Do_4_upland_sed_fulldata_vol_5_of_5.pdf

DFS#2 DB225ICAL_27-Mar-13 RF AND RRF LIMITS FOR METHOD 8290!1613B

RRF +20% -20% +25% .25% +15% - 15%

2378-TCDF 1.05451 1.26541 0.8436 1.3181 0.7909/ 1.2127/ 0.8963/

I 2378-PeCDF 23478-PeCDF I 23478-HxCDF 1 23678-HxCDF 234678-HxCDF 123789-HxCDF I 234678-HpCDF ' 234789HpCDF

OCDF

2378-TCDD

I 2378-PeCDD 1 23478-HxCDD 1 23678-HxCDD 1 23789-HxCDD 1 234678-HpCDD

OCDD

RRF +30% -30% +35% -35% +15% - 15%

13C-2378-TCDF 1.5971/ 2.0762 1.1180 7 2.1561 / 1.0381 1.8367/ 1.3575/

1 3C-1 2378-PeCDF I 3C-23478-PeCDF 1 3C-1 23478-HxCDF 130-1 23678-HxCDF 1 3C-234678-HxCDF I 3C-123789-HxCDF I 3C-1234678-HpCDF 1 3C-1234789-HpCDF

I 3C-2378-TCDD

1 30-1 2378-PeCDD 1 3C-123478-HxCDD 1 3C-123678-HxCDD 1 3C-1234678-HpCDD

1 3C-OCDD

3701-2378-TODD 1.1322/ 1.4719 0.7925 1.5285/ 0.7359 1.3020 0.9624

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1.22E6 mlz= 292.48188-

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2.66E5 mlz= 380.47550- 381.47550

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1.29E3 mlz= 375.7364- 375.9364

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3.35E2 m/z= 331.8370- 332.0370

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1.17E6 m/z= 292.48188- 293.48188

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2.66E5 mlz= 380.47550- 381 .47550

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Vol. 5 of 5 p.2439

Vol. 5 of 5 p.2440

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Vol. 5 of 5 p.2443

Vol. 5 of 5 p.2444

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Vol. 5 of 5 p.2446

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2.03E2 m/z= 319.7970- 319.9970

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3.48E2 mlz= 321 .7940- 321.9940

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1.27E5 mlz= 331.8370- 332.0370

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1.59E5 mlz= 333.8340- 334.0340

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Vol. 5 of 5 p.2447

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Vol. 5 of 5 p.2451

C:\XcaUbur\.. .\03271 306 3/27/2013 2:03:34 PM 52607-6408 1613 CS1

RI: 190048.0O

2016 95 100- 91Pd 150 ci)

Ct, C

-Q ci)

Ct, ci)

0:::

418 .°L 144 I ci)c) C Ct C ci)

(ci ci)

- 11Q

NL:

1008 1.11E6

6.49 m/z=

292.481 88- 293.48188 i c-MS k iñ.! ( 03271306

762 862 869 951 1055 2

9.80 42.52 42.71 44.94 68E5 mlz=

WWii /t38o .47550- 381.47550

MS

03271306

2U 22 24 25 2 30 32 34 36 38 40 42 44 46 48

Vol. 5 of 5 p.2452 g e o f

F i l e n a m e

C S

C a l

A m t s t x t

A c q u i r e d

P r o c e s s e d

R a w

D a t a

C a l

P r o c

F i l e

C S

S a m p l e t e x t

C S

5:

C o m m e n t s

T y p

N a m e

A m o u n t

Q M

A r e a

PI

ll

A r e a

P A

P T

R F

D n k

T C D F

E y

C n N

P e C D F

C n N

P e C D F

C n N

H x C D F

C n N

F i x C D F

C n N

H x C D F

C n N

F I x C D F

C n N l M p C D F

C n N

H p C D F

C n N

O C D F

C n N

T C D D l E l E y

C n N l P e C D D

C n N

H x C D D

U n k

R x C D D

C n N

H x C D D

C n k l R p C D D

U n k

O C D D

I S R T

C T C D F

E l l E y

I S

C P e C D F

I S

C P e C D F

I S

C H x C D F

I S

C H x C D F

I S

C H x C D F

I S l C H x C D F

I S

C H p C D F

I S l C l H p C D F

I S

C T C D D

E l E y

I S

C P e C D D

I S

C H x C D D

I S

C H x C D D

I S l C R p C D D

I S

C O C D D

P S c T C D D

E

E y

R S R T

C H x C D D c u p

C T C D D

E

E y

T o t

T o t a l

T e t r a F u r a n s

E

E y

E

T o t

T o t a l

T e t r a D i o x i n s

E l E y

E

T o t

T o t a l

P e n t a F u r a n s n

T o t

T o t a l

P e n t a D i o x i n s n

T o t

T o t a l

H e x a F u r a n s n

T o t

T o t a l

H e x a D i o x i n s fl

T o t

T o t a l

H e p t a F u r a n s n

T o t

T o t a l

H e p t a D i o x i n s n

Vol. 5 of 5 p.2453

C:\XcaUbur\..\03271 307 3/27/2013 2:55:08 PM 52607-64-09 1613 CS2

RT: 19.87-33.13 SM: 5G

I

CO

Co Co

03271307

NL:

2.37E3

N- miz-

303,8020- 304.0020

MS ICIS

U) CD 0)0) c.

0 N-Co - ('4 -CDCD Co

CD

0 U')

CO ('4

..j.

2.98E3

CD

J.iju-

"4 305.9990

MS ICIS

03271307

0 cOLD o co ' U) COLD Co L'

U') CD CO

I

NL:

U) 1.08E5 Co m/z= 315.8420- 316.0420

MS ICIS

03271307

U') N- - 0 U) (N - U) Co 0) C' U) C'4Co U) CD Co U) Co - Co Co

I r r r

NL:

1.35E5

0)(0 mIz 317.8390- 318.0390

MS ICIS

03271307

' CD

/CD0) N-U) 2CO -

' ('4 00)0) N- Co CD (N CO

INL

NL:

8.71 El

N- 3751364- ('4 Lt) O

' 375.9364 MS lOIS

03271307

CON- CDt 0 U) U) ('4Q) 0C'.J t CD N-C'4 w--a)o 100-fl I U) CO

< OU 0 0 0 C\1 0 0 0) (0 N

(N CD Co - CD - 0) CO 0 0) j niii0

CD N-

CD CO

CO

CO

v- -

CD

CO

CO CD

l00

20 21 22 23 24 25 26 27 28 29 30 31 32 33

Vol. 5 of 5 p.2454

C:\Xcaiibur\...\03271 307 3/27/2013 2:55:08 PM 52607-64-09 1613 CS2

C)

QC) U,

N r N

IC)

NL:

5,79E3

C) mlz= 319.7970- 319.9970

MS ICIS

03271307

NL:

8.73E3

U) mlz=

N 321.7940- 321.9940

100 MS ICIS

03271307 p 80-

40-cj 20-

7.76E4 co N

N mlz= U, 331 .8370-

. 332.0370 100-i MS ICIS

03271307 80R

60-

40 C) C) C)

U, 20- S

.- c) N- U, N

C) N I

S U, NL:

cc) 9.74E4 U, m/z=

N 333.8340- 334.0340 lO0-i MS ICIS I 03271307

80-a

-I 60-i

40 co - I C) (.5)

N N C' N- U, IC) CO U,

N- N-

C)O - 'O (0 C)

C) •

(.5)

- N- N-

(.3 N

CO N-

19 20 21 2 23

Vol. 5 of 5 p.2455

C:\Xcalibur\...\03271307

100- iC

a) C Ct

C ci)

Ct ci)

ci) C Ca

C

-Q ci

. 4 cci

949 993 NL.730 811 942

44.89 4608 1.19E68 93 41.13 44JQ.

m/z=

MS

03271307

1U 100 136 895 '(

92719.35 2t80 22.77

298 28.13 410 454 511 668 776 434244.02 4429

I 3142 3297 3724 4018

3/27/2013 2:55:08 PM 52607-64-09 1613 CS2

2.77E5 mlz= 380.47550- 381.47550

MS

03271307

20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 Time (mm)

374 493

Vol. 5 of 5 p.2456 g e o f

F i l e n a m e

C S

C a l

A m t s t x t

A c q u i r e d

P r o c e s s e d

R a w

D a t a

C a l

P r o c

F i l e

C S

S a m p l e t e x t

C S

S:

C o m m e n t s

T y p

N a m e

A m o u n t

Q N

A r e a

P

A r e a

R A

R T

R F

U n k

T C D F l E y

U n k

P e C D F

U n k

P e C D F

U n k

H x C D F

U n k

H x C D F

U n k

H x C D F

U n k

H x C D F

C o t

H p C D F l in k

-H p C

D F l i n k

O C D F l i n k

T C D D y

U n k

P e C D D l i n k

H x C D D l in k

-N x

C D

D l i n k

H x C D D l i n k

H p C D D l i n k

O C D D

I S R T

C T C D F

E l E y

I S

C P e C D F

I S

C P e C D F

I S l C l H x C D F

I S

C N x C D F

I S

C H x C D F

I S

C H x C D F

I S

C H p C D F

I S

C H p C D F

I S l C T C D D

E

E y

I S

C P e C D D

I S

C N x C D D

I S

C H x C D D

I S

C H p C D D

I S

C O C D D

R S

C T C D D

E y

R S R T

C H x C D D

C U p

C T C D D y

T o t

T o t a l

T e t r a F u r a n s

E l E y

T o t

T o t a l

T e t r a D i o x i n s y

T o t

T o t a l

P e n t a F u r a n s n

T o t

T o t a l

P e n t a D i o x i n a n

T o t

T o t a l

H e x a F u r a n s fl

T o t

T o t a l

H e x a D i o x i n s n

T o t

T o t a l

H e p t a F u r a n s n

T o t

T o t a l

H e p t a D i o x i n s n

Vol. 5 of 5 p.2457

C:\Xcalibur\...\03271308 3/27/2013 3:46:32 PM 52607-64-10 1613 CS3

RT: 19.87 - 3313 SM: 5G

I

CD

-co ce.)

U, C)

N- C) C)

N- C) fL

I

1)

IC)

NL

1.52E4 mlz= 303.8020- 304.0020

MS ICIS

03271308

(0

IC)

NL:

1.90E4 m/z

Iu- 3059990

MS ICIS

03271308

CD

N- co Q (0 Co c) CO C) ,- CD c) i i ci)0 100

C -

0.

< N- cC

- (0 -C) C)

(0 CO

C) CD - ON-

C) C) (OCN

I r c

c) N- c0c)

IC) (0 N-CD

C) - O)-

U-

(0 CD

100-

C."

CD

(0cv, mlz=

315.8420- 316.0420

MS ICIS

03271308

C) U)

CO

L

CD

0) N-

(0 CO

U) 00 - cJ- CD

317.8390- 318.0390

MS ICIS

03271308

NL:

1.18E2 mIz 375.7364-

'-. . 375.9364 çf)

C) 'MS ICIS

- 0327l308

20 21 22 23 24 25 26 27 28 29 30 31 32 33

Vol. 5 of 5 p.2458

C:\Xcalibur\...\03271308 3127/2013 3:46:32 PM 52607-64-10 1613 CS3

RT: 18.33 -27.94 SM: 5G

Co aD C) C) co

NN- N-

O)N N -

CO() 03

20-

I)

U) 80-

-Q

C) CO C) IC) 03 C) CO CO

It) N- N- N It) CO CO IC) r (V) r cC r r N

C) N- N C) C)

'- C) C) N co C)

N IC)

CO N-

N- N-

N

C) N C)

NL:

1.17E4 mlz= 31 9.7970- 319.9970

MS ICIS

03271308

C)

NL:

1.46E4 mlz= 321.7940- 321 .9940

MS ICIS

03271308

NL:

1.04E5 mlz= 331.8370- 332.0370

MS ICIS

03271308

C)

10 CON N-'C)

'-v- 100) N-COIC)

CO N- 0) N It)

;L

CO

N N

CO

- N-

CO '

A A

IC)

C) 100)COC)'- CO

0 N- 0) C) 10 r

CO N

'-CO -Co

N- N-N- CO 0310

C)

N

CO

co

II IJ I II IjIl Eli I II

19 20 21 22 23 24 25 26 27

N L:

1. 31 E5 m/z 333.8340- 334.0340

MS ICIS

03271308

Vol. 5 of 5 p.2459

C:\Xcalibur\...\03271308

RT: 1900 - 48.00

28 138 212 248

19.83 100: 22.82 24.83 25.81 a) ci)

Cu U)

3/27(2013 3:46:32 PM 52607-64-10 1613 CS3

I

532 578 672 689 699 789 860 977 354 38.0840.53 42.46 45.64

NL:

1.21 E6

m/z

292.48 1 88-

293.481 88

MS

03271308

NL:

2.70E51046

903 1007 47.52 m/z= 380.47550-43.63 46.46 381 .47550

MS

03271308

a) C Cu C

ci) cu ci)

I

20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 Time (mm)

493 597 649 fl 729 100: 21.52 25.87 2715 28.83

32.48 35.31 36.72 38.52 38.90 vv 90-i t A .M A

Vol. 5 of 5 p.2460 g e o f

F i l e n a m e

C S

C a l

A m t s t x t

A c q u i r e d

P r o c e s s e d

R a w

D a t a

C a l

P r o c

F i l e

C S

S a m p l e t e x t l l

C S

S:

C o m m e n t s

T y p

N a m e

A m o u n t

Q M

A r e a

R N

A r e a

P A

R T

R F

U n k

T C D F

E y

U n k

P e C D F

U n k

P e C D F

U n k l H x C D F

U n k

H x C D F tJ nk

H x C D F

U n k

H x C D F

U n k

N p C D F

U n k

H p C D F

U n k

O C D F

U n k

T C D D l E y

U n k

P e C D D

U n k

H x C D D

U n k

H x C D D

U n k l H x C D D

U n k

H p C D D

U n k

O C D D

I S R T

C T C D F

E y

I S

C P e C D F

I S

C P e C D F

I S

C H x C D F

I S l C H x C D F

I S

C H x C D F

I S

C H x C D F

I S l C M p C D F

I S l C H p C D F

I S

C T C D D y

I S

C P e C D D

I S l C l H x C D D

I s l C l H x C D D

I S

C H p C D D

I S

C O C D D

R S l C T C D D y

R S R T l C H x C D D

C U p

C T C D D l l O E

E y

T o t

T o t a l

T e t r a F u r a n s

E y

T o t

T o t a l

T e t r a D i o x i n s

E y

E O l

T o t

T o t a l

P e n t a F u r a n s fl

T o t

T o t a l

P e n t a D i o x i n s n

T o t

T o t a l

H e x a F u r a n s n

T o t

T o t a l

H e x a D i o x i n a

T o t

T o t a l

H e p t a F u r a n s

T o t

T o t a l

H e p t a D i o x i n s

Vol. 5 of 5 p.2461

C:\Xcalibur\...\03271 309 3/27/2013 4:37:56 PM 52607-64-11 1613 CS4

RT: 19.87-33.13 SM: 5G

NL:

7.20E4

Co mlz= 303.8020- 304.0020

MS ICIS

100- 03271309

Co Co

UV çj CN Co Li') Co C) CO '' Co

C) Co N C) N- - CO C) N- N- Co CJ

0 . ___________________________NL:

8.85E4 Coo mlz= fir' Co )U3JU-

305.9990

MS ICIS

100T 03271309

C'J Co

C)) Co co 0U Li) 'J 14') . 'j U') . CO Co . C) (N

Co j' Co C) C) - (N ' Co N- Co i.69E5 o m/z=

315.8420- 316.0420

MSICIS

03271309

NL:

2.14E5 cC) Co mlz=

317.8390- 318.0390

N MSICIS

100- 11 03271309

Co v- Co U') 0) Co CO C)

- CO ' Co 0 Co Co U') CO

CO v- U') Co Co C) U') C) CO ' CC)

4rr;

4.69E2 mlz= 375.7364-co 375.9364

MSICIS

100- 03271309

I I I I I I I I I I I I I I I I I I I 20 21 22 23 24 25 26 27 28 29 30 31 32 33

Vol. 5 of 5 p.2462

C:\Xcalibur\...\03271 309 3/27/2013 4:37:56 PM 52607-64-111613 CS4

NL:

C) 5.79E4 cc m/z

319.7970- 319.9970

MS ICIS

100- 03271309

E .

0- rr

IN L

7.33E4 cc mlz=

321,7940- 321.9940

MS ICIS

100- 03271309 ci)

80- Cci V Ic -

I C) C)

Ar'> '.ttJ cc cc N -cc

- CD C)

cc U)

(N C) U)

N-

N- C) U)

CD

(N

CD

C)

CD - (N c) Co - cc

- cc c) co cc N- (N t

- C) U) - C) - cc cc u cc cc c C') C') cc '- r '- r

C') C) U)

CD

C)(N co (N CD

(N

U') L cc N-

Co N-t

N -rp ii T I I I i T I I

19 20 21 22 23 24 25 26 F

N- cc (N CD -Co cc C') QN-r r cc r r t26E5 mlz= 331.8370- 332.0370

MS ICIS

03271309

NL:

1.54E5 rnIz 333.8340- 334.0340

MS ICIS

03271309

Vol. 5 of 5 p.2463

C:\Xcalibur\...\03271309 3/27/20134:37:56 PM 52607-64-111613 CS4

RT: 19.00 -48.00

96 109 211

21.69 22.04 24.8100-: . . .

I) C Co a)

Co

I

a) C (0

C ci)

CO

ci)

NL:

1.1 8E6 mlz= 292.48188- 293.48188

MS

03271309

2.80E5 mlz= 380.47550- 381.47550

MS

03271309

20 22 24 26 28 30 32 34 36 38 40 42 44 46 48

Vol. 5 of 5 p.2464 g e o f

F i l e n a m e

C S

C a l

A m t s t x t

A c q u i r e d

P r o c e s s e d

R a w

D a t a

C a l

P r o c

F i l e

C S

S a m p l e t e x t

C S

S:

C o m m e n t s

T y p

N a m e

A m o u n t

Q N

A r e a

R M

A r e a

P A

R T

R F

Li nk

T C D F

E l l E y

Li nk l P e C D F

Li nk

P e C D F

Li nk

H x C D F

T

Jn k

H x C D F

Li nk H x C D F

Li nk

E x C D F

S

TJ

nk

H p C D F

Li nk H p C D F

L in k

O C D F

L in k

T C D D

E

E y

L in k

P e C D D

L in k

H x C D D

L in k

H x C D D

L in k

H x C D D

L in k

N p C D D

L i n k

O C D D

I s R T

C T C D F l E l E y

I S

C l P e C D F

I S

C P e C D F

I S

C H x C D F

I S

C H x C D F

I S

C H x C D F

I S

C H x C D F

I S

C H p C D F

I S

C H p C D F

I S l C T C D D l E y

I S

C P e C D D

I S

C H x C D D

I S

C H x C D D

I S

C H p C D D

I S

O C D D

R S

C T C D D

E y

R S R T

C H x C D D

C L i p

C l T C D D

E y

T o t

T o t a l

T e t r a F u r a n s

E l l E y

T o t

T o t a l

T e t r a D i o x i n s

E y l E

T o t

T o t a l

P e n t a F u r a n s fl

T o t

T o t a l

P e n t a D i o x i n s n

T o t

T o t a l

H e x a F u r a n s n

T o t

T o t a l

H e x a D i o x i n s fl

T o t

T o t a l

H e p t a F u r a n s fl

T o t

T o t a l

H e p t a D i o x i n s

II

Vol. 5 of 5 p.2465

C:\Xcalibur\,..\03271310

- LU Co C) LU Co LU -

JLI Co Co Co LU LU 0)

- Co Co C) N- C) C)

- - - CO CJ C'.l CO r Co C) CO - Co

C) N. CO CO -

Co 0) Co 'r CO

(N Co - N.

I)0100 C Co

C rrt Co

*3) T '

CO

0-

CO 0) LU

N--LO Co N.'- Co '- Co

(N LU

(N

Co Co (N (N LU Co cCo

(N - (NO)

Co Co N.

Co

I

3/27/2013 5:29:30 PM 52607-64-12 1613 CS5

Co

CO

CO

Co

/LU

C)

C) PCN COCo

LU-

14; iU Co Co Co

LU

(0 0) Co

LU

Co

JL

0)

- - 0) Co (N 0) i i N.

C) Co (N (N

LU

CO

CN

LU

Co 0) (0

C) 0)

CO

Co C) Co Co N-

NL

3.71E5 mlz= 303.8020- 304.0020 MS tC!S 03271310

LU

Co C) Co

N -

4.66E5 mIz= Ub. f9U-

305.9990

MS ICIS

03271310

N-

CO

CO

N-

CO

Co

Co t

NL

1. 81 E5 m/z= 315.8420- 316.0420

MS ICIS

03271310

(Nt- LU N-(N 'J- CoCoCo

Ui 2.26E5 m/z= 317.8390- 318.0390

MS ICIS

03271310

C) '- (N

LU

r

C) C)

LU

Co

0) N- (N

NL:

2.21E3 m/z= 375.7364- 375.9364

MS ICIS

03271310

20 21 22 23 24 25 26 27 28 29 30 31 32 33 Time(min)

Vol. 5 of 5 p.2466

C:'Xcalibur\.\03271310 3/27/2013 5:29:30 PM 52607-64-12 1613 CS5

I

0-

O

C)

NO)

N-C)

C)

CO

N

LU

CO

C)

100-i U) C-) C C', C -

-Q

CLU 'j- LU

- cTh LU

C', - 0)N- (0 20-ii-

NL:

2.85E5

LU

(V.) mlz=

319.7970- N

3199970

MS !C!S

03271310

C1) N N.

(I) (1)

NL

3.65E5 mlz= 321.7940- 321 9940.

MS ICIS

03271310

C) Co 0)

0) N.

(0 C.0 N (0

LQ CO

LU CD (I) (0 N. 'J- C1) Co N. CO -

0) LU 0)0 (0 (0 - 14) N CO N - N.

20- LU - N. c') (1) N. N v' C') CO '-

QL rU r-

(00) N-

CO

LU N.

80-

60-

40- 14) N. o - _ (0

(1) N. 0 N. (0 LU 0 LU

0 - C) 0 (1) (0 N(0N

20- - N. N. - 0) LU N. Co 0)

- L __________I I I I I I I I I I 19 20 21 22 23 24 25 26 27

Time (mm)

NL:

1.25E5 m/z= 331.8370- 332.0370

MS ICIS

03271310

NL:

1.56E5 miz= 333.8340- 334.0340

MS ICIS

03271310

Vol. 5 of 5 p.2467

C:\Xcalibur\. .\03271 310 3/2712013 5:29:30 PM 52607-64-12 1613 CS5

RT: 19.00 - 48.00

78 98 227 350 386 425 461 lao, 21.19 2.1.74 25.25 28.59 29.57 30.63

ci) C-, C', C

-o ci)

(ti U) a:

I

ci) C Cu C

-o

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6 379

NL:

1055 1.17E6

47.77 mlz= [292.481 88-

293.48188

MS

03271310

NL:

1061 2.61E5

17.93 mlz=

380.47550- 381.47550

MS

03271310

615 649 768 i

L 4 Zb ti 30 32 34 36 38 40 42 44 46 48

Vol. 5 of 5 p.2468

C:\Xcalibur\...\03271 311 3/27/2013 6:21:06 PM decane blank

RT:19.87 - 33.13 SM: 5G

NL:

1,46E3 m/z= 303.8020- 304.0020

1.68E3 C) m/z= 305.7990- 305.9990 MS lOIS

3.76E2

R c 3160420

032713i1

50 ILA

a)

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3.27E2 c.'J mlz= 317.8390-c.J 0 ..(C

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9.23E3 c\J -C\J N.

z- 375.7364-

100-i .. 3759364

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03271311

20 21 22 23 24 25 26 27 28 29 30 31 32 33 Time(min)

- 3

Vol. 5 of 5 p.2469

C:\Xcalibur\...\03271 311 3/27/2013 6:21 :06 PM decane blank

I

Co C)

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5.74E3

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MS C!S

03271311

N- 9.09E3 0)Co mIz(N

321.7940- 321.9940

MS ICIS

03271311

NL:

2.05E2

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331 .8370- 332.0370

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Co (N)0) (0 03271311

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E f140- Al J I I 20-

01 I I I I I I I F I 1.1 I I I I I 1 F I I 11 19 20 21 22 23 24 25 26 27

Time (mm)

2.91E2 m/z 333.8340- 3340340 MS lOIS 03271311

Vol. 5 of 5 p.2470

C:\XcaUbur\..\03271 311

100n1918 83 116 19321.33 2222

ci) C.)

ci) ci)

296109 184 97R4 356

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3/27/2013 6:21:06 PM decane blank

607 654

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1.20E6 mlz=

292.48 1 88- 293.48188

MS

03271311

NL:

2.62E5 mlz= 380.47550- 381.47550

MS

03271311

330 470 481 ci

22 24 2b 2 30 32 34 36 38 40 42 44 46 48

Vol. 5 of 5 p.2471

Vol. 5 of 5 p.2472

F i l e n a m e

C S

C a l

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S a m p l e t e x t

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Vol. 5 of 5 p.2473

C:\Xcalibur\..\03271312

0) 0)

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CDC)(N (0 ('4

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1.81E4 m/z 303,8020- 304.0020

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03271312

C) Co Co

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2.23E4 m/z 305.7990- 305.9990

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03271312

0)

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NL:

1.72E5 mlz= 315.8420- 316.0420

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03271312

C)

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2.15E5 mIz 317.8390- 318.0390

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03271312

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3/27/2013 7:13:53 PM

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Vol. 5 of 5 p.2474

C:\)(calibur\..;\03271312

3/27/2013 7:13:53 PM 52607-35-02 1613 Well CS3

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Vol. 5 of 5 p.2475

C:\Xcalibur\...\03271312 iT 19.00 - 48.00 120 130 202

a) C) a)

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292.48 188- 293.48188

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D3271312

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2.65E5 mlz= 380.47550- 381.47550

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03271312 i 54 3b 38 40 42 44 46 48

Vol. 5 of 5 p.2476

F i l e n a m e

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A m t s t x t

R a w

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S a m p l e t e x t

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C:\Xcalibur\...\03271313

CD

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Vol. 5 of 5 p.2479

C:\Xcalibur\...\03271313 3/27/2013 8:06:37 PM 5260767-02 WS+CP+CS3

FT: 19.00-48.00

20 16 132 209 276 285 365 ioo, 22.66 24.76 26.58 '9A

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Vol. 5 of 5 p.2480

C:\Xcalibur\...\03271314

RI: 26.65 - 27.89 SM: 3G

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3/27/2013 8:58:03 PM

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Vol. 5 of 5 p.2481

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C:\Xcalibur\...\03271314

RT: 19.00 - 48.00

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ci) C

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3/27/2013 8:58:03 PM

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03271314

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Vol. 5 of 5 p.2507

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Vol. 5 of 5 p.2513

Vol. 5 of 5 p.2514

D D

P C D F

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Vol. 5 of 5 p.2519

Vol. 5 of 5 p.2520

D D

P C D F

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L A B E L E D

C O N F O U N D S

D D D l C T C D D l C l P e C D D l C H x C D D l C l H x C D D l C l H p C D D l C O C D D l C T C D F l C l P e C D F l C P e C D F l C l H x C D F l C l H x C D F l C l H X C D F l C H x C D F l C l H p C D F l C l H p C D F

C L E A N U P

S T A N D A R D

C T C D D

C

P a g e o f u n i t s g m

D F S m

Z B p g

S P I K E

C O N C

C O N C

F O U N D

H

I O N

R A T I O

Vol. 5 of 5 p.2521 g e o f

A c q u i r e d

P r o c e s s e d

C a l

D B I C A L

R e s u l t s i i

S

C o m m e n t s

Q M

A r e a

R t

A r e a

R A

R T

C o n c

T o x

D L

R e c

O C D F y

/5 -P eC D

E e C D F

:C D

E

-i x

C D F

C

D t

C F

C J F

T C D D y

-P c

C D

D x C D D x D

D D D

C D D

T C D F y

C F

P e C O F

H C D F

Hx C

DF

I

CD

E

I C D F lC

IF

I o i u p u i l

C C D D y l C I

P e C D D

I

C D D l l i

H C D D

H p C D D

C C D D

I T C D D y

C

D D

C

T C D D y

I a f e t a u r a n s y

T o t

T

I n

D l o x l n s

T o t r l u r n s

T o t

-E I o x rn s u ra n i x I i s r o n

Vol. 5 of 5 p.2522

53720-85-02 20130918

NL:

4,98E2 mlz= 303.8020- 304.0020

MS ICIS

07281306

NL:

6,33E2 m/z= 305.7990- 305.9990

MS ICIS

07281306

D C cr N- Q(D cc cc cc

IC)

cc cc 00

U) 't 0)

IC) IC)

cc cc

N-

IC)

N-r cc

Ncc U) << < < < <

N C) N-co 'tcc

- C) cccc cc ('-I

N- cc N-tcd N tN 10 cc -.

0 10 C)

N N c cc

N cc .-cccc IC) cc IC)ctc'4 1C) O N- cc ccocc N 0) 0) N cccc 0) cc -

N cc cc N P cc N cc N

N N

NL:

1.18E4 mlz= 315.8420- 316.0420

MS ICIS

07281306

NL:

1.46E4 mIz 317.8390- 318.0390

MS ICES

07281306

NL:

3.59E1 m/z= 375,7364- 375.9364

MS ICIS

07281306

20 21 22 23 24 25 26 27 28 29 30 31 32 33 time (mm)

Vol. 5 of 5 p.2523

C:\Xcaflbur\.,.\072813\07281306 7/28/2013 5:16:22 PM

RT: 1833-27.94 SM: 5G

(0

0)

60 1

4O c)

(0

(0 aD

)L)c) (v

C)

N N- N

80- -o

-Q aD

(0

0) co N Q

N-

I

U') N-co 0)

(0

LI)

(0

53720-85-02 20130918

N

N

(")LC)

N

LI)

(0 N (0 r

N- Co Co N Co

U) (00)

N- Cot- N N- N -

19 20 21 22 23 24 25 26 27

NL:

1.76E3 mlz= 319.7970- 319.9970

MS ICIS

07281306

NL:

230E3 mlz= 321.7940- 321.9940

MS ICIS

07281306

1.73E4 mIz 331.8370- 332.0370

MS CIS

07281306

NL:

2.1 5E4 m/z= 333.8340- 334.0340

MS CIS

07281306

Vol. 5 of 5 p.2524

C:\Xcalibur\. .\07281 3\07281 306 7/28/2013 5:16:22 PM 53720-85-02 20130918

19.18 132

21.16 22.66 234 253 341 467 558 640 670 755 818 949 977

95' ' 25.43

25.95 28.34 31.77 34.24 36,47 39.60 4132 4488 ,454 a, C

D C

<5

19.18 54

20.54

22 71 19395 !1v ' 24.32

287 308 90 26.87 27.44

80-

(a C

.0

(a a, NL:

1.35E5 m/z= 292.48188- 293.48188

MS

07281306

NL:

7.88E4 mlz=

732 764 807 858 936 1018 380.47550-

3381 38.98 39.85 41.02 42.40 4453 46.76 381.47550 34.14

07281306

20 22 24 26 28 30 32 34 36 38 40 42 44 46 48

Vol. 5 of 5 p.2525

Vol. 5 of 5 p.2526

D rt e : p rn

I S Q i .n t

/2

)1

/2

/1

/2

T im e:

g /g d ry

P C D D

P C D F

A N A L Y S I S

D A T A

S H E E T

L a b

S a m p l e

I D

S a m p l e

W t V o l

I n i t i a l

C a l i b r a t i o n

D a t e

I n s t r u m e n t

I D

C C

C o l u m n

I D

S a m p l e

D a t a

F i l e n a m e

B l a n k

D a t a

F i l e n a m e

C a l

V e r

D a t a

F i l e n a m e

C o n c e n t r a t i o n

U n i t s

C O N C

D E T E C T I O N

F O U N D

L I M I T

I O N

R A T I O N

T E Q

L A B E L E D

C O M P O U N D S l C T C D D l C l P e C D D l C l H x C D D l C l H x C D D l C l H p C D D

C O C D D l C T C D F l C l P e C D F l C P e C D F

3C Hx C

DF

l C l H X C D F l C l H x C D F l C N X C D F

C l N p C D F l C l N p C D F

C L E A N U P

S T A N D A R D

C l T C D D

-8

-0

.4 u n it s gm

/2

/2

D F S m

Z B p g

P a g e o f

S P I R E

C O N C

C O N C

F O U N D

R

I O N

R A T I O

Vol. 5 of 5 p.2527 g e o f

A c q u i r e d

P r o c e s s e d

C a l

D B I C A L

R e s u l t s

1- S

C o m m e n t s

Q M

A r e a

R M

A r e a

P A

P T

C o n c

T o x

D L

F e c y

F 35 p

C F

4 2

J F

I -1

F

H p C D F

C C

C F

ID

y

0 IF

y

IF 31

F

ID

F p

I F D F

H p

ID

F j H D F

I T C D D y il l

-1

C

I y y c ta

I lO lt

F u ra n s y

T o t a r m D i p i n s

I I

F tr a n s cC p in s u r a n s o x i n p u r in s in

Vol. 5 of 5 p.2528

CAXcaUbur\...\072813\07281307 7/28/2013 6:07:56 PM

RT: 1987- 33.13 SM: 5G

C)

04 N - (') 04

COLt) N-100

CO

N-Co -' Co

80 N-

N- -i CO •, Co

60 CO Co _ 0) A (0_ LULUCOI

I - Co NII 40 H A I\i\ A9fl I\ !) /1 i\ A

CO

C)

04 (0

CO co

LO J WJL1AII

C) C

I, 40 C'() Co CO

0)Co C)

COCO

CO

(N N- Cx) 0) 04 - ('4 C) 0)

40 -N- N-

Co

LU

LU

QcOcf

C'4-CO

CO

CO

COLt)

QLU

S C) Co

Co.. Co

53720-85-06 20130920

Co N -

CO

(N N-d

NL:

9.29E3 mlz= 315 8420-.

316.0420 MS lOIS 07281307

N- '! I -

0) CO CO Co C'('

Co

0) c.4

N -

(0 C) r Co CO (0 Co

NL

1.18E4

N-mlz= 317 8390-.

318.0390 MS lOIS 07281307

Co

LU CU

(UCo

(V) N-çj

CO

Co CU

0)

Co C) CU

'- LU

Co 04 (5.4

N-

N-

LU

0) ('4L L__

NL:

CO N-

3.33E1

LU0) 0)

C)

LU L.m/z=

CO

N-(U

?375.7364 375.9364

MSICIS

.O7281307

NL:

3.91E2 mlz= 303.8020- 304,0020

MS ICIS

07281307

NL:

4.92E2 m/z= 305.7990- 305.9990

MS ICIS

07281307

20 21 22 23 24 25 26 27 28 29 30 31 32 33

Vol. 5 of 5 p.2529

C:\Xcahbur\. \07281 3\07281 307 7/28/2013 6:07:56 PM

RT: 1833-2794 SM: 5G

cc, C) L()

CD

- I CD

(OCO t C)

- cocO (0 CO

1 _______ - ____

60 I-

40 cO O ca cc,c,) c,) co co

LL(

C) cc, CC cON-N-

N-

Co N-

Co

N- ('1

N- N- C)

Co C)

CC

It)

53720-85-06 20130920

It) C-"

0(0

C"•LO

c'4 C-'

CD

0)

C-)

CD

C) CC

C-) (0 Co CO

C)

N- LU

ON-

(0 c'

(0

19 20 21 22 23 24 25 26 27 Time (mm)

NL:

126E3 m/z= 3197970- 3199970

MS CIS

07281307

NL:

183E3 mIz 3217940- 3219940

MS CS

07281307

132E4 mlz= 3318370- 3320370

MS ICIS

07281307

162E4 mlz= 333 8340- 3340340

MS CS

07281307

Vol. 5 of 5 p.2530

C:\XcaUbur\ \072813\07281307

RI: 19.00 -48.00

15119.56 208 309 lOOij , 23.18 24.73 27.47.1 a)

D C :3

-1

5.

1 9.€

IOOTJ A

a) C

C :3 a) a)

7/28/2013 6:07:56 PM 53720-85-06 20130920

NL:

429 571 579 707 817 899 942 972 1.32E5

30.74 34,60 34:82 3830 4129 43.52 44,69 45.51 mlz= A A y 4 A

'A'JfA.A i A\ 292.48188- 293.48188

MS

07281307

NL:

7.91 E4

m/z= 380.47550- 381.47550

MS

07281307

20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 flme (mm)

Vol. 5 of 5 p.2531

Vol. 5 of 5 p.2532 te

: pL

D i] i c o r

C o n c e r a ti o n U ti ts

1.

T o ta l T

E Q

S e d im e n t

/1

/2

/2

/2

T im e:

0 1 p g /n d ry

P C D D

P C D F

A N A L Y S I S

D A T A

S H E E T

L a b

S a m p l e

I D

S a m p l e

W t V o l

I n i t i a l

C a l i b r a t i o n

D a t e

I n s t r u m e n t

I D

G C

C o l u m n

I D

S a m p l e

D a t a

F i l e n a m e

B l a n k

D a t a

F i l e n a m e

C a l

T e r

D a t a

F i l e n a m e

C o n c e n t r a t i o n

U n i t s

O .1

D E

T E

C T

IO

N

L I M I T

I O N

R A T I O N

T E Q

L A B E L E D

C O M P O U N D S

C T C D D

C P e C D D

C H x C D D

C l N X C D D

C l H p C D D

C O C D D

C T C D F

C P e C D F

C P e C D F

C H x C D F l C H X C D F

C H X C D F l C H x C D F l C H p C D F l C l H p C D F

C L E A N U P

S T A N D A R D

C T C D D

P a g e o f u n i t s g m

D F S

D m

Z B p g

S P I K E

C O N C

C O N C

F O U N D

R

I O N

R A T I O

0 1:

Vol. 5 of 5 p.2533 g e o f

'1 A c q u i r e d

P r o c e s s e d

C a l

D B I C A L

R e s u l t s

S

C o m m e n t s

N a m e

Q1 A r e a

R M

A r e a

R A

R T

C o n c

T o x

D L

R e c

T C D F y

I C F C

F IF

7 2 y

3D

H

H p C D D

C E

T C D F y

P e C D F

P e D F

C

H x C D F

1 3

F i i O

N P C E F l r C

I I C D D y

P e

C

H x C D D

I

H x C D D i

H C D D

C

O C D D

2- T O D D y i C

D D

T C D D y l o t C i

O t r s F u r a n s y

T o t a l

T e t r

D i o x i n s

C t

P e n t i F u r a n s

I

I l l

P n t a D i o i n s

I i a F u r a n s o x i n s

F o c a l s a-o n

Vol. 5 of 5 p.2534

C:\Xcalibur\. .\07281 3\07281 308 7/28/2013 6:59:32 PM 53720-85-07 20130921

RT: 1987 - 33.13 SM: 5G

6O-1coQ{/ .. cO cç co fl A a 100 a)40

___ ___ I ____ ___

- c, '- co co Lf…