]pyrene Poor Chromatography addisonc 06/07/13 13:0717.30

Perylene-d12 Poor Chromatography addisonc 06/07/13 13:0617.40

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/10

D0607IC7.D06/07/13 12:56 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 14:162.15

Benzoic acid Poor Chromatography addisonc 06/07/13 14:177.26

Pentachlorophenol Poor Chromatography addisonc 06/07/13 14:1710.46

Perylene-d12 Poor Chromatography addisonc 06/07/13 14:1617.41

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 06/07/13 14:1719.84

Dibenz(a,h)anthracene Poor Chromatography addisonc 06/07/13 14:1819.88

07/30/2013Page 29 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:732 74298

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/11

D0607IC8.D06/07/13 13:23 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Unspecified addisonc 06/07/13 14:072.15

Benzoic acid Poor Chromatography addisonc 06/07/13 14:087.29

Pentachlorophenol Poor Chromatography addisonc 06/07/13 14:0810.46

Benzo[k]fluoranthene Poor Chromatography piccolino v

06/10/13 08:3016.69

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 06/07/13 14:0919.85

Dibenz(a,h)anthracene Poor Chromatography addisonc 06/07/13 14:0919.89

Benzo[g,h,i]perylene Poor Chromatography addisonc 06/07/13 14:0920.55

07/30/2013Page 30 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:732 77998

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCVIS 180-77998/23

D0719CC1.D07/19/13 13:54 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 07/22/13 06:012.16

Benzoic acid Poor Chromatography addisonc 07/22/13 06:017.21

Pentachlorophenol Poor Chromatography addisonc 07/22/13 06:0210.47

Perylene-d12 Poor Chromatography addisonc 07/22/13 06:0117.42

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LCS 180-77590/2-A

D0719002.D07/19/13 17:33 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 07/22/13 06:272.11 bis (2-chloroisopropyl) ether Poor Chromatography addisonc 07/22/13 06:276.44

Pentachlorophenol Poor Chromatography addisonc 07/22/13 06:2910.45

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 07/22/13 06:2919.81

Dibenz(a,h)anthracene Poor Chromatography addisonc 07/22/13 06:2919.83

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 MS #20130941 AMENDED COMPOSITE B MS

D0719007.D07/19/13 21:09 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 07/22/13 06:452.10

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 07/22/13 06:4719.81

Dibenz(a,h)anthracene Peak Not Found addisonc 07/22/13 06:4719.85

Benzo[g,h,i]perylene Poor Chromatography addisonc 07/22/13 06:4720.51

07/30/2013Page 31 of 4260

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:732 77998

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-4 MSD #20130941 AMENDED COMPOSITE B MSD

D0719008.D07/19/13 21:36 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 07/22/13 06:482.11

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 07/22/13 06:5019.82

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22919-6

D0719010.D07/19/13 22:30 GC Column: Rxi-5SilMS ID: 0.32(mm)

Perylene-d12 Poor Chromatography addisonc 07/22/13 06:5217.39

07/30/2013Page 32 of 4260

PESTICIDES MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:GC15 77728

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCV 180-77728/24

BQ07130000386.D07/17/13 18:17 GC Column: MR-2 ID: 0.53(mm)

Endrin Baseline Event eppinged 07/18/13 10:117.13

4,4'-DDD Baseline Event eppinged 07/18/13 10:117.23

8081A

07/30/2013Page 33 of 4260

PCBS MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:GC8 77773

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77773/1

O0730500.D07/15/13 14:31 GC Column: RTX-50 ID: 0.53(mm)

Aroclor-1221 Unspecified guptaa 07/16/13 09:24

PCB-1221 Peak 1 Unspecified guptaa 07/16/13 09:247.61

PCB-1221 Peak 2 Unspecified guptaa 07/16/13 09:247.86

PCB-1221 Peak 3 Unspecified guptaa 07/16/13 09:247.93

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77773/3

O0730502.D07/15/13 15:41 GC Column: RTX-50 ID: 0.53(mm)

Aroclor-1221 Poor Chromatography guptaa 07/16/13 09:24

PCB-1221 Peak 1 Poor Chromatography guptaa 07/16/13 09:247.62

PCB-1221 Peak 2 Poor Chromatography guptaa 07/16/13 09:247.84

PCB-1221 Peak 3 Poor Chromatography guptaa 07/16/13 09:247.94

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77773/4

O0730503.D07/15/13 16:16 GC Column: RTX-50 ID: 0.53(mm)

Aroclor-1221 Poor Chromatography guptaa 07/16/13 09:25

PCB-1221 Peak 1 Poor Chromatography guptaa 07/16/13 09:257.62

PCB-1221 Peak 2 Poor Chromatography guptaa 07/16/13 09:257.84

PCB-1221 Peak 3 Poor Chromatography guptaa 07/16/13 09:257.94

07/30/2013Page 34 of 4260

PCBS MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:GC8 77773

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77773/5

O0730504.D07/15/13 16:51 GC Column: RTX-50 ID: 0.53(mm)

Aroclor-1221 Poor Chromatography guptaa 07/16/13 09:25

PCB-1221 Peak 1 Poor Chromatography guptaa 07/16/13 09:257.62

PCB-1221 Peak 2 Poor Chromatography guptaa 07/16/13 09:257.84

PCB-1221 Peak 3 Poor Chromatography guptaa 07/16/13 09:257.94

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77773/11

O0730510.D07/15/13 20:22 GC Column: RTX-50 ID: 0.53(mm)

Aroclor-1248 Poor Chromatography guptaa 07/16/13 09:40

PCB-1248 Peak 1 Poor Chromatography guptaa 07/16/13 09:4010.93

PCB-1248 Peak 2 Poor Chromatography guptaa 07/16/13 09:4011.16

PCB-1248 Peak 3 Poor Chromatography guptaa 07/16/13 09:4011.42

PCB-1248 Peak 4 Poor Chromatography guptaa 07/16/13 09:4011.81

PCB-1248 Peak 5 Poor Chromatography guptaa 07/16/13 09:4013.22

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77773/13

O0730512.D07/15/13 21:32 GC Column: RTX-50 ID: 0.53(mm)

Aroclor-1248 Poor Chromatography guptaa 07/16/13 09:41

PCB-1248 Peak 1 Poor Chromatography guptaa 07/16/13 09:4110.93

PCB-1248 Peak 2 Poor Chromatography guptaa 07/16/13 09:4111.16

PCB-1248 Peak 3 Poor Chromatography guptaa 07/16/13 09:4111.42

PCB-1248 Peak 4 Poor Chromatography guptaa 07/16/13 09:4111.81

PCB-1248 Peak 5 Poor Chromatography guptaa 07/16/13 09:4113.21

07/30/2013Page 35 of 4260

PCBS MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:GC8 77773

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77773/19

O0730518.D07/16/13 01:03 GC Column: RTX-50 ID: 0.53(mm)

DCB Decachlorobiphenyl (Surr) Poor Chromatography guptaa26.84

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77773/21

O0730520.D07/16/13 02:13 GC Column: RTX-50 ID: 0.53(mm)

DCB Decachlorobiphenyl (Surr) Poor Chromatography guptaa 07/16/13 10:0226.82

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77773/22

O0730521.D07/16/13 02:47 GC Column: RTX-50 ID: 0.53(mm)

DCB Decachlorobiphenyl (Surr) Peak Integrated Incorrectly guptaa 07/16/13 10:0126.83

07/30/2013Page 36 of 4260

PCBS MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22919-1

Instrument ID: Analysis Batch Number:GC8 78217

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYST…