J22826-1_Analytical_Report_(1_of_2).pdf

ANALYTICAL REPORT

Job Number: 180-22826-1

Job Description: Newark Bay - Upland 33-061

For:

Battelle

397 Washington Street Duxbury, MA 02332

Attention: Elisabeth Barrows

Approved for release.

Debra Bowen Project Manager I

7/31/2013 3:22 PM

Designee for Carrie L Gamber, Senior Project Manager 301 Alpha Drive, Pittsburgh, PA, 15238

(412)963-2428 carrie.gamber@testamericainc.com

07/31/2013

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to the NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory. This report is confidential and is intended for the sole use of TestAmerica and its client. All questions regarding this report should be directed to the TestAmerica Project Manager or designee who has signed this report.

TestAmerica Laboratories, Inc.

TestAmerica Pittsburgh 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238

Tel (412) 963-7058 Fax (412) 963-2468 www.testamericainc.com

07/31/2013Page 1 of 5251 mailto:carrie.gamber@testamericainc.com http://www.testamericainc.com http://

Table of Contents Cover Title Page

Data Summaries

Report Narrative

Manual Integration Summary

Sample Summary

Executive Summary

Method Summary

Method / Analyst Summary

Sample Datasheets

Surrogate Summary

QC Data Summary

Data Qualifiers

QC Association Summary

Lab Chronicle

Reagent Traceability

COAs

Certification Summary

Organic Sample Data

GC/MS VOA

Method 8260B Method 8260B QC Summary Method 8260B Sample Data Standards Data

Method 8260B ICAL Data Method 8260B CCAL Data

Raw QC Data

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Method 8260B Tune Data Method 8260B Blank Data Method 8260B LCS/LCSD Data Method 8260B MS/MSD Data

Method 8260B Run Logs Method 8260B Prep Data

GC/MS Semi VOA

Method 8270C Method 8270C QC Summary Method 8270C Sample Data Standards Data

Method 8270C ICAL Data Method 8270C CCAL Data

Raw QC Data Method 8270C Tune Data Method 8270C Blank Data Method 8270C LCS/LCSD Data Method 8270C MS/MSD Data

Method 8270C Run Logs Method 8270C Prep Data

GC Semi VOA

Method 8081A Method 8081A QC Summary Method 8081A Sample Data Standards Data

Method 8081A ICAL Data

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Method 8081A PEM Data Method 8081A CCAL Data

Raw QC Data Method 8081A Blank Data Method 8081A LCS/LCSD Data Method 8081A MS/MSD Data

Method 8081A Run Logs Method 8081A Prep Data

Method 8082 Method 8082 QC Summary Method 8082 Sample Data Standards Data

Method 8082 ICAL Data Method 8082 CCAL Data

Raw QC Data Method 8082 Blank Data Method 8082 LCS/LCSD Data Method 8082 MS/MSD Data

Method 8082 Run Logs Method 8082 Prep Data

Method 8151A Method 8151A QC Summary Method 8151A Sample Data Standards Data

Method 8151A ICAL Data Method 8151A CCAL Data

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Raw QC Data

Method 8151A Blank Data Method 8151A LCS/LCSD Data Method 8151A MS/MSD Data

Method 8151A Run Logs Method 8151A Prep Data

Inorganic Sample Data

Metals Data

Met Cover Page

Met Sample Data

Met QC Data Met ICV/CCV Met CRQL Met Blanks Met ICSA/ICSAB Met MS/MSD/PDS Met LCS/LCSD Met Serial Dilution

Met MDL

Met IECF

Met Linear Ranges

Met Preparation Log

Met Analysis Run Log

Met Raw Data

Met Prep Data

General Chemistry Data

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Gen Chem Cover Page

Gen Chem Sample Data

Gen Chem QC Data Gen Chem ICV/CCV Gen Chem Blanks Gen Chem MS/MSD/PDS Gen Chem Duplicates Gen Chem LCS/LCSD

Gen Chem MDL

Gen Chem Preparation Log

Gen Chem Analysis Run Log

Gen Chem Raw Data

Gen Chem Prep Data

Subcontracted Data

Shipping and Receiving Documents

Client Chain of Custody

Sample Receipt Checklist

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CASE NARRATIVE

Client: Battelle

Project: Newark Bay - Upland 33-061

Report Number: 180-22826-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

RECEIPT

The samples were received on 07/03/2013. The samples arrived in good condition. The temperatures of the coolers at receipt time were

2.4º C and 3.4º C.

VOLATILE ORGANIC COMPOUNDS (GC-MS)

Dibromofluoromethane (Surr) failed the surrogate recovery criteria low for samples #20130951 AMENDED COMPOSITE L (180-22826-3) and #20130948 AMENDED COMPOSITE I (180-22826-4). Re-extraction and/or re-analysis was performed with concurring results. Matrix issue is confirmed by analysis of MS/MSD. All data are reported.

Acetone was detected in method blank MB 180-22826 at a level that was above the method detection limit but below the reporting limit.

The value should be considered estimate, and has been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged

Several analytes failed the recovery criteria for the MS and/or MSD of sample #20130948 AMENDED COMPOSITE I (180-22826-4).

The laboratory control sample LCS-180-76936 recovered outside control limits trichlorofluoromethane. This analyte was biased high in the LCS but was not detected in the associated samples; therefore, the data have been reported.

SEMIVOLATILE ORGANIC COMPOUNDS (GC-MS)

Several samples were analyzed at a dilution due to the abundance of target analytes and/or matrix interference. As such, the surrogate concentration(s) will be considered as estimated. The reporting limits have been adjusted accordingly.

Several analytes failed the recovery criteria for the MS and/or MSD of sample #20130948 AMENDED COMPOSITE I (180-22826-4).

N-Nitrosodiphenylamine failed the recovery criteria high for LCS 180-76817. This compound was not detected in the associated samples.

The data are reported.

Benzidine failed the recovery criteria low for LCS 180-77168. This compound has been identified as a poor performing analyte when analyzed using this method; therefore, re-extraction/re-analysis was not performed.

N-Nitrosodiphenylamine failed the recovery criteria high for the MS/MSD of sample #20130926 COMPOSITE I (180-22826-2). The presence of the 'NC' qualifier in the data indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.

ORGANOCHLORINE PESTICIDES

Sample SRM Amended (180-22826-5) was analyzed at a dilution due to the abundance of target analytes and/or matrix interference. The reporting limits have been adjusted accordingly.

Tetrachloro-m-xylene failed the surrogate recovery low on one column for sample #20130948 AMENDED COMPOSITE I (180-22826-4).

DCB Decachlorobiphenyl recovered within acceptable QC limits. The data reported.

Several analytes failed the recovery criteria for the MS and/or MSD of sample #20130948 AMENDED COMPOSITE I (180-22826-4).

Several analytes exceeded the relative percent difference (RPD) limits.

Several analytes failed the recovery criteria for the MS and/or MSD of sample #20130926 COMPOSITE IMS (180-22826-2) in batch

180-77576. Several analytes exceeded the RPD limit.

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The ending CCV failed slightly high for D-BHC and Dieldrin on MR-2 column (conf). This was 2nd analysis with similar failure.

POLYCHLORINATED BIPHENYLS (PCBS)

Weathered PCB were present in these samples.

HERBICIDES

2,4-D exceeded the relative percent difference (RPD) limit for the MS/ MSD of sample #20130948 AMENDED COMPOSITE I

(180-22826-4).

METALS

Several samples were analyzed at a dilution due to the abundance of target analytes and/or matrix interference. The reporting limits have been adjusted accordingly.

Several analytes were detected in laboratory blank LB 180-76799 at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged.

Several analytes were detected in the method blanks LB 180-77408 at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the

MDL and/or RL, the result has been flagged.

Aluminum was detected in method blank MB 180-77107/1-A at a level exceeding the reporting limit. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. Beryllium and Cobalt were detected in method blank MB 180-77107/1-A at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. Calcium was detected in method blank MB 180-77597/1-A at a level exceeding the reporting limit. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. Cobalt and Sodium were detected in method blank MB 180-77597/1-A at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the MDL and/or RL, the result has been flagged. Refer to the QC report for details.

Antimony failed the recovery criteria for the MS/MSD of sample #20130926 COMPOSITE I (180-22826-2) in batch 180-78089. The presence of the '4' qualifier in the data indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.

Antimony and lead failed the recovery criteria low for the MS and/or MSD of sample #20130948 AMENDED COMPOSITE I

(180-22826-4). The presence of the '4' qualifier in the data indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.

Several analytes exceeded the acceptance criteria for the serial dilution of samples #20130926 COMPOSITE I (180-22826-2) and sample

#20130948 AMENDED COMPOSITE I (180-22826-4).

GENERAL CHEMISTRY

Cr (VI) and Cr (VI) failed the recovery criteria low for the MS of samples #20130926 COMPOSITE IMS (180-22826-2) and #20130948

AMENDED COMPOSITE I (180-22826-4).

The matrix soluble spike, insoluble spike and post digestion spike (MSS/MSI/PDS) recoveries for batch 78072 were outside of control limits. The associated laboratory control sample (LCSS/LCSI) recoveries met acceptance criteria, which demonstrates that the analytical system was operating in control. This condition is most likely due to a matrix interference. An ORP was performed for samples

180-180-22826-B-2 and 180-22826-B-4 and the chart is included in the report. This is the first analysis of the batch; a reanalysis will be performed in accordance with the SOP.

The matrix soluble spike, insoluble spike and post digestion spike (MSS/MSI/PDS) recoveries for batch 78017 were outside of control limits. The associated laboratory control sample (LCSS/LCSI) recoveries met acceptance criteria, which demonstrates that the analytical system was operating in control. This condition is most likely due to a matrix interference. An ORP was performed for samples

180-22826-B-2 and 180-22826-B-4 and the chart is included in the report. This is the second analysis of the batch in accordance with the

SOP.

Cr (VI) exceeded the RPD limit for the duplicate analyses of samples #20130926 COMPOSITE I (180-22826-2) and #20130948

AMENDED COMPOSITE IDU (180-22826-4).

Cyanide, Total failed the recovery criteria for the MS/MSD of sample #20130948 AMENDED COMPOSITE I (180-22826-4). Cyanide, Total exceeded the RPD limit.

Cyanide, Total failed the recovery criteria low for the MS of sample #20130926 COMPOSITE IMS (180-22826-2).

SUBCONTRACT WORK

Method 1613B Dioxin-SPLP LEACH: This method was subcontracted to TestAmerica Knoxville. The subcontract certification is different from those listed on the TestAmerica cover page of this final report.

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Lab Name: Job No.:

SDG No.:

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP3 76109

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/2

3062803.D06/28/13 06:41 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:391.76

Trichlorofluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:402.96

Acrolein Peak Integrated Incorrectly gordonk 06/28/13 07:423.59

1,1-Dichloroethene Peak Integrated Incorrectly gordonk 06/28/13 07:403.74

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly gordonk 06/28/13 07:393.82

Carbon disulfide Peak Integrated Incorrectly gordonk 06/28/13 07:404.06 tert-Butyl alcohol Peak Integrated Incorrectly gordonk 06/28/13 07:414.80

Hexane Peak Integrated Incorrectly gordonk 06/28/13 07:425.39

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 07:416.33

Bromochloromethane Peak Integrated Incorrectly gordonk 06/28/13 07:406.57

Isobutyl alcohol Peak Integrated Incorrectly gordonk 06/28/13 07:427.24

Ethyl methacrylate Peak Integrated Incorrectly gordonk 06/28/13 07:429.62

1,2-Dibromo-3-Chloropropane Peak Integrated Incorrectly gordonk 06/28/13 07:4114.19

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/3

3062804.D06/28/13 07:06 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:441.76

Chloroethane Peak Integrated Incorrectly gordonk 06/28/13 07:442.60

Carbon disulfide Peak Integrated Incorrectly gordonk 06/28/13 07:444.05

Methylene Chloride Peak Integrated Incorrectly gordonk 06/28/13 07:454.54

2,2-Dichloropropane Peak Integrated Incorrectly gordonk 06/28/13 07:456.30

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 07:456.33

1,1,1-Trichloroethane Peak Integrated Incorrectly gordonk 06/28/13 07:456.89

8260B

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GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP3 76109

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/4

3062805.D06/28/13 07:32 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:471.76

1,1-Dichloroethene Peak Integrated Incorrectly gordonk 06/28/13 07:483.73

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly gordonk 06/28/13 07:473.81

Acetone Peak Integrated Incorrectly gordonk 06/28/13 07:483.85

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 07:486.33

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-76109/5

3062806.D06/28/13 07:58 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 06/28/13 07:593.87

Iodomethane Peak Integrated Incorrectly gordonk 06/28/13 08:003.95

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/6

3062807.D06/28/13 08:20 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 06/28/13 08:363.86

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 08:376.33

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/7

3062808.D06/28/13 08:46 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly gordonk 06/28/13 08:533.59

Acetone Peak Integrated Incorrectly gordonk 06/28/13 08:533.86

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GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP3 76109

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/8

3062809.D06/28/13 09:11 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 06/28/13 09:173.86

07/31/2013Page 11 of 5251

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP3 76830

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-4 #20130948 AMENDED COMPOSITE I

30709K04.D07/09/13 07:53 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 07/09/13 07:543.85

Carbon disulfide Peak Integrated Incorrectly gordonk 07/09/13 07:544.07

Methylene Chloride Peak Integrated Incorrectly gordonk 07/09/13 07:554.55

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-4 MS #20130948 AMENDED COMPOSITE I MS

30709K06.D07/09/13 08:37 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly gordonk 07/09/13 08:393.60

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LCS 180-76827/2-A

30709K07.D07/09/13 09:00 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 07/09/13 09:023.86

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-4 MSD #20130948 AMENDED COMPOSITE I MSD

30709K08.D07/09/13 09:22 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly gordonk 07/09/13 09:303.58

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-3 #20130951 AMENDED COMPOSITE L

30709K10.D07/09/13 10:06 GC Column: DB-624 ID: 0.18(mm)

Methylene Chloride Peak Integrated Incorrectly gordonk 07/09/13 10:074.54

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GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP3 76830

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-3 RA #20130951 AMENDED COMPOSITE L RA

30709K12.D07/09/13 10:50 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly gordonk 07/09/13 10:544.06

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 07/09/13 10:556.34

07/31/2013Page 13 of 5251

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP7 76932

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/2

7070904.D07/09/13 01:35 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:011.96

Chloromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:011.99

1,3-Butadiene Peak Integrated Incorrectly zukowskim 07/09/13 02:072.19

Bromomethane Peak Integrated Incorrectly zukowskim 07/09/13 02:022.47

Chloroethane Peak Integrated Incorrectly zukowskim 07/09/13 02:022.59

Dichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:032.85

Trichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:032.90

Ethyl ether Peak Integrated Incorrectly zukowskim 07/09/13 02:083.38

1,1-Dichloroethene Peak Integrated Incorrectly zukowskim 07/09/13 02:043.54

Acrolein Peak Integrated Incorrectly zukowskim 07/09/13 02:083.54

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly zukowskim 07/09/13 02:033.66

Iodomethane Peak Integrated Incorrectly zukowskim 07/09/13 02:083.77

Acetone Peak Integrated Incorrectly zukowskim 07/09/13 02:053.84

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 04:573.85

Allyl chloride Unspecified zukowskim 07/09/13 04:564.00

Methylene Chloride Peak Integrated Incorrectly zukowskim 07/09/13 02:054.36 trans-1,2-Dichloroethene Peak Integrated Incorrectly zukowskim 07/09/13 02:054.75

Acrylonitrile Peak Integrated Incorrectly zukowskim 07/09/13 02:084.81 tert-Butyl alcohol Peak Integrated Incorrectly zukowskim 07/09/13 02:084.88

Vinyl acetate Peak Integrated Incorrectly zukowskim 07/09/13 02:095.50

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 02:066.18

Dioxane-d8 (IS) Peak Integrated Incorrectly zukowskim 07/09/13 02:018.14

07/31/2013Page 14 of 5251

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP7 76932

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/3

7070905.D07/09/13 02:02 GC Column: DB-624 ID: 0.18(mm)

Bromomethane Peak Integrated Incorrectly zukowskim 07/09/13 02:282.51

Chloroethane Peak Integrated Incorrectly zukowskim 07/09/13 02:292.61

Dichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:292.89

Trichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 02:292.91

Ethyl ether Peak Integrated Incorrectly zukowskim 07/09/13 02:333.35

Acrolein Peak Integrated Incorrectly zukowskim 07/09/13 02:333.53

1,1-Dichloroethene Peak Integrated Incorrectly zukowskim 07/09/13 02:293.55

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly zukowskim 07/09/13 02:293.65

Acetone Peak Integrated Incorrectly zukowskim 07/09/13 02:303.77

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 04:583.84

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 04:574.16

Methylene Chloride Peak Integrated Incorrectly zukowskim 07/09/13 02:304.38 trans-1,2-Dichloroethene Peak Integrated Incorrectly zukowskim 07/09/13 02:304.75

Acrylonitrile Peak Integrated Incorrectly zukowskim 07/09/13 02:334.79

MTBE Peak Integrated Incorrectly zukowskim 07/09/13 02:314.87

Hexane Peak Integrated Incorrectly zukowskim 07/09/13 02:345.17

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 02:316.17

07/31/2013Page 15 of 5251

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP7 76932

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/4

7070906.D07/09/13 02:27 GC Column: DB-624 ID: 0.18(mm)

Bromomethane Peak Integrated Incorrectly zukowskim 07/09/13 03:322.48

Chloroethane Peak Integrated Incorrectly zukowskim 07/09/13 03:322.60

Trichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 03:332.90

Ethyl ether Peak Integrated Incorrectly zukowskim 07/09/13 03:343.37

Acrolein Peak Integrated Incorrectly zukowskim 07/09/13 03:353.52

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly zukowskim 07/09/13 03:333.62

Acetone Peak Integrated Incorrectly zukowskim 07/09/13 03:343.80

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 04:583.83

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 04:584.12

Acrylonitrile Peak Integrated Incorrectly zukowskim 07/09/13 03:344.80 tert-Butyl alcohol Peak Integrated Incorrectly zukowskim 07/09/13 03:354.85

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 03:346.20

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-76932/5

7070907.D07/09/13 02:56 GC Column: DB-624 ID: 0.18(mm)

Chloromethane Peak Integrated Incorrectly zukowskim 07/09/13 03:352.01

Bromomethane Peak Integrated Incorrectly zukowskim 07/09/13 03:362.50

Chloroethane Peak Integrated Incorrectly zukowskim 07/09/13 03:362.60

Dichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 03:372.89

Acrolein Peak Integrated Incorrectly zukowskim 07/09/13 03:373.51

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 04:593.83

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 04:594.15

Acrylonitrile Peak Integrated Incorrectly zukowskim 07/09/13 03:374.80 tert-Butyl alcohol Peak Integrated Incorrectly zukowskim 07/09/13 03:384.88

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 03:376.20

07/31/2013Page 16 of 5251

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP7 76932

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/6

7070908.D07/09/13 03:23 GC Column: DB-624 ID: 0.18(mm)

Bromomethane Peak Integrated Incorrectly zukowskim 07/09/13 04:332.49

Ethyl ether Peak Integrated Incorrectly zukowskim 07/09/13 04:373.39

Acrolein Peak Integrated Incorrectly zukowskim 07/09/13 04:373.51

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 04:593.84

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 05:004.14

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 04:356.19

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/7

7070909.D07/09/13 03:52 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 04:391.96

Vinyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 04:392.19

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 05:003.85

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 05:004.15

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 04:406.18

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76932/8

7070910.D07/09/13 04:36 GC Column: DB-624 ID: 0.18(mm)

Dichlorofluoromethane Peak Integrated Incorrectly zukowskim 07/09/13 05:042.87

Acetone Peak Integrated Incorrectly zukowskim 07/09/13 05:053.81

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/09/13 05:053.81

Allyl chloride Peak Integrated Incorrectly zukowskim 07/09/13 05:074.13

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/09/13 05:066.18

07/31/2013Page 17 of 5251

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP7 76936

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCVIS 180-76936/2

7071003.D07/10/13 00:00 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly zukowskim 07/10/13 00:293.48

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/10/13 00:273.84

Allyl chloride Peak Integrated Incorrectly zukowskim 07/10/13 00:294.14

Dioxane-d8 (IS) Peak Integrated Incorrectly zukowskim 07/10/13 00:278.14

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LB 180-76671/15-A

7071006.D07/10/13 01:43 GC Column: DB-624 ID: 0.18(mm)

TBA-d9 (IS) Peak Integrated Incorrectly zukowskim 07/10/13 02:104.59

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-4 #20130948 AMENDED COMPOSITE I

7071007.D07/10/13 02:12 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly zukowskim 07/10/13 02:573.77

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/10/13 02:573.98

07/31/2013Page 18 of 5251

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP7 76936

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LCS 180-76936/5

7071008.D07/10/13 02:40 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly zukowskim 07/10/13 03:072.00

Bromomethane Peak Integrated Incorrectly zukowskim 07/10/13 03:072.53

Acrolein Peak Integrated Incorrectly zukowskim 07/10/13 03:083.49

Acetone Peak Integrated Incorrectly zukowskim 07/10/13 03:083.75

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/10/13 03:083.88 tert-Butyl alcohol Peak Integrated Incorrectly zukowskim 07/10/13 03:084.77

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/10/13 03:086.18

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-4 MS #20130948 AMENDED COMPOSITE I MS

7071009.D07/10/13 03:09 GC Column: DB-624 ID: 0.18(mm)

Bromomethane Peak Integrated Incorrectly zukowskim 07/10/13 03:372.51

Acrolein Peak Integrated Incorrectly zukowskim 07/10/13 03:393.50

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/10/13 03:383.84 tert-Butyl alcohol Peak Integrated Incorrectly zukowskim 07/10/13 03:394.84

2-Butanone (MEK) Peak Integrated Incorrectly zukowskim 07/10/13 03:386.18

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-4 MSD #20130948 AMENDED COMPOSITE I MSD

7071010.D07/10/13 03:35 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly zukowskim 07/10/13 04:051.93

Bromomethane Peak Integrated Incorrectly zukowskim 07/10/13 04:052.48

Acrolein Peak Integrated Incorrectly zukowskim 07/10/13 04:073.48

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/10/13 04:063.82 tert-Butyl alcohol Peak Integrated Incorrectly zukowskim 07/10/13 04:074.87

07/31/2013Page 19 of 5251

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:HP7 76936

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-3 #20130951 AMENDED COMPOSITE L

7071023.D07/10/13 09:17 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 07/10/13 10:103.78

Carbon disulfide Peak Integrated Incorrectly gordonk 07/10/13 10:103.95

Methylene Chloride Peak Integrated Incorrectly gordonk 07/10/13 10:104.41

07/31/2013Page 20 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:71 77297

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/3

S07110C1.D07/11/13 21:05 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Peak Integrated Incorrectly bungardf 07/11/13 21:471.80

N-Nitrosodimethylamine Peak Integrated Incorrectly bungardf 07/11/13 21:472.46

Isophorone Peak Integrated Incorrectly bungardf 07/11/13 21:477.08

2-Nitrophenol Peak Integrated Incorrectly bungardf 07/11/13 21:477.17

4-Nitrophenol Peak Integrated Incorrectly bungardf 07/11/13 21:489.23

2-Naphthylamine Peak Integrated Incorrectly bungardf 07/11/13 21:489.49

4-Nitroaniline Peak Integrated Incorrectly bungardf 07/11/13 21:489.66

4,6-Dinitro-2-methylphenol Peak Integrated Incorrectly bungardf 07/11/13 21:489.69

2,4,6-Tribromophenol Peak Integrated Incorrectly bungardf 07/11/13 21:499.89

Atrazine Peak Integrated Incorrectly bungardf 07/11/13 21:4810.22

Di-n-butyl phthalate Peak Integrated Incorrectly bungardf 07/11/13 21:4811.06

Benzidine Peak Integrated Incorrectly bungardf 07/11/13 21:4912.01

3,3'-Dichlorobenzidine Peak Integrated Incorrectly bungardf 07/11/13 21:4914.03

Bis(2-ethylhexyl) phthalate Peak Integrated Incorrectly bungardf 07/11/13 21:4914.07

Di-n-octyl phthalate Peak Integrated Incorrectly bungardf 07/11/13 21:4915.38

Benzo[a]pyrene Peak Integrated Incorrectly bungardf 07/11/13 21:4916.98

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/11/13 21:4919.35

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/11/13 21:4919.38

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/11/13 21:4919.96

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/4

S07110C2.D07/11/13 21:31 GC Column: Rxi-5SilMS ID: 0.32(mm)

Di-n-octyl phthalate Peak Not Found bungardf 07/11/13 22:0615.38

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/11/13 22:0616.33

8270C

07/31/2013Page 21 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:71 77297

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/5

S07110C3.D07/11/13 21:58 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/11/13 22:222.53

Benzoic acid Peak Integrated Incorrectly bungardf 07/11/13 22:227.23

Di-n-octyl phthalate Peak Integrated Incorrectly bungardf 07/11/13 22:2315.39

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-77297/6

S07110C4.D07/11/13 22:24 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/11/13 22:522.51

Benzoic acid Peak Integrated Incorrectly bungardf 07/11/13 22:537.25

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/11/13 22:5310.36

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/7

S07110C5.D07/11/13 22:51 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzoic acid Peak Integrated Incorrectly bungardf 07/14/13 21:187.27

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/14/13 21:1810.36

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/8

S07110C6.D07/11/13 23:17 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/14/13 21:192.50

Benzoic acid Peak Integrated Incorrectly bungardf 07/14/13 21:207.29

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/14/13 21:2010.36

07/31/2013Page 22 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:71 77297

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/9

S07110C7.D07/11/13 23:44 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/14/13 21:212.50

Benzoic acid Peak Integrated Incorrectly bungardf 07/14/13 21:227.31

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/14/13 21:2210.36

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-77297/10

S07110C8.D07/12/13 00:10 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/14/13 21:232.49

Benzoic acid Peak Integrated Incorrectly bungardf 07/14/13 21:247.32

07/31/2013Page 23 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:71 77550

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCVIS 180-77550/19

S07150C1.D07/16/13 01:19 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzoic acid Peak Integrated Incorrectly bungardf 07/16/13 01:447.26

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/16/13 01:4210.36

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LCS 180-77168/2-A

S0715002.D07/16/13 02:37 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/16/13 03:042.52 bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/16/13 03:046.57

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-4 MS #20130948 AMENDED COMPOSITE I MS

S0715003.D07/16/13 03:04 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/16/13 03:282.52 bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/16/13 03:286.57

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-4 MSD #20130948 AMENDED COMPOSITE I MSD

S0715004.D07/16/13 03:31 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/16/13 03:572.53 bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/16/13 03:576.57

Benzidine Peak Integrated Incorrectly bungardf 07/16/13 03:5812.01

07/31/2013Page 24 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:71 77550

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-1 #20130929 COMPOSITE L

S0715005.D07/16/13 03:57 GC Column: Rxi-5SilMS ID: 0.32(mm)

Phenanthrene Peak Integrated Incorrectly bungardf 07/16/13 04:2110.57

Anthracene Peak Integrated Incorrectly bungardf 07/16/13 04:2110.62

Benzo[a]anthracene Peak Integrated Incorrectly bungardf 07/16/13 04:2114.11

Benzo[a]pyrene Peak Integrated Incorrectly bungardf 07/16/13 04:2216.97

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/16/13 04:2219.35

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/16/13 04:2219.98

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-3 #20130951 AMENDED COMPOSITE L

S0715006.D07/16/13 04:24 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[b]fluoranthene Peak Integrated Incorrectly bungardf 07/17/13 00:5416.28

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/17/13 00:5416.33

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/17/13 00:5419.34

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/17/13 00:5419.97

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-4 #20130948 AMENDED COMPOSITE I

S0715007.D07/16/13 04:51 GC Column: Rxi-5SilMS ID: 0.32(mm)

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/17/13 00:5619.35

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/17/13 00:5619.95

07/31/2013Page 25 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:71 77550

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-5 SRM Amended

S0715008.D07/16/13 05:18 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[a]anthracene Peak Integrated Incorrectly bungardf 07/17/13 00:5814.11

Benzo[b]fluoranthene Peak Integrated Incorrectly bungardf 07/17/13 00:5816.29

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/17/13 00:5916.32

07/31/2013Page 26 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:722 74231

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/1

F06060C1.D06/05/13 22:26 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 07:592.45

2,4-Dinitrophenol Peak Integrated Incorrectly bungardf 06/06/13 00:459.26

2,4,6-Tribromophenol Peak Not Found addisonc 06/07/13 08:069.97

Bis(2-ethylhexyl) phthalate Poor Chromatography addisonc 06/07/13 08:0114.45

Di-n-octyl phthalate Poor Chromatography addisonc 06/07/13 08:0115.84

Benzo[k]fluoranthene Unspecified bungardf 06/06/13 00:4716.77

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 06/07/13 08:0519.96

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/2

F06060C2.D06/05/13 22:53 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Peak Integrated Incorrectly bungardf 06/06/13 00:481.70

N-Nitrosodimethylamine Peak Integrated Incorrectly bungardf 06/06/13 00:482.29

Pyridine Poor Chromatography addisonc 06/07/13 08:062.40

Benzoic acid Peak Integrated Incorrectly bungardf 06/06/13 00:497.20

2,4-Dinitrophenol Peak Integrated Incorrectly bungardf 06/06/13 00:509.24

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:0810.45

Dibenz(a,h)anthracene Poor Chromatography addisonc 06/07/13 08:0819.97

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/3

F06060C3.D06/05/13 23:19 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:112.38

Benzoic acid Poor Chromatography addisonc 06/07/13 08:127.21

2,4-Dinitrophenol Peak Integrated Incorrectly bungardf 06/06/13 00:539.24

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:1210.44

07/31/2013Page 27 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:722 74231

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-74231/4

F06060C4.D06/05/13 23:46 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:132.37

Benzoic acid Poor Chromatography addisonc 06/07/13 08:147.23

2-Chloronaphthalene Peak Not Found addisonc 06/07/13 08:148.67

Hexadecane Poor Chromatography addisonc 06/07/13 08:159.59

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:1510.45

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/5

F06060C5.D06/06/13 00:13 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:162.35

Benzoic acid Poor Chromatography addisonc 06/07/13 08:177.24

2-Chloronaphthalene Poor Chromatography addisonc 06/07/13 08:178.67

2,4-Dinitrophenol Peak Integrated Incorrectly bungardf 06/06/13 00:559.23

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:1810.44

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/6

F06060C6.D06/06/13 00:40 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:182.36

Benzoic acid Peak Not Found addisonc 06/07/13 08:197.27

2,4-Dinitrophenol Peak Integrated Incorrectly bungardf 06/06/13 01:049.24

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:2010.44

07/31/2013Page 28 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:722 74231

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/7

F06060C7.D06/06/13 01:07 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:512.35

Benzoic acid Poor Chromatography addisonc 06/07/13 08:527.28

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:5210.44

Benzo[b]fluoranthene Poor Chromatography addisonc 06/07/13 08:5316.69

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/8

F06060C8.D06/06/13 01:33 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:532.34

Benzoic acid Poor Chromatography addisonc 06/07/13 08:547.29

1,3-Dinitrobenzene Unspecified bungardf 06/06/13 02:058.94

Hexadecane Unspecified bungardf 06/06/13 02:139.58

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:5510.44

07/31/2013Page 29 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:722 77135

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCVIS 180-77135/4

F07090C1.D07/10/13 00:06 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/10/13 00:292.32

Benzoic acid Peak Integrated Incorrectly bungardf 07/10/13 00:307.20

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/10/13 00:3010.41

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LCS 180-76817/2-A

F0709009.D07/10/13 02:50 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/10/13 03:162.31 bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/10/13 03:166.46

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/10/13 03:1810.37

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-2 MS #20130926 COMPOSITE I MS

F0709010.D07/10/13 05:05 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/11/13 17:422.33 bis (2-chloroisopropyl) ether Unspecified bungardf 07/11/13 17:456.46

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/11/13 17:4320.17

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/11/13 17:4420.89

07/31/2013Page 30 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:722 77135

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-2 MSD #20130926 COMPOSITE I MSD

F0709011.D07/10/13 05:32 GC Column: Rxi-5SilMS ID: 0.32(mm)

N-Nitrosodimethylamine Peak Integrated Incorrectly bungardf 07/11/13 17:452.27

Pyridine Peak Integrated Incorrectly bungardf 07/11/13 17:452.33 bis (2-chloroisopropyl) ether Unspecified bungardf 07/11/13 17:456.46

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/11/13 17:4620.17

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/11/13 17:4620.88

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22826-2 #20130926 COMPOSITE I

F0709012.D07/10/13 05:59 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/11/13 17:4816.77

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/11/13 17:4820.11

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/11/13 17:4820.83

07/31/2013Page 31 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:732 74298

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/4

D0607IC1.D06/07/13 09:17 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Peak Not Found addisonc 06/07/13 12:141.53

N-Nitrosodimethylamine Poor Chromatography addisonc 06/07/13 12:142.10

Pyridine Poor Chromatography addisonc 06/07/13 12:142.21

Isophorone Peak Not Found addisonc 06/07/13 12:157.00

Butyl benzyl phthalate Peak Not Found addisonc 06/07/13 12:1513.39

3,3'-Dichlorobenzidine Peak Not Found addisonc 06/07/13 12:1514.39

Bis(2-ethylhexyl) phthalate Peak Not Found addisonc 06/07/13 12:1514.44

Di-n-octyl phthalate Peak Not Found addisonc 06/07/13 12:1515.76

7,12-Dimethylbenz(a)anthracene Peak Not Found addisonc 06/07/13 12:1616.60

Indeno[1,2,3-cd]pyrene Peak Not Found addisonc 06/07/13 12:1619.82

Dibenz(a,h)anthracene Peak Not Found addisonc 06/07/13 12:1619.84

Benzo[g,h,i]perylene Poor Chromatography addisonc 06/07/13 12:1620.51

07/31/2013Page 32 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:732 74298

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/5

D0607IC2.D06/07/13 10:39 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Poor Chromatography piccolino v

06/10/13 08:221.52

Pyridine Peak Not Found addisonc 06/07/13 12:162.17

Benzoic acid Poor Chromatography addisonc 06/07/13 12:167.17

3,3'-Dichlorobenzidine Poor Chromatography piccolino v

06/10/13 08:2314.39

Chrysene Poor Chromatography piccolino v

06/10/13 08:2414.52

Benzo[k]fluoranthene Poor Chromatography piccolino v

06/10/13 08:2416.67

Benzo[a]pyrene Poor Chromatography addisonc 06/07/13 12:1717.28

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 06/07/13 12:1719.81

Dibenz(a,h)anthracene Poor Chromatography addisonc 06/07/13 12:1719.85

Benzo[g,h,i]perylene Poor Chromatography addisonc 06/07/13 12:1720.51

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/6

D0607IC3.D06/07/13 11:06 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 12:182.15

Benzoic acid Poor Chromatography addisonc 06/07/13 12:187.18

2,3,4,6-Tetrachlorophenol Poor Chromatography piccolino v

06/10/13 08:259.51

Pentachlorophenol Poor Chromatography addisonc 06/07/13 12:1910.46

Chrysene-d12 Poor Chromatography addisonc 06/07/13 12:1814.48

7,12-Dimethylbenz(a)anthracene Poor Chromatography addisonc 06/07/13 12:1916.59

Benzo[k]fluoranthene Poor Chromatography piccolino v

06/10/13 08:2516.67

Dibenz(a,h)anthracene Poor Chromatography piccolino v

06/10/13 08:2519.85

Benzo[g,h,i]perylene Poor Chromatography addisonc 06/07/13 12:1920.50

07/31/2013Page 33 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22826-1

Instrument ID: Analysis Batch Number:732 74298

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-74298/7

D0607IC4.D06/07/13 11:33 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 12:092.17

Benzoic acid Poor Chromatography addisonc 06/07/13 12:107.20

2,3,4,6-Tetrachlorophenol Poor Chromatography piccolino v

06/10/13 08:269.51

2-Naphthylamine Poor Chromatography piccolino v

06/10/13 08:269.54

Pentachlorophenol Poor Chromatography addisonc 06/07/13 12:1110.46

Benzo[k]fluoranthene Poor Chromatography piccolino v

06/10/13 08:2716.66

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 06/07/13 12:1119.81

Dibenz(a,h)anthracene Poor Chromatography piccolino v

06/10/13 08:2719.84

Benzo[g,h,i]perylene Poor Chromatography piccolino v

06/10/13 08:2720.50

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74298/8

D0607IC5.D06/07/13 12:01 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 12:422.17

Benzoic acid Poor Chromatography addisonc 06/07/13 12:437.22

Pentachlorophenol Poor Chromatography addisonc 06/07/13 12:4310.46

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 06/07/13 12:4419.80

Dibenz(a,h)anthracene Poor Chromatography addisonc 06/07/13 12:4419.86

07/31/2013Page 34 of 5251

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY