Do_4_upland_sed_fulldata_vol_3_of_5.pdf

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Vol 3 of 5 p. 1229

C:\Xcalibur\Data\Dioxin\07301 3\07301 302 7/30/2013 2:44:27 PM 52607-67-03 WS+CP+CS3

RT: 25.54 - 26.47

9; Q

Time (mm)

NL:

1.10E3 mlz= 319.3965- 320.3965

MS

07301302

Vol 3 of 5 p. 1230

C:\Xcalibur\Data\Dioxin\07301 3\07301 302

RT: 1895- 2827 SM: 5G

(0 co

100-

50-

C) (N (0 r

5 Co Co Coco

C)

NL:

1.87E3 m/z=

0 305.7990-

LU

0 305.9990

MS ICIS

07301302

- NL:

N- 1.35E4 C) m/z= co 31 5.8420-

316.0420 100-i MS ICIS

C 07301302Co

C

N- (N Co

N-LU

ci) C) C')

H t C) v- C) C) -

IQ 0- I _-i

NL:

co 1.69E4 C) C) m/z=0

317.8390- 318.0390

100_1 MS ICIS

07301302

C) Il c) C) H C) H (N N- H C)

J L

7/30/2013 2:44:27 PM 52607-67-03 WS+CP+CS3

NL:

1.49E3 mlz=(N

C) N-

LU 303.8020-

CO 304.0020

MS ICIS

07301302

(0 (N

NL:

2.19E1 m/z= 375.7364- 375.9364

MS ICIS

07301302

19 20 21 22 23 24 25 26 27 28 Time (mm) ---

Vol 3 of 5 p. 1231

C:\Xcabur\Data\Dioxin\07301 3\07301 302 7/30/2013 2:44:27 PM 52607-67-03 WS+CP+CS3

RT: 20.78 - 28.43 SM: 5G

NL:

9.98E2 mlz=

(0

0)

0) -oL()

IC)

IUU

.. - 0 co.. A MSICIS

80- A fl 07301302 ci r- o

.I i 100-

NL:

1.24E3 m/z=

0 321 .7940- N- 321.9940c.'J

MS lOIS 07301302

NL:

8.76E3 mlz= 331.8370- 332.0370 MS lOIS 07301302

H ! H C(0

20 Iu ;

0- ______________________

NL:

1.12E4 m/z-IC) N- 333.8340-

100- 334.0340

MSICIS

- A 07301302 l

ON-0

1 (000 (0 I I°

J \. -

21 22 23 24 25 26 27 28 Time (mm)

Vol 3 of 5 p. 1232

C:\Xcaiibur\Data\Dioxin\07301 3\07301 302 7/30/2013 2:44:27 PM 52607-67-03 WS+CP+CS3

RI: 2665 - 36.79 SM: 5G

C)

LU

100-

(N

C'.)

N-

LU

N- N- CO

C) (N (N (N

NL:

8.98E3 m/z= c (0 339.7600- C)

CD

CD

(N 339.9600

LU MSICIS

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A

NL:

LU 5.63E3

LU mlz=

LU

(N CD

C) 341.7570-

C'.)

LU 341.9570

100- C) LU MSICIS

07301302

50- C)fl

NL:

co C'.) 1.27E4 mlz-

0 CO

C) 351 .8000- 352.0000

MS ICIS

07301302 ci)

0 NL:

0 (0 7.94E3 (0 m/z=C') (0 3537970

353.9970

MS ICIS

07301302

50-

'I

N C')

C'.)

100-i

2.24E1 m/z= 409.6974- 409.8974 MS lOtS 07301302

27 28 29 30 31 32 33 34 35 36

Vol 3 of 5 p. 1233

C:\Xcalibur\Data\Dioxin\07301 3\07301 302

RT: 27.74 - 37.50 SM: 5G

I

c) '4.)

0)

(0 0)

7/30/2013 2:44:27 PM 52607-67-03 WS^CP+CS3

C) 0)

(0 o

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co co

NL:

4.29E3 mlz= 355.7550- 355.9550

MS ICIS

07301302

NL:

2.67E3 mlz= 357.7520-c7 Q;,)n 1 00 ..% -.. SJ.JI . SI'.dL_

I IL

8.35E3

(0 miz-

367.7950-

100- 367.9950

MSIC!S

07301302

(0 't(O (N 0

-(OC') OCN (0

co

N-

L() t NN 0

00) c) -i_li 5.08E3 mlz= 369.7920-q qq9n

100 MS ICIS

07301302 80-

60-

LU

0(N 0 0 (N

20-

LUOO

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0 iJfTfl F F r11TT 28 29 30 31 32 33 34 35 36 37

Time (mm)

0)

Vol 3 of 5 p. 1234

C:\XcaIibur\Data\Doxin\073O1 3\07301 302

RI: 37.02 - 42.45 SM: 5G

LC)

IC)

7/30/2013 2:44:27 PM 52607-67-03 WS+CP+CS3

NL:

Lx) C'iN- Co co 8.56E3

N-r - coo, m/z= N-

COQ 373.7210-

CO 373.9210

MS ICIS

07301302

CO CO c'O C'J 375 7180-

CO

375.9180 100-

JL IL

c'j CO 1.66E4

C) IC) CD

CO

CO m,z-

N- .. 385.7610-

N- 385.9610

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01302:1 o co 1.30E4

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mz-

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.. 387.9580

A A MSICIS

H A 07301302

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d fl C) J coV JL

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2.12E1 mlz= 445.6555- 445.8555

MS ICIS

07301302

Vol 3 of 5 p. 1235

C:\Xcalibur\Data\Dioxin\07301 3\07301 302 7/30/2013 2:44:27 PM

RT: 3625 - 42.67 SM: 5G

C) C) cx:

('.1

L

-o -

40- U) ci)

LU1 C)

52607-67-03 WS+CP+CS3

c.'J 0C) co

C)C) 0

CNC'J N -

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NL:

5.43E3 mlz= 389.7160- 389.9160

MS ICIS

07301302

NL:

4.38E3 mlz= 391.7130- 391 .91 30

MS ICIS

07301302

NL:

1.01E4 f L() m/z=N-C ) r L() 401.7560-

100 401.95601 MSICtS fi 07301302

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NL:

7. 84E3 mIz 403.7530- 403.9530

MS ICIS

07301302

(-'1

37 38 39 40 41 42

Vol 3 of 5 p. 1236

C:\Xcalibur\Data\Dioxin\07301 3\07301 302 7/30/2013 2:44:27 PM 526O767O3 WS+CP+CS3

RI: 42.08 - 48.50 SM: 5G

NL:

co 6.70E3 Co Co m/z=(v)

407.6818- 407.8818

MS ICIS

80H 07301302

60H

40 -

L

0) Q

1 11 Co

20 I

NL:

L() 6.38E3

Co miz= Co N- 409.6789-

100 409.8789

MS ICIS

80 07301302

40 I I 0 CoCo

C) Co Co ('4 -vCo o NL:

S Co S

Co

0)

Co mlz= 419.7220-

100 419.9220 o MS ICIS

80 07301302 St, ° o NL:

Co 0 1.15E4

Co m/z= ('4 421.7190-

100 421.9190

MS ICIS

80 A 07301302

Co

Co Co 1() c'i o "1N-co 00)

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NL:

2. 32E 1 m/z= 479.6165- 479.8165

MS ICIS

07301302

43 44 45 46 47 48

Vol 3 of 5 p. 1237

C:\Xcalibur\Data\Dioxin\07301 3\07301 302 7/30/2013 2:44:27 PM 52607-67O3 WS+CP+CS3

RT: 42.08 - 48.50 SM: 5G

100-i

80-

60-

40- -I 0

2O-

(v.)

C C (N

0) F-

0)

N- 0)

C (N

(N 1 co ce.)

-ct 0)

NL:

4.23E3 mlz= 423.6770- 423.8770

MS ICIS

07301302

(N L() (N

(N -0)

NL:

4.09E3 m/z= 425.6740- 49 74fl

100-i t_ PSI' IS 07301302

80- 1 60-

40-

20-

NL:

(N Cv) (0

LI)

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435.7170-

100- 435.9170

MSICIS

07301302

0) C

C

CD

N

LI)

C

C'-) (vS)

NL:

6.60E3 m/z= 437.7140- 437.9140

MS ICIS

07301302

0)C'-) (0 N- '- N- - (N

47 48

Vol 3 of 5 p. 1238

C:\Xcalibur\Data\Dioxin\07301 3\07301 302 7/30/2013 2:44:27 PM 52607-67-03 WS+CP+CS3

RT: 4714-51.54 SM: 5G

NL:

Q 9.11E3 0) m/z= 441.6430-

441.8430

1 MS ICIS

07301302

80-

60- A40-

NL:c) 1.02E4

('.10) mlz= 443.6400-

100- 443 8400

MS ICIS

U) 07301302 o 80- C -

60-

I) 40-

NL:

C 1.16E4

C

L() mlz= 469.6780-

1 OO-i 469 8780

MS ICIS

07301302

80-

0)

U

0)

50.5 51.0

NL:

1.30E4 mlz= 471.6750- 471.8750

MS ICIS

07301302

51.5

Vol 3 of 5 p. 1239

C:\Xcalibur\Data\Djoxin\07301 3\07301 302 7/30/2013 2:44:27 PM 52607-67-03 WS+CP+CS3

RT: 4773 - 5137 SM: 5G

NL:L()

6.78E3

c) m/z= 4576380-

I 00 4578380

MS ICIS

07301302

8O

60-

40-

20-

NL:N-.

7.42E3

1'- mlz= 459.6350-

100 459 8350 MS tCIS 07301302 o 80

60-

40-

20-

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1.16E40

LU m/z= 469.6780-

100 469 8780

MS ICIS

07301302

60-

40-

20-

0-

NL:

1.30E4

LU mlz= 471.6750-

100 471 8750

MS IC!S

07301302

60-

40-

20-

0 F F FF F 4

48.0 48.5 49.0 49.5 50.0 50.5 51.0

Vol 3 of 5 p. 1240

C:\Xcalibur\Data\Djoxjn\07301 3\07301 302

RI: 2000 - 53.00

89 186 252 392 ioo- 21.00 23.12 24.56 27.62

478 491 555 674 730 77629.63 29.92 31.33 33.97 35.21 9:

7/30/2013 2:44:27 PM 52607-67-03 WS+CP+CS3

846 932 1053 1133 100- 403 493 608 677

37.69 39.13 4116 42.50

27.97 29.96 32.51 34.04::

1181 1223 132O 1361

43.41 44.13 45.80 46.50

NL:

7.11E4 m/z=

304.48 1 80- 305.48180

MS

07301302

1.66E5 mlz= 330.47869- 331.47869

MS

07301302

NL:

1.01E5 mlz= 380.47550- 381.47550

MS

07301302

NL:

5. 86E4 m/z= 392.47550- 393.47550

MS

07301302

1398 1413 1587 1646 NL:

47.25 47.53 50.80 51.90 6.42E4

*4\mIz= 430.47231- 431.47231

MS

07301302

25 30 35 40 45 50

Vol 3 of 5 p. 1241

This page intentionally left blank.

Vol 3 of 5 p. 1242

N am e:

ix

S ed im en t pi e

R ec ei pt

D at e:

7/

/2

D at e:

7/

/2 ys is

D at e:

7/

/2 sc t V ol um e (p

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:ti on

V ol um e

(p L)

: 1 io nF ac to r:

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Vol 3 of 5 p. 1243

D D

P C D F

A N A L Y S I S

D A T A

S H E E T

L a b

N a m e

L a b

S a m p l e

I D

M a t r i x

S e d i m e n t

S a m p l e

W t V o l

S a m p l e

R e c e i p t

D a t e

I n i t i a l

C a l i b r a t i o n

D a t e

E x t

D a t e

I n s t r u m e n t

I D

A n a l y s i s

D a t e

T i m e

G C

C o l u m n

I D

E x t r a c t

V o l u m e p L

S a m p l e

D a t a

F i l e n a m e

I n j e c t i o n

V o l u m e p L

B l a n k

D a t a

F i l e n a m e

D i l u t i o n F a c t o r

C a l

V e r

D a t a

F i l e n a m e

C o n c e n t r a t i o n

U n i t s p g g d r y

C o n c e n t r a t i o n

U n i t s

C O N C

D E T E C T I O N

A N A L Y T E

F O U N D

L I M I T

I O N

R A T I O N

T E Q

L A B E L E D

C O M P O U N D S

T C D D l C T C D D

P e C D D l C P e C D D l N x C D D

C H x C D D

H x C D D l C l N x C D D

H x C D D l C l H p C D D l H p C D D l C O C D D

O C D D l C T C D F

T C D F l C l P e C D F

P e C D F l C P e C D F

P e C D F l C l N x C D F l N x C D F l C l N x C D F

N x C D F l C l H x C D F l H x C D F

C H x C D F

N x C D F

C l H p C D F

H p C D F l C l N p C D F

H p C D F

O C D F

C L E A N U P

S T A N D A R D

C l T C D D

T o t a l

T E Q

P a g e

O P R u n i t s

D F S p g

S P I K E

C O N C

C O N C

F O U N D

R

I O N

R A T I O

Vol 3 of 5 p. 1244 g e o f

F i l e n a m e:

A c q u i r e d

P r o c e s s e d

C A n a l y t e

N O

M A P P I N G

C a l

G l O A T

R e s u l t s

O P R

S a m p l e t e x t

O P R

S:

C o m m e n t s

T y p

N a m e

Q M

A r e a

R M

A r e a

R A

R T

C o n c

T o x

D L

R e c ti nk T C D F y

[i nk P e C D F y

[i nk P e C D F y

[i nk l H x C D F y

[i nk l I x C D F y

[i nk H x C D F y

[i nk l F I x C D F y

[i nk l H p C D F y

[i nk l H p C D F y

[i nk

O C D F y

[i nk

T C D D y

[i nk l P e C D D y

[i nk l N x C D D y

[i nk l H x C D D y

[i nk l H x C D D y

[i nk l H p C D D y

[i nk

O C D D y

I S S T l C T C D F y

I S l C l P e C D F y

I S l C P e C D F y

I S l C l H x C D F y

I S l C H x C D F y

I S l C H x C D F y

I S l C l N x C D F y

I S l C l H p C D F y

I S l C l H p C D F y

I S l C T C D D y

I S l C l P e C D D y

I S l C l H x C D D y

I S l C l H x C D D y

I S l C l H p C D D y

I S

C O C D D y

R S l C l T C D D y

R S R T l C l H x C D D y

C U p

C l T C D D y

T o t

T o t a l

T e t r a F u r a n s y

T o t

T o t a l

T e t r a D i o x i n s y

T o t

T o t a l

P e n t a F u r a n s y

T o t

T o t a l

P e n t a D i o x i n s y

T o t

T o t a l

H e x a F u r a n s y

T o t

T o t a l

H e x a D i o x i n s y

T o t

T o t a l

H e p t a F u r a n s y

T o t

T o t a l

H e p t a D i o x i n s y

Vol 3 of 5 p. 1245

C:\Xcalibur\Data\Dioxin\07301 3\07301 303 7/30/2013 4:10:07 PM 53720-90-20 OPR

RT: 18.95-28.27 SM: 5G / NL:

2.45E2 m/z= 303.8020-

0100: 304.002

MS CIS

80H 07301303

60 Q

40 •(NC'J co

20-

NL:

2.94E2 mlz= 305.7990-

100:

305.999

7.77E3 mlz= 315.8420- 316.0420

) 100/ A MS ICIS

80/ 07301303

L (N 0)0) N -w N- L() ()

c) C)

C) N- (0 t (N (0

N- N- - It) (N (N -

(N t (N

NL:

9.64E3 mlz= 317.8390- 318.0390

IOOT:1 A MS ICIS

NL:

2.26E1 mlz= 375.7364- 375.9364

80 07301303

073003

19 20 21 22 23 24 25 26 27 28

Vol 3 of 5 p. 1246

100-

4 c'J a)

CD

0)co

NL:

1.65E2 mlz= 319.7970- 319.9970

MS ICIS

07301303

Q LU

NL:

2.1 0E2 mlz= 321.7940- 321.9940

MS ICIS

07301303

(0 1.41E4co mlz= co 331.8370- 332.0370

NL:

1.74E4 mlz= 333.8340- 334.0340

MS CIS

07301303

21 22 23 24 25 26 27 28

Vol 3 of 5 p. 1247

C:\Xcalibur\Data\Dioxin\07301 3\07301 303

RT: 26.65 - 36.79 SM: 5G

7/30/2013 4:10:07 PM 53720-90-20 OPR

0a)

NL:

1.17E3 mlz= 339.7600- 3399600

MS ICIS

07301303

40:

NL:

7.36E2

(0 rn/z=

tt) 341.7570-

100 341.9570

NL:

N- N- 8.81E3 N-co (0 m/z=L() (0

351.8000- 3520000

MS CIS

80 07301303 -c

I40

20- -iii Q: H r c'J (0 c)

100:

NL:

N- c 5.44E3

(0 m/z= 353.7970-

7353.99 0

MS ICIS

07301303

0 IL

NL:

2.26E1

(0 -Nrn Z 409.6974- 409.8974

AMS ICIS

07301303

27 28 29 30 31 32 33 34 35 36

Vol 3 of 5 p. 1248

Co

40- ce Co i r

0)

Co

NL:

8.19E2 mlz= 355.7550- 355.9550

MS ICIS

07301303

N cO 0 10(0

(N CO (NO

NL:

5.24E2 mlz= 357.7520-

7 ciz'rn 1 00-

MS ICIS

80- 07301303

_I_ _ 6.10E3 mlz= 367.7950-

100-i 367.9950

11 MSICIS

07301303

40-

(NN-

.O)CO

Co1dCo

20- (NO) r-u•) Co

Co (N

0 0) (N Q Co

N- 0 O)N-CO

IC) N -

60-

OCoto Co IC) )(NCOto

20- - - co Co IC) N-

0jr-rnT 31 32 33 34

Time (mm)

N- (N

N- (N to to Q (Os- Co 0 Cr0 '- (0 (N-

35 36 37

3.75E3 m/z= 369.7920- 369.9920

MS CIS

07301303

Vol 3 of 5 p. 1249

RT: 37.02 - 42.45 SM: 5G

NL:

o I

1.49E3

3737210- 373.9210

100- MS ICIS

301303

JL

co 1.13E3

LO L) mlz=

UD 7 1 03 5.9 8

IL __

NL:

0 1.04E4 c) L•) L()

N -

I.() cD mlz=

IC)

cD (0 385.7610-

I00 385.9610

W 0 MS lOIS

80- 07301303

60-ci 40

20- W

NL:

0 8.13E3 C)

N-c)

(0 0 C) m/z=N- (0 C)

387.7580- 387.9580

100- MS ICIS

80- /I /\ A

07301303

60-

JVL IL!

co

C) cON- N Q cD••

C) ('4 IC)100-1c')

NL:

2.17E1 mlz= 445.6555- 445.8555

MS ICIS

07301303

37,5 38.0 38.5 39.0 39.5 40.0 40,5 41.0 41.5 42.0

Vol 3 of 5 p. 1250

C:\Xcalibur\Data\Dioxin\07301 3\07301 303 7/30/2013 4:10:07 PM 5372090-20 OPR

RT: 36.25 - 42.67 SM: 5G

/ NL:

9.76E2

\ cc mlz= rLC) çj '- 389.7160-

389.9160

MSICIS

07301303

a) o8

-o

-o ci)

Q cc

LC)

(0

NL:

7.74E2 mlz= 391.7130- 391 .9130

MS ICIS

07301303

1(

NL:

(N

1.41E4 'ci- N- m/z=

401.7560-

)0- 401.9560 MS lOIS 07301303

(0(0 cO'ci-

O)N- C)

N- t)-

(N L() (N C) N-0N-

(N

37 38 39 40 41 Time (mm) cc L()

(N cc cc

(Nc) cc

NL:

1.1 2E4 mlz= 403.7530- 403.9530 MS lOIS

Vol 3 of 5 p. 1251

1 O0

0co (0

It)

(N

100 c':-

80-

60-

NL:

1.36E3 mlz= 409.6789- 409.8789

MS CIS

07301303 i ft J L1L: j jJi ii_ .

9.70E3 mlz= 419.7220-a 100 419.9220

MSICIS

80: 07301303

60 H 40 co

20H J L

NL:

9.25E3

It) mlz= 421.7190-

100 421.9190

MSICIS

:1 07301303

L

I (0 N N- CD

2.36E1 -miz-

NL:

1.41E3 mlz= 407.6818- 407.8818

MS ICIS

07301303

Vol 3 of 5 p. 1252

100-

7/30/2013 4:10:07 PM

(N

40H H ('P) (0 H C) .H 0 L()

53720-90-20 OPR

(Nu)

NL:

9.80E2 mlz= 423.6770- 423.8770

MS ICIS

07301303

NL:

9.35E2

(N -

425.6740-

1 00-

MS ICIS

O) 07301303 o , 8u- (0 -

60-

40 0 Co

- ce.)

Co

(N Co (N

NL:0)

Co 7.09E3 (N C'.)

(1) mlz=

435.7170-

100-i 435.9170

MS ICIS

07301303

80-

0) (N(N

(-S (S-S

- Co

(N 0)

C') (0(0(0 I (N çQ

'CoC)0 Co 10 v- Co (N - (N çS)

Co C'.)

Co C'.)

(N 0 fl N -

H (-Co '.)(N 0 N- 10

I 10 - C')

0 Co

43 44 45 46 47 Time (mm)

6.48E3 mlz= 437.7140- 437.9140

MS ICIS

Vol 3 of 5 p. 1253

C:\Xcalibur\Data\Djoxjn\07301 3\07301 303 7/30/2013 4:10:07 PM 5372090-20 OPR

RI: 47.74 - 51.54 SM: 5G

NL:

/ 1.53E3 mlz= 441 .6430-

441.8430100- MS ICIS

07301303

(OO

LU

Co Co 0) N-o 0)

'- 0r- c)

NL:

1.75E3 m/z= 443.6400- AA SMnfl

100 MS ICIS

07301303 j ::

40-i0 _

NL:0)

8.70E3 mlz= 469.6780-

100- 469.8780

MS ICIS

07301303

80-

N- 0) 0 H 0

(N JL Co

-0 -

NL:

CO 9.60E3

C)LU mlz=

471.6750-

1 00- 471.8750

MS ICIS

07301303

80-

60-

40-

20-

0 F

48.0 48.5 49.0 49.5 50.0 50.5 51.0 51.5

Vol 3 of 5 p. 1254

C:\Xcalibur\Data\Ijioxin\07301 3\07301 303 7/30/2013 4:10:07 PM 53720-90-20 OPR

RT: 47.73 51.37 SM: 5G

NL:

/ 1.37E3 L) t mlz= 457.6380-

457.83801OO A MS ICIS

/\ 07301303

I

C-)

C ci)

C', ci)

C'J co

CD

NL:

1.48E3 mlz= 459.6350- 459.8350

MS ICIS

07301303

NL:

C)

8.70E3 m/z= 469.6780-

9100 46 .8780

MSICIS

07301303

NL:

L() CD 9.60E3c) IC) m/z

471.6750- 471.8750

A MS ICIS

07301303

48.0 48.5 49.0 49.5 50.0 50.5 51.0

Vol 3 of 5 p. 1255

C:\XcaHbur\Data\Dioxiri\07301 3\07301 303

RI: 20.00 - 53.00

69 114 361 39420.58 21.56 26.96 27.68I 00fk .

7/30/2013 4:10:07 PM 53720-90-20 OPR

NL:

6.85E4 m/z= 304.48180- 305.48180

MS

07301303

402 I1 b40 797

100 27.97 28.21 171 33.24 36:72

813 828 869 100 37.15 37.40 38.0

399 424 502 659 90 28.46 30.19 33.662780- .

NL:

I .54E5 mlz= 330.47869- 331.47869

MS

07301303

NL:

1154 1.01E5 42.87

1 mlz= 380.47550- 381 .47550

MS

07301303

1197 "-'-'- I)OO

A71 44.58 46.02 46.98 J. I

'-I

20 25 30 35 40 45 Time (mm)

NL:

5.92E4 mlz= 392.47550- 393.47550

MS

07301303

1596 NL:

1456 1584 50.98 6.72E4

48.36 50.76

430.4723 1- 431.47231

MS

07301303

Vol 3 of 5 p. 1256

C :\Xcalibur\Data\Dioxin\07301 3\07301 304 7/30/2013 5:13:08 PM decane blank

RT: 18.95-2827 SM: 5G

CD -

C.) (N 0 N-

CD -

C.) CD (N

N- t C.) CD Lt) c.)

C.) L

100 .

60-

20-

NL:

2.27E1 m/z=

LC) 303.8020-

304.0020

1 MS ICIS

07301304 co N- . co

'4) 0 CD

N- c) CD

100T

2OTI

0) CDoco

0) (N N-0 dC)

C.) (4 L() (NO

100T1

NL:

3.08E1

CD N- •.

L()

14) mlz= d Co N- .. 305.7990-rr / , / 07301304

NL:

CD 3.83E1

- o LOcO

CDO 0 m/z=

CD 317.8390-

LU .. r 318.0390

A I A vn A

A A .A A A <

MS JCIS

07301304

Lr

0) 0 L() CD N- CD

CD: I.c CD N- CD CD v- 0 CD

LUç.) (N (Nt

0 T IThr 1FfT

19 20 21 22 23 24 25

Time (mm)

NL:

CD 2.19E1

LU CD 0 CD mlz= C)

375.7364-

375.9364

MS ICIS

07301304

26 27 28

Vol 3 of 5 p. 1257

C :\Xcalibur\Data\Dioxin\07301 3\07301 304

N- Co

(V))

100 (0 Co

Co (0 Co (0 c.'j (.J ..

c -

7/30/2013 5:13:08 PM decane blank

NL:

2.63E1 m/z= co 319 7970-.

319.9970

073004

NL:

co C) Q mlz= C) C) f -co ' o C')

N-N- 321.7940- , i

C'4 C') (0 C')

1 1

NL:

4.03E1

C') m/z= 333.8340- 334.0340

MSICS

I 07301304\ LjLI;L/\ jI. .

21 22 23 24 25 26 27 28

Vol 3 of 5 p. 1258

C:\Xcalibur\Data\Dioxin\073013\07301304 7/30/2013 5:13:08 PM decane blank

CD

P

CD - C)

Cv.)

NL:

2.49E1 mlz=IC) 339.7600- 339.9600

MSICIS

07301304

CD

100W

40-

20-

NL:

2.95E1

IC) ('4 . CD

CC) _ N. N.CNCDOCD'ct mlz=

IC) N. (D CO ('4 CD c Q 341.7570-

D CC) CO N. C') N. N. °'

341 9570

MSICIS

. . - 07301304

NL:

4.73E1 mlz= 351 .8000-

100-

0730 1304J j J\J

NL:

3.36E1 mlz= 353.7970-

E1

0) C'4 409 6974-.

I I I F F r F F F

27 28 29 30 31 32 33 34 35 36

Vol 3 of 5 p. 1259

C:\Xcalibur\Data\Dioxin\07301 3\07301 304 7/30/2013 5:13:08 PM decane blank

0) '- (0 U

100.1

NL:

ro r- 268E1 mlz= 355 7550-(

.. •. •.•• t0)

355.9550

A 073004

2.54E1 C\J C, Co CO

N- C m/z 369 7920-

CO Lt) (\ t.)

1 I\ A A

MSICIS

07301304

28 29 30 31 32 33 34 35 36 37

Vol 3 of 5 p. 1260

C:\Xcalibur\Data\Dioxin\07301 3\07301 304 c4

c) 9o (0 ()

H j.

/\R A

100-T o)

7/30/2013 5:13:08 PM decane blank

C (0

0) I.')

N -c)

<C

C Ac)

NL:

3.15E1 mlz= 373.7210- 373.9210

MSICIS

1\AA

07301304

NL:

8.22E1

IC)

(N cp 100-c_)

L:flJ JjL 8.06E1 m/z= 387.7580-

60-

20 L:

2,12E1 mlz=

445.6555-

37.5 38.0 38.5 39.0 39.5 40.0 40.5 41.0 41.5 42.0

Vol 3 of 5 p. 1261

C:\Xcalibur\Data\Dioxjn\073013\07301 304 7/30/2013 5:13:08 PM decane blank

RT : 3625 - 42.67 SM: 5G

NL:

335E1 rT;/z= 389.7160-

° 389.9160 m/z= Co 391 .7130

100 391.9130

c) MSICIS

I 2:

NL:

1.11E2 mlz= 401.7560-

100 401.9560

MS ICIS

07301304 u'J_J 0)11)

-CN

co

4-l

20-

(Dc0

(N N -

37 38

C) aD

39 40 Time (mm)

C (N 'a-

0)03

A

41 42

NL:

8.58E1 m/z 403.7530- 403.9530

MS ICIS

07301304

(0

IC)

Vol 3 of 5 p. 1262

NL:

3.73E1

N- m/z= 407.6818-

1 0 407.8818I

07301304

4.42E1 mlz= 409.6789- 409.8789

01304:

8.1 4E1 to m/z= 419,7220-

,100 _ 419.9220

8.79E1 m/z= 421.7190- 421.9190

2.29E1

479.6165-

80 - 07301304

60i

0 , r1rrr1 rr rrr r J

43 44 45 46 47 48

Vol 3 of 5 p. 1263

L) c'4

C)

LU

7/30/2013 5:13:08 PM

N- N-

N-

0)co

LU

decane blank

Co

CO C•'

r 'cr

'- LU

CN

NL:

3.72E1 m/z= 423.6770- 423.8770

MS ICIS

07301304

NL:

3.84E1 mlz= 425.6740- N)c 7An

: !i ]J 4 .&L

NL:

7.37E1

(N m/z= 435.7170-

100- 435.9170 i MS ICISE 07301304

60-

- (N - - ..

0) LU CO

40i

0 -

NL:

5.29E1

C)

0) m/z=

437.7140-

100 437.9140

A MSICIS

H 07301304 80 0

60-i CO

A A A

43 44 45 46 47 48

Vol 3 of 5 p. 1264

RT: 47.74-51.54 SM: 5G

('1 N -co co

NL:

4.80E1 mlz= 441.6430- 441.8430

MS ICS

07301304

NL:

5.29E1 mlz= 443.6400-dL1 SAflfl

100-

NL:

1.27E2 mlz=

100-1

30°4LL

NL:

1.38E2 m/z= 471 .6750-

100 471.8750

MSICIS

07301304

'-I"

40N iN-

0F 11FfF T flT F F T1TJ

48.0 48.5 49.0 49.5 50.0 50.5 51.0 51.5

Vol 3 of 5 p. 1265

C:\Xcalibur\Data\Dioxjn\073013\07301304 7/30/2013 5:13:08 PM decane blank

RT: 47.73 - 51,37 SM: 5G

NL:

4.69E1

Q mlz= 457.6380- 457.838010O

A MS ICIS

07301304

NL:

4.62E1 mlz= 459.6350- 459.8350

NL:

1.27E2 cD LU m/z=

469.6780-

100 469.8780

A 07301304

LU

Co

0I

NL:

1.38E2 m/z= 471.6750- 471.8750

100-i A MS ICIS 07301304

48.0 48.5 49.0 49.5 50.0 50.5 51.0 Time (miri)

Vol 3 of 5 p. 1266

RT: 20.00 - 53.00

164 264 385

22.65 24.84 27.48 I 0- ...A

7/30/2013 5:13:08 PM decane blank

398 408 430 670 735 800 NL:

100- 27.88 28.10 28.59 33.90 35.34 36.78 1.56E5 ii mlz= 330.47869-

80 331 .47869

MS

60 07301304

813 845 1037 1138 1161 NL:

100 37.15 37.68 40.91 42.60 42.99 1.01E5

28.05 31.33 33.95 mlz=

-: ii

406 554 672

60-

40-co 20-h

20 25 30 35 40 45 Time (mm)

380.47550- 381.47550

MS

07301304

1167 ILO

43.19 44.92 46.55

NL:

6.89E4 mlz= 304.48180- 305.48180

MS

07301304

6.23E4 mlz= 392.47550- 393.47550

MS

07301304

1429 1456 1571 NL:

47.85 48.36 50.52 6.62E4

430.47231- 431.47231

MS

07301304

Vol 3 of 5 p. 1267

Vol 3 of 5 p. 1268 b

N a m e

M a t r i x

S a m p l e

R e c e i p t

D a t e

E x t

D a t e

A n a l y s i s

D a t e

E x t r a c t

V o l u m e p L

I n j e c t i o n

V o l u m e p L

D i l u t i o n F a c t o r

C o n c e n t r a t i o n

U n i t s

A N A L Y T E

T C D D l P e C D D l H x C D D l H x C D D l H x C D D l H p C D D

O C D D

T C D F l P e C D F

P e C D F

H x C D F

H x C D F

H x C D F

H x C D F

H p C

D R

H p C D F

O C D F

T o t a l

T E Q

S e d i m e n t

T i m e

1 1 p g g d r y

C O N C

F O U N D n d n d n d n d n d

S n d n d n d n d n d n d n d n d n d

P C D D

P C D F

A N A L Y S I S

D A T A

S H E E T

L a b

S a m p l e

I D

M B

S a m p l e

W t V o l u n i t s g m

I n i t i a l

C a l i b r a t i o n

D a t e

I n s t r u m e n t

I D

D F S

C C

C o l u m n

I D m

Z B

S a m p l e

D a t a

F i l e n a m e

B l a n k

D a t a

F i l e n a m e

C a l

V e r

D a t a

F i l e n a m e

C o n c e n t r a t i o n

U n i t s p g

D E T E C T

I O N

L I M I T

I O N

R A T I O N

T E Q

L A B E L E D

C O M P O U N D S n d l C T C D D n d l C l P e C D D n d l C l H x C D D n d l C H x C D D n d l C H p C D D l C O C D D l C T C D F n d l C l P e C D F n d l C P e C D F n d l C l H x C D F n d l C l H x C D F n d l C l H x C D F n d l C H x C D F n d l C l H p C D F n d l C l N p C D F n d

C L E A N U P

S T A N D A R D

C l T C D D

P a g e o f

S P I K E

C O N C

C O N C

F O U N D

R

I O N

R A T I O

L l V

Vol 3 of 5 p. 1269 q e o f

F i l e n a m e:

A c q u i r e d

P r o c e s s e d

/2

J /2

O

A n a l y t e

N O

N A P P I N G

C al

D

T C

O T

R e s u l t s

N B

S a m p l e t e x t

N B

S:

C o m m e n t s

T y p

N a m e

Q M

A r e a

R N

A r e a

R A

R T

C o n c

T o x

D L

N e c

O n k

T C D F n n d n d

U n k

P e C D F n n d n d

U n k

P e C D F n n d n d

U n k l H x C D F n n d n d

U n k

H x C D F n n d n d

U n k

H x C D F n n d n d

U n k l H x C D F n n d n d

U n k

N p C D F n n d n d

U n k

H p C D F n n d n d

U n k

O C D F y

U n k

T C D D n n d n d

U n k l P e C D D n n d n d

U n k

H x C D D n n d n d

U n k l H x C D D n m d n d

U n k l H x C D D n n d m d ti nk l N p C D D y

U n k

O C D D y

I S N T l C T C D F y

I S

C P e C D F y

I S

C P e C D F y

I S

C H x C D F y

I S

C H x C D F y

I S

C N x C D F y

I S l C l H x C D F y

I S l C l H p C D F y

I S l C l H p C D F y

I S l C T C D D y

I S

C P e C D D y

I S

C H x C D D y

I S l C N x C D D y

I S

C N p C D D y

I S l C O C D D y

R S l C l T C D D y

R S R T l C l N x C D D y

C O p

C l T C D D y

T o t

T o ta l T e tr a -F u ra n s n

T o t T o ta l T e tr a -D io x in s n

T o t

T o t a l

P e n t a F u r a n s y

T o t

T o t a l

P e n t a D i o x i n s y

T o t

T o t a l

N e x a F u r a n s y

T o t

T o t a l

N e x a D i o x i n s n

T o t

T o t a l

H e p t a F u r a n s y

T o t

T o t a l

H e p t a D i o x i n s y

Vol 3 of 5 p. 1270

C:\Xcalibur\Data\Dioxin\07301 3\07301 305

RT: 1895 - 28.27 SM: 5G

co 0) (vU)

7/30/2013 6:16:19 PM

c) C C Co C C' N CD CO Co

53720-85-21 MB

CO

L() N -

(0 0)1.0 (oN-ioco cr

NL:

2.68E1

C m/z= g 303.8020- N 304.0020

MSICIS

07301305

NL:

2.75E3 mlz= 315.8420- 316.0420

4 MS ICIS

80: 07301305

- CO CO 0) N (0 t Lt) C' 0) CO C - CO CO

1. LC) 0) LO co COCO

a) -J C - N LC) co C - C.') N- C.') C.') - N- CO C.') CD CO 0)

NL:

3.47E3 mlz= 317.8390-

18 039 100 4

3 . 0

MS ICIS

80- / 07301305

C LI)

0)

0)N LU v' NC.')

LI') N NN

19 20

Co

0)

NL:

LI') 2.24E1

I' LC) (01.0 m/z=

375.7364-

07301305

22 23 24 25 26 27 28

Vol 3 of 5 p. 1271

C:\XcaIibur\Data\Dioxn\07301 3\07301 305

N-

CD

C) C) CD

N-.

CD -

10011 < -1

7/30/2013 6:16:19 PM 53720-85-21 MB

- N- CD

Lo

QN-

CD

- C)

.. c)

4c) odCD co

CDCD

NL:

3.01 El

mlz= 319.7970- 319.9970

MS ICIS

07301305

NL:

to 2.90E1 co miz-

CD N-

321.7940 0 - 321.9940

Fio

CD

C)

N- ('4 - Q t 0 f ('4 CD tN c) CD c (

C') r r r r r to)

C) C)

N.

21 22 23 24 25 Time (mm)

) C') to) to) r CD N - ? c'3 .'4-- ('4

]Ff:H HF

NL:

1.92E4 m/z= 333.8340- 334.0340 MS lOIS 07301305

Vol 3 of 5 p. 1272

RI: 2665 - 36.79 SM: 5G

(N (N L()

100-i

7/30/2013 6:16:19 PM

(0 C) co co C)

53720-85-21 MB

NL:

2 .7 1 El mlz= 339.7600- 339.9600

MSICIS

07301305

CD

N- N- (0

(0 - co

NL:

CO 0)

(0 cd,0 '- N- - _

(N

CO _CC)

1.0 2

CO.... o 341.7570-

341.9570

Jv1 1 07301305

NL:

(N

6.70E3

IC)

(N L1•) m/z=

351.8000-w100-i

CO 352.0000

C) MS ICIS

80 07301305

-C

60-f A H c

> H- c" 0)

20 LW____

NL:

N-(N 4.19E3 0) (N Cv.) mlz=

(N 0)0 353.7970-)

C') 353.9970

MS ICIS

80 07301305

I iLl __ThL:

C, c' c2.22E1

C) CO (010

coo (0dmIz-

10 CO .. 409 6974-.

409.8974 01o

27 28 29 30 31 32 33 34 35 36

Vol 3 of 5 p. 1273

C:\Xcalibur\Data\Dioxin\07301 3\07301 305 7/30/2013 6:16:19 PM 53720-852 1 MB mlz= U 355.7550

10O A 355.9550

MS ICIS

(N (C)

N P 07301305

- Co

AU- A A A

NL:

N- 3.89E1 mlz= d 357.7520- _c7 q:;

100 S.-, 4.96E3 mlz= 367.7950- 367.9950

100-i MSICIS Ii 07301305

IC) Nt-N Q C)cO'zt

N- 0) N- t N C) C) (0-

20- N - N IC) - - IC) IC)

N-N-IC) N -

C0c)cI-r N

28 29

- C)

- N -

0) N (0 0)

0)0)

C) LC)IC)CN- IC)-

(v) LC)LC) 00)L;. i;ii i;

C) co N N

C") N N co

- f I r I J ]F[]f]F

30 31 32 33 34 35 Time (mm)

(0

PC") N -

NC") -

(0w- IC)

36 37

NL:

3.1 6E3 m/z= 369.7920- 369.9920

MS CIS

Vol 3 of 5 p. 1274

C:\Xcalibur\Data\Dioxin\07301 3\07301 305 7/30/2013 6:16:19 PM 53720-85-21 MB

L

NL:

3.95E1 m/z= 373.7210- 373.9210

MS ICIS

07301305

N- 0)

0)

LU

co

Q) t CON-

LU

N-

LU

.. ('J . c-si

NL:

3.1OE1

m/z= 375.7180-co375.9180

MS ICIS

07301305

NL:

LU 1.30E4

(-.4 N-i- 0) LU c-'J

(-'4 mlz=0) LU LU CO

LU

385.7610-

LU 385.9610

MS lOIS0

80 07301305

60J

H / \ co N- (NO)

LU LUN-

•5 H jH

NL:

0) 0)

LU LU 9.85E3

(S4 c

C0 ('4

(N C)

LU

(0 LU mlz= cO cO-ci- 'ci- 387.7580-

'ci- 387.9580

MS lOIS 80 A I\ 07301305

LU

40, N-

NL:

2.17E1

('4 (0 m/z=

445.6555-

100 ..

445.8555

A Il A A A A

MS!CIS

07301305

37.5 38.0 38.5 39.0 39.5 40.0 40.5 41.0 41.5 42.0

Vol 3 of 5 p. 1275

C :\Xcalibur\Data\Dioxin\07301 3\07301 305 7/30/2013 6:16:19 PM 53720-85-21 MB

RT: 36,25 - 42.67 SM: 5G

k NL:

3.20E1 m/z= 389.7160-

100 N- 389.9160

NL:

2.93E110 cc 0 mlz=co o 10 391.7130-

N- C) Q Q1 Q1fl

1.90E4 m/z= 401 .7560- 401.9560

100 I MSICIS

07301305

0ç.

'-10 COc)

NC)

C)ç)

(0 N-ce') (0'-

NL:

1.50E4 mlz= 403.7530- 403.9530

MS ICIS

07301305

37 38 39 40 41 42 Time (mm)

C') c-4 ('1

Vol 3 of 5 p. 1276

N

100:

80 00)('j) LU cc

40H

7/30/2013 6:16:19 PM 53720-85-21 MB

I

NL:

7.53E1 m/z= 407.6818- 407.8818

MS ICIS

07301305

NL:

6.67E1

LU

m/z= 409.6789-

C) 409.8789

I MS ICIS

80-.. cc LU

N 07301305

60-

40- .1 - -

NL:

C) 1.10E4

LU

LU

LU mlz=cc

- 41 9.7220- 19 92204 .

., 100 MS ICIS0

8OT A 07301305

60-

40- LU

N N

C)LO

d N-

Ncco

NN--

20-w J

NL:

C 1.05E4 C)

C) Ncc mlz= N 421.7190-

421.9190

100 MS ICIS

80- A 07301305

N N-Ce)

CD - -

LU

N-cc

N-

N-cc N

N- N

LU N-C)

LU N-C)

j.

NLU çN

NLU ..

43 44 45 46 47 48 Time (mm)

NL:

2 .34E 1 m/z=

479.6 1 65- 479.8165

MS ICIS

Vol 3 of 5 p. 1277

C:\Xcalibur\Data\Dioxin\07301 3\07301 305 7/30/2013 6:16:19 PM 53720-85-21 MB

RT: 4208 - 48.50 SM: 5G

CD

CD

Co

100 _

N- 0)

Co

NL:

4.45E1

° Or) mlz= 423.6770-

(0 0) 423.8770

MSICIS

07301305

C) N I)co Q

NL:

3. 94E I mlz= 425.6740- 49 R74() lOOii - MSICIS

N- QN-

c.o 07301305 80 c

a) -

0- NL:

C) (0 m/z= 435.7170- 435.9170

100 A MSICIS

07301305 ci.)

43 44

N-

0) L1 O)N-oO co 0)0) ("J vC'4v

N-c) (0 C', C', fl (0 cco L)

II C') ON-c0CDO fl C') N-v-C'4CO

Fr fl frrr-r

45 46 47 Time (mm)

NL:

7.38E3 mlz= 437.7140- 437.9140

MS ICIS

07301305

Vol 3 of 5 p. 1278

Chromatogram

RT: 44.43 46.43 SM: SC

100:

80-

! 601

20-

44.89 45.14

RI: 45.40

45.85

45.61 4600

4.45E1 m/z= 423.7e-

46.36 423.20 MS

T\0 7301 3.0

NL:

100- RI. 45.38 94E1

/ \ miz 80 / 4Z57

42S0 MS

60 4475 4490 4516 4571 4598 4619 4633 O73O130

44.6 44.8 45.0 45.2 45.4 45.6 45.8 46.0 46.2 45.4 Time (mm)

Entry: I 234872-hpcdd IS: 123.4Th-HpCDD

Entry Parameters

Compound Name Entry Identifier QM Retention Time QM Area RM1 Area RM1 Ratio (A) Amount (pglg dry) Percent Recovery (A) Detection Limit (A) Status Overview

TEF

TEQ (A)

1234678-H pCDD 1234678-h pcdd 45.40 1.1056 0.95

0.0494 passed 0.0100 0.0095

Vol 3 of 5 p. 1279

C:\Xca!ibur\Data\Dioxin\07301 3\07301 305 7/30/2013 6:16:19 PM 53720-85-21 MB

RI: 47.74- 51.54 SM: 5G

NL:/ 5.88E1

(0 mlz= 441.6430-

1 00- 441.8430

MS ICIS

2: .

NL:

6.64E1 m/z= 443.6400-

10011 443.8400

1 MS ICIS

w 305 o 80Hc Ct -o

- v-

(S N-

60-1 v- N-

Co (N-o 11

20-

NL:

N- 1.07E4 (0 m/z= 469.6780-

I 00-n 469 8780

MS ICIS

07301305

L

NL:

1,17E4

C

U, mlz= 471.6750-

100 471.8750

MSICIS

07301305

40-H -H U, (0

C)

20'J (O (N

F F F F

48.0 48.5 49.0 49.5 50.0 50.5 51.0 51.5

Vol 3 of 5 p. 1280

C:\Xcalibur\Data\Dioxin\073013\07301305 7/30/2013 6:16:19 PM 53720-85-21 MB

RT: 47.73 - 51.37 SM: 5G

NL:

6.38E1

(\J m/z= 457,6380- 457.8380

100I MS ICIS

07301305

NL:

6.46E1 mlz= 459.6350- 459.8350

MS ICIS

07301305

NL:1$)

1.07E4Co C) m/z=

469.6780- 469.8780

MS ICIS

07301305

NL:0

1 17E4.

m/z= 471 .6750-

100 471.8750 tl MSICIS

07301305

48.0 48.5 49.0 49.5 50.0 50.5 51.0

Vol 3 of 5 p. 1281

RT: 47.91 - 49.91 SM: 5G

1 00-:

C) -

(U

C -

40- 4811

20-

0- 100-

49.18 49.37 tQA1

C. 4CE 1

459.71-

459.75 MS

07501505

40- ct iQ 17 M -u

48.0 48.2 48.4 48.6 48.8 49.0 49.2 49.4 49.6 49.8 Time (mm)

Entry: d 5: OCOD

C SOEI

m/z= 457,71-

457,75 MS

07301305

Entry Parameters

Compound Name OCDD Entry Identifier ocdd QM Retention Time 48.88 QMArea 197 RM1 Area 186 RM1 Ratio (A) 0.9425 Amount (pglg dry) 3.13 Percent Recovery (A) Detection Limit (A) 0.0403 Status Overview passed

TEF 0.0003

TEQ (A) 0.0009

RI: 48.88

Vol 3 of 5 p. 1282

C:\Xcalibur\Data\Djoxjn\07301 3\07301 305

RI: 20.00 - 53.00

59 102 256 335 3822036 21.30 24.66 26.39 27.41

7/30/2013 6:16:19 PM 53720-85-21 MB

402 477 623 695 807

27.96 29.63 32.86 34.45 36.94

818 915 1117 1133 NL:

100 37,23 38.86 42.25 42.52 1.04E5 402 558 617 787 m/z=

80 27.96

60-

380.47550-

381.47550WI

- H MS

07301305

. H <'1a) 4r > "Jr

0 ____ 1253 1291 1362

100 i 44.66 4532 46.53

NL:

7.17E4 m/z=

304.48 1 80- 305.48180

MS

07301305

NL:

1.60E5 m/z= 330.47869- 331.47869

MS

07301305

NL:

6.12E4 mlz= 392.47550- 393.47550

MS

07301305

91 50.10 52.88 6.93E4 V/mIz=47.14

430.47231- 431.47231

MS

07301305

20 25 30 35 40 45 50 lime (mm)

Vol 3 of 5 p. 1283

Vol 3 of 5 p. 1284 b

N a m e

M a t r i x

S a m p l e

R e c e i p t

D a t e

E x t

D a t e

A n a l y s i s

D a t e

E x t r a c t

V o l u m e p L

I n j e c t i o n

V o l u m e p L

D i l u t i o n F a c t o r

C o n c e n t r a t i o n

U n i t s

K N A L Y T E

T C D D l P e C D D l H x C D D l N x C D D l H x C D D l H p C D D

C D D

T C D F l P e C D F

P e C D F

N x C D F l N x C D F l N x C D F

H x C D F

H p C D F

H p C D F a l

T E Q

S e d i m e n t

T i m e

1 1 p g g d r y

C O N C

F O U N D n d n d n d n d n d n d n d n d n d n d n d n d n d n d

P C D D

P C D F

A N A L Y S I S

D A T A

S H E E T

L a b

S a m p l e

I D

S a m p l e

W t V o l

I n i t i a l

C a l i b r a t i o n

D a t e

I n s t r u m e n t

I D

G C

C o l u m n

I D

S a m p l e

D a t a

F i l e n a m e

B l a n k

D a t a

F i l e n a m e

C a l

V e r

D a t a

F i l e n a m e

C o n c e n t r a t i o n

U n i t s

D E T E C T I O N

L I M I T

I O N

R A T I O N

T E Q

L A B E L E D

C O M P O U N D S n d l C T C D D n d l C l P e C D D n d

C l N x C D D n d l C l N x C D D n d l C l N p C D D n d l C O C D D l C T C D F n d

C l P e C D F n d l C P e C D F n d l C l H X C D F n d l C l H X C D F n d

C H x C D F l C H x C D F n d

C H p C D F n d l C l N p C D F n d

C L E A N U P

S T A N D A R D

C T C D D

P a g e o f

M B u n i t s g m

D F S m

Z B p g

S P I K E

C O N C

C O N C

F O U N D

R

I O N

R A T I O

V

J J

Vol 3 of 5 p. 1285

F i l e n a m e

A c q u i r e d

P r o c e s s e d

A n a l y t e

N O

N A P P I N G

C a l

D I C A L

R e s u l t s

N B

S a m p l e t e x t l

N B

S:

C o m m e n t s

.4

T y p

N a m e

Q N

A r e a

R N

A r e a

R A

R T

C o n c

T o x

D L

R e c

U n k

T C D F n n d m d ti nk l P e C D F n m d n d

U n k

P e C D F n m d m d

U n k l N x C D F m m d m d

S U n k l H x C D F m m d n d

U n k

N x C D F m m d m d

U n k l N x C D F y

U n k l H p C D F n m d m d

U n k l N p C D F m m d m d

U m k

O C D F y

U n k

T C D D m m d m d

U n k l P e C D D m m d m d

U m k l H x C D D m m d n d

U m k l H x C D D m m d m d

U n k l N x C D D m m d m d

U m k l N p C D D m m d m d

U m k

O C D D y

I S R T l C T C D F y

I S l C l P e C D F y

I S l C P e C D F y

I S l C l N x C D F y

I S l C l N x C D F y

I S l C H x C D F y

I S l C l H x C D F y

I S l C l H p C D F y

I S

C l H p C D F y

I S l C T C D D y

I S

C l P e C D D y

I S l C l H x C D D y

I S l C l N x C D D y

I S l C l H p C D D y

I S l C O C D D y

R B l C T C D D y

R S R T l C N x C D D y

C U p

C l T C D D y

T o t

T o ta l

T e tr a -F u ra m s m

T o t

T o ta l T e tr a -D io x in s m

.7

T o t

T o t a l

P e m t a F u r a n s m

T o t

T o t a l

P e n t a D i o x i m s m

T o t

T o t a l

H e x a F u r a m s y

T o t

T o t a l

N e x a D i o x i m s y

T o t

T o t a l

H e p t a F u r a m s m

T o t

T o t a l

H e p t a D i o x i m s m

P a o e o f

Vol 3 of 5 p. 1286

C:\Xcalibur\Data\Dioxin\07301 3\07301 306

RT: 18.95-28.27 SM: 50

C.'J C) C) C)

100-

60H

40-

7/30/2013 7:19:38 PM 53720-90-21 MB

('4co

LU

Q LUC) CO

o

CO

C)

CDC) LU CD

NL:

2.79E1 mlz= o 303.8020- 304.0020

.. MSICIS

07301306

C) ('4 N-

CD ('4

('-I

NL:

3.15E1

N- o

- CD N-

CD

C) mlz=

LU •. 305.7990-

A A A

MSKS

07301306

NL:

4.75E3 m/z= 315 8420-.

316.0420

11 : 073306

60- 1

CD 0 0 0 CD CD CD

40 CCC O)C) LO

CD CO C (Y) LU N- 0 v C) _

NL:

5.77E3 mlz=

318.0390

100 A MS ICIS

07301306

H 40-1

LU CD

N

CD

C)

C)

CD ,4_ C') LU

100.

20-

0 r

-C)

LUC9

t C') N - ('4 C0 ') N-c') C')

C') LU N- C') - LU C')

CD C) c') r - ('4C LU

NL:

2.17E1c-'j co C) C)CD mlz=

375.7364- < 375.9364

..' -< MSICIS

07301306

20 21 22 23 24 25 26 27 28

Vol 3 of 5 p. 1287

C:\Xcalibur\Data\Dioxin\07301 3\07301 306 7/30/2013 7:19:38 PM 53720-90-21 MB

RT: 2078 - 28.43 SM: 5G

C)

(0 0

(0 (0

C) C) co i i iooL c' c h A 1\

(0 (0 N -

I 40-

-I

NL:

2.73E1 mlz=

(N 319.7970-co N- 319.9970

MS ICIS

07301306

NL:

2.73E1 m/z= co 321.7940- 321.9940 r MSICIS

A 07301306

N-

21 22 23 24 25 Time (mm)

C)

(N

(0 (N

C)

N

(0 -

\ (0 L() 0 - C) ('4 - (N

26 27 28

(0 -C) 0

(0(i) (Nt-

NL:

1.23E4 mlz= 331.8370- 332.0370

MS ICIS

07301306

NL:

1.50E4 m/z= 333.8340- 334.0340

MS ICIS

07301306

Vol 3 of 5 p. 1288

7/30/2013 7:19:38 PM

C) Co

CO

N U, NL:

2.43E1

U) Q mlz=

1- 339.7600-r 339.9600

MSICIS

53720-90-21 MB

c co

U, U, N N rLo

COL)

L C) -

100T

NL:

c)

CO

co co

C) C)cO

CDCD.

,m/z= C)341 7570-.

341.9570

MSICIS

V\r'\fi\I r.J'07301 306

-, NL:

co

C)(N 4.84E3 U, (0

U) N () mlz=

351.8000-wlOO 352.0000

MS ICIS

80: 07301306

60H

U, c)

C) (0

> N d co fl

N c)

LI __ ________

I

U, LO

(N co(N

U, Co

(N

Q N

U, (0 U, (N (N

NL:

2.91 E3

m/z= 353.7970- 353.9970

MS ICIS

07301306

(0

(N

NL:

2.1 7E I m/z= 409.6974- 409.8974

-MS ICIS

07301306

27 28 29 30 31 32 33 34 35 36

Vol 3 of 5 p. 1289 lOo_J Co co Co Q N

6O

7/30/2013 7:19:38 PM 53720-90-21 MB

NL:

N- ¼ 3.79E1 (0

CD =

h 355 7550-.

355 9550.

MSICIS

Co .. Co 07301306

A

NL:

4.29E1

0 --

C" 357.7520- < 357 9520.

MS ICIS

07301306

N-.O)cd 2c0N

0r- i-o

Co. <..<<

CJ.ct

CN-

20 C"

NL:

N-N- 3.23E3 Co m/z= 367.7950- 367.9950

MS ICIS

07301306

Co P

N- C

It) N-r c o C\J c'.j

XI-

CO

r

NL:

2.01 E3

mlz= 369.7920- 369.9920

MS ICIS

07301306

N-

CO 0)

IC)

N- C') rj I

30 31 32 33 34 35 36 37

Vol 3 of 5 p. 1290

C:\Xcalibur\Data\Dioxin\07301 3\07301 306 7/30/2013 7:19:38 PM

N-coo C2

100 1010 CO Q co

90co c 10< co co Co 0 c'4

C.) -

80-

- H

Co co a)

Co coN- Co

Co<dCo

NL:

2.78E1

If) m/z= Co 375.7180-° 375.9180

10 < If) Co MSICIS

07301306

53720-90-21 MB

NL:

2.92E1 mlz= 373.7210-co o ci: 373.9210

If) MS ICIS 07301306 co If:

Co Co

IC) N

(0Co 10 N- Co (0 (0 0 • Co

A

NL:

7.31 E3

mlz= Co Co 385.7610-

385.9610

MS ICIS

07301306 co (0 0)

NL:

If)

(0 Co 5.80E3

If) 0

0) mlz=Co

Co

C'J If) c'.J

387.7580- 387.9580

MSICIS

07301306

(c.

If)

N-

If)

CO CO

N- 10 CO o co

A A. A

NL:

2.19E1

0) (sJ

CO

(0 0) miz= c' Co 445.6555- 445.8555

A. A

MS ICIS

07301306

37.5 38.0 38.5 39.0 39.5 40.0 40.5 41.0 41.5 42.0

Vol 3 of 5 p. 1291

C:\Xcalibur\Data\Dioxin\07301 3\07301 306 7/30/2013 7:19:38 PM

RT: 36.25 - 42.67 SM: 5G

53720-90-21 MB

c, IC) (C)

'cN

NL:

2.66E1 mlz= 389.7160- 389.9160

MS ICIS

A .07301306

Q 0)

10 - ç. r-

(0 IC) ('1

.. CC)

NL:

N- - (0

2.51E1 mlz=

CO

C\J 391.7130-

- 391.9130 Af\

PI\ £rA -..

MSICIS

.-07301306

NL:

IC)

o 1.49E4 m/z=N- 401.7560- 401.9560

MS ICIS

07301306

100) cOO)coC'J CJ C-'i

0)

IC)

- N -

N- N -r r

NL:

1.18E4 m/z= 403,7530- 403.9530

MS ICIS

07301306

37 38 39 40 41 42

Vol 3 of 5 p. 1292

C:\Xcalibur\Data\Dioxin\0730 1 3\07301 306 lOOi L() Il c4c H (-j

80- N0)C)

60:

JLL2

7/30/2013 7:19:38 PM 53720-90-21 MB

NL:

4.80E1 mlz= 407.6818-

CO N-

- 407.8818

(\N- C) C-1

CD 0) MSJCIS

CD CD 07301306

NL:

6.29E1

N-mlz= 409,6789- 409.8789

CD MSICIS

CD

c) CD

CC

- LU t

CD

- CC)

07301306 N- - (v )

NL:

6.20E3 co CD mlz=CN CD 419 7220-

4 N

419.9220 c lOOi MSICIS

80- 07301306 C

< LU LU 'cj - N- N- CO

0)()CO

CD

0 NL:

6.00E3

N- m/z=

CO 421.7190-

421.9190ioo- MSICIS

01306::

CD CD LU 0)

LU LU CO

2.36E1 m/zCO d CD 0)

CD 479 6165-.

TJ 1I \

43 44 45 46 47 48

Vol 3 of 5 p. 1293

C:\Xcalibur\Data\Dioxin\07301 3\07301 306 7/30/2013 7:19:38 PM 53720-9021 MB

RI: 4208 - 48,50 SM: 5G

NL:

3.74E1 m/z=('4 423.6770-

100 ('.J It) Lt) Ci')

N-co 423.8770

MS ICIS

07301306

60-

40-

20-I

NL:

3.1OE1

('4 m/z= 425.6740-

00-c)

IO

N- N.

'0') C'4 It) 425.8740

Co

CO CO

MS ICIS

07301306 o 80 C

60-

40-oil

NL:

N- 4.32E3 Co m/z=

435.7 1 70- 4359170

100 MS ICIS

07301306

80-

60-

40 It) C)

0 0IO

20- N- co

.t t -oc 0)C

H

0 ______

NL:

C) 4.15E3

L) aD mlz=

437.7140- 437.9140

100 MS ICIS

07301306

H HT fl r r'1 rH'T HH

43 44 45 46 Time (mm)

N-(010 ('4c) - 0) 10

c) '- c) r

47 48

Vol 3 of 5 p. 1294

C:\Xcalibur\Data\Dioxin\07301 3\07301 306 7/30/2013 7:19:38 PM 53720-90-21 MB

RI: 47.74 - 51.54 SM: 5G

NL:

4.61 El

m/z= 441.6430- 441 .8430

MS ICIS

07301306 r

NL:

5.15E3 mlz= 469.6780- 469.8780

MS ICIS

07301306

Q N- N -

20JL

(V)

NL:

5.76E3

(0(N m/z=

471 6750

471.8750100 MS ICIS

07301306

(N (N 0) Co (N

I Y I f I T I r I [ T

48.0 48.5 49.0 49.5 50.0 50.5 51.0 51.5

Time (mm)

(0

NL:

4.97E1 m/z= 443.6400- 443.8400

MS ICIS

07301306

Vol 3 of 5 p. 1295

RT: 47.99-49.99 SM: 5G

100-

80- Vt, I;'

48.6113°

40-

20-

RT:48.99

49.20 493 49.46 468

F4L 4.97E1

443.72-

443.7 MS

0730 130C

RT: 48.99

48.16

48.0 48.2 48.4

Ertfy: cdf IS: OCDD

Entry Parameters

Compound Name Entry Identifier QM Retention Time QM Area RM1 Area RM1 Ratio (A) Amount (pg/g dry) Percent Recovery (A) Detection Limit (A) Status Overview

TEE

lEO (A)

OCDF

ocdf 48.99 0.8355 2.43

0.0504 passed 0,0003 0.0007

4.O1EI

m'z 441.72-

441.7C MS

49.91 0730130

Vol 3 of 5 p. 1296

RT: 47.73- 51.37 SM: 5G

100i a)

(t -o C a)

7/30/2013 7:19:38 PM 53720-90-2 1 MB

NL:

4.67E1 mlz= 457.6380- 457.8380

MS ICIS

07301306

NL:

4.72 El

mlz= 459.6350- 459.8350

MS ICIS

07301306

NL:

5.15E3 mlz= 469.6780- 469.8780

5.76E3 m/z 471 .6750- 471.8750

MS ICIS

07301306

48.0 48.5 r

49.0 49.5 50.0 T T

50.5 51.0

Vol 3 of 5 p. 1297

C:\Xcalibur\Data\Dioxin\07301 3\07301 306 7/30/2013 7:19:38 PM 5372090-21 MB

82 131 238 32620.86 21 93100 2427 26.19

NL:

7.13E4 mlz= 304.48180- 305.48180

MS

07301306

- 398 461 604 761 808

27.88 29.27 32.44 35.92 36.9(1 00 , .. A,,.

40-

20-

0-

NL:

1.58E5 mlz= 330.47869- 331 .47869

MS

07301306

NL:

1.04E5 mlz= 380.47550- 381 .47550

MS

07301306

64816 3855 41.

42,76100_

402 500 557 3721

27.97 30.14 31.40

60-ci: I W 4-

20-

1166 IL.JI

AQ Ia 43.78 45.65 46.80

NL:

6.21 E4

mlz= 392.47550- 393.47550

MS

07301306

1490 1659 NL:1412 49.01 52187.11E4

47.54 m/z=

430.4723 1- 431.47231

MS

07301306

20 25 30 35 40 45 50

Vol 3 of 5 p. 1298 b

N a m e

M a t r i x

S a m p l e

R e c e i p t

D a t e

E x t

D a t e

A n a l y s i s

D a t e

E x t r a c t

V o l u m e p L

I n j e c t i o n

V o l u m e p L

D i l u t i o n F a c t o r

C o n c e n t r a t i o n

U n i t s

A N A L Y T E

T C D D l P e C D D l H x C D D l H x C D D l H x C D D

N p C D D

O C D D

T C D F

P e C D F

P e C D F l H x C D F l H x C D F

H x C D F

H x C D F l N p C D F l H p C D F a l

T E Q

S e d i m e n t

T i m e

1 1 p g g d r y

P C D D

P C D F

A N A L Y S I S

D A T A

S H E E T

L a b

S a m p l e

I D

S a m p l e

W t V o l

I n i t i a l

C a l i b r a t i o n

D a t e

I n s t r u m e n t

I D

G C

C o l u m n

I D

S a m p l e

D a t a

F i l e n a m e

B l a n k

D a t a

F i l e n a m e

C a l

V e r

D a t a

F i l e n a m e

C o n c e n t r a t i o n

U n i t s

C O N C

D E T E C T I D N

F O U N D

L I M I T

I O N

R A T I O N n d n d

T E Q

L A B E L E D

C O M P O U N D S l C T C D D l C P e C D D n d

C l H x C D D

C l N x C D D

C l H p C D D l C O C D D l C T C D F l C l P e C D F l C P e C D F l C l H x C D F l C H x C D F

C N x C D F n d l C H x C D F

C H p C D F l C l H p C D F

C L E A N U P

S T A N D A R D

C T C D D l u n i t s

D F S

D m

Z B p g

S P I K E

C O N C . 1

CO

N C.

F O U N D g m

P a g e o f

R

I O N

R A T I O

\1 D

Vol 3 of 5 p. 1299

F i l e n a m e

A c q u i r e d

P r o c e s s e d

/2

A n a l y t e

N O

M A P P I N G

C a l

D I C A L

R e s u l t s

S a m p l e t e x t

C o m m e n t s

T y p

N a m e

Q M

A r e a

P8

A r e a

R A

R T

C o n c

T o x

D L

R e c

U n k

T C D F y

U n k

P e C D F y

U n k

P e C D F y

U nk l H x C D F y

U n k l H x C D F y

U n k

H x C D F y

U n k

H x C D F n n d n d

U n k

H p C D F y

U n k l N p C D F y

U n k

O C D F y

U n k

T C D D y

U n k l P e C D D y

U n k l H x C D D n n d n d

U n k

H x C D D y

U n k

H x C D D y

U n k l N p C D D y

U n k

O C D D y

I S P T l C T C D F y

I S l C l P e C D F y

I S l C P e C D F y

I S l C l H x C D F y

I S

C l H x C D F y

I S l C H x C D F y

I S l C l H x C D F y

I S

C l H p C D F y

I S

C l N p C D F y

I S

C T C D D y

I S

C P e C D D y

I S l C l H x C D D y

I S l C l H x C D D y

I S

C l H p C D D y

I S l C O C D D y

P S

C l T C D D y

P S P T

C l H x C D D y

C U p

C T C D D y

T o t

T o t a l

T e t r a F u r a n s y

T o t

T o t a l

T e t r a D i o x i n s y

T o t

T o t a l

P e n t a F u r a n s y

T o t

T o t a l

P e n t a D i o x i n s y

T o t

T o t a l

H e x a F u r a n s y

T o t

T o t a l

H e x a D i o x i n s y

T o t

T o t a l

H e p t a F u r a n s y

T o t

T o t a l

H e p t a D i o x i n s y

P a q e o f

Vol 3 of 5 p. 1300

C:)(caIibur\Data\Dioxin\O73013\07301307 7/30/2013 8:22:57 PM 5372085-17 20130932

RT: 18.95 - 28.27 SM: 5G

/co , 6.38E2 mlz= 303.8020- 30 0 204. 0 co 8.27E2 mlz= 305 7990-.

305.9990

10? 07301307 i.10E4 mlz= 315.8420- 316.0420

MS ICIS

07301307

60H co L() LO r N- c'4 - co co co LO C.0 0' LO C'4 N- N.

40 C LOC'J CD N- O)L$) C) N coca co 'ci- -LO o co c c)Q N--- c' - Q'ct-LO

2±:

fl

NL:

1.38E4 mlz= 317.8390- 318.0390 lOO MS ICIS 07301307

H H O)L() C'J O)'ci 40 N- CD CD 'ci-

C) IC) Co o C) C) CO C) C IC) _C).

NL:

2. 70E 1 mlz= 375,7364- 375.9364

MS ICIS

07301307

19 20 21 22 23 24 25 26 27 28

Vol 3 of 5 p. 1301

C :\XcaHbur\Data\D ioxin\07301 3\07301 307

RT: 2078 - 28.43 SM: 5G

I

N C)

NL:

6.22E2 mlz= 31 9.7970- 319.9970

MS ICIS

07301307

NL:

7.72E2 m/z= 321.7940- 321 .9940

MS ICIS

07301307

40 H

0 NL:

1.81E4 co m/z=

331 .8370- 332.0370

100- 07301307

80-

60-

40 ICo -H

N- CO CO C)N t 20 J

7/30/2013 8:22:57 PM 53720-85-17 20130932

N

Co

(o N N

(0 0 N- Co Cofl

II

21 22 23 24 25 Time (mm)

CO

C) (0

CO

A0

IN-

ICO

1(0

H

LC)

CO N

NL:

2.26E4 m/z= 333,8340- 334.0340

MS ICIS

07301307

Vol 3 of 5 p. 1302

C:\XcaHbur\Data\Doxin\07301 3\07301 307

RT: 26.65 - 36.79 SM: 5G

I

100-

L()

U)

OU N -

c) w 100 I:.)

C c 80

6O1

G) 40= ci)

7/30/2013 8:22:57 PM 53720-85-17 20130932

L() 0) co

U ___

4I L i i.

L() U) c.'i c.4

N- - 0) - c)

NL:

1.03E3 mlz= 339.7600- 339.9600

MS ICIS

07301307

NL:

6.72E2 m/z= 341.7570- 341 .9570

MS ICIS

07301307

NL:

1.28E4 mlz= 351.8000- 352.0000

MS ICIS

07301307

NL:

8.01 E3

mlz= 353.7970- 353.9970

MS ICIS

07301307

L/ NL:

2.22E1

0)

C

N- m,z- 409.6974- 409.8974 i: w=

27 28 29 30 31 32 33 34 35 36

Vol 3 of 5 p. 1303

C:\Xcalibur\Data\Dioxjn\07301 3\07301 307 ct (N

(NN-°Q

QQ(N(DC)

c) - '- LU LU LU

100.

o 80- C

C -

-Q C) (D (0

40- ;;

2O4

I

LU

LU

C)

- (0

NL:

1.68E2 mlz= 355.7550- 355.9550

MS ICIS

07301307

NL:

1.16E2 mlz= 357.7520- 357.9520

MS ICIS

07301307

NL:

9.65E3

C) m/z= 367.7950- 367.9950

MS ICIS

07301307

7/30/2013 8:22:57 PM 53720-85-17 20130932

- co (N (N (N U N -r c) Lt C)(NLU..Q (N

LU

-coLU'-co

LU-

c)

C

C)

(0 (NLU LU

Time (mm)

(N N-

NL:

5.93E3 mlz= 369.7920- 369,9920

MS ICIS

Vol 3 of 5 p. 1304

RT: 33.48 - 35.48 SM: SC

100- 33.85

Cu 80-

Cu

60-

40- 0 33.63

20-

34.07

33.83

Entry Parameters

Compound Name 12378-PeCDD Entry Identifier 12378-pecdd QM Retention Time 34.49 QMArea 247 RM1 Area 161 RM1 Ratio (A) 0.6533 Amount (pglg dry) 2.53 Percent Recovery (A) Detection Limit (A) 0,1181 Status Overview passed

TEF 1.0000

TEQ (A) 2.5338

RT: 34.49

34.83 35.29

F4L:

C84E1 n1z=

355. 4-

355.87 MS

07301307

4 28E1 m2Z

35783-

35787 MS

Vol 3 of 5 p. 1305

NL:

1.55E3 mlz= 373.7210- 373.9210

MS ICIS

07301307

NL:

1.27E3

N- N- 0) mlz=

(0 375.7180-

375.9180

( MS ICIS

0)a) 07301307 N .. 0

60 N- H (0 a) a)

40 N A LI)

N

NL:

a) 1.83E4 N

0) (0 IS) m/z= N- N-

385.7610-

100W 385.9610

G)

0 MS ICIS

80 07301307 C

60-

(0

N-

N

- C)

20-

ci) :

07301 307

1.47E4 (0

a) N-

COc) mlz= N- a)

CD 387.7580-

387 9580

00 MS ICIS

80 07301307

40 (0 a:;

U'

NL:

2.34E1

0 mlz=

LI)

CO

c, 445.6555-

100 C r-445.8555

MS 1C15

90 R --

II

37.5 38.0 38.5 39.0 39.5 40.0 40.5 41.0 41.5 42.0

Vol 3 of 5 p. 1306

RT: 39.42-41.42 SM: 5G

39.52

20-

39.52 100 A

'NL:

3.00 E2

37S0-

375.54 MS

07301307

0- I I I I I I I I I I I I I I I I I I I I I I

39.6 39.8 40.0 40.2 40.4 40.6 40.8 41,0 41.2 41.4

Time (miii)

Entry: 2a4273-hxc1 IS: 23457SHxCDF

Entry Parameters

Compound Name 234678-HxCDF Entry Identifier 234678-hxcdf QM Retention Time 40.46 QM Area 986 RM1 Area 699 RM1 Ratio (A) 0.7091 Amount (pglg dry) 6.83 Percent Recovery (A) Detection Limit (A) 0.3693 Status Overview passed

TEF 0.1000

TEQ (A) 0.6832

40.01

RT 40 46

40.33 / \

40.75 40.93 41.22 4135

ML:

3.71 E2

mIz 373.20-

373,24 MS

Vol 3 of 5 p. 1307

C:\Xcahbur\Data\Dioxin\07301 3\07301 307

RI: 36.25 - 42.67 SM: 5G

N

7/30/2013 8:22:57 PM

co (0

53720-85-17 20130932

N (0

1'

N-

0) Co

0) 10' N-o 10<

C N-

NL:

8.60E2 mlz= 389.7160- 389.9160 MS lOIS 07301307

A

(0

20-

0-

NL:

7.41E2

-ci-

0) 'ci-m/z=(0 C)N- 391 7130-() .

391 9130.

MS ICIS

07301307

N 'ci.

'ci-c) Co

- N 10(0

NL:

1.70E4 mlz= 403.7530- 403.9530 MS lOIS 07301307

37 38 39 40 41 42

Vol 3 of 5 p. 1308

C:\Xcalibur\Data\Dioxin\07301 3\07301 307 7/30/2013 8:22:57 PM 53720-85-17 20130932 co NL:

co 5.51E3 mlz=c'-J 407 6818-.

407.8818

100= MS ICIS

80 07301307

Q

60 0)

L

40- (0 (0

20-

0 NL:co co 5.27E3 eQ mlz=('4 409.6789- 409.8789

100 MS ICIS

80 07301307 eQ N-

40 It) t4 It)

(0 It) N-

(0(N cor 4 ('4 It) ('4_ t- r N-

20=

0 _____

NL:

1.52E4

N- (0

0) CD m/z= eQ(0 41 9.7220-

419 9220.

G) 100 MS ICIS0 -

80 07301307

(0

It) eQ eQ co

Old N- N- eQ

20-o NL:

146E4

It) eQ C) mlz=(0 0 c0 421.7190-

421.9190

MS ICIS

A 07301307

- N- eQ II ('4 Hc 140

- 0) eQ eQ (0 coN (0C\J

20 J L JLi i i

NL:

1.82E2

It) mlz= 479.6165- 479.8165

MS CIS

07301307 jrr

Vol 3 of 5 p. 1309

RT:44.8546,85 SM: SC

100-:

80-

C

40-

20- 0 45.00 45.13

45.36 45.51 45.65

RT: 45,82

46.04 46.22 46.52 45

ML:

1.90E2

4o7.7e

407.50 ris 0730 307

RT: 45.82 ML:

1.SE2

miz j 4O5.'T..

409.50 MS

I 07301307

45.05 45.36 45.63

45.0 45.2 45,4

Erth'y: 1 234759-hpcdf IS: 1 2347294'{pCDF

6,0__6.23 46.37 46.59

I I I I I I I I

45,5 45.b 46,0 46.2 46.4 46.6 46.8 Time mm)

Entry Parameters

Compound Name 1234789-HpCDF Entry Identifier 1 234789-hpcdf QM Retention Time 45.82 QMArea 764 RM1 Area 775 RM1 Ratio (A) 1.0144 Amount (pglg dry) 8.25 Percent Recovery (A) Detection Limit (A) 0.1965 Status Overview passed

TEE 0.01 00

TEQ (A) 0,0825

Vol 3 of 5 p. 1310

C:\Xca!ibur\Data\Dioxin\07301 3\07301 307 7/30/2013 8:22:57 PM 53720-85-17 20130932

NL:

5.35E3 I-mz-N

423 6770-.

423.8770

MSICIS

07301307

Nco N N

N-

LU

J Ji 100-i

I-U

NL:

5.00E3 m/z= 425.6740- 425.8740

MS ICIS

07301307

NL:

1.02E4 m/z= 435.7170- 435.9170

MS ICIS

07301307 cOO)

NC9 I-C) N N -

ioo) r co 0) -v- N N t

NL:

9.38E3 mlz= 437.7140- 437.9140 MS lOIS 07301307

IC)

N

I N- N

43 44

NO LU

0 N

(0 CO() (0

LU LUC)C) 0)

I 45 46 47 Time (mm)

Vol 3 of 5 p. 1311

C:\Xcalibur\Data\Dioxin\07301 3\07301 307

RT: 47.74 - 51.54 SM: 5G

c)

CD

100 K

LC) -OD

O' C)

1 CN CD N-G)

20-j r- r c'-

(N N-

CD

CD

(N

7/30/2013 8:22:57 PM 53720-85-17 20130932

NL:

5.1 6E3 mlz= 441.6430- 441.8430

MS ICIS

07301307

NL:

1.49E4 m/z= 469.6780- 469.8780

MS ICIS

07301307

CDL ci C)

NL:

CD 1.63E4

N-m/z= 471 .6750- 471.8750

MS ICIS

07301307

Q

-4 CD () I I C)

C)

IC) -

LI)

IC)

20- 10CC)

N C) CO

0 F E

48,0 48.5 49.0 49.5 50.0 50.5 51.0 51.5

NL:

6.02 E3

m/z= 443.6400- 443.8400

MS ICIS

07301307

Vol 3 of 5 p. 1312

RT: 47.73 - 51.37 SM: 5G

40 0) C)

7/30/2013 8:22:57 PM 53720-85-17 20130932

NL:

2.91E4

N- 1m,z- '- I 457.6380-

457.8380

A MS ICIS

07301307

NL:

u•) 3.26E4 c) C) m/z=

459.6350- 459.8350

MS ICIS

07301307

Q

(0 (0

1.49E4 mlz= 469.6780- 469.8780

MS ICIS

07301307

U- NL:

1.63E4

(0 m/z=

N- 471 .6750- 471.8750

100-n MS ICIS 07301307

48.0 48,5 49.0 49,5 50.0 50.5 51.0

Vol 3 of 5 p. 1313

118 341 390i00_2024 21.64 26.51 27.59

7/30/2013 8:22:57 PM 53720-85-17 20130932

403 490 589 643 781 809 NL:

100111 27.98 29.91 32.10 33.30 36.3…