J22654-1_Analytical_Report_(1_of_2).pdf

ANALYTICAL REPORT

Job Number: 180-22654-1

Job Description: Newark Bay - Upland 33-061

For:

Battelle

397 Washington Street Duxbury, MA 02332

Attention: Elisabeth Barrows

Approved for release.

Jill L Colussy Project Manager I

7/29/2013 3:14 PM

Designee for Carrie L Gamber, Senior Project Manager 301 Alpha Drive, Pittsburgh, PA, 15238

(412)963-2428 carrie.gamber@testamericainc.com

07/29/2013

The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to the NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written approval of the laboratory. This report is confidential and is intended for the sole use of TestAmerica and its client. All questions regarding this report should be directed to the TestAmerica Project Manager or designee who has signed this report.

TestAmerica Laboratories, Inc.

TestAmerica Pittsburgh 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238

Tel (412) 963-7058 Fax (412) 963-2468 www.testamericainc.com mailto:carrie.gamber@testamericainc.com http://www.testamericainc.com http://

Table of Contents Cover Title Page

Data Summaries

Report Narrative

Manual Integration Summary

Sample Summary

Executive Summary

Method Summary

Method / Analyst Summary

Sample Datasheets

Surrogate Summary

QC Data Summary

Data Qualifiers

QC Association Summary

Lab Chronicle

Reagent Traceability

COAs

Certification Summary

Organic Sample Data

GC/MS VOA

Method 8260B Method 8260B QC Summary Method 8260B Sample Data Standards Data

Method 8260B ICAL Data Method 8260B CCAL Data

Raw QC Data

Method 8260B Tune Data Method 8260B Blank Data Method 8260B LCS/LCSD Data Method 8260B MS/MSD Data

Method 8260B Run Logs Method 8260B Prep Data

GC/MS Semi VOA

Method 8270C Method 8270C QC Summary Method 8270C Sample Data Standards Data

Method 8270C ICAL Data Method 8270C CCAL Data

Raw QC Data Method 8270C Tune Data Method 8270C Blank Data Method 8270C LCS/LCSD Data Method 8270C MS/MSD Data

Method 8270C Run Logs Method 8270C Prep Data

GC Semi VOA

Method 8081A Method 8081A QC Summary Method 8081A Sample Data Standards Data

Method 8081A ICAL Data

Method 8081A PEM Data Method 8081A CCAL Data

Raw QC Data Method 8081A Blank Data Method 8081A LCS/LCSD Data Method 8081A MS/MSD Data

Method 8081A Run Logs Method 8081A Prep Data

Method 8082 Method 8082 QC Summary Method 8082 Sample Data Standards Data

Method 8082 ICAL Data Method 8082 CCAL Data

Raw QC Data Method 8082 Blank Data Method 8082 LCS/LCSD Data Method 8082 MS/MSD Data

Method 8082 Run Logs Method 8082 Prep Data

Method 8151A Method 8151A QC Summary Method 8151A Sample Data Standards Data

Method 8151A ICAL Data Method 8151A CCAL Data

Raw QC Data

Method 8151A Blank Data Method 8151A LCS/LCSD Data Method 8151A MS/MSD Data

Method 8151A Run Logs Method 8151A Prep Data

Inorganic Sample Data

Metals Data

Met Cover Page

Met Sample Data

Met QC Data Met ICV/CCV Met CRQL Met Blanks Met ICSA/ICSAB Met MS/MSD/PDS Met LCS/LCSD Met Serial Dilution

Met MDL

Met IECF

Met Linear Ranges

Met Preparation Log

Met Analysis Run Log

Met Raw Data

Met Prep Data

General Chemistry Data

Gen Chem Cover Page

Gen Chem Sample Data

Gen Chem QC Data Gen Chem ICV/CCV Gen Chem Blanks Gen Chem MS/MSD/PDS Gen Chem Duplicates Gen Chem LCS/LCSD

Gen Chem MDL

Gen Chem Preparation Log

Gen Chem Analysis Run Log

Gen Chem Raw Data

Gen Chem Prep Data

Subcontracted Data

Shipping and Receiving Documents

Client Chain of Custody

Sample Receipt Checklist

CASE NARRATIVE

Client: Battelle

Project: Newark Bay - Upland 33-061

Report Number: 180-22654-1

With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.

Calculations are performed before rounding to avoid round-off errors in calculated results.

All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the individual sections below.

RECEIPT

The samples were received on 06/28/2013; the samples arrived in good condition and properly preserved. The cooler temperatures were outside of the proper range at 6.2º C and 7.7º C.

SPLP VOLATILE ORGANIC COMPOUNDS (GC-MS)

The matrix spike and matrix spike duplicate of sample #20130940 AMENDED COMP A (180-22654-8) recovered outside of the control limits for several compounds. The relative percent difference between the matrix spike and the matrix spike duplicate was outside of the control limits for trichllorofluoromethane.

VOLATILE ORGANIC COMPOUNDS (GC-MS)

Several samples had surrogate Dibromofluoromethane recover low and outside of the control limits. These samples were re-extracted.

The re-extracts also had this surrogate recover low and outside of the control limits confirming matrix interference. Both sets of data are reported.

The laboratory control standard for batch 180-76559 recovered outside of the control limits for several compounds. All control compounds recovered within the control limits. All data was reported.

The matrix spike duplicate of sample 20130918 COMPOSITE A (180-22654-1) recovered outside of the control limits for acrolein.

SPLP SEMIVOLATILE ORGANIC COMPOUNDS (GC-MS)

No difficulties were encountered during the analysis.

SEMIVOLATILE ORGANIC COMPOUNDS (GC-MS)

Due to the concentration of target compounds detected and/or matrix, the samples were analyzed at a dilution. As such, the surrogate concentration(s) will be considered as estimated and elevated reporting limits (RLs) are provided.

The method blank for batch 180-76465 had diethyl phthalate detected at a level that was above the method detection limit but below the reporting limit. The value should be considered an estimate, and has been flagged. If the associated sample reported a result above the

MDL and/or RL, the result has been flagged.

The laboratory control standard for batch 180-76477 recovered outside of the control limits for benzidine. All control compounds recovered within the control limits. All data was reported.

The matrix spike and matrix spike duplicate of sample #20130943 AMENDED COMP D (180-22654-9) recovered outside of the control limits for several compounds. The relative percent difference between the matrix spike and the matrix spike duplicate was outside of the control limits for 2,4,5-Trichlorophenol, 2,4,6-Trichlorophenol and 4-Nitrophenol.

SPLP PESTICIDES

No difficulties were encountered during the analysis.

PESTICIDES

Due to the concentration of target compounds detected and/or matrix, the samples were analyzed at a dilution. Elevated reporting limits

(RLs) are provided.

The matrix spike and matrix spike duplicate of sample #20130943 AMENDED COMP D (180-22654-9) recovered outside of the control limits for several compounds.

SPLP PCBS

No difficulties were encountered during the analysis.

PCBS

Due to the concentration of PCBS detected and/or matrix, the samples were analyzed at a dilution. Elevated reporting limits (RLs) are provided.

SPLP HERBICIDES

No difficulties were encountered during the analysis.

HERBICIDES

No difficulties were encountered during the analysis.

SPLP METALS

The presence of the '4' qualifier in the data indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.

The serial dilution of sample #20130940 AMENDED COMP A (180-22654-8) (180-22654-8) was outside of the percent difference control limits for aluminum.

METALS

Samples #20130944 AMEDNED COMP E (180-22654-10), #20130946 AMENDED COMP G (180-22654-11), #20130949 AMENDED

COMP J (180-22654-12), #20130955 AMENDED COMP P (180-22654-13), and #20130959 AMENDED COMP T (180-22654-14) were over the instruments linear range for calcium and required a dilution. Elevated reporting limits (RLs) are provided.

Samples #20130944 AMEDNED COMP E (180-22654-10)[2X] and #20130959 AMENDED COMP T (180-22654-14)[2X] were over the instruments calibration range for mercury and required a dilution. The reporting limits have been adjusted accordingly.

Several analytes were detected in method blank MB 180-77451/1-A at levels that were above the method detection limit but below the reporting limit. The values should be considered estimates, and have been flagged. If the associated sample reported a result above the

MDL and/or RL, the result has been flagged.

The matrix spike and matrix spike duplicate of sample #20130921 COMPOSITE D (180-22654-2) recovered outside of the control limits for several compounds. The relative percent difference between the matrix spike and the matrix spike duplicate was outside of the control limits for calcium.

The presence of the '4' qualifier in the data indicates analytes where the concentration in the unspiked sample exceeded four times the spiking amount.

The serial dilution of sample #20130921 COMPOSITE D (180-22654-2) was outside of the percent difference control limits for several compounds.

GENERAL CHEMISTRY

The matrix spike and matrix spike duplicate of SPLP sample #20130940 AMENDED COMP A (180-22654-8) in batch 180-76419 recovered outside of the control limits for CR(VI).

The spikes of sample #20130918 COMPOSITE ADU (180-22654-1) recovered outside of the control limits for hexavalent chromium. The samples were re-digested and re-analyzed. The spikes again recovered outside of the control limits confirming matrix interference. Both sets of data are reported.

DIOXINS

This method was subcontracted to TestAmerica Knoxville. The subcontract certification is different from those listed on the TestAmerica cover page of this final report.

Lab Name: Job No.:

SDG No.:

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP3 76109

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/2

3062803.D06/28/13 06:41 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:391.76

Trichlorofluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:402.96

Acrolein Peak Integrated Incorrectly gordonk 06/28/13 07:423.59

1,1-Dichloroethene Peak Integrated Incorrectly gordonk 06/28/13 07:403.74

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly gordonk 06/28/13 07:393.82

Carbon disulfide Peak Integrated Incorrectly gordonk 06/28/13 07:404.06 tert-Butyl alcohol Peak Integrated Incorrectly gordonk 06/28/13 07:414.80

Hexane Peak Integrated Incorrectly gordonk 06/28/13 07:425.39

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 07:416.33

Bromochloromethane Peak Integrated Incorrectly gordonk 06/28/13 07:406.57

Isobutyl alcohol Peak Integrated Incorrectly gordonk 06/28/13 07:427.24

Ethyl methacrylate Peak Integrated Incorrectly gordonk 06/28/13 07:429.62

1,2-Dibromo-3-Chloropropane Peak Integrated Incorrectly gordonk 06/28/13 07:4114.19

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/3

3062804.D06/28/13 07:06 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:441.76

Chloroethane Peak Integrated Incorrectly gordonk 06/28/13 07:442.60

Carbon disulfide Peak Integrated Incorrectly gordonk 06/28/13 07:444.05

Methylene Chloride Peak Integrated Incorrectly gordonk 06/28/13 07:454.54

2,2-Dichloropropane Peak Integrated Incorrectly gordonk 06/28/13 07:456.30

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 07:456.33

1,1,1-Trichloroethane Peak Integrated Incorrectly gordonk 06/28/13 07:456.89

8260B

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP3 76109

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/4

3062805.D06/28/13 07:32 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly gordonk 06/28/13 07:471.76

1,1-Dichloroethene Peak Integrated Incorrectly gordonk 06/28/13 07:483.73

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly gordonk 06/28/13 07:473.81

Acetone Peak Integrated Incorrectly gordonk 06/28/13 07:483.85

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 07:486.33

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-76109/5

3062806.D06/28/13 07:58 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 06/28/13 07:593.87

Iodomethane Peak Integrated Incorrectly gordonk 06/28/13 08:003.95

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/6

3062807.D06/28/13 08:20 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 06/28/13 08:363.86

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 06/28/13 08:376.33

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/7

3062808.D06/28/13 08:46 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly gordonk 06/28/13 08:533.59

Acetone Peak Integrated Incorrectly gordonk 06/28/13 08:533.86

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP3 76109

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-76109/8

3062809.D06/28/13 09:11 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 06/28/13 09:173.86

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP3 76260

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-14 #20130959 AMENDED COMP T

3070115.D07/01/13 10:04 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 07/01/13 10:103.85

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-4 #20130927 COMPOSITE J

3070118.D07/01/13 11:10 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 07/01/13 11:133.85

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-5 #20130933 COMPOSITE P

3070120.D07/01/13 11:53 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 07/02/13 04:003.85

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-13 RA #20130955 AMENDED COMP P RA

3070121.D07/01/13 12:15 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly gordonk 07/02/13 03:574.07

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-12 RA #20130949 AMENDED COMP J RA

3070125.D07/01/13 13:44 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly gordonk 07/02/13 04:254.06

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP3 76356

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCVIS 180-76356/2

3070202.D07/02/13 04:47 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 07/02/13 04:543.86

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-8 #20130940 AMENDED COMP A

3070205.D07/02/13 06:14 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly gordonk 07/02/13 06:253.85

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 07/02/13 06:256.32

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-8 RA #20130940 AMENDED COMP A RA

3070207.D07/02/13 06:59 GC Column: DB-624 ID: 0.18(mm)

2-Butanone (MEK) Peak Integrated Incorrectly gordonk 07/02/13 07:006.33

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-10 RA #20130944 AMEDNED COMP E RA

3070218.D07/02/13 11:06 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly gordonk 07/02/13 11:134.07

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP7 62175

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-62175/2

7012704.D01/27/13 17:47 GC Column: DB-624 ID: 0.18(mm)

Ethyl ether Peak Integrated Incorrectly journetp 01/28/13 07:493.31 tert-Butyl alcohol Peak Integrated Incorrectly journetp 01/28/13 07:514.63

Hexane Peak Integrated Incorrectly journetp 01/28/13 07:545.21 n-Butyl alcohol Peak Integrated Incorrectly journetp 01/28/13 07:597.78

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-62175/3

7012705.D01/27/13 18:12 GC Column: DB-624 ID: 0.18(mm)

Ethyl ether Peak Integrated Incorrectly journetp 01/28/13 07:513.30

Hexane Peak Integrated Incorrectly journetp 01/28/13 07:545.18 n-Butyl alcohol Peak Integrated Incorrectly journetp 01/28/13 07:597.78

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-62175/4

7012706.D01/27/13 18:37 GC Column: DB-624 ID: 0.18(mm)

Ethyl ether Peak Integrated Incorrectly journetp 01/28/13 07:513.31 tert-Butyl alcohol Peak Integrated Incorrectly journetp 01/28/13 07:524.63 n-Butyl alcohol Peak Integrated Incorrectly journetp 01/28/13 07:597.77

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP7 62175

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-62175/5

7012707.D01/27/13 19:02 GC Column: DB-624 ID: 0.18(mm)

Ethyl ether Peak Integrated Incorrectly journetp 01/28/13 07:503.33 tert-Butyl alcohol Peak Integrated Incorrectly journetp 01/28/13 07:524.63 n-Butyl alcohol Peak Integrated Incorrectly journetp 01/28/13 07:597.77

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-62175/6

7012708.D01/27/13 19:27 GC Column: DB-624 ID: 0.18(mm)

Ethyl ether Peak Integrated Incorrectly journetp 01/28/13 07:503.31 n-Butyl alcohol Peak Integrated Incorrectly journetp 01/28/13 07:597.77

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-62175/7

7012709.D01/27/13 19:52 GC Column: DB-624 ID: 0.18(mm)

Tetrahydrofuran Peak Integrated Incorrectly journetp 01/28/13 07:586.44 n-Butyl alcohol Peak Integrated Incorrectly journetp 01/28/13 07:597.78

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-62175/8

7012712.D01/27/13 21:07 GC Column: DB-624 ID: 0.18(mm)

Ethyl ether Peak Integrated Incorrectly journetp 01/28/13 07:503.34 tert-Butyl alcohol Peak Integrated Incorrectly journetp 01/28/13 07:524.63

Hexane Peak Integrated Incorrectly journetp 01/28/13 07:535.20

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP7 62406

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-62406/2

7013002.D01/29/13 23:13 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly zukowskim 01/29/13 23:543.49

Iodomethane Peak Integrated Incorrectly zukowskim 01/29/13 23:543.82

Allyl chloride Peak Integrated Incorrectly zukowskim 01/29/13 23:544.23

Propionitrile Peak Integrated Incorrectly zukowskim 01/29/13 23:546.21

Methacrylonitrile Peak Integrated Incorrectly zukowskim 01/29/13 23:546.38

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-62406/3

7013003.D01/29/13 23:54 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly zukowskim 01/30/13 00:573.50

Iodomethane Peak Integrated Incorrectly zukowskim 01/30/13 00:573.83

Allyl chloride Peak Integrated Incorrectly zukowskim 01/30/13 00:584.24

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-62406/6

7013006.D01/30/13 01:23 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly zukowskim 01/30/13 01:583.49

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP7 73309

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-73309/2

7052903.D05/29/13 10:55 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly journetp 05/29/13 13:061.91

Chloromethane Peak Integrated Incorrectly journetp 05/29/13 13:072.02

Vinyl chloride Peak Integrated Incorrectly journetp 05/29/13 13:082.15

Bromomethane Peak Integrated Incorrectly journetp 05/29/13 13:092.49

Chloroethane Peak Integrated Incorrectly journetp 05/29/13 13:092.58

Trichlorofluoromethane Peak Integrated Incorrectly journetp 05/29/13 13:092.89

1,1-Dichloroethene Peak Integrated Incorrectly journetp 05/29/13 13:103.54

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly journetp 05/29/13 13:093.70

Carbon disulfide Peak Integrated Incorrectly journetp 05/29/13 13:103.83

Acetone Peak Integrated Incorrectly journetp 05/29/13 13:103.84

Methyl acetate Peak Integrated Incorrectly journetp 05/29/13 13:134.31

Methylene Chloride Peak Integrated Incorrectly journetp 05/29/13 13:104.36 trans-1,2-Dichloroethene Peak Integrated Incorrectly journetp 05/29/13 13:104.74

MTBE Peak Integrated Incorrectly journetp 05/29/13 13:114.85

1,1-Dichloroethane Peak Integrated Incorrectly journetp 05/29/13 13:115.34 cis-1,2-Dichloroethene Peak Integrated Incorrectly journetp 05/29/13 13:116.09

2,2-Dichloropropane Peak Integrated Incorrectly journetp 05/29/13 13:116.12

2-Butanone (MEK) Peak Integrated Incorrectly journetp 05/29/13 13:126.18

1,1,1-Trichloroethane Peak Integrated Incorrectly journetp 05/29/13 13:126.68

Cyclohexane Peak Integrated Incorrectly journetp 05/29/13 13:136.74

Carbon tetrachloride Peak Integrated Incorrectly journetp 05/29/13 13:126.86

1,2-Dichloroethane Peak Integrated Incorrectly journetp 05/29/13 13:127.12

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP7 73309

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-73309/3

7052904.D05/29/13 11:21 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly journetp 05/29/13 13:521.91

Chloromethane Peak Integrated Incorrectly journetp 05/29/13 13:521.98

Chloroethane Peak Integrated Incorrectly journetp 05/29/13 13:522.58

Trichlorofluoromethane Peak Integrated Incorrectly journetp 05/29/13 13:522.95

1,1-Dichloroethene Peak Integrated Incorrectly journetp 05/29/13 13:523.56

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly journetp 05/29/13 13:523.66

Acetone Peak Integrated Incorrectly journetp 05/29/13 13:533.83

Carbon disulfide Peak Integrated Incorrectly journetp 05/29/13 13:533.85

Methyl acetate Unspecified journetp 05/29/13 13:514.28

Methylene Chloride Peak Integrated Incorrectly journetp 05/29/13 13:534.36 trans-1,2-Dichloroethene Peak Integrated Incorrectly journetp 05/29/13 13:534.78

MTBE Peak Integrated Incorrectly journetp 05/29/13 13:534.85

1,1-Dichloroethane Peak Integrated Incorrectly journetp 05/29/13 13:535.34

2,2-Dichloropropane Peak Integrated Incorrectly journetp 05/29/13 13:546.10

2-Butanone (MEK) Peak Integrated Incorrectly journetp 05/29/13 13:546.17

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP7 73309

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-73309/4

7052905.D05/29/13 11:47 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly journetp 05/29/13 13:561.95

Chloromethane Peak Integrated Incorrectly journetp 05/29/13 13:562.03

Bromomethane Peak Integrated Incorrectly journetp 05/29/13 13:572.49

Chloroethane Peak Integrated Incorrectly journetp 05/29/13 13:572.62

Trichlorofluoromethane Peak Integrated Incorrectly journetp 05/29/13 13:572.95

1,1-Dichloroethene Peak Integrated Incorrectly journetp 05/29/13 13:583.58

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly journetp 05/29/13 13:583.73

Acetone Peak Integrated Incorrectly journetp 05/29/13 13:583.79

Methyl acetate Peak Integrated Incorrectly journetp 05/29/13 13:594.30 trans-1,2-Dichloroethene Peak Integrated Incorrectly journetp 05/29/13 13:594.76

1,1-Dichloroethane Peak Integrated Incorrectly journetp 05/29/13 13:595.36 cis-1,2-Dichloroethene Peak Integrated Incorrectly journetp 05/29/13 13:596.10

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-73309/5

7052906.D05/29/13 12:23 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly journetp 05/29/13 14:001.94

Chloromethane Peak Integrated Incorrectly journetp 05/29/13 14:002.01

Vinyl chloride Peak Integrated Incorrectly journetp 05/29/13 14:002.22

Bromomethane Peak Integrated Incorrectly journetp 05/29/13 14:002.48

Trichlorofluoromethane Peak Integrated Incorrectly journetp 05/29/13 14:012.99

1,1-Dichloroethene Peak Integrated Incorrectly journetp 05/29/13 14:013.55

1,1,2-Trichloro-1,2,2-trifluoroet hane

Peak Integrated Incorrectly journetp 05/29/13 14:013.66

Acetone Peak Integrated Incorrectly journetp 05/29/13 14:013.77

Methyl acetate Peak Integrated Incorrectly journetp 05/29/13 13:594.30

Methylene Chloride Peak Integrated Incorrectly journetp 05/29/13 14:014.34

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP7 73309

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-73309/6

7052907.D05/29/13 12:59 GC Column: DB-624 ID: 0.18(mm)

Dichlorodifluoromethane Peak Integrated Incorrectly journetp 05/30/13 09:461.93

Trichlorofluoromethane Peak Integrated Incorrectly journetp 05/30/13 08:012.94

Methyl acetate Peak Integrated Incorrectly journetp 05/29/13 14:024.28

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-73309/7

7052908.D05/29/13 14:42 GC Column: DB-624 ID: 0.18(mm)

Chloroethane Peak Integrated Incorrectly journetp 05/29/13 15:412.59

Trichlorofluoromethane Peak Integrated Incorrectly journetp 05/29/13 15:412.96

Acetone Peak Integrated Incorrectly journetp 05/29/13 15:423.81

2-Butanone (MEK) Peak Integrated Incorrectly journetp 05/29/13 15:426.17

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-73309/8

7052909.D05/29/13 15:13 GC Column: DB-624 ID: 0.18(mm)

Chloroethane Peak Integrated Incorrectly journetp 05/29/13 15:432.59

Trichlorofluoromethane Peak Integrated Incorrectly journetp 05/29/13 15:432.88

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP7 76559

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCVIS 180-76559/2

7070303.D07/03/13 08:47 GC Column: DB-624 ID: 0.18(mm)

Chloroethane Peak Integrated Incorrectly journetp 07/03/13 09:142.67

Trichlorofluoromethane Peak Integrated Incorrectly journetp 07/03/13 09:143.01

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCV 180-76559/3

7070304.D07/03/13 09:24 GC Column: DB-624 ID: 0.18(mm)

Acrolein Peak Integrated Incorrectly journetp 07/03/13 10:473.49

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-8 #20130940 AMENDED COMP A

7070309.D07/03/13 11:45 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly journetp 07/03/13 12:313.92

Methylene Chloride Peak Integrated Incorrectly journetp 07/03/13 12:314.38

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LCS 180-76559/7

7070313.D07/03/13 13:48 GC Column: DB-624 ID: 0.18(mm)

Trichlorofluoromethane Peak Integrated Incorrectly journetp 07/03/13 14:483.01

Acetone Peak Integrated Incorrectly journetp 07/03/13 14:483.76

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP7 76559

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-8 MS #20130940 AMENDED COMP A MS

7070314.D07/03/13 14:21 GC Column: DB-624 ID: 0.18(mm)

Chloroethane Peak Integrated Incorrectly journetp 07/03/13 14:512.60

Trichlorofluoromethane Peak Integrated Incorrectly journetp 07/03/13 14:502.91

1,1-Dichloroethene Peak Integrated Incorrectly journetp 07/03/13 15:283.58

Methyl acetate Peak Integrated Incorrectly journetp 07/03/13 14:504.28

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-8 MSD #20130940 AMENDED COMP A MSD

7070315.D07/03/13 14:53 GC Column: DB-624 ID: 0.18(mm)

Chloroethane Peak Integrated Incorrectly journetp 07/03/13 15:262.61

Trichlorofluoromethane Peak Integrated Incorrectly journetp 07/03/13 15:272.91

1,1-Dichloroethene Peak Integrated Incorrectly journetp 07/03/13 15:273.60

Methyl acetate Peak Integrated Incorrectly journetp 07/03/13 15:264.28

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-9 #20130943 AMENDED COMP D

7070319.D07/03/13 16:49 GC Column: DB-624 ID: 0.18(mm)

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/04/13 00:453.96

Methylene Chloride Peak Integrated Incorrectly zukowskim 07/04/13 00:454.42

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-10 #20130944 AMEDNED COMP E

7070320.D07/03/13 17:15 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly zukowskim 07/04/13 00:483.80

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/04/13 00:473.94

GC/MS VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:HP7 76559

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-11 #20130946 AMENDED COMP G

7070321.D07/03/13 17:40 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly zukowskim 07/04/13 00:493.78

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/04/13 00:493.93

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-12 #20130949 AMENDED COMP J

7070322.D07/03/13 18:06 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly zukowskim 07/04/13 00:533.77

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/04/13 00:523.93

Methylene Chloride Peak Integrated Incorrectly zukowskim 07/04/13 00:534.41

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-13 #20130955 AMENDED COMP P

7070323.D07/03/13 18:31 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly zukowskim 07/04/13 00:543.78

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-14 #20130959 AMENDED COMP T

7070324.D07/03/13 18:57 GC Column: DB-624 ID: 0.18(mm)

Acetone Peak Integrated Incorrectly zukowskim 07/04/13 00:553.78

Carbon disulfide Peak Integrated Incorrectly zukowskim 07/04/13 00:553.90

Methylene Chloride Peak Integrated Incorrectly zukowskim 07/04/13 00:564.40

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:722 74231

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/1

F06060C1.D06/05/13 22:26 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 07:592.45

2,4-Dinitrophenol Peak Integrated Incorrectly bungardf 06/06/13 00:459.26

2,4,6-Tribromophenol Peak Not Found addisonc 06/07/13 08:069.97

Bis(2-ethylhexyl) phthalate Poor Chromatography addisonc 06/07/13 08:0114.45

Di-n-octyl phthalate Poor Chromatography addisonc 06/07/13 08:0115.84

Benzo[k]fluoranthene Unspecified bungardf 06/06/13 00:4716.77

Indeno[1,2,3-cd]pyrene Poor Chromatography addisonc 06/07/13 08:0519.96

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/2

F06060C2.D06/05/13 22:53 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Peak Integrated Incorrectly bungardf 06/06/13 00:481.70

N-Nitrosodimethylamine Peak Integrated Incorrectly bungardf 06/06/13 00:482.29

Pyridine Poor Chromatography addisonc 06/07/13 08:062.40

Benzoic acid Peak Integrated Incorrectly bungardf 06/06/13 00:497.20

2,4-Dinitrophenol Peak Integrated Incorrectly bungardf 06/06/13 00:509.24

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:0810.45

Dibenz(a,h)anthracene Poor Chromatography addisonc 06/07/13 08:0819.97

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/3

F06060C3.D06/05/13 23:19 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:112.38

Benzoic acid Poor Chromatography addisonc 06/07/13 08:127.21

2,4-Dinitrophenol Peak Integrated Incorrectly bungardf 06/06/13 00:539.24

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:1210.44

8270C

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:722 74231

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-74231/4

F06060C4.D06/05/13 23:46 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:132.37

Benzoic acid Poor Chromatography addisonc 06/07/13 08:147.23

2-Chloronaphthalene Peak Not Found addisonc 06/07/13 08:148.67

Hexadecane Poor Chromatography addisonc 06/07/13 08:159.59

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:1510.45

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/5

F06060C5.D06/06/13 00:13 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:162.35

Benzoic acid Poor Chromatography addisonc 06/07/13 08:177.24

2-Chloronaphthalene Poor Chromatography addisonc 06/07/13 08:178.67

2,4-Dinitrophenol Peak Integrated Incorrectly bungardf 06/06/13 00:559.23

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:1810.44

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/6

F06060C6.D06/06/13 00:40 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:182.36

Benzoic acid Peak Not Found addisonc 06/07/13 08:197.27

2,4-Dinitrophenol Peak Integrated Incorrectly bungardf 06/06/13 01:049.24

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:2010.44

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:722 74231

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/7

F06060C7.D06/06/13 01:07 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:512.35

Benzoic acid Poor Chromatography addisonc 06/07/13 08:527.28

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:5210.44

Benzo[b]fluoranthene Poor Chromatography addisonc 06/07/13 08:5316.69

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-74231/8

F06060C8.D06/06/13 01:33 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography addisonc 06/07/13 08:532.34

Benzoic acid Poor Chromatography addisonc 06/07/13 08:547.29

1,3-Dinitrobenzene Unspecified bungardf 06/06/13 02:058.94

Hexadecane Unspecified bungardf 06/06/13 02:139.58

Pentachlorophenol Poor Chromatography addisonc 06/07/13 08:5510.44

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:722 76804

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCVIS 180-76804/21

F07070C1.D07/07/13 23:43 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/08/13 00:312.30

Benzoic acid Peak Integrated Incorrectly bungardf 07/08/13 00:327.19

Pentachlorophenol Peak Integrated Incorrectly bachas 07/09/13 12:0610.38

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

LCS 180-76477/2-A

F0707014.D07/08/13 05:27 GC Column: Rxi-5SilMS ID: 0.32(mm)

N-Nitrosodimethylamine Peak Integrated Incorrectly bungardf 07/08/13 21:082.21

Pyridine Peak Integrated Incorrectly bungardf 07/08/13 21:082.27 bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/08/13 21:086.45

Pentachlorophenol Peak Integrated Incorrectly bungardf 07/08/13 21:1010.34

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-9 MS #20130943 AMENDED COMP D MS

F0707015.D07/08/13 09:03 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/08/13 21:112.29 bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/08/13 21:116.45

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-9 MSD #20130943 AMENDED COMP D MSD

F0707016.D07/08/13 09:30 GC Column: Rxi-5SilMS ID: 0.32(mm) bis (2-chloroisopropyl) ether Peak Integrated Incorrectly bungardf 07/08/13 21:166.45

Benzidine Peak Integrated Incorrectly bungardf 07/08/13 21:1712.03

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/08/13 21:1720.23

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:722 76804

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-1 #20130918 COMPOSITE A

F0707017.D07/08/13 09:57 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[k]fluoranthene Peak Not Found bungardf 07/08/13 21:1916.45

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-2 #20130921 COMPOSITE D

F0707018.D07/08/13 10:24 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[a]pyrene Peak Integrated Incorrectly bungardf 07/08/13 21:2017.13

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/08/13 21:2119.57

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/08/13 21:2120.22

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-3 #20130924 COMPOSITE G

F0707019.D07/08/13 10:51 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/08/13 21:2216.47

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/08/13 21:2219.57

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/08/13 21:2319.60

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-4 #20130927 COMPOSITE J

F0707020.D07/08/13 11:19 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/08/13 21:2416.47

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/08/13 21:2519.55

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/08/13 21:2519.59

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/08/13 21:2520.20

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:722 76930

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

CCVIS 180-76930/16

F07080C1.D07/08/13 22:38 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Peak Integrated Incorrectly bungardf 07/08/13 23:512.28

Benzoic acid Peak Integrated Incorrectly bungardf 07/08/13 23:527.18

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-6 #20130937 COMPOSITE T

F0708017.D07/09/13 02:14 GC Column: Rxi-5SilMS ID: 0.32(mm)

Chrysene Peak Integrated Incorrectly bungardf 07/09/13 02:3614.26

Benzo[b]fluoranthene Peak Integrated Incorrectly bungardf 07/09/13 02:3716.41

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/09/13 02:3716.44

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/09/13 02:3719.56

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/09/13 02:3820.19

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-7 #20130922 COMPOSITE E

F0708018.D07/09/13 02:42 GC Column: Rxi-5SilMS ID: 0.32(mm)

Fluorene Peak Integrated Incorrectly bungardf 07/09/13 03:089.63

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-8 #20130940 AMENDED COMP A

F0708019.D07/09/13 03:09 GC Column: Rxi-5SilMS ID: 0.32(mm)

Anthracene Peak Integrated Incorrectly bungardf 07/09/13 03:3410.60

Benzo[b]fluoranthene Peak Integrated Incorrectly bungardf 07/09/13 03:3416.44

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/09/13 03:3516.48

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/09/13 03:3519.62

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:722 76930

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-9 #20130943 AMENDED COMP D

F0708020.D07/09/13 03:37 GC Column: Rxi-5SilMS ID: 0.32(mm)

Diethyl phthalate Peak Not Found bungardf 07/09/13 04:019.47

2,4,6-Tribromophenol Peak Integrated Incorrectly bungardf 07/09/13 04:039.86

Benzo[k]fluoranthene Peak Not Found bungardf 07/09/13 04:0216.48

Benzo[a]pyrene Peak Integrated Incorrectly bungardf 07/09/13 04:0217.12

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/09/13 04:0219.57

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/09/13 04:0319.61

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-10 #20130944 AMEDNED COMP E

F0708021.D07/09/13 04:04 GC Column: Rxi-5SilMS ID: 0.32(mm)

Chrysene Peak Integrated Incorrectly bungardf 07/09/13 21:0914.27

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/09/13 21:1019.57

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/09/13 21:1019.61

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/09/13 21:1020.22

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-11 #20130946 AMENDED COMP G

F0708022.D07/09/13 04:31 GC Column: Rxi-5SilMS ID: 0.32(mm)

2,4,6-Tribromophenol Peak Integrated Incorrectly bungardf 07/09/13 21:119.86

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/09/13 21:1119.56

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/09/13 21:1120.19

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:722 76930

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-12 #20130949 AMENDED COMP J

F0708023.D07/09/13 04:58 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzo[b]fluoranthene Peak Integrated Incorrectly bachas 07/11/13 15:2116.46

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/09/13 21:1219.62

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/09/13 21:1320.27

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-13 #20130955 AMENDED COMP P

F0708024.D07/09/13 05:26 GC Column: Rxi-5SilMS ID: 0.32(mm)

2,4,6-Tribromophenol Unspecified bungardf 07/09/13 21:159.86

Chrysene Peak Integrated Incorrectly bungardf 07/09/13 21:1414.27

Benzo[k]fluoranthene Peak Integrated Incorrectly bungardf 07/09/13 21:1416.48

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/09/13 21:1419.60

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-14 #20130959 AMENDED COMP T

F0708025.D07/09/13 05:53 GC Column: Rxi-5SilMS ID: 0.32(mm)

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/09/13 21:1619.59

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/09/13 21:1620.25

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

180-22654-15 SRM Sediment

F0708026.D07/09/13 06:20 GC Column: Rxi-5SilMS ID: 0.32(mm)

Indeno[1,2,3-cd]pyrene Peak Integrated Incorrectly bungardf 07/09/13 21:1719.56

Dibenz(a,h)anthracene Peak Integrated Incorrectly bungardf 07/09/13 21:1819.59

Benzo[g,h,i]perylene Peak Integrated Incorrectly bungardf 07/09/13 21:1820.21

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:731 75091

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-75091/2

V0617IC1.D06/17/13 06:41 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Peak Not Found piccolino v

06/17/13 09:061.81

N-Nitrosodimethylamine Poor Chromatography piccolino v

06/17/13 09:062.48

Pyridine Poor Chromatography piccolino v

06/17/13 09:062.60

Di-n-octyl phthalate Poor Chromatography piccolino v

06/17/13 09:0715.22

Benzo[b]fluoranthene Poor Chromatography piccolino v

06/17/13 09:0716.11

Indeno[1,2,3-cd]pyrene Poor Chromatography piccolino v

06/17/13 09:0719.13

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-75091/3

V0617IC2.D06/17/13 07:08 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Poor Chromatography piccolino v

06/17/13 09:071.81

Pyridine Poor Chromatography piccolino v

06/17/13 09:072.57

Benzoic acid Poor Chromatography piccolino v

06/17/13 09:087.21

Pentachlorophenol Poor Chromatography piccolino v

06/17/13 09:0810.31

Dibenz(a,h)anthracene Poor Chromatography piccolino v

06/17/13 09:0819.14

Benzo[g,h,i]perylene Poor Chromatography piccolino v

06/17/13 09:0819.70

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:731 75091

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-75091/4

V0617IC3.D06/17/13 07:34 GC Column: Rxi-5SilMS ID: 0.32(mm)

1,4-Dioxane Poor Chromatography piccolino v

06/17/13 09:091.81

Pyridine Poor Chromatography piccolino v

06/17/13 09:092.56

Benzoic acid Poor Chromatography piccolino v

06/17/13 09:097.22

2,4,5-Trichlorophenol Poor Chromatography piccolino v

06/17/13 09:098.44

2,4-Dinitrophenol Poor Chromatography piccolino v

06/17/13 09:099.15

2,3,4,6-Tetrachlorophenol Poor Chromatography piccolino v

06/17/13 09:109.41

Di-n-octyl phthalate Poor Chromatography piccolino v

06/17/13 09:1015.19

Dibenz(a,h)anthracene Poor Chromatography piccolino v

06/17/13 09:1019.11

Benzo[g,h,i]perylene Poor Chromatography piccolino v

06/17/13 09:1019.68

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

ICIS 180-75091/5

V0617IC4.D06/17/13 08:00 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography piccolino v

06/17/13 09:112.54

Benzoic acid Poor Chromatography piccolino v

06/17/13 09:117.24

Indeno[1,2,3-cd]pyrene Poor Chromatography piccolino v

06/17/13 09:1119.06

Dibenz(a,h)anthracene Poor Chromatography piccolino v

06/17/13 09:1119.11

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrument ID: Analysis Batch Number:731 75091

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-75091/6

V0617IC5.D06/17/13 08:27 GC Column: Rxi-5SilMS ID: 0.32(mm)

Pyridine Poor Chromatography piccolino v

06/17/13 09:122.53

Benzoic acid Poor Chromatography piccolino v

06/17/13 09:127.26

Benzo[a]anthracene Poor Chromatography piccolino v

06/17/13 09:1213.94

Benzo[a]pyrene Poor Chromatography piccolino v

06/17/13 09:1316.76

Perylene-d12 Poor Chromatography piccolino v

06/17/13 09:1216.88

Indeno[1,2,3-cd]pyrene Poor Chromatography piccolino v

06/17/13 09:1319.06

Lab Sample ID: Client Sample ID:

Date Analyzed: Lab File ID:

COMPOUND NAME RETENTION

TIME

MANUAL INTEGRATION

DATEANALYSTREASON

IC 180-75091/7

V0617IC6.D06/17/13 08:54 GC Column: Rxi-5SilMS ID: 0.32(mm)

Benzoic acid Poor Chromatography piccolino v

06/18/13 07:077.28

Benzo[g,h,i]perylene Poor Chromatography piccolino v

06/18/13 07:0819.65

GC/MS SEMI VOA MANUAL INTEGRATION SUMMARY

TestAmerica Pittsburgh 180-22654-1

Instrume…